Academic literature on the topic 'Rechargeable-Iron Batteries'

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Journal articles on the topic "Rechargeable-Iron Batteries"

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Ritchie, A. G., P. G. Bowles, and D. P. Scattergood. "Lithium-ion/iron sulphide rechargeable batteries." Journal of Power Sources 136, no. 2 (October 2004): 276–80. http://dx.doi.org/10.1016/j.jpowsour.2004.03.043.

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You, Gongchuan, and Liang He. "High Performance Electrolyte for Iron-Ion batteries." Academic Journal of Science and Technology 5, no. 2 (April 2, 2023): 244–47. http://dx.doi.org/10.54097/ajst.v5i2.6995.

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Aqueous rechargeable batteries have received widespread attention due to their excellent power density, simple manufacturing process, and inexpensive electrolyte. Iron-ion batteries are expected to meet the goals of high safety, low cost, and non-toxicity pursued in the field of rechargeable batteries. However, passivation, parasitic hydrogen evolution reaction (HER), and low electroplating efficiency (50%-70%) limit the improvement of electrochemical performance, which greatly restricts their practical application. In this study, a high-performance electrolyte for iron-ion batteries was prepared, and the effect of zinc chloride (ZnCl2) additives on inhibiting HER and the improvement of coulomb efficiency in ferrous chloride (FeCl2) electrolyte was explored. Additionally, the effect of the addition of complexing agents in the electrolyte on the coulomb efficiency of the electrodes was studied. It’s demonstrated that the electrode can still obtain a coulomb efficiency of nearly 100% after 20 hours cycling in the electrolyte containing ZnCl2 additive and FeCl2, while in FeCl2 electrolyte, its coulomb efficiency after 20 hours of cycling is only 65%.
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He, Z., F. Xiong, S. Tan, X. Yao, C. Zhang, and Q. An. "Iron metal anode for aqueous rechargeable batteries." Materials Today Advances 11 (September 2021): 100156. http://dx.doi.org/10.1016/j.mtadv.2021.100156.

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Kumar, Harish, and A. K. Shukla. "Fabrication Fe/Fe3O4/Graphene Nanocomposite Electrode Material for Rechargeable Ni/Fe Batteries in Hybrid Electric Vehicles." International Letters of Chemistry, Physics and Astronomy 19 (October 2013): 15–25. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.19.15.

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Fe/Fe3O4/Graphene composite electrode material was synthesized by a thermal reduction method and then used as anode material along with Nickel cathode in rechargeable Ni/Fe alkaline batteries in hybrid electric vehicles. Reduced graphene /Fe/Fe3O4 composite electrode material was prepared using a facile three step synthesis involving synthesis of iron oxalate and subsequent reduction of exfoliated graphene oxide and iron oxalate by thermal decomposition method. The synthesis approach presents a promising route for a large-scale production of reduced graphene /Fe/Fe3O4 composite as electrode material for Ni/Fe rechargeable batteries. The particle size and structure of the samples were characterized by SEM and XRD.
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Kumar, Harish, and A. K. Shukla. "Fabrication Fe/Fe<sub>3</sub>O<sub>4</sub>/Graphene Nanocomposite Electrode Material for Rechargeable Ni/Fe Batteries in Hybrid Electric Vehicles." International Letters of Chemistry, Physics and Astronomy 19 (October 2, 2013): 15–25. http://dx.doi.org/10.56431/p-oqaeru.

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Fe/Fe3O4/Graphene composite electrode material was synthesized by a thermal reduction method and then used as anode material along with Nickel cathode in rechargeable Ni/Fe alkaline batteries in hybrid electric vehicles. Reduced graphene /Fe/Fe3O4 composite electrode material was prepared using a facile three step synthesis involving synthesis of iron oxalate and subsequent reduction of exfoliated graphene oxide and iron oxalate by thermal decomposition method. The synthesis approach presents a promising route for a large-scale production of reduced graphene /Fe/Fe3O4 composite as electrode material for Ni/Fe rechargeable batteries. The particle size and structure of the samples were characterized by SEM and XRD.
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Hayashi, Kazushi, Yasutaka Maeda, Tsubasa Suzuki, Hisatoshi Sakamoto, Toshihiro Kugimiya, Wai Kian Tan, Go Kawamura, Hiroyuki Muto, and Atsunori Matsuda. "Development of Iron-Based Rechargeable Batteries with Sintered Porous Iron Electrodes." ECS Transactions 75, no. 18 (January 10, 2017): 111–16. http://dx.doi.org/10.1149/07518.0111ecst.

