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1
Hu, Bin, Ying Zhang, and Qi Jie Wang. "Surface magneto plasmons and their applications in the infrared frequencies." Nanophotonics 4, no. 4 (November 6, 2015): 383–96. http://dx.doi.org/10.1515/nanoph-2014-0026.
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Abstract Due to their promising properties, surface magneto plasmons have attracted great interests in the field of plasmonics recently. Apart from flexible modulation of the plasmonic properties by an external magnetic field, surface magneto plasmons also promise nonreciprocal effect and multi-bands of propagation, which can be applied into the design of integrated plasmonic devices for biosensing and telecommunication applications. In the visible frequencies, because it demands extremely strong magnetic fields for the manipulation of metallic plasmonic materials, nano-devices consisting of metals and magnetic materials based on surface magneto plasmon are difficult to be realized due to the challenges in device fabrication and high losses. In the infrared frequencies, highly-doped semiconductors can replace metals, owning to the lower incident wave frequencies and lower plasma frequencies. The required magnetic field is also low, which makes the tunable devices based on surface magneto plasmons more practically to be realized. Furthermore, a promising 2D material-graphene shows great potential in infrared magnetic plasmonics. In this paper, we review the magneto plasmonics in the infrared frequencies with a focus on device designs and applications. We investigate surface magneto plasmons propagating in different structures, including plane surface structures and slot waveguides. Based on the fundamental investigation and theoretical studies, we illustrate various magneto plasmonic micro/nano devices in the infrared, such as tunable waveguides, filters, and beam-splitters. Novel plasmonic devices such as one-way waveguides and broad-band waveguides are also introduced.
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Allami, Hassan, and Jacob J. Krich. "Lossless plasmons in highly mismatched alloys." Applied Physics Letters 120, no. 25 (June 20, 2022): 252102. http://dx.doi.org/10.1063/5.0095766.
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We explore the potential of highly mismatched alloys (HMAs) for realizing lossless plasmonics. Systems with a plasmon frequency at which there are no interband or intraband processes possible are called lossless, as there is no two-particle loss channel for the plasmon. We find that the band splitting in HMAs with a conduction band anticrossing guarantees a lossless frequency window. When such a material is doped, producing plasmonic behavior, we study the conditions required for the plasmon frequency to fall in the lossless window, realizing lossless plasmons. Considering a generic class of HMAs with a conduction band anticrossing, we find universal contours in their parameter space within which lossless plasmons are possible for some doping range. Our analysis shows that HMAs with heavy effective masses and small high-frequency permittivity are most promising for realizing a lossless plasmonic material.
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Moskovits, Martin. "Canada’s early contributions to plasmonics." Canadian Journal of Chemistry 97, no. 6 (June 2019): 483–87. http://dx.doi.org/10.1139/cjc-2018-0365.
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The field of plasmonics — the study of collective electron excitation in nanostructured metal and other conductors — is currently highly active with research foci in a number of related fields, including plasmon-enhanced spectroscopies and plasmon-mediated photochemical and photocatalytic processes through which the energy stored temporarily as plasmons can be used to enable and (or) accelerate photochemistry. This enhancement is accomplished either by the action of the large optical fields produced in the vicinity of plasmonic nanostructures or mediated by the energetic electrons and holes surviving transiently following the dephasing of the plasmon. This article traces the early contributions to the foundation of the current field of plasmonics by two scientists working in Canada in the early 1970s, J. P. Marton at McMaster University and Welwyn Corporation and the current author while he was at the University of Toronto.
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Bhattarai, Jay K., Md Helal Uddin Maruf, and Keith J. Stine. "Plasmonic-Active Nanostructured Thin Films." Processes 8, no. 1 (January 16, 2020): 115. http://dx.doi.org/10.3390/pr8010115.
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Plasmonic-active nanomaterials are of high interest to scientists because of their expanding applications in the field for medicine and energy. Chemical and biological sensors based on plasmonic nanomaterials are well-established and commercially available, but the role of plasmonic nanomaterials on photothermal therapeutics, solar cells, super-resolution imaging, organic synthesis, etc. is still emerging. The effectiveness of the plasmonic materials on these technologies depends on their stability and sensitivity. Preparing plasmonics-active nanostructured thin films (PANTFs) on a solid substrate improves their physical stability. More importantly, the surface plasmons of thin film and that of nanostructures can couple in PANTFs enhancing the sensitivity. A PANTF can be used as a transducer for any of the three plasmonic-based sensing techniques, namely, the propagating surface plasmon, localized surface plasmon resonance, and surface-enhanced Raman spectroscopy-based sensing techniques. Additionally, continuous nanostructured metal films have an advantage for implementing electrical controls such as simultaneous sensing using both plasmonic and electrochemical techniques. Although research and development on PANTFs have been rapidly advancing, very few reviews on synthetic methods have been published. In this review, we provide some fundamental and practical aspects of plasmonics along with the recent advances in PANTFs synthesis, focusing on the advantages and shortcomings of the fabrication techniques. We also provide an overview of different types of PANTFs and their sensitivity for biosensing.
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Law, Stephanie, Viktor Podolskiy, and Daniel Wasserman. "Towards nano-scale photonics with micro-scale photons: the opportunities and challenges of mid-infrared plasmonics." Nanophotonics 2, no. 2 (April 1, 2013): 103–30. http://dx.doi.org/10.1515/nanoph-2012-0027.
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AbstractSurface plasmon polaritons and their localized counterparts, surface plasmons, are widely used at visible and near-infrared (near-IR) frequencies to confine, enhance, and manipulate light on the subwavelength scale. At these frequencies, surface plasmons serve as enabling mechanisms for future on-chip communications architectures, high-performance sensors, and high-resolution imaging and lithography systems. Successful implementation of plasmonics-inspired solutions at longer wavelengths, in the mid-infrared (mid-IR) frequency range, would benefit a number of highly important technologies in health- and defense-related fields that include trace-gas detection, heat-signature sensing, mimicking, and cloaking, and source and detector development. However, the body of knowledge of visible/near-IR frequency plasmonics cannot be easily transferred to the mid-IR due to the fundamentally different material response of metals in these two frequency ranges. Therefore, mid-IR plasmonic architectures for subwavelength light manipulation require both new materials and new geometries. In this work we attempt to provide a comprehensive review of recent approaches to realize nano-scale plasmonic devices and structures operating at mid-IR wavelengths. We first discuss the motivation for the development of the field of mid-IR plasmonics and the fundamental differences between plasmonics in the mid-IR and at shorter wavelengths. We then discuss early plasmonics work in the mid-IR using traditional plasmonic metals, illuminating both the impressive results of this work, as well as the challenges arising from the very different behavior of metals in the mid-IR, when compared to shorter wavelengths. Finally, we discuss the potential of new classes of mid-IR plasmonic materials, capable of mimicking the behavior of traditional metals at shorter wavelengths, and allowing for true subwavelength, and ultimately, nano-scale confinement at long wavelengths.
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Huang, Shenyang, Chaoyu Song, Guowei Zhang, and Hugen Yan. "Graphene plasmonics: physics and potential applications." Nanophotonics 6, no. 6 (October 18, 2016): 1191–204. http://dx.doi.org/10.1515/nanoph-2016-0126.
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AbstractPlasmon in graphene possesses many unique properties. It originates from the collective motion of massless Dirac fermions, and the carrier density dependence is distinctively different from conventional plasmons. In addition, graphene plasmon is highly tunable and shows strong energy confinement capability. Most intriguingly, as an atom-thin layer, graphene and its plasmon are very sensitive to the immediate environment. Graphene plasmons strongly couple to polar phonons of the substrate, molecular vibrations of the adsorbates, and lattice vibrations of other atomically thin layers. In this review, we present the most important advances in graphene plasmonics field. The topics include terahertz plasmons, mid-infrared plasmons, plasmon-phonon interactions, and potential applications. Graphene plasmonics opens an avenue for reconfigurable metamaterials and metasurfaces; it is an exciting and promising new subject in the nanophotonics and plasmonics research field.
