Academic literature on the topic 'PEDOT:PSS/Si'

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Journal articles on the topic "PEDOT:PSS/Si"

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Lu, Wenhui, Shuai Zhang, Enqi Dai, Bin Miao, Yiran Peng, Tao Pang, Tiansheng Zhang, et al. "Adjustable electrical characteristics in hybrid Si/PEDOT:PSS core/shell nanowire hetero-junctions." Journal of Materials Chemistry C 5, no. 16 (2017): 3932–36. http://dx.doi.org/10.1039/c7tc00376e.

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Si/PEDOT:PSS core/shell nanowire hetero-junctions with adjustable electrical characteristics are reported. They exhibit an ohmic behavior ascribed to p-type Si/PEDOT:PSS, whereas n-type Si/PEDOT:PSS displays a rectifying nature.
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Park, Na Yeon, Gwan Seung Jeong, Young-Jin Yu, Yoon-Chae Jung, Jin Hee Lee, Jung Hwa Seo, and Jea-Young Choi. "Photovoltaic Device Application of a Hydroquinone-Modified Conductive Polymer and Dual-Functional Molecular Si Surface Passivation Technology." Polymers 14, no. 3 (January 25, 2022): 478. http://dx.doi.org/10.3390/polym14030478.

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In the last decades, the conductive polymer PEDOT:PSS has been introduced in Si-based hybrid solar cells, gaining noticeable research interest and being considered a promising candidate for next generation solar cells which can achieve both of low manufacturing cost and high power conversion efficiency. This study succeeded in improving the electrical conductivity of PEDOT:PSS to 937 S/cm through a simple process of adding hydroquinone (HQ) to the pristine PEDOT:PSS solution. The results also showed that the addition of HQ to PEDOT:PSS(HQ-PEDOT:PSS) could not only dramatically improve the conductivity but also well-sustain the work function characteristics of PEDOT:PSS by promoting the formation of more continuous conductive-PEDOT channels without removing the insulating PSS. In this report, we reveal that the application of the HQ-PEDOT:PSS to the Si/PEDOT:PSS HSC could significantly improve the short-circuit current and open-circuit voltage characteristics to increase the power conversion efficiency of the HSCs compared to the conventional approaches. Moreover, we also treated the Si surface with the organic monomer, benzoquinone (BQ) to (1) passivate the excess Si surface defect states and (2) to improve the properties of the Si/PEDOT:PSS interface. We show that BQ treatment is able to dramatically increase the minority carrier lifetime induced by effective chemical and field-effect passivation in addition to enhancing the wettability of the Si surface with the PEDOT:PSS solution. As a result, the power conversion efficiency was increased by 10.6% by introducing HQ and BQ into the fabrication process of the Si/PEDOT:PSS HSC.
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Li, Jian Ying, Hao Yu, Juan Juan Wen, Zhi Dong Li, Zhen Cheng Xu, Ya Feng Zhang, Hang Yu, Bing Rui Lu, Ran Liu, and Yi Fang Chen. "Fabrication of Nano-Strctures on PEDOT:PSS Film by Nanoimprint Lithography." Advanced Materials Research 465 (February 2012): 287–91. http://dx.doi.org/10.4028/www.scientific.net/amr.465.287.

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It is very hard to fabricate nano-strctures on PEDOT:PSS film by conventional Nanoimprint Lithography for its non-thermoplastic property. Here we demonstrated a new nanoimprint process to pattern the PEDOT:PSS film at low temperature and low pressure by adding proper amount of Glycerol into PEDOT:PSS solution and pressing the Si-mold into Glycerol-PEDOT:PSS film under a pressure of 6.2Mpa for 45min at 80°C. We also compared our result to L. Tan and co-workers’. They found that positive replica was left on PEDOT:PSS film after pressing the Si-mold into Glycerol-PEDOT:PSS film under a pressure of 10Kpa for 5min at 80°C, but our work showed negative replica formed. Pressing time maybe is the critical reason to explain the different results. Holding the pressure longer gave the PEDOT:PSS enough time to flow into Si-mold and also gave Glycerol enough time to evaporate so that PEDOT:PSS became strong enough when separated the Si-mold from the PEDOT:PSS film. At last, Roman spectra was measured to confirm adding glycerol to PEDOT:PSS will not influence its molecular structure.
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Ryu, Beo Deul, Jung-Hwan Hyung, Min Han, Gil-Sung Kim, Nam Han, Kang Bok Ko, Ko Ku Kang, Tran Viet Cuong, and Chang-Hee Hong. "Long-term stability of Si-organic hybrid solar cells with a thermally tunable graphene oxide platform." RSC Advances 6, no. 76 (2016): 72342–50. http://dx.doi.org/10.1039/c6ra12441k.

