Dissertations / Theses on the topic 'Quantum mappings'
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Vázquez, Molina Joan. "Mappings between Thermodynamics and Quantum Mechanics that support its interpretation as an emergent theory." Doctoral thesis, Universitat Politècnica de València, 2017. http://hdl.handle.net/10251/83122.
Full textLa presente tesis doctoral se presenta como compendio de las publicaciones \cite{NS, holographic, topological}. El siguiente resumen es una adaptación de sus resumenes. Se ha argumentado que la mecánica cuántica podría emerger como promediado de una teoría determinista subyacente. Se apoya dicha visión estableciendo mapeos entre la mecánica cuántica no relativista y teorías termodinámicas, ya que estas constituyen el paradigma de teoría emergente. Primero, se establece un mapeo entre soluciones de la ecuación de Schroedinger y soluciones de la ecuación de Navier-Stokes irrotacional para fluidos viscosos. Aunque formalmente se trate de una generalización de la interpretación hidrodinámica de Madelung, la presencia del término viscoso sugiere una nueva interpretación. Se propone la probabilidad cuántica como modelo físico del fluido. Se obtiene que la viscosidad (dependiente del estado) es proporcional a la constante de Planck, mientras que la densidad de entropía es proporcional a la constante de Boltzmann. Los estados estacionarios tienen viscosidad y tasa de producción de densidad de entropía nulas. Por otro lado, la viscosidad no nula de los estados no estacionarios proporciona un mecanismo de pérdida de información por el cual una teoría determinista (un fluido clásico gobernado por la ec. de Navier-Stokes) da lugar a una teoría emergente (una partícula cuántica gobernada por la ec. de Schroedinger). Después, se presenta un mapeo entre la mecánica cuántica y la termodinámica clásica de procesos irreversibles. En particular, los propagadores del oscilador armónico cuántico se mapean a las probabilidades condicionales que resuelven la ecuación de Chapman-Kolmogorov para procesos de Markov Gaussianos. Aunque no hay gravedad, el mapeo exhibe propiedades que recuerdan al principio holográfico de la gravedad cuántica. Finalmente, se muestra cómo la termoestática clásica de procesos de equilibrio posee una teoría cuántica dual con un espacio de Hilbert finito - dimensional de estados cuánticos. Concretamente, el núcleo de cierto operador Hamiltoniano se convierte en el espacio de Hilbert de una mecánica cuántica cuasiestática. La relación de la termoestática a la teoría topológica de campos se discute en el contexto de la mecánica cuántica emergente, donde el concepto de entropía juega un papel clave.
Aquesta tesi doctoral es presenta com a compilació de les publicacions \cite{NS, holographic, topological}. El següent resum es una adaptació dels seus resums. S'ha argumentat que la mecànica quàntica podria emergir com a granulat gros d'una teoria determinista subjacent. Es dóna suport a aquesta visió mitjaçant uns mapes entre la mecànica quàntica no relativista i teories termodinàmiques, ja que les darreres són el paradigma de teoria emergent. Primer, s'estableix un mapa entre certes solucions de l'equació de Schroedinger i solucions de l'equació de Navier-Stokes irrotacional per a fluids viscosos. Tot i que formalment es tracte d'una generalització de la interpretació hidrodinàmica de Madelung, la presència del terme viscós ens porta a una nova interpretación. Es proposa la probabilitat quàntica com a model físic del fluid. S'obté que la viscositat del fluid (que depén de l'estat) es proporcional a la constant de Planck, mentre que la densitat d'entropía es proporcional a la constant de Boltzmann. Els estats estacionaris tenen viscositat nul·la i taxa de producció d'entropia nul·la. Per alta banda, la viscositat no nul·la dels estats estacionaris proporciona un mecanisme de pèrdua d'informació pel qual una teoria determinista (un fluid clàssic governat per l'equació de Navier-Stokes) dóna lloc a una teoria emergent (una partícula quàntica governada per l'equació de Schroedinger). Després, es presenta un mapa entre la mecànica quàntica i la termodinàmica clàssica de processos irreversibles. En particular, els propagadors de l'oscil·lador harmònic quàntic es mapejen a les probabilitats condicional que resolen l'ecuació de Chapman-Kolmogorov per a processos de Markov Gaussians. Tot i que no hi ha gravetat present a la nostra construcció, el mapa exhibeix propietats que recorden al principi hologràfic de la gravetat quàntica. Finalment, es mostra cóm la termoestàtica clàssica de processos d'equilibri té una teoria quàntica dual amb un espai de Hilbert de dimensió finita d'estats quàntics. En concret, el nucli de cert operador Hamiltonià es converteix en l'espai de Hilbert d'una mecànica quàntica quasiestàtica. La relació de la termoestàtica a la teoria topològica de camps es dicuteix en el context de la mecànica quàntica emergent, on el concepte d'entropia té un paper clau.
