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Journal articles on the topic 'Oxyde thermique'

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1

Mansurov, Z. A., D. S. Abdulkarimova, O. Odawara, et al. "Peculiarities of Self-Propagating High-Temperature Synthesis and Structure Formation of TiB2-Al2O3 and CrB2-Al2O3 Composites." Eurasian Chemico-Technological Journal 13, no. 3-4 (2011): 161. http://dx.doi.org/10.18321/ectj.80.

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Preparation of TiB2-Al2O3 and CrB2-Al2O3 composites with a broad range of phase composition was conducted by self-propagating high-temperature synthesis (SHS) involving reaction of different types. The formation of fibrous crystals of aluminum oxide with length of about 10-25 microns and with diameter of 200-500 nm at self-propagating high-temperature synthesis in the system 2B2O3-Cr2O3-6A1 was established. Thermite mixtures of Al-TiO2 and Al-TiO2-B2O3 were incorporated with the Ti-B combustion system to produce the composites of TiB2-Al2O3, within which the increase of the thermite mixture fo
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2

Sojiphan, Kittichai. "Experimental and simulation study of phase transformation in thermite welded railway steel heat-affected zone regions." Zavarivanje i zavarene konstrukcije 66, no. 2 (2021): 63–71. http://dx.doi.org/10.5937/zzk2102063s.

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Rail transportation has been an emerging and promising transportation method for economic development in Thailand and several countries. Thermite welding is one of the major welding and joining processes used to weld rail steel both during construction and maintenance. Unlike most welding processes in which heat is generated by electrical energy, thermite welding use heat generated during the chemical reactions between iron oxide and aluminum or other metallic compounds to create the weld. The amount of heat generated is thus depended on the composition and ratios of iron oxide, aluminum, as w
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3

Enkov, Maksim O., Tatiana I. Gorbenko, and Mikhail V. Gorbenko. "Thermodynamic modeling of high-energy thermite systems based on calcium iodate." Vestnik Tomskogo gosudarstvennogo universiteta. Matematika i mekhanika, no. 87 (2024): 106–19. http://dx.doi.org/10.17223/19988621/87/9.

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The article presents the results of a thermodynamic study of the component content influence and their physical and chemical properties on the regulation of the main energy characteristics and combustion product characteristics of thermite systems based on calcium iodate containing Al, B and Ti. The adiabatic combustion temperature, enthalpy of combustion products, specific impulse, exhaust velocity of combustion products, mass fraction of condensed phases, content of gaseous and condensed combustion products are determined. The influence of the metal oxide/metal fuel content in the thermite s
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4

Lowry, Bill, Andrew Louden, Robin Jerman, and Tatiana Pyatina. "Corrosion-Resistant Plug Materials for Geothermal Well Fluid Control." Materials 15, no. 19 (2022): 6703. http://dx.doi.org/10.3390/ma15196703.

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Conventional cements and plugs are challenged by corrosion in CO2-rich and extreme geothermal environments, due to the hostile chemistry and high temperatures. Thermite-based sealing and well intervention technologies are being applied in the oil and gas industry, combining the energy delivery capability of thermite materials with the sealing characteristics of low melt temperature alloys. The thermite reaction products (ceramics) and the sealing alloys used in these plugs both have very attractive corrosion properties, and their operating envelopes extend into geothermal conditions. Thermite
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5

Nadir, S., JL Lacout, and M. Ferhat. "Comportement thermique de l’hydroxyapatite en présence de divers oxydes." Journal de Chimie Physique 88 (1991): 1919–24. http://dx.doi.org/10.1051/jcp/1991881919.

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6

Courvoisier, Emilie, Yoann Bicaba, and Xavier Colin. "Analyse de la dégradation thermique du Poly(éther imide)." Matériaux & Techniques 105, no. 4 (2017): 402. http://dx.doi.org/10.1051/mattech/2018006.

