Academic literature on the topic 'Palladium-based'

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Journal articles on the topic "Palladium-based"

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Hotta, Hideki, Toshiro Kuji, and Hirohisa Uchida. "Hydride Stability for Palladium and Palladium Based fcc Alloys." Journal of the Japan Institute of Metals 69, no. 4 (2005): 362–67. http://dx.doi.org/10.2320/jinstmet.69.362.

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Nicolas, M., H. Raffy, L. Dumoulin, and J. P. Burger. "Absorption of hydrogen in ultrathin palladium and palladium-based alloys." Journal of the Less Common Metals 130 (March 1987): 61–67. http://dx.doi.org/10.1016/0022-5088(87)90087-7.

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Denisov, M. "Palladium-based enzyme inhibitors (review)." Perm Scientific Center Journal 14, no. 4 (2021): 6–18. http://dx.doi.org/10.7242/2658-705x/2021.4.1.

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Behzadi Pour, Ghobad, Leila Fekri Aval, Mehdi Nasiri Sarvi, Sedigheh Fekri Aval, and Hamed Nazarpour Fard. "Hydrogen sensors: palladium-based electrode." Journal of Materials Science: Materials in Electronics 30, no. 9 (March 28, 2019): 8145–53. http://dx.doi.org/10.1007/s10854-019-01190-7.

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Andrés, Román, Ernesto de Jesús, and Juan Carlos Flores. "Catalysts based on palladium dendrimers." New Journal of Chemistry 31, no. 7 (2007): 1161. http://dx.doi.org/10.1039/b615761k.

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Rustamova, Ekaterina G., Maria S. Kagirina, and Sergey P. Gubin. "Obtaining ink based on palladium nanoparticles for possible use in printed electronics." Radioelectronics. Nanosystems. Information Technologies. 14, no. 2 (June 30, 2022): 143–50. http://dx.doi.org/10.17725/rensit.2022.14.143.

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The possibility of obtaining conductive ink based on palladium nanoparticles obtained by the polyol method is considered. The composition of the ink is adapted for use in printed electronics. The ink contains 20 mass% palladium, has a viscosity of 17-20 cps and a surface tension of 35-38 N/m. During heat treatment, the specific surface resistance of palladium nanostructures changes from 0.38 to 0.07 Ω. These and other characteristics, such as high stability and good wettability of the substrate, make it possible to use palladium nanoink in printer printing.
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Yin, Yanru, Changna Wen, Ning Ma, Baoyan Wang, Lianying Zhang, Hongliang Li, and Peizhi Guo. "Sodium Alginate-Assisted Synthesis of PdAg Bimetallic Nanoparticles and their Enhanced Activity for Electrooxidation of Ethanol." Nano 14, no. 09 (September 2019): 1950120. http://dx.doi.org/10.1142/s1793292019501200.

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Palladium and palladium-silver bimetallic nanocrystals have been synthesized hydrothermally by using environmental-friendly sodium alginate as the stabilizer and reducing agent. The pure palladium nanoparticles were spherical-like possibly due to the principle of the lowest surface energy, however, the formation of bimetallic palladium-silver nanoparticles was much more complicated, which was thinner and more irregular nanostructures than pure palladium nanoparticles. Electrochemical measurements showed that the electrocatalytic activity toward ethanol oxidation was increased first with the increase of silver content in bimetallic nanoparticles, from pure palladium of around 1070[Formula: see text]mA/mg, to PdAg-20 of 1160[Formula: see text]mA/mg and to PdAg-10 of 1750[Formula: see text]mA/mg, and declined greatly at a high content of silver, approximately 279[Formula: see text]mA/mg. Electrochemical stability test showed that PdAg-10 and PdAg-5 were the best and worst among four palladium-based samples, respectively. Based on the experimental data, the formation mechanism of pure palladium and palladium-silver bimetallic nanoparticles and the structure-property relationship of these samples have been discussed.
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Hamagami, Junichi, Ryo Araki, Shohei Onimaru, G. Kawamura, and Atsunori Matsuda. "Influence of Catalyst Loading Method on Titania-Based Optical Hydrogen Gas Sensing Properties." Key Engineering Materials 582 (September 2013): 210–13. http://dx.doi.org/10.4028/www.scientific.net/kem.582.210.

