Relevant bibliographies by topics / Poly(vinyl methyl ether) Blend

Academic literature on the topic 'Poly(vinyl methyl ether) Blend'

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Published: 6 September 2023

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Journal articles on the topic "Poly(vinyl methyl ether) Blend"

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Kuang, Chen, Sahar Qavi, and Reza Foudazi. "Double-stage phase separation in dynamically asymmetric ternary polymer blends." RSC Advances 6, no. 94 (2016): 92104–14. http://dx.doi.org/10.1039/c6ra17274a.

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In this work, the phase separation behavior of ternary blends of polystyrene/poly(vinyl methyl ether)/polyisoprene, PS/PVME/PI, and polystyrene/poly(vinyl methyl ether)/poly(ethyl methacrylate), PS/PVME/PEMA are investigated.
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Peng, Yong-jin, Yu-ling Liu, Jun-hua Hao, Rong-chun Zhang, and Ping-chuan Sun. "Phase structure and dynamics of polystyrene/poly(vinyl methyl ether) blend studied using solid-state NMR." RSC Advances 7, no. 89 (2017): 56311–16. http://dx.doi.org/10.1039/c7ra12287j.

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In this work, solid-state 1H NMR experiments were conducted to fully characterize the dynamic characteristics of a polystyrene/poly(vinyl methyl ether) blend with a mass ratio of 3 : 1 (PS/PVME 75/25).
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El-Mabrouk, Khalil, Sébastien Vaudreuil, Abderrahim Zeghloul, and Mosto Bousmina. "Effect of Shear on Phase-Separation in Polystyrene/Poly(vinyl methyl ether)/Organoclay Nanocomposites." Journal of Nanoscience and Nanotechnology 8, no. 4 (April 1, 2008): 1895–900. http://dx.doi.org/10.1166/jnn.2008.0191895.

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Blends of polystyrene (PS)/poly(vinyl methyl ether) (PVME) modified with two types of organoclay were prepared by solution casting from toluene. The effect of clay addition on the phase separating morphology of PS/PVME blend with critical composition (25/75) was examined both under quiescent conditions and under shear flow. The variation in critical temperature of phase separation was assessed by rheology, small angle laser light scattering (SALLS) and by on-line laser light transmission during shearing at fixed shear rate during heating. Transmission electron microscopy and X-ray diffraction analyses were used to examine the state of delamination and distribution of clay nanoparticles with the blend matrix.
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Gestoso, Patricia, and Josée Brisson. "Orientation of uniaxially stretched poly(vinyl phenol)/poly(vinyl methyl ether) blends." Polymer 42, no. 20 (September 2001): 8415–24. http://dx.doi.org/10.1016/s0032-3861(01)00355-x.

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Green, Peter F., Douglas B. Adolf, and Laura R. Gilliom. "Dynamics of polystyrene/poly(vinyl methyl ether) blends." Macromolecules 24, no. 11 (May 1991): 3377–82. http://dx.doi.org/10.1021/ma00011a052.

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Ogawa, Hiroki, Toshiji Kanaya, Koji Nshida, and Go Matsuba. "Composition fluctuations before dewetting in polystyrene/poly(vinyl methyl ether) blend thin films." Polymer 49, no. 10 (May 2008): 2553–59. http://dx.doi.org/10.1016/j.polymer.2008.03.034.

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Chakraborty, S. S., N. Maiti, B. M. Mandal, and S. N. Bhattacharyya. "Miscibility and phase diagrams for poly(vinyl methyl ether) and polyacrylate blend systems." Polymer 34, no. 1 (January 1993): 111–14. http://dx.doi.org/10.1016/0032-3861(93)90291-h.

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Tezuka, Akinori, K. Takegoshi, and Kunio Hikichi. "Solid state deuteron NMR study of a polystyrene/poly(vinyl methyl ether) blend." Journal of Molecular Structure 355, no. 1 (August 1995): 1–7. http://dx.doi.org/10.1016/0022-2860(95)08859-t.

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Tanaka, Keiji, Jeong-Sik Yoon, Atsushi Takahara, and Tisato Kajiyama. "Ultrathinning-Induced Surface Phase Separation of Polystyrene/Poly(vinyl methyl ether) Blend Film." Macromolecules 28, no. 4 (July 1995): 934–38. http://dx.doi.org/10.1021/ma00108a021.

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YANG, YULIANG, HONGDONG ZHANG, and FENG QIU. "STRAIN FIELD INDUCED ANISOTROPIC PHASE SEPARATION OF POLYMER BLENDS." International Journal of Modern Physics B 17, no. 01n02 (January 20, 2003): 77–82. http://dx.doi.org/10.1142/s0217979203017114.

