Dissertations / Theses on the topic 'Refuse as fuel – Ontario'
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Wu, Aiping. "Controlled Oxidation Studies of Coal/Refuse Fuel Blends." TopSCHOLAR®, 1994. http://digitalcommons.wku.edu/theses/956.
Full textAttili, Bassam Saleem. "Manufacturer [Sic] of Densified-Refuse Derived Fuel (d-RDF) Pellets and Methods for the Determination of d-RDF Pellet Densities." Thesis, North Texas State University, 1986. https://digital.library.unt.edu/ark:/67531/metadc500977/.
Full textWaite, Ian Vowles. "Refuse-derived fuel for electricity generation in the UK." Thesis, London South Bank University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.323891.
Full textBrännvall, Evelina. "Accelerate ageing of refuse-derived-fuel (RDF) fly ashes." Licentiate thesis, Luleå tekniska universitet, Geovetenskap och miljöteknik, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-17584.
Full textAskor har egenskaper som kan användas, en del askor kan t ex användas vid konstruktion av tätskikt i en deponisluttäckning. En deponisluttäckning är en flerskiktskonstruktion som skyddar miljön från t.ex. växthusgaser från deponin och hindrar vatteninträngning till avfall. Naturliga täta material som lera, syntetiska som geomembraner eller bentonitmattor eller en kombination av dessa är vanligt förekommande i sluttäckningskonstruktioner på deponier. Eftersom differentialsättningar kan uppkomma och de syntetiska materialens livslängd är osäker, är det en fördel om tjocka mineraliska konstruktioner kan användas. För dessa är materialbehovet stort och det är en stor resursbesparing om alternativa material, som aska, kan användas.Aska utsätts för åldringsprocesser både när den deponeras eller användas som byggmaterial. Materialet genomgår fysiska, kemiska och mineralogiska förändringar orsakade av t.ex. variationer av temperatur och luftfuktighet, atmosfäriska gaser eller surt regn. Aska innehåller olika farliga och ofarliga kemiska föreningar. Därför måste försiktighetsåtgärder vidtas för att undvika läckage av tungmetaller i miljön. Befintliga och nybildade mineralfaser är främst ansvariga för immobilisering eller utlakning av olika metaller och salter. Nybildade mineralfaser som lermineraler är av stort intresse på grund av deras mycket höga katjonutbyteskapacitet, svällnings- och expansionsegenskaper. Förhållandena som råder i en deponisluttäckning förväntas gynna lermineralbildning.Denna avhandling är resultatet av studier av effekten av accelererad åldring på flygaska från energiutvinning. För att förutsäga stabiliteten i flygaska som används i ett deponitätskikt har laboratorieexperiment utförts för att studera effekterna av accelererad åldring under kontrollerade förhållanden. Ett reducerat faktorförsök har gjorts för att utvärdera påverkan av fem faktorer: koldioxid (CO2), temperatur, relativ luftfuktighet (RH), tid och kvalitet på tillsatt vatten. Inflytandet av dessa faktorer på mineralomvandlingen i askan, askans syraneutraliserande förmåga (ANC) och urlakningsbeteendet har analyserats och utvärderats med hjälp av bl a multivariat dataanalys. Mineraler (ettringit och hydrocalumit) som främjar fixeringen av farliga ämnen finns i både färsk aska och prover som åldrats under atmosfäriska förhållanden men försvann efter karbonatisering. Aska som åldrats under 20 % och 100 % CO2 hade kalcit, gips / anhydrit och vaterit som huvudmineraler. Förekomsten av gips och anhydrit var direkt relaterad till temperaturnivån som askan hade åldrats i. Aska som åldrades under 20 % CO2, 65 % RH, 30 °C temperatur (motsvarande förhållandena i en deponitäckning) hade kalcit och gips/bassanit som huvudmineraler. pH-värdena i proverna varierade från 7,2 till 7,6 vilket indikerar en långt fortskriden karbonatisering. Åldrandet sänkte pH-värdena från 12,4 till 7,2 och påverkar därmed urlakningsbeteendet för många lakvattenkomponenter. Barium, Ca, Cl, Cr, Cu, Pb, K och Na minskade under tiden, medan Mg, Zn och SO4 ökade jämfört med den färska askan. Inga lermineraler upptäcktes med hjälp av XRD och SEM i varken färsk eller åldrad aska. Geokemisk modellering visade dock möjligheten för dessa mineraler att bildas och fällas ut. Lermineraler som saponit, vermikulit, krysotil och hydrotalcit kunde enligt beräkningarna bildas i lakvatten från de flesta proverna som åldrades i 3, 10 och 22 månader. Smectit, montmorillonit och illit kan bildas i lakvatten från 31 månaders åldrad aska. Bildning av smectit, montmorillonit och vermikulit skulle var värdefull på grund av deras mycket höga katjonutbyteskapacitet, vilket gynnar stabilisering / immobilisering av tungmetaller i askan.
