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Journal articles on the topic 'Organometallic compounds – Synthesis'

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Author: Grafiati

Published: 4 June 2021

Last updated: 30 January 2023

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1

Asaad, Noora, Ahmed Z. M. AL-Bassam, and Sahar S. M. Alabdullah. "Uses of organometallic compounds in chemical processes." International Journal of Research in Engineering and Innovation 06, no. 02 (2022): 98–103. http://dx.doi.org/10.36037/ijrei.2022.6203.

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This review is proposed to address knowledge of organometallic compounds (OMC) in chemical applications and show these compounds' depth scope in different scientific studies. This review is based on outlining the gap between the traditional preparations and green chemistry synthesis of organometallic materials purposes in the experimental section of a researcher's papers. The most comparative research considers the drawbacks of organometallic compounds, including their applications in industrial, clinical, drug forms, and chemical reactions. However, many organometallic compounds are inherently poisonous. The most general challenge is producing alternative substances to creative green organometallic compounds, specifically in drug formulations systems. A wide range of chemical reactions have been investigated and formulated new organometallic properties this may be associated with an increased level of enhancement health systems. This study aims to determine the importance of organometallic compound in many path ways in various articles and confirmed how papers trying to characterize new organometallic substances in various chemical processes. Particular interest is given to knowledge synthesis OMC in medicine and industrially.

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2

TOKUDA, Masao. "Organometallic compounds in electroorganic synthesis." Journal of Synthetic Organic Chemistry, Japan 43, no. 6 (1985): 522–32. http://dx.doi.org/10.5059/yukigoseikyokaishi.43.522.

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3

Birch, Arthur J., Brian Chauncy, Lawrence F. Kelly, and David J. Thompson. "Organometallic compounds in organic synthesis." Journal of Organometallic Chemistry 286, no. 1 (April 1985): 37–46. http://dx.doi.org/10.1016/0022-328x(85)87233-8.

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4

Dong, Zhi-Bing, and Jin-Quan Chen. "Recent Progress in Utilization of Functionalized Organometallic Reagents in Cross Coupling Reactions and Nucleophilic Additions." Synthesis 52, no. 24 (November 4, 2020): 3714–34. http://dx.doi.org/10.1055/s-0040-1706550.

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AbstractOrganometallic compounds have become increasingly important in organic synthesis because of their high chemoselectivity and excellent reactivity. Recently, a variety of organometallic reagents were found to facilitate transition-metal-catalyzed cross-coupling reactions and nucleophilic addition reactions. Here, we have summarized the latest progress in cross-coupling reactions and in nucleophilic addition reactions with functionalized organometallic reagents present to illustrate their application value. Due to the tremendous contribution made by the Knochel group towards the development of novel organometallic reagents, this review draws extensively from their work in this area in recent years.Introduction1 Transition-Metal-Catalyzed Cross Couplings Involving Organozinc Reagents2 Transition-Metal-Catalyzed Cross Couplings Involving Organomagnesium Reagents3 Transition-Metal-Free Cross Couplings Involving Zn and Mg Organometallic Reagents4 Nucleophilic Additions Involving Zn and Mg Organometallic Reagents5 Cross-Coupling Reactions or Nucleophilic Additions Involving Mn, Al-, La-, Li-, Sm- and In-Organometallics6 Conclusion

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5

Storozhenko, P. A., A. A. Grachev, A. O. Klochkov, and V. I. Shiryaev. "Continuous organomagnesium synthesis of organometallic compounds." Russian Journal of Applied Chemistry 86, no. 3 (March 2013): 387–93. http://dx.doi.org/10.1134/s1070427213030166.

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6

Abbott, Julia K. C., Brenda A. Dougan, and Zi-Ling Xue. "ChemInform Abstract: Synthesis of Organometallic Compounds." ChemInform 42, no. 23 (May 12, 2011): no. http://dx.doi.org/10.1002/chin.201123214.

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7

Beletskaya, I. P. "Organometallic compounds in synthesis and catalysis." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 39, no. 10 (October 1990): 2013–28. http://dx.doi.org/10.1007/bf01557731.

