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Journal articles on the topic 'Phosphine-sulfonate'

Author: Grafiati

Published: 6 September 2023

Last updated: 31 July 2025

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1

Römbke, Patric, Annette Schier, and Hubert Schmidbaur. "(Phosphine)Silver(I) Sulfonate Complexes." Zeitschrift für Naturforschung B 58, no. 1 (2003): 168–72. http://dx.doi.org/10.1515/znb-2003-0126.

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Abstract Phosphine)silver(I) organosulfonate complexes of the type (R3P)AgOS(O)2R’ have been prepared in good yields from the corresponding silver sulfonates and tertiary phosphines in dichloromethane solution [R3 = Ph3, Ph2(2-Py), Me2Ph, with R’ = 4-Me-C6H4; R = Ph, R’ = Et and 2,5-Me2-C6H4]. If ethanol is present in the reaction mixture, the products contain one equivalent of ethanol. The crystal structures of (Ph3P)AgOS(O)2(C6H4-4-Me)(EtOH) (1), and (Me2PhP)AgOS(O)2(C6H4-4- Me) (5) have been determined. Complex 1 is present as a dimer in which the monomeric units feature intermolecular Ag-O

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2

Yon, Marjorie, Claire Pibourret, Jean-Daniel Marty, and Diana Ciuculescu-Pradines. "Easy colorimetric detection of gadolinium ions based on gold nanoparticles: key role of phosphine-sulfonate ligands." Nanoscale Advances 2, no. 10 (2020): 4671–81. http://dx.doi.org/10.1039/d0na00374c.

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Specific interactions between sulfonate groups of phosphine-sulfonate ligands on the surface of Au nanoparticles and Gd<sup>3+</sup> ions allow the colorimetric detection of Gd<sup>3+</sup> ions at the μM level.

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3

Xia, Jian, Yixin Zhang, Xiaoqiang Hu, et al. "Sterically very bulky aliphatic/aromatic phosphine-sulfonate palladium catalysts for ethylene polymerization and copolymerization with polar monomers." Polymer Chemistry 10, no. 4 (2019): 546–54. http://dx.doi.org/10.1039/c8py01568f.

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4

Song, Guangzhi, Wenmin Pang, Weimin Li, Min Chen, and Changle Chen. "Phosphine-sulfonate-based nickel catalysts: ethylene polymerization and copolymerization with polar-functionalized norbornenes." Polymer Chemistry 8, no. 47 (2017): 7400–7405. http://dx.doi.org/10.1039/c7py01661a.

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5

Na, Yinna, Dan Zhang, and Changle Chen. "Modulating polyolefin properties through the incorporation of nitrogen-containing polar monomers." Polymer Chemistry 8, no. 15 (2017): 2405–9. http://dx.doi.org/10.1039/c7py00127d.

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6

Chen, Min, Wenping Zou, Zhengguo Cai, and Changle Chen. "Norbornene homopolymerization and copolymerization with ethylene by phosphine-sulfonate nickel catalysts." Polymer Chemistry 6, no. 14 (2015): 2669–76. http://dx.doi.org/10.1039/c5py00010f.

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7

Leonard, Nadia G., Grace V. Parker, Paul G. Williard, and Wesley H. Bernskoetter. "Coordination Chemistry of Iridium Phosphine–Sulfonate Complexes." Journal of Inorganic and Organometallic Polymers and Materials 24, no. 1 (2013): 157–63. http://dx.doi.org/10.1007/s10904-013-9966-y.

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8

Zhou, Xiaoyuan, Sébastien Bontemps, and Richard F. Jordan. "Base-Free Phosphine−Sulfonate Nickel Benzyl Complexes." Organometallics 27, no. 19 (2008): 4821–24. http://dx.doi.org/10.1021/om800741w.

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9

Rezabal, E., J. M. Ugalde, and G. Frenking. "The trans Effect in Palladium Phosphine Sulfonate Complexes." Journal of Physical Chemistry A 121, no. 40 (2017): 7709–16. http://dx.doi.org/10.1021/acs.jpca.7b06856.