Vázquez Molina, J. (2017). Mappings between Thermodynamics and Quantum Mechanics that support its interpretation as an emergent theory [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/83122
TESIS
Kleeman, R. "Generalized quantization and colour algebras /." Title page, table of contents and abstract only, 1985. http://web4.library.adelaide.edu.au/theses/09PH/09phk635.pdf.
Full textAlmeida, Alexandre Araujo Amaral de. "Methodology for mapping quantum and reversible circuits to IBM Q architectures /." Ilha Solteira, 2019. http://hdl.handle.net/11449/190680.
Full textAbstract: Research in the field of quantum circuits has increased as technology advances in the development of quantum computers. IBM offers access to quantum computers via the cloud service called IBM Q. However, these architectures have some restrictions regarding the types of quantum gates that can be realized. This work proposes a methodology for the mapping of quantum and reversible circuits to the architectures made available by the IBM Q project. The methodology consists in finding CNOT mappings using a set of defined qubits movements to satisfy the architectures constraints by adding as few gates as possible. In order to reduce the number of CNOT gates needing mapping, the permutation of the circuit can be changed. One alternative to find this permutation is trough exhaustive search. However, is not feasible as the number of qubit increases. To solve this problem, the permutation problem was formulated as an Integer Linear Programming problem. The mapping of quantum circuits realized with non-implementable gates and reversible Toffoli circuits to the IBM quantum architectures were proposed in this work as well. This was done by adapting the developed CNOT mappings along with the Integer Linear Programming formulation. The proposed methodology was evaluated by mapping quantum and reversible circuits to an IBM quantum architectures with 5 and 16 qubits. The results were compared with two algorithms that map quantum circuits to IBM architectures. The cost metric used in the evalua... (Complete abstract click electronic access below)
Resumo: Pesquisa no campo de circuitos quânticos tem alavancado conforme a tecnologia avança no desenvolvimento de computadores quânticos. Atualmente, a IBM oferece acesso a computadores quânticos através do serviço em nuvem chamado IBM Q. No entanto, essas arquiteturas têm algumas restrições com relação aos tipos de portas quânticas e qubits em que uma porta CNOT pode ser implementada. Neste trabalho foi proposta uma metodologia para o mapeamento de circuitos quânticos e reversíveis para as arquiteturas disponibilizadas pelo projeto IBM Q. A metodologia consiste em mapear as portas CNOT utilizando uma série de movimentos de qubits, mantendo a permutação do circuito inalterada. A fim de reduzir o número de portas CNOT não implementáveis, a permutação do circuito pode ser alterada. Uma alternativa para encontrar essa permutação é a busca exaustiva. No entanto, é inviável conforme o número de qubits aumenta. Para resolver este problema, o problema de permutação foi formulado como um problema de Programação Linear Inteira. Como a metodologia é facilmente adaptável, o mapeamento de circuitos quânticos utilizando portas quânticas não implementáveis e circuitos reversíveis Toffoli também foram propostas neste trabalho. A avaliação da metodologia proposta foi feita com a realização do mapeamento de circuitos quânticos e reversíveis para arquiteturas quânticas com 5 e 16 qubits. Os resultados foram comparados com dois algoritmos que mapeiam circuitos quânticos para arquiteturas IBM. A métric... (Resumo completo, clicar acesso eletrônico abaixo)
Doutor
Wallrapp, Frank. "Mixed quantum and classical simulation techniques for mapping electron transfer in proteins." Doctoral thesis, Universitat Pompeu Fabra, 2011. http://hdl.handle.net/10803/22685.