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8

Ding, Aishun, Marta Meazza, Hao Guo, Jung Woon Yang, and Ramon Rios. "New development in the enantioselective synthesis of spiro compounds." Chemical Society Reviews 47, no. 15 (2018): 5946–96. http://dx.doi.org/10.1039/c6cs00825a.

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9

Arnold, Polly L. "Direct Synthesis of Coordination and Organometallic Compounds." Journal of Organometallic Chemistry 610, no. 1-2 (September 2000): 122. http://dx.doi.org/10.1016/s0022-328x(00)00426-5.

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10

ZANI, P. "ChemInform Abstract: Organometallic Compounds in Organic Synthesis." ChemInform 26, no. 19 (August 18, 2010): no. http://dx.doi.org/10.1002/chin.199519271.

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11

STAROWIEYSKI, K. B. "ChemInform Abstract: Organometallic Compounds: Synthesis and Properties." ChemInform 25, no. 48 (August 18, 2010): no. http://dx.doi.org/10.1002/chin.199448288.

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12

Carrillo-Hermosilla, Fernando, Rafael Fernández-Galán, Alberto Ramos, and David Elorriaga. "Guanidinates as Alternative Ligands for Organometallic Complexes." Molecules 27, no. 18 (September 13, 2022): 5962. http://dx.doi.org/10.3390/molecules27185962.

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For decades, ligands such as phosphanes or cyclopentadienyl ring derivatives have dominated Coordination and Organometallic Chemistry. At the same time, alternative compounds have emerged that could compete either for a more practical and accessible synthesis or for greater control of steric and electronic properties. Guanidines, nitrogen-rich compounds, appear as one such potential alternatives as ligands or proligands. In addition to occurring in a plethora of natural compounds, and thus in compounds of pharmacological use, guanidines allow a wide variety of coordination modes to different metal centers along the periodic table, with their monoanionic chelate derivatives being the most common. In this review, we focused on the organometallic chemistry of guanidinato compounds, discussing selected examples of coordination modes, reactivity and uses in catalysis or materials science. We believe that these amazing ligands offer a new promise in Organometallic Chemistry.

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13

Adams, Christopher J., Matteo Lusi, Emily M. Mutambi, and A. Guy Orpen. "Two-step solid-state synthesis of PEPPSI-type compounds." Chemical Communications 51, no. 47 (2015): 9632–35. http://dx.doi.org/10.1039/c5cc02924d.

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The two-step mechanochemical preparation of an important class of organometallic compounds is reported. The carbene–metal complexes are all rapidly formed in excellent yield. The solvent-free synthesis is proved to be a viable synthetic route to useful NHC-containing compounds amenable to scale-up and mechanization.

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14

Bunzen, Hana, Maciej Grzywa, Andreas Kalytta-Mewes, and Dirk Volkmer. "One-pot synthesis of ultrastable pentanuclear alkylzinc complexes." Dalton Transactions 46, no. 8 (2017): 2618–25. http://dx.doi.org/10.1039/c6dt04778e.

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15

Kabalka, George W., and Rajender S. Varma. "The synthesis of radiolabeled compounds via organometallic intermediates." Tetrahedron 45, no. 21 (January 1989): 6601–21. http://dx.doi.org/10.1016/s0040-4020(01)89131-6.

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16

Al-Wassil, A., R. Abu-Samn, and M. Mukhalalati. "Synthesis of new bismuth organometallic compounds. Part II." Inorganica Chimica Acta 127, no. 1 (February 1987): L5—L6. http://dx.doi.org/10.1016/s0020-1693(00)88349-8.

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17

Balavoine, Gilbert G. A., and Eric Manoury. "Organometallic compounds in asymmetric synthesis: Oxygen atom transfer." Applied Organometallic Chemistry 9, no. 3 (May 1995): 199–225. http://dx.doi.org/10.1002/aoc.590090305.

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18

Andullah, M. A., and D. I. Tofiq. "Synthesis and Characterization of Novel Biological Mixed Organometallic Chromium (III) Complex of Potential Allyl-Sulfur Compounds of Garlic, Allicin." Journal of Zankoy Sulaimani - Part A 5, no. 1 (May 17, 2001): 11–26. http://dx.doi.org/10.17656/jzs.10085.