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We reported that titania ceramic coating loaded with palladium catalyst worked as an optical hydrogen gas sensor at room temperature. The palladium metal of this sensor worked as a catalyst not only for room-temperature operation but also for high selectivity to hydrogen gas. Precise control of metal/ceramic interface between the titania and the palladium was very important in order to improve the sensor performance such as sensitivity, response time, recovery time. Influence of a difference in palladium-catalyst loading method (photodeposition and sputtering) on the optical hydrogen gas sensing properties for the titania-based sensor was investigated. It was found that the catalytic loading process significantly affected the optical hydrogen characteristics of the titania-based coating.
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Cohen, S. M., A. Kakar, T. K. Vaidyanathan, and T. Viswanadhan. "Castability optimization of palladium based alloys." Journal of Prosthetic Dentistry 76, no. 2 (August 1996): 125–31. http://dx.doi.org/10.1016/s0022-3913(96)90295-4.

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Lang, Thomas, Ernest Graf, Nathalie Kyritsakas, and Mir Wais Hosseini. "Zinc– and palladium–porphyrin based turnstiles." New J. Chem. 37, no. 1 (2013): 112–18. http://dx.doi.org/10.1039/c2nj40657h.

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Dissertations / Theses on the topic "Palladium-based"

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Amandusson, Helena. "Hydrogen extraction with palladium based membranes /." Linköping : Univ, 2000. http://www.bibl.liu.se/liupubl/disp/disp2000/tek651s.htm.

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Elhage, Ayda. "Palladium-based Catalyst for Heterogeneous Photocatalysis." Thesis, Université d'Ottawa / University of Ottawa, 2019. http://hdl.handle.net/10393/39388.

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Over the past decade, heterogeneous photocatalysis have gained lots of interest and attention among the organic chemistry community due to its applicability as an alternative to its homogeneous counterpart. Heterogeneous catalysis offers the advantages of easy separation and reusability of the catalyst. Several studies showed that under optimized conditions, efficient and highly selective catalytic systems could be developed using supported metal/metal oxide nanoparticles. In this dissertation, we summarize the progress in the development of supported palladium nanoparticles for different types of organic reactions. Palladium-decorated TiO2 is a moisture, air-tolerant, and versatile catalyst. The direct excitation of Pd nanoparticles selectively isomerized the benzyl-substituted alkenes to phenyl-substituted alkenes (E-isomer) with complete conversion over Pd@TiO2 under H2-free conditions. Likewise, light excited Pd nanoparticles catalyzed Sonogashira coupling, a C-C coupling reaction between different aryl iodides and acetylenes under very mild conditions in short reaction times. On the other hand, UV irradiation of Pd@TiO2 in alcoholic solutions promotes alkenes hydrogenation at room temperature under Argon. Thus, The photocatalytic activity of Pd@TiO2 can be easily tuned by changing the irradiation wavelength. Nevertheless, some of these systems suffer from catalyst deactivation, one of the main challenges faced in heterogeneous catalysis that decreases the reusability potential of the materials. In order to overcome this problem, we developed an innovative method called “Catalytic Farming”. Our reactivation strategy is based on the crop rotation system used in agriculture. Thus, alternating different catalytic reactions using the same catalyst can reactivate the catalyst surface by restoring its oxidation states and extend the catalyst lifetime along with its selectivity and efficiency. In this work, the rotation strategy is illustrated by Sonogashira coupling –problem reaction that depletes the catalyst– and Ullmann homocoupling –plausible recovery reaction that restores the oxidation state of the catalyst (Pd@TiO2). The selection of the reactions in this approach is based on mechanistic studies that include the role of the solvent and evaluation of the palladium oxidation state after each reaction. In a more exploratory analysis, we successfully demonstrated that Pd nanoparticles could be supported in a wide range of materials, including inert ones such as nanodiamonds or glass fibers. The study of the action spectrum shows that direct excitation of the Pd nanoparticles is a requisite for Sonogashira coupling reactions. The main advantages of heterogeneous catalysis compared to its homogeneous counterpart are easy separation and reusability of the catalyst. Finally in order to facilitate catalyst separation from batch reaction and develop a suitable catalytic system for continuous flow chemistry, we employed glass fibers as catalyst support for a wide variety of thermal and photochemical organic reactions including C-C coupling, dehalogenation and cycloaddition. Different metal/metal oxide nanoparticles, namely Pd, Co, Cu, Au, and Ru were deposited on glass wool and fully characterized. As a proof of concept, Pd decorated glass fibers were employed in heterogeneous flow photocatalysis for Sonogashira coupling and reductive de-halogenation of aryl iodides.
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Kumar, Dheeraj. "Synthesis of vinyl acetate on palladium-based catalysts." [College Station, Tex. : Texas A&M University, 2006. http://hdl.handle.net/1969.1/ETD-TAMU-1747.

