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Journal articles on the topic 'Polynuclear Transition Metal Complexes'

Author: Grafiati

Published: 7 September 2023

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1

Yam, Vivian Wing-Wah. "Molecular design of luminescent metal-based materials." Pure and Applied Chemistry 73, no. 3 (January 1, 2001): 543–48. http://dx.doi.org/10.1351/pac200173030543.

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A series of soluble di- and polynuclear transition-metal acetylides with rich luminescence behavior have been designed and successfully isolated. The photophysical and photochemical properties have been studied. Luminescent polynuclear metal complexes have also been obtained based on the metal chalcogenide building block. These high-nuclearity transition-metal chalcogenide complexes have been structurally characterized and shown to display rich luminescence behavior. Various approaches and strategies to design and synthesize luminescent polynuclear metal complexes that may find potential applications as chemosensors and luminescence signalling devices will also be described.

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2

Umakoshi, Keisuke. "Stereocontrol and Metal-metal Interactions of Polynuclear Transition Metal Complexes." Bulletin of Japan Society of Coordination Chemistry 79 (June 6, 2022): 58–67. http://dx.doi.org/10.4019/bjscc.79.58.

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3

Balzani, Vincenzo, Alberto Juris, Margherita Venturi, Sebastiano Campagna, and Scolastica Serroni. "Luminescent and Redox-Active Polynuclear Transition Metal Complexes†." Chemical Reviews 96, no. 2 (January 1996): 759–834. http://dx.doi.org/10.1021/cr941154y.

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4

Siddiqi, K. S., Sadaf Khan, Shahab A. A. Nami, and M. M. El-ajaily. "Polynuclear transition metal complexes with thiocarbohydrazide and dithiocarbamates." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 67, no. 3-4 (July 2007): 995–1002. http://dx.doi.org/10.1016/j.saa.2006.09.019.

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5

Podewitz, Maren, Carmen Herrmann, Astrid Malassa, Matthias Westerhausen, and Markus Reiher. "Spin–Spin interactions in polynuclear transition-metal complexes." Chemical Physics Letters 451, no. 4-6 (January 2008): 301–8. http://dx.doi.org/10.1016/j.cplett.2007.12.011.

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6

Klingele, Julia, Sebastian Dechert, and Franc Meyer. "Polynuclear transition metal complexes of metal⋯metal-bridging compartmental pyrazolate ligands." Coordination Chemistry Reviews 253, no. 21-22 (November 2009): 2698–741. http://dx.doi.org/10.1016/j.ccr.2009.03.026.

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7

Satpathy, K. C., A. K. Panda, R. Mishra, A. Mahapatra, and A. Patel. "Polynuclear Metal Complexes: Transition Metal Complexes of bis(3-Formyl-Salicylic Acid)-hydrazone." Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 22, no. 2-3 (February 1992): 201–15. http://dx.doi.org/10.1080/00945719208021383.

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8

Ahmed, Ejaz, and Michael Ruck. "Chemistry of polynuclear transition-metal complexes in ionic liquids." Dalton Transactions 40, no. 37 (2011): 9347. http://dx.doi.org/10.1039/c1dt10829h.

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9

Provent, Christophe, and Alan F. Williams. "ChemInform Abstract: The Chirality of Polynuclear Transition Metal Complexes." ChemInform 31, no. 42 (October 17, 2000): no. http://dx.doi.org/10.1002/chin.200042291.

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10

Cirera, Jordi, Yuan Jiang, Lei Qin, Yan-Zhen Zheng, Guanghua Li, Gang Wu, and Eliseo Ruiz. "Ferromagnetism in polynuclear systems based on non-linear [MnII2MnIII] building blocks." Inorganic Chemistry Frontiers 3, no. 10 (2016): 1272–79. http://dx.doi.org/10.1039/c6qi00189k.

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Design of new polynuclear transition metal complexes showing ferromagnetic interactions to achieve high spin values is an important challenge due to the scarcity of bridging ligands that provide such coupling.

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11

Goodyear, Grant, and Richard M. Stratt. "What determines the spin states of polynuclear transition-metal complexes?" Journal of the American Chemical Society 115, no. 22 (November 1993): 10452–53. http://dx.doi.org/10.1021/ja00075a108.

