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Relevant bibliographies by topics / Polymerisation

Academic literature on the topic 'Polymerisation'

Author: Grafiati

Published: 4 June 2021

Last updated: 31 July 2024

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Journal articles on the topic "Polymerisation"

1

Goto, Hiromasa. "Polymerisation on Bio-Tissues." International Letters of Chemistry, Physics and Astronomy 68 (July 2016): 18–23. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.68.18.

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Preparation of electro-active polymers having characteristic surface on biological tissue was carried out. Direct polymerisation on biological material with unique structure can be a new method to obtain functional structure with no use of top-down or bottom-up technologies. Polymerisations of pyrrole, aniline, and 3,4-ethylenedioxythiophene (EDOT) were carried out on the bio-tissues. Surface structure of the bio-tissue/conducting polymer composite was observed with optical microscopy. The results of the present study involve demonstration of deposition of conducting polymers on the surface of wood, membrane of egg, fungus, flower, and bacteria in the water medium. This method allows preparation of electro-active composites with ordered structure through combination of structures of biological tissues. Note that electrochemical polymerisation in bacterial electrolyte solution can be a first example to date.

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Goto, Hiromasa. "Polymerisation on Bio-Tissues." International Letters of Chemistry, Physics and Astronomy 68 (July 19, 2016): 18–23. http://dx.doi.org/10.56431/p-50cxcl.

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Preparation of electro-active polymers having characteristic surface on biological tissue was carried out. Direct polymerisation on biological material with unique structure can be a new method to obtain functional structure with no use of top-down or bottom-up technologies. Polymerisations of pyrrole, aniline, and 3,4-ethylenedioxythiophene (EDOT) were carried out on the bio-tissues. Surface structure of the bio-tissue/conducting polymer composite was observed with optical microscopy. The results of the present study involve demonstration of deposition of conducting polymers on the surface of wood, membrane of egg, fungus, flower, and bacteria in the water medium. This method allows preparation of electro-active composites with ordered structure through combination of structures of biological tissues. Note that electrochemical polymerisation in bacterial electrolyte solution can be a first example to date.

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Betz, Kai C., Anna Westhues, and Werner Pauer. "Kinetic Study on Acrylic Acid Polymerisations in Isopropanol." Applied Sciences 11, no. 20 (October 18, 2021): 9719. http://dx.doi.org/10.3390/app11209719.

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The radical polymerisation of acrylic acid is largely concentration dependent and affected by the type of the surrounding solvent. This work investigates reaction rate constants, the activation energy, heat flux and the molecular weight in the industrially relevant synthesis of low molecular mass acrylic acid polymers in 2-propanol. The polymerisations were carried out isothermally in an RC1e calorimeter with inline Raman spectroscopy for monomer concentration monitoring. For a non-neutralised acrylic acid in isopropanol (150 g/L), a monomer reaction order of 1.73 ± 0.15, an activation energy of 58.6 ± 0.8 kJ/mol (0.5 mol% AIBN) and 88.5 ± 1.5 kJ/mol (1.0 mol% AIBN), and a reaction enthalpy of 66.4 ± 4.8 kJ/mol could be shown. This data is in accordance with the literature values for acrylic acid polymerisation in water. In addition, linear correlations between the respective reaction parameters and the molecular weight for customised polymer synthesis in the range from 1.2 to 1.7 × 104 g/mol could be established. In comparison with aqueous acrylic acid polymerisation, it was found that the reaction rate constants in isopropanol were slower by a factor of approximately 10 under similar reaction conditions.

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Połowiński, Stefan. "Template polymerisation and co-polymerisation." Progress in Polymer Science 27, no. 3 (April 2002): 537–77. http://dx.doi.org/10.1016/s0079-6700(01)00035-1.

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Campbell, Jonathan, Harrison Inglis, Elson Ng WeiLong, Cheylan McKinley, and David Lewis. "Morphology Control in a Dual-Cure System for Potential Applications in Additive Manufacturing." Polymers 11, no. 3 (March 5, 2019): 420. http://dx.doi.org/10.3390/polym11030420.

