Relevant bibliographies by topics / Reduced Graphene Oxide-Silver Nanocomposite

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Academic literature on the topic 'Reduced Graphene Oxide-Silver Nanocomposite'

Author: Grafiati
Published: 6 September 2023

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Journal articles on the topic "Reduced Graphene Oxide-Silver Nanocomposite"

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Qian, Yuhong, Yiting Wang, and Li Wang. "Preparation of cuprous oxide-supported silver-modified reduced graphene oxide nanocomposites for non-enzymatic electrochemical sensor." Reviews in Analytical Chemistry 41, no. 1 (January 1, 2022): 189–97. http://dx.doi.org/10.1515/revac-2022-0045.

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Abstract We constructed a non-enzymatic H2O2 sensor based on cuprous oxide-supported silver-modified reduced graphene oxide nanocomposites. It was found that the sensor exhibited good performances for sensing H2O2 with a detection limit of 0.34 μM and a wide detection range of 1–310 μM. The combination of graphene with silver and cuprous oxide improved the sensor’s sensitivity for detecting H2O2, with good repeatability, selectivity, and stability. The synthesis method of this nanocomposite provides a new idea for the green preparation of graphene-based nanocomposites and a new method for the construction of a new electrochemical sensor platform.
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Balakrishnan, Dhivyabharathi, and Cheng-I. Lee. "Surface Functionalization of Bamboo with Silver-Reduced Graphene Oxide Nanosheets to Improve Hydrophobicity and Mold Resistance." Coatings 12, no. 7 (July 11, 2022): 980. http://dx.doi.org/10.3390/coatings12070980.

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A natural polyphenolic compound was used to assemble nanocomposites. Owing to its stable bioactive properties, bamboo has earned significant attention in material science. Its high nutrient content and hydrophilicity makes bamboo more vulnerable to mold attacks and shortened shelf lives. To produce efficient, multipurpose, long-life bamboo products, a novel technique involving an immersion dry hydrothermal process was applied to impregnate the bamboo with polyphenol-assisted silver-reduced graphene oxide nanosheets. Curcumin (Cur), a natural polyphenol found in the rhizome of Curcuma longa, was used in the preparation of curcumin-enhanced silver-reduced graphene oxide nanosheets (Cur-AgrGONSs). The nanocomposites and nanocomposite-impregnated bamboo materials were examined by field emission scanning electron microscopy, X-ray diffraction and Fourier transform infrared spectroscopy. At the same time, a phytopathogen was isolated from infected bamboo products and identified by internal transcribed spacer (ITS) sequences. The nanocomposites effectively inhibited the growth of the isolated fungus. The mold resistance and moisture content of both the treated and untreated bamboo timbers were also examined to determine the efficiency of the prepared nanocomposite. The antifungal activity and hydrophobicity of the bamboo materials were significantly enhanced after the incorporation of curcumin-enriched silver-loaded reduced graphene oxide nanosheets (B@Cur-AgrGONSs). This research outcome confirms that the nanocomposite is a well-organized antimicrobial material for different advanced domains.
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Perumal, Dharshini, Che Azurahanim Che Abdullah, Emmellie Laura Albert, and Ruzniza Mohd Zawawi. "Green Synthesis of Silver Nanoparticle Decorated on Reduced Graphene Oxide Nanocomposite using Clinacanthus nutans and Its Applications." Sains Malaysiana 52, no. 3 (March 31, 2023): 953–66. http://dx.doi.org/10.17576/jsm-2023-5203-19.

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A straightforward approach that uses Clinacanthus nutans leaf extract as a bio-reduction agent has been reported to anchor silver nanoparticles onto graphene oxide (rGO-Ag). The nanocomposite was characterized by using ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, field emission scanning electron microscopy with energy-dispersive X-ray spectroscopy, and X-ray diffraction. A qualitative colour transition from yellowish to dark brown confirmed the biosynthesis of rGO-Ag nanocomposite and showed a surface plasmon resonance at 263 nm and 425 nm. Utilizing cyclic voltammetry, the electrochemical characteristics of the rGO-Ag nanocomposite modified screen printed carbon electrodes were examined. The rGO-Ag nanocomposite electrode enhanced anodic current approximately 1.29 times greater compared to silver nanoparticles (AgNPs) and 1.34 times greater compared to graphene oxide (GO). Moreover, rGO-Ag nanocomposites exhibited excellent antibacterial activity against typical Gram-positive (S. aureus) (11.99 ± 0.26 mm) and Gram-negative (E. coli) (11.86 ± 0.29 mm) bacteria. Toxicity was assayed using brine shrimp Artemia salina. The results of hatching and mortality assay demonstrates that AgNPs and rGO-Ag nanocomposite is biocompatible with A. salina at a low dosage (0.001 mg/mL). This work offers a guide for the future synthesis of nanocomposites using green reductants. The as- synthesized nanocomposite shows a promising component for the development of biomedical devices applications.
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Barua, Shaswat, Pronobesh Chattopadhyay, Mayur M. Phukan, Bolin K. Konwar, Johirul Islam, and Niranjan Karak. "Biocompatible hyperbranched epoxy/silver–reduced graphene oxide–curcumin nanocomposite as an advanced antimicrobial material." RSC Adv. 4, no. 88 (2014): 47797–805. http://dx.doi.org/10.1039/c4ra07802k.