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You, Chenglong, Apurv Chaitanya Nellikka, Israel De Leon, and Omar S. Magaña-Loaiza. "Multiparticle quantum plasmonics." Nanophotonics 9, no. 6 (April 17, 2020): 1243–69. http://dx.doi.org/10.1515/nanoph-2019-0517.
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AbstractA single photon can be coupled to collective charge oscillations at the interfaces between metals and dielectrics forming a single surface plasmon. The electromagnetic near-fields induced by single surface plasmons offer new degrees of freedom to perform an exquisite control of complex quantum dynamics. Remarkably, the control of quantum systems represents one of the most significant challenges in the field of quantum photonics. Recently, there has been an enormous interest in using plasmonic systems to control multiphoton dynamics in complex photonic circuits. In this review, we discuss recent advances that unveil novel routes to control multiparticle quantum systems composed of multiple photons and plasmons. We describe important properties that characterize optical multiparticle systems such as their statistical quantum fluctuations and correlations. In this regard, we discuss the role that photon-plasmon interactions play in the manipulation of these fundamental properties for multiparticle systems. We also review recent works that show novel platforms to manipulate many-body light-matter interactions. In this spirit, the foundations that will allow nonexperts to understand new perspectives in multiparticle quantum plasmonics are described. First, we discuss the quantum statistical fluctuations of the electromagnetic field as well as the fundamentals of plasmonics and its quantum properties. This discussion is followed by a brief treatment of the dynamics that characterize complex multiparticle interactions. We apply these ideas to describe quantum interactions in photonic-plasmonic multiparticle quantum systems. We summarize the state-of-the-art in quantum devices that rely on plasmonic interactions. The review is concluded with our perspective on the future applications and challenges in this burgeoning field.
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Ogawa, Shinpei, Shoichiro Fukushima, and Masaaki Shimatani. "Graphene Plasmonics in Sensor Applications: A Review." Sensors 20, no. 12 (June 23, 2020): 3563. http://dx.doi.org/10.3390/s20123563.
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Surface plasmon polaritons (SPPs) can be generated in graphene at frequencies in the mid-infrared to terahertz range, which is not possible using conventional plasmonic materials such as noble metals. Moreover, the lifetime and confinement volume of such SPPs are much longer and smaller, respectively, than those in metals. For these reasons, graphene plasmonics has potential applications in novel plasmonic sensors and various concepts have been proposed. This review paper examines the potential of such graphene plasmonics with regard to the development of novel high-performance sensors. The theoretical background is summarized and the intrinsic nature of graphene plasmons, interactions between graphene and SPPs induced by metallic nanostructures and the electrical control of SPPs by adjusting the Fermi level of graphene are discussed. Subsequently, the development of optical sensors, biological sensors and important components such as absorbers/emitters and reconfigurable optical mirrors for use in new sensor systems are reviewed. Finally, future challenges related to the fabrication of graphene-based devices as well as various advanced optical devices incorporating other two-dimensional materials are examined. This review is intended to assist researchers in both industry and academia in the design and development of novel sensors based on graphene plasmonics.
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Marinica, Dana Codruta, Mario Zapata, Peter Nordlander, Andrey K. Kazansky, Pedro M. Echenique, Javier Aizpurua, and Andrei G. Borisov. "Active quantum plasmonics." Science Advances 1, no. 11 (December 2015): e1501095. http://dx.doi.org/10.1126/sciadv.1501095.
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The ability of localized surface plasmons to squeeze light and engineer nanoscale electromagnetic fields through electron-photon coupling at dimensions below the wavelength has turned plasmonics into a driving tool in a variety of technological applications, targeting novel and more efficient optoelectronic processes. In this context, the development of active control of plasmon excitations is a major fundamental and practical challenge. We propose a mechanism for fast and active control of the optical response of metallic nanostructures based on exploiting quantum effects in subnanometric plasmonic gaps. By applying an external dc bias across a narrow gap, a substantial change in the tunneling conductance across the junction can be induced at optical frequencies, which modifies the plasmonic resonances of the system in a reversible manner. We demonstrate the feasibility of the concept using time-dependent density functional theory calculations. Thus, along with two-dimensional structures, metal nanoparticle plasmonics can benefit from the reversibility, fast response time, and versatility of an active control strategy based on applied bias. The proposed electrical manipulation of light using quantum plasmonics establishes a new platform for many practical applications in optoelectronics.
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Sebek, Matej, Ahmed Elbana, Arash Nemati, Jisheng Pan, Ze Xiang Shen, Minghui Hong, Xiaodi Su, Nguyen Thi Kim Thanh, and Jinghua Teng. "Hybrid Plasmonics and Two-Dimensional Materials: Theory and Applications." Journal of Molecular and Engineering Materials 08, no. 01n02 (March 2020): 2030001. http://dx.doi.org/10.1142/s2251237320300016.
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The inherent thinness of two-dimensional 2D materials limits their efficiency of light-matter interactions and the high loss of noble metal plasmonic nanostructures limits their applicability. Thus, a combination of 2D materials and plasmonics is highly attractive. This review describes the progress in the field of 2D plasmonics, which encompasses 2D plasmonic materials and hybrid plasmonic-2D materials structures. Novel plasmonic 2D materials, plasmon-exciton interaction within 2D materials and applications comprising sensors, photodetectors and, metasurfaces are discussed.
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Ali, Adnan, Fedwa El-Mellouhi, Anirban Mitra, and Brahim Aïssa. "Research Progress of Plasmonic Nanostructure-Enhanced Photovoltaic Solar Cells." Nanomaterials 12, no. 5 (February 25, 2022): 788. http://dx.doi.org/10.3390/nano12050788.
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Enhancement of the electromagnetic properties of metallic nanostructures constitute an extensive research field related to plasmonics. The latter term is derived from plasmons, which are quanta corresponding to longitudinal waves that are propagating in matter by the collective motion of electrons. Plasmonics are increasingly finding wide application in sensing, microscopy, optical communications, biophotonics, and light trapping enhancement for solar energy conversion. Although the plasmonics field has relatively a short history of development, it has led to substantial advancement in enhancing the absorption of the solar spectrum and charge carrier separation efficiency. Recently, huge developments have been made in understanding the basic parameters and mechanisms governing the application of plasmonics, including the effects of nanoparticles’ size, arrangement, and geometry and how all these factors impact the dielectric field in the surrounding medium of the plasmons. This review article emphasizes recent developments, fundamentals, and fabrication techniques for plasmonic nanostructures while investigating their thermal effects and detailing light-trapping enhancement mechanisms. The mismatch effect of the front and back light grating for optimum light trapping is also discussed. Different arrangements of plasmonic nanostructures in photovoltaics for efficiency enhancement, plasmonics’ limitations, and modeling performance are also deeply explored.
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Sun, Pengfei, Pengfei Xu, Kejian Zhu, and Zhiping Zhou. "Silicon-Based Optoelectronics Enhanced by Hybrid Plasmon Polaritons: Bridging Dielectric Photonics and Nanoplasmonics." Photonics 8, no. 11 (October 28, 2021): 482. http://dx.doi.org/10.3390/photonics8110482.
