Dissertations / Theses on the topic 'Petrology - South Africa - Kaapvaal Craton'

Kimberlites are igneous rocks that originate by small degrees of melting of the mantle. Notably, kimberlites carry large variety of crustal and mantle xenoliths. Geochemical data on xenoliths can provide insights into the processes occurring in the subcontinental lithosphere (SCLM) and deeper. The Kaapvaal craton in South Africa hosts one of the best-studied kimberlite populations on Earth. In this thesis, a total of 24 thin sections of peridotite xenoliths from Group I Letlhakane, Letseng, Premier and Frank Smith kimberlites were investigated to constrain the pressure, temperature and depth of these mantle xenoliths. To do so, olivine, orthopyroxene, clinopyroxene, garnet and spinel were analyzed for their major element chemistry using electron microprobe analysis (EPMA). P-T calculations were performed using the PTEXL3 spreadsheet program, which contains different geothermobarometers. Depth constraints were fitted to the characteristic Kaapvaal craton geotherm. According to geochemical results and rough modal mineral estimations, the majority of the mantle xenoliths were identified as depleted harzburgites or lherzolites. Mineral major element compositions show trends of depletion, which correlate with the corresponding mantle xenolith sampling depth. Olivine and orthopyroxene have high average Mg# values of 92.1 and 93.0, respectively, at shallower depth ~70–160 Km. Below ~160 km, Mg# starts to drop rapidly and transition towards a more typical asthenospheric composition. The majority of garnet compositions fall into the G9 classification field. Titanium shows a distinct partition trend that correlates with depletion. Garnets have well developed alteration reaction rims, especially at shallower depths. Geothermobarometric calculations for four-phase peridotites are comparable with the results from other studies. However, the temperature estimates obtained by T(BKN90) are slightly overestimated and, in contrast, the pressure estimates from P(BBG08) are slightly underestimated. Other assemblages have considerable calculated pressure and temperature conditions and were best fitted for the regional conductive geotherm. The mantle xenoliths show pressures ranging from 22 to 56 kb and temperatures from 753 to 1344 °C that characterize an extensive sampling depth range from 70 to 190 km. Three of the samples extend into the diamond stability field. The obtained P-T data for mantle xenoliths cluster along a 44.0±2.0 mWm⁻² conductive Kaapvaal craton continental geotherm, being slightly higher than that of the average thermal state estimate for the craton.

>Magister Scientiae - MSc
The group of granites on the eastern margin of the Mesoproterozoic Namaqua sector of the polydeformed and highly metamorphosed Namaqua-Natal Province of southern Africa is known as the Keimoes Suite. The suite includes mixtures of diverse rock types not belonging to a single intrusive series and so it should be subdivided into more than one intrusive suite. The exact definition, extent, distribution and petrogenesis of these granites have been poorly defined in the past, with various authors defining the suite differently due to the lack of proper geochronology and geochemical data. The exact contact between the Namaqua sector and Kaapvaal Craton together with the role of the suite to the Namaqua tectonic evolution is still unclear. The granites of the Keimoes Suite are thought to mark the contact between the Namaqua sector and the Kaapvaal Craton. This study seeks to address the above mentioned problems by making use of new geochronology, isotope, major and trace element geochemistry together with petrography. The granites of the Keimoes Suite were previously grouped based on their degree of deformation. The geochronology, undertaken as part of this study, has proven that this classification is unfounded. The degree of foliation in these granites appears to be largely controlled by the abundance of platy minerals, such as biotite and muscovite, together with the intrusion mechanism, with deformational processes, such as shearing, playing a secondary role. The geochronology, together with geochemistry has helped to redefine the previously defined Keimoes Suite so that two well defined separate suites are recognized and the third is poorly defined due to lack of more samples of that age group. The new classification or grouping of the granites of the eastern Namaqua sector allows a more detailed examination of the tectonic evolution of this region. A member of the 1225 to 1200 Ma early syn-tectonic granites, the Josling Granite, shows a strongly developed foliation and was derived from a depleted source with a relatively low continental crustal component. This granite intruded during the time of arc accretion, and is associated with, and partly responsible for the D₁ deformation and M₁ metamorphism recognized in most of the rocks of the eastern terranes of the Namaqua sector. In terms of age, the syn-tectonic granites of the Augrabies Suite extend from 1200 to 1120 Ma and were largely derived from depleted sources with variable but more substantial amounts of continental crustal components as compared to the early syn-tectonic granite. The granites of this suite intruded during the period of peak D₂ deformation with peak magmatism between 1180 - 1135 Ma, and particularly around 1150 Ma, during the peak of metamorphism (M₂) caused by, and associated with these voluminous intrusions. The Keimoes Suite can now be defined as comprising granites of late- to post-tectonic age relative to the 1.2 - 1.08 Ga Namaquan Orogeny with magmatism occurring on the western side of the Kaapvaal Craton. The 1116 to 1066 Ma Keimoes Suite intruded during the stage of the Namaquan Orogeny in which there was continued indentation of the Kaapvaal Craton into the Namaqua sector with wrenching and shearing causing the development of rifting into which the granites intruded. The Keimoes Suite granites were derived from continental crustal sources and incorporated varying degrees of depleted source components. The intrusives and extrusives of this age occured after the main collisional event between the Namaqua Sector and the Kaapvaal Craton and are associated with the D₃ deformational event, imparting the thermal conditions leading to the M₃ metamorphic event of the rocks within both the Kakamas and Areachap Terranes. The suites mark the suture between the Archean Kaapvaal Craton and the Proterozoic Namaqua sector. The compositions of the granites of the individual suites were mainly controlled by the source with the degree of partial melting exerting a major control. The proportion of entrained peritectic assemblages and accessory minerals played a major role in controlling the compositions of the granites, particularly those of the trace elements. Variations within the compositions of the same suite are due to source heterogeneities. Generally, fractionation processes played a secondary role in influencing the composition of the granites.