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The PEDOT:PSS/Si solar cell with a rGO layer enhances the stability in a package-free device as the rGO layer with various annealing temperatures plays a critical role as a passivation layer in the PEDOT:PSS/Si interface.
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Li, Shuxin, Zhibin Pei, Fei Zhou, Ying Liu, Haibo Hu, Shulin Ji, and Changhui Ye. "Flexible Si/PEDOT:PSS hybrid solar cells." Nano Research 8, no. 10 (August 6, 2015): 3141–49. http://dx.doi.org/10.1007/s12274-015-0814-y.

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Ikeda, Natsumi, Tomoyuki Koganezawa, Daisuke Kajiya, and Ken-ichi Saitow. "Performance of Si/PEDOT:PSS Hybrid Solar Cell Controlled by PEDOT:PSS Film Nanostructure." Journal of Physical Chemistry C 120, no. 34 (August 23, 2016): 19043–48. http://dx.doi.org/10.1021/acs.jpcc.6b07101.

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Subramani, Thiyagu, Chen-Chih Hsueh, Hong-Jhang Syu, Chien-Ting Liu, Song-Ting Yang, and Ching-Fuh Lin. "Interface modification for efficiency enhancement in silicon nanohole hybrid solar cells." RSC Advances 6, no. 15 (2016): 12374–81. http://dx.doi.org/10.1039/c5ra23109d.

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In this paper, the interface between Si nanoholes (SiNHs) and poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is investigated and improved to achieve high-efficiency SiNH/PEDOT:PSS hybrid solar cells.
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Dai, Ruijie, Tengzuo Huang, Weijie Zhou, Jinpeng Yang, Hua Zhang, Fayin Yu, Anran Chen, et al. "Improved Interfacial Contact for Pyramidal Texturing of Silicon Heterojunction Solar Cells." Molecules 27, no. 5 (March 5, 2022): 1710. http://dx.doi.org/10.3390/molecules27051710.

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Reducing the surface reflectivity of silicon substrates is essential for preparing high-performance Si-based solar cells. We synthesized pyramid-nanowire-structured Si (Si-PNWs) anti-reflection substrates, which have excellent light-trapping ability (<4% reflectance). Furthermore, diethyl phthalate (DEP), a water-insoluble phthalic acid ester, was applied to optimize the Si-PNWs/PEDOT:PSS interface; the photoelectric conversion efficiency of heterojunction solar cells was shown to increase from 9.82% to 13.48%. We performed a detailed examination of the shape and optical characteristics of Si-PNWs, as well as associated photoelectric performance tests, to investigate the origin of performance improvements in Si-PNWs/PEDOT:PSS heterojunction solar cells (HSCs).
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Jung, Pil-Hoon, Yang Doo Kim, Hak-Jong Choi, Jae-Hyun Kim, and Heon Lee. "Effect of Si nanostructures on PEDOT:PSS Si hybrid solar cells." Thin Solid Films 616 (October 2016): 335–38. http://dx.doi.org/10.1016/j.tsf.2016.08.037.

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Jäckle, Sara, Martin Liebhaber, Jens Niederhausen, Matthias Büchele, Roberto Félix, Regan G. Wilks, Marcus Bär, Klaus Lips, and Silke Christiansen. "Unveiling the Hybrid n-Si/PEDOT:PSS Interface." ACS Applied Materials & Interfaces 8, no. 13 (March 23, 2016): 8841–48. http://dx.doi.org/10.1021/acsami.6b01596.

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Dissertations / Theses on the topic "PEDOT:PSS/Si"

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Слипченко, Н. И., Н. В. Герасименко, and А. Г. Донченко. "Аналитическая оценка КПД солнечного элемента PEDOT:PSS/Si." Thesis, Харьковский национальный университет радиоэлектроники, 2015. http://openarchive.nure.ua/handle/document/9018.