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Periyasamy, Gnanaprakasam, Selvaraju Thangavelu, and Saravanan Muthupandian. "Single-Step Synthesis of Ag Hexagonal Nanoplate-Decorated Reduced Graphene Oxide and Its Cytotoxicity Studies." Oxidative Medicine and Cellular Longevity 2023 (July 1, 2023): 1–13. http://dx.doi.org/10.1155/2023/4466394.

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Graphene-based Ag nanocomposites are of specific interest because of their unique properties and applications, especially in the field of cytotoxicity. However, developing a simple method to synthesize reduced graphene oxide (rGO)/silver hexagonal nanoplate (Ag HNPT) (rGO–Ag HNPT) nanocomposites with well-defined morphology has been believed to be a major challenge. In this work, a facile, robust, and single-step synthesis method was developed to prepare silver-graphene (rGO–Ag HNPT) nanocomposites with hexagonal-structured silver nanoplates without any templates. The primary characterizations of the synthesized nanocomposite were done using a UV-visible spectrophotometer, X-ray diffraction (XRD), and Raman spectroscopy. The formation of uniformed hexagonal-shaped Ag nanoplates was confirmed by high-resolution transmission electron microscopy (HR-TEM), and the elemental composition was confirmed using energy dispersive X-ray analysis (EDX). With SiHa cervical cancer cells, the short-term in vitro cytotoxicity of the as-synthesized rGO–Ag HNPTs was evaluated by the 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay. The anticancer response of the rGO–Ag HNPTs was investigated using an MTT assay.
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Sedki, Mohammed, Mona B. Mohamed, Manal Fawzy, Dalia A. Abdelrehim, and Mohamed M. S. A. Abdel-Mottaleb. "Phytosynthesis of silver–reduced graphene oxide (Ag–RGO) nanocomposite with an enhanced antibacterial effect using Potamogeton pectinatus extract." RSC Advances 5, no. 22 (2015): 17358–65. http://dx.doi.org/10.1039/c4ra13117g.

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Challa, Maalathi, M. R. Ambika, S. R. Usharani, Basappa C. Yallur, and Vinayak Adimule. "Study on Optical Properties of Cu-MOF Nano Metal Oxide Composites." Applied Mechanics and Materials 908 (August 2, 2022): 19–28. http://dx.doi.org/10.4028/p-266wz9.

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A copper metal organic frame work (MOF) is synthesized by taking equimolar terephthalic acid and copper nitrate and its MOF /nanocomposite are fabricated with silver oxide and reduced graphene oxide nanocompounds. It is characterized by XRD, UV-Vis spectroscopy and FTIR. The band gap of the MOF/ nanocomposites is reduced when compare to individuals. This reduction of band gap is due to a slight change in their individual band gaps or lattice distortion hybridization leads to shifting of the energy level.
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Shaikh, Aasiya, Smrutiranjan Parida, and Sivasambu Böhm. "One step eco-friendly synthesis of Ag–reduced graphene oxide nanocomposite by phytoreduction for sensitive nitrite determination." RSC Advances 6, no. 102 (2016): 100383–91. http://dx.doi.org/10.1039/c6ra23655c.

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Bai, Rui, Yunpeng Zhao, Cuiying Lu, Yu Meng, Wenwen Gao, Yan Wang, Rui Dang, Miao Mu, Jinxi Wang, and Yurong Jiao. "Sonochemical synthesis and electrochemical performance of reduced graphene oxide/cerium dioxide nanocomposites." Journal of Chemical Research 47, no. 2 (March 2023): 174751982311587. http://dx.doi.org/10.1177/17475198231158745.

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Reduced graphene oxide/cerium dioxide (is synthesized by a simple sonochemical route. The morphology and chemical structure of the nanocomposites are characterized by scanning electron microscopy, energy disperse spectroscopy, insitu infrared spectroscopy, and X-ray diffraction. The electrochemical properties of a fabricat reduced graphene oxide/cerium dioxide2 nanocomposite electrode examined by cyclic voltammetry, galvanostatic charge/discharge, and electrochemical impedance spectroscopy. The results indicate that the reduced graphene oxide can prevent the aggregation of cerium dioxide nanoparticles; meanwhile, the reduced graphene oxide/cerium dioxide-3 nanocomposite electrode exhibits excellent electrochemical performance with a high specific capacitance of 185 F·g−1 at 0.5 A·g−1, a high rate capability, and good reversibility, which results from the synergism and coupling between reduced graphene oxide nanosheets and cerium dioxide nanoparticles.
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Farouk, A., S. El-Sayed Saeed, S. Sharaf, and M. M. Abd El-Hady. "Photocatalytic activity and antibacterial properties of linen fabric using reduced graphene oxide/silver nanocomposite." RSC Advances 10, no. 68 (2020): 41600–41611. http://dx.doi.org/10.1039/d0ra07544b.