Council for Geoscience and National Research Foundation

>Magister Scientiae - MSc
The Proterozoic Namaqua-Natal Province comprises highly deformed rocks of medium to high grade metamorphism and is bordering the Archean Kaapvaal Craton to the west, south and east in South Africa. The sector to the west of the Craton, namely the Namaqua Sector, is structurally complex and subdivided from west to east into the Bushmanland Subprovince, the Kakamas and Areachap terranes of the Gordonia Subprovince and the Kheis Subprovince. The prominent Neusberg Mountain Range, with exposures to the north and south of the Orange River in the Kakamas Terrane constitutes evidence of crustal shortening as a result of continental collision of the Namaqua Sector block with the Kaapvaal Craton during the Namaquan Orogeny. The Mesoproterozoic Korannaland Group in the Kakamas Terrane is affected by faulting, folding and shearing.

The MRS/MISS of the Makgabeng Formation encompasses sand cracks, wrinkle marks, mat fragments, mat chips and roll-ups and those of the Magaliesberg formation are wrinkle marks, petees/petee ridges, sand cracks, and multi-directional ripples. The sedimentary process that moderated the formational mechanism of the MISS of the Makgabeng Formation is (descriptively allochthonous) of high energy (inter-dune depositional setting) that eroded, transported and re-deposited mat bound sediments. The genetic mechanism of the MISS of the Magaliesberg Formation is descriptively authochthonous because of enhanced resistance of biostabilized sediments to being reworked. XRF (major and trace) and XRD analysis (qualitative and quantitative) was done on MISS bearing sedimentary rock layers (A) and underlying sedimentary sections (B) of Magaliesberg and Makgabeng samples. Result show high quartz content of all the analyzed samples compared to average sandstones. This premise suggests a relation of microbes (e.g. cyanobacteria) to phototrophy and/photoautotrophy because of the conduction properties of translucent quartz. Also plausible inference is that the intense chemical weathering that produced the quartz arenite was positively influenced by microbes, as noted in some Proterozoic basins. There is higher concentration of Ba in all A samples compared to B (Makgabeng and Magaliesberg) which might be emblematic of biogenicity. The Magaliesberg analyzed samples (MAG 101, 102, 103) exhibit homogeneity by the higher concentration of Al2O3, TiO2, K2O, and P2O5, and lower concentration of SiO2 in the A compared to the B subsamples of a particular sample. Also, Magaliesberg analyzed samples (MAG 101, 102, 103) exhibit homogeneity by the lower concentration of quartz and higher concentration of muscovite in the A compared to the B subsamples. This exact established negative correlation between the duo of SiO2 and quartz, and the quartet of Al2O3, TiO2, K2O, and P2O5, and muscovite as in Magaliesberg samples pertains also to a Makgabeng sample (MKG 102; roll-up). MKG 101 (mat fragment) deviates from this mineralogical and geochemical trend. Each of the A samples of MAG 101, 102, 103, are uniformly of higher concentration in Ce, Cr, Nb, Th, V, Y, Zn, Zr compared to the B version of that sample. MKG 101 and 102 are uniformly of lower concentration of Ce, Cr, Nb, Th, V, Y, Zn, Zr in A compared to the B version of that sample. The A of each of the samples MAG 101, 102, and 103 has higher concentration of Hf and Rb compared to its B; a character that is also exhibit in MKG 102, and MKG 101 is vice versa. Microscopy shows that A of all the samples is of smaller grain size compared to B, espousing affinity of microbes to fine-medium grained sandstones. Microscopy of the Magaliesberg Formation samples show Pseudo petee ridges and pseudo cross lamination which reflect biostabilization, and microscopy of the Makgabeng Formation show roll-ups, mat chips and composite mat chips. The MISS genetic difference of the two formations is related to energy, water residence time (emergence and inundation), Ph, and similarity is related to mutuality in shallow water environment. Mat types are inferred to be biologically, physically and chemically moderated adaptations of microbial communities to specific cum peculiar locally prevailing environmental conditions; factors that are premised on taphonomy and ecology.