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La dégradation thermique du PEI a été étudiée dans de larges intervalles de température (entre 180 et 250 °C) et de pression partielle d’oxygène (entre 0,21 et 50 bars). Tout d’abord, les mécanismes de vieillissement thermique ont été analysés et élucidés par spectroscopie IRTF et par calorimétrie différentielle (DSC) sur des films de PEI suffisamment minces (entre 10 et 60 μm d’épaisseur) pour s’affranchir totalement des effets de la diffusion d’oxygène. Comme attendu, et par analogie avec d’autres polymères aromatiques de structure chimique similaire, l’oxydation se produit préférentiellemen
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7

Novoseltsev, A. I., L. I. Sorokina, A. V. Sysa, R. M. Ryazanov, and E. A. Lebedev. "Al-CuOx multilayer nanostructures: formation features and thermal properties of new type of local heat source." Journal of Physics: Conference Series 2086, no. 1 (2021): 012213. http://dx.doi.org/10.1088/1742-6596/2086/1/012213.

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Abstract In this work, multilayer nanostructured thermite materials are considered - a new type of local heat sources. Aluminium and copper oxide were chosen as components of the thermite mixture. The formation of multilayer structures was carried out on the surface of the substrate by the method of magnetron sputtering. The features of the deposition process as well as the energy properties of the formed materials have been investigated. The results obtained confirm the prospects of using this class of materials as local heat sources.
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8

Hocquaux, H., and R. Meilland. "Analyse des oxydes et des nitrures par décomposition thermique fractionnée." Revue de Métallurgie 89, no. 2 (1992): 193–99. http://dx.doi.org/10.1051/metal/199289020193.

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9

Kim, Namgyu, and Hae-Bum Yun. "Noncontact mobile sensing for absolute stress in rail using photoluminescence piezospectroscopy." Structural Health Monitoring 17, no. 5 (2017): 1213–24. http://dx.doi.org/10.1177/1475921717742102.

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A novel noncontact, mobile sensing technique to measure absolute stress in rail using photoluminescence piezospectroscopy is presented. Photoluminescence piezospectroscopy is a vibrational spectroscopy technique for chemical identification and stress measurement by focusing low-power laser on a substance surface. Thermite welding is a major welding method for continuous welded rail, which produces iron (Fe) and aluminum oxides (Al2O3) after aluminothermic reaction. Photoluminescence piezospectroscopy was used as a noncontact stress sensing method since photoluminescence piezospectroscopy has a
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10

Zhang, Mi, Hui Ren, Qingzhong Cui, Hanjian Li, and Yongjin Chen. "Effects of Different Nanocarbon Materials on the Properties of Al/MoO3/NCM Thermite Prepared by Electrostatic Spinning." Nanomaterials 12, no. 4 (2022): 635. http://dx.doi.org/10.3390/nano12040635.

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In order to improve thermal conductivity, energy performance, and combustion performance of the aluminum-containing thermite, nanocarbon materials were added to thermite. Aluminum/molybdenum and trioxide/nanocarbon materials (Al/MoO3/NCM) were fabricated by electrostatic spinning technology. The Al and MoO3 particles of the nAl/MoO3/NCM thermite are much smaller than nitrocellulose (NC); thus, the two components can be better attached to NC fibers. Results on thermal conductivity demonstrated that the addition of NCM can improve the thermal conductivity of Al/MoO3, and the addition of reduced
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11

Ivanova, O. V., R. O. Cherepanov, and S. A. Zelepugin. "Numerical simulation of solid-phase chemical transformations in thermite mixtures under shock-wave loading." Journal of Physics: Conference Series 2154, no. 1 (2022): 012005. http://dx.doi.org/10.1088/1742-6596/2154/1/012005.

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Abstract Shock-wave loading of a steel cylindrical ampoule that contained an aluminum-copper oxide(Al/CuO) thermite mixture is simulated in three-dimensional space using the SPH method.The chemical reaction starts after the performance of the criterion on temperature or pressure.Thechemical reaction equations are integrated using the first-order Euler method.The elastic-plastic flow is calculated using the variational formulation.The numerical study of solid-phase chemical transformations in the Al/CuO thermite mixture under shock-wave loading shows that the initiation of reactions in the shoc
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12

Maquestiau, A., Y. van Haverbeke, R. Flammang, S. O. Chua, M. J. Cook, and A. R. Katritzky. "Degradation Thermique D'Imidazole-N-Oxydes dans la Source D'Un Spectrometre de Masse." Bulletin des Sociétés Chimiques Belges 83, no. 1-2 (2010): 105–6. http://dx.doi.org/10.1002/bscb.19740830112.