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Dissertations / Theses on the topic "Reduced Graphene Oxide-Silver Nanocomposite"

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Kim, K. B., J. G. Kim, H. K. Kim, J. P. Jegal, K. H. Kim, J. Y. Kim, and S. H. Park. "Nanocomposites of Reduced Graphene Oxide for Energy Storage Applications." Thesis, Sumy State University, 2012. http://essuir.sumdu.edu.ua/handle/123456789/35266.

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A well-crystallized and nano-sized Metal oxide/reduced graphene oxide composite material for lithium ion batteries has been successfully synthesized. The nano-sized metal oxide particles were evenly dispersed on the reduced graphene oxide template without any agglomeration, which allows the inherent high active surface area of individual metal oxide nano-particles in the composite. These unique structural and morphological properties of metal oxide on the highly conductive reduced graphene oxide sheets in the composite enable achieving the high specific capacity, and excellent high rate capability and stable cycling performance. an analysis of the cyclic voltammogram data revealed that a large surface charge storage contribution of the metal oxide/reduced graphene oxide nanocomposite plays an important role in achieving faster charge/discharge. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35266
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Sass, Danielle. "Nano silver-Iron-reduced graphene oxide modified titanium dioxide photocatalyst for the remediation of Organic dye in water systems." University of the Western Cape, 2018. http://hdl.handle.net/11394/6274.

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Magister Scientiae - MSc (Chemistry)
Drinking water with high concentrations of inorganic and organic contaminants can cause adverse health defects. Specifically methyl orange dye is an organic water contaminant that has been known (along with others like methyl blue etc.) to have an increase in our water systems over the past few years due to increasing demand in industrial processes. It is therefore of utmost importance to remediate organic contaminants and ultimately enable prevention. The contaminants can be removed by photocatalysis. Anatase TiO2 is known for its photocatalytic degradation of environmental pollutants and photoelectro-chemical conversion of solar energy. However its application is limited since it is a wide band gap semiconductor, (Eg = 3.2 eV). The following study deals with the enhancement of the photocatalytic properties of TiO2 for remediation of organic water contaminants. The study was carried out to produce the two nanocomposites AgFe-TiO2 and AgFe-TiO2-rGO photocatalyst which purpose is to be cheap and easy to apply, with improved (fast and effective) photocatalytic degradation of methyl orange. The main objective was to decrease the band gap and to introduce intra-band gap states to absorb visible light. Modification of the TiO2 with small bandgap semiconductor, graphene and Ag- Fe nanoalloy reduced the bandgap energy for visible light absorption and photocatalytic degradation of methyl orange dye. The two composites were synthesised using sonication and chemical synthesis methods. A photocatalytic study (degradation of methyl orange dye) was carried out using a system incorporating an UV lamp source to determine the degradation of methyl orange catalysed by the synthesised photocatalysts AgFe-TiO2-rGO and AgFe-TiO2 along with UV-vis Spectroscopy. Morphological studies were carried out using HRSEM and HRTEM which determined the spherical agglomerated nature of AgFe-TiO2 and the sheet-like nature of AgFe-TiO2-rGO containing spherical agglomerants but that also contained pockets formed by the sheets of the rGO. XRD served as confirmation of the phase of TiO2 in both composites to be anatase. Analysis confirmed the formation and elemental determination of both composites. It was observed that the Band gap of TiO2 degussa decreased from 2.94 eV to 2.77 eV in the composite AgFe-TiO2. The photocatalytic reactivity of AgFe- TiO2 was an improvement from TiO2 and AgFe-TiO2-rGO based on the photocatalytic study. Therefore concluding that AgFe-TiO2 was the best catalyst to convert the dye (Orange II) into free radicals and ultimately remove the contaminant from the water compared to AgFe-TiO2-rGO.
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Sass, Danielle Thandi. "Nano silver-iron-reduced graphene oxide modified titanium dioxide photocatalyst for the remediation of organic dye in water systems." University of the Western Cape, 2018. http://hdl.handle.net/11394/6410.