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19

Castillo-Pazos, Durbis J., Juan D. Lasso, and Chao-Jun Li. "Modern methods for the synthesis of perfluoroalkylated aromatics." Organic & Biomolecular Chemistry 19, no. 33 (2021): 7116–28. http://dx.doi.org/10.1039/d1ob01122g.

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This review summarizes the most recent organometallic, photochemical and electrochemical methods for the synthesis of perfluoroalkylated aromatic scaffolds, a family of compounds that is omnipresent in modern commercial and research applications.

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20

Chan, T. H., C. J. Li, M. C. Lee, and Z. Y. Wei. "1993 R.U. Lemieux Award Lecture Organometallic-type reactions in aqueous media—a new challenge in organic synthesis." Canadian Journal of Chemistry 72, no. 5 (May 1, 1994): 1181–92. http://dx.doi.org/10.1139/v94-151.

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The development of organometallic-type reactions in aqueous media is reviewed. Coupling reactions of allyl halides with carbonyl compounds mediated by zinc, or tin, or indium in aqueous media to give homoallylic alcohols are discussed. The stereochemical outcome is compared with similar reactions in organic solvents. A concise synthesis of (+)-muscarine is used to illustrate the usefulness of aqueous organometallic-type reactions in organic synthesis. The procedure to protect–deprotect hydroxy functional groups may not be necessary in these reactions. An application in the carbohydrate area is demonstrated with the synthesis of (+)-3-deoxy-D-glycero-D-galacto-nonulosonic acid (KDN). The mechanistic possibilities of organometallic-type reactions in aqueous media are outlined.

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21

Gielen, M., and J. Topart. "Organometallic Compounds. 34. A Convenient Method Of Synthesis For Haloalkyltin Compounds." Bulletin des Sociétés Chimiques Belges 80, no. 5-6 (September 2, 2010): 655–58. http://dx.doi.org/10.1002/bscb.19710800535.

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22

Wu, Zhe, Rafael Ortiz, Alain Fort, Marguerite Barzoukas, and Seth R. Marder. "Synthesis and optical properties of a new class of organometallic compounds: Organometallic merocyanines." Journal of Organometallic Chemistry 528, no. 1-2 (February 1997): 217–19. http://dx.doi.org/10.1016/s0022-328x(96)06575-8.

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23

Vizer, S. A., and K. B. Yerzhanov. "Heterocycles Synthesis at Carbonylation of Acetylenic Compounds." Eurasian Chemico-Technological Journal 5, no. 2 (April 5, 2016): 145. http://dx.doi.org/10.18321/ectj294.

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The carbonylation of unsaturated hydrocarbons, alcohols, organic halides and other substrates catalyzed by transition metals, salts of transition metals and organometallic complexes is a wide used synthesis method of new carbonyl, carboxyl and alkoxy carbonyl containing compounds including creation or modificationt of heterocycles. The data about synthesis of heterocycles at carbonylation of acetylenic compounds have been appeared at last 20 years and are demonstrated in our review. Introduction of carbon monoxide in the catalytic reactions of acetylenic compounds permits to obtain in oneput process the diverse heterocycles, having carbonyl, carboxyl or alkoxycarbonyl substitutes or containing these fragments inside of heterocycles.

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24

Wei, Baosheng, Wen-Xiong Zhang, and Zhenfeng Xi. "Well-defined styryl and biphenyl calcium complexes from dilithio compounds and calcium iodide: synthesis, structure and reactivity toward nitrous oxide." Dalton Transactions 47, no. 36 (2018): 12540–45. http://dx.doi.org/10.1039/c8dt01046c.

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25

Sohail, Muhammad, Muhammad Zeshan Ashraf, Raziya Nadeem, Shamsa Bibi, Rabia Rehman, and Muhammad Adnan Iqbal. "Techniques in the synthesis of organometallic compounds of tungsten." Reviews in Inorganic Chemistry 40, no. 1 (March 26, 2020): 1–45. http://dx.doi.org/10.1515/revic-2019-0013.

