Dissertations / Theses on the topic 'Palaeoclimate proxy'

The Permian/Triassic (P/Tr) boundary is widely assumed to have been a time of extreme environmental upheaval and change. In the terrestrial realm, a negative anomaly in 813C isotope values has been reported from organic carbon in Antarctica, Australia, India and Madagascar, and from marine carbonate in the Karoo Basin. However, these sections are all from southern palaeolatitudes. Analysis from the Permian-Triassic terrestrial sedimentary record of the South Urals, in Russia, comprising of many Aridisol and Vertisol horizons has revealed that, like the Southern Hemisphere, there is a dramatic change in paleosol morphology across the P/Tr boundary linked to a shift from meandering rivers to conglomeratic alluvial fans. Most of the paleosols include pedogenic carbonates at different stages of development, both above and below the P/Tr boundary. By the Triassic there is evidence of depressed water tables and increased seasonality. Analyses of the S13Qarba nd S18Ocarbsi gnatures of these pedogenic carbonates have revealed a number of negative excursions in 813Ccarabn d 5180carbin the Late Permian, including a negative excursion in the mid-Changhsingian, the first time such an event has been recorded in a terrestrial environment. Associated with this excursion are indicators of increasing extremes of climate, including pedogenic dolomite, which suggest a dramatic change in climate up to the P/Tr boundary. Equally, there is an increase in the range of precipitation, suggesting that what caused this mid-Changhsingian event also had a profound effect on the atmosphere. There is also evidence, in the form of the 818Ocaeßx, cursion, of a rise in temperaturej ust prior to the onset of the conglomeratic alluvial fan deposits, which mark the P/Tr boundary in Russia. Although in the Russian paleosols this excursion could be explained by a rise in the effect of seasonal rain or atmospheric temperature, estimates from unaltered brachiopods from the Italian Dolomites confirm that there is a rise in temperature and suggests that this is in the region of 7-8°C. These paleosols also record a dramatic rise in pCO2 in the Earliest Triassic similar to what has been recorded in stomatal records across this period suggesting a dramatic input of CO2 in to the atmosphere.

At the boundary between the Paleocene and Eocene epochs (ca. 56 Ma) a significant global warming event, termed the Paleocene-Eocene Thermal Maximum (PETM), occurred. Records of this event are characterised by a negative carbon isotope excursion (CIE) which has been associated with the release of thousands of petagrams of isotopically light carbon into the ocean-atmosphere system, initiating changes in the carbon cycle, the climate system, ocean chemistry and the marine and continental ecosystems. The amount of isotopically light carbon that was required to cause the event, its source and the rapidity of its release are, however, are still debated. This study uses δ13CTOC, δ13Cn-alkane, δ13CCARB and palynological data to evaluate the PETM CIE in terms of the magnitude of the CIE in both continental and marine settings, rapidity of release and drawdown of carbon, and mobilisation of different organic matter (OM) pools as a response to the climate change. The sections studied span a continental to marine transect in northern Spain. This represents the first organic geochemical study of these PETM sections, one of the first comparisons of CIE magnitude between continental and marine sections within the same sediment routing system, and one of the first comparisons of the same OM proxies within different depositional environments. The data suggest that different OM pools were mobilised in response to the PETM, with reworking of older material, soil residence times, and contemporaneous vegetation all contributing. CIE profile shapes predominantly suggest a rapid onset and recovery from the event. The magnitude of the CIE was also assessed. The current resolution of the data suggests that the differences between continental and marine CIE magnitudes could be minimal within a single sediment routing system, perhaps establishing a realistic CIE magnitude for the PETM, for use in future modelling scenarios.

Minimum blue intensity is a reflected light imaging technique that provides an inexpensive, robust and reliable surrogate for maximum latewood density. In this application it was found that temperature reconstructions from resin-extracted samples of Pinus sylvestris (L.) from Fennoscandia provide results equivalent to conventional x-ray densitometry. This paper describes the implementation of the blue intensity method using commercially available software and a flat-bed scanner. A calibration procedure is presented that permits results obtained by different laboratories, or using different scanners, to be compared. In addition, the use of carefully prepared and chemically treated 10-mm-diameter cores are explored; suggesting that it may not be necessary to produce thin laths with the rings aligned exactly perpendicular to the measurement surface.

This study examined samples part of a larger project exploring environmental changes at Lake Hawdon, mid Canterbury, involving Queen’s University Belfast and the University of Canterbury. The author was responsible for the analysis of 85 fossil diatom samples from Lake Hawdon to create a high resolution study to assess their use as a biological proxy of past environmental changes through the Late Glacial Inter-Glacial Transition. Qualitative interpretations suggest three main phases of environmental change in Lake Hawdon during ~17,000 to 10,000 cal. BP. The first is a cool stage where taxa such as Cocconeis placentula and fragilarioid complex taxa Staurosirella pinnata and Pseudostaurosira brevistriata suggest a cool shallow lake with increasing macrophyte growth. The second phase suggests cold deepening water from at 13,928 +/- 142 to 12,686 +/- 166 cal. BP, dominated by Pseudostaurosira brevistriata, which coincides with the Antarctic Cold Reversal. The third phase represents a warm deep water phase after 12,686 +/- 166 cal. BP, dominated by planktonic taxon Cyclotella stelligera and epiphytic taxon Epithemia sorex, suggesting that Lake Hawdon does not exhibit the Younger Dryas event. Pollen and chironomid data from Lake Hawdon, generated by other project members, are included in the quantitative analyses to further inform palaeoenvironmental inferences generated from diatom data. Chironomid temperature reconstructions complement diatom interpretations for all three phases of change in the lake however diatom resolution allows changes to be detected earlier than other proxies suggest. Stabilisation of the landscape ~12, 686 +/- 166 cal. BP is suggested by tree pollen appearing near the end of the diatom cold phase, confirming with the diatoms and chironomid data that there was a warming out of the cold phase. Interpretations from Lake Hawdon add to other proxy studies in New Zealand that suggest an Antarctic Cold Reversal type event, but fail to highlight the Younger Dryas event. The generation of a transfer function was attempted with the diatom data based on Northern Hemisphere datasets, but a Principal Component Analysis plot highlighted major dissimilarities between the New Zealand fossil data and modern European data. This raised the issue of having morphologically similar but genetically separate taxa, potentially displaying convergent environmental adaptation, a crucial area for further research globally, and particularly in isolated areas like New Zealand.

