Academic literature on the topic 'Organometallic Chemistry'

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Journal articles on the topic "Organometallic Chemistry"

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Ezquerro, C., A. E. Sepúlveda, A. Grau-Atienza, E. Serrano, E. Lalinde, J. R. Berenguer, and J. García-Martínez. "Organometallic phosphors as building blocks in sol–gel chemistry: luminescent organometallo-silica materials." Journal of Materials Chemistry C 5, no. 37 (2017): 9721–32. http://dx.doi.org/10.1039/c7tc02188g.

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When organometallics meet silica, the solid state mimics solution! Condensation of organometallic Ir(iii) and Pt(ii) phosphors with TEOS yields highly stable luminescent hybrid organometallo-silica materials with excellent optical and textural properties.
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Eisenstein, Odile. "Concluding remarks for “Mechanistic Processes in Organometallic Chemistry”: the importance of a multidisciplinary approach." Faraday Discussions 220 (2019): 489–95. http://dx.doi.org/10.1039/c9fd00101h.

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The Faraday Discussions meeting on Mechanistic Processes in Organometallic Chemistry was a brilliant occasion to assemble chemists from diverse sub-disciplines to discuss the progress and limitations of the study of reaction mechanisms using organometallic systems for stoichiometric or catalytic reactions.
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Straub, Bernd F., Rolf Gleiter, Claudia Meier, and Lutz H. Gade. "Organometallic chemistry." Beilstein Journal of Organic Chemistry 12 (October 19, 2016): 2216–21. http://dx.doi.org/10.3762/bjoc.12.213.

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Baranoff, Etienne, and John S. Fossey. "Organometallic chemistry." Annual Reports Section "B" (Organic Chemistry) 108 (2012): 71. http://dx.doi.org/10.1039/c2oc90022j.

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Fossey, John S., and Etienne Baranoff. "Organometallic chemistry." Annual Reports Section "B" (Organic Chemistry) 109 (2013): 207. http://dx.doi.org/10.1039/c3oc90017g.

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Fossey, John S. "Organometallic chemistry." Annual Reports Section "B" (Organic Chemistry) 107 (2011): 91. http://dx.doi.org/10.1039/c1oc90021h.

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Poli, Rinaldo, and Philippe Kalck. "Organometallic Chemistry." European Journal of Inorganic Chemistry 2012, no. 9 (March 2012): 1292–93. http://dx.doi.org/10.1002/ejic.201290022.

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Green, M. L. H., and W. P. Griffith. "Sir Geoffrey Wilkinson. 14 July 1921 — 26 September 1996." Biographical Memoirs of Fellows of the Royal Society 46 (January 2000): 593–606. http://dx.doi.org/10.1098/rsbm.1999.0103.

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Geoffrey Wilkinson was one of the most influential chemists of the postwar era, a major contributor to the renaissance of inorganic chemistry and probably the most influential founder of modern organometallic chemistry. His scientific career spanned more than fifty years and he worked throughout that entire period with undiminished enthusiasm and intellectual vigour. His work covered most of the elements in the Periodic Table, and he made remarkable and highly individual contributions to radiochemistry, organometallic chemistry, coordination chemistry and homogeneous catalysis.
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Errington, R. J. "Journal of Organometallic Chemistry Library 20: Organometallic Chemistry Reviews." Polyhedron 8, no. 22 (January 1989): 2735. http://dx.doi.org/10.1016/s0277-5387(00)80449-0.

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Brisdon, B. J. "Organometallic chemistry reviews. Journal of organometallic chemistry library, 20." Endeavour 13, no. 3 (January 1989): 143. http://dx.doi.org/10.1016/0160-9327(89)90102-6.

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Dissertations / Theses on the topic "Organometallic Chemistry"

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Chatakondu, Kalyan. "Organometallic intercalation chemistry." Thesis, University of Oxford, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.258017.