Godkänd; 2010; 20101020 (evebra); LICENTIATSEMINARIUM Ämnesområde: Avfallsteknik/Waste Science and Technology Examinator: Professor Anders Lagerkvist, Luleå tekniska universitet Diskutant: Professor Britt-Marie Steenari, Chalmers tekniska högskola Tid: Onsdag den 17 november 2010 kl 09.30 Plats: F1031, Luleå tekniska universitet
Brooks, Cheryl L. (Cheryl Leigh). "An Analysis of Refuse Derived Fuel as an Environmentally Acceptable Fuel Alternative for the Cement Industry." Thesis, University of North Texas, 1991. https://digital.library.unt.edu/ark:/67531/metadc504331/.
Full textRobinson, Travis. "Bubbling Fluidized Bed Gasification of Biomass and Refuse Derived Fuel." Thesis, Université d'Ottawa / University of Ottawa, 2015. http://hdl.handle.net/10393/33157.
Full textHaj-Mahmoud, Qasem M. (Qasem Mohammed). "Pyrolysis Capillary Chromatography of Refuse-Derived Fuel and Aquatic Fulvic Acids." Thesis, University of North Texas, 1989. https://digital.library.unt.edu/ark:/67531/metadc331124/.
Full textAdefeso, Ismail Babatunde. "Techno-economic analysis of a gasification system using refuse-derived fuel from municipal solid waste." Thesis, Cape Peninsula University of Technology, 2017. http://hdl.handle.net/20.500.11838/2753.
Full textThe search for alternatives to fossil fuel is necessary with a view to reducing the negative environmental impact of fossil fuel and most importantly, to exploit an affordable and secured fuel source. This study investigated the viability of municipal solid waste gasification for a fuel cell system. Potential solid fuels obtained from the study in the form of refuse-derived fuel (RDF) had high heating value (HHV) between 18.17 MJ/Kg - 28.91 MJ/Kg with energy density increased from 4142.07 MJ/m3 to 10735.80 MJ/m3. The molecular formulas of RDF derived from Ladies Smith drop-off site, Woodstock drop-off site and an average molecular formula of all thirteen municipal solid waste (MSW) disposal facilities were CH1.43O1.02, CH1.49O1.19, and CH1.50O0.86 respectively. The comparative ratios of C/H were in the range of 7.11 to 8.90. The Thermo Gravimetric Analysis showed that the dehydration, thermal decompositions, char combustions were involved in the production of gaseous products but flaming pyrolysis stage was when most tar was converted to syngas mixture. The simulation of RDF gasification allowed a prediction of the RDF gasification behaviour under various operating parameters in an air-blown downdraft gasifier. Optimum SFR (steam flowrate) values for RDF1, RDF2 and RDF3 were determined to be within these values 2.80, 2.50 and 3.50 and Optimum ER values for RDF1, RDF2 and RDF3 were also determined to be within these values 0.15, 0.04 and 0.08. These conditions produced the desired high molar ratio of H2/CO yield in the syngas mixture in the product stream. The molar ratios of H2/CO yield in the syngas mixture in the product stream for all the RDFs were between 18.81 and 20.16. The values of H2/CO satisfy the requirement for fuel cell application. The highest concentration of heavy metal was observed for Al, Fe, Zn and Cr, namely 16627.77 mg/Kg at Coastal Park (CP), 17232.37 mg/Kg at Killarney (KL), 235.01 mg/Kg at Tygerdal (TG), and 564.87 mg/Kg at Kraaifontein (KF) respectively. The results of quantitative economic evaluation measurements were a net return (NR) of $0.20 million, a rate of return on investment (ROI) of 27.88 %, payback time (PBP) of 2.30 years, a net present value (NPV) of $1.11 million and a discounted cash flow rate of return (DCFROR) of 24.80 % and 28.20 % respectively. The results of the economic evaluations revealed that some findings of the economic benefits of this system would be viable if costs of handling MSW were further quantified into the costs analysis. The viability of the costs could depend on government responsibility to accept costs of handling MSW.