Climate north of the Atlas Mountain belt in NW Africa is dominated by extratropical disturbances. However, climatic controls to the south, where climate transitions from extratropical to tropical regimes, are poorly understood due to a paucity of both instrumental and palaeoclimate data. In this thesis past climate change between the High Atlas Mountains and Sahara Desert is reconstructed using the stable isotopic composition and radiometric dating of speleothems. A high-resolution record from the mid-Holocene and a discontinuous record covering the past 400,000 years are developed. Supplemented by U-Th dating of a further four samples, these records indicate increased humidity in this area concomitant with the wider African Humid Period, and indicate a link between the West African Monsoon and humidity north of 30°N. Reconstructed glacial-interglacial scale increases in humidity overlap with "green Sahara" conditions and evidence a recurrent humid corridor connecting NW Africa and the central Sahara that is highly relevant to discussions of prehistoric human migrations. Evidence for a strong influence of high-latitude and solar forcing on decadal to millennial time- scales in this area is also presented. Further to this work, the potential of cadmium-to-calcite ratios as a novel proxy for palaeo-hydrology is confirmed using an annually-resolved trace element, stable isotope and calcite fabric dataset from a North Moroccan stalagmite. The first measurements of cadmium-to-calcite ratios in natural speleothem are here presented, and the palaeoclimatic significance and potential of this proxy for aiding the quantitative reconstruction of changes in calcite precipitation behaviour are demonstrated.

This thesis investigates the potential of the bivalve Arctica islandica (Linnaeus, 1767) from fjordic sites in NW Scotland for reconstructing past marine environmental /climatic variability. Using dendrochronological and sclerochronological techniques, six master chronologies were created which when compared show little common variability between the sites, indicating no common response to regional scale forcing. The chronologies were compared to local and regional scale SST and land based datasets, with no significant, time stable responses to climate found. It is clear the growth/climate response of A. islandica from these sites is complex, potentially due to the shallow nature of the sample sites, direct local drivers such as food availability and, potentially, anthropogenic activity in the region. Geochemical analyses of the shell material were undertaken to examine the timing and magnitude of the radiocarbon bomb-peak and the stable carbon isotope signature of the oceanic Suess Effect. The timing of the radiocarbon bomb-peak in Loch Etive does not appear to match previously published results from other marine locations and are a potentially serious challenge to the assumption that A. islandica GI are always annual features. Results comparing δ¹³C values and the age of the specimen when these values are incorporated into the shell material strongly indicate an ontogenetic control over δ¹³C, meaning the Suess Effect could not be effectively investigated. To take these ontogenetic influences into account it is suggested that any data from the juvenile period of shell life is not used. Analysis of shell biometrics and morphology indicate significant relationships between shell age and height and age and weight, however the errors for these are large (±78 years and ±80 years respectively). These results indicate that despite large errors shell height, as a predictor of age, has the potential to be used for in situ population studies.

