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Dissertations / Theses on the topic 'Phase rule and equilibrium'

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Published: 4 June 2021

Last updated: 1 August 2024

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1

Chu, Jennifer Hsing-chung. "Phase behavior and binary interaction energies of copolymer blends /." Digital version accessible at:, 1999. http://wwwlib.umi.com/cr/utexas/main.

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2

Sankarasubramanian, R. "Symmetry-Breaking Transitions In Equilibrium Shapes Of Coherent Precipitates." Thesis, Indian Institute of Science, 2000. https://etd.iisc.ac.in/handle/2005/191.

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We present a general approach for determining the equilibrium shape of isolated, coherent, misfitting particles by minimizing the sum of elastic and interfacial energies using a synthesis of finite element and optimization techniques. The generality derives from the fact that there is no restriction on the initial or final shape, or on the elastic moduli of the particle and matrix, or on the nature of misfit. The particle shape is parameterized using a set of design variables which are the magnitudes of vectors from a reference point inside the particle to points on the particle/matrix interfa

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3

Sankarasubramanian, R. "Symmetry-Breaking Transitions In Equilibrium Shapes Of Coherent Precipitates." Thesis, Indian Institute of Science, 2000. http://hdl.handle.net/2005/191.

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We present a general approach for determining the equilibrium shape of isolated, coherent, misfitting particles by minimizing the sum of elastic and interfacial energies using a synthesis of finite element and optimization techniques. The generality derives from the fact that there is no restriction on the initial or final shape, or on the elastic moduli of the particle and matrix, or on the nature of misfit. The particle shape is parameterized using a set of design variables which are the magnitudes of vectors from a reference point inside the particle to points on the particle/matrix interfa

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4

Billman, John Frederick. "Structure and phase behavior in microemulsions /." Thesis, Connect to this title online; UW restricted, 1990. http://hdl.handle.net/1773/9825.

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5

Maeda, Nobuo. "Phase transitions of long-chain n-alkanes at interfaces." View thesis entry in Australian Digital Theses Program, 2001. http://thesis.anu.edu.au/public/adt-ANU20011203.151921/index.html.

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6

Hong, Seung-pyo. "Role of hydrocarbon structures in gas solvent + hydrocarbon multiphase equilibria /." Access abstract and link to full text, 1992. http://0-wwwlib.umi.com.library.utulsa.edu/dissertations/fullcit/9303400.

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7

Variankaval, Narayan. "Structure and thermodynamics of associating solutions : prediction of phase equilibria." Diss., Georgia Institute of Technology, 2001. http://hdl.handle.net/1853/8304.

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8

Bhansali, Anil P. "Heat transfer resulting from a turbulent, submerged jet impinging on a phase change material." Diss., Georgia Institute of Technology, 1994. http://hdl.handle.net/1853/19568.

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9

Bush, David Martin. "Phase equilibria of solid-supercritical carbon dioxide solutions." Diss., Georgia Institute of Technology, 1997. http://hdl.handle.net/1853/12075.

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10

Smith, Richard Lee Jr. "Measurement and correlation of critical states." Diss., Georgia Institute of Technology, 1985. http://hdl.handle.net/1853/10099.

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11

Sommacal, Silvano. "Computational petrology : subsolidus equilibria in the upper mantle /." View thesis entry in Australian Digital Theses Program, 2004. http://thesis.anu.edu.au/public/adt-ANU20050415.151025/index.html.

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12

D'Souza, Rupert. "Separation of fructose from glucose using supercritical solvents." Diss., Georgia Institute of Technology, 1986. http://hdl.handle.net/1853/21530.

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13

Chandler, Karen. "Phase equilibria of alkanes in supercritical carbon dioxide determined from chromatographic data." Thesis, Georgia Institute of Technology, 1995. http://hdl.handle.net/1853/11160.

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14

Du, Rand Marlie. "High pressure fluid phase equilibria." Thesis, Stellenbosch : Stellenbosch University, 2000. http://hdl.handle.net/10019.1/51789.

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Thesis (MScEng)--University of Stellenbosch, 2000.<br>ENGLISH ABSTRACT: Supercritical extraction is being investigated as a possible alternative to the processes currently used in the fractionation of paraffinic waxes. By removing the lighter carbon fractions from the wax, the wax hardness will be improved and its melting temperature range reduced, hence improving the performance of the wax product in certain applications. In order to evaluate and operate such an extraction process optimally, it is necessary to have a thermodynamic model that accurately represents the process system. Th

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15

Fulakis, Chris. "A theoretical analysis of combined melting and vaporization using the boundary element method." Thesis, This resource online, 1993. http://scholar.lib.vt.edu/theses/available/etd-09052009-040759/.