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13

Gibot, Pierre, and Estelle Puel. "Study on Indium (III) Oxide/Aluminum Thermite Energetic Composites." Journal of Composites Science 5, no. 7 (2021): 166. http://dx.doi.org/10.3390/jcs5070166.

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Thermites or composite energetic materials are mixtures made of fuel and oxidizer particles at micron-scale. Thermite reactions are characterized by high adiabatic flame temperatures (>1000 °C) and high heats of reaction (>kJ/cm3), sometimes combined with gas generation. These properties strongly depend on the chemical nature of the couple of components implemented. The present work focuses on the use of indium (III) oxide nanoparticles as oxidizer in the elaboration of nanothermites. Mixed with an aluminum nanopowder, heat of reaction of the resulting Al/In2O3 energetic nanocomposite wa
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14

Boutouta, Aziza, and Mohamed Yacine Debili. "Microstructural and thermal characteristics of the sintered Al-Fe2O3 composites." Engineering review 40, no. 1 (2020): 32–38. http://dx.doi.org/10.30765/er.40.1.05.

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This work has as an objective a study of evolution of characteristic properties of crystalline microstructure and mechanical hardening of aluminum by iron oxide (III), (hematite α-Fe2O3) nan energetic material known as thermite, samples of massive alloys, Al (base)-X wt% Fe2O3 (X =2, 4, 16 and 40) were studied.Al-Fe2O3 composite was developed by a sintering technique from the mixtures of compacted powders of Al high purity and α-Fe2O3 under a temperature of 700 °C for 1 hour and then slowly cooled. We have not noted the formation of thermite as foreseen by the chemical reaction due to the mixt
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15

Sundaram, V., K. V. Logan, and R. F. Speyer. "Reaction path in the magnesium thermite reaction to synthesize titanium diboride." Journal of Materials Research 12, no. 10 (1997): 2657–64. http://dx.doi.org/10.1557/jmr.1997.0355.

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TiB2, along with MgO and Mg3B2O6, was formed by a thermite reaction between Mg, amorphous B2O3, and TiO2 powders in argon. The mixture 5Mg–TiO2–B2O3 along with binary mixtures and single components were analyzed using differential thermal analysis (DTA) and x-ray diffraction (XRD). Large (25 g) specimens were also ignited in bulk using a resistance-heated nichrome wire. The reaction path in forming TiB2 in the three component mixture was deduced. Mg reduces TiO2 and B2O3 to form Ti and MgB2, respectively, which in turn react to form TiB2. In an oxidizing atmosphere, the significant speed of th
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16

Hou, Qing, Zhi Cheng Shi, Run Hua Fan, and Li Cheng Ju. "Cryomilling and Characterization of Metal/Ceramic Powders." Key Engineering Materials 512-515 (June 2012): 127–31. http://dx.doi.org/10.4028/www.scientific.net/kem.512-515.127.

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Al/Fe2O3 thermite powders were prepared by cryomilling at liquid nitrogen temperature. The cryogenic temperature will restrain the mechanochemical reaction between alumina and iron oxide, leading to high reactivitive nanoscale powders. The size distribution of the powders was analyzed using laser particle size analyzer, and cryomilling was proved to be an effective method to prepare ultrafine powders. The differential scanning calorimetry (DSC) analysis indicated that the cryomilled powders get more fully-reacted, a larger proportion of solid-solid reaction and more heat release in the solid-l
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17

Mei, J., R. D. Halldearn, and P. Xiao. "Mechanisms of the aluminium-iron oxide thermite reaction." Scripta Materialia 41, no. 5 (1999): 541–48. http://dx.doi.org/10.1016/s1359-6462(99)00148-7.

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18

Yin, Yanjun, and Zili Ma. "Pseudo-oxide metal carbodiimides: Application in thermite reactions." Combustion and Flame 252 (June 2023): 112741. http://dx.doi.org/10.1016/j.combustflame.2023.112741.

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19

Cervantes, Octavio G., Joshua D. Kuntz, Alexander E. Gash, and Zuhair A. Munir. "Activation energy of tantalum–tungsten oxide thermite reactions." Combustion and Flame 158, no. 1 (2011): 117–22. http://dx.doi.org/10.1016/j.combustflame.2010.07.023.