Full textThe focus of this PhD thesis lies on electron transfer (ET) processes, belonging to the simplest but most crucial reactions in biochemistry. Getting direct information of the forces driving the process and the actual electron pathway is not a trivial task. Such atomic and electronic detailed information, however, is very valuable in terms of a better understanding of the enzymatic cycle, which might lead, for example, to more efficient protein inhibitor design. The main objective of this thesis was the development of a methodology for the quantitative study of ET in biological systems. In this regard, we developed a novel approach to map long-‐range electron transfer pathways, called QM/MM e-‐Pathway. The method is based on a successive search for important ET residues in terms of modifying the QM region following the evolution of the spin density of the electron (hole) within a given transfer region. We proved the usefulness and applicability of the algorithm on the P450cam/Pdx complex, indicating the key role of Arg112 of P450cam and Asp48 of Pdx for its ET pathway, both being known to be important from the literature. Besides only identifying the ET pathways, we further quantified their importance in terms of electronic coupling of donor and acceptor incorporating the particular pathway residues. Within this regard, we performed two systematic evaluations of the underlying reasons for the influence of solvent and temperature onto electronic coupling in oligopeptide model systems. Both studies revealed that electronic coupling values strongly fluctuate throughout the molecular dynamics trajectories obtained, and the mechanism of electron transfer is affected by the conformational space the system is able to occupy. Combining both ET mapping and electronic coupling calculations, we finally investigated the electron transfer in the CcP/Cytc complex. Our findings indicate the key role of Trp191 being the bridge-‐localized state of the ET as well as the main pathway consisting of Ala194, Ala193, Gly192 and Trp191 between CcP and Cytc. Both findings were confirmed through the literature. Moreover, our calculations on several snapshots state a nongated ET mechanism in this protein complex. The methodology developed along this thesis, mapping ET pathways together with their evaluation through electronic coupling calculations, suggests a straightforward and promising approach to investigate long-‐range ET in proteins.
Weggler, Timo [Verfasser]. "Paving the way for structure mapping measurements of biological macromolecules using a single quantum sensor / Timo Weggler." Ulm : Universität Ulm, 2021. http://d-nb.info/1239180241/34.
Full textFaitg, Matthieu. "Mapping class groups, skein algebras and combinatorial quantization." Thesis, Montpellier, 2019. http://www.theses.fr/2019MONTS023/document.
Full textThe algebras L(g,n,H) have been introduced by Alekseev-Grosse-Schomerus and Buffenoir-Roche in the middle of the 1990's, in the program of combinatorial quantization of the moduli space of flat G-connections over the surface S(g,n) of genus g with n open disks removed. The Hopf algebra H, called gauge algebra, was originally the quantum group U_q(g), with g = Lie(G). In this thesis we apply these algebras L(g,n,H) to low-dimensional topology (mapping class groups and skein algebras of surfaces), under the assumption that H is a finite dimensional factorizable ribbon Hopf algebra which is not necessarily semisimple, the guiding example of such a Hopf algebra being the restricted quantum group associated to sl(2) (at a 2p-th root of unity).First, we construct from L(g,n,H) a projective representation of the mapping class groups of S(g,0)D and of S(g,0) (D being an open disk). We provide formulas for the representations of Dehn twists generating the mapping class group; in particular these formulas allow us to show that our representation is equivalent to the one constructed by Lyubashenko-Majid and Lyubashenko via categorical methods. For the torus S(1,0) with the restricted quantum group associated to sl(2) for the gauge algebra, we compute explicitly the representation of SL(2,Z) using a suitable basis of the representation space and we determine the structure of this representation.Second, we introduce a diagrammatic description of L(g,n,H) which enables us to define in a very natural way the Wilson loop map W. This maps associates an element of L(g,n,H) to any link in (S(g,n)D) x [0,1] which is framed, oriented and colored by H-modules. When the gauge algebra is the restricted quantum group associated to sl(2), we use W and the representations of L(g,n,H) to construct representations of the skein algebras S_q(S(g,n)). For the torus S(1,0) we explicitly study this representation
Chuang, Patty. "Comparison of EC-Kit with Quanti-Tray[tm] : testing, verification, and drinking water quality mapping in Capiz Province, Philippines." Thesis, Massachusetts Institute of Technology, 2010. http://hdl.handle.net/1721.1/60761.