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В работе с помощью аналитического метода рассчитан КПД солнечного элемента на основе структуры PEDOT:PSS/Si, а также выполнены расчеты зависимости рабочих параметров фотопреобразователя от уровня легирования и концентрации ловушек.
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Cheng, Chieh-wen, and 鄭傑文. "Wafer-bonded PEDOT:PSS/GaAs thin-film hybrid solar cells and Wafer-scale PEDOT:PSS/Si hybrid solar cells." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/90953425913119300561.

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碩士
國立交通大學
應用化學系碩博士班
104
In recent years, development of hybrid solar cells which combines the advantages from inorganic materials and organic solar cells provides a simple, low temperature process to fabricate solar cell devices with reduced cost. Content of this thesis work was divided into two parts. In the first part, we demonstrated a PEDOT:PSS on GaAs thin film hybrid solar cells by using wafer bonding and chemical wet etching techniques. The thin film hybrid solar cells reached an excellent power conversion efficiency efficiency of 8.93% when an additional p+ Al0.3Ga0.7As epi-layer is deposited on the surface of the solar cells to provide a front-surface field. However, we uncovered that the bonding materials was able to diffuse into the GaAs thin film during the wafer-bonding stage, which led to the decrease in efficiency. In the second part of the thesis, we demonstrated an 4 inch PEDOT:PSS/silicon hybrid solar cell device by adding the DuPont Capstone FS-31 surfactant into the spin-coated PEDOT:PSS layer. Effects of the non-uniformity of the PEDOT:PSS layer on cell performance was investigated. The device achieved an overall conversion efficiency of 10.25% and a total output current and voltage of 26.23 mA/cm2 and 0.46 V, respectively. The as-made large-area solar cells benefits from the reduction in the fabrication time and cost, and particularly in preventing the pollution from the wafer-cutting.
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Huang, Pang-Hua, and 黃邦華. "Large-Area Hybrid PEDOT:PSS/Si Solar Cells Using Blade Coating." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/ppsjak.

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碩士
國立交通大學
光電系統研究所
106
Hybrid organic/ silicon solar cells employ low-temperature and solution processes and is compatible to be fabricated on bendable and thin substrates, making them promising candidates for future photovoltaic industry. However, scalability of hybrid solar cells has been limited by the uniformity of the organic thin film. In this work, we have developed a blade coating technique to expand the active area of the hybrid solar cells, from 1x1 cm2 up to 10x10 cm2 while minimizing the power loss upon scaling. First, an carbon-nanotube (CNT) doped poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) is employed as the hole conducting material for its high transparency and conductivity. The properties of CNT-doped PEDOT:PSS against the blade coating speed are tested, followed by the material modifications using surfactant and ethanol. By optimizing the amount of surfactant, we achieve a power conversion efficiency of 13.0% on a 1x1 cm2 device at the 200 nm/sec coating speed. Second, we scale up the cell area to 2x2 cm2 by optimizing the shadow ratio of the frontal silver grid, while controlling the uniformity of the film thickness at proper coating speed. An excellent PCE of 13.5% was achieved on the 2x2 cm2 device using 1wt% surfactant, 10% shadow ratio and 400 mm/s blade coating speed, showing an PCE enhancement factor of 13.4% compared to the spin coating process. Finally the film thickness and blade coating speed have been tested on a 6-inch silicon wafer for therealization of large-area hybrid solar cells. Preliminary results show that a cell with a 10x10cm2 active area exhibits a PCE of 6.9% possibly limited by the Ag grid design.
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Lin, An-Hua, and 林安樺. "Highly Efficient Back-Contact Cross-Finger Type PEDOT:PSS/Si Heterojunction Solar Cell." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/74081702605300287811.