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12

BALZANI, V., A. JURIS, M. VENTURI, S. CAMPAGNA, and S. SERRONI. "ChemInform Abstract: Luminescent and Redox-Active Polynuclear Transition Metal Complexes." ChemInform 27, no. 30 (August 5, 2010): no. http://dx.doi.org/10.1002/chin.199630316.

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13

Wilhelmi, Caroline, Maximilian Gaffga, Yu Sun, Gereon Niedner-Schatteburg, and Werner R. Thiel. "A Novel Bifunctional Ligand for the Synthesis of Polynuclear Alkynyl Complexes." Zeitschrift für Naturforschung B 69, no. 11-12 (December 1, 2014): 1290–98. http://dx.doi.org/10.5560/znb.2014-4164.

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Abstract The synthesis of 2-(1-(prop-2-yn-1-yl)-1H-pyrazol-3-yl)pyridine is presented. This ligand contains both, an alkynyl function being suitable for metal-carbon bond formation with electron-rich late transition metal sites, and a pyrazolylpyridine unit, which is well-known to undergo chelation reactions similar to 2,2′-bipyridine. This strategy allows building up polynuclear complexes with broad combinations of different metal sites. Two platinum alkynyl complexes were structurally characterized, and a trinuclear Ru2Pt complex was indentified by means of NMR spectroscopy and ESI mass spectrometry.

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14

Isaka, Yusuke, Kohei Oyama, Yusuke Yamada, Tomoyoshi Suenobu, and Shunichi Fukuzumi. "Photocatalytic production of hydrogen peroxide from water and dioxygen using cyano-bridged polynuclear transition metal complexes as water oxidation catalysts." Catalysis Science & Technology 6, no. 3 (2016): 681–84. http://dx.doi.org/10.1039/c5cy01845e.

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H₂O₂ was produced from H₂O and O₂ using cyano-bridged polynuclear transition metal complexes as water oxidation catalysts with a Ru photocatalyst in water under visible light irradiation.

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15

Ahmed, Ejaz, and Michael Ruck. "ChemInform Abstract: Chemistry of Polynuclear Transition-Metal Complexes in Ionic Liquids." ChemInform 42, no. 48 (November 3, 2011): no. http://dx.doi.org/10.1002/chin.201148223.

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16

Gerasko, O. A., M. N. Sokolov, and V. P. Fedin. "Mono- and polynuclear aqua complexes and cucurbit[6]uril: Versatile building blocks for supramolecular chemistry." Pure and Applied Chemistry 76, no. 9 (September 30, 2004): 1633–46. http://dx.doi.org/10.1351/pac200476091633.

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The review surveys new data on the directed construction of supramolecular organic–inorganic compounds from macrocyclic cavitand cucurbit[6]uril (C36H36N24O12)and mono- and polynuclear aqua complexes. Due to the presence of polarized carbonyl groups, cucurbit[6]uril forms strong complexes with alkali, alkaline earth and rare-earth metal ions, and hydrogen-bonded supramolecular adducts with cluster and polynuclear aqua complexes of transitional metals. A wide variety of supramolecular compounds and their unique structures are described.

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17

Sokolov, Maxim N., Alexander V. Anyushin, Rita Hernandez-Molina, Rosa Llusar, and Manuel G. Basallote. "Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization." Pure and Applied Chemistry 89, no. 3 (March 1, 2017): 379–92. http://dx.doi.org/10.1515/pac-2017-0105.

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AbstractThis contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P–(CH2)x–OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.

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18

Bignozzi, C. A., M. Alebbi, E. Costa, C. J. Kleverlaan, R. Argazzi, and G. J. Meyer. "Remote interfacial electron transfer processes on nanocrystallineTiO2sensitized with polynuclear complexes." International Journal of Photoenergy 1, no. 3 (1999): 135–42. http://dx.doi.org/10.1155/s1110662x99000239.

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The kinetic study of interfacial electron transfer in sensitized nanocrystalline semiconductor is essential to the design of molecular devices performing specific light induced functions in a microheterogeneous environment. A series of molecular assemblies performing direct and remote charge injection to the semiconductor have been discussed in the context of artificial photosynthesis. A particular attention in this article has been paid to the factors that control the interfacial electron transfer processes in nanocrystallineTiO2films sensitized with mononuclear and polynuclear transition metal complexes.