Full textCataloged from PDF version of thesis.
Includes bibliographical references (p. 67-70).
This thesis accomplishes three tasks. First, it verifies the EC-Kit under different water source conditions by comparing it to a laboratory standard method, the IDEXX Quanti-Tray[tm]. The EC-Kit is a simple, inexpensive field test kit that contains complementary tests for Escherichia coli and total coliform: the Colilert[tm] 10-milliliter presence/absence test and 3MTMS Petrifilm[tm] test. This work was executed by analyzing 521 water samples collected in Capiz Province, Philippines as well as 40 water samples from the Charles River in Cambridge, Massachusetts. Second, it determines the risk level for drinking water sources according to E.coli and total coliform levels in Capiz Province for difference locations and source types. Third, this study contributes to an ongoing mapping project, aimed at creating an interactive, searchable map of water quality results from EC-Kit and Quanti-Tray[tm]. The results of the study reveal that each component of EC-Kit and the entire kit itself is correlated to Quanti-Tray[tm] in a statistically significant way. Moreover, from the calculations of error and proportional reduction in error for unimproved/improved water sources, it is possible to make better predictions with just the use of the Colilert[tm] test, but not just the use of the TM T Petrifilm . This is because the detection limits for PetrifilmTM are an order of magnitude higher than Colilert[tm], namely PetrifilmTM colony counts of 1-10/1 mL sample results fall within the High and colony counts of 10-100/1 mL of sample fall within the Very High risk level categories, whereas positive Colilert[tm] results fall within the Intermediate, High, and Very High risk level categories. Most importantly, the EC-Kit allows for the best reduction in error, with a proportional reduction in error of 63% for unimproved water sources and 60% for improved water sources. This finding is significant because it means that a simple, inexpensive field kit can change our understanding of the safety of drinking water compared to simply knowing the United Nations infrastructure designation of improved versus unimproved water sources. Furthermore, the statistical analysis revealed that while the EC-Kit does not exactly match the Quanti-Tray[tm] results, it still provides useful information for assessing at-risk water sources.
by Patty Chuang.
M.Eng.
Zamoum, Redouane. "Etude théorique des fluctuations de courant de l'admittance et de la densité d'états d'un nano-système en interaction." Phd thesis, Aix-Marseille Université, 2013. http://tel.archives-ouvertes.fr/tel-00881571.
Full textMartel-Tordjman, Jules. "Interprétations homologiques d'invariants quantiques." Thesis, Toulouse 3, 2019. http://www.theses.fr/2019TOU30285.