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10

Zhu, Ling, Shuang Li, Xiaohui Kang, Wenzhen Zhang та Yi Luo. "A DFT Study of the Copolymerization of Methyl Vinyl Sulfone and Ethylene Catalyzed by Phosphine–Sulfonate and α-Diimine Palladium Complexes". Catalysts 13, № 6 (2023): 1026. http://dx.doi.org/10.3390/catal13061026.

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Density functional theory (DFT) calculations were comparatively carried out to reveal the origins of different catalytic performances from phosphine–benzene sulfonate (A, [{P^O}PdMe(L)] (P^O = Κ2-P,O-Ar2PC6H4SO3 with Ar = 2-MeOC6H4)) and α-diimine (B, [{N^N}PdMe(Cl)] (N^N = (ArN=C(Me)-C(Me)=NAr) with Ar = 2,6-iPr2C6H3)) palladium complexes toward the copolymerization of ethylene and methyl vinyl sulfone (MVS). Having achieved agreement between theory and experiment, it was found that the favorable 2,1-selective insertion of MVS into phosphine–sulfonate palladium complex A was due to there bein

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11

Bashir, Oumar, Laurence Piche, and Jerome P. Claverie. "18-Electron Ruthenium Phosphine Sulfonate Catalysts for Olefin Metathesis." Organometallics 33, no. 14 (2014): 3695–701. http://dx.doi.org/10.1021/om500212x.

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12

Ito, Shingo, Yusuke Ota, and Kyoko Nozaki. "Ethylene/allyl monomer cooligomerization by nickel/phosphine–sulfonate catalysts." Dalton Transactions 41, no. 45 (2012): 13807. http://dx.doi.org/10.1039/c2dt31771k.

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13

Du, Qing, Liping Zhao, Lihua Guo, et al. "Lysosome-targeted Cyclometalated Iridium (III) Anticancer Complexes Bearing Phosphine-Sulfonate Ligands." Applied Organometallic Chemistry 33, no. 2 (2018): e4746. http://dx.doi.org/10.1002/aoc.4746.

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14

Blaskó, Andrei, Clifford A. Bunton, Eduardo A. Toledo, Paul M. Holland, and Faruk Nome. "SN2 reactions of a sulfonate ester in mixed cationic/phosphine oxide micelles." J. Chem. Soc., Perkin Trans. 2, no. 12 (1995): 2367–73. http://dx.doi.org/10.1039/p29950002367.

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15

Anselment, Timo M. J., Christian Wichmann, Carly E. Anderson, Eberhardt Herdtweck, and Bernhard Rieger. "Structural Modification of Functionalized Phosphine Sulfonate-Based Palladium(II) Olefin Polymerization Catalysts." Organometallics 30, no. 24 (2011): 6602–11. http://dx.doi.org/10.1021/om200734x.

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16

Ravasio, Andrea, Laura Boggioni, and Incoronata Tritto. "Copolymerization of Ethylene with Norbornene by Neutral Aryl Phosphine Sulfonate Palladium Catalyst." Macromolecules 44, no. 11 (2011): 4180–86. http://dx.doi.org/10.1021/ma2006427.

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17

Skupov, Kirill M., Pooja R. Marella, Michel Simard, et al. "Palladium Aryl Sulfonate Phosphine Catalysts for the Copolymerization of Acrylates with Ethene." Macromolecular Rapid Communications 28, no. 20 (2007): 2033–38. http://dx.doi.org/10.1002/marc.200700370.

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18

Weng, Wei, Zhongliang Shen, and Richard F. Jordan. "Copolymerization of Ethylene and Vinyl Fluoride by (Phosphine-Sulfonate)Pd(Me)(py) Catalysts." Journal of the American Chemical Society 129, no. 50 (2007): 15450–51. http://dx.doi.org/10.1021/ja0774717.