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19

徐, 晶晶. "Research Progress of Polynuclear Transition Metal Complexes Based on Schiff-Based Ligands." Journal of Advances in Physical Chemistry 10, no. 03 (2021): 142–61. http://dx.doi.org/10.12677/japc.2021.103014.

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20

Bencini, Alessandro, Federico Totti, Claude A. Daul, Karel Doclo, Piercarlo Fantucci, and Vincenzo Barone. "Density Functional Calculations of Magnetic Exchange Interactions in Polynuclear Transition Metal Complexes." Inorganic Chemistry 36, no. 22 (October 1997): 5022–30. http://dx.doi.org/10.1021/ic961448x.

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21

Ruiz, Eliseo, Antonio Rodríguez-Fortea, Joan Cano, Santiago Alvarez, and Pere Alemany. "About the calculation of exchange coupling constants in polynuclear transition metal complexes." Journal of Computational Chemistry 24, no. 8 (April 16, 2003): 982–89. http://dx.doi.org/10.1002/jcc.10257.

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22

Sison, Girlie Naomi N., Arnie R. De Leon, and Janir T. Datukan. "Synthesis and Spectroscopic Analysis of Novel Polynuclear Rhenium(I) Complexes of the Form [Re(CO)3Cl]n[tppq] (n = 1, 2, 3, or 4; tppq = 2,3,1,8-tetra-2-Pyridylpyrazino[2,3-g]quinoxalineJ." KIMIKA 23 (March 1, 2010): 55–63. http://dx.doi.org/10.26534/kimika.v23i1.55-63.

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A number of transition metal complexes have been investigated as potential electrocatalystsfor C02 reduction. Among these are rhenium monometallic complexes, which have shownunique activity towards C02 reduction. Further development of multimetallic systems,capable of storing multiple equivalents of electrons has shown some potential in increasingthe selectivity of the C02 conversion processes toward highly reduced products. This studyreports the synthesis and characterization of novel polynuclear rhenium(I) complexes whererhenium is incorporated to the bridging ligand tppq (2,3,7,8-tetra-2-pyridylpyrazino[2,3-g]quinoxaline), which is capable of attaching up to four metal centers. The resultingcomplexes were characterized using different spectroscopic techniques (infrared, UV-Vis,emission) and cyclic voltammetry. The results suggest that the synthetic procedure adoptedwas successful.

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23

Thompson, Laurence K. "2004 Alcan Award LectureFrom dinuclear to triakontahexanuclear complexes Adventures in supramolecular coordination chemistry." Canadian Journal of Chemistry 83, no. 2 (February 1, 2005): 77–92. http://dx.doi.org/10.1139/v04-173.

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Polynuclear coordination complexes result from the interplay between the arrangement of the binding sites of a ligand, and their donor content, and the coordination preferences of the metal ion involved. Rational control of the ligand properties, such as denticity, geometry, and size, can lead to large, and sometimes predictable, polynuclear assemblies. This Alcan Award Lecture highlights our "adventures" with polynucleating ligands over the last 25 years, with examples ranging from simple dinucleating to more exotic high-denticity ligands. Complexes with nuclearities ranging from 2 to 36 have been produced, many of which have novel magnetic, electrochemical, and spectroscopic properties. Self-assembly strategies using relatively simple "polytopic" ligands have been very successful in producing high-nuclearity clusters in high yield. For example, linear "tritopic" ligands produce M9 (M = Mn(II), Fe(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II)) [3 × 3], flat grid-like molecules, which have quantum dot-like arrays of nine closely spaced metal centers in electronic communication. Some of these grids are discussed in terms of their novel magnetic and electrochemical properties, and also as multistable nanometer-scale platforms for potential molecular device behaviour. Bigger ligands with extended arrays of coordination pockets, and the capacity to self-assemble into much larger grids, are highlighted to illustrate our current and longer term goals of generating polymetallic molecular two-dimensional layers on surfaces.Key words: Alcan Award Lecture, transition metal, polynuclear, structure, magnetism, electrochemistry, surface studies, molecular device.