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20

Su, Jiaxin, Yan Hu, Bin Zhou, Yinghua Ye, and Ruiqi Shen. "The Role of Graphene Oxide in the Exothermic Mechanism of Al/CuO Nanocomposites." Molecules 27, no. 21 (2022): 7614. http://dx.doi.org/10.3390/molecules27217614.

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Metastable intermixed composites (MICs) have received increasing attention in the field of energy materials in recent years due to their high energy and good combustion performance. The exploration of ways of improving their potential release of heat is still underway. In this study, Al–CuO/graphene oxide (GO) nanocomposites were prepared using a combination of the self-assembly and in-suit synthesis methods. The formulation and experimental conditions were also optimized to maximize the exothermic heat. The DSC analysis shows that the addition of the GO made a significant contribution to the
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21

Cervantes, Octavio G., Joshua D. Kuntz, Alexander E. Gash, and Zuhair A. Munir. "Heat of combustion of tantalum–tungsten oxide thermite composites." Combustion and Flame 157, no. 12 (2010): 2326–32. http://dx.doi.org/10.1016/j.combustflame.2010.07.002.

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22

Joo, H., J. Yun, K. Hwang, and B. S. Jun. "Synthesis of AlON Refractory Raw Materials from Aluminum Dross Using Thermite Reaction Process." Materials Science Forum 510-511 (March 2006): 866–69. http://dx.doi.org/10.4028/www.scientific.net/msf.510-511.866.

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Aluminum dross is presented as a potential material to form AlON using thermite reaction. The commercial MgAl powder, active carbon, and titania were prepared to make a chemical furnace (self-propagation combustion). The preheating temperature of 300 is enough to intitate ignition of the mixture as fuel and oxidizer. The addition of Y2O3 (1wt. %) is effective to enhance solid solution products between Al2O3 and AlN in the Aluminum dross. The level of contamination like an alkali metal oxide in the Aluminum dross was reduced highly by the heat from chemical furnace.
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23

Elmasmodi, Abdellatif, Didier Barbry, Bruno Hasiak, and Daniel Couturier. "Evolution thermique de derives des hexahydrobenzazocines-2 et des hexahydro-1H-benzazonines-2 N-quaternarises (ammoniums, N-oxydes)." Collection of Czechoslovak Chemical Communications 54, no. 10 (1989): 2767–74. http://dx.doi.org/10.1135/cccc19892767.

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La thermolyse des hydroxydes d’ammonium derives des hexahydrobenzazocines-2 et de la methyl-2-hexahydro-1H benzazonine-2 conduit a un melange de composes ethyleniques [butenyl-3 (ou pentenyl-4) N,N-dimethylbenzylamine et dimethylamino-1 orthotolyl-4 butene-3 (ou pentene-4)]. Les N-oxydes de N-methyl hexahydrobenzazocines-2 se decomposent thermiquement en derives de l’oxa-2 hexahydro-1H-benzazonines-3 souilles de la benzazocine de depart.
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24

Lau, Cheryl, Alexander S. Mukasyan, and Arvind Varma. "Reaction and phase separation mechanisms during synthesis of alloys by thermite type combustion reactions." Journal of Materials Research 18, no. 1 (2003): 121–28. http://dx.doi.org/10.1557/jmr.2003.0018.

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Combustion of the thermite system is a promising approach for synthesis of alloys (e.g., Co-based) that are widely used in orthopedic applications. This process typically involves formation of two liquids (oxide and metal alloy), followed by their phase separation. The latter is generally believed to be controlled solely by gravity-driven buoyancy. To verify this hypothesis, a fundamental study of phase separation during alloy synthesis was conducted in both normal gravity and microgravity conditions. It was shown that a non-gravity-driven mechanism primarily controls the segregation process.
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Russell, R., S. Bless, and M. Pantoya. "Impact-Driven Thermite Reactions with Iodine Pentoxide and Silver Oxide." Journal of Energetic Materials 29, no. 2 (2011): 175–92. http://dx.doi.org/10.1080/07370652.2010.514318.

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26

Gibot, Pierre, and Virginie Goetz. "Aluminium/tin (IV) oxide thermite composite: sensitivities and reaction propagation." Journal of Energetic Materials 38, no. 3 (2019): 295–308. http://dx.doi.org/10.1080/07370652.2019.1685024.

