Journal articles on the topic 'Proxies de pCO2'
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Badger, Marcus P. S., Thomas B. Chalk, Gavin L. Foster, Paul R. Bown, Samantha J. Gibbs, Philip F. Sexton, Daniela N. Schmidt, Heiko Pälike, Andreas Mackensen, and Richard D. Pancost. "Insensitivity of alkenone carbon isotopes to atmospheric CO<sub>2</sub> at low to moderate CO<sub>2</sub> levels." Climate of the Past 15, no. 2 (March 27, 2019): 539–54. http://dx.doi.org/10.5194/cp-15-539-2019.
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Abstract. Atmospheric pCO2 is a critical component of the global carbon system and is considered to be the major control of Earth's past, present, and future climate. Accurate and precise reconstructions of its concentration through geological time are therefore crucial to our understanding of the Earth system. Ice core records document pCO2 for the past 800 kyr, but at no point during this interval were CO2 levels higher than today. Interpretation of older pCO2 has been hampered by discrepancies during some time intervals between two of the main ocean-based proxy methods used to reconstruct pCO2: the carbon isotope fractionation that occurs during photosynthesis as recorded by haptophyte biomarkers (alkenones) and the boron isotope composition (δ11B) of foraminifer shells. Here, we present alkenone and δ11B-based pCO2 reconstructions generated from the same samples from the Pliocene and across a Pleistocene glacial–interglacial cycle at Ocean Drilling Program (ODP) Site 999. We find a muted response to pCO2 in the alkenone record compared to contemporaneous ice core and δ11B records, suggesting caution in the interpretation of alkenone-based records at low pCO2 levels. This is possibly caused by the physiology of CO2 uptake in the haptophytes. Our new understanding resolves some of the inconsistencies between the proxies and highlights that caution may be required when interpreting alkenone-based reconstructions of pCO2.
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Dupont, Lydie M., Thibaut Caley, and Isla S. Castañeda. "Effects of atmospheric CO<sub>2</sub> variability of the past 800 kyr on the biomes of southeast Africa." Climate of the Past 15, no. 3 (June 19, 2019): 1083–97. http://dx.doi.org/10.5194/cp-15-1083-2019.
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Abstract. Very little is known about the impact of atmospheric carbon dioxide pressure (pCO2) on the shaping of biomes. The development of pCO2 throughout the Brunhes Chron may be considered a natural experiment to elucidate relationships between vegetation and pCO2. While the glacial periods show low to very low values (∼220 to ∼190 ppmv, respectively), the pCO2 levels of the interglacial periods vary from intermediate to relatively high (∼250 to more than 270 ppmv, respectively). To study the influence of pCO2 on the Pleistocene development of SE African vegetation, we used the pollen record of a marine core (MD96-2048) retrieved from Delagoa Bight south of the Limpopo River mouth in combination with stable isotopes and geochemical proxies. Applying endmember analysis, four pollen assemblages could be distinguished representing different biomes: heathland, mountain forest, shrubland and woodland. We find that the vegetation of the Limpopo River catchment and the coastal region of southern Mozambique is influenced not only by hydroclimate but also by temperature and atmospheric pCO2. Our results suggest that the extension of mountain forest occurred during those parts of the glacials when pCO2 and temperatures were moderate and that only during the colder periods when atmospheric pCO2 was low (less than 220 ppmv) open ericaceous vegetation including C4 sedges extended. The main development of woodlands in the area took place after the Mid-Brunhes Event (∼430 ka) when interglacial pCO2 levels regularly rose over 270 ppmv.
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Schwemmer, T. G., H. Baumann, C. S. Murray, A. I. Molina, and J. A. Nye. "Acidification and hypoxia interactively affect metabolism in embryos, but not larvae, of the coastal forage fish Menidia menidia." Journal of Experimental Biology 223, no. 22 (October 12, 2020): jeb228015. http://dx.doi.org/10.1242/jeb.228015.
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ABSTRACTOcean acidification is occurring in conjunction with warming and deoxygenation as a result of anthropogenic greenhouse gas emissions. Multistressor experiments are critically needed to better understand the sensitivity of marine organisms to these concurrent changes. Growth and survival responses to acidification have been documented for many marine species, but studies that explore underlying physiological mechanisms of carbon dioxide (CO2) sensitivity are less common. We investigated oxygen consumption rates as proxies for metabolic responses in embryos and newly hatched larvae of an estuarine forage fish (Atlantic silverside, Menidia menidia) to factorial combinations of CO2×temperature or CO2×oxygen. Metabolic rates of embryos and larvae significantly increased with temperature, but partial pressure of CO2 (PCO2) alone did not affect metabolic rates in any experiment. However, there was a significant interaction between PCO2 and partial pressure of oxygen (PO2) in embryos, because metabolic rates were unaffected by PO2 level at ambient PCO2, but decreased with declining PO2 under elevated PCO2. For larvae, however, PCO2 and PO2 had no significant effect on metabolic rates. Our findings suggest high individual variability in metabolic responses to high PCO2, perhaps owing to parental effects and time of spawning. We conclude that early life metabolism is largely resilient to elevated PCO2 in this species, but that acidification likely influences energetic responses and thus vulnerability to hypoxia.
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Witkowski, Caitlyn R., Sylvain Agostini, Ben P. Harvey, Marcel T. J. van der Meer, Jaap S. Sinninghe Damsté, and Stefan Schouten. "Validation of carbon isotope fractionation in algal lipids as a <i>p</i>CO<sub>2</sub> proxy using a natural CO<sub>2</sub> seep (Shikine Island, Japan)." Biogeosciences 16, no. 22 (November 25, 2019): 4451–61. http://dx.doi.org/10.5194/bg-16-4451-2019.
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Abstract. Carbon dioxide concentrations in the atmosphere play an integral role in many Earth system dynamics, including its influence on global temperature. The past can provide insights into these dynamics, but unfortunately reconstructing long-term trends of atmospheric carbon dioxide (expressed in partial pressure; pCO2) remains a challenge in paleoclimatology. One promising approach for reconstructing past pCO2 utilizes the isotopic fractionation associated with CO2 fixation during photosynthesis into organic matter (εp). Previous studies have focused primarily on testing estimates of εp derived from the δ13C of species-specific alkenone compounds in laboratory cultures and mesocosm experiments. Here, we analyze εp derived from the δ13C of more general algal biomarkers, i.e., compounds derived from a multitude of species from sites near a CO2 seep off the coast of Shikine Island (Japan), a natural environment with CO2 concentrations ranging from ambient (ca. 310 µatm) to elevated (ca. 770 µatm) pCO2. We observed strong, consistent δ13C shifts in several algal biomarkers from a variety of sample matrices over the steep CO2 gradient. Of the three general algal biomarkers explored here, namely loliolide, phytol, and cholesterol, εp positively correlates with pCO2, in agreement with εp theory and previous culture studies. pCO2 reconstructed from the εp of general algal biomarkers show the same trends throughout, as well as the correct control values, but with lower absolute reconstructed values than the measured values at the elevated pCO2 sites. Our results show that naturally occurring CO2 seeps may provide useful testing grounds for pCO2 proxies and that general algal biomarkers show promise for reconstructing past pCO2.
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Li, Xianghui, Jingyu Wang, Troy Rasbury, Min Zhou, Zhen Wei, and Chaokai Zhang. "Early Jurassic climate and atmospheric CO<sub>2</sub> concentration in the Sichuan paleobasin, southwestern China." Climate of the Past 16, no. 6 (November 4, 2020): 2055–74. http://dx.doi.org/10.5194/cp-16-2055-2020.
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Abstract. Climatic oscillations have been developed through the (Early) Jurassic from marine sedimentary archives but remain unclear from terrestrial records. This work presents investigation of climate-sensitive sediments and carbon and oxygen isotope analyses of lacustrine and pedogenic carbonates for the Early Jurassic Ziliujing Formation taken from the Basin in southwestern China. Sedimentary and stable isotope proxies manifest that an overall secular (semi)arid climate dominated the Sichuan Basin during the Early Jurassic, except for the Hettangian. This climate pattern is similar to the arid climate in the Colorado Plateau region in western North America but is distinct from the relatively warm and humid climate in northern China and at high latitudes in the Southern Hemisphere. The estimated atmospheric CO2 concentration (pCO2) from carbon isotopes of pedogenic carbonates shows a range of 980–2610 ppmv (∼3.5–10 times the pre-industrial value) with a mean of 1660 ppmv. Three phases of pCO2 (the Sinemurian 1500–2000 ppmv, the Pliensbachian 1000–1500 ppmv, and the early Toarcian 1094–2610 ppmv) and two events of pCO2 rapidly falling by ∼1000–1300 ppmv are observed, illustrating the pCO2 perturbation in the Early Jurassic. The perturbation of pCO2 is compatible with seawater temperature and carbon cycle from the coeval marine sediments, suggesting a positive feedback of climate to pCO2 through the Early Jurassic.
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Thomsen, J., M. A. Gutowska, J. Saphörster, A. Heinemann, K. Trübenbach, J. Fietzke, C. Hiebenthal, et al. "Calcifying invertebrates succeed in a naturally CO<sub>2</sub> enriched coastal habitat but are threatened by high levels of future acidification." Biogeosciences Discussions 7, no. 4 (July 2, 2010): 5119–56. http://dx.doi.org/10.5194/bgd-7-5119-2010.
