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Books on the topic 'Polyaniline'

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Author: Grafiati

Published: 4 June 2021

Last updated: 22 June 2024

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1

United States. National Aeronautics and Space Administration., ed. New anti-corrosive coatings with resin-bonded polyaniline and related electroactive groups: Final report, grant no. NAG10-0174. [Washington, DC: National Aeronautics and Space Administration, 1997.

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2

United States. National Aeronautics and Space Administration., ed. New anti-corrosive coatings with resin-bonded polyaniline and related electroactive groups: Final report, grant no. NAG10-0174. [Washington, DC: National Aeronautics and Space Administration, 1997.

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3

United States. National Aeronautics and Space Administration., ed. New anti-corrosive coatings with resin-bonded polyaniline and related electroactive groups: Final report, grant no. NAG10-0174. [Washington, DC: National Aeronautics and Space Administration, 1997.

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4

Rahman, Aminur, Al-Nakib Chowdhury, Takeo Ohsaka, and Mominul Islam. Trends in Polyaniline Research. Nova Science Publishers, Incorporated, 2013.

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5

Polyaniline Blends, Composites, and Nanocomposites. Elsevier, 2018. http://dx.doi.org/10.1016/c2015-0-06537-6.

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6

Visakh, P. M., Cristina Della Pina, and Ermelinda Falletta. Polyaniline Blends, Composites, and Nanocomposites. Elsevier Science & Technology Books, 2017.

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7

Pina, Cristina Della, and Ermelinda Falletta. Polyaniline: From Tradition to Innovation. Nova Science Publishers, Incorporated, 2014.

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8

Visakh, P. M., Cristina Della Pina, and Ermelinda Falletta. Polyaniline Blends, Composites, and Nanocomposites. Elsevier, 2017.

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9

Mozafari, Masoud, and Narendra Pal Singh Chauhan. Fundamentals and Emerging Applications of Polyaniline. Elsevier, 2019.

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10

Panigrahi, Muktikanta, and Arpan Kumar Nayak. Polyaniline based Composite for Gas Sensors. IOR PRESS, 2021. http://dx.doi.org/10.34256/ioriip212.

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In this research work, we have demonstrated the synthesis, spectroscopic characteristics, thermal behaviour and DC conductivity of a few nanostructured composites, substituted conducting polymers (ICPs) and composites of ICPs. The physical properties of aforementioned composites are significantly changed by the doping with HCl, H2SO4, HNO3, H3PO4, or acrylic acid. The charge transport properties of these polymeric materials have been studied in detail because of their potential application in gas sensors. In the current work, varieties of conducting polymer based materials such as PANI-ES/Cloisite 20A nanostructured composite, acrylic acid (AA) doped PANI polymer, N-substituted conducting polyaniline polymer, DL−PLA/PANI-ES composites, poly methyl methacrylate (PMMA) based polyaniline composite, and inorganic acid doped polyaniline are sucessfuly synthesized using aniline/aniline hydrochloride as precursors in acidic medium. Particularly, AA based synthesised PANI polymer was found with higher solubility The spectroscopic, thermal stability, enthalpy of fusion, room temperature DC conductivity and temperature dependent DC conductivity measurements with and without magnetic was carried out with as-synthesized materials. The FTR/ATR−FTIR spectra indicated the presence of different functional groups in the as-prepared composite materials. The UV−Visible absorption spectroscopic analysis showed the presence of polaron band suggesting PANI-ES form. The Room temperature DC conductivity, temperature variation DC conductivity (in presence and absence of magnetic field), and magnetoresistance (MR) of as-prepared conducting polyaniline based were analysed. The highest room temperature DC conductivity value was obtained from H2SO4 doped based composite materials and all prepared conductive composites were followed ohms law. The low temperature DC conductivity was carried out in order to study the semiconducting nature of prepared materials. The Mott type VRH model was found to be well fitted the conductivity data and described the density of states at the Fermi level which is constant in this temperature range. From MR plots, a negative MR was observed, which described the quantum interference effect on hopping conduction. We discuss different gas analytes i.e., NO2, LPG, H2, NH3, CH4, and CO of conducting polymer based materials.

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11

Fundamentals and Emerging Applications of Polyaniline. Elsevier, 2019. http://dx.doi.org/10.1016/c2018-0-02707-3.

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12

Roy, Aashish. Hybrid Polyaniline Nanocomposite For Humidity Sensing. Lulu.com, 2018.

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13

Fundamentals and Emerging Applications of Polyaniline. Elsevier, 2019.