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16

Fall, David J. "An experimental study of the phase equilibria behavior of binary mixtures containing carbon dioxide and hydrocarbons /." Access abstract and link to full text, 1985. http://0-wwwlib.umi.com.library.utulsa.edu/dissertations/fullcit/8506426.

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17

Estrera, Susana Santos. "Multiphase equilibria thermodynamics in prototype rich gas + hydrocarbon mixtures /." Access abstract and link to full text, 1987. http://0-wwwlib.umi.com.library.utulsa.edu/dissertations/fullcit/8801650.

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18

Fall, Jaimie Linn. "Multiphase equilibria in binary and ternary hydrocarbon systems containing carbon dioxide /." Access abstract and link to full text, 1985. http://0-wwwlib.umi.com.library.utulsa.edu/dissertations/fullcit/8603795.

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19

Sukhadia, Tejas. "Prediction of phase equilibria in solutions : an associative reformulation of thermodynamic theories of solutions." Diss., Georgia Institute of Technology, 1998. http://hdl.handle.net/1853/11886.

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20

Smith, Vicky S. "Solid-fluid equilibria in natural gas systems." Diss., Georgia Institute of Technology, 1995. http://hdl.handle.net/1853/10095.

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21

Janert, Philipp Klaus. "Phase behavior of homopolymer/diblock blends /." Thesis, Connect to this title online; UW restricted, 1997. http://hdl.handle.net/1773/9763.

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22

Jangkamolkulchai, Adisak. "The occurrence and influence of multiple fluid phases in the phase of equilibria of CO2and rich gas-hydrocarbon systems /." Access abstract and link to full text, 1988. http://0-wwwlib.umi.com.library.utulsa.edu/dissertations/fullcit/8809460.

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23

Miller, Melanie Marie. "Multiphase equilibria behavior of carbon dioxide and ethane + hydrocarbon binary and ternary mixtures /." Access abstract and link to full text, 1988. http://0-wwwlib.umi.com.library.utulsa.edu/dissertations/fullcit/8825490.

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24

Wang, Xichun. "Application of MPCM slurry with cooled ceiling to realize a low energy building design." online access from Digital Dissertation Consortium, 2008. http://libweb.cityu.edu.hk/cgi-bin/er/db/ddcdiss.pl?3341125.

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25

Hansson, Robert. "Phase equilibria of zincite containing systems relevant to zinc/lead smelting /." [St. Lucia, Qld.], 2005. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe19174.pdf.

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26

Mirabelli, Thomas G. "The effect of gravity on the evolution of pore and grain structure during liquid-phase sintering." Thesis, Georgia Institute of Technology, 1999. http://hdl.handle.net/1853/20021.

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27

Oh, Minseok. "Growth kinetics of intermetallic phases in the Cu-Sn binary and the Cu-Ni-Sn ternary systems at low temperatures." access full-text online access from Digital Dissertation Consortium, 1994. http://libweb.cityu.edu.hk/cgi-bin/er/db/ddcdiss.pl?9513132.

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28

Swanson, Karl. "Analytical modeling of thermal storage systems for high power density portable electronics." abstract and full text PDF (free order & download UNR users only), 2008. http://0-gateway.proquest.com.innopac.library.unr.edu/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:1460783.

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29

Lam, Daniel H. "Multiphase equilibrium behavior of ethane, nitrous oxide and carbon dioxide + n-alkanol binary and ternary mixtures /." Access abstract and link to full text, 1990. http://0-wwwlib.umi.com.library.utulsa.edu/dissertations/fullcit/9034205.

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30

Tewari, Asim. "Effect of micro-gravity on the microstructural evolution during liquid phase sintering." Diss., Georgia Institute of Technology, 1999. http://hdl.handle.net/1853/18969.

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31

Nascimento, Barreto Maria do. "Modulated structures." Thesis, University of Oxford, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.670400.

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32

Gendron, François-Xavier. "Contribution à la discrimination chirale à l'état solide et accès aux énantiomères pures par cristallisation." Thesis, Normandie, 2018. http://www.theses.fr/2018NORMR032/document.

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Le besoin d’accès aux énantiomères purs a largement augmenté depuis les années 90. Les procédés ayant recours à la cristallisation sont souvent moins cher mais tout aussi efficace que les autres procédés. Deux études ont été réalisées dans cette thèse : -La première concerne l’amélioration d’un procédé déjà établi. En effet, l’efficacité de la Cristallisation Préférentielle (PC) de conglomérat est connue. Néanmoins, son application à des solutions solides images l’une de l’autre dans un miroir est plus complexe. Est présenté le premier exemple de PC réalisée sur un système à solution solide c

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33

Mäder, Urs Karl. "Carbon dioxide and carbon dioxide-water mixtures : |b P-V-T properties and fugacities to high pressure and temperature constrained by thermodynamic analysis and phase equilibrium experiments." Thesis, University of British Columbia, 1990. http://hdl.handle.net/2429/30629.