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The polymerisation, morphology and mechanical properties of a two-component in-situ reacting system consisting of a rubbery dimethacrylate and a rigid epoxy polymer were investigated. The methacrylate component of the mixture was photocured using UV light exposure and, in a second curing process, the mixture was thermally postcured. The polymers formed a partially miscible system with two glass transition temperature (Tg) peaks measured using dynamic mechanical thermal analysis (DMTA). The composition and relative rate of reaction of the two orthogonal polymerisations influenced the extent of miscibility of the two polymer-rich phases and the samples were transparent, indicating that the two phases were finely dispersed. The addition of a glycidyl methacrylate compatibiliser further increased the miscibility of the two polymers. The utility of this polymer system for additive manufacturing was investigated and simulated through layer-by-layer processing of the mixture in two steps. Firstly, the methacrylate component was photocured to solidify the material into its final shape, whilst the second step of thermal curing was used to polymerise the epoxy component. With the use of a simulated photomask, a simple shape was formed using the two orthogonal polymerisation stages to produce a solid object. The mechanical properties of this two-phase system were superior to a control sample made only of the methacrylate component, indicating that some reinforcing due to polymerisation of the epoxy across the interfaces had occurred in the postcuring stage.

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Lloyd, Anthony C., and Robert F. T. Stepto. "Rate theory of random polymerisation: RA3 polymerisation." British Polymer Journal 17, no. 2 (June 1985): 190–99. http://dx.doi.org/10.1002/pi.4980170219.

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Houliston, E. "Microtubule translocation and polymerisation during cortical rotation in Xenopus eggs." Development 120, no. 5 (May 1, 1994): 1213–20. http://dx.doi.org/10.1242/dev.120.5.1213.

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The development of dorsal axial structures in frogs depends on a process of cortical rotation in which the cortex of the fertilised egg becomes displaced with respect to the cytoplasm. An array of aligned microtubules that develops between the vegetal cortex and cytoplasm is implicated in generating movement. Rhodamine-tubulin was injected into eggs to allow patterns of microtubule movement and polymerisation in the vegetal array to be examined. Time-lapse video microscopy of living eggs showed that mo st of these microtubules move with the vegetal cytoplasm relative to the cortex, at the same speed as cytoplasmic pigment granules. This implies that movement is generated between the microtubules of the vegetal array and the cortex. A few microtubules we re also detected that appeared immobile with respect to the cortex. Rhodamine-tubulin became incorporated into vegetal microtubules when injected at any time during the period of cortical rotation. The newly formed microtubules connected the vegetal array and internal cytoplasm. This indicates that local outward-direct ed polymerisation continues in this region as the cortex translocates. Experiments with low doses of nocodazole showed that this continuing polymerisation does not contribute to the rotation. Concentrations of the drug that prevented tubulin polymerisatio n had no effect on the speed of rotation if applied after the vegetal array had formed. The same doses prevented movement if applied early enough to prevent the formation of the array. These observations support the idea that mechanochemical enzymes assoc iated with the vegetal microtubules translocate the cortex along microtubules anchored in the subcortical cytoplasm.

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Bagheri, Ali, Suzanne Boniface, and Christopher M. Fellows. "Reversible-Deactivation Radical Polymerisation: chain polymerisation made simple." Chemistry Teacher International 3, no. 2 (February 10, 2021): 19–32. http://dx.doi.org/10.1515/cti-2020-0025.

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Abstract Reversible-Deactivation Radical Polymerisation (RDRP) is one of the most exciting developments in chemistry over the past few decades, but it is rarely mentioned when polymerisation mechanisms are introduced in the final years of secondary education or first years of tertiary education. We propose that this is unfortunate, as RDRP is simpler than conventional Radical Polymerisation both conceptually and in terms of setting quantitative problems, and that it illustrates several other important features of chemistry as a human endeavour: How essential mechanistic unities are hidden by the details of how we write a chemical reaction, how a ‘bug’ in one stage of development of a process can become a ‘feature’ in a later stage, and how exciting changes can occur quite suddenly in fields thought to be mature and uninteresting.