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19

Luo, Shuji, Javier Vela, Graham R. Lief, and Richard F. Jordan. "Copolymerization of Ethylene and Alkyl Vinyl Ethers by a (Phosphine- sulfonate)PdMe Catalyst." Journal of the American Chemical Society 129, no. 29 (2007): 8946–47. http://dx.doi.org/10.1021/ja072562p.

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20

Zou, Chen, Wenmin Pang, and Changle Chen. "Influence of chelate ring size on the properties of phosphine-sulfonate palladium catalysts." Science China Chemistry 61, no. 9 (2018): 1175–78. http://dx.doi.org/10.1007/s11426-018-9237-6.

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21

Yang, Bangpei, Wenmin Pang, and Min Chen. "Redox Control in Olefin Polymerization Catalysis by Phosphine-Sulfonate Palladium and Nickel Complexes." European Journal of Inorganic Chemistry 2017, no. 18 (2017): 2510–14. http://dx.doi.org/10.1002/ejic.201700214.

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22

Chen, Min, Bangpei Yang, and Changle Chen. "Redox-Controlled Olefin (Co)Polymerization Catalyzed by Ferrocene-Bridged Phosphine-Sulfonate Palladium Complexes." Angewandte Chemie International Edition 54, no. 51 (2015): 15520–24. http://dx.doi.org/10.1002/anie.201507274.

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23

Chen, Min, Bangpei Yang, and Changle Chen. "Redox-Controlled Olefin (Co)Polymerization Catalyzed by Ferrocene-Bridged Phosphine-Sulfonate Palladium Complexes." Angewandte Chemie 127, no. 51 (2015): 15740–44. http://dx.doi.org/10.1002/ange.201507274.

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24

Tan, Chen, Muhammad Qasim, Wenmin Pang, and Changle Chen. "Ligand–metal secondary interactions in phosphine–sulfonate palladium and nickel catalyzed ethylene (co)polymerization." Polymer Chemistry 11, no. 2 (2020): 411–16. http://dx.doi.org/10.1039/c9py00904c.

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25

Liang, Tao, and Changle Chen. "Side-Arm Control in Phosphine-Sulfonate Palladium- and Nickel-Catalyzed Ethylene Polymerization and Copolymerization." Organometallics 36, no. 12 (2017): 2338–44. http://dx.doi.org/10.1021/acs.organomet.7b00294.

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26

Kochi, Takuya, Shusuke Noda, Kenji Yoshimura, and Kyoko Nozaki. "Formation of Linear Copolymers of Ethylene and Acrylonitrile Catalyzed by Phosphine Sulfonate Palladium Complexes." Journal of the American Chemical Society 129, no. 29 (2007): 8948–49. http://dx.doi.org/10.1021/ja0725504.

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27

Nakamura, Akifumi, Takeharu Kageyama, Hiroki Goto, Brad P. Carrow, Shingo Ito, and Kyoko Nozaki. "P-Chiral Phosphine–Sulfonate/Palladium-Catalyzed Asymmetric Copolymerization of Vinyl Acetate with Carbon Monoxide." Journal of the American Chemical Society 134, no. 30 (2012): 12366–69. http://dx.doi.org/10.1021/ja3044344.

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28

Lanzinger, Dominik, Marco M. Giuman, Timo M. J. Anselment, and Bernhard Rieger. "Copolymerization of Ethylene and 3,3,3-Trifluoropropene Using (Phosphine-sulfonate)Pd(Me)(DMSO) as Catalyst." ACS Macro Letters 3, no. 9 (2014): 931–34. http://dx.doi.org/10.1021/mz5004344.

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29

Yang, Bangpei, Shuoyan Xiong, and Changle Chen. "Manipulation of polymer branching density in phosphine-sulfonate palladium and nickel catalyzed ethylene polymerization." Polym. Chem. 8, no. 40 (2017): 6272–76. http://dx.doi.org/10.1039/c7py01281k.