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The thermophysical properties of supercritical CO₂ and H₂O-CO₂ mixtures are reviewed and their computation and prediction improved through theory and experiment. A resolution is attempted among inconsistencies between and within data sets, including P-V-T measurements, phase equilibrium experiments and equations of state. Pure carbon dioxide: Equations of state for CO₂ (Kerrick & Jacobs, 1981; Bottinga & Richet, 1981; Holloway, 1977) are based solely on P-V-T data up to 8 kbar and lead to deviations from phase equilibrium data at pressures greater than 10-20 kbar. Mathematical programming an

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34

Veatch, Sarah Louise. "Liquid immiscibility in model bilayer lipid membranes /." Thesis, Connect to this title online; UW restricted, 2004. http://hdl.handle.net/1773/9772.

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35

Tran, Thao T. "Acetone planar laser-induced fluorescence and phosphorescence for mixing studies of multiphase flows at high pressure and temperature." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/24737.

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Thesis (Ph.D.)--Aerospace Engineering, Georgia Institute of Technology, 2008.<br>Committee Chair: Seitzman, Jerry; Committee Member: Jagoda, Jechiel; Committee Member: Lieuwen, Tim; Committee Member: Menon, Suresh; Committee Member: Tan, David.

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36

Gupta, Niraj. "First Principles Study of Metastable Beta Titanium Alloys." Thesis, University of North Texas, 2015. https://digital.library.unt.edu/ark:/67531/metadc804949/.

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The high temperature BCC phase (b) of titanium undergoes a martensitic transformation to HCP phase (a) upon cooling, but can be stabilized at room temperature by alloying with BCC transition metals such as Mo. There exists a metastable composition range within which the alloyed b phase separates into a + b upon equilibrium cooling but not when rapidly quenched. Compositional partitioning of the stabilizing element in as-quenched b microstructure creates nanoscale precipitates of a new simple hexagonal w phase, which considerably reduces ductility. These phase transformation reactions have been

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37

Allanson, Oliver Douglas. "Theory of one-dimensional Vlasov-Maxwell equilibria : with applications to collisionless current sheets and flux tubes." Thesis, University of St Andrews, 2017. http://hdl.handle.net/10023/11916.

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Vlasov-Maxwell equilibria are characterised by the self-consistent descriptions of the steady-states of collisionless plasmas in particle phase-space, and balanced macroscopic forces. We study the theory of Vlasov-Maxwell equilibria in one spatial dimension, as well as its application to current sheet and flux tube models. The ‘inverse problem' is that of determining a Vlasov-Maxwell equilibrium distribution function self-consistent with a given magnetic field. We develop the theory of inversion using expansions in Hermite polynomial functions of the canonical momenta. Sufficient conditions fo

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38

Benages, Vilau Raúl. "Growth, Morphology and Solid State Miscibility of Alkali Nitrates." Doctoral thesis, Universitat de Barcelona, 2013. http://hdl.handle.net/10803/129370.

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This PhD thesis is focused in structural aspects of alkali nitrates. In the first chapter, we recollected the most important advancement in this field in alkali nitrates compounds published since 1970. Along this lines, crystal structure, polymorphism and phase transition is discussed first; second, crystal growth, and third, the morphology. And, finally a section concerning solid state miscibility and binary phase diagrams between these compounds is presented. The following chapters present a deeper study of growth morphology and how the impurities affect to the morphology and growth rate. T

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39

Wylock, Christophe. "Contribution à l'étude des transferts de matière gaz-liquide en présence de réactions chimiques." Doctoral thesis, Universite Libre de Bruxelles, 2009. http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/210257.

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Le bicarbonate de soude raffiné, produit industriellement par la société Solvay, est fabriqué dans des colonnes à bulles de grande taille, appelées les colonnes BIR.<p>Dans ces colonnes, une phase gazeuse contenant un mélange d’air et dioxyde de carbone (CO2) est dispersée sous forme de bulles dans une solution aqueuse de carbonate et de bicarbonate de sodium (respectivement Na2CO3 et NaHCO3). Cette dispersion donne lieu à un transfert de CO2 des bulles vers la phase liquide. Au sein des colonnes, la phase gazeuse se répartit dans deux populations de bulles :des petites bulles (diamètre de que

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40

Plée, Vincent. "Prédiction du comportement de phases et des enthalpies de mélange de gaz naturels atypiques contenant de l'argon, du monoxyde de carbone et de l'hélium." Thesis, Université de Lorraine, 2014. http://www.theses.fr/2014LORR0186/document.