Guyemat, Mbourou Sarah Marielle. "Plastic waste gasification using a small scale IR reactor : experimental and modelling analysis." Thesis, Cape Peninsula University of Technology, 2016. http://hdl.handle.net/20.500.11838/2480.
Full textThe generation of municipal solid waste has increased significantly due to the exponential population growth and it has become a global issue. Gasification technology, an alternative method for waste treatment is a thermochemical process where carbon-based material are exposed to an environment deprived in oxygen, was used for this project. The aim of this thesis is to study the gasification of plastic waste which is a potential alternative energy source using infrared heaters. To achieve this goal, fundamental studies have been numerically and experimentally conducted for an infrared gasifier and subsequently establishing the temperature profile for gasification using a small scale reactor. A detailed study on low density polyethylene was conducted using Infrared Spectrometry and thermal decomposition techniques such as Thermogravimetry and Differential Scanning Calorimetry were performed to establish the temperature at which plastic pellets sample used for this research gasify. The gasification behaviour of pelletized low density polyethylene (plastic pellets) was tested and three case studies were done to evaluate the most suitable temperature profile for the reactor to gasify the low density polyethylene at high temperature for less amount of time. Subsequently, the reactor model was simulated and results validate the use of reactor at an optimum temperature of 800 °C for a gasification process with less residue content. The reactor designed for this research is fully functional and validates the temperature behaviour predicted during simulation. The experimental results show infrared heaters are suitable for gas production using this gasification process.
Gokhale, Bhushan. "Application of landfill gas as a liquefied natural gas fuel for refuse trucks in Texas." Texas A&M University, 2006. http://hdl.handle.net/1969.1/4704.
Full textLai, Wei-Chuan. "Reaction engineering of heterogeneous feeds : municipal solid waste as a model /." Thesis, Connect to this title online; UW restricted, 1991. http://hdl.handle.net/1773/9849.
Full textLiu, Yi. "Modelling and characterisation of the pyrolysis of secondary refuse fuel briquettes and biomass materials." Thesis, University of South Wales, 2010. https://pure.southwales.ac.uk/en/studentthesis/modelling-and-characterisation-of-the-pyrolysis-of-secondary-refuse-fuel-briquettes-and-biomass-materials(b5b30d2e-92ca-4e2a-926e-81e09898f5b8).html.
Full textJahani, Aghamolla. "Comparative Toxicity of Refuse-Derived Fuel Fly Ash on Two Species of Earthworms, Lumbricus terrestris and E. foetida, Using an Artificial Soil Exposure Protocol." Thesis, University of North Texas, 1991. https://digital.library.unt.edu/ark:/67531/metadc504583/.
Full textBlanco, Sanchez Paula Helena. "Nickel based catalysts for hydrogen production from the pyrolysis/gasification of refuse derived fuel (RDF)." Thesis, University of Leeds, 2014. http://etheses.whiterose.ac.uk/7414/.
Full textSukhtankar, Samir A. "Thermochemical conversion of biomass into fuels and chemicals /." free to MU campus, to others for purchase, 2003. http://wwwlib.umi.com/cr/mo/fullcit?p1418068.
Full textEmerson, Charles W. "Hydrogen energy : a study of the use of anaerobic digester gas to generate electricity utilizing stand-alone hydrogen fuel cells at wastewater treatment plants /." Online version of thesis, 2007. http://hdl.handle.net/1850/5474.
Full textNgai, Yuen-yi Helen, and 魏婉儀. "Soil genesis and vegetation growth in pulverized fuel ash and refuse landfills capped by decomposed granite." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31219780.