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30

Xiao, Xieyi, Handou Zheng, Heng Gao, et al. "Recent Advances in Synthesis of Non-Alternating Polyketone Generated by Copolymerization of Carbon Monoxide and Ethylene." International Journal of Molecular Sciences 25, no. 2 (2024): 1348. http://dx.doi.org/10.3390/ijms25021348.

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The copolymers of carbon monoxide (CO) and ethylene, namely aliphatic polyketones (PKs), have attracted considerable attention due to their unique property and degradation. Based on the arrangement of the ethylene and carbonyl groups in the polymer chain, PKs can be divided into perfect alternating and non-perfect alternating copolymers. Perfect alternating PKs have been previously reviewed, we herein focus on recent advances in the synthesis of PKs without a perfect alternating structure including non-perfect alternating PKs and PE with in-chain ketones. The chain structure of PKs, catalytic

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31

Kochi, Takuya, Kenji Yoshimura, and Kyoko Nozaki. "Synthesis of anionic methylpalladium complexes with phosphine–sulfonate ligands and their activities for olefin polymerization." Dalton Trans., no. 1 (2006): 25–27. http://dx.doi.org/10.1039/b512452m.

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32

Rezabal, Elixabete, José M. Asua, and Jesus M. Ugalde. "Homopolymerization of Ethylene by Palladium Phosphine Sulfonate Catalysts: The Role of Structural and Environmental Factors." Organometallics 34, no. 1 (2014): 373–80. http://dx.doi.org/10.1021/om5011947.

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33

Sun, Jiajie, Min Chen, Gen Luo, Changle Chen, and Yi Luo. "Diphosphazane-monoxide and Phosphine-sulfonate Palladium Catalyzed Ethylene Copolymerization with Polar Monomers: A Computational Study." Organometallics 38, no. 3 (2019): 638–46. http://dx.doi.org/10.1021/acs.organomet.8b00796.

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34

Wu, Zixia, Min Chen, and Changle Chen. "Ethylene Polymerization and Copolymerization by Palladium and Nickel Catalysts Containing Naphthalene-Bridged Phosphine–Sulfonate Ligands." Organometallics 35, no. 10 (2016): 1472–79. http://dx.doi.org/10.1021/acs.organomet.6b00076.

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35

Kageyama, Takeharu, Shingo Ito, and Kyoko Nozaki. "Vinylarene/CO Copolymerization and Vinylarene/Polar Vinyl Monomer/CO Terpolymerization Using Palladium/Phosphine-Sulfonate Catalysts." Chemistry - An Asian Journal 6, no. 2 (2011): 690–97. http://dx.doi.org/10.1002/asia.201000668.

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36

Zhang, Randi, Rong Gao, Qingqiang Gou, Jingjing Lai, and Xinyang Li. "Recent Advances in the Copolymerization of Ethylene with Polar Comonomers by Nickel Catalysts." Polymers 14, no. 18 (2022): 3809. http://dx.doi.org/10.3390/polym14183809.

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The less-expensive and earth-abundant nickel catalyst is highly promising in the copolymerization of ethylene with polar monomers and has thus attracted increasing attention in both industry and academia. Herein, we have summarized the recent advancements made in the state-of-the-art nickel catalysts with different types of ligands for ethylene copolymerization and how these modifications influence the catalyst performance, as well as new polymerization modulation strategies. With regard to α-diimine, salicylaldimine/ketoiminato, phosphino-phenolate, phosphine-sulfonate, bisphospnine monoxide,

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37

Kapdi, Anant R., Shatrughn Bhilare, Santosh Kori, et al. "Scale-Up of a Heck Alkenylation Reaction: Application to the Synthesis of an Amino-Modifier Nucleoside ‘Ruth Linker’." Synthesis 52, no. 23 (2020): 3595–603. http://dx.doi.org/10.1055/s-0040-1707260.