Sediment records of three European lakes were investigated in order to reconstruct the regional climate development during the Lateglacial and Holocene, to investigate the response of local ecosystems to climatic fluctuations and human impact and to relate regional peculiarities of past climate development to climatic changes on a larger spatial scale. The Lake Hańcza (NE Poland) sediment record was studied with a focus on reconstructing the early Holocene climate development and identifying possible differences to Western Europe. Following the initial Holocene climatic improvement, a further climatic improvement occurred between 10 000 and 9000 cal. a BP. Apparently, relatively cold and dry climate conditions persisted in NE Poland during the first ca. 1500 years of the Holocene, most likely due to a specific regional atmospheric circulation pattern. Prevailing anticyclonic circulation linked to a high-pressure cell above the remaining Scandinavian Ice Sheet (SIS) might have blocked the eastward propagation of warm and moist Westerlies and thus attenuated the early Holocene climatic amelioration in this region until the final decay of the SIS, a pattern different from climate development in Western Europe. The Lateglacial sediment record of Lake Mondsee (Upper Austria) was investigated in order to study the regional climate development and the environmental response to rapid climatic fluctuations. While the temperature rise and environmental response at the onset of the Holocene took place quasi-synchronously, major leads and lags in proxy responses characterize the onset of the Lateglacial Interstadial. In particular, the spread of coniferous woodlands and the reduction of detrital flux lagged the initial Lateglacial warming by ca. 500–750 years. Major cooling at the onset of the Younger Dryas took place synchronously with a change in vegetation, while the increase of detrital matter flux was delayed by about 150–300 years. Complex proxy responses are also detected for short-term Lateglacial climatic fluctuations. In summary, periods of abrupt climatic changes are characterized by complex and temporally variable proxy responses, mainly controlled by ecosystem inertia and the environmental preconditions. A second study on the Lake Mondsee sediment record focused on two small-scale climate deteriorations around 8200 and 9100 cal. a BP, which have been triggered by freshwater discharges to the North Atlantic, causing a shutdown of the Atlantic meridional overturning circulation (MOC). Combining microscopic varve counting and AMS 14C dating yielded a precise duration estimate (ca. 150 years) and absolute dating of the 8.2 ka cold event, both being in good agreement with results from other palaeoclimate records. Moreover, a sudden temperature overshoot after the 8.2 ka cold event was identified, also seen in other proxy records around the North Atlantic. This was most likely caused by enhanced resumption of the MOC, which also initiated substantial shifts of oceanic and atmospheric front systems. Although there is also evidence from other proxy records for pronounced recovery of the MOC and atmospheric circulation changes after the 9.1 ka cold event, no temperature overshoot is seen in the Lake Mondsee record, indicating the complex behaviour of the global climate system. The Holocene sediment record of Lake Iseo (northern Italy) was studied to shed light on regional earthquake activity and the influence of climate variability and anthropogenic impact on catchment erosion and detrital flux into the lake. Frequent small-scale detrital layers within the sediments reflect allochthonous sediment supply by extreme surface runoff events. During the early to mid-Holocene, increased detrital flux coincides with periods of cold and wet climate conditions, thus apparently being mainly controlled by climate variability. In contrast, intervals of high detrital flux during the late Holocene partly also correlate with phases of increased human impact, reflecting the complex influences on catchment erosion processes. Five large-scale event layers within the sediments, which are composed of mass-wasting deposits and turbidites, are supposed to have been triggered by strong local earthquakes. While the uppermost of these event layers is assigned to a documented adjacent earthquake in AD 1222, the four other layers are supposed to be related to previously undocumented prehistorical earthquakes.
Sedimente aus drei europäischen Seen wurden untersucht um die regionale Klimaentwicklung während des Spätglazials und Holozäns und die Reaktion der Ökosysteme auf Klimaschwankungen und menschlichen Einfluss zu rekonstruieren sowie die regionalen Besonderheiten der spätquartären Klimaveränderungen in einen überregionalen Kontext zu setzen. Die Sedimente des Jezioro Hańcza (Nordostpolen) wurden im Hinblick auf die frühholozäne Klimaentwicklung und die Identifikation möglicher Unterschiede gegenüber Westeuropa untersucht. Im Anschluss an die Erwärmung zu Beginn des Holozäns konnte eine weitere Verbesserung der Klimabedingungen zwischen 10 000 und 9000 Jahren vor heute nachgewiesen werden. Offensichtlich herrschten in Nordostpolen während der ersten 1500 Jahre des Holozäns noch relative kalte und trockene Klimabedingungen, höchstwahrscheinlich als Resultat besonderer regionaler atmosphärischer Zirkulationsverhältnisse. Eine antizyklonale Zirkulationszelle als Resultat eines Hochdruckgebiets über dem Rest des Skandinavischen Eisschilds verhinderte wahrscheinlich das Vordringen warmer und feuchter Luftmassen aus Westen und verursachte damit eine Abschwächung der frühholozänen Klimaverbesserung in dieser Region bis zum endgültigen Zerfall des Eisschilds, was grundsätzlich von der frühholozänen Klimaentwicklung in Westeuropa abweicht. Die spätglazialen Sedimente des Mondsees (Oberösterreich) wurden im Hinblick auf die regionale Klimaentwicklung und die Reaktion des Ökosystems auf abrupte Klimaschwankungen untersucht. Während die Erwärmung zu Beginn des Holozäns von einer zeitgleichen Reaktion des Ökosystems begleitet wurde, war die Reaktion des Ökosystems auf die Erwärmung zu Beginn des Spätglazials deutlich verzögert. Insbesondere die Ausbreitung von Nadelwäldern und die Reduktion des klastischen Eintrags folgten der spätglazialen Erwärmung erst mit einer Verzögerung von ca. 500–750 Jahren. Die Abkühlung zu Beginn der Jüngeren Dryas war durch eine deutliche Synchronizität zwischen Temperatur- und Vegetationsänderung gekennzeichnet, wohingegen der Anstieg des klastischen Eintrags erst 150–300 Jahre verzögert folgte. Eine komplexe Reaktion des Ökosystems zeigt sich auch während kurzfristiger spätglazialer Klimaschwankungen. Zusammenfassend lässt sich sagen, dass abrupte Klimaveränderungen durch komplexe und zeitlich variable Reaktionsmuster des Ökosystems gekennzeichnet sind, die hauptsächlich von dessen Klimasensitivität und den ökologischen Ausgangsbedingungen abhängen. Eine zweite Studie an den Sedimenten des Mondsees konzentrierte sich auf zwei Klimaschwankungen vor ca. 8200 und 9100 Jahren, für die Schmelzwassereintrag in den Nordatlantik und ein damit verbundenes Zusammenbrechen der thermohalinen Zirkulation als Ursache angesehen wird. Durch Warvenzählungen und 14C-Datierungen konnten sowohl die Dauer (ca. 150 Jahre) als auch das absolute Alter der Kältephase vor ca. 8200 Jahren zuverlässig bestimmt werden, welche in guter Übereinstimmung mit Resultaten aus anderen Paläoklimaarchiven stehen. Darüber hinaus wurde eine kurze Warmphase direkt im Anschluss an das Abkühlungsereignis identifiziert, die auch in anderen Klimaarchiven im nordatlantischen Raum nachweisbar ist. Diese wurde wahrscheinlich durch ein Wiedererstarken der thermohalinen Zirkulation verursacht, welches darüber hinaus eine Verschiebung ozeanischer und atmosphärischer Frontsysteme zur Folge hatte. Obwohl andere Klimaarchive auch nach dem Abkühlungsereignis vor ca. 9100 Jahren auf ein Wiedererstarken der thermohalinen Zirkulation hindeuten, finden sich in den Sedimenten des Mondsees keine Anzeichen für eine solche Wärmeperiode, was die Komplexität des globalen Klimasystems verdeutlicht. Die holozänen Sedimente des Lago d’Iseo (Norditalien) wurden im Hinblick auf die regionale Erdbebenaktivität und den Einfluss von Klima und Mensch auf Erosionsprozesse im Einzugsgebiet und den klastischen Eintrag in den See untersucht. Zahlreiche kleinere detritische Lagen in den Sedimenten spiegeln Eintrag durch extreme Oberflächenabflussereignisse wieder. Während des Früh- und Mittelholozäns zeigt sich eine deutliche Übereinstimmung zwischen erhöhtem klastischen Eintrag und kühleren und feuchteren Klimaverhältnissen, was auf einen dominanten Einfluss der natürlichen Klimavariabilität hindeutet. Im Gegensatz dazu zeigen Phasen erhöhten klastischen Eintrags während des Spätholozäns teilweise auch eine Korrelation mit erhöhter Siedlungsaktivität, was die Komplexität der Einflüsse auf Erosionsprozesse im Einzugsgebiet verdeutlicht. Darüber hinaus konnten auch fünf größere Ereignislagen nachgewiesen werden, welche durch Rutschmassen und Turbidite gekennzeichnet sind und für die lokale Erdbeben als Ursache vermutet werden. Die jüngste Ereignislage kann mit einem historisch dokumentierten proximalen Erdbeben im Jahr AD 1222 korreliert werden. Für die anderen vier Ereignislagen werden bisher undokumentierte prähistorische Erdbeben als Ursache angenommen.

Le Crétacé a été une période d'instabilité climatique et du cycle du carbone, dont le CO2 atmosphérique a été désigné comme le driver majeur. Cependant, les reconstitutions du CO2 atmosphérique ne reflètent ni les dynamiques climatiques ni les grands évènements de perturbation du cycle du carbone décrits pour cette période. J'ai utilisé la composition isotopique de carbone de la plante fossile Frenelopsis (d13Cleaf) comme un nouvel proxy pour reconstituer le CO2 atmosphérique du Crétacé en termes de composition isotopique de carbone (d13CCO2) et de concentration (pCO2). La première courbe de d13CCO2 pour toute la durée du Crétacé a été construite à partir du d13C des carbonates marins. Sa comparaison avec des estimations de d13CCO2 à partir du d13Cleaf a révélé que les modèles développés jusqu'à maintenant ont une tendance à exagérer les valeurs de d13CCO2. Des estimations du fractionnement isotopique du carbone issu par des plantes (13Cleaf) obtenues à partir des nouvelles données d e d13Cleaf et d13CCO2 ont permis de reconstituer l'évolution à grande échelle de la pCO2. Ces résultats indiquent que le CO2 a probablement été une conséquence à long terme du changement climatique durant le Crétacé. Des cycles de d13CCO2 de ~1.2, ~2.1, ~5.4 et ~10.2 Ma ont été détectés, synchrones à ceux du niveau de la mer et à la cyclicité des paramètres de l'orbite terrestre décrits pour le Mésozoïque. Mes résultats fournissent une nouvelle perspective du système climatique et du cycle du carbone du Crétacé, dominés principalement par les paramètres orbitaux de la Terre et secondairement par des évènements catastrophiques de libération de CO2 d'origine volcanique dans l'atmosphère
The Cretaceous was a period characterized by strongly marked climate change and major carbon cycle instability. Atmospheric CO2 has repeatedly been pointed out as a major agent involved in these changing conditions during the period. However, long-term trends in CO2 described for the Cretaceous are not consistent with those of temperature and the large disturbance events of the carbon cycle described for the period. This raises a double question of whether descriptions of the long-term evolution of atmospheric CO2 made so far are accurate or, if so, atmospheric CO2 was actually a major driver of carbon cycle and climate dynamics as usually stated. In this thesis the close relationship between the carbon isotope composition of plants and atmospheric CO2 is used to address this question. Based on its ecological significance, distribution, morphological features and its excellent preservation, the fossil conifer genus Frenelopsis is proposed as a new plant proxy for climate reconstructions during the Cretaceous. The capacity of carbon isotope compositions of Frenelopsis leaves (d13Cleaf) to reconstruct past atmospheric CO2, with regards to both carbon isotope composition (d13CCO2) and concentration (pCO2), is tested based on materials coming from twelve Cretaceous episodes. To provide a framework to test the capacity of d13Cleaf to reconstruct d13CCO2 and allowing for climate estimates from carbon isotope discrimination by plants (?13Cleaf), a new d13CCO2 curve for the Cretaceous based on carbon isotope compositions of marine carbonates has been constructed. Comparison with d13Cleaf-based d13CCO2 estimates reveals that although d13CCO2 and d13Cleaf values follow consistent trends, models developed so far to estimate d13CCO2 from d13Cleaf tend to exaggerate d13CCO2 trends because of assuming a linear relationship between both values. However, given the hyperbolic relationship between ?13Cleaf and pCO2, by considering an independently-estimated correction factor for pCO2 for a given episode, d13Cleaf values may be a valuable proxy for d13CCO2 reconstructions. ?13Cleaf estimates obtained from d13CCO2 and d13Cleaf values were used to reconstruct the long-term evolution of pCO2. The magnitude of estimated pCO2 values is in accordance with that of the most recent and relevant model- and proxy-based pCO2 reconstructions. However, these new results evidence long-term drawdowns of pCO2 for Cretaceous time intervals in which temperature maxima have been described