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Magister Scientiae - MSc (Chemistry)
Drinking water with high concentrations of inorganic and organic contaminants can cause adverse health defects. Specifically methyl orange dye is an organic water contaminant that has been known (along with others like methyl blue etc.) to have an increase in our water systems over the past few years due to increasing demand in industrial processes. It is therefore of utmost importance to remediate organic contaminants and ultimately enable prevention. The contaminants can be removed by photocatalysis. Anatase TiO2 is known for its photocatalytic degradation of environmental pollutants and photoelectro-chemical conversion of solar energy. However its application is limited since it is a wide band gap semiconductor, (Eg = 3.2 eV). The following study deals with the enhancement of the photocatalytic properties of TiO2 for remediation of organic water contaminants.
2021-12-31
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Yarmolenko, O. V., S. A. Baskakov, Y. M. Shulga, P. I. Vengrus, and O. N. Efimov. "Supercapacitors Based on Composite Polyaniline / Reduced Graphene Oxide with Network Nanocomposite Polymer Electrolyte." Thesis, Sumy State University, 2013. http://essuir.sumdu.edu.ua/handle/123456789/35510.

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The paper describes investigation on new types of supercapacitors based on composite polyani-line/reduced graphene oxide with network nanocomposite polymer electrolyte. Its prototypes are all solid state. The new network polymer electrolytes based on polyethylene glycol diacrylate and nanoparticle SiO2 was synthesized by reaction of radical polymerization in the environment of liquid organic electrolyte. The work is aimed to obtain a polymer electrolyte that is compatible with the electrode materials of superca-pacitors. For these purposes the method of FTIR spectroscopy, a.c. electrochemical impedance and gal-vanostatic cycling were used. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35510
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Leve, Zandile Dennis. "Determination of paracetamol at the electrochemically reduced graphene oxide-metal nanocomposite modified pencil graphite (ERGO-MC-PGE) electrode using adsorptive stripping differential pulse voltammetry." University of Western Cape, 2020. http://hdl.handle.net/11394/7350.

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>Magister Scientiae - MSc
This project focuses on the development of simple, highly sensitive, accurate, and low cost electrochemical sensors based on the modification of pencil graphite electrodes by the electrochemical reduction of graphene oxide-metal salts as nanocomposites (ERGO-MC-PGE; MC = Sb or Au nanocomposite). The electrochemical sensors ERGO-Sb-PGE and ERGO-Au-PGE were used in the determination of paracetamol (PC) in pharmaceutical formulations using adsorptive stripping differential pulse voltammetry. The GO was prepared from graphite via a modified Hummers’ method and characterized by FTIR and Raman spectroscopy to confirm the presence of oxygen functional groups in the conjugated carbon-based structure whilst, changes in crystalline structure was observed after XRD analysis of graphite and GO.
2023-10-07
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Aher, Ashish. "SYNTHESIS, CHARACTERIZATION AND APPLICATIONS OF REDUCED GRAPHENE OXIDE AND COMPOSITE MEMBRANES FOR SELECTIVE SEPARATIONS AND REMOVAL OF ORGANIC CONTAMINANTS." UKnowledge, 2019. https://uknowledge.uky.edu/cme_etds/111.

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Among the next generation materials being investigated for membrane development, partially reduced Graphene Oxide (rGO) has received increasing attention from the membrane community. rGO-based nanofiltration membranes have shown promising results in applications such as partial desalination, organic contaminant removal, gas-phase separations, and separations from solvent media. rGO offers a unique platform compared to common polymeric membranes since it can be used for separation applications in both aqueous and organic solvent media. An rGO-based platform could also be utilized to synthesize reactive membranes, giving rGO membranes the additional capability of reactively removing organic contaminants. This research focuses on the synthesis of rGO and nanocomposite membranes for applications including the separation of high-value phenolic compounds from a solvent-water mixture, removal of organic contaminants, and treatment of refinery wastewater. First, the behavior of a rGO membrane in water and isopropanol was investigated along with its ability to separate high-value, lignin-derived oligomeric compounds from a solvent-water mixture. This study revealed the formation of stable sorbates of water in the GO channels that resulted in declined membrane permeance and improved size-exclusion cutoff. Through controlled reduction of GO by heat treatment, it was demonstrated that physicochemical properties of the GO membrane could be modulated and separation performance tuned based on the extent of reduction. A varying degree of interlayer spacing was attained between the GO laminates by controlling the O/C ratio of GO. This allowed the rGO membrane to achieve tunable molecular separation of lignin-derived model oligomeric compounds from a solvent-water mixture. Second, the mechanism of ionic transport through the rGO membrane was studied as well as its application in partial desalination and removal of persistent organic contaminants from water. Through comprehensive experimental investigations and mathematical analysis, along with the aid of the extended Nernst Planck equation, the impacts of steric hindrance and charge interactions on the underlying ion transport mechanism were quantified. Charge interactions were observed to be the dominant exclusion mechanism for the rGO membranes. The application of rGO membranes for treatment of high TDS produced water was investigated with the goal of partial hardness and dissolved oil removal. In addition, this study demonstrated the removal of emerging organic contaminants, specifically perfluorooctanoic acid, by rGO membranes and elucidated a charge interaction-dominated exclusion mechanism for this contaminant, as well. Finally, rGO-based and microporous polyvinylidene fluoride (PVDF)-based catalytic membrane platforms were synthesized for removal of organic contaminants via an oxidative pathway. Herein, an advanced oxidation process was integrated with membrane technology by the in-situ synthesis of Fe-based nanoparticles. The unique capability to oxidatively remove contaminants in a continuous mode of operation was explored in addition to the separation performance of the membrane. The rGO-based platform achieved high oxidative removal of trichloroethylene via a sulfate-free, radical-mediated pathway, while simultaneously removing humic acids from water and potentially eliminating undesired side reactions. A PVDF-based microporous catalytic membrane platform was shown to effectively remove organic impurities, such as Naphthenic acids, from high TDS produced water by the same pathway. The enhancement of reaction extent for elevated temperatures and longer residence times was also quantified in this study. These studies benefit the membrane community in the following ways: 1) The work identifies the critical role of the physicochemical properties of GO, such as the O/C ratio and water sorption, for determining the permeability-selectivity of rGO membranes for solvent nanofiltration. 2) Investigations of ion transport through rGO membranes led to an understanding of a charge-dominated separation mechanism for ion retention. The Nernst-Planck equation-based approach employed in this study would enable further assessment and comparison of rGO membranes under a wide set of parameters. 3) Catalytic membrane platforms (rGO and microporous PVDF-based) were synthesized for conducting advanced oxidation reactions in the porous membrane domain, demonstrating potential applications in environmental remediation of organic contaminants.
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Al-Nafiey, Amer Khudair Hussien. "Reduced graphene oxide-based nanocomposites : synthesis, characterization and applications." Thesis, Lille 1, 2016. http://www.theses.fr/2016LIL10009/document.