Full textWe provide homological interpretations for some quantum invariants. We recall basic notions involved in this work: topological ones on one hand (braids, mapping class groups, and homological representations of the latter) and algebaic ones on the other hand (Hopf algebra, quantum groups, categories of modules, braiding). Then, we study "small cases": We show that the Gassner representation is contained in quantum representations of the braid group. We build Bigelow-Krammer-Lawrence representations in a colored version and we give matrices for the action. Finally we study the non semi-simple TQFT (built by Blanchet - Costantino - Geer - Patureau) representation of the mapping class group of the sphere with 4 punctures. We recognize homological representation inside of it, and this leads to the faithfulness of the representation. In the last chapter, we study modules of relative and locally finite homology modules with coefficients in an abelian local system, over configuration spaces of punctured disks. We endow them with an algebra representation of the quantized algebra of sl(2) in an integral version. We recognize a tensor product of integral Verma modules. We identify the natural braid group representation induced on this homology (by mapping class) with the ones obtain by the braiding of the quantized algebra of sl(2). This work extends Kohno's theorem (recovered via a nice homological operation) in several directions: • it relates homological representations to the entire tensor product of Verma modules (and not only to the highest weight vectors) • it includes a homological interpretation for the action of quantum sl(2), whose definitions are inspired by a work of Felder - Wieczerkowski for which the homological aspect remained conjectural. • it is an integral version of Kohno's theorem, namely it preserves the integral structure on Laurent polynomials, thus exposes conditions of genericity previously required by Kohno's theorem. We finally reach the level of knot invariants: in Chapter 4, this homological model for quantum braid representations allows us to show that colored Jones polynomials compute some weighted sum of abelianized Lefschetz numbers
Gür, Fatih Nadi. "Plasmonic waveguides self-assembled on DNA origami templates: from synthesis to near-field characterizations." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2018. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-235762.
Full textDie Manipulation des Lichts durch die Kontrolle von Oberflächenplasmonen auf metallischen Oberflächen und Nanopartikeln gilt als vielversprechende Methode zur Überbrückung der Größen-Lücke zwischen Mikrometer-großen photonischen und nanometer-großen elektronischen Schaltkreisen. Plasmonische Wellenleiter basierend auf metallischen Nanopartikeln sind vom besonderen Interesse, da sie die Umgehung des Beugungslimits und somit eine Hochgeschwindigkeitskommunikation über kurze Distanzen in immer kleiner werdenden Schaltkreisen ermöglichen könnten. Allerdings ist die skalierbare und kostengünstige Anordnung von Partikeln eine große Herausforderung und es werden Nahfelduntersuchungen benötigt um plasmonische Interaktionen detektieren zu können. Das Ziel dieser Arbeit ist die Selbstassemblierung von multi-partikel Wellenleitern auf DNA Gerüsten. Die Verwendung von DNA-Origami bietet eine äußerst vielseitige Plattform zur skalierbaren Herstellung von Nanostrukturen mittels Selbstassemblierung und ermöglicht eine präzise Kontrolle der Anordnungen im Nanobereich. Für den Aufbau der plasmonischen Wellenleiter werden DNA-Origami Nanoröhren, bestehend aus sechs Helices als Templat für die Anbindung von monodispersen und monokristallinen Goldnanopartikeln mit einem interpartikulären Abstand von 1-2 nm verwendet. Im ersten Abschnitt dieser Arbeit werden die beeinflussenden Faktoren dieser Assemblierungsreaktion systematisch untersucht. Die Ausbeute der assemblierten Strukturen und die Besetzung der Bindungsstellen werden durch eine automatisierte und effiziente Bildanalyse von Elektronenmikroskopieaufnahmen ausgewertet. Durch die Entwicklung eines optimierten Syntheseprotokolls werden bisher unerreichte Assemblierungsausbeuten ermöglicht. Zusätzlich erfolgen die experimentelle Realisierung von Strukturen mit verschieden großen Goldnanopartikeln und unterschiedlichen interpartikulären Abständen, sowie die Anbindung von Quantenpunkten an die Wellenleiter und eine Verknüpfung der assemblierten Strukturen. Der zweite Abschnitt dieser Dissertation befasst sich mit der Untersuchung des Energietransports in selbstassemblierten Wellenleitern über einen fluoreszierenden Nanodiamanten. Dazu erfolgen hochaufgelöste Nahfeldmessungen der Wellenleiter mittels Elektronenenergieverlustspektroskopie und Kathodolumineszenz-mikroskopie. Die experimentellen Ergebnisse und zusätzlich durchgeführte Simulationen bestätigen eine durch gekoppelte Oberflächenplasmonenmoden induzierte Weitergabe der Energie innerhalb des Wellenleiters. Diese Oberflächenplasmonenmoden werden bei hoher räumlicher und spektraler Auflösung untersucht. Das hier umgesetzte Konzept der Selbstassemblierung wird den Aufbau komplexer plasmonischer Geräte für Anwendungen im Bereich der optischen Hochgeschwindigkeitsdatenübertragung, der Quanteninformations-technolgie und der Sensorik ermöglichen
Katona, Gregory. "Field Theoretic Lagrangian From Off-Shell Supermultiplet Gauge Quotients." Doctoral diss., University of Central Florida, 2013. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/5958.