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Using a small angle light scattering (SALS) technique, we investigated the anisotropic SALS patterns formed in a phase separating polystyrene (PS) and poly (vinyl methyl ether) (PVME) blend under strain fields. We have found that, in addition to the interfacial relaxations, the stretching of the polymer chains plays an important role in the phase separation of the PS/PVME blend under a strain field. Two novel scattering patterns and the strain induced slowing down of the phase separation dynamics are observed. The experimental results are compared to a theoretical calculation based on a time-dependent Ginzburg-Landau equation incorporated with the chain stretching effect.
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Dissertations / Theses on the topic "Poly(vinyl methyl ether) Blend"

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Pietri, Valerie. "Electron beam irradiation of polystyrene/poly(vinyl methyl ether) blends." Thesis, This resource online, 1993. http://scholar.lib.vt.edu/theses/available/etd-07292009-090349/.

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Gestoso, Souto Patricia. "Orientation study of poly(vinyl phenol)/poly(vinyl methyl ether) blends by infrared dichroism and molecular dynamics." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp05/NQ65420.pdf.

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Souza, Ligia Elene [Verfasser]. "Poly(vinyl methyl ether-alt-maleic anhydride) based nanoparticles and nanocapsules : formulation and characterization / Ligia Elene Souza." Halle, 2017. http://d-nb.info/1155173295/34.

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Goetz, Lee Ann. "Preparation and analysis of crosslinked lignocellulosic fibers and cellulose nanowhiskers with poly(methyl-vinyl ether co maleic acid) â " polyethylene glycol to create novel water absorbing materials." Diss., Georgia Institute of Technology, 2012. http://hdl.handle.net/1853/45893.

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The search for cellulosic based products as a viable alternative for petroleum-based products was the impetus for covalently crosslinking lignocellulosic fibers and nanocellulose whiskers with poly(methyl vinyl ether) co maleic acid (PMVEMA) - polyethylene glycol (PEG). The lignocellulosics used were ECF bleached softwood (pine) and ECF bleached birch kraft pulp. This thesis also tests the hypothesis that water absorption and retention can be improved by grafting PMVEMA-PEG to the surface of ECF bleached kraft pulp hardwood and softwood fibers via microwave initiated crosslinking. The crosslinking of the PMVEMA to hardwood and softwood kraft ECF bleached pulp fibers resulted in enhanced water absorbing pulp fibers where the PMVEMA is grafted onto the surface of the fibers. The crosslinking was initiated both thermally and via microwave irradiation and the water absorption and water retention was measured as the percent of grafted PMVEMA. This was the first application of microwave crosslinking of pulp fibers with the goal of creating water absorbing pulp fibers. Ultimately, the water absorption values ranged from 28.70 g water per g dry crosslinked pulp fiber (g/g) to 230.10 g/g and the water retention values ranged from 26% to 71% of the water retained that was absorbed by the crosslinked pulp fibers. The microwave initiated crosslinked fibers had comparable results to the thermally crosslinked fibers with a decreased reaction time, from 6.50 min (thermal) to 1 min 45 sec (microwave). Cellulose nanowhiskers, crystalline rods of cellulose, have been investigated due to their unique properties, such as nanoscale dimensions, low density, high surface area, mechanical strength, and surface morphology and available surface chemistry. Prior to this study, the crosslinking of cellulose whiskers with the matrix via solution casting of liquid suspensions of whiskers and matrix had not been explored. The hypothesis to be investigated was that incorporating cellulosic whiskers with the PMVEMA-PEG matrix and crosslinking the whiskers with the matrix would yield films that demonstrate unique properties when compared to prior work of crosslinking of PMVEMA-PEG to macroscopic ECF bleached kraft pulp fibers. Solution cast composites of cellulose nanowhiskers-PMVEMA-PEG were crosslinked at 135 °C for 6.5 min and analyzed for crosslinking, thermal stability, strength and mechanical properties, whisker dispersion, and water absorption and uptake rates. The whisker-composites demonstrated unique properties upon crosslinking the whiskers with PMVEMA-PEG, especially the elongation at break and tensile strength upon conditioning of the final materials at various relative humidities. In addition, the whiskers improved the thermal stability of the PMVEMA-PEG matrix. This is significant as methods of improving processing thermal stability are key to developing new materials that utilize cellulose whiskers, PMVEMA, and PEG. This thesis addresses the hypothesis that cellulose nanowhiskers that are crosslinked with a matrix can create new whisker-matrix composites that behave differently after crosslinking.
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YANG, XIAN-WEI, and 楊顯威. "The nuclear magnetic resonance studies of the miscibility of polystyrene/poly (vinyl methyl ether) blend." Thesis, 1990. http://ndltd.ncl.edu.tw/handle/98067088709894671623.