Dissertation (MSc)--University of Pretoria, 2014.
tm2015
Geology
MSc
Unrestricted

With an estimated erupted volume of 300,000 km3 and an areal extent of more than 200,000 km2, the Paleoproterozoic (2.06 Ga) silicic volcanic rocks of the Rooiberg Group (Kaapvaal Craton) in northern South Africa forms one of the largest and to the same time oldest silicic large igneous provinces (SLIPs) known. This large volume of rocks can be sub-divided into four formations: the Dullstroom, Damwal, Kwaggasnek and Schrikkloof Formations. The results of this study show that a clear chemostratigraphy (by using major elements such as TiO2, SiO2, Na2O, K2O, P2O2, MgO, and Fe2O3) can be established in the area north of Loskop Dam, dividing the rocks of the study area into the Damwal, Kwaggasnek and Schrikkloof formations. The studied rocks are characterized by aphanitic lavas bearing amygdales, spherulitic textures and flow-bands with some sedimentary and pyroclastic interbeds. The dacites could mainly be described as high-Mg felsites (HMF), whereas the rhyolites could be described as low-Mg felsites (LMF). The negative Eu anomaly, Nb and Ta values of the upper part of the Rooiberg Group range between 5.38-24.2 and 0.45-1.86 ppm, respectively, similar to crustal compositions. Furthermore, Nb/Ta values range from 10.91-14.83 (also similar to typical crustal compositions) while few samples from the Damwal Formation exhibit higher values of 15.13-16.02, similar to mantle-derived compositions. Tectonic discriminant diagrams show that the rocks used in this study evolved from fractional crystallization of a mafic liquid although all samples plot in fields with crustal signatures. Plot of ƐNd and 87Sr/86Sr show a mantle-derived origin for the upper part of the Rooiberg Group. However, ƐNd values of the upper part of the Rooiberg Group range between ~-10 to ~-6, typical of crustal composition or continental basalts formed in the crust. From the results, the Rooiberg Group exhibit both mantle (as observed in the Dullstroom and lower Damwal formations) and crustal signatures as exhibited by the Kwaggasnek and Schrikkloof formations. This is interprested as a result of the interaction of the thick crust and a shallow mantle source within the Bushveld Province during magmatism. Furthermore, similarities in geochemical signatures between the Rooiberg Group and selected SLIPs around the world suggest a similar origin for SLIPs by fractional crystallization of a mafic melt and melted (or assimilated) crustal material.
Thesis (PhD)--University of Pretoria, 2017.
Geology
PhD
Unrestricted

M.Sc. (Geology)
The south-easternmost Kaapvaal Craton is composed of scattered inliers of Archaean basement granitoid-greenstone terrane exposed through Phanerozoic cover successions. In addition, erosional remnants of the supracrustal Mesoarchaean Pongola Supergroup unconformably overlay this granitoid-greenstone terrane in the same inliers. Into this crust a variety of Precambrian intrusions occur. These are comprised of SE-, ENE- and NE-trending dolerite dykes. Also, the Hlagothi Complex intrudes into Pongola strata in the Nkandla region, particularly the quartzites of the basal Mantonga Formation. The whole area, including Phanerozoic strata, has in turn been intruded by Jurassic sills and dykes related to the Karoo Large Igneous Province. All the rocks of the Archaean inliers, with the exception of the Jurassic sills and dykes have been subjected to greenschist facies metamorphism and deformation, with petrographic, Ar-Ar geochronologic and palaeomagnetic studies attesting to this. This metamorphism and deformation is associated with the Mesoproterozoic orogeny from the nearby Namaqua-Natal Mobile Belt located to the south. This orogeny has a decreasing influence with distance from the cratonic margin, and is highly variable from locality to locality. However, it is generally upper greenschist facies up to a metamorphic isograd 50 km from the craton margin. Overprints directions seen within the palaeomagnetic data confirm directions associated with the post-Pongola granitoids across the region and the Namaqua-Natal Mobile Belt. The dolerite dykes consist of several trends and generations. Up to five different generations within the three Precambrian trends have potentially been recognised. SEtrending dykes represent the oldest dyke swarm in the area, being cross-cut by all the other dyke trends. These dykes consist of two possible generations with similar basaltic to basaltic andesite geochemistry. They provide evidence of a geochemically enriched or contaminated magma having been emplaced into the craton. This is similar to SE-trending dolerite dyke swarms across the Barberton-Badplaas region to the north from literature. In northern KwaZulu-Natal the SE-trending dolerite dyke swarms have been geochronologically, geochemically and paleomagnetically linked to either ca. 2.95 or ca. 2.87 Ga magmatic events across the Kaapvaal Craton. The 2866 ± 2 Ma Hlagothi Complex is composed of a series of layered sills intruding into Nkandla sub-basin quartzites of the Pongola Supergroup. The sills consist of meta-peridotite, pyroxenite and gabbro. At least two distinct pulses of magmatism have been recognised in the sills from their geochemistry. The distinct high-MgO units are compositionally different from the older Dominion Group and Nsuze Group volcanic rocks, as well as younger Ventersdorp volcanic rocks. This resurgence of high-MgO magmatism is similar to komatiitic lithologies seen in the Barberton Greenstone Belt. It is indicative of a more primitive magma source, such as one derived from a mantle plume. A mantle plume would also account for the Hlagothi Complex and the widespread distribution of magmatic events of possible temporal and spatial similarity across the craton. Examples include the layered Thole Complex, gabbroic phases of the ca. 2990 to 2870 Ma Usushwana Complex, and the 2874 ± 2 Ma SE-trending dykes of northern KwaZulu-Natal already described above and dated herein. A generation of NE-trending dolerite dykes in northern KwaZulu-Natal can also be palaeomagnetically linked to this event with either a primary or overprint direction. Flood basalts seen within the upper Witwatersrand and Pongola Supergroups (i.e., Crown, Bird, Tobolsk and Gabela lavas) may also be related. This large, voluminous extent of magmatism allows us to provide evidence for a new Large Igneous Province on the Kaapvaal Craton during the Mesoarchaean. This new Large Igneous Province would encompass all of the above mentioned geological units. It is possible that it could be generated by a shortlived transient mantle plume(s), in several distinct pulses. This plume would also explain the development of unconformities within the Mozaan Group. This is