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Polywka, M. E. C. "Mechanistic organometallic chemistry." Thesis, University of Oxford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.253399.

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Brown, Stephen L. "Mechanistic organometallic chemistry." Thesis, University of Oxford, 1986. http://ora.ox.ac.uk/objects/uuid:96218480-9b1d-4d53-9d1d-033e2b451818.

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A number of organometallic transformations related to proposed elementary steps in the reductive polymerization of carbon monoxide are discussed. The use of isonitrile as model ligands for carbon monoxide, with which they are isoelectronic, is proposed. Investigations show that alkyl migration to isonitrile is preferred over migration to carbon monoxide. Iminoformyl products due to hydride migration to isonitrile are not, however, observed. Syntheses of a range of cationic complexes of the type [ (η5-C5H5)M(L)2(CNR)]+, [(η5-C9H7)Ru(L)2(CNR)]+ and [(η5-C9H7)M(L)2(CO)]+ (M = Fe, Ru; L = CO, phosphine) are described. In two cases, addition of hydride to the isonitrile cations is followed by protonation on work-up to give aminocarbene complexes. These are inert to further reduction under the conditions employed. The majority of isonitrile cations lose the isonitrile ligand to give good yields of metal hydride complexes. A mechanism involving ring-slippage of the hydrocarbon ligand is implicated. Hydride addition to η5-C9H7 complexes results, in the majority of cases, in loss of the hydrocarbon ligand from the complex and recovery of indane. Evidence for the intermediacy of metal formyl complexes in a number of hydride donation reactions is presented. These formyl complexes are formed from carbonyl hydride complexes either under moderate CO pressure or in THF solution. Hydride complexes lacking a carbonyl ligand are found to be inert. Finally, two reactions, one involving an alkyl migration reaction catalyzed by silver(I) salts, and the other involving the reduction of a metal acyl ligand to metal alkyl, are combined to demonstrate a model for carbon chain growth at a metal centre. The synthesis of an iron pentanoyl complex, followed by a decomplexation reaction, gives pentanoic acid in which all the catbon atoms are potentially directly derived from carbon monoxide. This is the first synthesis of a single homologous acid from carbon monoxide.
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Ortuño, Maqueda Manuel Ángel. "Scope of computational organometallic chemistry. Structure, reactivity and properties." Doctoral thesis, Universitat Autònoma de Barcelona, 2014. http://hdl.handle.net/10803/285645.