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Abstract. CO2 emissions are leading to an acidification of the oceans. Predicting marine community vulnerability towards acidification is difficult, as adaptation processes cannot be accounted for in most experimental studies. Naturally CO2 enriched sites thus can serve as valuable proxies for future changes in community structure. Here we describe a natural analogue site in the Western Baltic Sea. Seawater pCO2 in Kiel Fjord is elevated for large parts of the year due to upwelling of CO2 rich waters. Peak pCO2 values of >230 Pa (>2300 μatm) and pH values of <7.5 are encountered during summer and autumn, average pCO2 values are ~70 Pa (~700 μatm). In contrast to previously described naturally CO2 enriched sites that have suggested a progressive displacement of calcifying auto- and heterotrophic species, the macrobenthic community in Kiel Fjord is dominated by calcifying invertebrates. We show that blue mussels from Kiel Fjord can maintain control rates of somatic and shell growth at a pCO2 of 142 Pa (1400 μatm, pH=7.7). Juvenile mussel recruitment peaks during the summer months, when high water pCO2 values of ~100 Pa (~1000 μatm) prevail. Our findings indicate that calcifying keystone species may be able to cope with surface ocean pH values projected for the end of this century. However, owing to non-linear synergistic effects of future acidification and upwelling of corrosive water, peak seawater pCO2 in Kiel Fjord and many other productive estuarine habitats could increase to values >400 Pa (>4000 μatm). These changes will most likely affect calcification and recruitment, and increase external shell dissolution.
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Thomsen, J., M. A. Gutowska, J. Saphörster, A. Heinemann, K. Trübenbach, J. Fietzke, C. Hiebenthal, et al. "Calcifying invertebrates succeed in a naturally CO<sub>2</sub>-rich coastal habitat but are threatened by high levels of future acidification." Biogeosciences 7, no. 11 (November 26, 2010): 3879–91. http://dx.doi.org/10.5194/bg-7-3879-2010.
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Abstract. CO2 emissions are leading to an acidification of the oceans. Predicting marine community vulnerability towards acidification is difficult, as adaptation processes cannot be accounted for in most experimental studies. Naturally CO2 enriched sites thus can serve as valuable proxies for future changes in community structure. Here we describe a natural analogue site in the Western Baltic Sea. Seawater pCO2 in Kiel Fjord is elevated for large parts of the year due to upwelling of CO2 rich waters. Peak pCO2 values of >230 Pa (>2300 μatm) and pHNBS values of <7.5 are encountered during summer and autumn, average pCO2 values are ~70 Pa (~700 μatm). In contrast to previously described naturally CO2 enriched sites that have suggested a progressive displacement of calcifying auto- and heterotrophic species, the macrobenthic community in Kiel Fjord is dominated by calcifying invertebrates. We show that blue mussels from Kiel Fjord can maintain control rates of somatic and shell growth at a pCO2 of 142 Pa (1400 μatm, pHNBS = 7.7). Juvenile mussel recruitment peaks during the summer months, when high water pCO2 values of ~100 Pa (~1000 μatm) prevail. Our findings indicate that calcifying keystone species may be able to cope with surface ocean pHNBS values projected for the end of this century when food supply is sufficient. However, owing to non-linear synergistic effects of future acidification and upwelling of corrosive water, peak seawater pCO2 in Kiel Fjord and many other productive estuarine habitats could increase to values >400 Pa (>4000 μatm). These changes will most likely affect calcification and recruitment, and increase external shell dissolution.
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Noonan, Sam H. C., and Katharina E. Fabricius. "Ocean acidification affects productivity but not the severity of thermal bleaching in some tropical corals." ICES Journal of Marine Science 73, no. 3 (July 22, 2015): 715–26. http://dx.doi.org/10.1093/icesjms/fsv127.
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Abstract Increasing carbon dioxide (CO2) emissions are raising sea surface temperature (SST) and causing ocean acidification (OA). While higher SST increases the frequency of mass coral bleaching events, it is unclear how OA will interact to affect this process. In this study, we combine in situ bleaching surveys around three tropical CO2 seeps with a 2-month two-factor (CO2 and temperature) tank experiment to investigate how OA and SST in combination will affect the bleaching susceptibility of tropical reef corals. Surveys at CO2 seep and control sites during a minor regional bleaching event gave little indication that elevated pCO2 influenced the bleaching susceptibility of the wider coral community, the four most common coral families (Acroporidae, Faviidae, Pocilloporidae, or Poritidae), or the thermally sensitive coral species Seriatopora hystrix. In the tank experiment, sublethal bleaching was observed at 31°C after 5 d in S. hystrix and 12 d in Acropora millepora, whereas controls (28°C) did not bleach. None of the measured proxies for coral bleaching was negatively affected by elevated pCO2 at pHT 7.79 (vs. 7.95 pHT in controls), equivalent to ∼780 µatm pCO2 and an aragonite saturation state of 2.5. On the contrary, high pCO2 benefitted some photophysiological measures (although temperature effects were much stronger than CO2 effects): maximum photosystem II quantum yields and light-limited electron transport rates increased in both species at high pCO2, whereas gross photosynthesis and pigment concentrations increased in S. hystrix at high pCO2. The field and laboratory data in combination suggest that OA levels up to a pHT of 7.8 will have little effect on the sensitivity of tropical corals to thermal bleaching. Indeed, some species appear to be able to utilize the more abundant dissolved inorganic carbon to increase productivity; however, these gains offset only a small proportion of the massive bleaching-related energy losses during thermal stress.
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Sigwart, Julia D., Gillian Lyons, Artur Fink, Magdalena A. Gutowska, Darren Murray, Frank Melzner, Jonathan D. R. Houghton, and Marian Yong-an Hu. "Elevated pCO2 drives lower growth and yet increased calcification in the early life history of the cuttlefish Sepia officinalis (Mollusca: Cephalopoda)." ICES Journal of Marine Science 73, no. 3 (October 29, 2015): 970–80. http://dx.doi.org/10.1093/icesjms/fsv188.
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Abstract Ocean acidification is an escalating environmental issue and associated changes in the ocean carbonate system have implications for many calcifying organisms. The present study followed the growth of Sepia officinalis from early-stage embryos, through hatching, to 7-week-old juveniles. Responses of cuttlefish to elevated pCO2 (hypercapnia) were investigated to test the impacts of near-future and extreme ocean acidification conditions on growth, developmental time, oxygen consumption, and yolk utilization as proxies for individual fitness. We further examined gross morphological characteristics of the internal calcareous cuttlebone to determine whether embryonically secreted shell lamellae are impacted by environmental hypercapnia. Embryonic growth was reduced and hatching delayed under elevated pCO2, both at environmentally relevant levels (0.14 kPa pCO2 similar to predicted ocean conditions in 2100) and extreme conditions (0.40 kPa pCO2). Comparing various metrics from control and intermediate treatments generally showed no significant difference in experimental measurements. Yet, results from the high pCO2 treatment showed significant changes compared with controls and revealed a consistent general trend across the three treatment levels. The proportion of animal mass contributed by the cuttlebone increased in both elevated pCO2 treatments. Gross cuttlebone morphology was affected under such conditions and cuttlebones of hypercapnic individuals were proportionally shorter. Embryonic shell morphology was maintained consistently in all treatments, despite compounding hypercapnia in the perivitelline fluid; however, post-hatching, hypercapnic animals developed denser cuttlebone laminae in shorter cuttlebones. Juvenile cuttlefish in acidified environments thus experience lower growth and yet increased calcification of their internal shell. The results of this study support recent findings that early cuttlefish life stages are more vulnerable towards hypercapnia than juveniles and adults, which may have negative repercussions on the biological fitness of cuttlefish hatchlings in future oceans.
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Hu, Jin-Jin, Yao-Wu Xing, Tao Su, Yong-Jiang Huang, and Zhe-Kun Zhou. "Stomatal frequency of Quercus glauca from three material sources shows the same inverse response to atmospheric pCO2." Annals of Botany 123, no. 7 (March 12, 2019): 1147–58. http://dx.doi.org/10.1093/aob/mcz020.
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AbstractBackground and AimsThe inverse correlation between atmospheric CO2 partial pressure (pCO2) and stomatal frequency in many plants has been widely used to estimate palaeo-CO2 levels. However, apparent discrepancies exist among the obtained estimates. This study attempts to find a potential proxy for palaeo-CO2 concentrations by analysing the stomatal frequency of Quercus glauca (section Cyclobalanopsis, Fagaceae), a dominant species in East Asian sub-tropical forests with abundant fossil relatives.MethodsStomatal frequencies of Q. glauca from three material sources were analysed: seedlings grown in four climatic chambers with elevated CO2 ranging from 400 to 1300 ppm; extant samples collected from 14 field sites at altitudes ranging from 142 to 1555 m; and 18 herbarium specimens collected between 1930 and 2011. Stomatal frequency–pCO2 correlations were determined using samples from these three sources.Key ResultsAn inverse correlation between stomatal frequency and pCO2 was found for Q. glauca through cross-validation of the three material sources. The combined calibration curves integrating data of extant altitudinal samples and historical herbarium specimens improved the reliability and accuracy of the curves. However, materials in the climatic chambers exhibited a weak response and relatively high stomatal frequency possibly due to insufficient treatment time.ConclusionsA new inverse stomatal frequency–pCO2 correlation for Q. glauca was determined using samples from three sources. These three material types show the same response, indicating that Q. glauca is sensitive to atmospheric pCO2 and is an ideal proxy for palaeo-CO2 levels. Quercus glauca is a nearest living relative (NLR) of section Cyclobalanopsis fossils, which are widely distributed in the strata of East Asia ranging from the Eocene to Pliocene, thereby providing excellent materials to reconstruct the atmospheric CO2 concentration history of the Cenozoic. Quercus glauca will add to the variety of proxies that can be widely used in addition to Ginkgo and Metasequoia.
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Kvacek, Zlatko. "Tertiary vegetation of Europe and its dynamics and climatic signal-new approaches in botany of the past." Journal of Palaeosciences 57, no. (1-3) (December 31, 2008): 459–63. http://dx.doi.org/10.54991/jop.2008.264.