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Paulraj, Alagar Raj, Yohannes Kiros, Björn Skårman, and Hilmar Vidarsson. "Core/Shell Structure Nano-Iron/Iron Carbide Electrodes for Rechargeable Alkaline Iron Batteries." Journal of The Electrochemical Society 164, no. 7 (2017): A1665—A1672. http://dx.doi.org/10.1149/2.1431707jes.

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Mayer, Sergio Federico, Cristina de la Calle, María Teresa Fernández-Díaz, José Manuel Amarilla, and José Antonio Alonso. "Nitridation effect on lithium iron phosphate cathode for rechargeable batteries." RSC Advances 12, no. 6 (2022): 3696–707. http://dx.doi.org/10.1039/d1ra07574h.

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Abdalla, Abdallah H., Charles I. Oseghale, Jorge O. Gil Posada, and Peter J. Hall. "Rechargeable nickel–iron batteries for large‐scale energy storage." IET Renewable Power Generation 10, no. 10 (November 2016): 1529–34. http://dx.doi.org/10.1049/iet-rpg.2016.0051.

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Morzilli, S., and B. Scrosati. "Iron oxide electrodes in lithium organic electrolyte rechargeable batteries." Electrochimica Acta 30, no. 10 (October 1985): 1271–76. http://dx.doi.org/10.1016/0013-4686(85)85002-7.

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Dissertations / Theses on the topic "Rechargeable-Iron Batteries"

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Abdalla, Abdallah Hussin. "Iron-based rechargeable batteries for large-scale battery energy storage." Thesis, University of Sheffield, 2017. http://etheses.whiterose.ac.uk/19953/.

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It is a global challenge to develop green, sustainable power source for modern portable devices, and stationary power generation. Energy storage systems (ESS) can improve the stability and quality of the power grid. Moreover, ESS can be used for peak shaving, integration viable renewable sources to the electricity network. Several ESSs technologies are existing, electrical, thermal, mechanical, and electrochemical storage technologies. This thesis proposes the potential of iron-based electrode batteries such as Nickel-Iron (NiFe) batteries to be implemented for large-scale grid power. This proposal applies to other types of iron-based electrode rechargeable batteries. Iron-based electrode batteries such as Ni-Fe batteries are particularly attractive and compelling to utilise the energy generated from renewable resources. NiFe battery clearly stood out in view of their cost-effective, robust, and eco-friendly materials. Numerous problems have hindered their developments. Those limitations are poor discharge capability and charge efficiency. In fact, the performance of these batteries is drastically reduced by the parasitic evolution of hydrogen. The key is to develop electrode/electrolyte electroactive materials as additives to improve the performance of the battery. This approach has been successful in many rechargeable batteries. In this thesis, investigation of several electrode/electrolyte additives for advanced NiFe batteries is conducted. In this, an effort is made to improve the performance of the NiFe battery by including different electrode and electrolyte additives to suppress the hydrogen evolution (HER) despite the fact that the addition of various percentages of Bi2S3, FeS, K2S, CuSO4 or other sulfide elements to the electrode and electrolyte is a very effective method of suppressing the HER. In this study, paste-type and hot-pressed types electrode samples were used to produce the electrode samples. Galvanostatic charge/discharge cycling, and cyclic voltammetry were used to investigate the electrochemical properties of the electrode samples. The prepared and cycled electrode samples were characterised a variety of physical techniques including X-ray diffraction (XRD), atomic force microscopy (AFM), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It has been found in this study that, the presence of iron sulfide in the electrode has a real incidence on increasing the reversibility and performance of the electrode samples than using copper alone. Therefore, this improves the overall performance of NiFe batteries; however, due to the fact that we have used commercial grade reactants and materials, this technology definitely has the potential to be further developed in the long run and could provide a cost-effective solution to large-scale energy storage.
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Madsen, Alex. "Lithium iron sulphide as a positive electrode material for rechargeable lithium batteries." Thesis, University of Southampton, 2013. https://eprints.soton.ac.uk/355748/.