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AbstractTungsten is an elegant substance, and its compounds have great significance because of their extensive range of applications in diverse fields such as in gas sensors, photocatalysis, lithium ion batteries, H2 production, electrochromic devices, dyed sensitized solar cells, microchip technology, and liquid crystal displays. Tungsten compounds exhibit a more efficient catalytic behavior, and tungsten-dependent enzymes generally catalyze the transfer of an oxygen atom to or from a physiological donor/acceptor with the metal center. Furthermore, tungsten has an n-type semiconductor band gap. Tungsten forms complexes by reacting with several elements such as H, C, N, O, and P as well as other numerous inorganic elements. Interestingly, all tungsten reactions occur at ambient temperature, usually with tetrahydrofuran and dichloromethane under vacuum. Tungsten has extraordinarily high-temperature properties, making it very useful for X-ray production and heating elements in furnaces. Tungsten coordinates with diverse nonmetallic elements and ligands and produces interesting compounds. This article describes an overview of the synthesis of various organometallic compounds of tungsten.

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26

Ahmed, Gamal A., Nabila A. Ismail, and Fathy A. Yassin. "SYNTHESIS AND REACTIONS OF SOME NEW ORGANOMETALLIC COMPOUNDS: SYNTHESIS OF TRIPHENYLSILYLSULFINYLAMINE." Phosphorus, Sulfur, and Silicon and the Related Elements 69, no. 3-4 (July 1992): 253–55. http://dx.doi.org/10.1080/10426509208040643.

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27

Pignon, Antoine, Erwan Le Gall, and Thierry Martens. "A new manganese-mediated, cobalt-catalyzed three-component synthesis of (diarylmethyl)sulfonamides." Beilstein Journal of Organic Chemistry 10 (February 17, 2014): 425–31. http://dx.doi.org/10.3762/bjoc.10.39.

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The synthesis of (diarylmethyl)sulfonamides and related compounds by a new manganese-mediated, cobalt-catalyzed three-component reaction between sulfonamides, carbonyl compounds and organic bromides is described. This organometallic Mannich-like process allows the formation of the coupling products within minutes at room temperature. A possible mechanism, emphasizing the crucial role of manganese is proposed.

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28

Kadomtsevа, A. V., I. V. Zhdanovich, M. S. Piskunovа, A. N. Lineva, A. N. Novikova, and P. A. Loginov. "ASSESSMENT OF TOXICITY OF GERMANIUM COORDINATION COMPOUNDS." Toxicological Review, no. 2 (April 28, 2019): 16–21. http://dx.doi.org/10.36946/0869-7922-2019-2-16-21.

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The synthesis of biologically active coordination compounds and the design on their basis of effective pharmacological preparations is currently the promising area. This paper presents the results of the toxicological studies on digermanium and its complex derivatives. It should be noted that the positive medical properties of organometallic compounds of germanium are confirmed by numerous studies, therefore, the development of the methods of synthesis, as well as investigations of physicochemical and pharmacological properties of these compounds are at the center of attention.

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29

Farooq M, Gulam, and Manohar V Lokhande. "Synthesis of Ferrocene Based Organometallic Compounds & Antimicrobial Activity." IOSR Journal of Applied Chemistry 7, no. 2 (2014): 27–32. http://dx.doi.org/10.9790/5736-07212732.

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30

Shul'pin, Georgiy B., Luísa M. Martins, and Richard D. Adams. "Special issue on Synthesis and Applications of Organometallic Compounds." Journal of Organometallic Chemistry 891 (August 2019): 85. http://dx.doi.org/10.1016/j.jorganchem.2019.04.013.

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31

Jousseaume, Bernard. "Organometallic synthesis and chemistry of tin and lead compounds." Mikrochimica Acta 109, no. 1-4 (January 1992): 5–12. http://dx.doi.org/10.1007/bf01243203.

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32

Boudier, Andreas, Lars O. Bromm, Matthias Lotz, and Paul Knochel. "New Applications of Polyfunctional Organometallic Compounds in Organic Synthesis." Angewandte Chemie International Edition 39, no. 24 (December 15, 2000): 4414–35. http://dx.doi.org/10.1002/1521-3773(20001215)39:24<4414::aid-anie4414>3.0.co;2-c.

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33

Gielen, M., J. Nasielski, and J. Topart. "Organometallic compounds. Part IX: Synthesis of a series of racemic tetraorganotin compounds." Recueil des Travaux Chimiques des Pays-Bas 87, no. 9 (September 2, 2010): 1051–52. http://dx.doi.org/10.1002/recl.19680870912.