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Li, Guangqin. "Studies on Hydrogen-Storage Properties of Palladium Based Nanomaterials." 京都大学 (Kyoto University), 2014. http://hdl.handle.net/2433/193566.

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Brazeau, Nicolas. "Palladium-Based Catalysts for Ethanol Electrooxidation in Alkaline Media." Thesis, Université d'Ottawa / University of Ottawa, 2015. http://hdl.handle.net/10393/32201.

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Direct ethanol fuel cells have been shown to be a good alternative to internal combustion engines in order to reduce the CO2 emissions. In this study, Pd and Pd-based nanocatalysts were deposited on various supports (carbon black, graphene, SnO2, CeO2, TiO2, TiO2 nanotubes and SnO2/TiO2 nanotubes) and their effects on the catalytic properties of the deposited metal for ethanol oxidation in alkaline media are studied. These modifications to the catalytic systems have shown to cause an increase in the reaction rate at the surface of the catalyst and to reduce the overpotential of the ethanol oxidation reaction. Two different promotion mechanisms have been identified. Firstly, the supply of OH- ions at the metal-support interface facilitates the oxidation of adsorbed molecules on neighbouring Pd sites. Secondly, an increase in electron density of Pd nanoparticles with increasing support reducibility modifies the adsorption strength of ethanol and its oxidation intermediates.
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Shao, Zhecheng. "Novel conducting aniline-based materials using advanced palladium catalysts." Thesis, University of Bristol, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.540875.

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Galkin, Maxim. "Palladium-catalyzed lignin valorization : Towards a lignin-based biorefinery." Doctoral thesis, Uppsala universitet, Syntetisk organisk kemi, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-265315.

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The work described in this thesis focuses on the cleavage of the β-O-4′ bond, which is the most abundant interunit linkage in the lignin polymer. In the first part, three methods based on palladium catalysis have been developed and their applicability has been verified using lignin model compounds. A transfer hydrogenolysis of the β-O-4′ bond using formic acid as a mild hydrogen donor together with a base. An aerobic oxidation of the benzylic alcohol motif in the β-O-4′ linkage to generate a key intermediate in the cleavage reaction was performed. A redox neutral cleavage of the β-O-4′ bond was accomplished in which no stoichiometric reducing or oxidizing agents were added. In the second part of the thesis, a mechanistic study is presented. The corresponding ketone from a dehydrogenation reaction of the benzylic alcohol motif was identified to be the key intermediate. This ketone and its enol tautomer was found to be responsible for the β-O-4′ bond cleavage reaction under the employed reaction conditions. In the final part of this thesis, the methodologies have been applied to native lignin. The depolymerization reaction was combined with organosolv pulping. This approach was successful, and together with cellulose and hemicellulose, propenyl aryls were generated in excellent yields directly from wood. In this transformation, the lignin derived molecules have been reduced by an endogenous hydrogen donor from the wood.
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Wang, Lixin. "Ferrocene-based molecular electronics and nanomanufacturing of palladium nanowires." College Park, Md. : University of Maryland, 2007. http://hdl.handle.net/1903/7757.