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Limer, Adam, Alex Heming, Ian Shirley, and David Haddleton. "Living radical polymerisation in heterogeneous conditions—suspension polymerisation." European Polymer Journal 41, no. 4 (April 2005): 805–16. http://dx.doi.org/10.1016/j.eurpolymj.2004.11.002.

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Kudo, Yuki, Kosuke Kawabata, and Hiromasa Goto. "Crystal Surface/Liquid Crystal Interfacial Polymerisation: Preparation of Helical π-Conjugated Polymer on Mineral Crystal." International Letters of Chemistry, Physics and Astronomy 69 (August 2016): 58–65. http://dx.doi.org/10.18052/www.scipress.com/ilcpa.69.58.

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Crystal surface/liquid crystal interfacial polymerisation was developed. Poly(3,4-ethylenedioxythiophene) (PEDOT, EDOT = ethylene dioxythiophene) and poly(EDOT-fluorene-EDOT) were prepared in a cholesteric liquid crystal electrolyte solution on the surface of pyrite. Polymerisation in liquid crystal produces polymers showing fingerprint structure through transcription of molecular aggregation in the polymerisation process. Surface structures of the polymers were observed with circular polarised differential interference contrast microscopy (C-DIM) and scanning electron microscopy (SEM). The polymerisation reaction proceeds interface between liquid crystal and pyrite surface. The polymers thus prepared in liquid crystal on the pyrite shows fingerprint structure on steps structure of pyrite. This is a first report of liquid crystal interfacial electrochemical polymerisation on a natural mineral crystal.

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Dissertations / Theses on the topic "Polymerisation"

1

Bechthold, Nina. "Polymerisation in Miniemulsion." Phd thesis, [S.l. : s.n.], 2000. http://deposit.ddb.de/cgi-bin/dokserv?idn=961879416.

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Greenhalgh, Edward T. "Fundamental understanding of microwave assisted ring-opening polymerisation and co-polymerisation." Thesis, University of Nottingham, 2014. http://eprints.nottingham.ac.uk/14265/.

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The work presented in the thesis attempted to gain in-depth understanding of the effect that the microwave energy has on various facets of the ring-opening polymerisation of cyclic esters with a view to synthesising novel bio-degradable homopolymers, branched structures and copolymers. Chapter 1 introduces the various synthetic polymer procedures and lists possible final product architectures. The main technique that is used throughout this thesis, ring-opening polymerisation, is discussed in great detail. The various targeted linear aliphatic polyesters are introduced. Finally, the fundamental theory behind microwave dielectric heating is discussed. Chapter 2 outlines the various characterisation techniques that are used to analyse the various synthesised materials throughout the work in this thesis. The polymerisation techniques used, particularly using the microwave reactor, is also discussed. In Chapter 3, the effect that microwave heating has upon the homopolymerisation of poly(ε-caprolactone) is investigated. Detailed analysis of the dielectric properties of the reagents and accurate temperature monitoring is applied at various stages of the reaction mechanism to compare and contrast the effect of microwave and conventional heating. Chapter 4 describes the impact that microwave energy has upon the copolymerisation reactions when a second cyclic ester is introduced, D/L-lactide. Various procedures are utilised in an attempt to synthesise bio-degradable block copolymers with interesting mechanical properties and degradation rates. The dielectric properties of the reagents and their polymer structures are used to rationalise any experimental observations. The work presented in Chapter 5 investigates the synthesis of branched polymers using a di-lactone branching agent, composed to two joined ε-CL units. Various analytical techniques are employed to guarantee successful branching. The effect of microwave energy is scrutinised, with a view to creating faster rates of reaction and altering the final product structure using direct dielectric heating. Finally, Chapter 6 provides the overall conclusions obtained from the work presented in this thesis, before providing possible routes of subsequent study for further research into this area.

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Zaher, Damien. "Early transition metal benzimidazolyl-based catalysts for olefin polymerisation and co-polymerisation." Thesis, Imperial College London, 2007. http://hdl.handle.net/10044/1/8352.

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Fonseca, Jose Luis Cardozo. "Plasma polymerisation of organosilanes." Thesis, Durham University, 1994. http://etheses.dur.ac.uk/10490/.