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34

Schottenberger, Herwig, Klaus Wurst, Ulrike E. I. Horvath, Stephanie Cronje, Josef Lukasser, Johann Polin, Jean M. McKenzie, and Helgard G. Raubenheimer. "Synthesis and characterisation of organometallic imidazolium compounds that include a new organometallic ionic liquid." Dalton Trans., no. 22 (2003): 4275–81. http://dx.doi.org/10.1039/b308252k.

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35

da Silva, Artur V., Simoni M. P. Meneghetti, and Mario R. Meneghetti. "Benzodiazepines: Drugs with Chemical Skeletons Suitable for the Preparation of Metallacycles with Potential Pharmacological Activity." Molecules 26, no. 9 (May 10, 2021): 2796. http://dx.doi.org/10.3390/molecules26092796.

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The synthesis of organometallic compounds with potential pharmacological activity has attracted the attention of many research groups, aiming to take advantage of aspects that the presence of the metal-carbon bond can bring to the design of new pharmaceutical drugs. In this context, we have gathered studies reported in the literature in which psychoactive benzodiazepine drugs were used as ligands in the preparation of organometallic and metal complexes and provide details on some of their biological effects. We also highlight that most commonly known benzodiazepine-based drugs display molecular features that allow the preparation of metallacycles via C-H activation. These organometallic compounds merit further attention regarding their potential biological effects, not only in terms of psychoactive drugs but also in the search for drug replacements, for example, for cancer treatments.

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36

Farinola, Gianluca M., Francesco Babudri, Antonio Cardone, Omar Hassan Omar, Carmela Martinelli, Francesco Naso, Vita Pinto, and Roberta Ragni. "Synthesis of Fluorinated Organic and Organometallic Electroluminescent Materials: Tuning Emission in the Blue." Advances in Science and Technology 75 (October 2010): 108–17. http://dx.doi.org/10.4028/www.scientific.net/ast.75.108.

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Functionalization with fluorine atoms represents a versatile structural modification to finely tune both the emission colour and the electronic properties of organic and organometallic electroluminescent compounds. This paper reports an overview of our systematic investigation on the design and synthesis of the fluorinated version of two important classes of materials for organic light emitting diodes (OLEDs), namely poly(arylenevinylene)s and phosphorescent phenylpyridine Iridium complexes. Synthetic pathways based on organometallic methodologies affording selectively fluorinated molecular structures will be discussed together with a summary of the effect of fluorination on the optical properties of the resulting materials. In particular we will highlight the possibilities offered by the organometallic methodologies as straightforward and resourceful tools to provide a wide series of fluorinated molecular architectures with high regio- and stereoselectivity, mild experimental conditions and good yields.

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37

Helgadottir, I., G. Freychet, P. Arquillière, M. Maret, P. Gergaud, P. H. Haumesser, and C. C. Santini. "Ru-core/Cu-shell bimetallic nanoparticles with controlled size formed in one-pot synthesis." Nanoscale 6, no. 24 (2014): 14856–62. http://dx.doi.org/10.1039/c4nr03666b.

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Anomalous Small-Angle X-ray Scattering (ASAXS) experiments attest the core-shell structure of bimetallic nanoparticles Ru and Cu, synthesized by simultaneous decomposition of two organometallic compounds in an ionic liquid.

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38

Kadomtseva, A. V., P. A. Zarubenko, and L. B. Loginova. "THE ROLE OF IMMOBILIZED METAL-ORGANIC COMPOUNDS IN THE COMPLEX TREATMENT OF PURULENT-INFLAMMATORY DISEASE OF SKIN AND SOFT TISSUES." Novosti Khirurgii 29, no. 3 (July 25, 2021): 334–46. http://dx.doi.org/10.18484/2305-0047.2021.3.334.