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碩士
國立交通大學
應用化學系碩博士班
104
This thesis aims at the improvement of back-junction type PEDOT:PSS/Si hybrid solar cells, which was first proposed and demonstrated by Zieke and coworkers with a decent power conversion efficiency. The limited efficiency of current PEDOT:PSS/Si solar cells were basically due to the facts that the heterojunction was located on the front of the cell, resulting in a parasitic light absorption within the organic material. In addition, the rear surface of those front-junction solar cells was usually poorly passivated. To overcome above difficulties, one must place the PEDOT:PSS on the rear side of the device and the solar cell must be fabricated on a thin Si wafer to reduce carrier recombination. By adapting back contact cross-finger type PEDOT:PSS/Si heterostructures on thin Si wafers, we are able to reduce the shading loss to zero and enhance carrier collection. The absence of the metallization grid on the front side increases the short- circuit current (Jsc) of the cells dramatically. BackPEDOT cells with cross-finger type electrodes of different back emitter shading ratios were fabricated and tested. An optimized efficiency of 15.7% was achieved from cells with a shading ratio of 67%. It indicates that, at this particular shading ratio, diffusion lengths and carrier collection efficiency were optimized for both majority and minority carriers. By further increasing the width of Al electrodes from 200 um to 300 um and reducing the pitch between anode and cathode from 200 um to 150 um, the Fill Factor and efficiency of the BackPEDOT solar cells were further improved from 0.54 to 0.6 and from 15.7 % to 17.6%, respectively. Due to the cross-finger type electrodes employed on the devices, the rear side of the cells is not fully covered by the electrodes, which means that there are still exposed organic-silicon junction areas that can absorb sunlight. An efficiency of 1% was measured when the rear side of the solar cell was under 1.5AM illumination. Therefore, in principle, one can expect a total conversion efficiency of 18.6% when both sides of the cell are illuminated simultaneously.
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Hsu, Che-Wei, and 許哲瑋. "Highly Efficient PEDOT:PSS/GaAs Solar Cell by using Front-surface/Back-surface Field and Studies on the PEDOT:PSS/Si Interface Properties." Thesis, 2014. http://ndltd.ncl.edu.tw/handle/60061638060636494951.

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碩士
國立交通大學
應用化學系分子科學碩博士班
102
Research work presented in this thesis is divided into two parts: (1) to investigate the interface of PEDOT:PSS/Si using X-ray photoelectron spectroscopy and simulations. (2) to enhance the efficiency of PEDOT:PSS/GaAs solar cells by using front-surface and back-surface field. (1)In this study, results from X-ray photoelectron spectroscopy indicate that the unsaturated carbons of PEDOT are bonded with the electron-withdrawing groups. The Gaussian simulations also show that the HOMO and LUMO levels of the PEDOT are mostly contributed from the unsaturated carbons. Therefore, chemical reactions are most likely to take place on those unsaturated carbons. Based on preliminary results from X-ray photoelectron spectroscopy, Gaussian simulations, and VASP calculations, we speculate that the unsaturated carbons on the PEDOT interact with oxygen or silicon atoms of the silicon oxide. (2)Planar hybrid solar cells based on bulk GaAs wafers with a background doping density of 1016 cm-3 and poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate), which demonstrated an excellent power conversion efficiency of 8.46%. The efficiency of the cell was enhanced to 9.87% with a back-surface field feature using a molecular beam epitaxially grown n-type GaAs epi-layer. The efficiency and fill factor reaches a record high 11.86% and 0.8 when an additional p+ GaAs epi-layer is deposited on the surface of the solar cells to provide a front-surface field. The demonstrated hybrid solar cells that combine GaAs and conjugated polymers at low temperatures provide a possible alternative technology to simplify fabrication processes and reduce costs.
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Li, Chien, and 李謙. "The study of hybrid solar cells based on N-type Si substrate with PEDOT:PSS." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/su4ss9.

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碩士
國立清華大學
材料科學工程學系
105
Silicon is a high-performance material for solar cells. The hybrid solar cells combine the advantages of organic solar cells and inorganic solar cells. This study used PEDOT:PSS as the p-type organic semiconductor material and Si substrate as the n-type inorganic material to fabricate hybrid solar cells. Various device fabrication parameters were investigated systematically. We first discussed the influences of the native oxide forming time on the PEDOT:PSS coating. Then, we studied the influences of PEDOT:PSS coating spin rate and coating time on the device performance. The optimal device fabrication parameters were found to be a native oxide forming time of 4 hr and the PEDOT:PSS coating spin rate and time of 3000 rpm and 60 s, respectively. The Si/PEDOT:PSS solar cell based on the optimal fabrication parameters has exhibited a power conversion efficiency of 5.811%.
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Chang, Kai-Wen, and 張凱雯. "Highly efficient back-junction PEDOT:PSS/n-Si hybrid solar cell with omni-directional anti-reflection nanowire structures." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/n6r59t.