reasoned through thermal uplift from the plume leading to erosion of the underlying strata, culminating in the eruption of flood basalts coeval to the Hlagothi Complex. Marine incursion and sediment deposition would occur during thermal subsidence from the plume into the Witwatersrand-Mozaan basin. This magmatic event also assists in resolving the apparent polar wander path for the Kaapvaal Craton during the Meso- to Neoarchaean. Between existing poles established for the older ca. 2.95 Ga Nsuze event, to poles established for the younger ca. 2.65 Ga Ventersdorp event, a new magnetic component for this ca. 2.87 Ga magmatic event can be shown. This new component has a virtual geographic pole of 23.4° N, 53.4° E and a dp and dm of 8.2° and 11.8° for the Hlagothi Complex, with a similar magnetic direction seen in one generation of NE-trending dolerite dykes in the region. This new ca. 2870 Ma addition to the magmatic barcode of the Kaapvaal Craton allows for comparisons to be made to other coeval magmatic units on cratons from around the world. Specific examples include the Millindinna Complex and the Zebra Hills dykes on the Pilbara Craton. Precise age dating and palaeomagnetism on these magmatic units is needed to confirm a temporal and spatial link between all the events. If substantiated, this link would assist in further validating the existence of the Vaalbara supercraton during the Mesoarchaean. After the Hlagothi Complex event, different pulses of magma can be seen associated with the Neoarchaean Ventersdorp event. A generation of NE-trending dolerite dykes in the region was dated herein at 2652 ± 11 Ma. In addition, a primary Ventersdorp virtual geographic pole established in Lubnina et al. (2010) from ENE-trending dolerite dykes was confirmed in this study. This ENE-trending dolerite dyke has a virtual geographic pole of 31.7° S, 13.6° E and a dp and dm of 7.0° and 7.2°. This date and virtual geographic poles from NE- and ENE-trending dolerite dyke swarms in northern KwaZulu-Natal match up with NE- and E-trending palaeostress fields seen in the Neoarchaean Ventersdorp and proto- Transvaal volcanics by Olsson et al. (2010). Both generations of dolerite dykes also demonstrate variable geochemistry. The NE-trending dolerite dyke swarm is tholeiitic, and the ENE dolerite dyke swarm is calc-alkaline. In addition, some of the tholeiitic NE-trending dolerite dykes have a similar magnetic component to NE-trending dolerite dykes much further to the north in the Black Hills area according to Lubnina et al. (2010). This magnetic component is also similar to the Mazowe dolerite dyke swarm on the Zimbabwe Craton. The NE-trending dolerite dykes in the Black Hills area differ geochemically from those in northern KwaZulu-Natal though, but are also of ca. 1.90 Ga age. The Mazowe dolerite dyke swarm was linked to the dyke swarm of the Black Hills dyke swarm through palaeomagnetic studies. The Mazowe dolerite dyke swarm however is geochemically similar to the NE-trending dolerite dykes of northern KwaZulu-Natal, creating greater complexity in the relationship between the three dyke swarms. It is clear from the complex array of dolerite dyke swarms and other intrusions into these Archaean inliers of northern KwaZulu-Natal, that much more work on the dykes within the south-easternmost Kaapvaal Craton needs to be done. This will resolve these complex patterns and outstanding issues with regard to their palaeo-tectonic framework.

M.Sc.
The Kaapvaal craton is one of few regions on earth with an almost continuous record of wellpreserved supracrustal rocks ranging in age from ~3.5 Ga to the late Paleoproterozoic at ~1.75 Ga. In this study diagenetic carbonates from the Paleoarchean Buck Reef Chert and Joe’s Luck Formation of the Swaziland Supergroup, the Mesoarchean Thalu and Promise Formations of the Mozaan/Witwatersrand Supergroups and the Paleoproterozoic Timeball Hill and Silverton Formations of the Transvaal Supergroup were sampled and analyzed. The aim of the study was to determine possible variations in the composition of the carbonates through time and their significance especially with regards to microbial activity in diagenetic systems in early Earth history. Results indicate similar petrographic observations and geochemical signatures in diagenetic carbonates of iron formations in the Buck Reef Chert, Joe’s Luck and Griquatown Iron Formation. The carbonates all tend to be siderites with iron derived from hydrothermal input and all are depleted in 13C relative to Peedee Belemnite standard. It suggested that siderite formed as a result of microbial respiration. Microbes degrade organic matter and reduce iron in this process. This resulted in the depletion in 13C and in the precipitation of siderite. However in order for iron reduction to have occurred the reduced iron first had to be oxidized. This most probably occurred through iron oxidizing chemolithoautotrophs under microaerophilic conditions. Diagenetic carbonate concretions of the Thalu and Promise Formations are manganiferous and are highly depleted in 13C relative to PDB. There is also strong evidence for hydrothermal input of manganese and iron into the system because of positive europium anomalies. The carbonates from both of the formations strongly suggest the presence of some free oxygen. The reasoning behind this conclusion is as follows: The depletion of 13C in the carbonates points to microbial decomposition of organic matter and manganese respiration (the decomposition of organic matter by microbial MnO2 reduction) is shown to be the most reasonable process that led to the formation of the carbonate concretions. The implication is that MnO2 must first have been precipitated and that can only be achieved in the presence of free oxygen with the oxidation reaction often catalyzed by manganese oxidizing chemolithoautotrophs. The carbonates of the Timeball Hill and Silverton Formationsare calcites ad contain little no iron. There is also little or no evidence for hydrothermal input and the basin appears to be a clastic dominated. It is generally accepted that a major rise in oxygen in the oceans and the atmosphere occurred at about 2.32 Ga. This rise in oxygen levels is reflected in the diagenetic calcite concretions of the Silverton Formation. Both iron and manganese reduction where not very effective because of the depletion in the basin water of these two elements, organic carbon taken up in the calcite concretions, indicated by negative δ13CPDB carbonate values, was most probably derived from aerobic and/or nitrate respiration. The most important conclusion from this study is that sufficient free oxygen and hence oxygenic photosynthesis were present to oxidize both Fe and Mn at least as far back as the Paleo-Mesoarchean.