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24

Sidorov, Alexey A., Mikhail A. Kiskin, Alexander E. Baranchikov, Vladimir K. Ivanov, and Igor L. Eremenko. "Methods for Synthesis of Molecular Materials with Unique Physical Properties." Vestnik RFFI, no. 2 (June 25, 2019): 82–100. http://dx.doi.org/10.22204/2410-4639-2019-102-02-82-100.

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The authors discovered and investigated new types of stable heterometallic carboxylate complexes in which divalent transition metal atoms of the 4th period of the Periodic Table of Chemical Elements (V, Co, Ni, Cu, Zn) combine with atoms of lithium, magnesium, calcium or rare earth elements. These polynuclear heterometallic compounds retain their structure under conditions when the homometallic compounds of these transition metals decompose to mononuclear complexes. The different metals combination in one molecule allows us to use the obtained heterometallic compounds for producing disperse and film oxide materials, and bimetallic oxide catalysts. The stability of the complexes allows to immobilize them in various matrices and to assemble 3D polymer structures on their base. Since the metal ions under consideration (V, Co, Ni, Cu, Zn) are capable to form isostructural heterometallic compounds, it becomes possible to obtain compounds within a single structural type with a given combination of physical properties, determined by the nature of the metal ions.

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25

Jia, Rui, Ting Gao, Ruoxi Chen, Yu Yang, Po Gao, Yan Wang, and Pengfei Yan. "Syntheses and Structures of Homodinuclear (Na–Na) and Heterodinuclear (Cu–Na, Cu–K) Metal Complexes." Australian Journal of Chemistry 69, no. 1 (2016): 20. http://dx.doi.org/10.1071/ch15200.

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The study of polynuclear metal complexes has gained great recognition over the last decade owing to their fascinating topological structures, various properties, and potential applications as functional solid materials in luminescence, catalysis, and magnetic materials. A large number of heterodinuclear 3d–4f and 3d–3d′ complexes have been widely studied due to their functional applications. To our knowledge, structurally characterised heterodinuclear (3d–Na, 3d–K) and homodinuclear (Na–Na) metal complexes are rare. Three metal complexes, [CuIINaI(HL1)2(SbF6)]n (1), [CuIIKI(HL1)2(PF6)]n (2), and [Na2(H2L2)2] (3), were synthesised by two kinds of ligands, o-vanillin (HL1) and N,N′-ethylene-bis(3-methoxysalicylideneimine) (H2L2). The structures of heterodinuclear complexes 1 and 2 are both one-dimensional chain structures, including transition metal ions (CuII) and main group metal ions (NaI and KI). However, the complex 3, as a homodinuclear metal complex, only has one kind of centre, a NaI ion. The structures of complexes 1–3 were determined by single crystal X-ray crystallographic studies.

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26

Bencini, Andrea, Antonio Bianchi, Piero Paoletti, and Paola Paoli. "Thermodynamic and structural aspects of transition metal compounds. Polynuclear complexes of aza-macrocycles." Coordination Chemistry Reviews 120 (November 1992): 51–85. http://dx.doi.org/10.1016/0010-8545(92)80047-u.

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27

Bencini, Alessandro, and Stefano Midollini. "Some synthetic and theoretical aspects of the chemistry of polynuclear transition-metal complexes." Coordination Chemistry Reviews 120 (November 1992): 87–136. http://dx.doi.org/10.1016/0010-8545(92)80048-v.

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28

Ahlrichs, Reinhart, Dieter Fenske, Katharina Fromm, Harald Krautscheid, Ulrike Krautscheid, and Oliver Treutler. "Zintl Anions as Starting Compounds for the Synthesis of Polynuclear Transition Metal Complexes." Chemistry - A European Journal 2, no. 2 (February 1996): 238–44. http://dx.doi.org/10.1002/chem.19960020217.

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29

Nesterov, Dmytro, and Oksana Nesterova. "Polynuclear Cobalt Complexes as Catalysts for Light-Driven Water Oxidation: A Review of Recent Advances." Catalysts 8, no. 12 (December 2, 2018): 602. http://dx.doi.org/10.3390/catal8120602.

