Academic literature on the topic 'Polypyridyl complex'

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Journal articles on the topic "Polypyridyl complex"

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Martínez-Alonso, Marta, and Gilles Gasser. "Ruthenium polypyridyl complex-containing bioconjugates." Coordination Chemistry Reviews 434 (May 2021): 213736. http://dx.doi.org/10.1016/j.ccr.2020.213736.

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Martin, Aaron, Aisling Byrne, Ciarán Dolan, Robert J. Forster, and Tia E. Keyes. "Solvent switchable dual emission from a bichromophoric ruthenium–BODIPY complex." Chemical Communications 51, no. 87 (2015): 15839–41. http://dx.doi.org/10.1039/c5cc07135f.

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Margonis, Caroline M., Marissa Ho, Benjamin D. Travis, William W. Brennessel, and William R. McNamara. "Iron polypyridyl complex adsorbed on carbon surfaces for hydrogen generation." Chemical Communications 57, no. 62 (2021): 7697–700. http://dx.doi.org/10.1039/d1cc02131a.

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Singh, Vikram, Prakash Chandra Mondal, Megha Chhatwal, Yekkoni Lakshmanan Jeyachandran, and Michael Zharnikov. "Catalytic oxidation of ascorbic acid via copper–polypyridyl complex immobilized on glass." RSC Adv. 4, no. 44 (2014): 23168–76. http://dx.doi.org/10.1039/c4ra00817k.

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He, Chixian, Shiwen Yu, Shuye Ma, et al. "A Novel Ruthenium(II) Polypyridyl Complex Bearing 1,8-Naphthyridine as a High Selectivity and Sensitivity Fluorescent Chemosensor for Cu2+ and Fe3+ Ions." Molecules 24, no. 22 (2019): 4032. http://dx.doi.org/10.3390/molecules24224032.

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A novel ruthenium(II) polypyridyl complex bearing 1,8-naphthyridine was successfully designed and synthesized. This complex was fully characterized by EI-HRMS, NMR, and elemental analyses. The recognition properties of the complex for various metal ions were investigated. The results suggested that the complex displayed high selectivity and sensitivity for Cu2+ and Fe3+ ions with good anti-interference in the CH3CN/H2O (1:1, v/v) solution. The fluorescent chemosensor showed obvious fluorescence quenching when the Cu2+ and Fe3+ ions were added. The detection limits of Cu2+ and Fe3+ were 39.9 nm
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Lee, Sze Koon, Mio Kondo, Go Nakamura, Masaya Okamura, and Shigeyuki Masaoka. "Low-overpotential CO2 reduction by a phosphine-substituted Ru(ii) polypyridyl complex." Chemical Communications 54, no. 50 (2018): 6915–18. http://dx.doi.org/10.1039/c8cc02150c.

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Pierroz, Vanessa, Riccardo Rubbiani, Christian Gentili, et al. "Dual mode of cell death upon the photo-irradiation of a RuIIpolypyridyl complex in interphase or mitosis." Chemical Science 7, no. 9 (2016): 6115–24. http://dx.doi.org/10.1039/c6sc00387g.

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Yamaguchi, Eiji, Nao Taguchi, and Akichika Itoh. "Ruthenium polypyridyl complex-catalysed aryl alkoxylation of styrenes: improving reactivity using a continuous flow photo-microreactor." Reaction Chemistry & Engineering 4, no. 6 (2019): 995–99. http://dx.doi.org/10.1039/c9re00061e.

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Li, Shuang, Gang Xu, Yuhua Zhu, Jian Zhao, and Shaohua Gou. "Bifunctional ruthenium(ii) polypyridyl complexes of curcumin as potential anticancer agents." Dalton Transactions 49, no. 27 (2020): 9454–63. http://dx.doi.org/10.1039/d0dt01040e.

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Azar, Daniel F., Hassib Audi, Stephanie Farhat, Mirvat El-Sibai, Ralph J. Abi-Habib, and Rony S. Khnayzer. "Phototoxicity of strained Ru(ii) complexes: is it the metal complex or the dissociating ligand?" Dalton Transactions 46, no. 35 (2017): 11529–32. http://dx.doi.org/10.1039/c7dt02255g.

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Dissertations / Theses on the topic "Polypyridyl complex"

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Howell, Sarah Louise, and n/a. "Excited state structures of polypyridyl complexes : a spectroscopic and DFT study." University of Otago. Department of Chemistry, 2005. http://adt.otago.ac.nz./public/adt-NZDU20070221.155843.