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MAO, Yung-jen, and 毛勇仁. "Phase Behavior and Miscibility in a Ternary Blend System Comprising Polycaprolactone, Poly(benzyl methacrylate) and Poly(vinyl methyl ether)." Thesis, 2000. http://ndltd.ncl.edu.tw/handle/15644801075846606593.

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碩士
國立成功大學
化學工程學系
88
Phase behavior and miscibility of a ternary polymer blend comprising polycaprolactone (PCL), poly(benzyl methacrylate) (PBzMA) and poly(vinyl methyl ether) (PVME) was investigated by polarizing optical microscopy (POM), scanning electron microscopy (SEM), differential scanning calorimeter (DSC) and Fourier-transform infrared spectroscopy (FTIR). Each composition of the ternary mixture forms a miscible blend with a homogeneous phase structure. The ternary blend system exhibits lower critical solution temperature (LCST) behavior through optical observation for phase separation on heating. The existence of a single Tg in each blend also indicates that the ternary blend system is miscible according to the conventional standard of glass transition. Nevertheless, widening of the thermal transition breadth was obvious and contingent upon blend composition suggesting that miscellaneous scales of molecular aggregation. The FTIR result shows that the intermolecular interactions were weak and not specific
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Jiang, Z., Y. Wang, L. Fu, Benjamin R. Whiteside, John Wyborn, Keith Norris, Z. Wu, Philip D. Coates, and Y. Men. "Tensile Deformation of Oriented Poly(ε-caprolactone) and Its Miscible Blends with Poly(vinyl methyl ether)." 2013. http://hdl.handle.net/10454/6037.

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The structural evolution of micromolded poly(ε-caprolactone) (PCL) and its miscible blends with noncrystallizable poly(vinyl methyl ether) (PVME) at the nanoscale was investigated as a function of deformation ratio and blend composition using in situ synchrotron smallangle X-ray scattering (SAXS) and scanning SAXS techniques. It was found that the deformation mechanism of the oriented samples shows a general scheme for the process of tensile deformation: crystal block slips within the lamellae occur at small deformations followed by a stressinduced fragmentation and recrystallization process along the drawing direction at a critical strain where the average thickness of the crystalline lamellae remains essentially constant during stretching. The value of the critical strain depends on the amount of the amorphous component incorporated in the blends, which could be traced back to the lower modulus of the entangled amorphous phase and, therefore, the reduced network stress acting on the crystallites upon addition of PVME. When stretching beyond the critical strain the slippage of the fibrils (stacks of newly formed lamellae) past each other takes place resulting in a relaxation of stretched interlamellar amorphous chains. Because of deformation-induced introduction of the amorphous PVME into the interfibrillar regions in the highly oriented blends, the interactions between fibrils becomes stronger upon further deformation and thus impeding sliding of the fibrils to some extent leading finally to less contraction of the interlamellar amorphous layers compared to the pure PCL
National Natural Science Foundation of China (21204088 and 21134006). This work is within the framework of the RCUK/EPSRC Science Bridges China project of UK−China Advanced Materials Research Institute (AMRI).
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Chiang, Wan-Jing, and 蔣宛菁. "Effects of Poly(vinyl methyl ether) on Phase Morphology in Blends Comprising Biodegradable Polyesters." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/77926870645651589616.