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Silicon-based optoelectronics large-scale integrated circuits have been of interest to the world in recent decades due to the need for higher complexity, larger link capacity, and lower cost. Surface plasmons are electromagnetic waves that propagate along the interface between a conductor and a dielectric, which can be confined several orders smaller than the wavelength in a vacuum and offers the potential for minimizing photonic circuits to the nanoscale. However, plasmonic waveguides are usually accompanied by substantial propagation loss because metals always exhibit significant resistive heating losses when interacting with light. Therefore, it is better to couple silicon-based optoelectronics and plasmonics and bridge the gap between micro-photonics and nanodevices, especially some nano-electronic devices. In this review, we discuss methods to enhance silicon-based optoelectronics by hybrid plasmon polaritons and summarize some recently reported designs. It is believed that by utilizing the strong light confinement of plasmonics, we can overcome the conventional diffraction limit of light and further improve the integration of optoelectronic circuits.
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Kawata, Satoshi. "Plasmonics for Nanoimaging and Nanospectroscopy." Applied Spectroscopy 67, no. 2 (February 2013): 117–25. http://dx.doi.org/10.1366/12-06861.
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The science of surface plasmon polaritons, known as “plasmonics,” is reviewed from the viewpoint of applied spectroscopy. In this discussion, noble metals are regarded as reservoirs of photons exhibiting the functions of photon confinement and field enhancement at metallic nanostructures. The functions of surface plasmons are described in detail with an historical overview, and the applications of plasmonics to a variety of industry and sciences are shown. The slow light effect of surface plasmons is also discussed for nanoimaging capability of the near-field optical microscopy and tip-enhanced Raman microscopy. The future issues of plasmonics are also shown, including metamaterials and the extension to the ultraviolet and terahertz regions.
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Tao, Z. H., H. M. Dong, and Y. F. Duan. "Anomalous plasmon modes of single-layer MoS2." Modern Physics Letters B 33, no. 18 (June 26, 2019): 1950200. http://dx.doi.org/10.1142/s0217984919502002.
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The electronic plasmons of single layer MoS2 induced by different spin subbands owing to spin-orbit couplings (SOCs) are theoretically investigated. The study shows that two new and anomalous plasmonic modes can be achieved via inter-spin subband transitions around the Fermi level due to the SOCs. The plasmon modes are optic-like, which are very different from the plasmons reported recently in single-layer (SL) MoS2, and the other two-dimensional systems. The frequency of such plasmons ascends with the increasing of electron density or spin polarizability, and decreases with the increasing of wave vector. The promising plasmonic properties of SL MoS2 make it interesting for future applications in plasmonic and terahertz devices.
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Liu, Jianxun, Huilin He, Dong Xiao, Shengtao Yin, Wei Ji, Shouzhen Jiang, Dan Luo, Bing Wang, and Yanjun Liu. "Recent Advances of Plasmonic Nanoparticles and their Applications." Materials 11, no. 10 (September 26, 2018): 1833. http://dx.doi.org/10.3390/ma11101833.
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In the past half-century, surface plasmon resonance in noble metallic nanoparticles has been an important research subject. Recent advances in the synthesis, assembly, characterization, and theories of traditional and non-traditional metal nanostructures open a new pathway to the kaleidoscopic applications of plasmonics. However, accurate and precise models of plasmon resonance are still challenging, as its characteristics can be affected by multiple factors. We herein summarize the recent advances of plasmonic nanoparticles and their applications, particularly regarding the fundamentals and applications of surface plasmon resonance (SPR) in Au nanoparticles, plasmon-enhanced upconversion luminescence, and plasmonic chiral metasurfaces.
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Huang, Cheng-Ping, and Yong-Yuan Zhu. "Plasmonics: Manipulating Light at the Subwavelength Scale." Active and Passive Electronic Components 2007 (2007): 1–13. http://dx.doi.org/10.1155/2007/30946.
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The coupling of light to collective oscillation of electrons on the metal surface allows the creation of surface plasmon-polariton wave. This surface wave is of central interest in the field of plasmonics. In this paper, we will present a brief review of this field, focusing on the plasmonic waveguide and plasmonic transmission. In the plasmonic waveguide, the light can be guided along the metal surface with subwavelength lateral dimensions, enabling the possibility of high-density integration of the optical elements. On the other hand, in the plasmonic transmission, the propagation of light through a metal surface can be tailored with the subwavelength holes, leading to the anomalous transmission behaviors which have received extensive investigations in recent years. In addition, as a supplement to plasmonics in the visible and near-infrared region, the study of THz plasmonics has also been discussed.
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Li, Shaobo, Shuming Yang, Fei Wang, Qiang Liu, Biyao Cheng, and Yossi Rosenwaks. "Plasmonic interference modulation for broadband nanofocusing." Nanophotonics 10, no. 16 (October 26, 2021): 4113–23. http://dx.doi.org/10.1515/nanoph-2021-0405.
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Abstract Metallic plasmonic probes have been successfully applied in near-field imaging, nanolithography, and Raman enhanced spectroscopy because of their ability to squeeze light into nanoscale and provide significant electric field enhancement. Most of these probes rely on nanometric alignment of incident beam and resonant structures with limited spectral bandwidth. This paper proposes and experimentally demonstrates an asymmetric fiber tip for broadband interference nanofocusing within its full optical wavelengths (500–800 nm) at the nanotip with 10 nm apex. The asymmetric geometry consisting of two semicircular slits rotates plasmonic polarization and converts the linearly polarized plasmonic mode to the radially polarized plasmonic mode when the linearly polarized beam couples to the optical fiber. The three-dimensional plasmonic modulation induces circumference interference and nanofocus of surface plasmons, which is significantly different from the nanofocusing through plasmon propagation and plasmon evolution. The plasmonic interference modulation provides fundamental insights into the plasmon engineering and has important applications in plasmon nanophotonic technologies.
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Yang, Ruoxi, and Zhaolin Lu. "Subwavelength Plasmonic Waveguides and Plasmonic Materials." International Journal of Optics 2012 (2012): 1–12. http://dx.doi.org/10.1155/2012/258013.
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With the fast development of microfabrication technology and advanced computational tools, nanophotonics has been widely studied for high-speed data transmission, sensitive optical detection, manipulation of ultrasmall objects, and visualization of nanoscale patterns. As an important branch of nanophotonics, plasmonics has enabled light-matter interactions at a deep subwavelength length scale. Plasmonics, or surface plasmon based photonics, focus on how to exploit the optical property of metals with abundant free electrons and hence negative permittivity. The oscillation of free electrons, when properly driven by electromagnetic waves, would form plasmon-polaritons in the vicinity of metal surfaces and potentially result in extreme light confinement. The objective of this article is to review the progress of subwavelength or deep subwavelength plasmonic waveguides, and fabrication techniques of plasmonic materials.
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Jacak, Janusz, and Witold Jacak. "Plasmons and Plasmon–Polaritons in Finite Ionic Systems: Toward Soft-Plasmonics of Confined Electrolyte Structures." Applied Sciences 9, no. 6 (March 19, 2019): 1159. http://dx.doi.org/10.3390/app9061159.
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We address the field of soft plasmonics in finite electrolyte liquid systems ranged by insulating membranes by an analogy to the plasmonics of metallic nanostructures. The confined electrolyte systems can be encountered on a bio-cell organizational level, taking into account that the characteristics of ion plasmons fall to the micrometer size scale instead of the nanometer in metals because of at least three orders of magnitude larger masses of ions in comparison to electrons. The lower density of ions in electrolytes in comparison to density of electrons in metal may also reduce the energy of plasmons by several orders. We provide the fully analytical description of surface and volume plasmons in finite ionic micro-systems allowing for further applications. We next apply the theory of ionic plasmons to plasmon–polaritons in ionic periodic systems. The complete theory of ionic plasmon–polariton kinetics in the chain of micrometer-sized electrolyte spheres, confined by a dielectric membrane, is formulated and solved. The latter theory has next been applied to the explanation of a mysterious and unclear (for several dozen of years) problem of so-called saltatory conduction of the action potential in myelinated axons of nerve cells. Contrary to conventional models of nerve signaling, the plasmon–polariton model pretty well fits to the queer properties of the saltatory conduction. Moreover, the presented application of soft plasmonics to signaling in periodically myelinated axons may allow for identification of a different role in information processing of the white and gray matters in brain and spinal cord. We have outlined some perspectives to utilize the difference between the electricity of myelinated and non-myelinated nerve cells in brain to develop the topological concept of the memory functioning. The proposed ionic plasmon–polariton model of the saltatory conduction differently recognizes the role of the insulating myelin than previously was thought which may be helpful in the development of a better understanding of the demyelination diseases.