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Lithium iron sulphide has been investigated as a low-cost, high energy density and relatively safe positive electrode material for secondary lithium batteries. Lithium iron sulphide was synthesised, characterised and compared with natural pyrite samples and was shown to have a capacity of 350 mAh.g-1 upon cycling between 1.45 and 2.80 V vs. Li. The capacity was attributed to the Fe2+/Fe3+ redox couple at potentials up to 2.55 V, and oxidation of sulphur sites from Fe3+(S2-)2 to Fe3+S2-(S2)2-0.5 up to 2.80 V. The cycle life performance of lithium iron sulphide is poor when the cell is cycled between 1.45 and 2.80 V, with the cell loosing approximately 1.4 mAh.g-1 per cycle, although this performance is superior to comparable pyrite electrodes. Calcium doped samples of lithium iron sulphide were synthesised. Calcium doping was shown to impact upon lithium transport properties of the bulk lithium iron sulphide, improving the rate performance of the material. Improvements in cycle life performance of the calcium doped samples were offset by decreased specific capacity due to lithium substitution. The poor cycle life performance of lithium iron sulphide cells was attributed to the utilisation of the high voltage plateau corresponding to sulphur site oxidation/reduction. Experiments utilising a variety of negative electrode materials has identified the formation of soluble polysulphide species upon cycling of the cell, which reduce irreversibly at the negative electrode, contributing to active mass loss and poor cycle life performance. In-situ XRD studies have highlighted the structural decomposition that occurs upon utilisation of the sulphide, which results in irreversible amorphisation of the lithium iron sulphide crystal structure. Lithium iron sulphide was treated via coating with lithium boron oxide glass and a novel carbon coating method via thermal decomposition of butyl-methyl-pyrrolydinium-dicyanimide. Both treatments were shown to increase the cycle life performance of lithium iron sulphide, due to decreased dissolution of polysulphide upon cycling. The choice of binder, electrode formulation and electrolyte was also shown to impact upon the cycle life performance of lithium iron sulphide cells.
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MASESE, TITUS NYAMWARO. "Iron-based Polyanion Cathode Materials for High-Energy Density Rechargeable Lithium and Magnesium Batteries." Kyoto University, 2015. http://hdl.handle.net/2433/199395.

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Kyoto University (京都大学)
0048
新制・課程博士
博士(人間・環境学)
甲第19071号
人博第724号
新制||人||174(附属図書館)
26||人博||724(吉田南総合図書館)
32022
京都大学大学院人間・環境学研究科相関環境学専攻
(主査)教授 内本 喜晴, 教授 田部 勢津久, 准教授 藤原 直樹
学位規則第4条第1項該当
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Hong, Pengda, and 洪鹏达. "Synthesis and characterization of LiNi0.6Mn0.35Co0.05O2 and Li2FeSiO4/C as electrodes for rechargeable lithium ion battery." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2011. http://hub.hku.hk/bib/B47150294.

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The rechargeable lithium ion batteries (LIB) are playing increasingly important roles in powering portal commercial electronic devices. They are also the potential power sources of electric mobile vehicles. The first kind of the cathode materials, LiXCoO2, was commercialized by Sony Company in 1980s, and it is still widely used today in LIB. However, the high cost of cobalt source, its environmental unfriendliness and the safety issue of LiXCoO2 have hindered its widespread usage today. Searching for alternative cathode materials with low cost of the precursors, being environmentally benign and more stable in usage has become a hot topic in LIB research and development. In the first part of this study, lithium nickel manganese cobalt oxide (LiNi0.6Mn0.35Co0.05O2) is studied as the electrode. The materials are synthesized at high temperatures by solid state reaction method. The effect of synthesis temperature on the electrochemical performance is investigated, where characterizations by, for example, X-ray diffraction (XRD) and scanning electron microscopy (SEM), for particle size distribution, specific surface area, and charge-discharge property, are done over samples prepared at different conditions for comparison. The electrochemical tests of the rechargeable Li ion batteries using LiNi0.6Mn0.35Co0.05 cathode prepared at optimum conditions are carried out in various voltage ranges, at different discharge rates and at high temperature. In another set of experiments, the material is adopted as anode with lithium foil as the cathode, and its capacitance is tested. In the second part of this study, the iron based cathode material is investigated. Lithium iron orthosilicate with carbon coating is synthesized at 700℃ by solid state reaction, which is assisted by high energy ball milling. Characterizations are done for discharge capacities of the samples with different carbon weight ratio coatings.
published_or_final_version
Physics
Master
Master of Philosophy
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Sundar, Rajan A. "Studies on Alkaline Iron Electrodes for Nickel-Iron Accumulators." Thesis, 2015. https://etd.iisc.ac.in/handle/2005/4525.