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This thesis reports the spectroscopic and computational studies of a number of Cu(I), Re(I) and Ru(II) complexes of polypyridyl ligands. The ligands considered in this study were 1,10-phenanthroline, 4,7-diphenyl-1,10-phenanthroline, 3,4,7,8-tetramethyl-1,10-phenanthroline, dibenzo[b,j][1,10]phenanthroline, dipyrido[2,3-a:3�,2�-c]phenazine, dipyrido[2,3-a:3�,2�-c]-6,7-dichlorophenazine and dipyrido[2,3-a:3�,2�-c]-6,7-dimethylphenazine. Density functional theory calculations were carried out on the polypyridyl ligands. Validation of the calculations was carried out by comparison of the predic
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Olaprath, Waynie Wilson. "Electrochemical and spectroscopic characterization of a polypyridyl Ru(II) complex containing a fused alloxazine /." View online, 2009. http://repository.eiu.edu/theses/docs/32211131598949.pdf.

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Sun, Yang. "STUDY OF THE MECHANISM OF ACTION FOR Ru(II) POLYPYRIDYL COMPLEXES AS POTENTIAL ANTICANCER AGENTS." UKnowledge, 2018. https://uknowledge.uky.edu/chemistry_etds/97.

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Application of chemotherapeutic agents in current cancer treatment has been limited by adverse effects as poor selectivity results in systemic toxicity; most chemotherapy approaches also experience inherited or acquired drug resistance which lead to reduced treatment outcome. Research efforts have focused on the discovery of novel chemotherapies that overcome the limitations mentioned above. Ru(II) polypyridyl complexes with anti-cancer properties have been extensively studied as traditional cytotoxic agents and photodynamic therapy agents due to their photophysical and photochemical character
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Kwok, Chi-ho, and 郭志豪. "Design and synthesis of functionalized alkynylplatinum (II) polypyridyl complexes and oligothienylenevinylene derivatives : from dye-sensitized solar cells to bilayer heterojunction photovoltaics." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2012. http://hdl.handle.net/10722/208172.

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A series of alkynylplatinum(II) polypyridine complexes with 4,4′,4′′-tricarboxy-2,2′:6′,2′′-terpyridine and 4,4′-dicarboxy-2,2′-bipyridine as TiO2 anchoring functionalities, has been successfully synthesized. Their photophysical, electrochemical and luminescence properties have been extensively studied. The excited state properties were probed using nanosecond transient absorption spectroscopy. [Pt(tctpy)(C≡C-Th-BTD-Th)][NnBu4]2 displayed a long-lived transient signal which was tentatively assigned to result from the formation of a charge-separated state, which could be alternatively de
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Fairbanks, Simon David. "A structural study into the binding of a chiral dinuclear ruthenium (II) polypyridyl complex to a B-DNA oligonucleotide." Thesis, University of Sheffield, 2018. http://etheses.whiterose.ac.uk/22410/.

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Tang, Wing-suen, and 鄧詠璇. "Design and synthesis of luminescent metal polypyridyl complexes of platinum(II), ruthenium(II) and osmium(II) for chemosensing andbiological studies." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B38767624.

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Tang, Wing-suen. "Design and synthesis of luminescent metal polypyridyl complexes of platinum(II), ruthenium(II) and osmium(II) for chemosensing and biological studies." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B38767624.

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Wright, Joseph. "Oxygen-Sensitive Luminophores: A Survey of the Literature and Efforts toward a Novel Porphyrin-Pillared Zirconium Phosphonate." ScholarWorks @ UVM, 2016. http://scholarworks.uvm.edu/graddis/653.

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Measurement and mapping of the pressure distribution across the surface of a suitably scaled model is an integral step in the design of any aircraft or automobile. For this purpose, the traditional workhorses of the aeronautic and automotive industries have been pressure taps--small orifices that contain electronic pressure transducers. Unfortunately, in addition to the limited spatial resolution achievable with such devices, their technical complexity and cost constitute serious disadvantages. For more than 35 years, researchers have pursued a fundamentally different alternative: indirect mea
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Petzold, Holm, Paul Djomgoue, Gerald Hörner, J. Matthäus Speck, Tobias Rüffer, and Dieter Schaarschmidt. "1H NMR spectroscopic elucidation in solution of the kinetics and thermodynamics of spin crossover for an exceptionally robust Fe2+ complex." Universitätsbibliothek Chemnitz, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-210226.