Peatlands in Southern South America (SSA), in the path of the Southern Westerly Wind belt (SWW), offer the potential of reliable palaeoclimate archives. This investigation aimed to test the late-Holocene climate signal related to variability of the SWW. Three sites were investigated: San Juan and Karukinka bog, southernmost Chile and San Carlos, a Sphagnum dominated bog, discovered in the Falkland Islands, to form a regional comparison. A multi-proxy approach was used, combining both palaeoecological and stable isotopic methods. At one site, Karukinka, intra-site replicability was tested across three profiles located along a microtopographical gradient. A low number of statistically significant correlations between proxies were evident. KAR-EM-1, the low-hummock profile, displayed the highest number of significant correlations, suggesting an optimal coring location. Chronological uncertainty in the high-hummock profile, KAR-EM-3, was the focus of discussion. Intra-site replicability between the palaeoecological records was improved by plotting the records against a ‘master chronology’, from the mid-hummock profile, KAR-EM-2, assuming a synchronous acrotelm-catotelm boundary across the profiles. The testate amoeba inferred depth to water table (WTD) reconstructions offered the highest intra-site coherence, while the stable isotope records suggested generally poor intra-site replicability. A semi-quantitative method of intra-site comparison was carried out which resulted in a number of climate scenarios. The inter-site comparison assessed correlations between the records from the three sites. A lack of significant correlations between the sites may have been due to regional climate variations and differences in the temporal resolution of the records. Robust climatic inferences were limited to the last 300 years. The WTD reconstructions displayed the highest inter-site coherence and suggested a drying trend after AD 1930 due to a southerly shift of the SWW. Late-Holocene climate variability was inferred from the palaeoecological records from Karukinka. Two periods were identified: a MCA period of generally wetter conditions (AD 750-1100) and a LIA period of overall drier conditions (~AD 1100-1900) during a southerly and northerly shifted SWW respectively, driven by solar variability and polar cell strengthening.

The characterization of natural climate variability is important in order to understand the climate response to natural forcings and to identify anthropogenic influences. The aim of this thesis is to reconstruct climate changes in the southwest of France, a region which is characterised by recurrent drought periods, where high resolution proxy records of the last millennia were lacking.The reconstruction is based on multiple proxies from two continental archives: speleothems and tree rings. Their combination can make use of the strengths of each archive while compensating their weaknesses. There are two principal objectives: first, to gain a better understanding of the climatic and non-climatic influences on each proxy; and second, to reconstruct drought periods in the past.The oxygen isotopic composition (δ18O) of speleothem fluid inclusions and tree ring cellulose is controlled to a large extent by the δ18O of precipitation, which can serve as a tracer of the atmospheric circulation. In order to interpret these proxies in terms of climate, it is necessary to understand how the climate signal becomes recorded in the proxy, and which processes modify the original signal during the formation of the archive.Measurements of δ18O in precipitation, cave drip water, and fluid inclusions in modern speleothem samples from Villars Cave demonstrated that the isotopic composition of cave drip water corresponds to the pluri-annual average precipitation. The speleothem fluid inclusions, in turn, preserve the isotopic composition of the drip water. Based on this calibration, it is possible to reconstruct drip water isotope variability using fluid inclusions in a more than 2000 year old stalagmite, which has been dated by laminae counting, as well as U-Th and 14C measurements. Changes in the cave environment, e.g. the vegetation cover, are indicated by other proxies from the same stalagmite (stable isotopes in calcite and trace element concentrations), but these changes do not seem to impact the fluid inclusion δ18O significantly.The isotopic composition of tree ring cellulose from Quercus spp. in the study area is strongly influenced by climate conditions during the summer. However, non-climatic influences on the isotopic composition of cellulose are identified. They are linked to the age of the trees and to site hydrology, and must be accounted for in the sampling and analytical procedures. Crossdated cores from living trees and timber wood in historic buildings near Angoulême are used to build an annually resolved chronology of cellulose δ18O. Significant correlations with meteorological data enable a calibration and a reconstruction of drought periods since 1360 AD.Lastly, this thesis explores a novel approach of integrating oxygen isotope records from speleothem fluid inclusions and tree ring cellulose from closely located sites to reconstruct both high- and low-frequency variability of droughts in the past.