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27

Durães, Luísa, José Campos, and António Portugal. "Radial Combustion Propagation in Iron(III) Oxide/Aluminum Thermite Mixtures." Propellants, Explosives, Pyrotechnics 31, no. 1 (2006): 42–49. http://dx.doi.org/10.1002/prep.200600006.

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28

Brotman, Sarah, Mehdi Djafari Rouhani, Samuel Charlot, Alain Estève, and Carole Rossi. "A Benchmark Study of Burning Rate of Selected Thermites through an Original Gasless Theoretical Model." Applied Sciences 11, no. 14 (2021): 6553. http://dx.doi.org/10.3390/app11146553.

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This paper describes a kinetic model dedicated to thermite nanopowder combustion, in which core equations are based on condensed phase mechanisms only. We explore all combinations of fuels/oxidizers, namely Al, Zr, B/CuO, Fe2O3, WO3, and Pb3O4, with 60 % of the theoretical maximum density packing, at which condensed phase mechanisms govern the reaction. Aluminothermites offer the best performances, with initiation delays in the range of a few tens of microseconds, and faster burn rates (60 cm s−1 for CuO). B and Zr based thermites are primarily limited by diffusion characteristics in their oxi
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29

Knapp, Sebastian, Stefan Kelzenberg, Angelika Raab, Evelin Roth, and Volker Weiser. "Emission Spectroscopy of the Combustion Flame of Aluminium/Copper Oxide Thermite." Propellants, Explosives, Pyrotechnics 44, no. 1 (2018): 9–17. http://dx.doi.org/10.1002/prep.201800235.

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30

Gesner, Jeffrey, Michelle L. Pantoya, and Valery I. Levitas. "Effect of oxide shell growth on nano-aluminum thermite propagation rates." Combustion and Flame 159, no. 11 (2012): 3448–53. http://dx.doi.org/10.1016/j.combustflame.2012.06.002.

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31

BENDRE, YU V., V. F. GORYUSHKIN, N. A. KOZYREV, R. A. SHEVCHENKO, and N. V. OZNOBIKHINA. "THERMODYNAMIC ASPECTS OF OXIDES REDUCING BY ALUMINUM AND TITANIUM AT THE THERMIT WELDING OF RAILS." Ferrous Metallurgy. Bulletin of Scientific , Technical and Economic Information 77, no. 12 (2021): 1291–95. http://dx.doi.org/10.32339/0135-5910-2021-12-1291-1295.

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During aluminothermic welding of rails, formation of aluminum oxides can take place, which become centers of residual stresses forming resulting in cracks formation followed by fracture and destruction of the welding joint. It was proposed to add titanium scrap in the form of preliminary made powders to the welding thermites composition. At the replacement of aluminum by titanium, titanium oxides formation takes place providing higher resistance against cracks formation. Comparative estimation of thermodynamic properties [∆rH°(T), ∆rG°(T)] of thermite reactions with aluminum and titanium in th
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32

Wang, Jie, Hongtao Yang, Long Cheng, Pin Gao, Yanchun Li, and Dongming Song. "Ignition and Combustion Characteristics of B/NC/CuO Thermite Microparticles." Metals 12, no. 9 (2022): 1419. http://dx.doi.org/10.3390/met12091419.

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To improve the combustion stability and ignition performance of thermite, B/NC/CuO micro particles were prepared from boron (B), nano copper oxide (CuO), and nitrocellulose (NC) as an energetic binder through the electrospray technique. The burning rate dependency on boron content, ambient temperature, and pressure was estimated by compressing B/NC/CuO micro particles into columns. Scanning electron microscopy results show that the sizes of these particles mostly lie in the range of 3–4 μm. The particles are ignitable and burn consistently with minor variations in the conditions: B content (8.
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33

WANG, Yi, Xiao-lan SONG, Wei JIANG, et al. "Mechanism for thermite reactions of aluminum/iron-oxide nanocomposites based on residue analysis." Transactions of Nonferrous Metals Society of China 24, no. 1 (2014): 263–70. http://dx.doi.org/10.1016/s1003-6326(14)63056-9.