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Using new methodologies for assessment of vegetation patterns and climatic proxies from the fossil plant record, considerable progress has been made in reconstructing paleoclimatic development at certain time intervals of the Neogene of Europe. Geobotanical mapping has employed new classification of zonal vegetation based on Integrated Plant Record (IPR) and developed a new technology to follow vegetation (and palaeoclimate) dynamics over large areas at a particular time slice. Improved paleoclimatic methodologies of the co-existence Approach (CA) and the Climate Leaf Analysis Multivariate Program based on dicot leaf physiognomy (CLAMP) produced climatic proxies that provided additional information on the Neogene climate over Europe. The stomatal density studies proved to be another useful tool for palaeoclimatology. New reconstructions of CO2 concentrations based on several Lauraceae and Ginkgo from the mid- Tertiary of Europe showed a positive correlation between higher levels of atmospheric CO2 (pCO2) and warming trends, expressed particularly in the Lower-Middle Miocene (“Miocene Climatic Optimum”).
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Guillermic, Maxence, Sambuddha Misra, Robert Eagle, and Aradhna Tripati. "Atmospheric CO<sub>2</sub> estimates for the Miocene to Pleistocene based on foraminiferal <i>δ</i><sup>11</sup>B at Ocean Drilling Program Sites 806 and 807 in the Western Equatorial Pacific." Climate of the Past 18, no. 2 (February 2, 2022): 183–207. http://dx.doi.org/10.5194/cp-18-183-2022.
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Abstract. Constraints on the evolution of atmospheric CO2 levels throughout Earth's history are foundational to our understanding of past variations in climate. Despite considerable effort, records vary in their temporal and spatial coverage and estimates of past CO2 levels do not always converge, and therefore new records and proxies are valuable. Here we reconstruct atmospheric CO2 values across major climate transitions over the past 16 million years using the boron isotopic composition (δ11B) of planktic foraminifera from 89 samples obtained from two sites in the West Pacific Warm Pool, Ocean Drilling Program (ODP) Sites 806 and 807, measured using high-precision multi-collector inductively coupled plasma mass spectrometry. We compare our results to published data from ODP Site 872, also in the Western Equatorial Pacific, that goes back to 22 million years ago. These sites are in a region that today is near equilibrium with the atmosphere and are thought to have been in equilibrium with the atmosphere for the interval studied. We show that δ11B data from this region are consistent with other boron-based studies. The data show evidence for elevated pCO2 during the Middle Miocene and Early to Middle Pliocene, and reductions in pCO2 of ∼200 ppm during the Middle Miocene Climate Transition, ∼250 ppm during Pliocene Glacial Intensification and ∼50 ppm during the Mid-Pleistocene Climate Transition. During the Mid-Pleistocene Transition there is a minimum pCO2 at marine isotopic stage (MIS) 30. Our results are consistent with a coupling between pCO2, temperature and ice sheet expansion from the Miocene to the late Quaternary.
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Crumpton-Banks, Jessica G. M., Thomas Tanner, Ivan Hernández Almeida, James W. B. Rae, and Heather Stoll. "Technical note: No impact of alkenone extraction on foraminiferal stable isotope, trace element and boron isotope geochemistry." Biogeosciences 19, no. 24 (December 14, 2022): 5633–44. http://dx.doi.org/10.5194/bg-19-5633-2022.
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Abstract. Recent advances in geochemical techniques mean that several robust proxies now exist to determine the past carbonate chemistry of the oceans. Foraminiferal δ11B and alkenone carbon isotopes allow us to reconstruct sea-surface pH and pCO2, respectively, and the ability to apply both proxies to the same sediment sample would give strongly paired datasets and reduce sample waste. However, no studies to date have examined whether the solvents and extraction techniques used to prepare alkenones for analysis also impact the geochemistry of foraminifera within those sediments. Here we examine six species pairs of planktic foraminifera, with half being taken from non-treated sediments and half being taken from sediments where alkenones have been extracted. We look for visual signs of contrasting preservation and compare analyses of δ18O, δ13C, δ11B and trace elements (Li, B, Na, Mn, Mg, Sr and U/Ca). We find no consistent geochemical offset between the treatments and excellent agreement in δ11B measurements between them. Our results show that boron isotope reconstructions of pH in foraminifera from alkenone-extracted sediments can be applied with confidence.
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Duke, Patrick J., Roberta C. Hamme, Debby Ianson, Peter Landschützer, Mohamed M. M. Ahmed, Neil C. Swart, and Paul A. Covert. "Estimating marine carbon uptake in the northeast Pacific using a neural network approach." Biogeosciences 20, no. 18 (September 27, 2023): 3919–41. http://dx.doi.org/10.5194/bg-20-3919-2023.
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Abstract. The global ocean takes up nearly a quarter of anthropogenic CO2 emissions annually, but the variability in this uptake at regional scales remains poorly understood. Here we use a neural network approach to interpolate sparse observations, creating a monthly gridded seawater partial pressure of CO2 (pCO2) data product from January 1998 to December 2019, at 1/12∘ × 1/12∘ spatial resolution, in the northeast Pacific open ocean, a net sink region. The data product (ANN-NEP; NCEI Accession 0277836) was created from pCO2 observations within the 2021 version of the Surface Ocean CO2 Atlas (SOCAT) and a range of predictor variables acting as proxies for processes affecting pCO2 to create nonlinear relationships to interpolate observations at a spatial resolution 4 times greater than leading global products and with better overall performance. In moving to a higher resolution, we show that the internal division of training data is the most important parameter for reducing overfitting. Using our pCO2 product, wind speed, and atmospheric CO2, we evaluate air–sea CO2 flux variability. On sub-decadal to decadal timescales, we find that the upwelling strength of the subpolar Alaskan Gyre, driven by large-scale atmospheric forcing, acts as the primary control on air–sea CO2 flux variability (r2=0.93, p<0.01). In the northern part of our study region, divergence from atmospheric CO2 is enhanced by increased local wind stress curl, enhancing upwelling and entrainment of naturally CO2-rich subsurface waters, leading to decade-long intervals of strong winter outgassing. During recent Pacific marine heat waves from 2013 on, we find enhanced atmospheric CO2 uptake (by as much as 45 %) due to limited wintertime entrainment. Our product estimates long-term surface ocean pCO2 increase at a rate below the atmospheric trend (1.4 ± 0.1 µatm yr−1) with the slowest increase in the center of the subpolar gyre where there is strong interaction with subsurface waters. This mismatch suggests the northeast Pacific Ocean sink for atmospheric CO2 may be increasing.
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Witkowski, Caitlyn R., Johan W. H. Weijers, Brian Blais, Stefan Schouten, and Jaap S. Sinninghe Damsté. "Molecular fossils from phytoplankton reveal secularPco2trend over the Phanerozoic." Science Advances 4, no. 11 (November 2018): eaat4556. http://dx.doi.org/10.1126/sciadv.aat4556.
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Past changes in the atmospheric concentration of carbon dioxide (Pco2) have had a major impact on earth system dynamics; yet, reconstructing secular trends of pastPco2remains a prevalent challenge in paleoclimate studies. The current long-termPco2reconstructions rely largely on the compilation of many different proxies, often with discrepancies among proxies, particularly for periods older than 100 million years (Ma). Here, we reconstructed PhanerozoicPco2from a single proxy: the stable carbon isotopic fractionation associated with photosynthesis (Ɛp) that increases asPco2increases. This concept has been widely applied to alkenones, but here, we expand this concept both spatially and temporally by applying it to all marine phytoplankton via a diagenetic product of chlorophyll, phytane. We obtained data from 306 marine sediments and oils, which showed that Ɛpranges from 11 to 24‰, agreeing with the observed range of maximum fractionation of Rubisco (i.e., 25 to 28‰). The observed secularPco2trend derived from phytane-based Ɛpmirrors the available compilations ofPco2over the past 420 Ma, except for two periods in which our higher estimates agree with the warm climate during those time periods. Our record currently provides the longest secular trend inPco2based on a single marine proxy, covering the past 500 Ma of Earth history.
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Donald, Hannah K., Gavin L. Foster, Nico Fröhberg, George E. A. Swann, Alex J. Poulton, C. Mark Moore, and Matthew P. Humphreys. "The pH dependency of the boron isotopic composition of diatom opal (<i>Thalassiosira weissflogii</i>)." Biogeosciences 17, no. 10 (May 27, 2020): 2825–37. http://dx.doi.org/10.5194/bg-17-2825-2020.
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Abstract. The high-latitude oceans are key areas of carbon and heat exchange between the atmosphere and the ocean. As such, they are a focus of both modern oceanographic and palaeoclimate research. However, most palaeoclimate proxies that could provide a long-term perspective are based on calcareous organisms, such as foraminifera, that are scarce or entirely absent in deep-sea sediments south of 50∘ S in the Southern Ocean and north of 40∘ N in the North Pacific. As a result, proxies need to be developed for the opal-based organisms (e.g. diatoms) found at these high latitudes, which dominate the biogenic sediments recovered from these regions. Here we present a method for the analysis of the boron (B) content and isotopic composition (δ11B) of diatom opal. We apply it for the first time to evaluate the relationship between seawater pH, δ11B and B concentration ([B]) in the frustules of the diatom Thalassiosira weissflogii, cultured across a range of carbon dioxide partial pressure (pCO2) and pH values. In agreement with existing data, we find that the [B] of the cultured diatom frustules increases with increasing pH (Mejía et al., 2013). δ11B shows a relatively well defined negative trend with increasing pH, completely distinct from any other biomineral previously measured. This relationship not only has implications for the magnitude of the isotopic fractionation that occurs during boron incorporation into opal, but also allows us to explore the potential of the boron-based proxies for palaeo-pH and palaeo-CO2 reconstruction in high-latitude marine sediments that have, up until now, eluded study due to the lack of suitable carbonate material.