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Objective. To study the current Russian and foreign literature dedicated to the problem of application of organometallic compounds immobilized on drugdelivery in the treatment of purulent-inflammatory disease of the skin and soft tissues. Methods. The modern Russian and foreign literature, available in the Pubmed, Medline, Springer, Scopus, e-LIBRARY databases were reviewed according to the problems of purulent-inflammatory diseases, skin and soft tissue infections, the integrated approach to the treatment of purulent-inflammatory diseases, synthesis, immobilized organometallic compounds. Results. The observational study of the specificrecent achievements in the modification of antimicrobial biomaterials is presented. Metal ions havea broad range of antimicrobial activity (especially on proliferation and remodeling), possess by bacteriostatic and bactericidal effect, demonstrate multiple inhibitory effects against bacterial strains and havebeen proveneffectivein improvingwoundhealing in all its phases. Natural products and especially biologically active metals such as silver, copper, zinc and germanium, are believed to be an alternative for the development of perspective biomaterials with antimicrobial properties. In recent years, new approach for the production and application of therapeutic and diagnostic drugs based on the immobilization or grafting of drugsubstances on polymer carriers has been developed. At present, namely the immobilized compounds that have opened the way to the creation of prolonged-action drugs with low toxicity and allergenicity. Conclusion. Template synthesis of new organometallic drug compounds is considered to be a promising direction in the wound infection treatment, which requires further experimental and clinical study.

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39

Arisawa, Mieko, and Masahiko Yamaguchi. "Rhodium-Catalyzed Synthesis of Organosulfur Compounds Involving S-S Bond Cleavage of Disulfides and Sulfur." Molecules 25, no. 16 (August 7, 2020): 3595. http://dx.doi.org/10.3390/molecules25163595.

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Organosulfur compounds are widely used for the manufacture of drugs and materials, and their synthesis in general conventionally employs nucleophilic substitution reactions of thiolate anions formed from thiols and bases. To synthesize advanced functional organosulfur compounds, development of novel synthetic methods is an important task. We have been studying the synthesis of organosulfur compounds by transition-metal catalysis using disulfides and sulfur, which are easier to handle and less odiferous than thiols. In this article, we describe our development that rhodium complexes efficiently catalyze the cleavage of S-S bonds and transfer organothio groups to organic compounds, which provide diverse organosulfur compounds. The synthesis does not require use of bases or organometallic reagents; furthermore, it is reversible, involving chemical equilibria and interconversion reactions.

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40

Pan, Ming, Tore Benneche, Petros Mamos, Nikolaos Karamanos, Dionissios Papaioannou, George W. Francis, and Teófilo Rojo. "Synthesis of Bis(trimethylsilyl) Ketone and Reactions with Organometallic Compounds." Acta Chemica Scandinavica 52 (1998): 1141–43. http://dx.doi.org/10.3891/acta.chem.scand.52-1141.

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41

Kiefer, Adam M., John A. Giles, and Patricia A. Shapley. "Synthesis, Structure, and Reactivity of Organometallic Osmium(VI) Hydroxo Compounds." Organometallics 26, no. 8 (April 2007): 1881–87. http://dx.doi.org/10.1021/om060918k.

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42

Domrachev, Georgy A., Lev N. Zakharov, and Yu A. Shevelev. "The Stability of Organometallic Compounds During Their Synthesis and Decomposition." Russian Chemical Reviews 54, no. 8 (August 31, 1985): 739–54. http://dx.doi.org/10.1070/rc1985v054n08abeh003108.

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43

Vertoprakhov, Vladimir N., Lyubov' D. Nikulina, and Igor K. Igumenov. "Oxide ferroelectric thin films: synthesis from organometallic compounds and properties." Russian Chemical Reviews 74, no. 8 (August 31, 2005): 725–46. http://dx.doi.org/10.1070/rc2005v074n08abeh000924.

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44

Ichinose, Hiromichi, Yoshinori Nibu, Hiroaki Katsuki, and Masamitsu Nagano. "Effects of Organometallic Compounds Introduced to Plasma on Diamond Synthesis." Japanese Journal of Applied Physics 32, Part 1, No. 1A (January 15, 1993): 144–49. http://dx.doi.org/10.1143/jjap.32.144.

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45

YAMAMOTO, Yoshinori, and Jun-ichi YAMADA. "Asymmetric synthesis of organometallic compounds. Application to steroid side chain." Kagaku To Seibutsu 24, no. 8 (1986): 515–22. http://dx.doi.org/10.1271/kagakutoseibutsu1962.24.515.