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Shooter, Andrew James. "Living free radical polymerisation." Thesis, University of Warwick, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263817.

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Snell, David John. "Ultrasonically assisted emulsion polymerisation." Thesis, University of Bath, 2002. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.760798.

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Smit, Madri. "Polymerisation of 1,5-hexadienes." Thesis, Stellenbosch : Stellenbosch University, 2001. http://hdl.handle.net/10019.1/52403.

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Thesis (MSc)--Stellenbosch University, 2001.
ENGLISH ABSTRACT: In this study, the feasibility of the non-conjugated 1,5-hexadiene as monomer in metallocene catalised cyclopolymerizations was considered. Homopolymers and copolymers with ethylene, propylene, 1-pentene, 1-hexene and 2-methyl-1,5- hexadiene as comonomers were synthesised in the presence of Cp2ZrCh and rac-Et(lnd)2Zrh. The microstructure (stereoregularity and cyclisation) and number-average molecular weight were determined from NMR analysis. Crystalline oligomers with functional (eg -OH) and vinylidene end groups were obtained.
AFRIKAANSE OPSOMMING: Die studie behels die ondersoek rakende die gebruik van ongekonjugeerde 1,5- heksadieen as monomeer in metalloseengekataliseerde polimerisasies. Homopolimere, sowel as kopolimere van etlieen, propileen, 1-penteen, 1- hekseen en 2-metiel-1,5-heksadieen, is in die teenwoordigheid van Cp2ZrChen rac-Et(lnd)2ZrCI2 gepolimeriseer. Die mikrostruktuur (stereochemie en siklisering) en die getal-gemiddelde molekulêre gewig van die gesintetiseerde polimere is met behulp van KMR spektroskopie ondersoek. Die studie het getoon dat kristallyne oligomere met funksionele (bv -OH) en vinilideen endgroepe gesintetiseer is.

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Alger, Luke. "Dispersion polymerisation of divinylbenzene." Thesis, Loughborough University, 2004. https://dspace.lboro.ac.uk/2134/34134.

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Particles containing 55% divinylbenzene (DVB) have been prepared using dispersion polymerisation. The steric stabilisers that have been utilised are partially hydrolysed poly(vinyl acetate)s, poly(ethylene oxide) and a poly(ethylene oxide) macromonomer in methanolic media. The concentrations of stabiliser, monomer and initiator have been varied to investigate the influence that they have on the particle size and the particle size distribution. The particles have been characterised by scanning electron microscopy (SEM) for a visual impression of the particles in addition to laser diffraction particle size analysis and hydrodynamic chromatography (HDC) for particle size.

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Walton, Mark. "New pre-catalysts for olefin polymerisation and ring-opening polymerisation of lactides/lactones." Thesis, University of East Anglia, 2014. https://ueaeprints.uea.ac.uk/50548/.

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A number of pre-catalysts featuring phenoxyimine, phenolate and calixarene ligand systems have been synthesized, characterised and screened for their ability to polymerize α-olefins or ring open polymerize (ROP) cyclic esters. The treatment of a number of related phenoxyimine ligands (L1H – L3H, L6H – L14H) and bridged phenoxyimines (L4H2 and L5H2) with vanadium trichloride (VCl3), vanadium oxytrichloride (VOCl3) or vanadium oxytripropoxide (VO(OnPr)3) afforded the compounds 1 – 20. Compounds 21, 22 and 23 were isolated from the reaction between VO(OnPr)3 and diphenolate ligand (L15H2) or bridged diphenolates (L16H4 or L17H4) respectively. Treatment of the alkali vanadium compound (LiVO(OtBu)4) with tert-butylcalix[6]arene (L18H6) afforded compound 24, while on a number of syntheses, the minor 1D polymeric compound 25 was also obtained. Whilst the reaction between tert-butylcalix[8]arene (L19H8) and NaVO(OtBu)4 led to the formation of compound 26, the use of the alkali free VO(OtBu)3 resulted in the formation of two solvates of compound 27. Imidazole (L20H), oxazole (L21H), α-diimine (L22), iminopyridine (L23, L24) and phenoxyimine (L25H – L29H) ligand sets have been treated with group 5 (Nb or Ta) chlorides or oxytrichlorides to afford compounds 28 – 50, which have been fully characterised. The screening of group 5 compounds 1 – 50 for the polymerisation of α-olefins revealed high activity, significantly in the case of the niobium precatalysts which were two orders of magnitude above the previously reported compounds. The reactions between 1,3-dipropoxy-p-tert-butyl-calix[4]arene (L30H2), hexahomotrioxacalix[3]arene (L31H3) or tripropoxy-p-tert-butylcalix[4]arene (L32H) with zinc or magnesium alkyls has been explored, resulting in the isolation of compounds 51 – 58, which includes a number of heterobimetallic compounds. While all of the zinc and magnesium compounds screened were found to be active for the ring opening polymerisation of either ε-caprolactone or rac-lactide, compound 58, featuring a tripropoxy-p-tert-butylcalix[4]arene (L32H) ligand with a magnesium n-butyl group was found to exhibit exceptional activity and immortal character.