Despite the recognized importance of understanding late Holocene climatic changes in southern Africa, a dearth of available evidence has resulted in a frag- mented view of the recent past. South Africa has been identified as a key focus region for palaeoclimatic studies, as it reflects the dynamics of both tropical and temperate climate regimes. This study aims to create a catchment-integrated view of palaeoenvironmental conditions in the country's Winter Rainfall Zone (WRZ) and Southern Benguela region during the late Holocene, in order to establish the linkages between oceanic and terrestrial climate components. A multiproxy analysis was conducted on a west coast mudbelt sediment core, where continuous deposition over the last 2,250 years has aided the production of an uninterrupted age model. Alkenone and isotopic analyses were conducted at a multi-decadal resolution to assist in the reconstruction of sea-surface tem- perature (SST) in the St. Helena Bay region, and hydrological variation in the WRZ. Changes in moisture availability were inferred via the application of in- organic proxies, including grain size variation (promoted through the use of an end-member proxy algorithm) and the Fe/K ratio, a proxy interpreted to be rep- resentative of changes in chemical weathering. Furthermore, a newly-developed proxy, TEX 86 , was used as an alternative palaeothermometer. TEX 86 produced an additional record of SST, independent of alkenones, which elicited a com- parative study between SST TEX86 and SST UK'37 . The comparison facilitated a review of the effectiveness of TEX 86 within the Benguela Upwelling System, and assisted in quantifying reasons for the observed differences between the two methods. The results of the multiproxy analysis sheds new light on southwest African late Holocene climatic dynamics. This study documents a decrease in SST accompanied by increasing WRZ rainfall, which is hypothesized to be a result of large-scale changes in the position and/or intensity of the austral westerly wind belt. A northerly migration/increase in intensity of the winds acts to produce cooler SSTs and wetter west coast continental conditions, both of which were most acutely experienced during the so-called Little Ice Age (LIA) (1300 - 1850 CE). Zonal symmetry across the Southern Hemisphere is hypothesized to be a consequence of the large geographical extent of the westerly winds, as cooler and wetter conditions have been experienced in coastal, winter-rainfall areas of Chile and Australia.

The presence of the sea ice diatom biomarker IP25 in Arctic marine sediments has been used in previous studies as a proxy for past spring sea ice occurrence and as an indicator of wider palaeoenvironmental conditions for different regions of the Arctic over various timescales. The current study describes a number of analytical and palaeoceanographic developments of the IP25 sea ice biomarker. First, IP25 was extracted and purified from Arctic marine sediments. This enabled the structure of IP25 to be confirmed and enabled instrumental (GC-MS) calibrations to be carried out so that quantitative measurements could be performed with greater accuracy. Second, palaeo sea ice reconstructions based on IP25 and other biomarkers were carried out for a suite of sub-Arctic areas within the Greenland, Norwegian and Barents Seas, each of which represent contrasting oceanographic and environmental settings. Further, an evaluation of some combined biomarker approaches (e.g. the PIP25 and DIP25 indices) for quantifying and/or refining definitions of sea ice conditions was carried out. Temporally, particular emphasis was placed on the characterisation of sea ice conditions during the Younger Dryas and the Holocene. Some comparisons with other proxies (e.g. foraminifera, IRD) were also made. A study of a sediment core from Andfjorden (69.16˚N, 16.25˚E), northern Norway, provided unequivocal evidence for the occurrence of seasonal sea ice conditions during the Younger Dryas. The onset (ca. 12.9 cal. kyr BP) and end (ca. 11.5 cal. kyr BP) of this stadial were especially clear in this location, while in a study from the Kveithola Trough (74.52˚N, 16.29˚E), western Barents Sea, these transitions were less apparent. This was attributed to the presence of colder surface waters and the occurrence of seasonal sea ice both before and after this stadial at higher latitudes. Some regional differences regarding the severity of the sea ice conditions were also observed, although an overall general picture was proposed, with more severe sea ice conditions during the early-mid Younger Dryas and less sea ice observed during the late Younger Dryas. A shift in the climate towards ice-free conditions was recorded in northern Norway during the early Holocene (ca. 11.5 – 7.2 cal. kyr BP). Milder conditions were also observed during the Holocene in the western Barents Sea, with three main climate periods observed. During the early Holocene (ca. 11.7 – 9.5 cal. kyr BP), the position of the spring ice edge was close to the study area which resulted in high productivity during summers. During the mid-late Holocene (ca. 9.5 – 1.6 cal. kyr BP), sea ice was mainly absent due to an increased influence of Atlantic waters and northward movement of the Polar Front. During the last ca. 1.6 cal. kyr BP, sea ice conditions were similar to those of the present day. In addition to the outcomes obtained from the Norwegian-Barents Sea region, comparison of biomarker and other proxy data from 3 short cores from Kangerdlugssuaq Trough (Denmark Strait/SE Greenland) with historical climate observations allowed the development of a model of sea ice conditions which was then tested for longer time-scales. It is suggested that the IP25 in sediments from this region is likely derived from drift ice carried from the Arctic Ocean via the East Greenland Current and that two main sea surface scenarios have existed over the last ca. 150 yr. From ca. AD 1850 – 1910, near perennial sea ice conditions resulted in very low primary productivity, while from ca. AD 1910 – 1986, local sea ice conditions were less severe with increased drift ice and enhanced primary productivity. This two-component model was subsequently developed to accommodate different sea surface conditions that existed during the retreat of the Greenland Ice Sheet during the deglaciation (ca. 16.3 – 10.9 cal. kyr BP).

A Dissertation submitted to the Faculty of Science, University of the Witwatersrand, in fulfillment of the requirements for the degree of Master of Science Johannesburg, 2018
The almost complete stratigraphic and fossil records of the Karoo Basin have made it one of the main focal points for Gondwanan palaeoenvironmental studies. The majority of Karoo palaeoenvironmental studies use vertebrate, invertebrate, macroflora and microflora fossils as proxies. Very few studies have been done on the Karoo fossil woods and their significance as palaeoenvironmental, and more specifically palaeoclimate, proxies. In this preliminary study, thirty-one Agathoxylon wood samples from the Ecca-Beaufort contact and five of the Beaufort Group’s (Karoo Basin) formations have been analysed to reconstruct the palaeoclimate for the Karoo Basin during the Beaufort times. The growth rings of each sample underwent a detailed growth ring analysis where six palaeoclimate significant anatomical features were chosen and used to obtain palaeoclimate information. The growth rings are generally wide and reflect a seasonal climate with warm/moderate temperatures and sufficient rainfall. The presence of false rings in some of the growth rings suggests that some years experienced water-stressed/semi-arid conditions. The intra-ring variation and CSDM curves of the growth rings indicate that the fossil wood samples generally reflect ‘complacent’ trees with deciduous habits. The majority of growth rings contain shear zones (i.e. S-type growth rings), which indicate a seasonal climate but can also be seen as indicators of zones with weakened wood cells (due to disease or post-depositional compression). Although this study only represents a small sample size (thirty-one specimens with very few growth rings each), the growth ring analysis illustrates the palaeoclimate potential of the Karoo fossil woods and how they could aid in improving Karoo Basin palaeoenvironmental interpretations. However, a wider geographic range and more fossil woods from other stratigraphic positions/time periods are required for the basin-wide palaeoclimate reconstruction that would make these improved palaeoenvironmental interpretations possible.
MT 2018