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碩士
國立交通大學
應用化學系分子科學碩博士班
106
Current poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS)/n-Si solar cells have limited efficiency because the heterojunction was located on the front of the cells that resulting in a parasitic light absorption within the organic material layer. And the rear surface of those front-junction solar cells was usually poorly passivated. To improve aforementioned shortcomings, we fabricated back-junction PEDOT:PSS/n-Si with front-surface field and SiNx anti-reflection layer but no front surface textures, which demonstrated a power conversion efficiency of over 11 %. By incorporating either a random pyramid or a nanowire anti-reflection structure to the front of the cell surface to enhance light absorption, the power conversion efficiencies were further enhanced to 13.9 % and 14.5 %, respectively. Moreover, cells with nanowire anti-reflection structure showed omni-directional light-trapping characteristics over the random pyramid structure and were able to maintain the power conversion efficiency even at an incident angle as large as 60 degrees. On the other hand, we also fabricated back-junction PEDOT:PSS/n-Si with back contact cross-finger type electrodes. Thus the front side of the devices would eliminate the shading loss and enhance carrier collection. However, the photovoltaic parameters of the cells were not improved as expected. It was attributed to the lacking of lateral diffusion driving force for carrier collection at the cross-finger type electrodes.
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古佩儒. "Pyramid nanostructures fabricated by UV-curing nanoimprint lithography and their applications on PEDOT:PSS/Si hybrid solar cells." Thesis, 2014. http://ndltd.ncl.edu.tw/handle/12577303339068294899.

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碩士
國立交通大學
應用化學系碩博士班
103
In recent years, highly efficient organic/inorganic hybrid solar cells were developed due to their low-temperature fabrication and low-cost processes. However, loss in light absorption due to the surface reflection is still the major concern for solar cells. It is known that the similar refractive index between interface result in the lower reflectivity. The pyramid-shaped nanostructures fabricated on the surface are able to provide graded refractive index and, therefore, reduce the surface reflection and increase light absorption.   In this report, we modified a Si substrate surface with pyramid nanostructures by combining the UV-curing nanoimprint lithography and chemical wet etching processes. The nanostructures improve anti-reflection effect and provide radial junction architecture that have enhanced light absorption and carrier collection efficiency. Compared with a planar device , the short circuit current density of the nanostructured device increase from 24.5 mA/cm2 to 34.8 mA/cm2.
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Chen, Kuan-Yu, and 陳冠妤. "Realization of a low-cost, high-conversion-efficiency solar cell by radial heterogeneous P-N junction of PEDOT:PSS/Si nanostructures." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/kuu93z.