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Laryea, Esther [Verfasser]. "Einfluss der Fluiddynamik auf Polymerisationen am Beispiel der freien radikalischen Polymerisation von Methylmethacrylat / Esther Laryea." München : Verlag Dr. Hut, 2020. http://d-nb.info/1219471089/34.

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Books on the topic "Polymerisation"

1

Palmans, Anja R. A., and Andreas Heise, eds. Enzymatic Polymerisation. Berlin, Heidelberg: Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-16376-0.

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Andreas, Heise, and SpringerLink (Online service), eds. Enzymatic Polymerisation. Berlin, Heidelberg: Springer-Verlag Berlin Heidelberg, 2011.

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3

Capek, I., J. Hernfández-Barajas, D. Hunkeler, J. L. Reddinger, J. R. Reynolds, and C. Wandrey, eds. Radical Polymerisation Polyelectrolytes. Berlin, Heidelberg: Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/3-540-70733-6.

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Ignác, Capek, ed. Radical polymerisation, polyelectrolytes. Berlin: Springer, 1999.

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Dove, Andrew, Haritz Sardon, and Stefan Naumann, eds. Organic Catalysis for Polymerisation. Cambridge: Royal Society of Chemistry, 2018. http://dx.doi.org/10.1039/9781788015738.

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6

Shooter, Andrew James. Living free radical polymerisation. [s.l.]: typescript, 1997.

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Orpin, M. R. Ethylene-propylene-diene polymerisation studies. Manchester: UMIST, 1993.

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H, Solomon D., and Moad Graeme, eds. The chemistry of radical polymerisation. 2nd ed. Boston: Elsevier, 2006.

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9

Connor, Eric. Palladium catalysed polymerisation of polycyclic and five-membered ring monocyclic olefins. Dublin: University College Dublin, 1997.

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van Herk, A. M., ed. Chemistry and Technology of Emulsion Polymerisation. Oxford, UK: John Wiley & Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118638521.

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Book chapters on the topic "Polymerisation"

1

Bährle-Rapp, Marina. "Polymerisation." In Springer Lexikon Kosmetik und Körperpflege, 439. Berlin, Heidelberg: Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/978-3-540-71095-0_8186.

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Koltzenburg, Sebastian, Michael Maskos, and Oskar Nuyken. "Ionische Polymerisation." In Polymere: Synthese, Eigenschaften und Anwendungen, 259–310. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-34773-3_10.

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Koltzenburg, Sebastian, Michael Maskos, and Oskar Nuyken. "Katalytische Polymerisation." In Polymere: Synthese, Eigenschaften und Anwendungen, 311–39. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-34773-3_11.

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Koltzenburg, Sebastian, Michael Maskos, and Oskar Nuyken. "Ringöffnende Polymerisation." In Polymere: Synthese, Eigenschaften und Anwendungen, 341–66. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-34773-3_12.

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Koltzenburg, Sebastian, Michael Maskos, and Oskar Nuyken. "Radikalische Polymerisation." In Polymere: Synthese, Eigenschaften und Anwendungen, 217–58. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-34773-3_9.