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碩士
國立成功大學
化學工程學系碩博士班
95
Various phase behavior of blends of poly(vinyl methyl ether) (PVME) with a series of polyesters with different ratios of aliphatic carbons to ester groups were examined using differential scanning calorimetry (DSC) and optical microscopy (OM). Effects of varying the main-chain polarity of the constituent polyesters on the phase behavior of the blends were analyzed. Miscibility in PVME/polyester blends were found only in polyesters with backbone CH2/CO ratio = 3.5 to 7.0. Tg-composition relationships for blends of PVME with highly crystalline polyesters (PBA, PHA, PCL, PHS) were found to differ significantly from those for PVME blends with less-crystalline polyesters (PTA, PEAz). Crystallinity of highly-crystalline polyester constituents in blends caused significant asymmetry in the Tg-composition relationships, and induced positive deviation of blends’ Tg above linearity; on the other hand, blends of PVME with less crystalline polyesters exhibit typical Fox or Gordon-Taylor types of relationships. The interaction parameters for the miscible blends were found to range from -0.17 to -0.33, reflecting generally weak interactions. Phase behavior was analyzed and compared among blends of PVME with rapidly-crystallizing vs. less-crystallizing polyesters, respectively. Effects of polyesters’ crystallinity and structures on phase behavior of PVME/polyester blends are discussed. As analogous polyester to PCL, PHA (with the same CH2/CO ratio) was used for comparison purpose; however, PHA has a stronger tendency for crystallization than PCL. Both PVME/PCL and PVME/PHA blends were proven to be miscible with weak and non-specific interactions, which is typical in blends involving ether-containing and carboxyl-containing polymers. Difference in spherulite ring-band patterns between neat PCL, neat PHA and miscible blends was probed to correlate with growth regimes. Spherulite growth in thin-film forms and transformation of spherulite patterns in different regimes were investigated. For neat PCL, in transition from regime III to regime II, the spherulites are patterned in ring-less to ring-banded types, respectively, in different regimes. For the PVME/PCL (20/80) blend, ring bands in spherulites are easily seen in Regime-III, but ring bands disappear in Regime-II. For neat PHA, in transition from regime II to regime I, the spherulites are patterned in ring-banded to ring-less types. For the PVME/PHA (20/80) blend, ring bands in spherulites are easily seen only in crystallization from Tc=40 ~ 42oC (Regime-II), but ring bands disappear in crystallization from Tc=30 ~ 38oC (Regime-II) and Tc=46 ~ 50oC (Regime-I).
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Valiquette, Dominic. "Électrofilage de fibres à partir de mélanges polystyrène/poly(vinyl méthyl éther)." Thèse, 2009. http://hdl.handle.net/1866/3607.

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L’électrofilage est un procédé permettant de préparer des fibres possédant un diamètre de l’ordre du micromètre ou de quelques centaines de nanomètres. Son utilisation est toutefois limitée par le manque de contrôle sur la structure et les propriétés des fibres ainsi produites. Dans ce travail, des fibres électrofilées à partir de mélanges de polystyrène (PS) et de poly(vinyl méthyl éther) (PVME) ont été caractérisées. La calorimétrie différentielle à balayage (DSC) a montré que les fibres du mélange PS/PVME sont miscibles (une seule transition vitreuse) lorsque préparées dans le benzène, alors qu'une séparation de phases a lieu lorsque le chloroforme est utilisé. Les fibres immiscibles sont néanmoins malléables, contrairement à un film préparé par évaporation du chloroforme qui a des propriétés mécaniques médiocres. Des clichés en microscopies optique et électronique à balayage (MEB) ont permis d’étudier l'effet de la composition et du solvant sur le diamètre et la morphologie des fibres. Des mesures d’angles de contact ont permis d’évaluer l’hydrophobicité des fibres, qui diminue avec l’ajout de PVME (hydrophile); les valeurs sont de 60° supérieures à celles des films de composition équivalente. Un retrait sélectif du PVME a été réalisé par l’immersion des fibres dans l’eau. La spectroscopie infrarouge a montré que la composition passe de 70 à 95% de PS pour une fibre immiscible mais seulement à 75% pour une fibre miscible. Ces résultats indiquent que la phase riche en PVME se situe presque uniquement à la surface des fibres immiscibles, ce qui a été confirmé par microscopie à force atomique (AFM) et MEB. Finalement, l’effet du mélange des deux solvants, lors de l’électrofilage du mélange PS/PVME, a été étudié. La présence du chloroforme, même en quantité réduite, provoque une séparation de phases similaire à celle observée avec ce solvant pur.
Electrospinning is a simple method for the preparation of polymer fibers with diameters of hundreds of nanometers to a few micrometers. Although it is a versatile method, some issues remain in the control of the structure and properties of electrospun fibers. In this study, fibers electrospun from polystyrene (PS)/poly(vinyl methyl ether) (PVME) blends were characterized. Differential scanning calorimetry (DSC) revealed that fibers electrospun from benzene are miscible while a phase separation occurs when the fibers are electrospun from chloroform. While films cast from chloroform show poor mechanical properties, immiscible fibers are ductile. The effects of the blend composition and the solvent on the fiber diameter and morphology were observed by scanning electron microscopy (SEM) and optical microscopy. Afterwards, contact angle measurements were made to evaluate the hydrophobicity of the fibers which decreases as hydrophilic PVME is added to the blend; the values for the fibers were found to be 60° higher than their equivalent in films. PVME was selectively removed from the immiscible fibers by complete immersion into water. Infrared spectroscopy revealed that this process increases the PS content from 70 to 95% for immiscible fibers but only to 75% for miscible fibers. These results show that the PVME-rich phase is almost completely distributed on the fiber surface, which was confirmed by atomic force microscopy (AFM) and SEM. Finally, the electrospinning of PS/PVME blends from chloroform/benzene solutions was studied. The presence of chloroform, even as a residual amount, causes a phase separation just as it does in fibers electrospun from pure chloroform.
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Chang, Hui-Yi, and 張慧怡. "Using 2-propanol and water to prepare hydrophobic poly(methyl methacrylate)/poly(vinyl acetate) blend submicron fibers by electrospinning." Thesis, 2019. http://ndltd.ncl.edu.tw/handle/7uv5vj.