A suite of mafic dykes occurs as a late component in a wellcharacterized trondhjemite–tonalite–diorite–granodiorite assemblage in the Johannesburg Dome of the central Kaapvaal Craton, southern Africa. The dykes have been subdivided into two sets, based on their orientation, and major and trace element geochemistry. Set 1 dykes are characterized by elevated SiO2, Al2O3 and TiO2, and particularly by enriched LILE and HSFE (e.g. Zr > 200 ppm, Nb > 20 ppm, Ba > 300 ppm), higher than in any of the accompanying felsic rocks. REE and trace element values for Set 1 dykes are similar to those for calc-alkaline lamprophyres. The Set 2 dykes have similar trace element distributions, but are significantly less enriched in general, and are broadly tholeiitic in composition, with enriched MgO (>11 wt.%) indicative of an olivine–phyric tholeiitic basaltic protolith. Field relationships and available U–Pb zircon geochronology indicate that the dykes are contemporaneous with components of the trondhjemitic host rocks, and with late granodiorites. The geochemical, geochronological and field petrological setting indicates partial melting of basaltic and eclogitic lithosphere at c. 3120 Myr ago in the basal Kaapvaal Craton, and subsequent emplacement into pre-existing c. 3430 Myr tonalitic to dioritic crust.

The provenance of the Neoarchaean Ventersdorp Supergroup and several age-related supracrustal successions was analysed to gain insight into the geotectonic evolution of the Kaapvaal Craton during the transition from the Archaean to Proterozoic Eras. The studied successions include, besides the siliciclastic formations of the Ventersdorp Supergroup, the upper Wolkberg and Buffelsfontein Groups, the Godwan Formation and the Schmidtsdrift Subgroup of the basal Transvaal Supergroup in Griqualand West. Petrographic, whole rock geochemical and Sm-Nd isotopic analyses were combined with SHRIMP U-Pb age dating of detrital zircons. Furthermore, Rb-Sr isotopic studies were carried out on carefully selected suites of samples from surface exposure or, wherever possible, on deep diamond drill core. The Ventersdorp Supergroup is an up to 5 km thick undeformed, only slightly metamorphosed volcano-sedimentary succession deposited on the Kaapvaal Craton between 2714 Ma and 2665 Ma. A lack of major time hiati to the underlying Mesoarchaean Witwatersrand Supergroup and covering Neoarchaean to Palaeoproterozoic Transvaal Supergroup render the Ventersdorp Supergroup very well suited for the investigation of the geotectonic evolution of the Kaapvaal Craton near the Archaean-Proterozoic boundary. This is supported by its excellent preservation, which also allowed detailed studies of sedimentological structures, such as seismites indicating Neoarchaean earthquakes. The provenance analyses carried out on the clastic formations of the Ventersdorp Supergroup point to a gradual change in tectonic evolution from typically Archaean to post-Archaean processes rather than a drastic, unique transition in the case of the Kaapvaal Craton. Texturally immature wackes of the Kameeldoorns Formation, representing the oldest clastic units of the Ventersdorp Supergroup, are derived mainly from Mesoarchaean source rocks, whereas the stratigraphically younger Bothaville Formation displays geochemical signatures comparable with Archaean trondhjemite-tonalite granodiorite-suites (TTGs), thus suggesting crustal addition in the so-called ‘Archaean-style’. The extension of provenance analyses to supracrustal successions that are tentatively correlated with the Bothaville Formation, revealed contributions from granitoid V sources that formed under post-Archaean and Archaean conditions. Furthermore, the geochemical data for all analysed formations support a passive margin setting. Arc settings, as indicated in some samples, are due to the input of less fractionated volcanic material that provides evidence of distal volcanism. Analyses of Nd-isotopic systematics and U-Pb ages of detrital zircons revealed a Mesoarchaean age for the source rocks of the formations. U-Pb age dating of detrital zircons of the Godwan Formation suggests that this formation is of Mesoarchaean age, and therefore not a correlative of the other Neoarchaean successions. Hence, the results suggest that the continental crust of the Kaapvaal Craton was thick enough since the Mesoarchaean (2.8 - 3.1 Ga) to allow long-term crustal recycling, and therefore modern plate tectonic processes could have operated earlier than on other well-studied cratonic blocks. During the Neoarchaean, however, crustal thickening of the Kaapvaal Craton took place by accretion of Archaean-style TTGs along the margins of the craton. Thus, Archaean and post-Archaean tectono-magmatic processes co-existed. Furthermore, the Neoarchaean supracrustal successions represent the first sedimentation events on an entirely stabilised and tectonically quiescent Kaapvaal Craton. Input from distal volcanic sources marks the last sign of volcanic activity prior to the craton-wide deposition of carbonate rocks of the Transvaal Supergroup. Geochronological data also imply a connection of the Neoarchaean Kaapvaal Craton to further cratonic blocks that may hold source rocks for the studied formations, as for some small age populations of older detrital zircons (ca. 3.1 - 3.4 Ga), no suitable source area could be identified on the Kaapvaal Craton itself. However, it seems unlikely that the Zimbabwe Craton was one of these cratonic blocks, because the Rb-Sr whole rock ages of all studied formations yield a model age of 2092 ± 55 Ma, which is thought to correspond to a craton-wide influence of the 2.05 Ga old Bushveld Igneous Complex on the Rb-Sr isotope systematics of all analysed clastic successions. This influence is apparently missing in the Southern and Central Marginal Zones of the Limpopo Belt, suggesting that the collision between the Kaapvaal and Zimbabwe Cratons only took place after the emplacement of the Bushveld Igneous Complex, i.e. after 2.05 Ga.