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Hoareau, G., B. Bomou, D. J. J. van Hinsbergen, N. Carry, D. Marquer, Y. Donnadieu, G. Le Hir, B. Vrielynck, and A. V. Walter-Simonnet. "Did high Neo-Tethys subduction rates contribute to early Cenozoic warming?" Climate of the Past 11, no. 12 (December 18, 2015): 1751–67. http://dx.doi.org/10.5194/cp-11-1751-2015.
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Abstract. The 58–51 Ma interval was characterized by a long-term increase of global temperatures (+4 to +6 °C) up to the Early Eocene Climate Optimum (EECO, 52.9–50.7 Ma), the warmest interval of the Cenozoic. It was recently suggested that sustained high atmospheric pCO2, controlling warm early Cenozoic climate, may have been released during Neo-Tethys closure through the subduction of large amounts of pelagic carbonates and their recycling as CO2 at arc volcanoes. To analyze the impact of Neo-Tethys closure on early Cenozoic warming, we have modeled the volume of subducted sediments and the amount of CO2 emitted along the northern Tethys margin. The impact of calculated CO2 fluxes on global temperature during the early Cenozoic have then been tested using a climate carbon cycle model (GEOCLIM). We show that CO2 production may have reached up to 1.55 × 1018 mol Ma−1 specifically during the EECO, ~ 4 to 37 % higher that the modern global volcanic CO2 output, owing to a dramatic India-Asia plate convergence increase. The subduction of thick Greater Indian continental margin carbonate sediments at ~ 55–50 Ma may also have led to additional CO2 production of 3.35 × 1018 mol Ma−1 during the EECO, making a total of 85 % of the global volcanic CO2 outgassed. However, climate modeling demonstrates that timing of maximum CO2 release only partially fits with the EECO, and that corresponding maximum pCO2 values (750 ppm) and surface warming (+2 °C) do not reach values inferred from geochemical proxies, a result consistent with conclusions arising from modeling based on other published CO2 fluxes. These results demonstrate that CO2 derived from decarbonation of Neo-Tethyan lithosphere may have possibly contributed to, but certainly cannot account alone for early Cenozoic warming. Other commonly cited sources of excess CO2 such as enhanced igneous province volcanism also appear to be up to 1 order of magnitude below fluxes required by the model to fit with proxy data of pCO2 and temperature at that time. An alternate explanation may be that CO2 consumption, a key parameter of the long-term atmospheric pCO2 balance, may have been lower than suggested by modeling. These results call for a better calibration of early Cenozoic weathering rates.
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Payne, Rebecca C., Don Brownlee, and James F. Kasting. "Oxidized micrometeorites suggest either high pCO2 or low pN2 during the Neoarchean." Proceedings of the National Academy of Sciences 117, no. 3 (January 6, 2020): 1360–66. http://dx.doi.org/10.1073/pnas.1910698117.
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Tomkins et al. [A. G. Tomkins et al., Nature 533, 235–238 (2016)] suggested that iron oxides contained in 2.7-Ga iron micrometeorites can be used to determine the concentration of O2 in the Archean upper atmosphere. Specifically, they argued that the presence of magnetite in these objects implies that O2 must have been near present-day levels (∼21%) within the altitude range where the micrometeorites were melted during entry. Here, we reevaluate their data using a 1D photochemical model. We find that atomic oxygen, O, is the most abundant strong oxidant in the upper atmosphere, rather than O2. But data from shock tube experiments suggest that CO2 itself may also serve as the oxidant, in which case micrometeorite oxidation really constrains the CO2/N2 ratio, not the total oxidant abundance. For an atmosphere containing 0.8 bar of N2, like today, the lower limit on the CO2 mixing ratio is ∼0.23. This would produce a mean surface temperature of ∼300 K at 2.7 Ga, which may be too high, given evidence for glaciation at roughly this time. If pN2 was half the present value, and warming by other greenhouse gases like methane was not a major factor, the mean surface temperature would drop to ∼291 K, consistent with glaciation. This suggests that surface pressure in the Neoarchean may need to have been lower—closer to 0.6 bar—for CO2 to have oxidized the micrometeorites. Ultimately, iron micrometeorites may be an indicator for ancient atmospheric CO2 and surface pressure; and could help resolve discrepancies between climate models and existing CO2 proxies such as paleosols.
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Piazza, Giulia, Valentina A. Bracchi, Antonio Langone, Agostino N. Meroni, and Daniela Basso. "Growth rate rather than temperature affects the B∕Ca ratio in the calcareous red alga <i>Lithothamnion corallioides</i>." Biogeosciences 19, no. 4 (February 17, 2022): 1047–65. http://dx.doi.org/10.5194/bg-19-1047-2022.
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Abstract. The B/Ca ratio in calcareous marine species is informative of past seawater CO32- concentrations, but scarce data exist on B/Ca in coralline algae. Recent studies suggest influences of temperature and growth rates on B/Ca, the effect of which could be critical for the reconstructions of surface ocean pH and atmospheric pCO2. In this paper, we present the first laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of Mg, Sr, Li, and B in the coralline alga Lithothamnion corallioides collected from different geographic settings and depths across the Mediterranean Sea and in the Atlantic Ocean. We produced the first data on putative temperature proxies (Mg/Ca, Li/Ca, Sr/Ca, Mg/Li) and B/Ca in a coralline algal species grown in different basins from across the photic zone (12, 40, 45, and 66 m depth). We tested the B/Ca correlation with temperature proxies and growth rates in order to evaluate their possible effect on B incorporation. Our results suggested a growth rate influence on B/Ca, which was evident in the sample with the lowest growth rate of 0.10 mm yr−1 (Pontian Isl., Italy; 66 m depth) and in Elba (Italy; 45 m depth), where the algal growth rate was the highest (0.14 mm yr−1). At these two sites, the measured B/Ca was the lowest at 462.8 ± 49.2 µmol mol−1 and the highest at 757.7 ± 75.5 µmol mol−1, respectively. A positive correlation between B/Ca and temperature proxies was found only in the shallowest sample from Morlaix (Atlantic coast of France; 12 m depth), where the amplitude of temperature variation (ΔT) was the highest (8.9 ∘C). Still, fluctuations in B/Ca did not mirror yearly seasonal temperature oscillations as for Mg/Ca, Li/Ca, and Sr/Ca. We concluded that growth rates, triggered by the different ΔT and light availability across depth, affect the B incorporation in L. corallioides.
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Hernandez Nava, Andres, Benjamin A. Black, Sally A. Gibson, Robert J. Bodnar, Paul R. Renne, and Loÿc Vanderkluysen. "Reconciling early Deccan Traps CO2 outgassing and pre-KPB global climate." Proceedings of the National Academy of Sciences 118, no. 14 (March 29, 2021): e2007797118. http://dx.doi.org/10.1073/pnas.2007797118.
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A 2 to 4 °C warming episode, known as the Latest Maastrichtian warming event (LMWE), preceded the Cretaceous–Paleogene boundary (KPB) mass extinction at 66.05 ± 0.08 Ma and has been linked with the onset of voluminous Deccan Traps volcanism. Here, we use direct measurements of melt-inclusion CO2 concentrations and trace-element proxies for CO2 to test the hypothesis that early Deccan magmatism triggered this warming interval. We report CO2 concentrations from NanoSIMS and Raman spectroscopic analyses of melt-inclusion glass and vapor bubbles hosted in magnesian olivines from pre-KPB Deccan primitive basalts. Reconstructed melt-inclusion CO2 concentrations range up to 0.23 to 1.2 wt% CO2 for lavas from the Saurashtra Peninsula and the Thakurvadi Formation in the Western Ghats region. Trace-element proxies for CO2 concentration (Ba and Nb) yield estimates of initial melt concentrations of 0.4 to 1.3 wt% CO2 prior to degassing. Our data imply carbon saturation and degassing of Deccan magmas initiated at high pressures near the Moho or in the lower crust. Furthermore, we find that the earliest Deccan magmas were more CO2 rich, which we hypothesize facilitated more efficient flushing and outgassing from intrusive magmas. Based on carbon cycle modeling and estimates of preserved lava volumes for pre-KPB lavas, we find that volcanic CO2 outgassing alone remains insufficient to account for the magnitude of the observed latest Maastrichtian warming. However, accounting for intrusive outgassing can reconcile early carbon-rich Deccan Traps outgassing with observed changes in climate and atmospheric pCO2.
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Köhler, P., and R. Bintanja. "The carbon cycle during the Mid Pleistocene Transition: the Southern Ocean Decoupling Hypothesis." Climate of the Past 4, no. 4 (December 2, 2008): 311–32. http://dx.doi.org/10.5194/cp-4-311-2008.