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La química organometálica se define como el área de conocimiento que une el mundo orgánico (ligando) con el inorgánico (metal), aprovechando lo mejor de ambos. Un aspecto interesante de los compuestos con metales de transición es la capacidad de realizar transformaciones químicas que no se pueden llevar a cabo fácilmente usado química convencional. Entre los retos que la química organometálica puede abordar se incluyen energías renovables, nuevos materiales y síntesis de compuestos de alto valor añadido. En este contexto, la química computacional juega un papel muy importante a la hora de entender los fenómenos químicos. La inmensa cantidad de técnicas disponibles permite analizar distintos tipos de enlace, proponer mecanismos de reacción, mejorar procesos catalíticos e incluso estimar propiedades espectroscópicas. En resumen, esta tesis cubre diferentes aspectos de la química organometálica desde un punto de vista computacional. El grueso de resultados se divide en tres capítulos: Estructura, Reactividad y Propiedades. En Estructura (i) se analiza la geometría de compuestos paramagnéticos de Pt(III) con el objetivo de distinguir entre estructuras plano-cuadradas y de tipo balancín, y (ii) se estudia la presencia de interacciones agósticas en especies insaturadas de Pt(II). En Reactividad (i) se evalúan los efectos estéricos y electrónicos de carbenos N-heterocíclicos en reacciones de activación C–H mediadas por platino, (ii) se explica el rol de la base en la etapa de transmetalación de reacciones de acoplamiento cruzado tipo Suzuki–Miyaura, y (iii) se proponen posibles mecanismos para justificar los productos observados en reacciones de vinilación con silanos catalizadas por paladio. En Propiedades (i) se predicen las constantes de acidez de varios complejos de dihidrógeno (Fe, Ru y Os) en agua, y (ii) se estiman los desplazamientos químicos de resonancia magnética nuclear de 103Rh en complejos de Rh(bisfosfina), correlacionándolos con distancias de enlace Rh–P. Como conclusión general, esta tesis demuestra como la química computacional se puede aplicar adecuadamente para explicar diversos tipos de problemas en química organometálica.
Organometallic chemistry stands for the area of expertise which manages to join organic (ligand) and inorganic (metal) worlds, taking advantage from both of them. One interesting feature of transition metal species is the possibility of promoting chemical transformations that cannot simply be performed using straightforward chemistry. The challenges that organometallic chemistry can address concern renewable energies, new materials, and fine chemical synthesis, among others. Under this scene, computational chemistry can play a major role in understanding chemical phenomena. The extensive toolbox of available techniques allows to analyse bonding situations, propose reaction mechanisms, improve catalytic processes, or estimate spectroscopic properties. In a nutshell, the current dissertation covers different aspects of organometallic chemistry from a computational point of view. The body of results is divided into three main chapters: Structure, Reactivity and Properties. Structure (i) analyses the geometry of paramagnetic Pt(III) compounds in order to discern between square-planar and see-saw dispositions and (ii) evaluates the presence of agostic interactions in low-coordinate Pt(II) species. Reactivity (i) studies the steric and electronic properties of N-heterocyclic carbenes in Pt-mediated C–H bond activations, (ii) unravels the role of the base in Suzuki–Miyaura cross-coupling transmetalation processes, and (iii) proposes feasible mechanisms of Pd-catalysed Si-based vinylation reactions to account for the different products experimentally observed. Properties (i) predicts the acid constants of several transition metal (Fe, Ru, Os) dihydrogen complexes in water and (ii) estimates the 103Rh NMR chemical shifts of Rh(bisphosphine) species, building correlations with Rh–P bond distances. As general conclusion, this thesis illustrates how computational chemistry can successfully be applied to explain a wide number of different chemical problems in the organometallic field.
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Leckey, N. T. "Studies in organometallic chemistry." Thesis, University of Ulster, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.378730.

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Wierzchleyski, Adam Tomasz. "Diastereoisomeric control in organometallic chemistry." Thesis, Imperial College London, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.261719.

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Michaelidou, Despo M. "Synthetic studies in organometallic chemistry." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.358726.

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Corradi, Marco Michael. "Aspects of d'o organometallic chemistry." Thesis, University of Sussex, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241717.

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Nairn, Jacqueline G. M. "Organometallic chemistry of triosmium clusters." Thesis, University of Edinburgh, 1995. http://hdl.handle.net/1842/15481.

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The interaction of transition metal carbonyl clusters with unsaturated cyclic and polycyclic ligand systems continues to stimulate ongoing research and this thesis is concerned mainly with the reactions of triosmium carbonyl clusters with such compounds. Chapter one contains a brief summary of triosmium dodecacarbonyl chemistry, incorporating both synthesis and reactivity. The arene chemistry of mononuclear complexes and cluster compounds is also discussed. Over the last decade there has been serious debate on the validity of the cluster-surface analogy; the boundary conditions are addressed herein. Chapter two details alternative synthetic routes to the compound M3(CO)9(μ-η2.2..2-C6H6) [M = Ru, Os]. A series of substituted 1,3-cyclohexadiene ligands have also been prepared and reacted with the cluster Os3(CO)10(MeCN)2. The successful synthesis of the bis-benzene cluster Os3(CO)63-η2.2.2.-C6H6)(η6-C6H6) is reported in chapter three. The systematic stepwise reaction of Os3(CO)932.2.2-C6H6) with trimethylamine-N-oxide and 1,3-cyclohexadiene leads to the formation of a range of benzene-diene clusters, all of which have been fully characterised. Their isomeric and fluxional behaviour has also been studied. The reactions of acenaphthylene, C12H8, a stable tricyclic system with 12 π-electrons available for bonding, are reported for Ru3(CO)12 and Os3(CO)12 in chapter four. The resulting compounds demonstrate the range of bonding modes adopted by this flexible ligand.
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Williams, Michael Lloyd. "New aspects of organometallic chemistry /." Title page, contents and abstract only, 1985. http://web4.library.adelaide.edu.au/theses/09PH/09phw725.pdf.