Dr. U. Zimmermann Prof. J. Gutzmer

Ph.D. (Geology)
Shear zone controlled hydrothermal alteration zones in the northern Kaapvaal craton (NKC) are developed in host rocks of vastly different chemical composition and metamorphic grade. Some carry appreciable Au and base metals and some are barren. Alteration zones in three different distinctive crustal zones were examined in detail to determine the controls of these two types of alteration. 1. The Matok Complex is situated in the southern marginal zone (SMZ) of the Limpopo Belt (LB), close to the zone of rehydration. Two major stages of hydrothermal alteration could be identified in local shear zones, a pervasive propylitization and a subsequent vein controlled quartzalbite alteration. The two-stage alteration occurred sometimes between the emplacement of the Matok Complex (2670 Ma) and the intrusion of unaltered mafic dykes (1900 Ma). Calculated isotopic compositions of the hydrothermal fluids indicate that magmatic ± meteoric waters as well as juvenile C02 were responsible for the establishment of the alteration zones. The fluids most probably were late magmatic fluids associated with the Matok magmatism. The propylitic alteration was accompanied by introduction of small amounts of CU + Au and represents an alteration type identical to that developed in porphyry copper deposits. The subsequent quartz-albite alteration was caused by extremely saline fluids which depleted the rocks of all the major and trace elements with exception of Si, Al, Na and Zr. 2. This chemical alteration pattern' contrasts with those developed in two alteration zones associated with economic gold mineralization in greenstone belts of the NKC (Sutherland and Pietersburg belts). At the Birthday and Eersteling gold mines, a biotite-calcite-quartz alteration is developed. The chemical pattern of the alteration is...

D.Phil.
The western margin of the Archean Kaapvaal Craton, at its contact with the polydeformed and metamorphosed Proterozoic Namaqua Province, is host to four volcanosedimentary successions of Mesoproterozoic age (1.1-1.3 Ga) that occur in close spatial and temporal association to each other. These are the Areachap Group, the Leerkrans Formation of the Wilgenhoutsdrif Group and the two volcanosedimentary successions that comprise the Koras Group. There has been protracted debate as to the exact nature, origin, age and tectonic evolution of these successions, particularly as they occur immediately adjacent to an important crustal suture. A comprehensive whole rock and isotope geochemical study, complemented by zircon-based geochronology where necessary, was thus carried out to characterize and compare the volcanic rocks associated with these four successions. The results are used to assess the role of the four volcanosedimentary successions during the development of the Mesoproterozoic suture between the Kaapvaal Craton and the Namaqua Province during the ~1.2-1.0 Ga Namaquan Orogeny. The geochemical study of the Areachap Group examined a suite of lithologies from different locations along the ~280km long outcrop belt, with the aim of testing the lateral continuity and integrity of this highly metamorphosed and deformed succession. As the bulk of the samples collected were from diamond drill core intersecting volcanogenic massive sulphide (VMS) Zn-Cu deposits it was only appropriate to extend the investigation to assess the metallogenesis and relation of these deposits to their host rock sequences. This included a survey of the sulphur isotope composition of sulphides and sulphates that comprise the Zn-Cu deposits. Furthermore, the architecture and origin of the world-class Copperton deposit, the largest Zn-Cu deposit of the Areachap Group, was examined. For this purpose, available literature data were collated and complemented by new geochemical and geochronological information. Sm-Nd isotopic systematics and U-Pb zircon ages suggest a coeval origin and close genetic link between the metavolcanic rocks of the Leerkrans Formation of the Wilgenhoutsdrif Group and the Areachap Group. Both successions record the establishment of an eastward-directed subduction zone on the western margin of the Kaapvaal Craton. The Areachap Group represents the highly metamorphosed and deformed remnants of a Mesoproterozoic (ca. 1.30-1.24 Ga) volcanic arc that was accreted onto the western margin of the Kaapvaal Craton at ~1.22-1.20 Ga, during the early stages of the Namaquan Orogeny. The igneous protoliths within the Areachap Group are low- to medium-K tholeiitic to calc-alkaline in composition ranging in composition from basaltic through to rhyolitic. Tholeiitic basalts, represented by volumetrically minor amphibolites within the succession have Sm-Nd isotopic characteristics indicative of derivation from a depleted mantle source as denoted by their positive Nd(t) values. The lithogeochemical results highlight the fact that, despite differences in lithological architecture on a local scale, the Areachap Group exhibits coherent geochemical characteristics along its entire strike length.