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Abstract. Various hypotheses were proposed within recent years for the interpretation of the Mid Pleistocene Transition (MPT), which occurred during past 2 000 000 years (2 Myr). We here add to already existing theories on the MPT some data and model-based aspects focusing on the dynamics of the carbon cycle. We find that the average glacial/interglacial (G/IG) amplitudes in benthic δ13C derived from sediment cores in the deep Pacific ocean increased across the MPT by ~40%, while similar amplitudes in the global benthic δ18C stack LR04 increased by a factor of two over the same time interval. The global carbon cycle box model BICYCLE is used for the interpretation of these observed changes in the carbon cycle. Our simulation approach is based on regression analyses of various paleo-climatic proxies with the LR04 benthic δ18C stack over the last 740 kyr, which are then used to extrapolate changing climatic boundary conditions over the whole 2 Myr time window. The observed dynamics in benthic δ13C cannot be explained if similar relations between LR04 and the individual climate variables are assumed prior and after the MPT. According to our analysis a model-based reconstruction of G/IG amplitudes in deep Pacific δ13C before the MPT is possible if we assume a different response to the applied forcings in the Southern Ocean prior and after the MPT. This behaviour is what we call the "Southern Ocean Decoupling Hypothesis". This decoupling might potentially be caused by a different cryosphere/ocean interaction and thus changes in the deep and bottom water formation rates in the Southern Ocean before the MPT, however an understanding from first principles remains elusive. Our hypothesis is also proposing dynamics in atmospheric pCO2 over the past 2 Myr. Simulated pCO2 is varying between 180 and 260 μatm before the MPT. The consequence of our Southern Ocean Decoupling Hypothesis is that the slope in the relationship between Southern Ocean SST and atmospheric pCO2 is different before and after the MPT, something for which first indications already exist in the 800 kyr CO2 record from the EPICA Dome C ice core. We finally discuss how our findings are related to other hypotheses on the MPT.
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Hoareau, G., B. Bomou, D. J. J. van Hinsbergen, N. Carry, D. Marquer, Y. Donnadieu, G. Le Hir, B. Vrielynck, and A. V. Walter-Simonnet. "Did high Neo-Tethys subduction rates contribute to early Cenozoic warming?" Climate of the Past Discussions 11, no. 4 (July 8, 2015): 2847–88. http://dx.doi.org/10.5194/cpd-11-2847-2015.
Full textAbstract:
Abstract. The 58–51 Ma interval was characterized by a long-term increase of global temperatures (+4 to +6 °C) up to the Early Eocene Climate Optimum (EECO, 52.9–50.7 Ma), the warmest interval of the Cenozoic. It was recently suggested that sustained high atmospheric pCO2, controlling warm early Cenozoic climate, may have been released during Neo-Tethys closure through the subduction of large amounts of pelagic carbonates and their recycling as CO2 at arc volcanoes ("carbonate subduction factory"). To analyze the impact of Neo-Tethys closure on early Cenozoic warming, we have modeled the volume of subducted sediments and the amount of CO2 emitted at active arc volcanoes along the northern Tethys margin. The impact of calculated CO2 fluxes on global temperature during the early Cenozoic have then been tested using a climate carbon cycle model (GEOCLIM). We first show that CO2 production may have reached up to 1.55 × 1018 mol Ma−1 specifically during the EECO, ~ 4 to 37 % higher that the modern global volcanic CO2 output, owing to a dramatic India–Asia plate convergence increase. In addition to the background CO2 degassing, the subduction of thick Greater Indian continental margin carbonate sediments at ~ 55–50 Ma may also have led to additional CO2 production of 3.35 × 1018 mol Ma−1 during the EECO, making a total of 85 % of the global volcanic CO2 outgassed. However, climate modelling demonstrates that timing of maximum CO2 release only partially fit with the EECO, and that corresponding maximum pCO2 values (750 ppm) and surface warming (+2 °C) do not reach values inferred from geochemical proxies, a result consistent with conclusions arise from modelling based on other published CO2 fluxes. These results demonstrate that CO2 derived from decarbonation of Neo-Tethyan lithosphere may have possibly contributed to, but certainly cannot account alone for early Cenozoic warming, including the EECO. Other commonly cited sources of excess CO2 such as enhanced igneous province volcanism also appear to be up to one order of magnitude below fluxes required by the model to fit with proxy data of pCO2 and temperature at that time.
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Köhler, P., and R. Bintanja. "The carbon cycle during the Mid Pleistocene Transition: the Southern Ocean Decoupling Hypothesis." Climate of the Past Discussions 4, no. 4 (July 9, 2008): 809–58. http://dx.doi.org/10.5194/cpd-4-809-2008.
Full textAbstract:
Abstract. Various hypotheses were proposed within recent years for the interpretation of the Mid Pleistocene Transition (MPT), which occurred during past 2 000 000 years (2 Myr). We here add to already existing theories on the MPT some data and model-based aspects focusing on the dynamics of the carbon cycle. We find that the average glacial/interglacial (G/IG) amplitudes in benthic δ13C derived from sediment cores in the deep Pacific ocean increased across the MPT by ~40%, while similar amplitudes in the global benthic δ18O stack LR04 increased by a factor of two over the same time interval. The global carbon cycle box model BICYCLE is used for the interpretation of these observed changes in the carbon cycle. Our simulation approach is based on regression analyses of various paleo-climatic proxies with the LR04 benthic δ18O stack over the last 740 kyr, which are then used to extrapolate changing climatic boundary conditions over the whole 2 Myr time window. The observed dynamics in benthic δ13C cannot be explained if similar relations between LR04 and the individual climate variables are assumed prior and after the MPT. According to our analysis a model-based reconstruction of G/IG amplitudes in deep Pacific δ13C before the MPT is possible if we assume a different response to the applied forcings in the Southern Ocean prior and after the MPT. This behaviour is what we call the "Southern Ocean Decoupling Hypothesis". This decoupling might potentially be caused by a different cryosphere/ocean interaction and thus changes in the deep and bottom water formation rates in the Southern Ocean before the MPT, however an understanding from first principles remains elusive. Our hypothesis is also proposing dynamics in atmospheric pCO2 over the past 2 Myr. Simulated pCO2 is varying between 180 and 260 μatm before the MPT. The consequence of our Southern Ocean Decoupling Hypothesis is that the slope in the relationship between Southern Ocean SST and atmospheric pCO2 is different before and after the MPT, something for which first indications already exist in the 800 kyr CO2 record from the EPICA Dome C ice core. We finally discuss how our findings are related to other hypotheses on the MPT.
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Brougham, Tom, and Nicolás E. Campione. "Body size correlates with discrete-character morphological proxies." Paleobiology 46, no. 3 (July 16, 2020): 304–19. http://dx.doi.org/10.1017/pab.2020.23.
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AbstractPrincipal coordinates analysis (PCoA) is a statistical ordination technique commonly applied to morphology-based cladistic matrices to study macroevolutionary patterns, morphospace occupation, and disparity. However, PCoA-based morphospaces are dissociated from the original data; therefore, whether such morphospaces accurately reflect body-plan disparity or extrinsic factors, such as body size, remains uncertain. We collated nine character–taxon matrices of dinosaurs together with body-mass estimates for all taxa and tested for relationships between body size and both the principal axis of variation (i.e., PCo1) and the entire set of PCo scores. The possible effects of body size on macroevolutionary hypotheses derived from ordinated matrices were tested by reevaluating evidence for the accelerated accumulation of avian-type traits indicated by a strong directional shift in PCo1 scores in hypothetical ancestors of modern birds. Body mass significantly accounted for, on average, approximately 50% and 16% of the phylogenetically corrected variance in PCo1 and all PCo scores, respectively. Along the avian stem lineage, approximately 30% of the morphological variation is attributed to the reconstructed body masses of each ancestor. When the effects of body size are adjusted, the period of accelerated trait accumulation is replaced by a more gradual, additive process. Our results indicate that even at low proportions of variance, body size can noticeably affect macroevolutionary hypotheses generated from ordinated morphospaces. Future studies should thoroughly explore the nature of their character data in association with PCoA-based morphospaces and use a residual/covariate approach to account for potential correlations with body size.
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Menezes, Maurícius Nascimento, Patrick Führ Dal' Bó, Jon J. Smith, Amanda Goulart Rodrigues, and Álvaro Rodríguez-Berriguete. "Maastrichtian atmospheric pCO2 and climatic reconstruction from carbonate paleosols of the Marília Formation (southeastern Brazil)." Journal of Sedimentary Research 92, no. 9 (September 7, 2022): 775–96. http://dx.doi.org/10.2110/jsr.2021.060.
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Abstract Paleosols are the product of ancient physical, chemical, and biological processes on the Earth's surface and, as such, may record information that can be used to reconstruct the paleoatmospheric and paleoenvironmental conditions under which they formed. In Brazilian continental sedimentary successions, few studies using ancient soils have focused on the relationship between paleopedogenesis and paleoclimate. The Marilia Formation is a 160-m-thick section of the Bauru Basin in which ∼ 66% of the deposits show some evidence of pedogenic modification as paleosols. In this paper, paleosol profiles in the Marilia Formation containing thick calcrete intervals are described and attributed to three pedotypes: Avencas, Monte Alto, and Garça. Macro and microscopic pedogenic features of each pedotype are described in detail. Moreover, the analysis of clay mineralogy, whole-rock geochemistry, and stable-isotope composition are used to define pedogenic processes, paleoclimate proxies, and atmospheric pCO2 estimates. The Avencas pedotype is composed of six polygenetic profiles with different phases of carbonate precipitation, clay illuviation, and biogenic actions. The Monte Alto pedotype is moderately developed and composed of calcic horizons formed mainly by rhizoliths, with higher degrees of calcification and oxidation compared to Avencas profiles. The Garça pedotype is well developed with five polygenetic profiles presenting high carbonate content and low accumulation of clay minerals (CIA-K) and leaching. Estimates of paleoprecipitation and paleotemperature from the studied paleosols using climofunctions of molar ratio of base to alumina, depth of carbonate accumulation, salinization, oxygen composition, and paleosol weathering index proxy (PWI) show values ranging from 242 to 718 mm/yr and 11° to 14°, respectively. Climofunction values suggest a paleoclimate of semiarid to subhumid during deposition of the Marília Formation. The climate data also suggests that during the Maastrichtian, the Bauru Basin was geographically within the Southern Hot Arid Belt zone, though showing strong influence of the lower latitudinal Equatorial Humid belt. Furthermore, atmospheric pCO2 values calculated from pedogenic carbonates may correlate with a cooling interval during the latest Maastrichtian (68.5–66.25 My).