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Books on the topic "Organometallic Chemistry"

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Fairlamb, I., and Jason M. Lynam, eds. Organometallic Chemistry. Cambridge: Royal Society of Chemistry, 2008. http://dx.doi.org/10.1039/9781847558466.

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Green, M., ed. Organometallic Chemistry. Cambridge: Royal Society of Chemistry, 2005. http://dx.doi.org/10.1039/9781847558497.

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Green, M., ed. Organometallic Chemistry. Cambridge: Royal Society of Chemistry, 2007. http://dx.doi.org/10.1039/9781847558503.

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Fairlamb, I. J. S., and J. M. Lynam, eds. Organometallic Chemistry. Cambridge: Royal Society of Chemistry, 2009. http://dx.doi.org/10.1039/9781847551030.

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Fairlamb, Ian J. S., and Jason M. Lynam, eds. Organometallic Chemistry. Cambridge: Royal Society of Chemistry, 2014. http://dx.doi.org/10.1039/9781849737692.

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Patmore, Nathan J., and Paul I. P. Elliott, eds. Organometallic Chemistry. Cambridge: Royal Society of Chemistry, 2020. http://dx.doi.org/10.1039/9781788017077.

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Nakazawa, Hiroshi, and Julian Koe, eds. Organometallic Chemistry. Cambridge: Royal Society of Chemistry, 2021. http://dx.doi.org/10.1039/9781839164200.

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Patmore, Nathan J., and Paul I. P. Elliott, eds. Organometallic Chemistry. Cambridge: Royal Society of Chemistry, 2018. http://dx.doi.org/10.1039/9781788010672.

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Fairlamb, Ian J. S., and J. M. Lynam, eds. Organometallic Chemistry. Cambridge: Royal Society of Chemistry, 2011. http://dx.doi.org/10.1039/9781849732802.

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Fairlamb, Ian J. S., and Jason M. Lynam, eds. Organometallic Chemistry. Cambridge: Royal Society of Chemistry, 2012. http://dx.doi.org/10.1039/9781849734868.

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Book chapters on the topic "Organometallic Chemistry"

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Tucker, William B. "Organometallic Chemistry." In Organic Chemistry, 190–99. Boca Raton: CRC Press, 2024. http://dx.doi.org/10.1201/9781003479352-17.

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Tucker, William B. "Organometallic Chemistry." In Organic Chemistry, 200–206. Boca Raton: CRC Press, 2024. http://dx.doi.org/10.1201/9781003479352-18.

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Lavastre, O., N. Pinault, and Z. Mincheva. "Organometallic Combinatorial Chemistry." In Principles and Methods for Accelerated Catalyst Design and Testing, 135–51. Dordrecht: Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0554-8_7.

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Hope, Eric G., Rena Simayi, and Alison M. Stuart. "Fluorous Organometallic Chemistry." In Topics in Organometallic Chemistry, 217–40. Cham: Springer International Publishing, 2015. http://dx.doi.org/10.1007/3418_2015_91.

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Burton, Donald J., and Long Lu. "Fluorinated Organometallic Compounds." In Organofluorine Chemistry, 45–89. Berlin, Heidelberg: Springer Berlin Heidelberg, 1997. http://dx.doi.org/10.1007/3-540-69197-9_2.