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Brooks, James L., Christopher L. Warkentin, Dayeeta Saha, Emily L. Keller, and Renee R. Frontiera. "Toward a mechanistic understanding of plasmon-mediated photocatalysis." Nanophotonics 7, no. 11 (August 29, 2018): 1697–724. http://dx.doi.org/10.1515/nanoph-2018-0073.
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AbstractOne of the most exciting new developments in the plasmonic nanomaterials field is the discovery of their ability to mediate a number of photocatalytic reactions. Since the initial prediction of driving chemical reactions with plasmons in the 1980s, the field has rapidly expanded in recent years, demonstrating the ability of plasmons to drive chemical reactions, such as water splitting, ammonia generation, and CO2 reduction, among many other examples. Unfortunately, the efficiencies of these processes are currently suboptimal for practical widespread applications. The limitations in recorded outputs can be linked to the current lack of a knowledge pertaining to mechanisms of the partitioning of plasmonic energy after photoexcitation. Providing a descriptive and quantitative mechanism of the processes involved in driving plasmon-induced photochemical reactions, starting at the initial plasmon excitation, followed by hot carrier generation, energy transfer, and thermal effects, is critical for the advancement of the field as a whole. Here, we provide a mechanistic perspective on plasmonic photocatalysis by reviewing select experimental approaches. We focus on spectroscopic and electrochemical techniques that provide molecular-scale information on the processes that occur in the coupled molecular-plasmonic system after photoexcitation. To conclude, we evaluate several promising techniques for future applications in elucidating the mechanism of plasmon-mediated photocatalysis.
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Kazlou, A., T. Kaihara, I. Razdolski, and A. Stupakiewicz. "Surface plasmon-assisted control of the phase of photo-induced spin precession." Applied Physics Letters 120, no. 25 (June 20, 2022): 251101. http://dx.doi.org/10.1063/5.0097539.
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We demonstrate surface plasmon-assisted control of a photo-magnetic spin precession phase in hybrid noble metal–dielectric magneto-plasmonic crystals. The plasmon-driven photo-magnetic excitation of the spin precession in the dielectric was performed by means of a time-resolved magneto-optical method in the near-infrared spectral range. We show, both experimentally and numerically, that a surface plasmon-polariton resonance results in the phase reversal of the spin precession. We discuss the similarity of plasmonic excitations in metal–dielectric bilayers to the action of photo-magnetic stimuli with orthogonal linear polarization in dielectrics. These results demonstrate rich possibilities of plasmonic excitations beyond conventional enhancement of the electric field intensity and indicate high promise of magneto-plasmonics for photo-magnetism at the nanoscale.
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Balevičius, Zigmas. "Strong Coupling between Tamm and Surface Plasmons for Advanced Optical Bio-Sensing." Coatings 10, no. 12 (December 5, 2020): 1187. http://dx.doi.org/10.3390/coatings10121187.
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The total internal reflection ellipsometry method was used to analyse the angular spectra of the hybrid Tamm and surface plasmon modes and to compare their results with those obtained using the conventional single SPR method. As such type of measurement is quite common in commercial SPR devices, more detailed attention was paid to the analysis of the p-polarization reflection intensity dependence. The conducted study showed that the presence of strong coupling in the hybrid plasmonic modes increases the sensitivity of the plasmonic-based sensors due to the reduced losses in the metal layer. The experimental results and analysis of the optical responses of three different plasmonic-based samples indicated that the optimized Tamm plasmons ΔRp(TP) and optimized surface plasmons ΔRp(SP) samples produce a response that is about five and six times greater than the conventional surface plasmon resonance ΔRp(SPR) in angular spectra. The sensitivity of the refractive index unit of the spectroscopic measurements for the optimized Tamm plasmon samples was 1.5 times higher than for conventional SPR, while for wavelength scanning, the SPR overcame the optimized TP by 1.5 times.
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Wang, Jingyu, Min Gao, Yonglin He, and Zhilin Yang. "Ultrasensitive and ultrafast nonlinear optical characterization of surface plasmons." APL Materials 10, no. 3 (March 1, 2022): 030701. http://dx.doi.org/10.1063/5.0083239.
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Amid the rapid development of nanosciences and nanotechnologies, plasmonics has emerged as an essential and fascinating discipline. Surface plasmons (SPs) lay solid physical foundations for plasmonics and have been broadly applied to ultrahigh-resolution spectroscopy, optical modulation, renewable energy, communication technology, etc. Sensitive optical characterizations for SPs, including far/near-field optics, spatial-resolved spectroscopy, and time-resolved behaviors of SPs, have prompted intense interest in diverse fields. In this Research Update, the ultrasensitive optical characterization for sub-radiant SPs is first introduced. Then, distinct characterization methods of nonlinear plasmonics, including plasmon-enhanced second harmonic generation and plasmon-enhanced sum frequency generation, are demonstrated in some classical nanostructures. Transient optical characterizations of SPs are also demonstrated in some well-defined nanostructures, enabling the deep realization of time-resolved behaviors. Finally, future prospects and efforts of optical characterization for SPs are proposed.
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Sarkar, Partha, Bansibadan Maji, Aritra Manna, Saradindu Panda, and Asish Kr Mukhopadhyay. "Effect of Surface Plasmon-Based Improvement in Optical Absorption in Plasmonic Solar Cell." International Journal of Nanoscience 17, no. 04 (July 8, 2018): 1760028. http://dx.doi.org/10.1142/s0219581x17600286.
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In the last few years, plasmonics has attracted much attention and has been included in the principal domains of nanophotonics that can manage optical fields at the nanodimension level. Its exquisite characteristic is to increase the electromagnetic fields at the nanometer scale particularly in the solar cell. In the plasmonic discipline, noble metals used as nanoparticles in which the density of the electron gas which oscillates at surface plasmon frequency at that time also enhances absorption via scattering. So the usage of plasmonics in solar cells offers better possibility of improving the performance through absorption, because the optical spectrum loss is principal as a part of the overall loss for the solar photovoltaic cell. So we investigated the impact of the nanoparticle size for the enhancement of extinction in terms of absorption and scattering by using surface plasmon resonance, and additionally studied the finite-difference time domain (FDTD)-based proposed model and found various plasmonic fields components and characterized optical enhancement in the plasmonic thin film solar cell.
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Lamri, Gwénaëlle, Alessandro Veltri, Jean Aubard, Pierre-Michel Adam, Nordin Felidj, and Anne-Laure Baudrion. "Polarization-dependent strong coupling between silver nanorods and photochromic molecules." Beilstein Journal of Nanotechnology 9 (October 8, 2018): 2657–64. http://dx.doi.org/10.3762/bjnano.9.247.
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Active plasmonics is a key focus for the development of advanced plasmonic applications. By selectively exciting the localized surface plasmon resonance sustained by the short or the long axis of silver nanorods, we demonstrate a polarization-dependent strong coupling between the plasmonic resonance and the excited state of photochromic molecules. By varying the width and the length of the nanorods independently, a clear Rabi splitting appears in the dispersion curves of both resonators.