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Hook, B. A., J. Halfar, Z. Gedalof, J. Bollmann, and D. J. Schulze. "Stable isotope paleoclimatology of the earliest Eocene using kimberlite-hosted mummified wood from the Canadian Subarctic." Biogeosciences 12, no. 20 (October 16, 2015): 5899–914. http://dx.doi.org/10.5194/bg-12-5899-2015.
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Abstract. The recent discovery of well-preserved mummified wood buried within a subarctic kimberlite diamond mine prompted a paleoclimatic study of the early Eocene "hothouse" (ca. 53.3 Ma). At the time of kimberlite eruption, the Subarctic was warm and humid producing a temperate rainforest biome well north of the Arctic Circle. Previous studies have estimated that mean annual temperatures in this region were 4–20 °C in the early Eocene, using a variety of proxies including leaf margin analysis and stable isotopes (δ13C and δ18O) of fossil cellulose. Here, we examine stable isotopes of tree-ring cellulose at subannual- to annual-scale resolution, using the oldest viable cellulose found to date. We use mechanistic models and transfer functions to estimate earliest Eocene temperatures using mummified cellulose, which was well preserved in the kimberlite. Multiple samples of Piceoxylon wood within the kimberlite were crossdated by tree-ring width. Multiple proxies are used in combination to tease apart likely environmental factors influencing the tree physiology and growth in the unique extinct ecosystem of the Polar rainforest. Calculations of interannual variation in temperature over a multidecadal time-slice in the early Eocene are presented, with a mean annual temperature (MAT) estimate of 11.4 °C (1 σ = 1.8 °C) based on δ18O, which is 16 °C warmer than the current MAT of the area (−4.6 °C). Early Eocene atmospheric δ13C (δ13Catm) estimates were −5.5 (±0.7) ‰. Isotopic discrimination (Δ) and leaf intercellular pCO2 ratio (ci/ca) were similar to modern values (Δ = 18.7 ± 0.8 ‰; ci/ca = 0.63 ± 0.03 %), but intrinsic water use efficiency (Early Eocene iWUE = 211 ± 20 μmol mol−1) was over twice the level found in modern high-latitude trees. Dual-isotope spectral analysis suggests that multidecadal climate cycles somewhat similar to the modern Pacific Decadal Oscillation likely drove temperature and cloudiness trends on 20–30-year timescales, influencing photosynthetic productivity and tree growth patterns.
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Winnick, M. J., J. M. Welker, and C. P. Chamberlain. "Stable isotopic evidence of El Niño-like atmospheric circulation in the Pliocene western United States." Climate of the Past 9, no. 2 (April 8, 2013): 903–12. http://dx.doi.org/10.5194/cp-9-903-2013.
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Abstract. Understanding how the hydrologic cycle has responded to warmer global temperatures in the past is especially important today as concentrations of CO2 in the atmosphere continue to increase due to human activities. The Pliocene offers an ideal window into a climate system that has equilibrated with current atmospheric pCO2. During the Pliocene the western United States was wetter than modern, an observation at odds with our current understanding of future warming scenarios, which involve the expansion and poleward migration of the subtropical dry zone. Here we compare Pliocene oxygen isotope profiles of pedogenic carbonates across the western US to modern isotopic anomalies in precipitation between phases of the El Niño–Southern Oscillation (ENSO). We find that when accounting for seasonality of carbonate formation, isotopic changes through the late Pliocene match modern precipitation isotopic anomalies in El Niño years. Furthermore, isotopic shifts through the late Pliocene mirror changes through the early Pleistocene, which likely represents the southward migration of the westerly storm track caused by growth of the Laurentide ice sheet. We propose that the westerly storm track migrated northward through the late Pliocene with the development of the modern cold tongue in the east equatorial Pacific, then returned southward with widespread glaciation in the Northern Hemisphere – a scenario supported by terrestrial climate proxies across the US. Together these data support the proposed existence of background El Niño-like conditions in western North America during the warm Pliocene. If the earth behaves similarly with future warming, this observation has important implications with regard to the amount and distribution of precipitation in western North America.
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Winnick, M. J., J. M. Welker, and C. P. Chamberlain. "Stable isotopic evidence of El Niño-like atmospheric circulation in the Pliocene Western United States." Climate of the Past Discussions 8, no. 5 (October 16, 2012): 5083–108. http://dx.doi.org/10.5194/cpd-8-5083-2012.
Full textAbstract:
Abstract. Understanding how the hydrologic cycle has responded to warmer global temperatures in the past is especially important today as concentrations of CO2 in the atmosphere continue to increase due to human activities. The Pliocene offers an ideal window into a climate system that has equilibrated with current atmospheric pCO2. During the Pliocene the Western United States was wetter than modern, an observation at odds with our current understanding of future warming scenarios, which involve the expansion and poleward migration of the subtropical dry zone. Here we compare Pliocene oxygen isotope profiles of pedogenic carbonates across the Western US to modern isotopic anomalies in precipitation between phases of the El Niño Southern Oscillation (ENSO). We find that when accounting for seasonality of carbonate formation, isotopic changes through the late Pliocene match modern precipitation isotopic anomalies in El Niño years. Furthermore, isotopic shifts through the late Pliocene mirror changes through the early Pleistocene, which likely represents the southward migration of the westerly storm track caused by growth of the Laurentide Ice Sheet. We propose that the westerly storm track migrated northward through the late Pliocene with the development of the modern Cold Tongue in the East Equatorial Pacific, then returned southward with widespread glaciation in the Northern Hemisphere – a scenario supported by terrestrial climate proxies across the US. Together these data support the proposed existence of background El Niño-like conditions in Western North America during the warm Pliocene. If the Earth behaves similarly with future warming, this observation has important implications with regard to the amount and distribution of precipitation in Western North America.
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Morée, Anne L., Jörg Schwinger, Ulysses S. Ninnemann, Aurich Jeltsch-Thömmes, Ingo Bethke, and Christoph Heinze. "Evaluating the biological pump efficiency of the Last Glacial Maximum ocean using <i>δ</i><sup>13</sup>C." Climate of the Past 17, no. 2 (April 6, 2021): 753–74. http://dx.doi.org/10.5194/cp-17-753-2021.
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Abstract. Although both physical and biological marine changes are required to explain the 100 ppm lower atmospheric pCO2 of the Last Glacial Maximum (LGM, ∼21 ka) as compared to preindustrial (PI) times, their exact contributions are debated. Proxies of past marine carbon cycling (such as δ13C) document these changes and thus provide constraints for quantifying the drivers of long-term carbon cycle variability. This modeling study discusses the physical and biological changes in the ocean needed to simulate an LGM ocean in satisfactory agreement with proxy data, here focusing especially on δ13C. We prepared a PI and LGM equilibrium simulation using the ocean model NorESM-OC with full biogeochemistry (including the carbon isotopes δ13C and radiocarbon) and dynamic sea ice. The modeled LGM–PI differences are evaluated against a wide range of physical and biogeochemical proxy data and show agreement for key aspects of the physical ocean state within the data uncertainties. However, the lack of a simulated increase of regenerated nutrients for the LGM indicates that additional biogeochemical changes are required to simulate an LGM ocean in agreement with proxy data. In order to examine these changes, we explore the potential effects of different global mean biological pump efficiencies on the simulated marine biogeochemical tracer distributions. Through estimating which biological pump efficiency reduces LGM model–proxy biases the most, we estimate that the global mean biological pump efficiency increased from 38 % (PI) to up to 75 % (LGM). The drivers of such an increase in the biological pump efficiency may be both biological and related to circulation changes that are incompletely captured by our model – such as stronger isolation of Southern Source Water. Finally, even after considering a 75 % biological pump efficiency in the LGM ocean, a remaining model–proxy error in δ13C exists that is 0.07 ‰ larger than the 0.19 ‰ data uncertainty. This error indicates that additional changes in ocean dynamics are needed to simulate an LGM ocean in agreement with proxy data.
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Linzmeier, Benjamin J., Andrew D. Jacobson, Bradley B. Sageman, Matthew T. Hurtgen, Meagan E. Ankney, Andrew L. Masterson, and Neil H. Landman. "Isotope systematics of subfossil, historical, and modern Nautilus macromphalus from New Caledonia." PLOS ONE 17, no. 12 (December 28, 2022): e0277666. http://dx.doi.org/10.1371/journal.pone.0277666.
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Cephalopod carbonate geochemistry underpins studies ranging from Phanerozoic, global-scale change to outcrop-scale paleoecological reconstructions. Interpreting these data hinges on assumed similarity to model organisms, such as Nautilus, and generalization from other molluscan biomineralization processes. Aquarium rearing and capture of wild Nautilus suggest shell carbonate precipitates quickly (35 μm/day) in oxygen isotope equilibrium with seawater. Other components of Nautilus shell chemistry are less well-studied but have potential to serve as proxies for paleobiology and paleoceanography. To calibrate the geochemical response of cephalopod δ15Norg, δ13Corg, δ13Ccarb, δ18Ocarb, and δ44/40Cacarb to modern anthropogenic environmental change, we analyzed modern, historical, and subfossil Nautilus macromphalus from New Caledonia. Samples span initial human habitation, colonialization, and industrial pCO2 increase. This sampling strategy is advantageous because it avoids the shock response that can affect geochemical change in aquarium experiments. Given the range of living depths and more complex ecology of Nautilus, however, some anthropogenic signals, such as ocean acidification, may not have propagated to their living depths. Our data suggest some environmental changes are more easily preserved than others given variability in cephalopod average living depth. Calculation of the percent respired carbon incorporated into the shell using δ13Corg, δ13Ccarb, and Suess-effect corrected δ13CDIC suggests an increase in the last 130 years that may have been caused by increasing carbon dioxide concentration or decreasing oxygen concentration at the depths these individuals inhabited. This pattern is consistent with increasing atmospheric CO2 and/or eutrophication offshore of New Caledonia. We find that δ44/40Ca remains stable across the last 130 years. The subfossil shell from a cenote may exhibit early δ44/40Ca diagenesis. Questions remain about the proportion of dietary vs ambient seawater calcium incorporation into the Nautilus shell. Values of δ15N do not indicate trophic level change in the last 130 years, and the subfossil shell may show diagenetic alteration of δ15N toward lower values. Future work using historical collections of Sepia and Spirula may provide additional calibration of fossil cephalopod geochemistry.