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Thesis (Ph. D.)--University of Maryland, College Park, 2007.
Thesis research directed by: Dept. of Chemistry and Biochemistry. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
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Awano, Tomotsugu. "Boron-Based Organic Synthesis via New Palladium-Catalyzed Coupling Reactions." 京都大学 (Kyoto University), 2011. http://hdl.handle.net/2433/142247.

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Sun, Desheng. "On the corrosion behavior and biocompatibility of palladium-based dental alloys." Columbus, Ohio : Ohio State University, 2004. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1085789516.

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Thesis (Ph. D.)--Ohio State University, 2004.
Title from first page of PDF file. Document formatted into pages; contains xix, 155 p.; also includes graphics (some col.). Includes abstract and vita. Advisor: William A. Brantley, College of Dentistry. Includes bibliographical references (p. 148-155).
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Books on the topic "Palladium-based"

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P, Wnuk V., and United States. National Aeronautics and Space Administration., eds. The development of a PdCr integral weldable strain measurement system based on NASA Lewis PdCr/Pt strain sensor for user-friendly elevated temperature strain measurements. [Washington, D.C: National Aeronautics and Space Administration, 1997.

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Book chapters on the topic "Palladium-based"

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Fernandez, Ekain, Fausto Gallucci, and David A. Pacheco Tanaka. "Palladium-Based Membrane (Palladium Alloy Membrane)." In Encyclopedia of Membranes, 1–4. Berlin, Heidelberg: Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-642-40872-4_1031-3.

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Fernandez, Ekain, and Gallucci Fausto. "Palladium-Based Membrane Reactor." In Encyclopedia of Membranes, 1–4. Berlin, Heidelberg: Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-642-40872-4_1032-3.

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Prince, Sharon, Selwyn Mapolie, and Angelique Blanckenberg. "Palladium-Based Anti-Cancer Therapeutics." In Encyclopedia of Cancer, 1–9. Berlin, Heidelberg: Springer Berlin Heidelberg, 2015. http://dx.doi.org/10.1007/978-3-642-27841-9_7085-1.

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Prince, Sharon, Selwyn Mapolie, and Angelique Blanckenberg. "Palladium-Based Anti-Cancer Therapeutics." In Encyclopedia of Cancer, 3371–78. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-46875-3_7085.

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Wu, Shuanghong, Han Zhou, Mengmeng Hao, and Zhi Chen. "Nanoporous Palladium Films Based Resistive Hydrogen Sensors." In Outlook and Challenges of Nano Devices, Sensors, and MEMS, 365–93. Cham: Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-50824-5_13.

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Shao, Minhua. "Palladium-Based Electrocatalysts for Oxygen Reduction Reaction." In Lecture Notes in Energy, 513–31. London: Springer London, 2013. http://dx.doi.org/10.1007/978-1-4471-4911-8_17.

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Ilkenhans, T., S. Poulston, L. Rowsell, A. W. J. Smith, and L. A. Terry. "Development of a new palladium-based ethylene scavenger." In Advances in Plant Ethylene Research, 211–13. Dordrecht: Springer Netherlands, 2007. http://dx.doi.org/10.1007/978-1-4020-6014-4_44.

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Modibedi, Remegia Mmalewane, Kenneth Ikechukwu Ozoemena, and Mkhulu Kenny Mathe. "Palladium-Based Nanocatalysts for Alcohol Electrooxidation in Alkaline Media." In Lecture Notes in Energy, 129–56. London: Springer London, 2013. http://dx.doi.org/10.1007/978-1-4471-4911-8_6.

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Bianchini, C. "4 Palladium-Based Electrocatalysts for Alcohol Oxidation in Direct Alcohol Fuel Cells." In Modern Aspects of Electrochemistry, 203–53. New York, NY: Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-5580-7_4.

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Karnik, Sooraj V., Miltiadis K. Hatalis, and Mayuresh V. Kothare. "Palladium based Micro-Membrane for Water Gas Shift Reaction and Hydrogen Gas Separation." In Microreaction Technology, 295–302. Berlin, Heidelberg: Springer Berlin Heidelberg, 2001. http://dx.doi.org/10.1007/978-3-642-56763-6_30.