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Photochemical water oxidation, as a half-reaction of water splitting, represents a great challenge towards the construction of artificial photosynthetic systems. Complexes of first-row transition metals have attracted great attention in the last decade due to their pronounced catalytic efficiency in water oxidation, comparable to that exhibited by classical platinum-group metal complexes. Cobalt, being an abundant and relatively cheap metal, has rich coordination chemistry allowing construction of a wide range of polynuclear architectures for the catalytic purposes. This review covers recent advances in application of cobalt complexes as (pre)catalysts for water oxidation in the model catalytic system comprising [Ru(bpy)3]2+ as a photosensitizer and S2O82− as a sacrificial electron acceptor. The catalytic parameters are summarized and discussed in view of the structures of the catalysts. Special attention is paid to the degradation of molecular catalysts under catalytic conditions and the experimental methods and techniques used to control their degradation as well as the leaching of cobalt ions.

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30

Fujisawa, Kiyoshi, Mai Saotome, Yoko Ishikawa, and David James Young. "The Influence of Aryl Substituents on the Supramolecular Structures and Photoluminescence of Cyclic Trinuclear Pyrazolato Copper(I) Complexes." Nanomaterials 11, no. 11 (November 17, 2021): 3101. http://dx.doi.org/10.3390/nano11113101.

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Cyclic trinuclear complexes with group 11 metal(I) ions are fascinating and important to coordination chemistry. One of the ligands known to form these cyclic trinuclear complexes is pyrazolate, which is a bridging ligand that coordinates many transition metal ions in a Npz–M–Npz linear mode (Npz = pyrazolyl nitrogen atom). In these group 11 metal(I) ions, copper is the most abundant metal. Therefore, polynuclear copper(I) complexes are very important in this field. The cyclic trinuclear copper(I) complex [Cu(3,5-Ph2pz)]3 (3,5-Ph2pz– = 3,5-diphenyl-1-pyrazolate anion) was reported in 1988 as a landmark complex, but its photoluminescence properties have hitherto not been described. In this study, we report the photoluminescence and two different polymorphs of [Cu(3,5-Ph2pz)]3 and its derivative [Cu(3-Me-5-Phpz)]3 (3-Me-5-Phpz– = 3-metyl-5-phenyl-1-pyrazale anion). The substituents in [Cu(3-Me-5-Phpz)]3 cause smaller distortions in the solid-state structure and a red-shift in photoluminescence due to the presence of intermolecular cuprophilic interactions.

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31

Krisyuk, Vladislav V., Samara Urkasym Kyzy, Tatyana V. Rybalova, Ilya V. Korolkov, Mariya A. Grebenkina, and Alexander N. Lavrov. "Structure and Properties of Heterometallics Based on Lanthanides and Transition Metals with Methoxy-β-Diketonates." Molecules 27, no. 23 (December 1, 2022): 8400. http://dx.doi.org/10.3390/molecules27238400.

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The possibility of obtaining volatile polynuclear heterometallic complexes containing lanthanides and transition metals bound by methoxy-β-diketonates was studied. New compounds were prepared by cocrystallization of monometallic complexes from organic solvents. Ln(tmhd)3 were used as initial monometallic complexes (Ln = La, Pr, Sm, Gd, Tb, Dy, Lu; tmhd = 2,2,6,6-tetramethylheptane-3,5-dionate) in combination with TML2 in various ratios (TM = Cu, Co, Ni, Mn; L: L1 = 1,1,1-trifluoro-5,5-dimethoxypentane-2,4-dionate, L2 = 1,1,1-trifluoro-5,5-dimethoxy-hexane-2,4-dionate, L3 = 1,1,1-trifluoro-5-methoxy-5-methylhexane-2,4-dionate). Heterometallic complexes of the composition [(LnL2tmhd)2TM(tmhd)2] were isolated for light lanthanides Ln= La, Pr, Sm, Gd, and L= L1 or L2. By single crystal XRD, it has been established that heterometallic compounds containing La, Pr, Cu, Co, and Ni are isostructural linear coordination polymers of alternating mononuclear transition metal complexes and binuclear heteroleptic lanthanide complexes, connected by donor–acceptor interactions between oxygen atoms of the methoxy groups and transition metal atoms. A comparison of powder XRD patterns has shown that all heterometallic complexes obtained are isostructural. Havier lanthanides Ln = Tb, Dy, Lu did not form heterometallics. Instead, homometallic complexes Ln(L3)3 were identified for Ln = Dy, Lu as well as for Ln = La. The thermal properties of the complexes were investigated by TG-DTA and vacuum sublimation tests. The heterometallic complexes were found to be not volatile and decomposed under heating to produce inorganic composites of TM oxides and Ln fluorides. In contrast, Ln(L3)3 is volatile and may be sublimed in a vacuum. Results of magnetic measurements are discussed for several heterometallic and homometallic complexes.