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14

Zaikov, G. E., and Oleksandr Reshetnyak. Computational and Experimental Analysis of Functional Materials. Taylor & Francis Group, 2021.

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15

Reshetnyak, Oleksandr V., and Gennady E. Zaikov. Computational and Experimental Analysis of Functional Materials. Apple Academic Press, Incorporated, 2017.

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16

Reshetnyak, Oleksandr V., and Gennady E. Zaikov. Computational and Experimental Analysis of Functional Materials. Apple Academic Press, Incorporated, 2017.

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17

Polyaniline - From Synthesis to Practical Applications [Working Title]. IntechOpen, 2018. http://dx.doi.org/10.5772/intechopen.76274.

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18

Undoped polyaniline/surfactant complex for the corrosion prevention. [Washington, DC: National Aeronautics and Space Administration, 1998.

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19

National Aeronautics and Space Administration (NASA) Staff. Undoped Polyaniline/Surfactant Complex for the Corrosion Prevention. Independently Published, 2018.

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20

Chander, Subhash, and Nirmala Kumari Jangid. Properties, Techniques, and Applications of Polyaniline Thin Films: Emerging Research and Opportunities. IGI Global, 2020.

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21

Chander, Subhash, and Nirmala Kumari Jangid. Properties, Techniques, and Applications of Polyaniline Thin Films: Emerging Research and Opportunities. IGI Global, 2020.

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22

Chander, Subhash, and Nirmala K. Jangid. Properties, Techniques, and Applications of Polyaniline Thin Films: Emerging Research and Opportunities. IGI Global, 2020.

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23

Chander, Subhash, and Nirmala Kumari Jangid. Properties, Techniques, and Applications of Polyaniline Thin Films: Emerging Research and Opportunities. IGI Global, 2020.

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24

Chander, Subhash, and Nirmala Kumari Jangid. Properties, Techniques, and Applications of Polyaniline Thin Films: Emerging Research and Opportunities. IGI Global, 2020.

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25

Gasparac, Rahela. New membrane technologies--nanotube membranes for biotechnological applications and polyaniline films for corrosion inhibition. 2003.

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26

New anti-corrosive coatings with resin-bonded polyaniline and related electroactive groups: Final report, grant no. NAG10-0174. [Washington, DC: National Aeronautics and Space Administration, 1997.

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27

Araújo, Ana Cláudia Vaz de. Síntese de nanopartículas de óxido de ferro e nanocompósitos com polianilina. Brazil Publishing, 2021. http://dx.doi.org/10.31012/978-65-5861-120-2.

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Abstract:

In this work magnetic Fe3O4 nanoparticles were synthesized through the precipitation method from an aqueous ferrous sulfate solution under ultrasound. A 23 factorial design in duplicate was carried out to determine the best synthesis conditions and to obtain the smallest crystallite sizes. Selected conditions were ultrasound frequency of 593 kHz for 40 min in 1.0 mol L-1 NaOH medium. Average crystallite sizes were of the order of 25 nm. The phase obtained was identified by X-ray diffractometry (XRD) as magnetite. Scanning electron microscopy (SEM) showed polydisperse particles with dimensions around 57 nm, while transmission electron microscopy (TEM) revealed average particle diameters around 29 nm, in the same order of magnitude of the crystallite size determined with Scherrer’s equation. These magnetic nanoparticles were used to obtain nanocomposites with polyaniline (PAni). The material was prepared under exposure to ultraviolet light (UV) or under heating, from dispersions of the nanoparticles in an acidic solution of aniline. Unlike other synthetic routes reported elsewhere, this new route does not utilize any additional oxidizing agent. XRD analysis showed the appearance of a second crystalline phase in all the PAni-Fe3O4 composites, which was indexed as goethite. Furthermore, the crystallite size decreases nearly 50 % with the increase in the synthesis time. This size decrease suggests that the nanoparticles are consumed during the synthesis. Thermogravimetric analysis showed that the amount of polyaniline increases with synthesis time. The nanocomposite electric conductivity was around 10-5 S cm-1, nearly one order of magnitude higher than for pure magnetite. Conductivity varied with the amount of PAni in the system, suggesting that the electric properties of the nanocomposites can be tuned according to their composition. Under an external magnetic field the nanocomposites showed hysteresis behavior at room temperature, characteristic of ferromagnetic materials. Saturation magnetization (MS) for pure magnetite was ~ 74 emu g-1. For the PAni-Fe3O4 nanocomposites, MS ranged from ~ 2 to 70 emu g-1, depending on the synthesis conditions. This suggests that composition can also be used to control the magnetic properties of the material.

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