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Kaminsky, W. "Polymerisation Catalysis." In Basic Principles in Applied Catalysis, 403–40. Berlin, Heidelberg: Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-662-05981-4_11.

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van Herk, A. M., and R. G. Gilbert. "Emulsion Polymerisation." In Chemistry and Technology of Emulsion Polymerisation, 43–73. Oxford, UK: John Wiley & Sons Ltd, 2013. http://dx.doi.org/10.1002/9781118638521.ch3.

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Divakar, Soundar. "Enzymatic Polymerisation." In Enzymatic Transformation, 65–79. India: Springer India, 2012. http://dx.doi.org/10.1007/978-81-322-0873-0_5.

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Koltzenburg, Sebastian, Michael Maskos, and Oskar Nuyken. "Katalytische Polymerisation." In Polymere: Synthese, Eigenschaften und Anwendungen, 335–66. Berlin, Heidelberg: Springer Berlin Heidelberg, 2024. http://dx.doi.org/10.1007/978-3-662-64601-4_11.

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Koltzenburg, Sebastian, Michael Maskos, and Oskar Nuyken. "Ringöffnende Polymerisation." In Polymere: Synthese, Eigenschaften und Anwendungen, 367–93. Berlin, Heidelberg: Springer Berlin Heidelberg, 2024. http://dx.doi.org/10.1007/978-3-662-64601-4_12.

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Conference papers on the topic "Polymerisation"

1

Armes, Steven. "Polymerisation-induced Self-assembly." In University of Sheffield Engineering Symposium. USES, 2015. http://dx.doi.org/10.15445/01022014.14.

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Spanos, Ioannis, Vasileia Melissinaki, and Maria Farsari. "3D Auxetic Metamaterials Made using Multiphoton Polymerisation." In 2019 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC). IEEE, 2019. http://dx.doi.org/10.1109/cleoe-eqec.2019.8872806.

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Wang, X. W., and S. Juodkazis. "Surface patterning by laser ablation and polymerisation." In 2016 Progress in Electromagnetic Research Symposium (PIERS). IEEE, 2016. http://dx.doi.org/10.1109/piers.2016.7735002.

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Lightbody, G. "Neural network modelling of a polymerisation reactor." In International Conference on Control '94. IEE, 1994. http://dx.doi.org/10.1049/cp:19940138.

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Margadonna, S., C. M. Brown, A. Lappas, K. Kordatos, K. Tanigaki, and K. Prassides. "Fulleride polymerisation at ambient and elevated pressure." In The 12th international winterschool on electronic properties of novel materials: progress in molecular nanostructures. AIP, 1998. http://dx.doi.org/10.1063/1.56470.

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Yuan, Peng, Qingsong Zhao, Xiaoheng Zhang, Xintong Ma, Jifeng Cheng, Kang Ren, and Run Ma. "A Study of Heterogeneous Load Polymerisation Methods." In 2023 4th International Conference on Smart Grid and Energy Engineering (SGEE). IEEE, 2023. http://dx.doi.org/10.1109/sgee60678.2023.10481710.

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Badyal, J. P. S. "Controlled plasmachemical deposition of polymeric coatings." In IEE Seminar Plasma Polymerisation - Processing for the Future. IEE, 1999. http://dx.doi.org/10.1049/ic:19990158.

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Neuville, S. "IEE conference Savoy Place 16.02.99." In IEE Seminar Plasma Polymerisation - Processing for the Future. IEE, 1999. http://dx.doi.org/10.1049/ic:19990159.

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Zeuner, M. "Process diagnostics in magnetron sputtering of polytetrafluorethylene (PTFE)." In IEE Seminar Plasma Polymerisation - Processing for the Future. IEE, 1999. http://dx.doi.org/10.1049/ic:19990160.

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Wilson, J. I. B. "Optimisation of plasma polymers for hydrophobic coatings." In IEE Seminar Plasma Polymerisation - Processing for the Future. IEE, 1999. http://dx.doi.org/10.1049/ic:19990161.

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