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碩士
淡江大學
化學工程與材料工程學系碩士班
107
In this study, it was adopted rubbing alcohol (2-propanol/water) as the solvent to prepare poly(methyl methacrylate) (PMMA) submicron fibers and PMMA/poly(vinyl acetate) (PVAc) blend submicron fibers by the electrospinning technique. The solvents commonly used to dissolve PMMA, such as acetone, tetrahydrofuran, chloroform, toluene, etc., are harmful and environmentally unfriendly. Therefore, the green and economical co-solvent system, 2-propanol + water, were employed. It was found that both PMMA and PMMA/PVAc solutions can be electrospun near room temperature to yield good quality fibers. By controlling the solution concentration and spinning parameters (e.g., voltage, diameter of needle, solution conductivity, etc.) fibers with diameters of 0.5~3 μm were obtainable. In addition, both electrospun PMMA and PMMA/PVAc mats were waterproof and demonstrated superb hydrophobicity with contact angles > 130 °, and the later has higher strength in terms of bendability.
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Book chapters on the topic "Poly(vinyl methyl ether) Blend"

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Frank, Curtis W., and Richard Gelles. "Rotational Dyad Statistics and Energy Migration in Miscible and Immiscible Polystyrene/Poly(Vinyl Methyl Ether) Blends." In Photophysical and Photochemical Tools in Polymer Science, 561–88. Dordrecht: Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4726-9_25.

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Steiner, G., and C. Zimmerer. "Poly(vinyl methyl ether) (PVME)." In Polymer Solids and Polymer Melts – Definitions and Physical Properties I, 1073–79. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-32072-9_123.

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Takegoshi, K., and Kunio Hikichi. "High-Resolution Solid-State 13C NMR Study on Effects of Blending on Chain Dynamics in Polystyrene/Poly (Vinyl Methyl Ether) Blends." In 25th Congress Ampere on Magnetic Resonance and Related Phenomena, 351. Berlin, Heidelberg: Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-76072-3_182.

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Wohlfarth, Ch. "Solubility parameter of poly(vinyl methyl ether)." In Polymer Solutions, 1677. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_1028.

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Wohlfarth, Ch. "Partial specific volume of poly(vinyl methyl ether)." In Polymer Solutions, 533. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_307.

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Wohlfarth, Ch. "Second virial coefficient of poly(vinyl methyl ether)." In Polymer Solutions, 1241–42. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-02890-8_745.

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Wohlfarth, Ch. "Vapor-liquid equilibrium data of poly(vinyl methyl ether) in benzene." In Polymer Solutions, 2401–5. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-88057-8_481.

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Wohlfarth, Ch. "Vapor-liquid equilibrium data of poly(vinyl methyl ether) in chlorobenzene." In Polymer Solutions, 2406–10. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-88057-8_482.

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Wohlfarth, Ch. "Vapor-liquid equilibrium data of poly(vinyl methyl ether) in cyclohexane." In Polymer Solutions, 2411–15. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-88057-8_483.

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Wohlfarth, Ch. "Vapor-liquid equilibrium data of poly(vinyl methyl ether) in ethylbenzene." In Polymer Solutions, 2431–35. Berlin, Heidelberg: Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-88057-8_487.

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Reports on the topic "Poly(vinyl methyl ether) Blend"

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Bhatia, Q. S., D. H. Pan, and J. T. Koberstein. Preferential Surface Adsorption in Miscible Blends of Polystyrene and Poly(vinyl methyl ether). Fort Belvoir, VA: Defense Technical Information Center, February 1988. http://dx.doi.org/10.21236/ada191451.

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