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46

Hirano, Shin-ichi, and Toshinobu Yogo. "Synthesis of Functional Carbons by Pressure Pyrolysis of Organometallic Compounds." REVIEW OF HIGH PRESSURE SCIENCE AND TECHNOLOGY 1, no. 2 (1992): 99–105. http://dx.doi.org/10.4131/jshpreview.1.99.

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47

BALAVOINE, G. G. A., and E. MANOURY. "ChemInform Abstract: Organometallic Compounds in Asymmetric Synthesis: Oxygen Atom Transfer." ChemInform 26, no. 42 (August 17, 2010): no. http://dx.doi.org/10.1002/chin.199542300.

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48

Kharissova, Oxana V., Boris I. Kharisov, and Ubaldo Ortiz Mendez. "ChemInform Abstract: Microwave-Assisted Synthesis of Coordination and Organometallic Compounds." ChemInform 43, no. 8 (January 27, 2012): no. http://dx.doi.org/10.1002/chin.201208230.

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49

Lozano-Cruz, Tania, Paula Ortega, Belen Batanero, Jose Luis Copa-Patiño, Juan Soliveri, Fco Javier de la Mata, and Rafael Gómez. "Synthesis, characterization and antibacterial behavior of water-soluble carbosilane dendrons containing ferrocene at the focal point." Dalton Transactions 44, no. 44 (2015): 19294–304. http://dx.doi.org/10.1039/c5dt02230d.

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Novel water-soluble ammonium-terminated carbosilane dendrons containing a ferrocene unit at the focal point were synthesized and evaluate them as a new class of potential organometallic-based antibacterial compounds.

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50

Jurgens, Sophie, Fritz E. Kuhn, and Angela Casini. "Cyclometalated Complexes of Platinum and Gold with Biological Properties: State-of-the-Art and Future Perspectives." Current Medicinal Chemistry 25, no. 4 (February 12, 2018): 437–61. http://dx.doi.org/10.2174/0929867324666170529125229.

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Background: The inherent problems accompanying chemotherapy necessitate the development of new anticancer approaches. The development of compounds that can disrupt cancerous cellular machinery by novel mechanisms, via interactions with proteins and non-canonical DNA structures (e.g. G-quadruplexes), as well as by alteration of the intracellular redox balance, is nowadays focus of intense research. In this context, organometallic compounds of the noble metals Pt and Au have become prominent experimental therapeutic agents. This review provides an overview of the Pt(II) and Au(III) cyclometalated compounds with a chelating ring containing a strong C-M σ -bond to improve the stability of the compounds with respect to ligand exchange reactions and biological reduction. Furthermore, these properties can be easily tuned by modification of either the anionic cyclometalated or the ancillary ligands. Special focus has been set to C^N, C^N^C, C^N^N and C^N^S platinum(II) and gold(III) pincer complexes regarding their synthesis and biological mechanisms of action as anticancer agents. Methods: A structured search of both chemical and medicinal databases for peerreviewed research literature has been conducted. The quality of retrieved papers was appraised using standard tools. The synthesis as well as the chemical and biological properties of the described compounds were carefully reviewed and described. The findings were outlined using a conceptual framework. Results: In this review we included 155 papers, the majority originating from high-impact papers on the synthesis and biological modes of platinum(II) and gold(III) compounds. Among them, 17 papers were highlighted to give an introduction to the use of Pt and Au compounds with medicinal properties, mainly focussing on coordination compounds. The synthesis and medicinal properties of organometallic compounds of various metals (such as Fe, Ru, Ti) were outlined in 51 papers. These compounds included metallocenes, metallo- arenes, metallo-carbonyls, metallo-carbenes (e.g. N-heterocyclic carbenes), and alkynyl complexes. The C^N, C^N^C, C^N^N and C^N^S pincer complexes of platinum( II) (46 papers) and gold(III) (44 papers) were discussed concerning their synthesis, stability and advantages to develop therapeutic compounds. We strove to show the consistent development of C^N, C^N^C, C^N^N and C^N^S platinum(II) and gold(III) pincer complexes regarding their synthesis and biological modes from the early beginnings to the most recent findings. Conclusion: This review supplies a profound overview of the development of organometallic compounds for medicinal purposes, setting special focus to the synthesis and stability of C^N, C^N^C, C^N^N and C^N^S pincer complexes of platinum(II) and gold(III) and their use as anticancer agents.

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