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Abed, Jehad, Nitul S. Rajput, Amine El Moutaouakil, and Mustapha Jouiad. "Recent Advances in the Design of Plasmonic Au/TiO2 Nanostructures for Enhanced Photocatalytic Water Splitting." Nanomaterials 10, no. 11 (November 15, 2020): 2260. http://dx.doi.org/10.3390/nano10112260.
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Plasmonic nanostructures have played a key role in extending the activity of photocatalysts to the visible light spectrum, preventing the electron–hole combination and providing with hot electrons to the photocatalysts, a crucial step towards efficient broadband photocatalysis. One plasmonic photocatalyst, Au/TiO2, is of a particular interest because it combines chemical stability, suitable electronic structure, and photoactivity for a wide range of catalytic reactions such as water splitting. In this review, we describe key mechanisms involving plasmonics to enhance photocatalytic properties leading to efficient water splitting such as production and transport of hot electrons through advanced analytical techniques used to probe the photoactivity of plasmonics in engineered Au/TiO2 devices. This work also discusses the emerging strategies to better design plasmonic photocatalysts and understand the underlying mechanisms behind the enhanced photoactivity of plasmon-assisted catalysts.
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Kuzmin, Dmitry A., Igor V. Bychkov, Vladimir G. Shavrov, and Vasily V. Temnov. "Plasmonics of magnetic and topological graphene-based nanostructures." Nanophotonics 7, no. 3 (February 23, 2018): 597–611. http://dx.doi.org/10.1515/nanoph-2017-0095.
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AbstractGraphene is a unique material in the study of the fundamental limits of plasmonics. Apart from the ultimate single-layer thickness, its carrier concentration can be tuned by chemical doping or applying an electric field. In this manner, the electrodynamic properties of graphene can be varied from highly conductive to dielectric. Graphene supports strongly confined, propagating surface plasmon polaritons (SPPs) in a broad spectral range from terahertz to mid-infrared frequencies. It also possesses a strong magneto-optical response and thus provides complimentary architectures to conventional magneto-plasmonics based on magneto-optically active metals or dielectrics. Despite a large number of review articles devoted to plasmonic properties and applications of graphene, little is known about graphene magneto-plasmonics and topological effects in graphene-based nanostructures, which represent the main subject of this review. We discuss several strategies to enhance plasmonic effects in topologically distinct closed surface landscapes, i.e. graphene nanotubes, cylindrical nanocavities and toroidal nanostructures. A novel phenomenon of the strongly asymmetric SPP propagation on chiral meta-structures and the fundamental relations between structural and plasmonic topological indices are reviewed.
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Ghalgaoui, Ahmed, and Klaus Reimann. "Excitation of tunable plasmons in silicon using microwave transmission through a metallic aperture." Applied Physics Letters 120, no. 16 (April 18, 2022): 162103. http://dx.doi.org/10.1063/5.0080262.
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Plasmon resonances in semiconductors at microwave frequencies offer the possibility for many functionalities and integration schemes. Semiconductor materials, such as germanium, gallium arsenide, and silicon, have the further advantage of being able to be integrated with standard electronics technology. Here, we probe the bulk plasmon modes in silicon in the vicinity of a copper plate perforated by a single aperture at frequencies between 10 and 60 GHz. Sharp transmission minima are observed at discrete frequencies. The observed frequencies depend on the size of the aperture and the carrier concentration in the silicon; they are well reproduced by the dispersion relation for bulk plasmons. Our results show that one can excite plasmons in silicon in the millimeter-wave region, opening a route to microwave plasmonics for large-scale applications, using low-cost technology.
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Dong, Jun, Zhenglong Zhang, Hairong Zheng, and Mentao Sun. "Recent Progress on Plasmon-Enhanced Fluorescence." Nanophotonics 4, no. 4 (December 30, 2015): 472–90. http://dx.doi.org/10.1515/nanoph-2015-0028.
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AbstractThe optically generated collective electron density waves on metal–dielectric boundaries known as surface plasmons have been of great scientific interest since their discovery. Being electromagnetic waves on gold or silver nanoparticle’s surface, localised surface plasmons (LSP) can strongly enhance the electromagnetic field. These strong electromagnetic fields near the metal surfaces have been used in various applications like surface enhanced spectroscopy (SES), plasmonic lithography, plasmonic trapping of particles, and plasmonic catalysis. Resonant coupling of LSPs to fluorophore can strongly enhance the emission intensity, the angular distribution, and the polarisation of the emitted radiation and even the speed of radiative decay, which is so-called plasmon enhanced fluorescence (PEF). As a result, more and more reports on surface-enhanced fluorescence have appeared, such as SPASER-s, plasmon assisted lasing, single molecule fluorescence measurements, surface plasmoncoupled emission (SPCE) in biological sensing, optical orbit designs etc. In this review, we focus on recent advanced reports on plasmon-enhanced fluorescence (PEF). First, the mechanism of PEF and early results of enhanced fluorescence observed by metal nanostructure will be introduced. Then, the enhanced substrates, including periodical and nonperiodical nanostructure, will be discussed and the most important factor of the spacer between molecule and surface and wavelength dependence on PEF is demonstrated. Finally, the recent progress of tipenhanced fluorescence and PEF from the rare-earth doped up-conversion (UC) and down-conversion (DC) nanoparticles (NPs) are also commented upon. This review provides an introduction to fundamentals of PEF, illustrates the current progress in the design of metallic nanostructures for efficient fluorescence signal amplification that utilises propagating and localised surface plasmons.
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Coello, Víctor, Cesar E. Garcia-Ortiz, and Manuel Garcia-Mendez. "Classical Plasmonics: Wave Propagation Control at Subwavelength Scale." Nano 10, no. 07 (October 2015): 1530005. http://dx.doi.org/10.1142/s1793292015300054.
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In this paper, surface plasmons polariton propagation and manipulation is reviewed in the context of experiments and modeling of optical images. We focus our attention in the interaction of surface plasmon polaritons with arrays of micro-scatereres and nanofabricated structures. Numerical simulations and experimental results of different plasmonic devices are presented. Plasmonic beam manipulation opens up numerous possibilities for application in biosensing, nanophotonics, and in general in the area of surface optics properties.
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Khurgin, Jacob B. "Replacing noble metals with alternative materials in plasmonics and metamaterials: how good an idea?" Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 375, no. 2090 (March 28, 2017): 20160068. http://dx.doi.org/10.1098/rsta.2016.0068.
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Noble metals that currently dominate the fields of plasmonics and metamaterials suffer from large ohmic losses. Some of the new plasmonic materials, such as doped oxides and nitrides, have smaller material loss, and using them in place of metals carries the promise of reduced-loss plasmonic and metamaterial structures, with sharper resonances and higher field concentrations. This promise is put to a rigorous analytical test in this work, which reveals that having low material loss is not sufficient to have reduced modal loss in plasmonic structures. To reduce the modal loss, it is absolutely necessary for the plasma frequency to be significantly higher than the operational frequency. Using examples of nanoparticle plasmons and gap plasmons one comes to the conclusion that, even in the mid-infrared spectrum, metals continue to hold an advantage over alternative media when it comes to propagation distances and field enhancements. Of course, the new materials still have an application niche where high absorption loss is beneficial, e.g. in medicine and thermal photovoltaics. This article is part of the themed issue ‘New horizons for nanophotonics’.
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Goswami, P., and U. P. Tyagi. "Graphene-TMD Van der Waals Heterostucture Plasmonics." Journal of Scientific Research 12, no. 2 (February 1, 2020): 169–74. http://dx.doi.org/10.3329/jsr.v12i2.43685.
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The collective excitations of electrons in the bulk or at the surface, viz. plasmons, play an important role in the properties of materials, and have generated the field of “plasmonics”. We report the observation of a highly unusual plasmon mode on the surface of Van der Waals heterostructures (vdWHs) of graphene monolayer on 2D transition metal dichalcogenide (Gr-TMD) substrate. Since the exponentially decaying fields of surface plasmon wave propagating along interface is highly sensitive to the ambient refractive index variations, such heterostructures are useful for ultra-sensitive bio-sensing.