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碩士
國立清華大學
材料科學工程學系
104
Recently, with further intensified energy crisis and consciousness of environmental protection, solar energy has caught much attention due to its non-polluting and highly abundant properties. However, an efficiency-to-cost ratio of photovoltaic techniques is still too low to substitute for fossil energy. Therefore, developing a cost-effective or high-efficient solar device has aroused many interests and become a must in the field of energy harvesting. Here, a potential candidate that combines a silicon substrate with a polymer layer as a heterojunction solar cell will be elaborated. In this study, a Si nanostructure/poly(3,4-ethylenedioxythiophene): poly(stylenesulfonate) (PEDOT:PSS) heterojunction solar cell is proposed and examined. First, different lengths of Si nanowire (SiNW) structures formed by metal-assisted chemical etching (MaCE) were fabricated to discuss a trade-off between light absorption efficiency and amounts of e--h+ recombination centers at surface defects. A solar device with 200 nm SiNWs possesses relatively low reflectance and less trapping defects, resulting in the best performance among the designed lengths of the NWs. Nonetheless, PEDOT:PSS cannot fully infiltrate into 200-nm-length SiNWs. Moreover, without passivation of PEDOT:PSS, there appear lots of surface defects at the bottom region of SiNWs. Hence, a step of post-KOH dipping is executed after the MaCE process to widen the spacing among SiNWs. Several lengths of SiNWs were used as starting substrates and devices with 150-nm-long nanostructures owned the best performance for both the starting substrates with the 200- and 300-nm-long SiNWs that might stem from suppressed surface recombination and also reduced contact resistance, benefiting from a better coverage of PEDOT:PSS on the surface of SiNWs. Moreover, influences from PEDOT:PSS as a hole transport layer are also discussed. In principle, the mobility of PEDOT:PSS (~10-2 cm2V-1S-1 for pristine film) is much smaller than Si’s (~103 cm2V-1S-1); thus, there exists a recombination region at the interface between Si and PEDOT:PSS due to the unbalanced mobility between an electron and a hole. Hence, in order to escalate the mobility of PEDOT:PSS, secondary dopants such as dimethyl sulfoxide (DMSO) and graphene oxide (GO) were mixed into PEDOT:PSS and a solar device based on the modified PEDOT:PSS of 0.2 wt% GO addition provided the best mobility and thus the best efficiency. Such Si nanostructure/PEDOT:PSS heterojunction solar cell could be simply fabricated via low temperature wet etching and spin-coating methods that can dramatically reduce fabrication cost. After optimizing the Si nanostructures and the amount of the secondary dopants, power conversion efficiency above 13% can be achieved and is believed to be ready for applications of energy harvesting.
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Book chapters on the topic "PEDOT:PSS/Si"

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Kumar, Anil, Kurias K. Markose, Irfan M. Khorakiwala, Bandana Singha, Pradeep R. Nair, and Aldrin Antony. "Studies on the PEDOT:PSS/n-Si Hybrid Heterojunction Diode." In Springer Proceedings in Physics, 423–27. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-319-97604-4_65.

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Manzoor, Rumysa, Prashant Singh, Sanjay K. Srivastava, P. Prathap, and C. M. S. Rauthan. "Alkaline Treatment of Silicon Nanostructures for Efficient PEDOT:PSS/Si Heterojunction Solar Cells." In Springer Proceedings in Physics, 477–80. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-319-97604-4_74.

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Nishad, G. R. "Applications of PEDOT:PSS in Solar Cells." In Materials Research Foundations, 40–76. Materials Research Forum LLC, 2021. http://dx.doi.org/10.21741/9781644901410-3.

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Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) is increasingly being used in the field of printed and flexible electronics in the form of electrode as well as intermediate layer. PEDOT:PSS belongs to the family of intrinsically conducting polymer materials whose members can conduct electricity in spite of their organic nature without the presence of metals. It is non-toxic, stable in the presence of air and humidity. Above all, it can be easily processed through conventional means. This chapter deals with the applications of PEDOT:PSS in organic solar cells (OSCs), dye sensitized solar cells (DSSCs) and silicon based hybrid solar cells. PEDOT:PSS is being used as electrode, buffer layer and hole conductive layer. It could manipulate the catalytic nature of counter electrode used in DSSCs. Whereas it may help to manipulate the morphological character in Si based hybrid solar cells along with enhancement of cell performance.
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Conference papers on the topic "PEDOT:PSS/Si"

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Derenko, S. S., and S. V. Kondratenko. "Transport in hybrid PEDOT:PSS-GeNCs-Si heterostructures." In Frontiers in Optics. Washington, D.C.: OSA, 2019. http://dx.doi.org/10.1364/fio.2019.jtu3a.25.

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Lam, C. Y., S. Q. Shi, J. Lu, and P. K. L. Chan. "Investigating the Humidity Effect on Si/PEDOT:PSS Hybrid Solar Cell and Power Conversion Efficiency Recovery by Re-Deposition of the Hole Transporting Layer." In ASME 2013 7th International Conference on Energy Sustainability collocated with the ASME 2013 Heat Transfer Summer Conference and the ASME 2013 11th International Conference on Fuel Cell Science, Engineering and Technology. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/es2013-18265.