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Nous avons synthétisé avec succès ces nano-composés (rGO/Arg-Ag NPs, rGO-Ni NPs and rGO-Co3O4NPs) et les avons caractérisés par de nombreuses techniques, XPS, SEM, TEM, FTIR, Raman, UV-Vis et TGA. Les analyses montrent que ces nano-composés à base de graphène ont des propriétés excellentes et une grande stabilité. Utilisés comme catalyseurs dans des applications environnementales, ils réduisent efficacement le 4-nitrophenol en 4-aminophenol ainsi que les colorants à forte adsorption et le chrome (VI) présents dans les eaux usées
We successfully obtained these nanocomposites (rGO/Arg-Ag NPs, rGO-Ni NPs and rGO-Co3O4NPs).The resulting rGO-based nanocomposites were characterized by a variety of different techniques, including XPS, SEM, TEM, FTIR, Raman, UV-Vis and TGA. These analysis shows that these graphene-based nanocomposites have excellent properties and stability. The rGO-based nanocomposites, applied as a catalyst in environmental applications and shows good catalytic performance for reduction of 4nitrophenol to 4aminophenol and high adsorption dyes and Cr (VI) from wastewater
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Ammar, Ali M. "REDUCTION OF GRAPHENE OXIDE USING MICROWAVE AND ITS EFFECT ON POLYMER NANOCOMPOSITES PROPERTIES." University of Akron / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=akron1533123263694685.

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Bai, Xiaoyun. "Development of reduced graphene oxide based nanocomposities for electrochemical biosensing applications." HKBU Institutional Repository, 2014. https://repository.hkbu.edu.hk/etd_oa/228.

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The modification of electrodes is always an important task in electrochemical detection of electroactive and biological molecules. Chemically modified electrodes can offer improved selectivity and sensitivity for the target analyte, which greatly enhance the electrode performance. Various materials such as conducting polymers, metal nanoparticles and carbon nanomaterials have been exploited and widely used for the modification of electrodes. Electrochemical or spontaneous deposition, electrostatic adsorption, layer-by-layer self assembly and covalent binding have also been developed for electrode modification and offer improved performance. Both Prussian blue (PB) and toluidine blue O (TBO) are excellent redox mediators and very popular in electrode modification. PB has shown strong catalytic property for the reduction of hydrogen peroxide, but the application in biosensor fabrication is limited for its instability at neutral pH. Graphene, as a single-atom-thick carbon material, is considered an ideal platform for designing composite nanomaterials for high-performance electrochemical or electrocatalytic devices. The combination of PB with reduced graphene oxide (RGO) and poly(toluidine blue O) (PTBO) will greatly improve the stability of PB. An amperometric biosensor based on glassy carbon (GC) electrode modified with reduced graphene oxide, PB and poly(toluidine blue O) was developed. Experimental results showed that the GC/RGO/PB/PTBO modified electrode offered an excellent electrocatalytic activity toward the reduction of hydrogen peroxide due to the possible synergistic effects of the PB-PTBO composite material. After codeposition of glucose oxidase (GOD) and chitosan (CHIT) coating, the resulting GC/RGO/PB/ PTBO/CHIT-GOD electrode exhibited excellent response to glucose with a sensitivity of 59 mA M1 cm2, a low detection limit of 8.4 μM and a linear range from 0.02 to 1.09 mM at a detection potential of +0.2 V vs. Ag.
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Ly, Kally Chein Sheng 1992. "Fabricação e caracterização de filme fino regenerável hidrofóbico." [s.n.], 2017. http://repositorio.unicamp.br/jspui/handle/REPOSIP/330349.