Full textNgai, Yuen-yi Helen. "Soil genesis and vegetation growth in pulverized fuel ash and refuse landfills capped by decomposed granite /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B19471166.
Full textNjenga, Beatrice Khamati. "Urban waste management : the potential of household refuse for use in food and fuel production in Nairobi." Thesis, University of Salford, 1998. http://usir.salford.ac.uk/26837/.
Full textMoore, Paul 1962. "The Analysis of PCDD and PCDF Emissions from the Cofiring of Densified Refuse Derived Fuel and Coal." Thesis, University of North Texas, 1990. https://digital.library.unt.edu/ark:/67531/metadc330690/.
Full textMak, Hoi-ting, and 麥凱婷. "The prospect of waste-to-energy facilities in Hong Kong." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2009. http://hub.hku.hk/bib/B43784112.
Full textSchütte, Renate. "The exploitation of methane from landfill." Thesis, Rhodes University, 1992. http://hdl.handle.net/10962/d1015949.
Full textLeung, Kei, and 梁[Qi]. "Feasibility study of waste to energy (WTE) facilities in Hong Kong." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2013. http://hdl.handle.net/10722/194584.
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Environmental Management
Master
Master of Science in Environmental Management
Yan, Binghua. "Enhanced methane gas generation by reutilization of acidogenic off-gas during two-phase anaerobic digestion of food waste." HKBU Institutional Repository, 2015. https://repository.hkbu.edu.hk/etd_oa/160.
Full textTai, Chia-Hui. "Trace Elemental Analysis of Ashes in the Combustion of the Binder Enhanced d-RDF by Inductively Coupled Plasma Atomic Emission Spectroscopy." Thesis, University of North Texas, 1988. https://digital.library.unt.edu/ark:/67531/metadc501168/.
Full textSerutla, Bokhabane Tlotliso Violet. "Potential for energy recovery and its economic evaluation from a municipal solid wastes landfill in Cape Town." Thesis, Cape Peninsula University of Technology, 2016. http://hdl.handle.net/20.500.11838/2463.
Full textLandfill gases, principally methane, CH4 are produced from the decomposition of the municipal solid wastes deposited on landfill sites. These gases can be captured and converted into usable energy or electricity which will assist in addressing energy needs of South Africa. Its capture also reduces the problems associated with greenhouse gases. The aim of this study is to estimate gases that can be produced from the Bellville landfill site in Cape Town. The landfill gas capacity was estimated using Intergovernmental Panel on Climate Change (IPCC) model. The IPCC model showed that 48 447m3/year of landfill gas capacity was determined only in 2013. The LFGTE process plant is designed in a manner of purifying landfill gas, which at the end methane gets up being the only gas combusted. As a matter of fact 14 544kg/year of gases which consists mainly methane gets combusted. The average energy that can be produced based on the generated landfill gas capacity (methane gas) is 1,004MWh/year. This translates to R1. 05million per year at Eskom’s current tariff of R2.86 /kWh) including sales from CO2 which is a by-product from the designed process plant. A LFGTE process plant has been developed from the gathered information on landfill gas capacity and the amount of energy that can be generated from the gas. In order, to start-up this project the total fixed capital costs of this project required amounted up to R2.5 million. On the other hand, the project made a profit amounted to R3.9million, the Net profit summed up to R1. 3million and the payback time of Landfill Gas ToEnergy (LFGTE) project is 4years.The break-even of the project is on second year of the plant’s operation. The maximum profit that this project can generate is around R1. 1million. The life span of the plant is nine years. Aspen plus indicated that about 87% of pure methane was separated from CO2 and H2S for combustion at theabsorption gas outletstream. I would suggest this project to be done because it is profitable when by-products such as CO2 sales add to the project’s revenues.
Attili, Bassam Saleem. "Particle size distribution and qualitative/quantitative analysis of trace metals in the combustion gas and fly ash of coal/refuse derived fuel." Thesis, University of North Texas, 1991. https://digital.library.unt.edu/ark:/67531/metadc332571/.
Full textSeres, Stephen. "The power generation sector's demand for fossil fuels : a quantitative assessment on the viability of carbon fees for the reduction of greenhouse gas emissions." Thesis, McGill University, 2001. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=31535.