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32

BENCINI, A., and S. MIDOLLINI. "ChemInform Abstract: Some Synthetic and Theoretical Aspects of the Chemistry of Polynuclear Transition-Metal Complexes." ChemInform 24, no. 12 (August 20, 2010): no. http://dx.doi.org/10.1002/chin.199312298.

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33

Wei, Yongli, Hongwei Hou, Yaoting Fan, and Yu Zhu. "Transition Metal Ion Directed Self-Assembly of Polynuclear Coordination Complexes: Structural Characterization and Magnetic Properties." European Journal of Inorganic Chemistry 2004, no. 19 (October 2004): 3946–57. http://dx.doi.org/10.1002/ejic.200400110.

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34

Boča, Roman, Ivan Nemec, Ivan Šalitroš, Ján Pavlik, Radovan Herchel, and Franz Renz. "Interplay between spin crossover and exchange interaction in iron(III) complexes." Pure and Applied Chemistry 81, no. 8 (July 20, 2009): 1357–83. http://dx.doi.org/10.1351/pac-con-08-07-20.

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In the dinuclear and polynuclear metal complexes exhibiting the low-spin (LS) to high-spin (HS) transition, the spin-crossover phenomenon interferes with the magnetic exchange interaction. The latter manifests itself in forming spin-multiplets, which causes a possible overlap of the band originating in different reference spin states (LL, LH, HL, and HH). A series of dinuclear Fe(III) complexes has been prepared; the iron centers are linked by a bidentate bridge (CN-, and diamagnetic metallacyanates {Fe(CN)5(NO)}, {Ni(CN)4}, {Pt(CN)4}, and {Ag(CN)2}). Magnetic measurements confirm that the spin crossover proceeds on the thermal propagation. This information has been completed also by the Mössbauer spectral (MS) data. A theoretical model has been developed that allows a simultaneous fitting of all available experimental data (magnetic susceptibility, magnetization, HS mole fraction) on a common set of parameters.

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35

Okamoto, Ken-ichi, Chieko Sasaki, Yasunori Yamada, and Takumi Konno. "Stereoselectivity for S-Bridged Polynuclear Transition Metal Complexes Formed by Aggregation of Octahedral Complexes to Square-Planar Palladium(II)." Bulletin of the Chemical Society of Japan 72, no. 8 (August 1999): 1685–96. http://dx.doi.org/10.1246/bcsj.72.1685.

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36

Nesterov, Dmytro S., and Oksana V. Nesterova. "Catalytic Oxidations with Meta-Chloroperoxybenzoic Acid (m-CPBA) and Mono- and Polynuclear Complexes of Nickel: A Mechanistic Outlook." Catalysts 11, no. 10 (September 25, 2021): 1148. http://dx.doi.org/10.3390/catal11101148.

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Selective catalytic functionalization of organic substrates using peroxides as terminal oxidants remains a challenge in modern chemistry. The high complexity of interactions between metal catalysts and organic peroxide compounds complicates the targeted construction of efficient catalytic systems. Among the members of the peroxide family, m-chloroperoxybenzoic acid (m-CPBA) exhibits quite complex behavior, where numerous reactive species could be formed upon reaction with a metal complex catalyst. Although m-CPBA finds plenty of applications in fine organic synthesis and catalysis, the factors that discriminate its decomposition routes under catalytic conditions are still poorly understood. The present review covers the advances in catalytic C–H oxidation and olefine epoxidation with m-CPBA catalyzed by mono- and polynuclear complexes of nickel, a cheap and abundant first-row transition metal. The reaction mechanisms are critically discussed, with special attention to the O–O bond splitting route. Selectivity parameters using recognized model hydrocarbon substrates are summarized and important factors that could improve further catalytic studies are outlined.