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Rush, William, Jean Self-Trail, Yang Zhang, Appy Sluijs, Henk Brinkhuis, James Zachos, James G. Ogg, and Marci Robinson. "Assessing environmental change associated with early Eocene hyperthermals in the Atlantic Coastal Plain, USA." Climate of the Past 19, no. 8 (August 17, 2023): 1677–98. http://dx.doi.org/10.5194/cp-19-1677-2023.
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Abstract. Eocene transient global warming events (hyperthermals) can provide insight into a future warmer world. While much research has focused on the Paleocene–Eocene Thermal Maximum (PETM), hyperthermals of a smaller magnitude can be used to characterize climatic responses over different magnitudes of forcing. This study identifies two events, namely the Eocene Thermal Maximum 2 (ETM2 and H2), in shallow marine sediments of the Eocene-aged Salisbury Embayment of Maryland, based on magnetostratigraphy, calcareous nannofossil, and dinocyst biostratigraphy, as well as the recognition of negative stable carbon isotope excursions (CIEs) in biogenic calcite. We assess local environmental change in the Salisbury Embayment, utilizing clay mineralogy, marine palynology, δ18O of biogenic calcite, and biomarker paleothermometry (TEX86). Paleotemperature proxies show broad agreement between surface water and bottom water temperature changes. However, the timing of the warming does not correspond to the CIE of the ETM2 as expected from other records, and the highest values are observed during H2, suggesting factors in addition to pCO2 forcing have influenced temperature changes in the region. The ETM2 interval exhibits a shift in clay mineralogy from smectite-dominated facies to illite-rich facies, suggesting hydroclimatic changes but with a rather dampened weathering response relative to that of the PETM in the same region. Organic walled dinoflagellate cyst assemblages show large fluctuations throughout the studied section, none of which seem systematically related to CIE warming. These observations are contrary to the typical tight correspondence between climate change and assemblages across the PETM, regionally and globally, and ETM2 in the Arctic Ocean. The data do indicate very warm and (seasonally) stratified conditions, likely salinity-driven, across H2. The absence of evidence for strong perturbations in local hydrology and nutrient supply during ETM2 and H2, compared to the PETM, is consistent with the less extreme forcing and the warmer pre-event baseline, as well as the non-linear response in hydroclimates to greenhouse forcing.
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Manche, Cameron J., and Stephen E. Kaczmarek. "A global study of dolomite stoichiometry and cation ordering through the Phanerozoic." Journal of Sedimentary Research 91, no. 5 (May 31, 2021): 520–46. http://dx.doi.org/10.2110/jsr.2020.204.
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ABSTRACT Various geochemical proxies are used to constrain the diagenetic origin and evolution of ancient dolomites. Dolomite stoichiometry (mole % MgCO3) and cation ordering, two mineralogical attributes that define dolomite, have also been shown to demonstrate utility in this regard. Observations from laboratory experiments and field studies suggest that these attributes broadly reflect the fluid chemistry and temperature of the dolomitizing environment. The degree to which these parameters reflect global conditions during dolomitization (e.g., seawater chemistry, eustasy, atmospheric pCO2) and long-term geological processes is poorly understood, however. Here, a large dataset consisting of mineralogical data from over 1,690 Phanerozoic dolomites from various geographic locations, stratigraphic ages, platform types, and depositional environments are queried to investigate the broader geological controls on dolomite stoichiometry and cation ordering in dolomites formed by early, near-surface dolomitization. A suite of statistical analyses performed on the global dataset indicate: 1) despite wide ranges at the eon, period, and epoch level, dolomite stoichiometry and cation ordering broadly increase with geologic age; 2) significant variations in dolomite stoichiometry and cation ordering throughout the Phanerozoic do not correlate with global parameters, such as seawater chemistry, eustasy, orogenic events, and ocean crust production; 3) dolomites associated with restricted depositional settings, such as restricted lagoons, and the intertidal and supratidal zones, are more stoichiometric than dolomites associated with open marine settings, such as the deep-subtidal and shallow-subtidal zones; and 4) dolomites from shallow ramps and epeiric carbonate platforms are generally more stoichiometric than dolomites from open shelves and isolated carbonate platforms. These observations permit a number of inferences to be drawn. First, the principal signal observed in the data is that local environmental conditions associated with platform type and depositional setting are the strongest control on dolomite mineralogy. The observation that more stoichiometric dolomites correlate with shallow and restricted depositional environments is consistent with laboratory experiments that show environmental factors, such as higher Mg:Ca, temperature, and salinity of the dolomitizing fluids yield more stoichiometric dolomite. Second, a weaker secondary signal is also observed such that dolomite stoichiometry and cation ordering both increase with geologic age, suggesting that progressive recrystallization driven by mineralogical stabilization during burial is also occurring. Collectively, these data suggest that spatial and temporal variations in stoichiometry and cation ordering reflect the interplay between local dolomitizing conditions near the surface and long-term mineralogical stabilization during burial.
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Copes, Lynn E., and Gary T. Schwartz. "The scale of it all: postcanine tooth size, the taxon-level effect, and the universality of Gould's scaling law." Paleobiology 36, no. 2 (2010): 188–203. http://dx.doi.org/10.1666/08089.1.
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In a seminal paper in 1975, Gould proposed that postcanine occlusal area (PCOA) should scale metabolically (0.75) with body mass across mammals. By regressing PCOA against skull length in a small sample of large-bodied herbivorous mammals, Gould provided some marginal support for this hypothesis, which he then extrapolated as a universal scaling law for Mammalia. Since then, many studies have sought to confirm this scaling relationship within a single order and have found equivocal support for Gould's assertion. In part, this may be related to the use of proxies for both PCOA and body mass, small sample sizes, or the influence of a “taxon-level effect,” rendering Gould's scaling “universal” problematic.Our goal was to test the universality of Gould's prediction and the impact of the taxon-level effect on regressions of tooth size on body mass in a large extant mammalian sample (683 species spanning 14 orders). We tested for the presence of two types of taxon-level effect that may influence the acceptance or rejection of hypothesized scaling coefficients. The hypotheses of both metabolic and isometric scaling can be rejected in Mammalia, but not in all sub-groups therein. The level of data aggregation also influences the interpretation of the scaling relationship. Because the scaling relationship of tooth size to body mass is highly dependent on both the taxonomic level of analysis and the mathematical methods used to organize the data, paleontologists attempting to retrodict body mass from fossilized dental remains must be aware of the effect that sample composition may have on their results.
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Witkowski, Caitlyn R., Marcel T. J. van der Meer, Nadine T. Smit, Jaap S. Sinninghe Damsté, and Stefan Schouten. "Testing algal-based pCO2 proxies at a modern CO2 seep (Vulcano, Italy)." Scientific Reports 10, no. 1 (June 29, 2020). http://dx.doi.org/10.1038/s41598-020-67483-8.
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MONTANEZ, ISABEL, University of Cal. "ABSTRACT: Evolution of Permian Atmospheric pCO2 and Western Equatorial Pangean Climate: As Recorded by Paleosol Morphologic and Geochemical Proxies." AAPG Bulletin 84 (2000). http://dx.doi.org/10.1306/8626c6db-173b-11d7-8645000102c1865d.
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You, Chen-Feng, P.-Y. Lin, Kuo-Fang Huang, Chuan-Hsiung Chung, and Zhifei Liu. "Ocean acidification in the Western Pacific: Boron isotopic composition recorded in a tropical massive coral core from Lanyu Islet SE Taiwan." Frontiers in Marine Science 9 (July 27, 2022). http://dx.doi.org/10.3389/fmars.2022.877810.
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Boron (B) and B isotopic compositions (δ11B) in biogenic carbonates are useful proxies for pH reconstruction in the ocean. However, high-resolution archives are scarce due to associated sampling and analytical difficulty. In this study, a modern long-lived massive coral skeleton (Porites lobata) from Lanyu Islet off southeast Taiwan was drilled and used for high-resolution major/trace element analyses, including trace elements B and δ11B, as well as oxygen and carbon isotopes, to investigate the associated environmental changes during 1991–1997. To avoid complicated biological influence, the top-most tissue layer was excluded in this study. The coralline records show a clear temporal trend in metal/Ca-based sea surface temperatures (SSTs) on annual and monthly timescales. In particular, the Mg/Ca-SSTs, the most sensitive temperature proxy at the site, show a significant warming trend (+0.2°C year−1) during the study period. On the other hand, subtle changes in the annual δ11B record were identified, corresponding to ~0.2 pH unit, which is comparable with other coral records in the Pacific, e.g., the South China Sea (SCS), Guam Island, Flinders, and Arlington Reef, as well as the in-situ seawater pH measurement at Hawaii station. This corresponds to an acidification rate of ~0.25 pH unit 100 year−1, similar to other coralline data, in-situ pH/pCO2 measurement, or model predictions, and emphasizes the importance of ocean acidification due to anthropogenic activities. Combined with the Mg/Ca-SST, the intra-annual data show a clear seasonal cycle with higher pH in winter, consistent with the pCO2 at the oceanic surface. These chemical and isotopic results in corals conclude that marine biogenic carbonates are informative for oceanic pH reconstruction and can provide new insights into the relationships between climate changes and environmental responses on the coast of Taiwan.