Full textAltare, Gabriele, Germano Franzoni, Jarmo Harsia, and Thomas Hickey. "Latest Technology Advancements in Hydraulic Systems for Refuse Vehicle Applications: The Case of an Automated Side Loader." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-200609.
Full textPaštěka, Michal. "Návrh roštového kotle na spalování tříděného odpadu." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2016. http://www.nusl.cz/ntk/nusl-241207.
Full textŠevčík, Martin. "NEAR-INFRARED SPECTROSCOPY FOR REFUSE DERIVED FUEL : Classification of waste material components using hyperspectral imaging and feasibility study of inorganic chlorine content quantification." Thesis, Mälardalens högskola, Akademin för ekonomi, samhälle och teknik, 2019. http://urn.kb.se/resolve?urn=urn:nbn:se:mdh:diva-42376.
Full textFUDIPO
Poslusny, Matthew. "Analysis of PAH and PCB Emissions from the Combustion of dRDF and the Nondestructive Analysis of Stamp Adhesives." Thesis, University of North Texas, 1989. https://digital.library.unt.edu/ark:/67531/metadc331998/.
Full textMyo, Min Win. "Thermochemical conversion characteristics of gas and tar generation from waste biomass and plastics." Kyoto University, 2020. http://hdl.handle.net/2433/253264.
Full textMokriš, Lukáš. "Roštový kotel na spalování tříděného odpadu 70t/h,4MPa, 400°C." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2013. http://www.nusl.cz/ntk/nusl-230882.
Full textJen, Jen-Fon. "Analysis of Acid Gas Emissions in the Combustion of the Binder Enhanced d-RDF by Ion Chromatography." Thesis, University of North Texas, 1988. https://digital.library.unt.edu/ark:/67531/metadc331848/.
Full textSampaio, Raquel Paschoal. "Estudo de caso dos possíveis efeitos deletérios causados pelo combustível derivado de resíduos (CDR) em caldeiras voltadas a produção de energia elétrica queimando principalmente bagaço de cana." Universidade de São Paulo, 2015. http://www.teses.usp.br/teses/disponiveis/18/18147/tde-20072015-152703/.
Full textThe state of São Paulo produces about 58,700 tons/day waste divided by its 645 municipalities in the vicinity of about 170 sugar and alcohol mills. Given this fact, the potential is evident to make the consortium use of these two fuels in power generation. This paper investigated the potential deleterious effects that the presence of chlorine, fluoride, sodium and potassium can bring the boilers focused on the production of electric power using bagasse and refuse derived fuel (RDF). A thorough search in the international literature with the view to possible deleterious effects on biomass boilers for power generation because of consortium use of residue in the boiler integrity aspect, particularly the role played by the elements chlorine, fluorine, sodium and potassium, and then a careful analysis of the results. This analysis was conducted through a case study, considering a bubbling fluidized bed (BFB) boiler of 60 MW, burning bagasse and part of the residue of a city of 600,000 inhabitants. It was found that the residue that the city produces can be turned into RDF which will feed the boiler as an auxiliary fuel, producing electricity in a clean and sustainable manner. A parameter used to set the maximum amount of burned RDF in the boiler, was the specific chlorine, measured by the ratio between the chlorine content and the lower heating value (LHV) of the fuel. Based on the literature found, the specific chlorine was limited to 40 mg/MJ, so there is no damage to the integrity of the equipment. The consortium combustion of bagasse and RDF can be an alternative to the state of São Paulo reduce the problem of landfills for waste disposal and a possibility for the sugar and alcohol mills producing electric power for a longer period in the year, saving bagasse.
Basov, Mykhailo. "Návrh roštového kotle s přirozenou cirkulací na spalování RDF." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2017. http://www.nusl.cz/ntk/nusl-319264.
Full textKrolák, Michal. "Roštový kotel na spalování tříděného odpadu." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2018. http://www.nusl.cz/ntk/nusl-378710.
Full textVítámvás, Zdeněk. "Parní kotel na spalování tříděného odpadu 85t/h." Master's thesis, Vysoké učení technické v Brně. Fakulta strojního inženýrství, 2011. http://www.nusl.cz/ntk/nusl-229411.