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Le développement du modèle prédictif E-PPR78, basé sur une méthode de contribution de groupe, a été entrepris depuis plus de dix ans pour prédire le comportement de systèmes multiconstituants. Ce modèle repose sur l'équation d'état de Peng-Robinson dans sa version de 1978 et les règles de mélanges de Van der Waals. Il utilise un seul paramètre d'interaction binaire, kij, qui dépend de la température. Afin de permettre au modèle E-PPR78 de prédire le comportement du gaz naturel, trois nouveaux groupes sont ajoutés : le monoxyde de carbone, l'hélium et l'argon. Pour cela, il a été nécessaire de

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41

Cebola, Maria Joao Dos Reis Matos. "Phase equilibrium in gas condensates." Thesis, Imperial College London, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.287214.

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42

Antunes, Nuno Dias. "Equilibrium and non-equilibrium aspects of early universe phase transitions." Thesis, University of Sussex, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.264553.

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43

Soga, K. Geoffrey (Kenneth Geoffrey). "Equilibrium phase separation in polymer brushes." Thesis, McGill University, 1996. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=40445.

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The equilibrium properties of polymers end-grafted to an impenetrable interface, the "polymer brush", are investigated. Relevant concepts and techniques of statistical polymer physics are discussed; in particular, a simulation technique that is very efficient for studying polymer brushes is introduced. This technique is demonstrated through simulations of a well characterized polymer brush system. The results of original investigations of phase separation in polymer brushes are also presented. An instability in the lateral monomer density of a polymer brush is observed under sufficiently poor

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44

Ho, Gutiérrez Iris V. (Iris Violeta). "Equilibrium compositions in two-phase partition." Thesis, McGill University, 1992. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=60712.

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The partition behavior of aqueous and organic ternary solutions into two immiscible phases at ambient temperatures was studied. A classification system of the types of materials which phase partition water and organic solvents was developed and a comprehensive list of systems for which phase diagram information is available in the literature has been presented.<br>Systems in three different classes of materials were studied. Equilibrium phase diagrams, tie-lines and plait points were generated for the ternary systems: poly(ethylene glycol)-1,000/sodium sulfate/water at 28$ sp circ$C; poly(ethy

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45

Hook, Daniel William. "Phase transitions in quantum microcanonical equilibrium." Thesis, Imperial College London, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.497906.

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46

Elkins, Linda Tarbox. "Phase equilibrium investigation of ternary feldspars." Thesis, Massachusetts Institute of Technology, 1987. http://hdl.handle.net/1721.1/57924.

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47

Zain, Husni K. "Phase equilibrium studies at moderate pressures." Thesis, Aston University, 1992. http://publications.aston.ac.uk/9743/.

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The theory of vapour-liquid equilibria is reviewed, as is the present status or prediction methods in this field. After discussion of the experimental methods available, development of a recirculating equilibrium still based on a previously successful design (the modified Raal, Code and Best still of O'Donnell and Jenkins) is described. This novel still is designed to work at pressures upto 35 bar and for the measurement of both isothermal and isobaric vapour-liquid equilibrium data. The equilibrium still was first commissioned by measuring the saturated vapour pressures of pure ethanol and cy

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48

Rafaquat, Mohammed. "Phase equilibrium studies at normal pressures." Thesis, Aston University, 1991. http://publications.aston.ac.uk/9734/.

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A total pressure apparatus has been developed to measure vapour-liquid equilibrium data on binary mixtures at atmospheric and sub-atmospheric pressures. The method gives isothermal data which can be obtained rapidly. Only measurements of total pressure are made as a direct function of composition of synthetic liquid phase composition, the vapour phase composition being deduced through the Gibbs-Duhem relationship. The need to analyse either of the phases is eliminated. As such the errors introduced by sampling and analysis are removed. The essential requirements are that the pure components be

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49

Tavares, Cabral JoaÌƒo Pedro Beija. "Polymer mixtures : dynamics, equilibrium & phase separation." Thesis, Imperial College London, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.272209.

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50

Kwon, Seok Joon. "Phase-equilibrium-mediated assembly of colloidal nanoparticles." Thesis, Massachusetts Institute of Technology, 2013. http://hdl.handle.net/1721.1/86862.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemical Engineering, 2013.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>Colloidal dispersion of nanoparticles (CNPs) has interesting properties both in terms of fundamental studies and industrials applications. Particular focus on the phase equilibrium and separation dynamics of CNPs has been necessary for understanding how exactly and fast CNPs are assembled and for controlling the assembly structure and dynamic properties. For understanding and controlling assembly structure and dynam

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