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Suárez-Ibarra, Jaime Y., Tiago M. Freire, Cristiane F. Frozza, Tainã M. L. Pinho, Sandro M. Petró, Bruna B. Dias, Thomas B. Chalk, et al. "Surface fertilisation and organic matter delivery enhanced carbonate dissolution in the western South Atlantic." Frontiers in Ecology and Evolution 11 (November 3, 2023). http://dx.doi.org/10.3389/fevo.2023.1238334.
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The last glacial inception was characterised by rapid changes in temperature, atmospheric pCO2, and changes in the water mass geometry of the major ocean basins. Although several climatic feedback mechanisms have been proposed to explain the glacial/interglacial cycles witnessed in the Quaternary, the exact mechanistic responses of these processes are still under constrained. In this study we use proxies including planktonic foraminifera compositional assemblages and oxygen stable isotopes to reconstruct past changes in sea surface productivity, stratification, and carbonate dissolution. We use core SIS-249 (2,091 mbsl, western South Atlantic 30°S 47°W), spanning 30–110 thousand years ago (ka), and currently bathed by modern Northern Component Water. We test existing hypotheses suggesting that the orbital obliquity cycle modulates the biological pump in the study area. Spectral analysis run on our synthesised productivity proxies recognises a ~43 kyr-cycle, related to the obliquity cycle. We propose that the enhanced productivity is produced by two mechanisms: i) the glacial upwelling of subsurface nutrient-rich waters and, ii) the continental (wind-driven dust and riverine outflows) fertilisation of the photic zone, with the latter process being obliquity-paced. We also suggest that not only the increased organic matter export but also a change in its bioavailability (from refractory to labile) led to calcium carbonate dissolution, as the degradation of the more soluble organic matter decreased the pH of the glacial bottom water, partially dissolving the calcium carbonate. Although our correlation analyses show a strong benthic-pelagic coupling through the relation between the enhanced biological pump and carbonate dissolution (ρ<0.05, r=0.80), we cannot reject the potential of corrosive Southern Component Water bathing the site during the glacial. Finally, we highlight that these processes are not mutually exclusive and that both can be modulated by the obliquity cycle.
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Broz, Adrian, Gregory J. Retallack, Toby M. Maxwell, and Lucas C. R. Silva. "A record of vapour pressure deficit preserved in wood and soil across biomes." Scientific Reports 11, no. 1 (January 12, 2021). http://dx.doi.org/10.1038/s41598-020-80006-9.
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AbstractThe drying power of air, or vapour pressure deficit (VPD), is an important measurement of potential plant stress and productivity. Estimates of VPD values of the past are integral for understanding the link between rising modern atmospheric carbon dioxide (pCO2) and global water balance. A geological record of VPD is needed for paleoclimate studies of past greenhouse spikes which attempt to constrain future climate, but at present there are few quantitative atmospheric moisture proxies that can be applied to fossil material. Here we show that VPD leaves a permanent record in the slope (S) of least-squares regressions between stable isotope ratios of carbon and oxygen (13C and 18O) found in cellulose and pedogenic carbonate. Using previously published data collected across four continents we show that S can be used to reconstruct VPD within and across biomes. As one application, we used S to estimate VPD of 0.46 kPa ± 0.26 kPa for cellulose preserved tens of millions of years ago—in the Eocene (45 Ma) Metasequoia from Axel Heiberg Island, Canada—and 0.82 kPa ± 0.52 kPa—in the Oligocene (26 Ma) for pedogenic carbonate from Oregon, USA—both of which are consistent with existing records at those locations. Finally, we discuss mechanisms that contribute to the positive correlation observed between VPD and S, which could help reconstruct past climatic conditions and constrain future alterations of global carbon and water cycles resulting from modern climate change.
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Cho, Tenichi, Masayuki Ikeda, and Tohru Ohta. "Increased Terrigenous Supply to the Pelagic Panthalassa Superocean Across the Carnian Pluvial Episode: A Possible Link With Extensive Aridification in the Pangean Interior." Frontiers in Earth Science 10 (June 24, 2022). http://dx.doi.org/10.3389/feart.2022.897396.
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In the Late Triassic, a global environmental change called the Carnian Pluvial Episode (CPE) emerged, causing major biological turnover. The CPE has been recognized by siliciclastic input to sedimentary basins, multiple carbon isotope perturbations, and climate proxies for humidification. The CPE is considered to have been associated with increased atmospheric pCO2 from eruptions of large igneous provinces. However, the nature of this global environmental perturbation on the continents is still not well understood. Here we present a geochemical analysis of a pelagic deep-sea bedded chert sequence across the CPE in the Jurassic accretionary complex of Mino terrane, central Japan. Fluctuations in terrigenous material supply were reconstructed using Principal Component Analysis of major element compositions. The first principal component positively correlates with elements enriched in clay minerals such as Al2O3, whereas it negatively correlates with CaO, P2O5, and MnO, derived from apatite and manganese. A sudden increase in terrigenous supply was detected around the Julian/Tuvalian boundary, suggesting that CPE-related siliciclastic input also occurred in the abyssal plain environment. The terrigenous supply returned to the pre-CPE state in the Tuvalian. Since the terrigenous material supplied to the abyssal plain is thought to be derived from eolian dust blown from continental arid regions, the increasing terrigenous supply detected in the pelagic deep-sea chert succession may indicate extensive aridification. This result seems to conflict with the common view of the CPE as a humidification event. This contradiction possibly suggests that the extensive aridification occurred within the interior of the supercontinent Pangea, while hydrological circulation enhanced on the coastal region during the CPE.
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Vervoort, P., S. Kirtland Turner, F. Rochholz, and A. Ridgwell. "Earth System Model Analysis of How Astronomical Forcing Is Imprinted Onto the Marine Geological Record: The Role of the Inorganic (Carbonate) Carbon Cycle and Feedbacks." Paleoceanography and Paleoclimatology 39, no. 3 (March 2024). http://dx.doi.org/10.1029/2023pa004826.
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AbstractAstronomical cycles are strongly expressed in marine geological records, providing important insights into Earth system dynamics and an invaluable means of constructing age models. However, how various astronomical periods are filtered by the Earth system and the mechanisms by which carbon reservoirs and climate components respond, particularly in absence of dynamic ice sheets, is unclear. Using an Earth system model that includes feedbacks between climate, ocean circulation, and inorganic (carbonate) carbon cycling relevant to geological timescales, we systematically explore the impact of astronomically‐modulated insolation forcing and its expression in model variables most comparable to key paleoceanographic proxies (temperature, the δ13C of inorganic carbon, and sedimentary carbonate content). Temperature predominately responds to obliquity and is little influenced by the modeled carbon cycle feedbacks. In contrast, the cycling of nutrients and carbon in the ocean generates significant precession power in atmospheric CO2, benthic ocean δ13C, and sedimentary wt% CaCO3, while inclusion of marine sedimentary and weathering processes shifts power to the long eccentricity period. Our simulations produce reduced pCO2 and dissolved inorganic carbon δ13C at long eccentricity maxima and, contrary to early Cenozoic marine records, CaCO3 preservation in the model is enhanced during eccentricity modulated warmth. Additionally, the magnitude of δ13C variability simulated in our model underestimates marine proxy records. These model‐data discrepancies hint at the possibility that the Paleogene silicate weathering feedback was weaker than modeled here and that additional organic carbon cycle feedbacks are necessary to explain the full response of the Earth system to astronomical forcing.
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Hudson, Adam M., Julia R. Kelson, James B. Paces, Chester A. Ruleman, Katharine W. Huntington, and Andrew J. Schauer. "Clumped Isotopes Record a Glacial‐Interglacial Shift in Seasonality of Soil Carbonate Accumulation in the San Luis Valley, Southern Rocky Mountains, USA." Geochemistry, Geophysics, Geosystems 25, no. 4 (March 30, 2024). http://dx.doi.org/10.1029/2023gc011221.
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AbstractClumped isotope paleothermometry using pedogenic carbonates is a powerful tool for investigating past climate changes. However, location‐specific seasonal patterns of precipitation and soil moisture cause systematic biases in the temperatures they record, hampering comparison of data across large areas or differing climate states. To account for biases, more systematic studies of carbonate forming processes are needed. We measured modern soil temperatures within the San Luis Valley of the Rocky Mountains and compared them to paleotemperatures determined using clumped isotopes. For Holocene‐age samples, clumped isotope results indicate carbonate accumulated at a range of temperatures with site averages similar to the annual mean. Paleotemperatures for late Pleistocene‐age samples (ranging 19–72 ka in age) yielded site averages only 2°C lower, despite evidence that annual temperatures during glacial periods were 5–9°C colder than modern. We use a 1D numerical model of soil physics to support the idea that differences in hydrologic conditions in interglacial versus glacial periods promote differences in the seasonal distribution of soil carbonate accumulation. Model simulations of modern (Holocene) conditions suggest that soil drying under low soil pCO2 favors year‐round carbonate accumulation in this region but peaking during post‐monsoon soil drying. During a “glacial” simulation with lowered temperatures and added snowpack, more carbonate accumulation shifted to the summer season. These experiments show that changing hydrologic regimes could change the seasonality of carbonate accumulation, which in this study blunts the use of clumped isotopes to quantify glacial‐interglacial temperature changes. This highlights the importance of understanding seasonal biases of climate proxies for accurate paleoenvironmental reconstruction.