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34

Kobyakov, V. P., and D. Yu Kovalev. "Phase constitution of the combustion products of thermite mixtures modified by titanium oxide." Combustion, Explosion, and Shock Waves 43, no. 6 (2007): 674–81. http://dx.doi.org/10.1007/s10573-007-0090-6.

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35

Lee, Hansung, Minsu Kim, and Byungmin Ahn. "Controlling Particle Size of Recycled Copper Oxide Powder for Copper Thermite Welding Characteristics." journal of Korean Powder Metallurgy Institute 30, no. 4 (2023): 332–38. http://dx.doi.org/10.4150/kpmi.2023.30.4.332.

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36

Choi, Sang-Kyu, Sung-Sang Park, and Eung-Ryul Baek. "Development of Thermite Powder for Rail Joining with Recycled Iron Oxide and Aluminium Powder." Journal of the Korean Welding and Joining Society 30, no. 5 (2012): 40–45. http://dx.doi.org/10.5781/kwjs.2012.30.5.434.

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37

Gromov, A. A., A. M. Gromov, E. M. Popenko, et al. "Formation of calcium in the products of iron oxide–aluminum thermite combustion in air." Russian Journal of Physical Chemistry A 90, no. 10 (2016): 2104–6. http://dx.doi.org/10.1134/s0036024416100137.

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38

Weiser, Volker, Evelin Roth, Angelika Raab, Maria del Mar Juez-Lorenzo, Stefan Kelzenberg, and Norbert Eisenreich. "Thermite Type Reactions of Different Metals with Iron-Oxide and the Influence of Pressure." Propellants, Explosives, Pyrotechnics 35, no. 3 (2010): 240–47. http://dx.doi.org/10.1002/prep.201000024.

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39

Kuntz, Joshua D., Octavio G. Cervantes, Alexander E. Gash, and Zuhair A. Munir. "Tantalum–tungsten oxide thermite composites prepared by sol–gel synthesis and spark plasma sintering." Combustion and Flame 157, no. 8 (2010): 1566–71. http://dx.doi.org/10.1016/j.combustflame.2010.01.005.

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40

Barbry, Didier, Bruno Hasiak, Jean-Michel Augait, and Daniel Couturier. "Evolution thermique de N-oxydes de dimethylamino-5 alcanols-1 substitues en 5. Competition entre rearrangements de cope et de Meisenheimer." Collection of Czechoslovak Chemical Communications 50, no. 4 (1985): 956–61. http://dx.doi.org/10.1135/cccc19850956.

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The effect of the substituent R in the position was studied in the decomposition of 1,5-aminoalcohol N-oxides: Meisenheimer rearrangement takes place when R is the vinyl group but is not observed with the phenyl substituent; elimination to alkenol only affects the more acidic hydrogen atom when R is the allyl or benzyl group; with substituents inducing less important electronic effects (methyl, ethyl), the reaction yields an alkenols mixture with statistical distribution.
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41

Polis, Mateusz, Agnieszka Stolarczyk, Karolina Glosz, and Tomasz Jarosz. "Quo Vadis, Nanothermite? A Review of Recent Progress." Materials 15, no. 9 (2022): 3215. http://dx.doi.org/10.3390/ma15093215.

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One of the groups of pyrotechnic compositions is thermite compositions, so-called thermites, which consist of an oxidant, usually in the form of a metal oxide or salt, and a free metal, which is the fuel. A characteristic feature of termite combustion reactions, apart from their extremely high exothermicity, is that they proceed, for the most part, in liquid and solid phases. Nanothermites are compositions, which include at least one component whose particles size is on the order of nanometers. The properties of nanothermites, such as high linear burning velocities, high reaction heats, high s
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42

Wang, Yi, Xiaolan Song, Wei Jiang, et al. "SYNTHESIS OF NANO-NICKEL-COATED MICRO-ALUMINUM AND THERMAL REACTIVITY OF ALUMINUM/NICKELSTANNIC-OXIDE THERMITE." International Journal of Energetic Materials and Chemical Propulsion 10, no. 3 (2011): 231–43. http://dx.doi.org/10.1615/intjenergeticmaterialschemprop.2012004927.

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43

Yeh, C. L., and J. A. Peng. "Effects of oxide precursors on fabrication of Mo5Si3–Al2O3 composites via thermite-based combustion synthesis." Intermetallics 83 (April 2017): 87–91. http://dx.doi.org/10.1016/j.intermet.2016.12.012.