Full textPh.D.
Doctorate
Physics
Sciences
Physics
Kleeman, R. (Richard). "Generalized quantization and colour algebras / by R. Kleeman." 1985. http://hdl.handle.net/2440/20597.
Full textvii, 147 leaves ; 30 cm.
Title page, contents and abstract only. The complete thesis in print form is available from the University Library.
Thesis (Ph.D.)--University of Adelaide, Dept. of Mathematical Physics, 1986
McBride, Matthew Scott. "D-bar and Dirac Type Operators on Classical and Quantum Domains." 2012. http://hdl.handle.net/1805/2931.
Full textI study d-bar and Dirac operators on classical and quantum domains subject to the APS boundary conditions, APS like boundary conditions, and other types of global boundary conditions. Moreover, the inverse or inverse modulo compact operators to these operators are computed. These inverses/parametrices are also shown to be bounded and are also shown to be compact, if possible. Also the index of some of the d-bar operators are computed when it doesn't have trivial index. Finally a certain type of limit statement can be said between the classical and quantum d-bar operators on specialized complex domains.
Silva, Carla Maria Alves Pereira da. "Quantum Machine Intelligence: Mapping AI Applications." Doctoral thesis, 2021. https://hdl.handle.net/10216/138490.
Full textSasanian, Zahra. "Technology mapping and optimization for reversible and quantum circuits." Thesis, 2012. http://hdl.handle.net/1828/4324.
Full textGraduate
Nassimi, Ali M. "A Study of Quantum-classical Dynamics in the Mapping Basis." Thesis, 2011. http://hdl.handle.net/1807/29824.
Full textLai, Yu-Ren, and 賴祐仁. "Complete experimental mapping of the quantum phase diagram for the two-impurity Kondo effect." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/52997432528651576679.
Full text國立交通大學
物理研究所
103
In this work, we fabricated a series of (Cu/Al)/AlOx/Y planar tunnel junctions which are on the different location of the phase diagram for two-impurity Kondo effect. In (Cu/Al)/AlOx/Y tunnel junctions, the Y atoms will diffuse into AlOx barrier to be treated as the spin-½ magnetic impurities and result in Kondo effect. We tune the coupling strength between magnetic impurity and electrode by modulating barrier properties. We measured the differential conductance G(V,T) in a dozen of (Cu/Al)/AlOx/Y tunnel junctions. For all junctions, we can observe the weak coupling behavior, i.e. G(0,T) is -logT dependence, between about 10 – 35 K. And a quantum critical regime also can be observed in the range about 2 – 25 K, in which shows non-Fermi liquid behavior. G(V,T) obeys the two-impurity Kondo universal scaling form. As the temperature further decreases, the G(V,T) of tunnel junctions will cross over to three different behaviors. First one is the Kondo screened ground state (Fermi liquid behavior), second one is the RKKY local spin singlet state (Fermi liquid behavior), and the other one is in the vicinity around quantum critical point. G(V,T) clearly shows three different behavior with varying temperature, bias voltage and applied magnetic field. Furthermore, the versatile tunnel junction can achieve very high TK (~ 40 K) to explore quantum phase transition in a wide window, and may be of potential relevance to many strongly correlated electron systems.
Abhale, Atul Prakash. "Laser Beam Induced Conductance Modulations as a Potential Microprobe in the Investigation of Defects and Inhomogeneities in Bulk Si and PbS, HgCdTe Quantum Dot Heterostructures." Thesis, 2017. http://etd.iisc.ernet.in/2005/3557.