Full textNobre, Catarina Pereira. "Thermochemical upgrading of Refuse Derived Fuel." Doctoral thesis, 2019. http://hdl.handle.net/10362/77043.
Full textNeves, José Luís Moreira. "Study of Refuse Derived Fuel Hydrogasification." Master's thesis, 2022. https://hdl.handle.net/10216/140759.
Full textSousa, Manuel Afonso Vidal de. "Production of methane via hydrogasification of Refuse Derived Fuel." Master's thesis, 2018. https://hdl.handle.net/10216/115404.
Full textSousa, Manuel Afonso Vidal de. "Production of methane via hydrogasification of Refuse Derived Fuel." Dissertação, 2018. https://hdl.handle.net/10216/115404.
Full textSousa, Manuel Afonso Vidal de. "Production of methane via hydrogasification of Refuse Derived Fuel." Dissertação, 2002. https://repositorio-aberto.up.pt/handle/10216/115404.
Full textCHEN, KAI-CHI, and 陳凱齊. "Refuse Derived Fuel from Agricultural wastes and Oil Sludge." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/7pfz2p.
Full text國立高雄科技大學
環境與安全衛生工程系
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The petroleum industry produces a lot of oil sludge during production process and storage, which contains amounts of hydrocarbons, is suitable for recycling and reuse as an available resource. Though the oil sludge contains high heating value, it is difficult to be ignited. In this study, waste mushroom bag with good combustion characteristics is added, and blended in different proportions to evaluate the feasibility of making refuse derived fuel (RDF). The blending ratio (weight ratio, g/g) is 8:2 (O8:M2), 7:3 (O7:M3), 6:4 (O6:M4), 5:5 (O5:M5). The results show that the combustibility(87.43, 87.37, 86.78, 86.75%) and heating value(9,176, 8,452, 7,871, 7,279 cal/g) of RDF decrease while the ratio of mushroom bag has increased. On the other hand, the results of the combustion characteristics analysis increase when the ratio of mushroom bag has increased, the comprehensive combustion characteristics are O5:M5 > O6:M4 > O7:M3 > O8:M2. According to the comprehensive evaluation and analysis results, the best ratio of oil sludge and waste mushroom bag is O6:M4(water 8.78%, ash 4.44%, combustibility 86.78%, heating value 7,871 cal/g), it can not only replace some fossil fuels as an energy source, but also assist in the treatment of agricultural waste, in line with the effective use of renewable resources, and achieves the goal of circular economy.
Wei-Cheng, Lin, and 林威呈. "Dehydrochlorination of Fuel Gas and Its Effect on Syngas for Refuse Derived Fuel Gasification." Thesis, 2003. http://ndltd.ncl.edu.tw/handle/70493404756159647835.
Full textIsaac, Kerina. "The co-combustion performance of South African coal and refuse derived fuel." Thesis, 2019. https://hdl.handle.net/10539/29052.