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Michard, G., D. Jezequel, and E. Viollier. "Vitesses de réaction de dissolution et précipitation au voisinage de l'interface oxydo-réducteur dans un lac méromictique : le lac Pavin (Puy de Dôme, France)." Revue des sciences de l'eau 16, no. 2 (2005): 199–218. http://dx.doi.org/10.7202/705504ar.

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Une étude à l'échelle centimétrique de l'interface redox situé à la limite entre mixolimnion et monimolimnion d'un lac méromictique (le lac Pavin) a permis d'observer très finement l'évolution de la concentration d'un certain nombre d'éléments chimiques. Nous avons choisi de présenter ici des résultats concernant 5 éléments qui présentent des comportements très contrastés : le rubidium, le fer, le baryum, le vanadium et le manganèse. La comparaison avec un élément conservatif, le sodium, montre que Rb est conservatif, que Fe, Ba et V sont précipités et que Mn est dissous dans cette zone. Une m
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Li, Shi, Tao Guo, Miao Yao, et al. "Effect of Bismuth Oxide Particles Size on the Thermal Excitation and Combustion Properties of Thermite Systems." ChemistryOpen 10, no. 4 (2021): 464–70. http://dx.doi.org/10.1002/open.202000358.

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Zhang, Yu-ying, Meng-jie Wang, Chun-ran Chang, Kang-zhen Xu, Hai-xia Ma, and Feng-qi Zhao. "A DFT study on the enthalpies of thermite reactions and enthalpies of formation of metal composite oxide." Chemical Physics 507 (May 2018): 19–27. http://dx.doi.org/10.1016/j.chemphys.2018.04.004.

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47

Woll, Karsten, John David Gibbins, Kyle Slusarski, Alex H. Kinsey, and Timothy P. Weihs. "The utilization of metal/metal oxide core-shell powders to enhance the reactivity of diluted thermite mixtures." Combustion and Flame 167 (May 2016): 259–67. http://dx.doi.org/10.1016/j.combustflame.2016.02.006.

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Gibot, Pierre, Estelle Puel, Bastien Lallemand, and Franck Oudot. "Conductive Oxides for Formulating Mitigated-Sensitivity Energetic Composite Materials." Journal of Composites Science 6, no. 6 (2022): 174. http://dx.doi.org/10.3390/jcs6060174.

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Composite energetic nanomaterials, otherwise known as nanothermites, consist of physical mixtures of fuel and oxidizer nanoparticles. When a combustion reaction takes place between both components, extremely impressive conditions are created, such as high temperatures (>1000 °C), intense heat releases (>kJ/cm3), and sometimes gas generation. These conditions can be adjusted by modifying the chemical nature of both reactants. However, these energetic composites are extremely sensitive to electrostatic discharge. This may lead to accidental ignitions during handling and transportation oper
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Yeh, Chun-Liang, and Kuan-Ting Chen. "Synthesis of FeSi-Al2O3 Composites by Autowave Combustion with Metallothermic Reduction." Metals 11, no. 2 (2021): 258. http://dx.doi.org/10.3390/met11020258.

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Fabrication of FeSi-Al2O3 composites with a molar ratio of FeSi/Al2O3 ranging from 1.2 to 4.5 was conducted by the self-propagating high-temperature synthesis (SHS) method. The synthesis reaction involved metallothermic reduction of Fe2O3 and SiO2 by Al and the chemical interaction of Fe and Si. Two combustion systems were examined: one contained thermite reagents of 0.6Fe2O3 + 0.6SiO2 + 2Al, and the other had Fe2O3 + 2Al to mix with different amounts of Fe and Si powders. A thermodynamic analysis indicated that metallothermic reduction of oxide precursors was sufficiently exothermic to sustai
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Hosseini, Seyed Ghorban, Ali Sheikhpour, Mohammad Hossein Keshavarz, and Saeed Tavangar. "The effect of metal oxide particle size on the thermal behavior and ignition kinetic of Mg–CuO thermite mixture." Thermochimica Acta 626 (February 2016): 1–8. http://dx.doi.org/10.1016/j.tca.2016.01.005.

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