D.Phil.
The tectonic history of the Kheis Terrane and its relationship with the Namaqua-Natal Metamorphic Province (NNMP) along the western margin of the Kaapvaal Craton were the focus of this study. Major issues addressed in this study are the origin and timing of formation of the Kheis Terrane and the recognition and definition of terrane boundaries in the area. Results of detailed measured sections across the Kheis Terrane, heavy mineral provenance studies, 40Ar/39Ar analyses of metamorphic muscovite, U-Pb SHRIMP dating of detrital zircon grains from 12 samples from the Kheis- and Kakamas Terranes and one igneous body from the Kakamas Terrane are presented. A new stratigraphic unit, the Keis Supergroup, comprising the Olifantshoek-, Groblershoop- and Wilgenhoutsdrif Groups, is defined. The base of the Keis Supergroup is taken at the basal conglomerate of the Neylan Formation. The Mapedi- and Lucknow Formations, previously considered part of the Olifantshoek Group, are now incorporated into the underlying Transvaal Supergroup. The Dabep Fault was found not to represent a terrane boundary. Rather, the Blackridge Thrust represents the boundary between the rocks of the Kheis Terrane and the Kaapvaal Craton. Provenance studies indicate that the rocks of the Keis Supergroup were deposited along a passive continental margin on the western side of the Kaapvaal-Zimbabwe Craton with the detritus derived from a cratonic interior. Detrital zircon grains from the rocks of the Keis Supergroup of the Kheis Terrane all gave similar detrital zircon age populations of ~1800Ma to ~2300Ma and ~2500Ma to ~2700Ma. The Kaapvaal Craton most probably never acted as a major source area for the rocks of the Keis Supergroup because of the lack of Paleo- to Mesoarchean zircon populations in the Keis Supergroup. Most of the detrital zircon grains incorporated into the Keis Supergroup were derived from the Magondi- and Limpopo Belts and the Zimbabwe Craton to the northeast of the Keis basin. The rock of the Kakamas Terrane was derived from a totally different source area with ages of ~1100Ma to ~1500Ma and ~1700Ma to ~1900Ma which were derived from the Richtersveld- and Bushmanland Terranes as well as the ~1166Ma old granitic gneisses ofthe Kakamas Terrane. Therefore the rocks of the Kheis- and Kakamas Terranes were separated from each other during their deposition. Detrital zircon populations from the Sprigg Formation indicate that it this unit was deposited after the amalgamation of the Kheis- and Kakamas Terranes and therefore does not belong to the Areachap Group. Results provide clear evidence for a tectonic model characterised by the presence of at least two Wilson cycles that affeected the western margin of the Kaapvaal Craton in the interval between the extrusion of the Hartley lavas at 1.93Ga and the collision with the Richtersveld tectonic domain at ~1.13Ga. According to the revised plate tectonic model for the western margin of the Kaapvaal- Zimbabwe Craton, the Neylan Formation represents the initiation of the first Wilson Cycle, with rifting at ~1927Ma ago, on the western margin of the Kaapvaal-Zimbabwe Craton. The metasedimentary rocks of the Olifantshoek Group were deposited in a braided river environment which gradually changed into a shallow marine environment towards the top of the Olifantshoek Group in the Top Dog Formation. The metasedimentary rocks of the Groblershoop Group were deposited in a shallow, passive or trailing continental margin on the western side of the Kaapvaal-Zimbabwe Craton. The rocks of the Wilgenhoutsdrif Group overlie the Groblershoop Group unconformably. This unconformity is related to crustal warping as a volcanic arc, represented by the metavolcanics of the Areachap Group, approached the Kaapvaal-Zimbabwe Craton from the west. The rocks of the Keis Supergroup were deformed into the Kheis Terrane during the collision of the Kaapvaal-Zimbabwe Craton, Areachap Arc and the Kgalagadi Terrane to form the Kaapvaal-Zimbabwe-Kgalagadi Craton. This event took place sometime between 1290Ma, the age of deformed granites in the Kheis Terrane and 1172Ma, the initiation of rifting represented by the Koras Group. This is supported by 40Ar/39Ar analyses of metamorphic muscovite from the Kheis Terrane that did not provide any evidence for a ~1.8Ga old Kheis orogeny (an age commonly suggested in the past for this orogeny). This collisional event resulted in the deformation of the rocks of the Keis Supergroup into the Kheis Terrane sometime between 1290Ma and 1172Ma.The second Wilson cycle was initiated during rifting along the Koras-Sinclair-Ghanzi rift on the Kaapvaal-Zimbabwe-Kgalagadi Craton at ~1172Ma. It was followed soon after by the initiation of subduction underneath the Richtersveld cratonic fragment at ~1166Ma after which the rocks of the