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AbstractRuth linker is a C5 pyrimidine modified nucleoside analogue widely utilized for the incorporation of a primary amine in a synthetic oligonucleotide. The increasing demand for non-radioactive labeling, detection of biomolecules, and assembly of COVID-19 test kits has triggered a need for scale-up of Ruth linker. Herein, an efficient protocol involving a palladium-catalyzed Heck alkenylation is described. The synthesis has been optimized with a goal of low catalyst concentration, column-free isolation, high product purity, reproducibility, and shorter reaction time. The scalability and u

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38

Burke, Nichola J., Andrew D. Burrows, Mary F. Mahon, and John E. Warren. "Hydrogen bond network structures based on sulfonated phosphine ligands: The effects of complex geometry, cation substituents and phosphine oxidation on guanidinium sulfonate sheet formation." Inorganica Chimica Acta 359, no. 11 (2006): 3497–506. http://dx.doi.org/10.1016/j.ica.2006.01.008.

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39

Chang, Chun-Fang, Kenji Hamase та Makoto Tsunoda. "Analysis of Total Thiols in the Urine of a Cystathionine β-Synthase-Deficient Mouse Model of Homocystinuria Using Hydrophilic Interaction Chromatography". Molecules 25, № 7 (2020): 1735. http://dx.doi.org/10.3390/molecules25071735.

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Homocysteine and related thiols (cysteine, cysteinylglycine, and glutathione) in the urine of a cystathionine β-synthase (CBS)-deficient mouse model were quantified using hydrophilic interaction chromatography with fluorescence detection. Urine samples were incubated with tris(2-carboxyethyl) phosphine to reduce disulfide bonds into thiols. After deproteinization, thiols were fluorescently derivatized with ammonium 7-fluoro-2,1,3-benzoxadiazole-4-sulfonate (SBD-F). Homocysteine, cysteine, cysteinylglycine, and glutathione in mouse urine were analyzed using an amide-type column with a mobile ph

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40

Noda, Shusuke, Takuya Kochi, and Kyoko Nozaki. "Synthesis of Allylnickel Complexes with Phosphine Sulfonate Ligands and Their Application for Olefin Polymerization without Activators." Organometallics 28, no. 2 (2009): 656–58. http://dx.doi.org/10.1021/om800781b.

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41

Noda, Shusuke, Takuya Kochi, and Kyoko Nozaki. "Synthesis of Allylnickel Complexes with Phosphine Sulfonate Ligands and Their Application for Olefin Polymerization without Activators." Organometallics 28, no. 21 (2009): 6378. http://dx.doi.org/10.1021/om900860v.

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42

Cai, Zhengguo, Zhongliang Shen, Xiaoyuan Zhou, and Richard F. Jordan. "Enhancement of Chain Growth and Chain Transfer Rates in Ethylene Polymerization by (Phosphine-sulfonate)PdMe Catalysts by Binding of B(C6F5)3 to the Sulfonate Group." ACS Catalysis 2, no. 6 (2012): 1187–95. http://dx.doi.org/10.1021/cs300147c.

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43

Feng, Ge, Matthew P. Conley, and Richard F. Jordan. "Differentiation between Chelate Ring Inversion and Aryl Rotation in a CF3-Substituted Phosphine-Sulfonate Palladium Methyl Complex." Organometallics 33, no. 17 (2014): 4486–96. http://dx.doi.org/10.1021/om500699t.

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44

Vacher, Antoine, Anissa Amar, Franck Camerel, et al. "Modulation of emission properties of phosphine-sulfonate ligand containing copper complexes: playing with solvato-, thermo-, and mechanochromism." Dalton Transactions 48, no. 6 (2019): 2128–34. http://dx.doi.org/10.1039/c8dt04502j.

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45

Xia, Jian, Yixin Zhang, Jianfu Zhang, and Zhongbao Jian. "High-Performance Neutral Phosphine-Sulfonate Nickel(II) Catalysts for Efficient Ethylene Polymerization and Copolymerization with Polar Monomers." Organometallics 38, no. 5 (2019): 1118–26. http://dx.doi.org/10.1021/acs.organomet.8b00916.