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37

Tchougréeff, A. L., and A. V. Soudackov. "Effective Hamiltonian crystal fields: Present status and applicability to magnetic interactions in polynuclear transition metal complexes." Russian Journal of Physical Chemistry A 88, no. 11 (October 10, 2014): 1904–13. http://dx.doi.org/10.1134/s0036024414110053.

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38

del Rosal, Iker, Torsten Gutmann, Bernadeta Walaszek, Iann C. Gerber, Bruno Chaudret, Hans-Heinrich Limbach, Gerd Buntkowsky, and Romuald Poteau. "2H NMR calculations on polynuclear transition metal complexes: on the influence of local symmetry and other factors." Physical Chemistry Chemical Physics 13, no. 45 (2011): 20199. http://dx.doi.org/10.1039/c1cp22081k.

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39

Lukov, V. V., I. N. Shcherbakov, S. I. Levchenkov, Yu P. Tupolova, L. D. Popov, I. V. Pankov, and S. V. Posokhova. "Controlled Molecular Magnetism of Bi- and Polynuclear Transition Metal Complexes Based on Hydrazones, Azomethines, and Their Analogs." Russian Journal of Coordination Chemistry 45, no. 3 (March 2019): 163–87. http://dx.doi.org/10.1134/s1070328419030060.

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40

Balch, Alan L., Rosalvina R. Guimerans, and John Linehan. "Mono- and polynuclear transition-metal complexes of the linear, small-bite tris(phosphine) bis((diphenylphosphino)methyl)phenylphosphine." Inorganic Chemistry 24, no. 3 (January 1985): 290–96. http://dx.doi.org/10.1021/ic00197a010.

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41

Ren, Zong-Li, Xiao-Yan Li, Jing Hao, Yang Zhang, and Wen-Kui Dong. "Syntheses, structural characterizations, and electrochemical and fluorescent properties of homo- and hetero-polynuclear transition metal(II) complexes." Applied Organometallic Chemistry 32, no. 12 (October 18, 2018): e4614. http://dx.doi.org/10.1002/aoc.4614.

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Phillips, Jordan J., and Juan E. Peralta. "Towards the blackbox computation of magnetic exchange coupling parameters in polynuclear transition-metal complexes: Theory, implementation, and application." Journal of Chemical Physics 138, no. 17 (May 7, 2013): 174115. http://dx.doi.org/10.1063/1.4802776.

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HIDAI, M., and Y. MIZOBE. "ChemInform Abstract: Toward Novel Organic Synthesis on Multimetallic Centers: Synthesis and Reactivities of Polynuclear Transition-Metal-Sulfur Complexes." ChemInform 28, no. 21 (August 4, 2010): no. http://dx.doi.org/10.1002/chin.199721267.

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Rybinskaya, M. I. "Sandwich mono- and polynuclear transition metal complexes as the basis for development of concepts on inorganic benzenoid systems." Bulletin of the Russian Academy of Sciences Division of Chemical Science 41, no. 5 (May 1992): 850–67. http://dx.doi.org/10.1007/bf00864532.

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WEI, HAIYAN, and ZHIDA CHEN. "MAGNETIC EXCHANGE IN POLYNUCLEAR TRANSITION METAL SYSTEM: AB INITIO CASPT2 AND DENSITY FUNCTIONAL THEORY STUDY ON TRIANGULAR COPPER(II) COMPLEXES." Journal of Theoretical and Computational Chemistry 05, spec01 (January 2006): 501–14. http://dx.doi.org/10.1142/s0219633606002428.