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Alberto, Roger. "Organometallic Radiopharmaceuticals." In Topics in Organometallic Chemistry, 219–46. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-13185-1_9.

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Maity, Ramananda, and Biprajit Sarkar. "Redox and photochemical/photophysical properties of compounds containing mesoionic carbene ligands." In Organometallic Chemistry, 1–22. Cambridge: Royal Society of Chemistry, 2022. http://dx.doi.org/10.1039/9781839167713-00001.

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Ayyappan, Ramaraj, Rosenildo C. Da Costa, and Gareth R. Owen. "Recent developments in homogeneous catalysis for the functionalisation of CO2." In Organometallic Chemistry, 23–67. Cambridge: Royal Society of Chemistry, 2022. http://dx.doi.org/10.1039/9781839167713-00023.

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Panda, Biswajit, and Gianluigi Albano. "Homogeneous gold catalysis under microwave irradiation: a greener approach." In Organometallic Chemistry, 68–91. Cambridge: Royal Society of Chemistry, 2022. http://dx.doi.org/10.1039/9781839167713-00068.

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Stringer, Tameryn, and Rianne M. Lord. "Medicinal applications of early transition metal β-diketonato complexes." In Organometallic Chemistry, 92–109. Cambridge: Royal Society of Chemistry, 2022. http://dx.doi.org/10.1039/9781839167713-00092.

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Conference papers on the topic "Organometallic Chemistry"

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GRUBBS, ROBERT H. "HOMOGENEOUS CATALYSIS: ORGANOMETALLIC CATALYSIS AND ORGANOCATALYSIS." In 24th International Solvay Conference on Chemistry. WORLD SCIENTIFIC, 2018. http://dx.doi.org/10.1142/9789813237179_0001.

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Fernández-Figueiras, Adolfo, Fátima Lucio, Paula Munín, Francisco Reigosa, Jose Vila, Maria Pereira, and Paula Polo. "SYNTHESIS OF IMINOPHOSPHORANES AS LIGANDS FOR ORGANOMETALLIC COMPOUNDS." In The 20th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2016. http://dx.doi.org/10.3390/ecsoc-20-a016.

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Huse, Nils, Hana Cho, Matthew L. Strader, Tae Kyu Kim, and Robert W. Schoenlein. "Organometallic Chemistry in Solutions Investigated with Time-resolved X-ray Spectroscopy." In International Conference on Ultrafast Structural Dynamics. Washington, D.C.: OSA, 2012. http://dx.doi.org/10.1364/icusd.2012.iw2d.2.

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G. Teixeira, Ricardo, Dimas C. Belisario, Ana Isabel Tomaz, Maria Helena Garcia, Chiara Riganti, and Andreia Valente. "Ruthenium organometallic compounds as ABC drug efflux-targeted agents and collateral sensitizers." In 6th International Electronic Conference on Medicinal Chemistry. Basel, Switzerland: MDPI, 2020. http://dx.doi.org/10.3390/ecmc2020-07439.

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Bouachrine, M., J. P. Lère-Porte, J. Moreau, F. Serein-Spirau, and T. Lakhlifi. "An Organometallic Selective Synthesis of Conjugated Polymers with Improved Physical Properties." In The 8th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2004. http://dx.doi.org/10.3390/ecsoc-8-01994.

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Ford, Peter C., John A. Di Benedetto, David W. Ryba, and Simon T. Belt. "Reaction intermediates in organometallic chemistry studied by time-resolved infrared spectral techniques." In OE/LASE '92, edited by William G. Golden. SPIE, 1992. http://dx.doi.org/10.1117/12.59289.

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Margl, Peter, Karlheinz Schwarz, and Peter E. Blöchl. "Finite-temperature characterization of organometallic systems from first-principles molecular dynamics simulations." In The first European conference on computational chemistry (E.C.C.C.1). AIP, 1995. http://dx.doi.org/10.1063/1.47651.