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Nishimura, Takuya, and Taiichi Otsuji. "TERAHERTZ POLARIZATION CONTROLLER BASED ON ELECTRONIC DISPERSION CONTROL OF 2D PLASMONS." International Journal of High Speed Electronics and Systems 17, no. 03 (September 2007): 547–55. http://dx.doi.org/10.1142/s0129156407004734.
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We numerically investigated the possibility of terahertz polarization controller based on electronic dispersion control of two dimensional (2D) plasmon gratings in semiconductor heterostructure material systems. Taking account of the Mikhailov's dispersive plasmonic conductivity model, the electromagnetic field emission properties of the gated 2D plasmon gratings were numerically analyzed with respect to the density (n) of electrons by using in-house Maxwell's FDTD (finite difference time domain method) simulator. When n is low under a constant drift-velocity condition, the fundamental plasmon mode is excited, being coupled with the radiative zeroth mode of transverse electric (TE) waves. When n exceeds a threshold level, the second harmonic mode of plasmon is predominantly excited, being coupled with the non-radiative first mode of TE waves. We numerically demonstrated that if a grating mesh of 2D plasmons is formed where two independent 2D plasmon gratings are combined orthogonally, the structure can act as a polarization controller by electronically controlling the two axial plasmonic dispersions.
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Song, Wen-Bo, Yun Qi, Xiao-Peng Zhang, Ming-Li Wan, and Jinna He. "Controlling the interference between localized and delocalized surface plasmons via incident polarization for optical switching." International Journal of Modern Physics B 32, no. 16 (June 28, 2018): 1850194. http://dx.doi.org/10.1142/s0217979218501941.
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Surface plasmons supported by various metallic nanostructures have given rise to several significant breakthroughs in the field of integrated photonic devices due to its ability to effectively confine and enhance optical field in subwavelength volume. In particular, the demand to actively control optical responses of plasmonic systems becomes urgent for the miniaturization of signal processing devices, surface-enhanced Raman scattering (SERS) substrates and biochemical sensors. In this paper, we systematically investigate the plasmon modes as well as their interaction in a layered nanostructure composed of a periodically-arranged radiative nanoring and a metallic ground plane, as well as a thin insulating spacer. A tunable transparent peak on the background of the broadband plasmon resonance emerges in the reflection spectrum as changing the periodicity of nanoparticle array, a plasmonic analogue of electromagnetically induced transparency (EIT). Owing to the structural symmetry of the rings, we demonstrate a new scheme of controlling the interference between localized and delocalized plasmons by means of incident polarization and believe that the proposed metasurface may find applications in optical switching if the polarization-controlled components are introduced.
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Davis, Timothy J., Daniel E. Gómez, and Ann Roberts. "Plasmonic circuits for manipulating optical information." Nanophotonics 6, no. 3 (October 26, 2016): 543–59. http://dx.doi.org/10.1515/nanoph-2016-0131.
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AbstractSurface plasmons excited by light in metal structures provide a means for manipulating optical energy at the nanoscale. Plasmons are associated with the collective oscillations of conduction electrons in metals and play a role intermediate between photonics and electronics. As such, plasmonic devices have been created that mimic photonic waveguides as well as electrical circuits operating at optical frequencies. We review the plasmon technologies and circuits proposed, modeled, and demonstrated over the past decade that have potential applications in optical computing and optical information processing.
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Zhang, Xiaoyu, Chanda Ranjit Yonzon, and Richard P. Van Duyne. "Nanosphere lithography fabricated plasmonic materials and their applications." Journal of Materials Research 21, no. 5 (May 1, 2006): 1083–92. http://dx.doi.org/10.1557/jmr.2006.0136.
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Nanosphere lithography fabricated nanostructures have highly tunable localized surface plasmons, which have been used for important sensing and spectroscopy applications. In this work, the authors focus on biological applications and technologies that utilize two types of related plasmonic phenomena: localized surface plasmon resonance (LSPR) spectroscopy and surface-enhanced Raman spectroscopy (SERS). Two applications of these plasmonic materials are presented: (i) the development of an ultrasensitive nanoscale optical biosensor based on LSPR wavelength-shift spectroscopy and (ii) the SERS detection of an anthrax biomarker.
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Wen, Chunchao, Jie Luo, Wei Xu, Zhihong Zhu, Shiqiao Qin, and Jianfa Zhang. "Enhanced Molecular Infrared Spectroscopy Employing Bilayer Graphene Acoustic Plasmon Resonator." Biosensors 11, no. 11 (October 31, 2021): 431. http://dx.doi.org/10.3390/bios11110431.
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Graphene plasmon resonators with the ability to support plasmonic resonances in the infrared region make them a promising platform for plasmon-enhanced spectroscopy techniques. Here we propose a resonant graphene plasmonic system for infrared spectroscopy sensing that consists of continuous graphene and graphene ribbons separated by a nanometric gap. Such a bilayer graphene resonator can support acoustic graphene plasmons (AGPs) that provide ultraconfined electromagnetic fields and strong field enhancement inside the nano-gap. This allows us to selectively enhance the infrared absorption of protein molecules and precisely resolve the molecular structural information by sweeping graphene Fermi energy. Compared to the conventional graphene plasmonic sensors, the proposed bilayer AGP sensor provides better sensitivity and improvement of molecular vibrational fingerprints of nanoscale analyte samples. Our work provides a novel avenue for enhanced infrared spectroscopy sensing with ultrasmall volumes of molecules.
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Genç, Aziz, Javier Patarroyo, Jordi Sancho-Parramon, Neus G. Bastús, Victor Puntes, and Jordi Arbiol. "Hollow metal nanostructures for enhanced plasmonics: synthesis, local plasmonic properties and applications." Nanophotonics 6, no. 1 (January 6, 2017): 193–213. http://dx.doi.org/10.1515/nanoph-2016-0124.
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AbstractMetallic nanostructures have received great attention due to their ability to generate surface plasmon resonances, which are collective oscillations of conduction electrons of a material excited by an electromagnetic wave. Plasmonic metal nanostructures are able to localize and manipulate the light at the nanoscale and, therefore, are attractive building blocks for various emerging applications. In particular, hollow nanostructures are promising plasmonic materials as cavities are known to have better plasmonic properties than their solid counterparts thanks to the plasmon hybridization mechanism. The hybridization of the plasmons results in the enhancement of the plasmon fields along with more homogeneous distribution as well as the reduction of localized surface plasmon resonance (LSPR) quenching due to absorption. In this review, we summarize the efforts on the synthesis of hollow metal nanostructures with an emphasis on the galvanic replacement reaction. In the second part of this review, we discuss the advancements on the characterization of plasmonic properties of hollow nanostructures, covering the single nanoparticle experiments, nanoscale characterization via electron energy-loss spectroscopy and modeling and simulation studies. Examples of the applications, i.e. sensing, surface enhanced Raman spectroscopy, photothermal ablation therapy of cancer, drug delivery or catalysis among others, where hollow nanostructures perform better than their solid counterparts, are also evaluated.
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Song, Hyerin, Heesang Ahn, Taeyeon Kim, Jong-ryul Choi, and Kyujung Kim. "Localized Surface Plasmon Fields Manipulation on Nanostructures Using Wavelength Shifting." Applied Sciences 11, no. 19 (September 30, 2021): 9133. http://dx.doi.org/10.3390/app11199133.