Research Doctorate - Doctor of Philosophy (PhD)
Changes in geochemical and physical properties of speleothems are considered to be accurate proxies of climate variability. However, the climate signal is modified by the internal dynamics of the whole karst system. The aim of the research was to obtain reproducible data extracted by established and non-conventional techniques from two coeval speleothems removed at Grotta Savi cave (Italy), to gain information about regional climate responses across the Last Glacial Maximum to Holocene transition. Different past hydrological regimes for the two stalagmites’ drips were reconstructed on the basis of stalagmites’ physical characteristics and this helped to disentangle the global from the local phenomena. This non-conventional approach, was applied here for the first time on fossil sample, resulting in a benchmark for interpreting the chemical proxies, and enabling assessment of calcite formation environment, hitherto not possible. The interpretation of δ¹⁸O values as reflecting past hydrology was then validated by using the Hydrology Index. The Index, developed in this study, considers two independent proxies: the Mg concentrations and the fraction of Sr uptake that is not dictated by growth rates. The method allowed recognition of a non-hydrological component encapsulated in δ¹⁸O values, then interpreted as changes of air mass provenance and rainfall seasonality. The δ¹³C was chiefly driven by temperature-dependent soil respiration rate. However, a hydrological component was also detected in the δ¹³C by using dead carbon proportion (dcp) and ⁸⁷Sr/⁸⁶Sr ratios. Increases of ⁸⁷Sr/⁸⁶Sr ratios suggest increases of aeolian dust deflated from proximal subalpine periglacial regions facilitated by vegetation-cover reduction, soil destabilisation and windier conditions, which in turn enhanced drier conditions. Although, the dcp trend was likely related to a local, faster, soil organic matter turnover, enhanced by warmer conditions, episodes of high dcp values were possibly hydrologically induced, as a result of wetter conditions. Furthermore, the Hydrology Index and δ¹³C signal allowed reconstructing that wet conditions occurred during climate cooling, an improvement relative to the state of the art of δ¹³C interpretation, where more commonly wet conditions occurs during warming. The comparison of δ¹³C trend of Savi with another stalagmite with similar physical characteristics, but from a cave (Sofular) located in Turkey, revealed a common trend despite the impact of the last glaciation having been drastic at Savi (no speleothem growth). Such δ¹³C similarity could be related to global phenomena and point to an intriguing possibility, which needs future testing, that speleothems may encode information of the C cycle, similar to soil carbonates. The palaeoclimate interpretation extracted from the Savi records between 15 to 9 ka indicates that the Younger Dryas (YD) was a dramatic climate reversal. In the northern Adriatic, the YD is characterised by high hydrological variability, strong winds and a cooling, which resulted in a decrease of vegetation cover and increase of soil erosion. The wind regime was possibly orographically induced, with the Alps acting as a barrier, deviating westerly winds and causing increased windiness in the northern Adriatic region. The Savi records reveal a significant Early Holocene anomaly (10.4 ka), whose drier and colder conditions were probably amplified by a local synoptic framework.

Research Doctorate - Doctor of Philosophy (PhD)
The records of environmental change in Australia’s arid zone can be greatly enriched by employing a multi-proxy approach and landscape-scale analysis. This research uses these tools to construct a palaeoenvironmental history of the Paroo/Warrego Region. While the Region’s flow regimes and water balances are characterised by medium-term (decadal) variability (Young, 1999), its hydrological records are inadequately brief. Subsequently, land and water management decisions are based on short term data, risking irreversible damage, desertification or loss of diversity. A better understanding of this highly dynamic landscape can thus improve the land and resource management outcomes. While dating was constrained by a lack of funds, the Paroo/Warrego history reconstructed from fluvial and aeolian deposits correlated well with events recorded from other inland regions of the Australian continent. In summary, this new research provided evidence of high lake water levels prior to the Last Glacial. The extreme aridity at the onset of Last Glacial caused long term drying of the lakes and mobilisation of the red sand dunes. In latter stages of the glacial phase the aridity gave way to periodic fluctuations between flood and drought events that probably lasted until 16 000 - 14 000 BP. The new climatic regime resulted in formation of gypsum lunettes and later, following reduction in gypsum supply, clay lunettes. The orientation of red sand dunes and lunettes indicates a more northerly extent of the westerlies than in modern times. Around the late Pleistocene-early Holocene boundary the climate became more stable and wetter, but still somewhat drier than during the pre-Last Glacial lacustrine phase. As a result, the region’s lakes reverted to a permanent and semi-permanent status. A strong aridity signal, comparable to the semi-regular droughts of the Last Glacial, was recorded in the Paroo/Warrego lakes during the late 1890s-1940s period of below average rainfall. It was followed by 50 years of wetter conditions with two extremely wet phases in the 1950s and the 1970s. Finally, the most recent records suggest a new drying trend. The semi-arid vegetation appears to have adapted to climate variability, with herbs and grasses expanding with the onset of wet conditions before being replaced by Chenopodiaceae as the landscape started to dry. The fresher lake basins and water courses were likely to provide refuge during prolonged arid phases and dispersal foci during intervening wetter periods, thus enabling greater flexibility in response to changes and enhancing resilience. The European land use interfered with the natural cycles and balances, leading to decrease in ground cover, suppression of fire, increase in runoff and catchment erosion, acceleration of sediment accumulation rates in wetlands, resulting in decline of their water holding capacity, and expansion of woody vegetation. The research improved the processing protocols, reference databases, and transfer of methods to enable greater sample processing efficiency and improve results. The use of multiple proxies (including biotic and abiotic components) and sites, as well as different depositional features, provided access to a broader picture of environmental change than was previously possible. It also facilitated multi-scale resolution, allowing discrimination between localised responses of individual lakes and regional trends. The full value of this research will come from informing natural resource managers, whose actions will shape the future landscapes of the Paroo and Warrego Region.