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A series of Fe2+ spin crossover (SCO) complexes [Fe(5/6)]2+ employing hexadentate ligands (5/6) with cis/trans-1,2-diamino cyclohexanes (4) as central building blocks were synthesised. The ligands were obtained by reductive amination of 4 with 2,2′-bipyridyl-6-carbaldehyde or 1,10-phenanthroline-2-carbaldehyde 3. The chelating effect and the rigid structure of the ligands 5/6 lead to exceptionally robust Fe2+ and Zn2+ complexes conserving their structure even in coordinating solvents like dmso at high temperatures. Their solution behavior was investigated using variable temperature (VT) 1H NMR
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Zheng, Sipeng. "The reactions of ruthenium (ii) polypyridyl complexes." Thesis, Nelson Mandela Metropolitan University, 2009. http://hdl.handle.net/10948/1089.

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Ruthenium (II) polypyridine complexes in general have been extensively studied because of their unique redox and photochemical properties. A typical example of such complexes is tris(2,2’-bipyridyl) ruthenium (II). In this study, this complex was synthesized and then characterized using electronic spectroscopy and cyclic voltammetry. It was also shown that the ruthenium concentration could be accurately determined using ICP-MS. It was found that the complex is very stable in various chemical environments. It was observed from spectrophotometric investigations that persulphate and lead dioxide
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Book chapters on the topic "Polypyridyl complex"

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Gill, Martin R., and Jim A. Thomas. "Targeting cellular DNA with Luminescent Ruthenium(II) Polypyridyl Complexes." In Ruthenium Complexes. Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527695225.ch11.

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Serpone, N., and M. Z. Hoffman. "Multiphoton-Induced Picosecond Photophysics of Chromium(III)- Polypyridyl Complexes." In Photochemistry and Photophysics of Coordination Compounds. Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-72666-8_12.

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Orellana, Guillermo, and David García-Fresnadillo. "Environmental and Industrial Optosensing with Tailored Luminescent Ru(II) Polypyridyl Complexes." In Optical Sensors. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-662-09111-1_13.

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Hoffman, M. Z., and N. Serpone. "Excited State Behavior as a Probe of Ground-State Ion-Pair Interactions in Chromium(III)-Polypyridyl Complexes." In Photochemistry and Photophysics of Coordination Compounds. Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-72666-8_9.

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Palmer, Richard A., Pingyun Chen, Susan E. Plunkett, and James L. Chao. "Excited State Structure and Relaxation Dynamics of Polypyridyl Complexes of Low Spin d 6 Metal Ions by Means of Step-Scan FTIR Time-Resolved Spectroscopy (S2FT-IR TRS)." In Progress in Fourier Transform Spectroscopy. Springer Vienna, 1997. http://dx.doi.org/10.1007/978-3-7091-6840-0_149.

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Xiong, Zushuang, Lanhai Lai, and Tianfeng Chen. "Self-Assembled Copper Polypyridyl Supramolecular Metallopolymer Achieving Enhanced Anticancer Efficacy." In Self-Assembly of Nanostructures and Patchy Nanoparticles. IntechOpen, 2020. http://dx.doi.org/10.5772/intechopen.92708.

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Metallopolymers, a combination of organic polymers and metal center, contain metal atoms in repeating monomers can change its dynamic and thermodynamic properties through the directionality of coordination bonds and chemical tailoring of ligands. In the past decade, self-assembled functional supramolecular metallopolymers have aroused a surge of research interest, and have demonstrated application potential in cancer therapy. In this chapter, we have summarized the progress in the rational design of biological application of different metallopolymers. Especially, a copper polypyridyl complex was found be able to self-assemble into a supramolecular metallopolymer driven by the intermolecular interactions, which could enhance the uptake in cancer cells through endocytosis, thus effectively inhibit tumor growth in vivo without damage to the major organs. This study may provide a good example to use self-assembled metallopolymer to achieve enhanced anticancer efficacy.
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Tsubonouchi, Yuta, Eman A. Mohamed, Zaki N. Zahran, and Masayuki Yagi. "Mechanisms of Photoisomerization and Water Oxidation Catalysis of Ruthenium(II) Aquo Complexes." In Ruthenium - an Element Loved by Researchers [Working Title]. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.99730.

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Polypyridyl ruthenium(II) complexes have been widely researched as promising functional molecules. We have found unique photoisomerization reactions of polypyridyl ruthenium(II) aquo complexes. Recently we have attempted to provide insight into the mechanism of the photoisomerization of the complexes and distinguish between the distal−/proximal-isomers in their physicochemical properties and functions. Moreover, polypyridyl ruthenium(II) aquo complexes have been intensively studied as active water oxidation catalysts (WOCs) which are indispensable for artificial photosynthesis. The catalytic aspect and mechanism of water oxidation by the distal-/proximal-isomers of polypyridyl ruthenium(II) aquo complexes have been investigated to provide the guided thought to develop more efficient molecular catalysts for water oxidation. The recent progress on the photoisomerization and water oxidation of polypyridyl ruthenium(II) aquo complexes in our group are reviewed to understand the properties and functions of ruthenium complexes.
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Kumar, Pramod, and Sushil Kumar. "Detection of Bio-Relevant Metal Ions by Luminescent Ru(II)-Polypyridyl Based Sensors." In Ruthenium - an Element Loved by Researchers [Working Title]. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.96453.