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Metallic nanowires have been utilized as a platform for propagating surface plasmon (SPs) fields. To be exploited for applications such as plasmonic circuits, manipulation of localized field propagating pattern is also important. In this study, we calculated the field distributions of localized surface plasmons (LSPs) on the specifically shaped nanostructures and explored the feasibility of manipulating LSP fields. Specifically, plasmonic fields were calculated at different wavelengths for a nanoscale rod array (I-shaped), an array connected with two nanoscale rods at right angles (T-shaped), and an array with three nanoscale rods at 120° to each other (Y-shaped). Three different types of nanostructures are suggested to manipulate the positions of LSP fields collaborating with adjustment of wavelength, polarization, and incident orientation of light source. The results of this study are important not only for the understanding of the wavelength-dependent surface plasmon field localization mechanism but also for the applicability of swept source-based plasmonic techniques or designing a plasmonic circuit.
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Tohari, Mariam M., Andreas Lyras, and Mohamad S. AlSalhi. "A Novel Metal Nanoparticles-Graphene Nanodisks-Quantum Dots Hybrid-System-Based Spaser." Nanomaterials 10, no. 3 (February 27, 2020): 416. http://dx.doi.org/10.3390/nano10030416.
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Active nanoplasmonics have recently led to the emergence of many promising applications. One of them is the spaser (surface plasmons amplification by stimulated emission of radiation) that has been shown to generate coherent and intense fields of selected surface plasmon modes that are strongly localized in the nanoscale. We propose a novel nanospaser composed of a metal nanoparticles-graphene nanodisks hybrid plasmonic system as its resonator and a quantum dots cascade stack as its gain medium. We derive the plasmonic fields induced by pulsed excitation through the use of the effective medium theory. Based on the density matrix approach and by solving the Lindblad quantum master equation, we analyze the ultrafast dynamics of the spaser associated with coherent amplified plasmonic fields. The intensity of the plasmonic field is significantly affected by the width of the metallic contact and the time duration of the laser pulse used to launch the surface plasmons. The proposed nanospaser shows an extremely low spasing threshold and operates in the mid-infrared region that has received much attention due to its wide biomedical, chemical and telecommunication applications.
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Nagy, Benedek J., Zsuzsanna Pápa, László Péter, Christine Prietl, Joachim R. Krenn, and Péter Dombi. "Near-Field-Induced Femtosecond Breakdown of Plasmonic Nanoparticles." Plasmonics 15, no. 2 (October 31, 2019): 335–40. http://dx.doi.org/10.1007/s11468-019-01043-3.
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Abstract We studied the evolution of femtosecond breakdown in lithographically produced plasmonic nanoparticles with increasing laser intensity. Localized plasmons were generated with 40-fs laser pulses with up to 1.4 × 1012 W/cm2 peak intensity. The damage morphology shows substantial variation with intensity, starting with the detachment of hot spots and stochastic nanoparticle removal. For higher intensities, we observe precise nanolithographic mapping of near-field distributions via ablation. The common feature of these phenomena is the central role played by the single plasmonic hot spot of the triangular nanoparticles used. We also derive a damage threshold value from stochastic damage trends on the arrays fostering the optimization of novel nanoarchitectures for nonlinear plasmonics.
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Intravaia, F., and A. Lambrecht. "The Role of Surface Plasmon Modes in the Casimir Effect." Open Systems & Information Dynamics 14, no. 02 (June 2007): 159–68. http://dx.doi.org/10.1007/s11080-007-9044-4.
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In this paper, we study the role of surface plasmon modes in the Casimir effect. First we write the Casimir energy as the sum over the modes of a real cavity. We may identify two sorts of modes, two evanescent surface plasmon modes and propagative modes. As one of the surface plasmon modes becomes propagative for some choice of parameters we adopt an adiabatic mode definition where we follow this mode into the propagative sector and count it together with the surface plasmon contribution, calling this contribution “plasmonic”. The remaining modes are propagative cavity modes, which we call “photonic”. The Casimir energy contains two main contributions, one coming from the plasmonic, the other from the photonic modes. Surprisingly we find that the plasmonic contribution to the Casimir energy becomes repulsive for intermediate and large mirror separations. Alternatively, we discuss the common surface plasmon defintion, which includes only evanescent waves, where this effect is not found. We show that, in contrast to an intuitive expectation, for both definitions the Casimir energy is the sum of two very large contributions which nearly cancel each other. The contribution of surface plasmons to the Casimir energy plays a fundamental role not only at short but also at large distances.
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Urban, Maximilian J., Chenqi Shen, Xiang-Tian Kong, Chenggan Zhu, Alexander O. Govorov, Qiangbin Wang, Mario Hentschel, and Na Liu. "Chiral Plasmonic Nanostructures Enabled by Bottom-Up Approaches." Annual Review of Physical Chemistry 70, no. 1 (June 14, 2019): 275–99. http://dx.doi.org/10.1146/annurev-physchem-050317-021332.
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We present a comprehensive review of recent developments in the field of chiral plasmonics. Significant advances have been made recently in understanding the working principles of chiral plasmonic structures. With advances in micro- and nanofabrication techniques, a variety of chiral plasmonic nanostructures have been experimentally realized; these tailored chiroptical properties vastly outperform those of their molecular counterparts. We focus on chiral plasmonic nanostructures created using bottom-up approaches, which not only allow for rational design and fabrication but most intriguingly in many cases also enable dynamic manipulation and tuning of chiroptical responses. We first discuss plasmon-induced chirality, resulting from the interaction of chiral molecules with plasmonic excitations. Subsequently, we discuss intrinsically chiral colloids, which give rise to optical chirality owing to their chiral shapes. Finally, we discuss plasmonic chirality, achieved by arranging achiral plasmonic particles into handed configurations on static or active templates. Chiral plasmonic nanostructures are very promising candidates for real-life applications owing to their significantly larger optical chirality than natural molecules. In addition, chiral plasmonic nanostructures offer engineerable and dynamic chiroptical responses, which are formidable to achieve in molecular systems. We thus anticipate that the field of chiral plasmonics will attract further widespread attention in applications ranging from enantioselective analysis to chiral sensing, structural determination, and in situ ultrasensitive detection of multiple disease biomarkers, as well as optical monitoring of transmembrane transport and intracellular metabolism.
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Томилина, О. А., В. Н. Бержанский, and С. В. Томилин. "Влияние перколяционного перехода на электропроводящие и оптические свойства сверхтонких металлических пленок." Физика твердого тела 62, no. 4 (2020): 614. http://dx.doi.org/10.21883/ftt.2020.04.49129.610.
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In paper the investigation results of features of electrophysical, optical and plasmonic properties changes in ultrathin metallic films during percolation transition from island structure to continuous are representative. It was shown that during Ti and Pt thin films condensation a change of their electrical conductivity above the percolation threshold is well described in the framework of the classical percolation theory. The resonance behavior of localized plasmons and surface (propagating) plasmon-polaritons in Au metal films during a percolation transition was studied. It was shown that when the film becomes to a granular state a decrease in the Q-factor of surface plasmon-polariton resonance is observed in the vicinity of the percolation transition, which is associated with excitation of localized plasmons in metallic nanoparticles. For all studied coatings the percolation threshold was determined.
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Amoako, G., W. Zhang, M. Zhou, S. S. Sackey, and P. Mensah-Amoah. "Rapid Laser Direct Writing of Plasmonic Components." Applied Physics Research 9, no. 6 (November 7, 2017): 19. http://dx.doi.org/10.5539/apr.v9n6p19.
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A new device named technology-plasmonics has recently emerged and can be used to manipulate light at the nano-scale level. Here, we report the method of two-photon photopolymerization for rapid laser direct writing of plasmonic components. The characterization of these components is performed by a leakage radiation microscope, which has the same system construction as the two-photon photopolymerization micro-fabrication system except the laser pattern. The dielectric structures covered with gold proved to be very efficient for the excitation of surface plasmon polaritons in this system and can achieve different plasmon fields.
