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Relevant bibliographies by topics / Phosphine-sulfonate

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Journal articles

Academic literature on the topic 'Phosphine-sulfonate'

Author: Grafiati

Published: 6 September 2023

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Journal articles on the topic "Phosphine-sulfonate"

1

Römbke, Patric, Annette Schier, and Hubert Schmidbaur. "(Phosphine)Silver(I) Sulfonate Complexes." Zeitschrift für Naturforschung B 58, no. 1 (January 1, 2003): 168–72. http://dx.doi.org/10.1515/znb-2003-0126.

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Abstract Phosphine)silver(I) organosulfonate complexes of the type (R3P)AgOS(O)2R’ have been prepared in good yields from the corresponding silver sulfonates and tertiary phosphines in dichloromethane solution [R3 = Ph3, Ph2(2-Py), Me2Ph, with R’ = 4-Me-C6H4; R = Ph, R’ = Et and 2,5-Me2-C6H4]. If ethanol is present in the reaction mixture, the products contain one equivalent of ethanol. The crystal structures of (Ph3P)AgOS(O)2(C6H4-4-Me)(EtOH) (1), and (Me2PhP)AgOS(O)2(C6H4-4- Me) (5) have been determined. Complex 1 is present as a dimer in which the monomeric units feature intermolecular Ag-O donor/acceptor bonding in a four-membered ring. The coordination sphere of the silver atoms is further complemented by an ethanol molecule which is also engaged in hydrogen bonding with one of the sulfonate oxygen atoms. The solvent-free complex 5 is associated into helical chains via Ag-O coordinative bonds which provide the silver atoms with a distorted planar T-shaped coordination.

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2

Yon, Marjorie, Claire Pibourret, Jean-Daniel Marty, and Diana Ciuculescu-Pradines. "Easy colorimetric detection of gadolinium ions based on gold nanoparticles: key role of phosphine-sulfonate ligands." Nanoscale Advances 2, no. 10 (2020): 4671–81. http://dx.doi.org/10.1039/d0na00374c.

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Specific interactions between sulfonate groups of phosphine-sulfonate ligands on the surface of Au nanoparticles and Gd³⁺ ions allow the colorimetric detection of Gd³⁺ ions at the μM level.

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3

Xia, Jian, Yixin Zhang, Xiaoqiang Hu, Xin Ma, Lei Cui, Jianfu Zhang, and Zhongbao Jian. "Sterically very bulky aliphatic/aromatic phosphine-sulfonate palladium catalysts for ethylene polymerization and copolymerization with polar monomers." Polymer Chemistry 10, no. 4 (2019): 546–54. http://dx.doi.org/10.1039/c8py01568f.

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4

Song, Guangzhi, Wenmin Pang, Weimin Li, Min Chen, and Changle Chen. "Phosphine-sulfonate-based nickel catalysts: ethylene polymerization and copolymerization with polar-functionalized norbornenes." Polymer Chemistry 8, no. 47 (2017): 7400–7405. http://dx.doi.org/10.1039/c7py01661a.

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5

Na, Yinna, Dan Zhang, and Changle Chen. "Modulating polyolefin properties through the incorporation of nitrogen-containing polar monomers." Polymer Chemistry 8, no. 15 (2017): 2405–9. http://dx.doi.org/10.1039/c7py00127d.

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6

Chen, Min, Wenping Zou, Zhengguo Cai, and Changle Chen. "Norbornene homopolymerization and copolymerization with ethylene by phosphine-sulfonate nickel catalysts." Polymer Chemistry 6, no. 14 (2015): 2669–76. http://dx.doi.org/10.1039/c5py00010f.

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7

Leonard, Nadia G., Grace V. Parker, Paul G. Williard, and Wesley H. Bernskoetter. "Coordination Chemistry of Iridium Phosphine–Sulfonate Complexes." Journal of Inorganic and Organometallic Polymers and Materials 24, no. 1 (October 2, 2013): 157–63. http://dx.doi.org/10.1007/s10904-013-9966-y.

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8

Zhou, Xiaoyuan, Sébastien Bontemps, and Richard F. Jordan. "Base-Free Phosphine−Sulfonate Nickel Benzyl Complexes." Organometallics 27, no. 19 (October 13, 2008): 4821–24. http://dx.doi.org/10.1021/om800741w.

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9

Rezabal, E., J. M. Ugalde, and G. Frenking. "The trans Effect in Palladium Phosphine Sulfonate Complexes." Journal of Physical Chemistry A 121, no. 40 (October 2, 2017): 7709–16. http://dx.doi.org/10.1021/acs.jpca.7b06856.

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10

Zhu, Ling, Shuang Li, Xiaohui Kang, Wenzhen Zhang, and Yi Luo. "A DFT Study of the Copolymerization of Methyl Vinyl Sulfone and Ethylene Catalyzed by Phosphine–Sulfonate and α-Diimine Palladium Complexes." Catalysts 13, no. 6 (June 20, 2023): 1026. http://dx.doi.org/10.3390/catal13061026.

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Density functional theory (DFT) calculations were comparatively carried out to reveal the origins of different catalytic performances from phosphine–benzene sulfonate (A, [{P^O}PdMe(L)] (P^O = Κ2-P,O-Ar2PC6H4SO3 with Ar = 2-MeOC6H4)) and α-diimine (B, [{N^N}PdMe(Cl)] (N^N = (ArN=C(Me)-C(Me)=NAr) with Ar = 2,6-iPr2C6H3)) palladium complexes toward the copolymerization of ethylene and methyl vinyl sulfone (MVS). Having achieved agreement between theory and experiment, it was found that the favorable 2,1-selective insertion of MVS into phosphine–sulfonate palladium complex A was due to there being less structural deformations in the catalyst and monomer. Both the MVS and ethylene insertions were calculated, and the former was found to be more favorable for chain initiation and chain propagation. In the case of α-diimine palladium system B, the resulting product of the first MVS insertion was quite stable, and the stronger O-backbiting interaction hampered the insertion of the incoming ethylene molecule. These computational results are expected to provide some hints for the design of transition metal copolymerization catalysts.

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