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Biorelevant metal ions such as Cu2+ and Fe2+/Fe3+ participate in various biological events which include electron transfer reactions, delivery and uptake of oxygen, DNA and RNA syntheses, and enzymatic catalysis to maintain fundamental physiological processes in living organisms. So far, several analytical techniques have been investigated for their precise detection; however, luminescence-based sensing is often superior due to its high sensitivity, selectivity, fast and easy operation and convenient cellular imaging. Owing to their immense photophysical and photochemical properties stemming from large Stokes shift, absorption in visible region, good photostability and long excited state lifetimes, Ru(II)-polypyridyl-based complexes have gained increasing interest as luminophores. Over past few decades, several Ru(II)-polypyridyl based chemosensors have rapidly been developed for detection of different biorelevant and other metal ions. The main object of this book chapter is to cover a majority of Ru(II)-polypyridyl based chemosensors showing a selective and sensitive detection of bio-relevant Cu2+ and Fe2+/Fe3+ ions. The photophysical properties of Ru(II) complexes, detection of metal ions, sensing mechanism and applications of these sensors are discussed at a length.
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Patra, Goutam Kumar, Anupam Ghorai, and Amit Kumar Manna. "Ru(II)-polypyridyl Complexes as Potential Sensing Agents for Cations and Anions." In Recent Advances in Analytical Techniques. BENTHAM SCIENCE PUBLISHERS, 2019. http://dx.doi.org/10.2174/9781681085722119030009.

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Conference papers on the topic "Polypyridyl complex"

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Zhang, Ye, Ning Zhou, and Bing Xu. "Cell Compatible Polypyridyl Ru-Complex Based Fluorophore as Long-Life Lysosome Tracker." In Biomedical Optics. OSA, 2014. http://dx.doi.org/10.1364/biomed.2014.bt3a.53.

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Handy, Erik S., Erika D. Abbas, Amlan J. Pal, and Michael F. Rubner. "Development of the tris-chelated polypyridyl ruthenium (II) complex as a solid state light emitter." In SPIE's International Symposium on Optical Science, Engineering, and Instrumentation, edited by Zakya H. Kafafi. SPIE, 1998. http://dx.doi.org/10.1117/12.332600.

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Durand, Nicolas, Paul Savel, Huriye Akdas-Kilic, Abdou Boucekkine, Jean-Pierre Malval, and Jean-Luc Fillaut. "Polypyridyl Ruthenium Complexes: Versatile Tools for Linear and Non-Linear Optics." In 2019 21st International Conference on Transparent Optical Networks (ICTON). IEEE, 2019. http://dx.doi.org/10.1109/icton.2019.8840409.

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Gordon, Keith C., Michael G. Fraser, Raphael Horvath, P. M. Champion, and L. D. Ziegler. "Resonance Raman Spectroscopy Of Rhenium(I) Complexes With Sulfur-Containing Polypyridyl Ligands." In XXII INTERNATIONAL CONFERENCE ON RAMAN SPECTROSCOPY. AIP, 2010. http://dx.doi.org/10.1063/1.3482689.

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Israil, R., L. Schüssler, M. Schmitt, et al. "Ultrafast Dynamics of RuII-polypyridyl Complexes – Photoinduced Ligand Dissociation Dynamics in Gas Phase and Solution." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 2022. http://dx.doi.org/10.1364/up.2022.tu4a.4.

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Ultrafast electronic dynamics and UV absorption of [RuII(bipyridine)2(nicotinamide)2]2+ isolated in an ion trap reveal by transient photodissociation short time constants and spectra comparable to transient absorption in solution. Ligand dissociation dynamics are elucidated.
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Premkumar, P., Krishnan Namboori P.K., M. Sathishkumar, K. I. Ramachandran, and Deepa Gopakumar. "Quantum Mechanical Modeling and Molecular Dynamic Simulation of Ruthenium (Ru) Polypyridyl Complexes to Study Feasibility of Artificial Photosynthesis." In 2009 International Conference on Advances in Recent Technologies in Communication and Computing. ARTCom 2009. IEEE, 2009. http://dx.doi.org/10.1109/artcom.2009.129.

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