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A battery is a companion whose interests are world-wide and whose society has never-ending interests. Batteries have applications in cars to space and there is ever growing addiction to batteries. A battery consists of two electrodes, an anode and a cathode, and an electrolyte through which electrically charged particles but not electrons or reactants can move. Two chemical reactions take place at the same time. The reaction taking place at the anode is an oxidation reaction which results in generation of electrons while the chemical reaction taking place at the cathode is a reduction reaction which results in the depletion of electrons. Accordingly, the anode and cathode of the battery are also referred to as negative and positive plates. When the battery is connected to an external circuit, the excess electrons from the anode flow through the circuit and back to the cathode. As the electrons move through the circuit, they lose energy. This energy may be used to create heat or light as in an electrical heater or light bulb, or to do work as in a motor. The flow of electrons results in a current and by convention the direction of the current is opposite to the direction of flow of electrons. The energy which the electrons lose as they move through the circuit is called voltage. The product of the current and the voltage is power delivered to the circuit. When a battery delivers electric current to an external load, certain active materials in the battery are converted into other materials at lower energy states and the battery is eventually discharged. During recharge, a storage battery behaves like an electrolytic cell where the active electrode materials are retrieved. It is desirable that the energy delivered by a battery during discharge should be as high as possible. The energy output of a battery is dependent on the amount of active material present in the battery. Since the weight and volume of the battery are at premium for most of the applications, it is the energy density which has to be maximized. Engineers refer to the quantity of electricity stored per kilogram of the battery as the energy density; the speed of delivery or rate of discharge is called power density. For many applications, such as traction and automotive, it is also necessary to have a high power density. However, the energy density tends to decrease with an increase in power density because at high rates of discharge, a part of the energy is irreversibly lost as heat in the system. For an efficient delivery of charge from a battery, it is desirable that, the energy density be maximized at optimum required power. Between periods of use, a loss in the available energy of the battery occurs partly due to a leakage of charge between the electrodes and partly due to consumption of charge at the electrodes by the parasitic reactions. This is commonly referred to as self-discharge. This results in a decrease in both the effectiveness of the battery as a source of energy and also its reliability for a given application during storage. Structural integrity of the battery is another important characteristic since this confers immunity from mechanical stresses such as vibrations and shocks to which batteries are often subjected in practice. In short, a maximum energy at optimum power density, minimum internal resistance, maximum charge retention, mechanical strength and long cycle-life are the desirable characteristics of a battery.
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Tsai, Yi-Ying, and 蔡宜穎. "Nickel iron layered double hydroxide derived bifunctional oxygen electrode catalyst for rechargeable zinc/air batteries." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/qwd872.