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Taskar, N. R., I. B. Bhat, K. K. Parat, S. K. Ghandhi, and G. J. Scilla. "Extrinsic p-doped HgCdTe grown by direct alloy growth organometallic epitaxy." In Physics and chemistry of mercury cadmium telluride and novel IR detector materials. AIP, 1991. http://dx.doi.org/10.1063/1.41079.

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Eryiğit, Resul, and Irving P. Herman. "Optical Response of GaAs(001) Surfaces for Monitoring and Control of Atomic-Layer-Defined Processing." In Chemistry and Physics of Small-Scale Structures. Washington, D.C.: Optica Publishing Group, 1997. http://dx.doi.org/10.1364/cps.1997.csud.1.

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Progress in the miniaturization of electronic devices, the emergence of compound semiconductors in optoelectronics applications, and the development of quantum device structures based on nanostructures can continue only with an improved understanding and control of surfaces and interfacial regions. One important way to achieve such control is by real-time measurements during growth and etching. In addition to the standard surface-analysis techniques that require near ultrahigh vacuum (UHV) conditions (such as XPS, LEED, and EELS), there is a need for noninvasive real-time surface probes with submonolayer sensitivity that will be applicable to either the UHV environment of a molecular beam epitaxy (MBE) chamber or the atmospheric-pressure environment of an organometallic vapor phase epitaxy (OMVPE) reactor. Optical probes can be used during either type of processing.
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Pereira, Sarah A. P., A. Catarina Baptista L., Lorenzo Biancalana, Fabio Marchetti, Paul Dyson, and M. Lúcia Saraiva. "The inhibitory capacity of organometallic compounds with anticancer features in GST P1-1 enzyme activity: An automatic approach." In 7th International Electronic Conference on Medicinal Chemistry. Basel, Switzerland: MDPI, 2021. http://dx.doi.org/10.3390/ecmc2021-11470.

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Reports on the topic "Organometallic Chemistry"

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Beachley, O. T., and Jr. Main Group Organometallic Chemistry. Fort Belvoir, VA: Defense Technical Information Center, November 1995. http://dx.doi.org/10.21236/ada301970.

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Casey, C. P. Organometallic chemistry of bimetallic compounds. Office of Scientific and Technical Information (OSTI), July 1991. http://dx.doi.org/10.2172/5977032.

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Casey, C. P. Organometallic chemistry of bimetallic compounds. Office of Scientific and Technical Information (OSTI), July 1992. http://dx.doi.org/10.2172/7047078.

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Payne, G. (Lanthanide and actinide organometallic chemistry). Office of Scientific and Technical Information (OSTI), January 1987. http://dx.doi.org/10.2172/6751202.

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Casey, C. Organometallic chemistry of bimetallic compounds. Office of Scientific and Technical Information (OSTI), August 1990. http://dx.doi.org/10.2172/6619707.

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Chamberlin, R. M., K. D. Abney, G. J. Balaich, and S. A. Fino. Advanced polymer chemistry of organometallic anions. Office of Scientific and Technical Information (OSTI), November 1997. http://dx.doi.org/10.2172/554744.

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Casey, C. P. Organometallic chemistry of bimetallic compounds. [Annual report]. Office of Scientific and Technical Information (OSTI), July 1992. http://dx.doi.org/10.2172/10187589.

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Casey, C. P. Organometallic chemistry of bimetallic compounds. Annual progress report. Office of Scientific and Technical Information (OSTI), July 1993. http://dx.doi.org/10.2172/10192817.

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Marks, T. J. Supported organometallic complexes: Surface chemistry, spectroscopy, and catalysis. Office of Scientific and Technical Information (OSTI), February 1992. http://dx.doi.org/10.2172/5757111.

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Marks, T. J. Supported organometallic complexes: Surface chemistry, spectroscopy, and catalysis. Office of Scientific and Technical Information (OSTI), February 1990. http://dx.doi.org/10.2172/7047437.

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