Full textThis research focuses on the co-firing of low-quality coal with refuse derived fuel (RDF) as a means to utilise some of the abundant high-ash coal available in South Africa as a fuel co-fired with RDF in existing pulverised fuel boilers. The use of RDF is also a means to reduce the volume of waste dumped in landfill sites. The physicochemical characteristics of the RDF, run of mine coal (ROM) and discard coal were investigated, along with the co-combustion behaviour and kinetics of the RDFs, coal and their blends at different weight ratios. The blends tested contained 85%, 70%, 50% and 25% coal with the remaining proportion made up of RDF. The gaseous emissions and ash residue from the combustion of coal, RDF and coal/RDF blends were also analysed to determine the environmental impact of co-firing with RDF. The physicochemical analysis revealed that the run-of-mine and discard coal have relatively low calorific values of 21.7 MJ/kg and 16.7 MJ/kg, respectively. The RDF samples were comprised of plastic and paper, as well as smaller amounts of other materials. The RDF sample containing mostly plastic (PL) and the other containing mostly paper (PB) were found to have higher energy contents of 31.2 MJ/kg and 22.4 MJ/kg, respectively. The thermogravimetric analysis was performed in an atmosphere of air, over a temperature range of 25 – 850°C, and the results showed that the RDF samples had lower ignition, devolatilisation, and burnout temperatures compared to the coals. The ignition temperatures for the blended fuel occurs in the lower temperature region when RDF is added to the blend, likewise the peak temperatures and burnout temperatures shifted to a lower temperature zone. The activation energies (Ea) were determined using the Coats-Redfern method. The Ea for the ROM coal of 104.4 kJ/mol, was found to reduce to 31.4 kJ/mol for 75% PB + 25% coal and 35 kJ/mol for 75% PL + 25% coal blends, respectively. The discard coal which had an Ea of 109.9 kJ/mol was reduced to 30.9 kJ/mol with the (paper blend) and 33.5 kJ/mol with the (plastic blend) for the 75% RDF + 25% coal discard blends. The analysis of the ash for the chloride and alkali metal content in the RDFs, coal samples and their blends were determined with the use of ion chromatography and X-ray fluorescence (XRF) techniques. The co-combustion ash of discard coal and RDF showed a decrease in chloride and alkali metal content as the ratio of coal was increased in the blend. The calculated slagging and fouling indices showed that as the coal ratio in the blend increases, the propensity of the fuel to slag and foul the boiler surfaces decreases. The propensity to slag was found to be low for the ash obtained from the co-fired blends, while the propensity to foul decreased from high to medium range for all the blends with less than 75% of the RDF PB. The concentration of gases emitted from the combustion and co-combustion test was determined with the aid of an MGA 11 mobile gas analyzer connected online at 1 scan per second. The co-combustion of RDF with coal showed a decrease in SO2 emissions from (387 ppm) for the discard coal to within the legislated maximum emission for South African new coal fired plants. This was attained with samples containing ˃ 15% PL and ˃ 30% PB RDF. The lowest SO2 emission of 50 ppm was achieved for the blend of 25% discard coal (C2) + 75% PL. The RDF sample (PL) emitted the highest NOx emission of 143 ppm. The peak concentration of NOx emitted was increased with the addition of RDF during co-combustion, however, the duration of the emission was greatly reduced and all samples were within the South African standard limits. There was also an increase in the emissions of CO and CO2 which could be due to the high volatile matter content of the RDF. The lowest CO2 emissions was 6000 ppm and this was achieved with the blend of 85% C2 + 15% PB. It was established in this study that the most favourable fuel blend that could be used for power generation is that of discard coal (70%) and PL (30%). This was based on the activation energy obtained from this blend, with the lowest apparent activation energies of 55.8 kJ/mol and 54.2 kJ/mol for the volatile and char combustion, respectively. This makes this blend the preferred alternative fuel to be fired in the existing pulverised fuel boilers, or other type of industrial boilers, in South Africa.
PH2020
Chang, ChinCheng, and 張志誠. "The Research on Formability of Refuse Derived Fuel (RDF-5)." Thesis, 2003. http://ndltd.ncl.edu.tw/handle/12736386351175225113.
Full text國立交通大學
機械工程系
91
RDF-5 is a fuel product recovered from combustible wastes. The producing processes of RDF-5 includes crushing, drying, separating and forming. This kind of product not only can solve the problem of municipal solid wastes but also have great advantage in recycling. This research focuses on the formability of RDF-5. After literatures survey, simplified material models such as continuum material and porous material were extruded numerically by FEM to obtain the basic relationships between extrusion pressure and extrusion parameters. On the bases of these relationships, extrusion experiments were conducted on wood saw dust and moisture contents of saw dust, extrusion ratios and half die angles were taken as controlled parameters to explore the formability of RDF-like saw dust. According to the results of experiments, the moisture content of saw dust was found to be the most significant effect on the formation of sound and solid extrusion product, while other extrusion parameters show inrelevant effect. Similar to results of metal extrusion, large extrusion ratio and higher half die angle require large forming pressure. Finally, straw, waste plastics and waste carton, which are typical ingredients in the RDF, were also extruded in the same experiment procedures to explore their formabilities. Similar results as those obtained from dust saw experiment were obtained.
Fong, Yen-Shou, and 馮彥碩. "The pellet research for rice straw in refuse derived fuel." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/25026957787957423322.