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Orientador: Antonio Riul Júnior
Dissertação (mestrado) - Universidade Estadual de Campinas, Instituto de Física Gleb Wataghin
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Resumo: Materiais biomiméticos são inspirados em estruturas biológicas para a obtenção de propriedades e funcionalidades específicas. Dentre os materiais biomiméticos, os que são capazes de se regenerar (self-healing) despertaram grande interesse pelo potencial de aplicação em diversas áreas. Para ilustrar, alguns materiais autorregeneráveis poliméricos apresentam regeneração múltipla, necessitando apenas de água para que a regeneração ocorra em alguns minutos, aumentando consideravelmente a proteção mecânica da superfície contra desgastes, danos mecânicos entre outros. Entretanto, múltiplas imersões em água ou em meios aquosos pode degradar o material e neste contexto este projeto visa incorporar a hidrofobicidade a um sistema regenerável. Desta forma, o material regenerável hidrofóbico, durante sua regeneração imersa em água, poderá diminuir a interação da superfície não danificada com a água, reduzindo corrosões e degradações devido a meios aquosos. Estudamos a nanoestruturação de materiais através da técnica de automontagem por adsorção física (LbL, do inglês Layer-by-Layer) utilizando os polieletrólitos poli(etileno imina) (PEI) e poli(ácido acrílico) (PAA), a fim de produzir revestimentos capazes de se regenerar a danos mecânicos micrométricos. Adicionalmente, foram incorporados a estes dois materiais nanofolhas de óxido de grafeno reduzido (rGO) funcionalizados com poli(cloridrato de alilamina) (GPAH) e poli(estireno-sulfonato de sódio) (GPSS), com o intuito de verificarmos um aumento de resistência a abrasão do material e alterações nas propriedades elétricas na nanoestrutura formada para aumentar o potencial de aplicação em eletrônica flexível. A arquitetura molecular (GPAH-PEI/GPSS-PAA)60 foi caracterizada com espectroscopia Raman, medidas de ângulo de contato, microscopia de força atômica, medidas elétricas e nanoindentação. Foi observada boa regeneração do material após 15 minutos de imersão em água a temperatura ambiente em um dano mecânico da ordem de 10 micrômetros. Também observamos boa hidrofobicidade do filme LbL (GPAH-PEI/GPSS-PAA)60 ( teta = 136º), e medidas de microscopia de força atômica e perfilometria indicaram, respectivamente, rugosidade superficial de 55 nm em uma área de (2 ?m x 2 ?m) e espessura de filme de 30 ?m. A análise Raman apontou para uma forte interação das nanofolhas de rGO com os polímeros, corroborando o tem caráter elétrico isolante do filme (GPAH-PEI/GPSS-PAA)60, que apresentou função trabalho ~ 5,2 eV e condutividade elétrica da ordem de 10-7 S/cm, que acreditamos resultar das fortes interações das nanofolhas com os polímeros. Por fim, medidas de nanoindentação indicaram que a incorporação de nanofolhas de GPSS e GPAH aumentou em 10 vezes a dureza do nanocompósito formado, sem comprometer a regeneração
Abstract: Biomimetic materials are inspired in biological structures to obtain specific properties and functionalities and among them, those capable of self-healing brought great interest due to high potential of application in different areas. To illustrate, some polymeric self-healing materials present multiple regeneration in the presence of water, with the regeneration occurring within a few minutes, increasing considerably the mechanical protection of a surface against wear and mechanical damage among others. Nevertheless, multiple immersions in water or in aqueous media can degrade the material and in this context this project aims the incorporation of hydrophobicity to a self-healing system. In this way, the self-healing, hydrophobic material during its immersion in water may decrease the interaction of the damaged surface with water, reducing corrosion and degradation due to aqueous media. We study the nanostructuration f materials through the layer-by-layer (LbL) technique using poly(ethylene imine) (PEI) and poly(acrylic acid) (PAA) in order to produce self-healing coatings from micrometric mechanical damages. In addition, we also incorporate to these materials reduced graphene oxide (rGO) functionalized with poly(allylamine hydrochloride) (GPAH) and poly(styrene-sodium sulfonate) (GPSS), with the purpose of verifying an increase in the mechanical abrasion resistance of the material and changes in the electrical properties of the nanostructures formed to increase the potential application in flexible electronics. The molecular architecture (GPAH-PEI/GPSS-PAA)60 was characterized by Raman spectroscopy, contact angle measurements, atomic force microscopy, electrical measurements and nanoindentation. It was observed good self-healing capacity after 15 min f immersion in water at room temperature in a mechanical scratch of the order of 10 micrometers. It was also observed good hydrophobicity in the (GPAH-PEI/GPSS-PAA)60 LbL film ( teta = 136º) and atomic force microscopy and perfilometer indicate, respectively, surface roughness of 55 nm in a (2 ?m x 2 ?m) area and film thickness of 30 ?m. Raman analysis pointed out to a strong physical interaction between the rGO nanoplatelets with the polymeric materials, corroborating the strong insulating nature of (GPAH-PEI/GPSS-PAA)60 film that displayed a work function of 5.2 eV and electrical conductivity of 10-7 S/cm, which we believe results from the strong interactions of the nanosheets with the polymers. Finally, nanoindentation measurements indicated that the incorporation of GPAH and GPSS nanoplatelets increased hardness by 10 times, without compromising the regeneration
Mestrado
Física
Mestra em Física
1543078/2015
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Book chapters on the topic "Reduced Graphene Oxide-Silver Nanocomposite"