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Abstract:

The magnetic exchange interactions for five representative triangular Copper(II) complexes: antiferromagnetic Cu 3( TiPB )6 (1), [ Cu 3(μ3- OH )( aaat )3( H 2 O )3]2+ (2), [ PPN ]2 [ Cu 3(μ3- O )(μ- pz )3 Cl 3] (3), [ PPN ][ Cu 3(μ3- OH )(μ- pz )3 Cl 3] (4) and ferromagnetic [ Cu 3(2- CH 3 C 6 H 4 CO 2)4{( C 2 H 5)2 NC 2 H 4 O }2 H 2 O ] (5) are investigated by using density functional theory combined with broken-symmetry approach (DFT-BS) and ab initio CASPT2 method. Our calculated results show that DFT-BS has remarkable dependence on the particular chosen XC functionals and is system-dependent, while the calculations at CASPT2 level of theory are able to give the accurate magnetic coupling constants. Qualitatively, the two theoretical methods reproduce consistently the linear correlation between the magnetic coupling constants and the departure of the (μ3- O ) oxygen atom from the { Cu3 } plane in the complexes (3) and (4). Spin population analyses reveal that the DFT-BS method overestimates the spin electronic delocalization from the Cu(II) center to the bridging ligands.

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46

Borisova, N. E., Yu A. Ustynyuk, M. D. Reshetova, G. G. Aleksandrov, I. L. Eremenko, and I. I. Moiseev. "Binuclear and polynuclear transition metal complexes with macrocyclic ligands. 5. Novel complexes of asymmetric polydentate macrocyclic Schiff bases. Step-by-step synthesis." Russian Chemical Bulletin 53, no. 2 (February 2004): 340–45. http://dx.doi.org/10.1023/b:rucb.0000030808.51647.f1.

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Retegan, Marius, Nicholas Cox, Dimitrios A. Pantazis, and Frank Neese. "A First-Principles Approach to the Calculation of the on-Site Zero-Field Splitting in Polynuclear Transition Metal Complexes." Inorganic Chemistry 53, no. 21 (October 23, 2014): 11785–93. http://dx.doi.org/10.1021/ic502081c.

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Roznyatovsky, V. V., N. E. Borisova, M. D. Reshetova, A. G. Buyanovskaya, and Yu A. Ustynyuk. "Binuclear and polynuclear transition metal complexes with macrocyclic ligands 7. Directed step-by-step synthesis of novel unsymmetric macrocyclic ligands." Russian Chemical Bulletin 54, no. 9 (September 2005): 2219–23. http://dx.doi.org/10.1007/s11172-006-0100-y.

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O'Brien, Ted A., and Ernest R. Davidson. "Semiempirical local spin: Theory and implementation of the ZILSH method for predicting Heisenberg exchange constants of polynuclear transition metal complexes." International Journal of Quantum Chemistry 92, no. 3 (February 10, 2003): 294–325. http://dx.doi.org/10.1002/qua.10513.

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Huang, Ting-Hong, Jie Yan, Hu Yang, Changbin Tan, and Yan Yang. "Synthesis, Structures, and Properties of Polynuclear Silver(I) Complexes Containing Tetra-Phosphine Ligand with Ag⋅⋅⋅C Interactions." Australian Journal of Chemistry 69, no. 3 (2016): 336. http://dx.doi.org/10.1071/ch15413.

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Abstract:

Reaction of AgNO3 and N,N,N′,N′-tetrakis((diphenylphosphino)methyl)benzene-1,4-diamine (pbaa) with sodium N-ethyldithiocarbamate (Na(Etdtc)) in CH3CN/toluene and CH3CN/DMF solvents produced two Ag4S4-based coordination complexes [Ag4(pbaa)(µ-κ1S,κ2S-Etdtc)4] (1) and [Ag4(pbaa)(µ-κ1S,κ2S-Etdtc)2(µ-κ1S,κ1S-Etdtc)2] (2). Structural analysis shows that the Ag4S4 cores in 1 are interconnected by one pbaa ligand in a tetradentate mode and four Etdtc– anions in a µ-κ1S,κ2S mode to form a three-layer conformation, whereas the Ag4S4 cores in 2 are linked by ligands pbaa (the tetradentate mode) and Etdtc– (the µ-κ1S,κ1S and µ-κ1S,κ2S modes) to yield the other type of three-layer conformation. In addition, in different solvent systems, the Ag atoms also form different types of weak Ag···C interactions with Ag···C distances of 3.297–3.344 Å in 1 and 3.237–3.416 Å in 2. The emission spectrum of complex 1 in DMF solution displays a broad orange–red emission peak at 518 nm, which may be assigned to the ligand-to-metal charge transfer transition.

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