Full text國立中央大學
機械工程研究所
95
The agriculture of Taiwan developed prosperity. The treatment of agricultural wastes has been failed to deal carefully with all the time. RDF technology was used as the main shaft in this research and the agricultural wastes of rice straw carries on the discussion. The expectation can bring a good contribution for the treatment which discards the rice straw. The influential parameter of pelleting includes moisture content, mold design and pelleting pressure. The rice straw that was just gathered in nearly had 70% extremely high moisture content and was not suitable for pelleting, so regard reducing moisture content of rice straw as the main goal. The result of study found that if shines the rice straw under the fine condition on day, spend about 2 days can reduced moisture content of rice straw under 14% suitable for pelleting. Because the rice straw is very fluffy, so the purpose of pelleting lies in convenient transportation. The best pelleting condition includes mainly: it makes the density higher than 1 g/cm3 that the packing amount needs reaching, the moisture content is in 8-14% of the ranges, but if over 20% will cause the rice straw it was unable to pellet and pelleting pressure was higher than 40 kg/cm2. The difference of the moisture content is the greatest reason for influencing the volume expansion of the finished product; it will cause the volume of the finished product to have inflation by a large margin very that the moisture content is more than 20%. This research also probes into the energy consumed in the course of making RDF. The main purpose is because RDF process needs to use energy made to it, and then burning and giving us energy, so energy benefit is an important topic.
張明益. "Analyses of Environmental and Economic Benefits of Refuse Derived Fuel System." Thesis, 2003. http://ndltd.ncl.edu.tw/handle/69856040081130956506.
Full text國立臺灣大學
環境工程學研究所
91
The refuse derived fuel (RDF) technique in our country has been stagnated in the stage of information collection and model test. In the assessment of energy, economic and environmental aspects regarding refuse derived fuel, we acquire relevant information through the statistic data obtained from the running plants in Japan. Yet, due to the deviation of some basic properties in the refuse origin, we cannot reach further exploring and study regarding the diverse benefits of refuse derived fuel that may possibly appear if it’s practically performed in Taiwan. Meanwhile, we are unable to predict actually if there is a sufficient economic-market-benefit for the refuse derived fuel plant operated in Taiwan. This study is mainly through the result of planning and design as well as beneficial assessment of real plants under operation to reach the following three purposes: 1. Analyze and compare the deviation of diverse benefits between the RDF plants in Taiwan and Japan, 2. Simulate various operation plans and find out the best plan and its incentive of investment through economic analysis, and then acquire the direction of market exploration, 3. Compare the contribution toward the environmental benefit (for example, take the reduction of greenhouse gases emission regarding the greenhouse effect) of RDF operation with other handling plans of refuse, to accommodate to the reduction of flue gas emission amount in regard of the greenhouse effect. The result of this study is abstracted as follows: in the aspect of energy input manufactured by RDF, if we use 1 kg refuse as the calculation base, then the requirements of power and fuel oil are 0.307 kwh and 0.07L respectively, which is higher than Japan case (0.17 kwh and 0.0435L), hence the energy recovery rate for Taiwan RDF is relatively lower than Japan. As a result of economic assessment, under the best operation mode, the net present value of investment in this study case is about 50,785,000 (the net present value rate is 84.55%), the retrieving period is 8.5 years and the internal rate of return to investment is 13.58%, which seems to be a sound investing plan. The analyzing result of plan sensitivity shows that the income of refuse treatment fee is the most significant factor influencing the feasibility of this plan. When the unit refuse- treatment cost is above 2,060/MT, the plan is feasible. In the analyzing result of environmental benefit with regard to the reduction of greenhouse gases emission amount corresponding to the greenhouse effect, it shows that there is 1.71 kg equivalent of carbon dioxide that can be reduced by producing one kwh electric power from the dealing of RDF in lieu of burning the refuse directly. If we estimate that we will handle 20% of national refuse generated using RDF process, then it will totally reduce approximately 2.06 million equivalent of carbon dioxide generated and emitted to the atmosphere annually. And the Eco-efficiency index of RDF method dealing with refuse is 1.94 times higher than the large-scale refuse incinerating plant as well.