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46

Mehmood, Andleeb, Xiaowei Xu, Xiaohui Kang, and Yi Luo. "Origin of different chain-end microstructures in ethylene/vinyl halide copolymerization catalysed by phosphine–sulfonate palladium complexes." New Journal of Chemistry 44, no. 39 (2020): 16941–47. http://dx.doi.org/10.1039/d0nj03350b.

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Ethylene and vinyl halide (VX, X = F or Cl) copolymerization mechanism in the presence of catalysts A ((PO<sup>OMe,OMe</sup>)PdMe, PO<sup>OMe,OMe</sup> = {2(2-MeOC<sub>6</sub>H<sub>4</sub>)(2-SO<sub>3</sub>-5-MeC<sub>6</sub>H<sub>3</sub>)P}) and A′ ((PO<sup>Bp,OMe</sup>)PdMe, PO<sup>Bp,OMe</sup> = {(2-MeOC<sub>6</sub>H<sub>4</sub>)(2-{2,6-(MeO)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>}C<sub>6</sub>H<sub>4</sub>)(2-SO<sub>3</sub>-5-MeC<sub>6</sub>H<sub>3</sub>)P}) has been comparatively studied via density functional theory (DFT) calculations.

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47

Chen, Min, and Changle Chen. "Rational Design of High-Performance Phosphine Sulfonate Nickel Catalysts for Ethylene Polymerization and Copolymerization with Polar Monomers." ACS Catalysis 7, no. 2 (2017): 1308–12. http://dx.doi.org/10.1021/acscatal.6b03394.

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48

Du, Qing, Yuliang Yang, Lihua Guo, et al. "Fluorescent half-sandwich phosphine-sulfonate iridium(III) and ruthenium(II) complexes as potential lysosome-targeted anticancer agents." Dyes and Pigments 162 (March 2019): 821–30. http://dx.doi.org/10.1016/j.dyepig.2018.11.009.

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49

Pfeiffer, Christine M., Dan L. Huff, S. Jay Smith, Dayton T. Miller, and Elaine W. Gunter. "Comparison of Plasma Total Homocysteine Measurements in 14 Laboratories: An International Study." Clinical Chemistry 45, no. 8 (1999): 1261–68. http://dx.doi.org/10.1093/clinchem/45.8.1261.

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Abstract Background: Information on interlaboratory variation and especially on methodological differences for plasma total homocysteine is lacking. Methods: We studied 14 laboratories that used eight different method types: HPLC with electrochemical detection (HPLC-ED); HPLC with fluorescence detection (HPLC-FD) further subdivided by type of reducing/derivatizing agent; gas chromatography/mass spectrometry (GC/MS); enzyme immunoassay (EIA); and fluorescence polarization immunoassay (FPIA). Three of these laboratories used two methods. The laboratories participated in a 2-day analysis of 46 pl

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50

Zong, Yanlin, Chaoqun Wang, Yixin Zhang, and Zhongbao Jian. "Polar-Functionalized Polyethylenes Enabled by Palladium-Catalyzed Copolymerization of Ethylene and Butadiene/Bio-Based Alcohol-Derived Monomers." Polymers 15, no. 4 (2023): 1044. http://dx.doi.org/10.3390/polym15041044.

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Polar-functionalized polyolefins are high-value materials with improved properties. However, their feedstocks generally come from non-renewable fossil products; thus, it requires the development of renewable bio-based monomers to produce functionalized polyolefins. In this contribution, via the Pd-catalyzed telomerization of 1,3-butadiene and three types of bio-based alcohols (furfuryl alcohol, tetrahydrofurfuryl alcohol, and solketal), 2,7-octadienyl ether monomers including OC8-FUR, OC8-THF, and OC8-SOL were synthesized and characterized, respectively. The copolymerization of these monomers

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