Research Doctorate - Doctor of Philosophy (PhD)
The records of environmental change in Australia’s arid zone can be greatly enriched by employing a multi-proxy approach and landscape-scale analysis. This research uses these tools to construct a palaeoenvironmental history of the Paroo/Warrego Region. While the Region’s flow regimes and water balances are characterised by medium-term (decadal) variability (Young, 1999), its hydrological records are inadequately brief. Subsequently, land and water management decisions are based on short term data, risking irreversible damage, desertification or loss of diversity. A better understanding of this highly dynamic landscape can thus improve the land and resource management outcomes. While dating was constrained by a lack of funds, the Paroo/Warrego history reconstructed from fluvial and aeolian deposits correlated well with events recorded from other inland regions of the Australian continent. In summary, this new research provided evidence of high lake water levels prior to the Last Glacial. The extreme aridity at the onset of Last Glacial caused long term drying of the lakes and mobilisation of the red sand dunes. In latter stages of the glacial phase the aridity gave way to periodic fluctuations between flood and drought events that probably lasted until 16 000 - 14 000 BP. The new climatic regime resulted in formation of gypsum lunettes and later, following reduction in gypsum supply, clay lunettes. The orientation of red sand dunes and lunettes indicates a more northerly extent of the westerlies than in modern times. Around the late Pleistocene-early Holocene boundary the climate became more stable and wetter, but still somewhat drier than during the pre-Last Glacial lacustrine phase. As a result, the region’s lakes reverted to a permanent and semi-permanent status. A strong aridity signal, comparable to the semi-regular droughts of the Last Glacial, was recorded in the Paroo/Warrego lakes during the late 1890s-1940s period of below average rainfall. It was followed by 50 years of wetter conditions with two extremely wet phases in the 1950s and the 1970s. Finally, the most recent records suggest a new drying trend. The semi-arid vegetation appears to have adapted to climate variability, with herbs and grasses expanding with the onset of wet conditions before being replaced by Chenopodiaceae as the landscape started to dry. The fresher lake basins and water courses were likely to provide refuge during prolonged arid phases and dispersal foci during intervening wetter periods, thus enabling greater flexibility in response to changes and enhancing resilience. The European land use interfered with the natural cycles and balances, leading to decrease in ground cover, suppression of fire, increase in runoff and catchment erosion, acceleration of sediment accumulation rates in wetlands, resulting in decline of their water holding capacity, and expansion of woody vegetation. The research improved the processing protocols, reference databases, and transfer of methods to enable greater sample processing efficiency and improve results. The use of multiple proxies (including biotic and abiotic components) and sites, as well as different depositional features, provided access to a broader picture of environmental change than was previously possible. It also facilitated multi-scale resolution, allowing discrimination between localised responses of individual lakes and regional trends. The full value of this research will come from informing natural resource managers, whose actions will shape the future landscapes of the Paroo and Warrego Region.

Studies in paleoclimate are important because they give us knowledge about how the climate system works and puts the current climate change in necessary perspective. By studying (pre)historic periods we increase our knowledge not just about these periods, but also about the processes that are important for climatic variations and changes. This thesis deals mainly with the interaction between climate and vegetation. Vegetation changes can affect climate in many different ways. These effects can be divided into two main categories: biogeochemical and biogeophysical processes. This thesis studies the biogeophysical effects of vegetation changes on climate in climate models. Climate models are a necessary tool for investigating how climate responds to changes in the climate system, as well as for making predictions of future climate. The biogeophysical processes are strongly related to characteristics of the land surface. Vegetation changes alter the land surface’s albedo (ability to reflect incoming solar radiation), roughness and evapotranspiration (the sum of evaporation and tran-spiration), which in turn affects the energy fluxes between the land surface and the atmosphere and thereby the climate. It is not, however, evident in what way; denser vegetation (e.g. forest instead of grassland) gives decreased albedo, which results in higher temperature, but also increased evapotranspiration, which contrastingly results in lower temperature. Vegetation changes are in this thesis studied in four different (pre)historic periods: two very cold periods with no human influence (c. 44,000 and 21,000 years ago), one warm period with minor human influence (c. 6,000 years ago) and a cold period with substantial human influence (c. 200 years ago). In addition to that the present climate is studied. The combination of these periods gives an estimate of the effect of both natural and anthropogenic vegetation on climate in different climatic contexts. The results show that vegetation changes can change temperature with 1–3 °C depending on season and region. The response is not the same everywhere, but depends on local properties of the land surface. During the winter half of the year, the albedo effect is usually most important as the difference in albedo between forest and open land is very large. During the summer half of the year the evapotranspiration effect is usually most important as differences in albedo between different vegetation types are smaller. A prerequisite for differences in evapotranspiration is that there is sufficient amount of water available. In dry regions, evapotranspiration does not change much with changes in vegetation, which means that the albedo effect will dominate also in summer. The conclusion of these studies is that vegetation changes can have a considerable effect on climate, comparable to the effect of increasing amounts of greenhouse gases in scenarios of future climate. Thus, it is important to have an appropriate description of the vegetation in studies of past, present and future climate. This means that vegetation has the potential to work as a feedback mechanism to natural climatic variations, but also that man can alter climate by altering the vegetation. It also means that mankind may have influenced climate before we started to use fossil fuel. Consequently, vegetation changes can be used as a means to mitigate climate change locally.
Studiet av paleoklimat är viktigt för att det ger kunskap om hur klimatsystemet fungerar samt för att det sätter nuvarande klimatförändring i ett nödvändigt perspektiv. Genom att studera (för)historiska perioder ökar vi vår kunskap om dessa perioder, men också om vilka processer som har betydelse för klimatets variationer. Denna avhandling behandlar framförallt interaktionen mellan klimat och växtlighet. Förändringar i växtligheten kan påverka klimatet på flera olika sätt. Dessa kan delas in i två huvudgrupper: biogeokemiska och biogeofysikaliska processer. Denna avhandling studerar de biogeofysikaliska effekterna på klimatet i klimatmodeller. Klimatmodeller är ett nödvändigt verktyg för att studera hur klimatet svarar på förändringar i klimatsystemet, samt för att göra förutsägelser om framtidens klimat. De biogeofysikaliska processerna är förknippade med markytans egenskaper. Förändrad växtlighet förändrar markytans albedo (förmågan att reflektera inkommande soltrålning), skrovlighet och förmågan att transportera vatten från marken till atmosfären genom evapotranspiration (summan av avdunstning och transpiration), vilket i sin tur påverkar energiflödena mellan markytan och atmosfären. Dessa förändringar påverkar sedermera klimatet. Det är emellertid inte självklart på vilket sätt; tätare växtlighet (t.ex. skog i stället för äng) ger minskat albedo vilket ger högre temperatur, men också ökad evapotranspiration vilket däremot ger lägre temperatur. Växtlighetsförändringars påverkan på klimatet studeras i denna avhandling i fyra olika (för)historiska perioder: två väldigt kalla perioder utan mänsklig påverkan (ca 44 000 och 21 000 år sedan), en varm period med liten mänsklig påverkan (ca 6 000 år sedan) och en kall period med avsevärd mänsklig påverkan (ca 200 år sedan). I tillägg till det studeras också dagens klimat. Resultaten visar att förändringar i växtlighet lokalt kan ha en signifikant effekt på klimatet. Kombinationen av dessa perioder ger en uppskattning av effekten av både naturlig och antropogen växtlighet i olika klimatsammanhang. Förändrad växtlighet kan ändra temperaturen med 1-3 °C beroende på årstid och område. Responsen är inte densamma överallt utan beror på lokala egenskaper hos markytan. Under vinterhalvåret är oftast albedoeffekten viktigast eftersom skillnaden i albedo mellan skog och öppet landskap då är mycket stor. Under sommarhalvåret är evapotranspirationen oftast viktigast eftersom skillnaden i albedo mellan olika växtlighetstyper då oftast är små. En förutsättning för det är att det finns tillräckligt med vatten tillgängligt för evapotranspiration. I torra områden förändras evapotranspirationen inte särskilt mycket när växtligheten förändras, vilket gör att albedoeffekten dominerar även på sommaren.  Slutsatsen av dessa studier blir att förändrad växtlighet kan ha en betydande effekt på klimatet, jämförbar med den effekt som ökade halter av växthusgaser har i scenarier för framtida klimat. Alltså är det viktigt att ha en korrekt beskrivning av växtligheten i studier av (för)historiskt, nutida och framtida klimat. Det betyder att växtligheten har potentialen att fungera som en återkopplingsmekanism till naturliga klimatvariationer, men också att människan kan påverka klimatet genom att förändra växtligheten. Det betyder också att mänskligheten kan ha påverkat klimatet innan vi började använda fossilt bränsle. Följaktligen kan växtlighetsförändringar användas som ett sätt att lokalt begränsa klimatförändringar.