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Chamoli, Pankaj, Soma Banerjee, K. K. Raina, and Kamal K. Kar. "Characteristics of Graphene/Reduced Graphene Oxide." In Handbook of Nanocomposite Supercapacitor Materials I, 155–77. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-43009-2_5.

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De, Bibekananda, Soma Banerjee, Tanvi Pal, Kapil Dev Verma, P. K. Manna, and Kamal K. Kar. "Graphene/Reduced Graphene Oxide as Electrode Materials for Supercapacitors." In Handbook of Nanocomposite Supercapacitor Materials II, 271–96. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-52359-6_11.

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De, Bibekananda, Prerna Sinha, Soma Banerjee, Tanvi Pal, Kapil Dev Verma, Alekha Tyagi, P. K. Manna, and Kamal K. Kar. "Transition Metal Oxide/Graphene/Reduced Graphene Oxide Composites as Electrode Materials for Supercapacitors." In Handbook of Nanocomposite Supercapacitor Materials II, 297–331. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-52359-6_12.

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Zito, C. A., and D. P. Volanti. "SnO2 -Reduced Graphene Oxide Nanocomposite for Ethanol Sensing at Room Temperature." In Developments in Strategic Ceramic Materials II, 271–79. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2017. http://dx.doi.org/10.1002/9781119321811.ch25.

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Vidyarajan, N., and L. K. Alexander. "Low-Temperature Gas Sensing Properties of Reduced Graphene Oxide Incorporated Perovskite Nanocomposite." In Nanostructured Smart Materials, 185–91. First edition.: Apple Academic Press, 2021. http://dx.doi.org/10.1201/9781003130468-12.

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Brahma, Sanjaya, Shao-Chieh Weng, Chia-Chin Chang, and Jow-Lay Huang. "Mn-Based Oxide Nanocomposite with Reduced Graphene Oxide as Anode Material in Li-Ion Battery." In Lithium-Related Batteries, 167–91. Boca Raton: CRC Press, 2022. http://dx.doi.org/10.1201/9781003263807-9.

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Soares, Carlos, Julyana Santana, Olgun Güven, and Esperidiana A. B. Moura. "A Comparison Between Graphene Oxide and Reduced Graphene Oxide as Reinforcement Agents in Polypropylene Nanocomposite Using Irradiated Polypropylene as Compatibilizer." In The Minerals, Metals & Materials Series, 385–94. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-36628-5_36.

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Anjali, Sonal Rattan, Rahul Sharma, Twinkle, Manpreet Kaur, Harjot Singh, Nihal, Mamta Sharma, Suresh Kumar, and J. K. Goswamy. "Reduced Graphene Oxide-Copper Nanocomposites Synthesis via Green Chemistry." In Springer Proceedings in Physics, 315–22. Singapore: Springer Singapore, 2022. http://dx.doi.org/10.1007/978-981-16-7691-8_31.

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Devi, Naorem Aruna, and Bibhu Prasad Swain. "Investigation of Metal-Oxide/Reduced Graphene-Oxide Nanocomposites for Gas Sensor Applications." In Materials Horizons: From Nature to Nanomaterials, 211–27. Singapore: Springer Singapore, 2020. http://dx.doi.org/10.1007/978-981-15-8307-0_11.

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Ahmad, Khursheed, and M. A. Gondal. "Reduced Graphene Oxide-Supported Hybrid Composites for Electrochemical-Sensing Applications." In Handbook of Nanomaterials and Nanocomposites for Energy and Environmental Applications, 3307–30. Cham: Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-36268-3_205.

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Conference papers on the topic "Reduced Graphene Oxide-Silver Nanocomposite"

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Veeresh, Shantappa, Honuu Ganesh, Yennappa Siddappa Nagaraju, Molahalli Vandana, Shankar Pawar Ashokkumar, Laxmayyaguddi Yesappa, Hebri Vijeth, and Hundekal Devendrappa. "Synthesis and characterization of reduced graphene oxide nanocomposite." In PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ON PHYSICS OF MATERIALS AND NANOTECHNOLOGY ICPN 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0009201.