Full textMoosavi, Askari Reza. "Experimental and numerical study of a magnetic realization of a Bose-Einstein Condensate in a purely organic spin-1/2 quantum magnet (NIT2Py)." Thèse, 2016. http://hdl.handle.net/1866/20605.
Full textGür, Fatih Nadi. "Plasmonic waveguides self-assembled on DNA origami templates: from synthesis to near-field characterizations." Doctoral thesis, 2017. https://tud.qucosa.de/id/qucosa%3A31000.
Full textDie Manipulation des Lichts durch die Kontrolle von Oberflächenplasmonen auf metallischen Oberflächen und Nanopartikeln gilt als vielversprechende Methode zur Überbrückung der Größen-Lücke zwischen Mikrometer-großen photonischen und nanometer-großen elektronischen Schaltkreisen. Plasmonische Wellenleiter basierend auf metallischen Nanopartikeln sind vom besonderen Interesse, da sie die Umgehung des Beugungslimits und somit eine Hochgeschwindigkeitskommunikation über kurze Distanzen in immer kleiner werdenden Schaltkreisen ermöglichen könnten. Allerdings ist die skalierbare und kostengünstige Anordnung von Partikeln eine große Herausforderung und es werden Nahfelduntersuchungen benötigt um plasmonische Interaktionen detektieren zu können. Das Ziel dieser Arbeit ist die Selbstassemblierung von multi-partikel Wellenleitern auf DNA Gerüsten. Die Verwendung von DNA-Origami bietet eine äußerst vielseitige Plattform zur skalierbaren Herstellung von Nanostrukturen mittels Selbstassemblierung und ermöglicht eine präzise Kontrolle der Anordnungen im Nanobereich. Für den Aufbau der plasmonischen Wellenleiter werden DNA-Origami Nanoröhren, bestehend aus sechs Helices als Templat für die Anbindung von monodispersen und monokristallinen Goldnanopartikeln mit einem interpartikulären Abstand von 1-2 nm verwendet. Im ersten Abschnitt dieser Arbeit werden die beeinflussenden Faktoren dieser Assemblierungsreaktion systematisch untersucht. Die Ausbeute der assemblierten Strukturen und die Besetzung der Bindungsstellen werden durch eine automatisierte und effiziente Bildanalyse von Elektronenmikroskopieaufnahmen ausgewertet. Durch die Entwicklung eines optimierten Syntheseprotokolls werden bisher unerreichte Assemblierungsausbeuten ermöglicht. Zusätzlich erfolgen die experimentelle Realisierung von Strukturen mit verschieden großen Goldnanopartikeln und unterschiedlichen interpartikulären Abständen, sowie die Anbindung von Quantenpunkten an die Wellenleiter und eine Verknüpfung der assemblierten Strukturen. Der zweite Abschnitt dieser Dissertation befasst sich mit der Untersuchung des Energietransports in selbstassemblierten Wellenleitern über einen fluoreszierenden Nanodiamanten. Dazu erfolgen hochaufgelöste Nahfeldmessungen der Wellenleiter mittels Elektronenenergieverlustspektroskopie und Kathodolumineszenz-mikroskopie. Die experimentellen Ergebnisse und zusätzlich durchgeführte Simulationen bestätigen eine durch gekoppelte Oberflächenplasmonenmoden induzierte Weitergabe der Energie innerhalb des Wellenleiters. Diese Oberflächenplasmonenmoden werden bei hoher räumlicher und spektraler Auflösung untersucht. Das hier umgesetzte Konzept der Selbstassemblierung wird den Aufbau komplexer plasmonischer Geräte für Anwendungen im Bereich der optischen Hochgeschwindigkeitsdatenübertragung, der Quanteninformations-technolgie und der Sensorik ermöglichen.
日比野, 倫夫, 孝明 花井, and せつ子 杉山. "高感度・高解像度元素マッピング像観察の研究." 1994. http://hdl.handle.net/2237/13002.
Full text