Korannaland Group were deposited. The closure of the oceanic basin between the Kaapvaal-Zimbabwe-Kgalagadi Craton and the Richtersveld cratonic fragment occurred about 50Ma later (~1113Ma, the age of neomorphic muscovite in the metasedimentary rocks of the Kakamas Terrane) and resulted in the large open folds characterising the Kheis terrane and NNMP. Detrital zircon populations in the Sprigg Formation show that this formation does not belong to the Areachap Group and that it was deposited after the closure of the oceanic basin between the Kaapvaal-Zimbabwe-Kgalagadi Craton and the Richtersveld cratonic fragment at ~1113Ma. The Areachap Group can be extended towards the north and into Botswana along the Kalahari line where it forms the boundary between the Kaapvaal-Zimbabwe Craton to its east and the Kgalagadi Terrane to its west. The Areachap Terrane is thus related to the collision of the Kaapvaal-Zimbabwe Craton and Kgalagadi Terrane and was deformed a second time during the oblique collision of the Richtersveld cratonic fragment with the combined Kaapvaal-Zimbabwe-Kgalagadi Craton. The extension of the Areachap Group to the north along the Kalahari line opens up new exploration prospects for Coppertontype massive sulphide deposits underneath the Kalahari sand.

A thesis submitted to the Faculty of Science, University of the Witwatersrand, Johannesburg in fulfilment of the requirements for the degree of Doctor of Philosophy, 2020
An attempt was made to place the proposed tectono-sedimentary evolution of the Free State Goldfield and the Witwatersrand Basin into the context of the geodynamic evolution of the Kaapvaal Craton, including the Zimbabwe Craton and Limpopo Central Zone Terrane, as all share a common and linked geodynamic evolution since the Neoarchaean. This was achieved through a comprehensive compilation and synthesis of a large published and unpublished geoscientific dataset. The outcome is a plate-tectonic reconstruction of the geodynamic evolution of the Kaapvaal and Zimbabwe cratons(and the southern African lithosphere in general) in time and relative space, since their stabilisation as protocratons in the Neoarchaean at ~3.1 Ga until present time, is summarised pictorially in a series of palaeogeographic and palaeogeologic reconstruction ‘time-slice’ maps to provide a perspective not previously available (Appendices 20-A –20-Z). For each time period of the reconstructed sequential geodynamic evolution, these ‘time-slice’ maps show: (1) Archaean continental/cratonic crust, (2) the main structures that were active, (3) the lithostratigraphic units that were deposited, and (4) areas of juvenile crust formation within regions of magmatic-arc/back-arc basin development. Gaps indicate areas, of unknown extent, inferred to have been occupied by either oceanic crust or lost fragments of continental crust that separated the continental crust at the time. Note: Given their illegibility, all time-slice maps presented in A3 format as Appendices 20-A –20-Z are available digitally in PDF file format on the supplementary CD.A summary of geochronological ages used for the plate-tectonic reconstruction is divided into various epochs and/or orogenic cycles (i.e. Archaean, Palaeoproterozoic, Kibaran, etc.) for the Kaapvaal and Zimbabwe cratons, and the Limpopo Central Zone Terrane separately, and is presented in tabular format in Appendices 21-A –21-C respectively. A proposed correlation of Palaeoproterozoic-Mesoproterozoic (~2.6-1.45 Ga) stratigraphic units and tectonic events within the Kaapvaal, Rehoboth, Zimbabwe, Pilbara, Yilgarn, Singhbhum, Bastar and Dharwar cratons, as well as the Limpopo Central Zone Terrane, is provided in Appendix 22.Summariesof Palaeoproterozoic (syn-Transvaal Supergroup; ~2.49-2.41 Ga) formation and resetting ages reported from the Kaapvaal and Zimbabwe cratons and Limpopo Central Zone Terraneare presented in Appendices23-A and 23-B, respectively. A summary of Palaeo-to Mesoproterozoic (post-Transvaal Supergroup; ~2.1-1.0 Ga) deformation events reported from the area of the Witwatersrand Basin and Bushveld Complex (i.e., central Kaapvaal Craton) and their correlation with far field stress related to the Magondi and Okwa orogenies, Bushveld Complex emplacement, and Vredefort meteorite impact, as well as Kheis, Kibaran and Lomanian (Namaqua-Natal) orogeniesis presented in Appendix 24. Summaries of Palaeo-to Mesoproterozoic (post-Transvaal Supergroup; ~2.1-1.0 Ga) formation and resetting ages reported from the Kaapvaal Craton are presented in Appendices25-A and 25-B, respectively. A tectono-structural and terrane interpretation summary map for the Kaapvaal Craton, Limpopo Central Zone Terrane and Zimbabwe Craton, covering the countries of Botswana, Zimbabwe, South Africa, and parts of Mozambique, is presented in Appendix 26
CK2021