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Conference papers on the topic "Palladium-based"

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Duy-Thach Phan and Gwiy-Sang Chung. "Effects of palladium nanocrystal morphologies on hydrogen sensors based on palladium-graphene hydrid." In 2015 IEEE Sensors. IEEE, 2015. http://dx.doi.org/10.1109/icsens.2015.7370203.

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Ye, S. Y., S. Tanaka, M. Esashi, S. Hamakawa, T. Hanaoka, and F. Mizukami. "MEMS-based thin palladium membrane microreactors." In ICI20:MEMS, MOEMS, and NEMS, edited by Masayoshi Esashi and Zhaoying Zhou. SPIE, 2006. http://dx.doi.org/10.1117/12.667851.

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Nguyen, Khoa, Stéphane Streiff, Sébastien Lyonnais, Laurence Goux-Capes, Arianna Filoramo, Marcelo Goffman, and Jean Philippe Bourgoin. "Synthesis of Palladium Conductive DNA-based Nanowires." In DNA-BASED NANOSCALE INTEGRATION: International Symposium on DNA-Based Nanoscale Integration. AIP, 2006. http://dx.doi.org/10.1063/1.2360585.

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Raval, Manan, Steve McKeown, Amir Arbabi, and Lynford L. Goddard. "Palladium Based Fabry-Pérot Etalons for Hydrogen Sensing." In Optical Sensors. Washington, D.C.: OSA, 2012. http://dx.doi.org/10.1364/sensors.2012.sth2b.5.

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Coelho, L., S. F. O. Silva, Paula A. R. Tafulo, J. L. Santos, O. Frazão, and F. X. Malcata. "Optical fibre hydrogen sensors based on palladium coatings." In International Conference on Applications of Optics and Photonics, edited by Manuel F. Costa. SPIE, 2011. http://dx.doi.org/10.1117/12.892014.

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Corso, Alain J., Marco Angiola, Enrico Tessarolo, Martino Guidolin, Alberto Donazzan, Alessandro Martucci, and Maria G. Pelizzo. "Continuous palladium-based thin films for hydrogen detection." In SPIE Optics + Optoelectronics, edited by Francesco Baldini, Jiri Homola, and Robert A. Lieberman. SPIE, 2017. http://dx.doi.org/10.1117/12.2266472.

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Fisser, Maximilian, Rodney A. Badcock, Paul D. Teal, and Arvid Hunze. "Palladium based hydrogen sensors using fiber Bragg gratings." In 25th International Conference on Optical Fiber Sensors, edited by Youngjoo Chung, Wei Jin, Byoungho Lee, John Canning, Kentaro Nakamura, and Libo Yuan. SPIE, 2017. http://dx.doi.org/10.1117/12.2262383.

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Mokurala, Krishnaiah, Anvita Kamble, Siva Sankar Nemala, Parag Bhargava, and Sudhanshu Mallick. "Palladium and platinum-palladium bi-layer based counter electrode for dye-sensitized solar cells with modified photoanode." In NANOFORUM 2014. AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4918120.

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Lan, Xinwei, Jie Huang, Tao Wei, Qun Han, Zhan Gao, and Hai Xiao. "Hydrogen sensor based on palladium coated SMS fiber structure." In Laser Applications to Chemical, Security and Environmental Analysis. Washington, D.C.: OSA, 2012. http://dx.doi.org/10.1364/lacsea.2012.lt6b.3.

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ALFANO, BRIGIDA, VERA LA FERRARA, ETTORE MASSERA, and GIROLAMO DI FRANCIA. "SELECTIVITY AND STABILITY OF PALLADIUM NANOWIRES BASED HYDROGEN SENSOR." In Proceedings of the 13th Italian Conference. WORLD SCIENTIFIC, 2008. http://dx.doi.org/10.1142/9789812835987_0029.

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Reports on the topic "Palladium-based"

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Hopkins, Scott. High-Performance Palladium Based Membrane for Hydrogen Separation and Purification. Office of Scientific and Technical Information (OSTI), January 2012. http://dx.doi.org/10.2172/1057924.

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