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Jiang, Jing, Xinhao Wang, Shuang Li, Fei Ding, Nantao Li, Shaoyu Meng, Ruifan Li, Jia Qi, Qingjun Liu, and Gang Logan Liu. "Plasmonic nano-arrays for ultrasensitive bio-sensing." Nanophotonics 7, no. 9 (August 28, 2018): 1517–31. http://dx.doi.org/10.1515/nanoph-2018-0023.
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AbstractSurface plasmon resonance (SPR) and localized SPR (LSPR) effects have been shown as the principles of some highlysensitive sensors in recent decades. Due to the advances in nano-fabrication technology, the plasmon nano-array sensors based on SPR and LSPR phenomena have been widely used in chemical and bioloical analysis. Sensing with surface-enhanced field and sensing for refractive index changes are able to identify the analytes quantitatively and qualitatively. With the newly developed ultrasensitive plasmonic biosensors, platforms with excellent performance have been built for various biomedical applications, including point-of-care diagnosis and personalized medicine. In addition, flexible integration of plasmonics nano-arrays and combining them with electrochemical sensing have significantly enlarged the application scenarios of the plasmonic nano-array sensors, as well as improved the sensing accuracy.
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Thangamuthu, Madasamy, T. V. Raziman, Olivier J. F. Martin, and Junwang Tang. "Review—Origin and Promotional Effects of Plasmonics in Photocatalysis." Journal of The Electrochemical Society 169, no. 3 (March 1, 2022): 036512. http://dx.doi.org/10.1149/1945-7111/ac5c97.
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Plasmonic effects including near-field coupling, light scattering, guided mode through surface plasmon polaritons (SPPs), Förster resonant energy transfer (FRET), and thermoplasmonics are extensively used for harnessing inexhaustible solar energy for photovoltaics and photocatalysis. Recently, plasmonic hot carrier-driven photocatalysis has received additional attention thanks to its specific selectivity in the catalytic conversion of gas molecules and organic compounds, resulting from the direct injection of hot carriers into the lowest unoccupied molecular orbital of the adsorbate molecule. The excellent light trapping property and high efficiency of hot charge-carrier generation through electromagnetic surface plasmon decay have been identified as the dominant mechanisms that promote energy-intensive chemical reactions at room temperature and atmospheric pressure. However, understanding the electromagnetic effects of plasmonics and distinguishing them from chemical effects in photocatalysis is challenging. While there exist several reviews underlining the experimental observations of plasmonic effects, this critical review addresses the physical origin of the various plasmon-related phenomena and how they can promote photocatalysis. The conditions under which each plasmonic effect dominates and how to distinguish one from another is also discussed, together with the analysis of the photoconversion efficiency. Finally, future research directions are proposed with the aim to accelerate progress in this field at the interface between chemistry and physics.
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Khan, Pritam, Grace Brennan, James Lillis, Syed A. M. Tofail, Ning Liu, and Christophe Silien. "Characterisation and Manipulation of Polarisation Response in Plasmonic and Magneto-Plasmonic Nanostructures and Metamaterials." Symmetry 12, no. 8 (August 17, 2020): 1365. http://dx.doi.org/10.3390/sym12081365.
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Optical properties of metal nanostructures, governed by the so-called localised surface plasmon resonance (LSPR) effects, have invoked intensive investigations in recent times owing to their fundamental nature and potential applications. LSPR scattering from metal nanostructures is expected to show the symmetry of the oscillation mode and the particle shape. Therefore, information on the polarisation properties of the LSPR scattering is crucial for identifying different oscillation modes within one particle and to distinguish differently shaped particles within one sample. On the contrary, the polarisation state of light itself can be arbitrarily manipulated by the inverse designed sample, known as metamaterials. Apart from polarisation state, external stimulus, e.g., magnetic field also controls the LSPR scattering from plasmonic nanostructures, giving rise to a new field of magneto-plasmonics. In this review, we pay special attention to polarisation and its effect in three contrasting aspects. First, tailoring between LSPR scattering and symmetry of plasmonic nanostructures, secondly, manipulating polarisation state through metamaterials and lastly, polarisation modulation in magneto-plasmonics. Finally, we will review recent progress in applications of plasmonic and magneto-plasmonic nanostructures and metamaterials in various fields.
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Sahar, Md Rahim, and S. K. Ghoshal. "Nanoglass: Present Challenges and Future Promises." Advanced Materials Research 1108 (June 2015): 45–58. http://dx.doi.org/10.4028/www.scientific.net/amr.1108.45.
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This presentation provides a panoramic overview of the recent progress in nanoglass plasmonics, challenges, excitement, applied interests and the future promises. A glimpse of our gamut research activities with some significant results is highlighted and facilely analyzed. The term'nanoglass'refers to the science and technology dealing with the manipulation of the physical properties of rare earth doped inorganic glasses by embedding metallic nanoparticles (NPs) or nanoclusters. On the other hand, the word'plasmonics'refer to the coherent coupling of photons to free electron oscillations (called plasmon) at the interface between a conductor and a dielectric. Nanoglass plasmonis being an emerging concept in advanced optical material of nanophotonics has given photonics the ability to exploit the optical response at nanoscale and opened up a new avenue in metal-based glass optics. There is a vast array of nanoglass plasmonic concepts yet to be explored, with applications spanning solar cells, (bio) sensing, communications, lasers, solid-state lighting, waveguides, imaging, optical data transfer, display and even bio-medicine. Localized surface plasmon resonance (LSPR) can enhance the optical response of nanoglass by orders of magnitude as observed. The luminescence enhancement and surface enhanced Raman scattering (SERS) are new paradigm of research. A thumbnail sketch of the fundamental aspects of SPR, LSPR, SERS and photonic applications of various rare earth doped/co-doped binary glasses containing metallic NPs are presented. The recent development in nanoglass in the context of Malaysia at the outset of international scenario is projected.
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Qi, Miao, Nancy Meng Ying Zhang, Kaiwei Li, Swee Chuan Tjin, and Lei Wei. "Hybrid Plasmonic Fiber-Optic Sensors." Sensors 20, no. 11 (June 8, 2020): 3266. http://dx.doi.org/10.3390/s20113266.
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With the increasing demand of achieving comprehensive perception in every aspect of life, optical fibers have shown great potential in various applications due to their highly-sensitive, highly-integrated, flexible and real-time sensing capabilities. Among various sensing mechanisms, plasmonics based fiber-optic sensors provide remarkable sensitivity benefiting from their outstanding plasmon–matter interaction. Therefore, surface plasmon resonance (SPR) and localized SPR (LSPR)-based hybrid fiber-optic sensors have captured intensive research attention. Conventionally, SPR- or LSPR-based hybrid fiber-optic sensors rely on the resonant electron oscillations of thin metallic films or metallic nanoparticles functionalized on fiber surfaces. Coupled with the new advances in functional nanomaterials as well as fiber structure design and fabrication in recent years, new solutions continue to emerge to further improve the fiber-optic plasmonic sensors’ performances in terms of sensitivity, specificity and biocompatibility. For instance, 2D materials like graphene can enhance the surface plasmon intensity at the metallic film surface due to the plasmon–matter interaction. Two-dimensional (2D) morphology of transition metal oxides can be doped with abundant free electrons to facilitate intrinsic plasmonics in visible or near-infrared frequencies, realizing exceptional field confinement and high sensitivity detection of analyte molecules. Gold nanoparticles capped with macrocyclic supramolecules show excellent selectivity to target biomolecules and ultralow limits of detection. Moreover, specially designed microstructured optical fibers are able to achieve high birefringence that can suppress the output inaccuracy induced by polarization crosstalk and meanwhile deliver promising sensitivity. This review aims to reveal and explore the frontiers of such hybrid plasmonic fiber-optic platforms in various sensing applications.