At the time of the doctoral defense, the following paper was unpublished and had a status as follows: Paper 4: Manuscript.

No
Multiproxy palaeohydrological records from three raised bogs in Northern Ireland indicate that a major shift to wetter/cooler climatic conditions postdated the rapid decrease in solar activity at 2800 cal. BP by ~100 years. This event is bracketed by two wiggle-match radiocarbon-dated cryptotephra layers in each profile, enabling a high degree of chronological precision. These replicated data corroborate previous findings based on Irish peat humification profiles, and may indicate spatial complexity in the climatic response to solar activity between oceanic and continental areas.

This item is only available electronically.
The variation in distribution and abundance of leaf wax n-alkanes has been proposed as a proxy for palaeoclimate. Understanding environmental controls on the variation in distribution and abundance of leaf wax n-alkanes is therefore necessary to determine if this is a robust tool for extracting climatic information from palaeo archives. Results of previous work to create a modern baseline for this proxy have, in some cases, been confounded by differences in species or plant type between sites or along gradients. This study investigates leaf wax n-alkane variation within a species of Australian shrub, Dodonaea viscosa, which inhabits a wide range of climatic conditions. Leaf wax n-alkane data from 43 individuals of D. viscosa were analysed from a climatic gradient ranging from central Australia to Kangaroo Island, with a mean annual temperature range of 13.9—22.7 °C and precipitation range of 164—808 mm/yr. Concentration of n-alkanes increase with increasing temperature along the gradient. Annual mean aridity index has the strongest relationship with the average chain length (ACL) of leaf wax n-alkanes and suggests that water availability is a strong driver of variation in ACL. In addition to n-alkane data, carbon isotope ratio (δ13C) and specific leaf area (SLA) data were measured to determine if this species shows predictable responses to these established and climatically sensitive leaf traits. Predicted responses in δ13C and SLA are observed in this species. Only weak effects of subspecies on leaf trait relationships with climate are found in this study. Scanning electron microscopy was used to qualitatively assess differences in leaf wax microstructure with climate and produced inconclusive results. Distributions of leaf wax n-alkanes have great potential as a proxy for palaeoclimate. Results presented here support the use of n-alkane ACL variation to detect aridity rather than temperature.
Thesis (B.Sc.(Hons)) -- University of Adelaide, School of Physical Sciences, 2015

Thesis submitted in fulfilment of the academic requirements for the degree of Doctor of Philosophy School of Geography, Archaeology and Environmental Studies University of the Witwatersrand, Johannesburg October 2015
The eastern Lesotho highlands observe climate patterns distinct from adjacent lower altitude regions, representing a niche environment with unique biodiversity, comprising well-adapted but restricted biomes. With a heavy reliance on subsistence agriculture, Lesotho faces risks to both the economy and individual livelihoods, should current rates of climate change persist or intensify. Furthermore, eastern Lesotho serves as southern Africa’s primary water catchment, with precipitation exceeding evaporation. Any changes in the climate and hydrological systems, as are likely under climate change scenarios, would compromise biomes, livelihoods, and water security both locally and regionally. Climate change research in eastern Lesotho, is thus of particular value, yet meteorological data are sparse and the palaeoenvironmental history remains poorly resolved. This research presents the first multi-proxy Holocene palaeoenvironmental and palaeoclimatic reconstruction for eastern Lesotho. This reconstruction is developed from the results from pollen, diatom and sediment analyses, extracted from sediment cores obtained from two peat bogs at Sani Valley (~2,800 m.asl) and Mafadi Wetland (~3,390 m.asl), and from an exposed gully-sidewall profile at Sekhokong (~2,950 m.asl), approximately 1km south of the Sani Valley site. The reconstructions are temporally constrained by AMS radiocarbon dates obtained for all three sites. Mafadi Wetland demonstrates marked differences to the lower altitude sites, including slower sedimentation rates, a decrease in pollen and diatom taxa diversity, and an increase in the relative abundance of ice-tolerant diatom taxa. The microtopography of the three sites influences the rates of sedimentation, sediment properties, pollen composition, and distinct palaeoenvironmental and palaeoclimatic reconstructions for each site. The Sekhokong record commences in the late Pleistocene, with a wet period from ~13,180-10,850 cal. yr BP, interrupted by a dry period from ~13,080-12,830 cal. yr BP. From ~10,550-6,420 cal. yr BP, the Sekhokong record indicates a drier climate with a slow transition to warmer, wetter conditions. The Mafadi Wetland record commences with cold, wet conditions from ~8,140-7,580 cal. yr BP, followed by a warmer, drier period from ~7,520-6,680 cal. yr BP. Thereafter, greater microclimatic differences are apparent. For Sekhokong, warmer, dry conditions are inferred for ~6,420-6,000 cal. yr BP, followed by cold, wet conditions from ~6,000-5,450 cal. yr BP. Warmer, dry conditions commence earlier at Mafadi Wetland, from ~6,160-5,700 cal. yr BP, coinciding with the initiation of a longer wet period at Sani Valley, from ~6,200-4,900 cal. yr BP. At Sekhokong, a dry, warmer period follows from ~5,450-3,700 cal. yr BP. At Sani Valley, drier conditions are evident from ~4,770-4,470 cal. yr BP, followed by a cold, wet period from ~4,460-2,260 cal. yr BP. For Mafadi Wetland, these cold, wet conditions endure longer, from ~5,600-1,100 cal. yr BP. This overlaps with similarly cool, wet conditions at Sekhokong, from ~3,650- 1,200 cal. yr BP. By contrast, dry conditions are evident at Sani Valley, from ~2,260-1,350 cal. yr BP. For all three sites, ~1,000 cal. yr BP to present is characterised by progressive drying, with discrete wet events. Pronounced cold events are detected at ~12,660 cal. yr BP, ~8,400-8,000 cal. yr BP and ~150 cal. yr BP. The results of this study indicate similarities with records from adjacent studies in western Lesotho and South Africa, although with notable variability in the timing of events. The palaeoenvironmental reconstructions for eastern Lesotho, and their comparison with existing studies, provide valuable information to improve the understanding of southern African Holocene climates, and to facilitate the development of high resolution, accurate climate models for the eastern Lesotho region.