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The degradation of silicon nanostructure / poly(3,4-ethylenedioxylthiophene : poly(styrenesulphonic acid) (SiNS/PEDOT:PSS) hybrid solar cell due to the moisture is investigated with an environmental chamber. The unencapsulated devices were tested under different relative humidity (RH) varied from (15% to 100%). Under different RH, the devices show various degradation trends. After 3hrs of storage under 100% RH, the average device power conversion efficiency (PCE) drops from 6.52% to 1.27%. While the device is stored under 15% RH, the averaged PCE just drop from 6.40% to 5.49% and the device at 60% RH degrades from 5.97% to 3.12%. To understand the cause of the device degradation, we compare the ITO conductivity and apply tunneling electron microscopy (TEM) to study the growth of the silicon dioxide layer on the silicon nanostructures. We confirmed that the major cause of the PCE drop in the current devices are due to the decrease of the PEDOT:PSS conductivity and the increase of the interface resistances. By re-depositing the PEDOT:PSS layer onto the degraded device and recycling the Si (and fresh ITO), we demonstrated that the efficiency of the device can be partially recovered (to fully recovered). The current work not only highlighted the importance of the humidity control in these SiNS/PEDOT:PSS hybrid solar cells, but also identified the major causes of the device degradation. The observation has been re-confirmed by recovering the PCE of the degraded device with a fresh PEDOT:PSS layer and a fresh ITO.
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Hong-Jhang Syu, Thiyagu Subramani, Chien-Ting Liu, Shu-Chia Shiu, Jiun-Jie Chao, and Ching-Fuh Lin. "Thorough organic/Si nanostructure heterojunction provided by surfactant assisted PEDOT:PSS." In 2015 IEEE 42nd Photovoltaic Specialists Conference (PVSC). IEEE, 2015. http://dx.doi.org/10.1109/pvsc.2015.7355721.

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Kurias, K. M., M. Jasna, M. R. Rajesh Menon, Aldrin Antony, and M. K. Jayaraj. "Fabrication of CNT-PEDOT:PSS/Si heterojunction carrier selective solar cell." In THE 3RD INTERNATIONAL CONFERENCE ON OPTOELECTRONIC AND NANO MATERIALS FOR ADVANCED TECHNOLOGY (icONMAT 2019). Author(s), 2019. http://dx.doi.org/10.1063/1.5093868.

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Nguyen, V. H., S. Kato, K. Gotoh, Y. Kurokawa, and N. Usami. "Solute PEDOT:PSS as an Excellent Passivation Material of Si Substrate." In 2019 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 2019. http://dx.doi.org/10.7567/ssdm.2019.c-6-03.

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Khan, Dil Nawaz, and Muhammad Hassan Sayyad. "Extraction of Electronic Parameters of PEDOT:PSS-PVA/n-Si Heterojunction Diode." In 2010 Second International Conference on Computer Research and Development. IEEE, 2010. http://dx.doi.org/10.1109/iccrd.2010.114.

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Lu, Wenhui, and Jun Zhang. "Hybrid Si/PEDOT:PSS Core/Shell Nanowire Array Photoanode for Photoelectrochemical Cells." In 2012 Symposium on Photonics and Optoelectronics (SOPO 2012). IEEE, 2012. http://dx.doi.org/10.1109/sopo.2012.6271127.

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Ho, Kuan-Ying, and Yuh-Renn Wu. "Numerical analysis and optimization of PEDOT:PSS/Si nanowire hybrid solar cells." In 2016 International Conference on Numerical Simulation of Optoelectronic Devices (NUSOD). IEEE, 2016. http://dx.doi.org/10.1109/nusod.2016.7547018.

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Ghods, Amirhossein, Vishal Saravade, Chuanle Zhou, Chang-Soo Kim, and Ian Ferguson. "PEDOT:PSS/n-Si Hybrid Solar Cells with Al2O3 Interfiacial Passivation Layer." In 2019 IEEE 16th International Conference on Smart Cities: Improving Quality of Life Using ICT & IoT and AI (HONET-ICT). IEEE, 2019. http://dx.doi.org/10.1109/honet.2019.8908087.

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Wang, Xuanchen, and Xianfeng Feng. "Simulation and analysis of Si/PEDOT:PSS hybrid interdigitated back contact solar cell." In 2019 IEEE International Conference on Electron Devices and Solid-State Circuits (EDSSC). IEEE, 2019. http://dx.doi.org/10.1109/edssc.2019.8754487.

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