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Sinha, Sayantan, Sumitra Nongthombam, N. Aruna Devi, Sadhna Rai, Rabina Bhujel, W. Ishwarchand Singh, Arindam Biswas, and Bibhu P. Swain. "Conduction Mechanism of Polyaniline/Reduced Graphene Oxide/Ag2O Nanocomposite." In 2020 IEEE VLSI Device Circuit and System (VLSI DCS). IEEE, 2020. http://dx.doi.org/10.1109/vlsidcs47293.2020.9179888.

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Kaur, Jasmeet, Kanika Anand, Kanica Anand, Gurpreet Singh, Anita Hastir, Virpal, and Ravi Chand Singh. "Reduced graphene oxide/CeO2 nanocomposite with enhanced photocatalytic performance." In PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ON CONDENSED MATTER PHYSICS 2014 (ICCMP 2014). AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4915400.

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Das, Trupti R., Rashmi Madhuri, and Prashant K. Sharma. "Electrocatalytic activity of silver nanoparticles decorated reduced graphene oxide (AgNP@rGO) nanocomposites." In DAE SOLID STATE PHYSICS SYMPOSIUM 2016. Author(s), 2017. http://dx.doi.org/10.1063/1.4980248.

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Siwatch, Poonam, Kriti Sharma, Nirmal Manyani, and S. K. Tripathi. "Electrochemical study of nanocomposite of nickel cobalt oxide with reduced graphene oxide." In ADVANCED MATERIALS AND RADIATION PHYSICS (AMRP-2020): 5th National e-Conference on Advanced Materials and Radiation Physics. AIP Publishing, 2021. http://dx.doi.org/10.1063/5.0052496.

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Poonam, Kriti Sharma, Nirmal, and S. K. Tripathi. "Electrochemical performance of nickel cobalt oxide-reduced graphene oxide-polyvinyl alcohol nanocomposite." In 3RD INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC-2019). AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0001838.

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Supriya, Sweety, Sunil Kumar, and Manoranjan Kar. "Impedance spectroscopy studies in cobalt ferrite-reduced graphene oxide nanocomposite." In INTERNATIONAL CONFERENCE ON CONDENSED MATTER AND APPLIED PHYSICS (ICC 2015): Proceeding of International Conference on Condensed Matter and Applied Physics. Author(s), 2016. http://dx.doi.org/10.1063/1.4946617.

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Junlong Huang, Guangzhong Xie, Yong Zhou, Tao Xie, and Guangjin Yang. "NO2 gas sensor based on polyvinylpyrrolidone/reduced graphene oxide nanocomposite." In 2014 IEEE Workshop on Advanced Research and Technology in Industry Applications (WARTIA). IEEE, 2014. http://dx.doi.org/10.1109/wartia.2014.6976459.

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Abdelrahman, Mustafa, Slade C. Jewell, Abdalla Elbella, and Shannon J. Timpe. "Graphene Oxide / Nanodiamond Nanocomposites Characterized via Particle Dispersion and Micro- and Nanoscale Mechanical Properties." In ASME 2021 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2021. http://dx.doi.org/10.1115/imece2021-72137.

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Abstract:
Abstract Polystyrene matrix nanocomposites were formulated using a custom nano particle consisting of nanodiamond covalently bonded to graphene oxide. Dispersion and mechanical property results for the nano composite are compared to those results for the neat polymer as well as for a nanocomposite infused with graphene oxide only. Dynamic light scattering was performed to determine the size of particles and the results showed that the custom nanoparticle reduced agglomeration by about 50% as compared to the graphene oxide alone. Microscale Vickers hardness testing revealed that neat polymer as well as the two nanocomposite samples all have similar hardness while nanoscale atomic force microscopy revealed that the neat polymer samples have the highest stiffness on average and the custom nanoparticle composite samples have the lowest stiffness. This difference in mechanical behavior with scale is attributed to local defects at the particle/matrix interface.
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Anand, Vijay Kumar, Rakesh Goyal, and G. S. Virdi. "Copper Nanowires/Reduced Graphene Oxide Nanocomposite Based Non-Enzymatic Glucose Sensor." In 2020 International Conference on Advances in Computing, Communication & Materials (ICACCM). IEEE, 2020. http://dx.doi.org/10.1109/icaccm50413.2020.9213041.

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Reports on the topic "Reduced Graphene Oxide-Silver Nanocomposite"

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Kichukova, Diana, Daniela Kovacheva, Anna Staneva, and Ivanka Spassova. Аntimicrobial Impact of Nanocomposites of Reduced Graphene Oxide with Silver and Copper. "Prof. Marin Drinov" Publishing House of Bulgarian Academy of Sciences, February 2021. http://dx.doi.org/10.7546/crabs.2021.02.04.

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