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碩士
國立臺灣科技大學
化學工程系
106
In recent years, rechargeable zinc-air batteries have attracted much attention owing to its high energy density, promising safety, and economic viability. In air electrode, bi-functional electrocatalysts are desirable since the dual functionality of the oxygen evolution reaction (OER) and oxygen oxygen reduction reaction (ORR) are required on the same electrode under charging and discharging processes, respectively. Unfortunately, both ORR catalyst Pt/C and OER catalyst IrO2 don’t have bifunctional property. The high cost of precious Pt/C and IrO2 catalysts also limit their wide spread application. In the light of this, this work provides a promising bi-functional electrocatalyst with earth-abundant elements to enable the oxygen conversion reaction efficiently. Carbon supported NiFe layered double hydroxide (NiFe LDH/C) can be synthesized by a facile hydrothermal method which can precisely control the catalyst’s composition. Then, the optimal NiFe LDH/C was used as precursor and further reduced to bi-functional catalyst by hydrogen reduction and thermal ammonolysis. The results show that NiFe/NiFeN/NC nanocomposites, characterized by duel electroactive sites for OER and ORR, can be simultaneously derived by thermal ammonolysis process. According to the electrochemical measurements by linear sweep voltammetry (LSV), NiFe/NiFeN/NC nanocomposite calcined in ammonia at 500 oC demonstrates excellent activities for oxygen conversion reaction, when compared to NiFe LDH and NiFe/C. Its overpotential △E between the ORR current density of 3 mA cm−2 and OER current density of 10 mA cm−2 is 0.91 (V). In the stability test, a chronoamperometry method was used in 0.1 M KOH. After 6 hours, NiFe/NiFeN/NC catalyst calcined at 500 oC showed high stability with a decline of current of 8.9% and 14.1% in OER and ORR, comparable to 29.1% for IrO2 and 7.7% for Pt/C, respectively. In addition, the ORR stability test in 1 M KOH showed that the activity decayed 18.4% for NiFe/NiFeN/NC, whereas 23.1% for Pt/C. This indicates that the composite catalyst is more suitable for operations under harsh environments. This study further attempts to establish a rechargeable zinc-air battery test platform and analyze material performance. NiFe/NiFeN/NC shows good stability and its performance is comparable to that of Pt/C+IrO2, confirming its bi-functional property. Considering the cost and mass production, NiFe/NiFeN/NC offers more advantages than the combination of noble materials with Pt/C and IrO2. Keywords:Alkaline, Bifunctional electrocatalyst, Layered double hydroxide, N-doped carbon, Rechargeable zinc-air battery.
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Hariprakash, B. "Studies On Lead-Acid, Nickel-Based And Silver-Zinc Rechargeable Batteries." Thesis, 2004. https://etd.iisc.ac.in/handle/2005/2207.

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Hariprakash, B. "Studies On Lead-Acid, Nickel-Based And Silver-Zinc Rechargeable Batteries." Thesis, 2004. http://etd.iisc.ernet.in/handle/2005/2207.

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Book chapters on the topic "Rechargeable-Iron Batteries"

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Jansen, A. N. "SECONDARY BATTERIES – LITHIUM RECHARGEABLE SYSTEMS | Lithium–Iron Sulfide." In Encyclopedia of Electrochemical Power Sources, 145–50. Elsevier, 2009. http://dx.doi.org/10.1016/b978-044452745-5.00183-0.

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Zaghib, K., A. Mauger, F. Gendron, C. M. Julien, and J. B. Goodenough. "SECONDARY BATTERIES – LITHIUM RECHARGEABLE SYSTEMS – LITHIUM-ION | Positive Electrode: Lithium Iron Phosphate." In Encyclopedia of Electrochemical Power Sources, 264–96. Elsevier, 2009. http://dx.doi.org/10.1016/b978-044452745-5.00204-5.

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Yan, Shan, and Amy C. Marschilok. "Conversion-Type Electrodes for Rechargeable Lithium Based Batteries: Case Studies of Iron Based Conversion Materials for Lithium-Ion Batteries and Molybdenum Disulfides for Lithium-Sulfur Batteries." In Encyclopedia of Energy Storage, 36–46. Elsevier, 2022. http://dx.doi.org/10.1016/b978-0-12-819723-3.00116-5.

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Conference papers on the topic "Rechargeable-Iron Batteries"

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Wang, Yixu, and Hsiao-Ying Shadow Huang. "Comparison of Lithium-Ion Battery Cathode Materials and the Internal Stress Development." In ASME 2011 International Mechanical Engineering Congress and Exposition. ASMEDC, 2011. http://dx.doi.org/10.1115/imece2011-65663.

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The need for development and deployment of reliable and efficient energy storage devices, such as lithium-ion rechargeable batteries, is becoming increasingly important due to the scarcity of petroleum. Lithium-ion batteries operate via an electrochemical process in which lithium ions are shuttled between cathode and anode while electrons flowing through an external wire to form an electrical circuit. The study showed that the development of lithium-iron-phosphate (LiFePO4) batteries promises an alternative to conventional lithium-ion batteries, with their potential for high energy capacity and power density, improved safety, and reduced cost. However, current prototype LiFePO4 batteries have been reported to lose capacity over ∼3000 charge/discharge cycles or degrade rapidly under high discharging rate. In this study, we report that the mechanical and structural failures are attributed to dislocations formations. Analytical models and crystal visualizations provide details to further understand the stress development due to lithium movements during charging or discharging. This study contributes to the fundamental understanding of the mechanisms of capacity loss in lithium-ion battery materials and helps the design of better rechargeable batteries, and thus leads to economic and environmental benefits.
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