Academic literature on the topic 'Organoindium'

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Journal articles on the topic "Organoindium"

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Singh, Atul. "Organoindium Reagents." Synlett 24, no. 11 (June 10, 2013): 1457–58. http://dx.doi.org/10.1055/s-0033-1339287.

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Zambroń, Bartosz K. "Internal Chelation within Functionalized Organoindium Reagents: Prospects for Regio- and Stereocontrol in the Allylation, Propargylation and Allenylation of Carbonyl Compounds." Synthesis 52, no. 08 (February 17, 2020): 1147–80. http://dx.doi.org/10.1055/s-0039-1690817.

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The low basicity, selective nucleophilicity, and mildness of organoindium compounds allow for the incorporation of many important yet sensitive functional groups into their structure, including examples capable of intramolecularly chelating the indium center within these reagents. The specific nature of such chelated organoindiums causes the reactions involving them to proceed in a unique manner, often with regio- and stereoselectivity inaccessible with simple organometallic reagents. This review covers the rare examples of regio- and stereoselective allylation, propargylation, and allenylation of carbonyl compounds with chelated organoindiums, including brief descriptions of the applications of the resulting adducts in the asymmetric synthesis of natural products and synthetic targets of biological and medicinal interest.1 Introduction2 Internal Chelation Control in the Allylation Processes2.1 Allylindiums with a Chelating Center at the γ-Position2.2 Allylindiums with a chelating Center at the δ-Position2.3 Allylindiums with a Chelating Center at ε- and ζ-Positions2.4 Allylindiums with a Chelating Center at γ′- and δ′-Positions3 Internal Chelation Control in Propargylation and Allenylation Processes­3.1 Additions of Chelated Allenylindiums3.2 Additions of Chelated Propargylindiums4 Conclusion
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Cowley, Alan H., François P. Gabbaï, Harold S. Isom, Andreas Decken, and Robert D. Culp. "Structural Diversity in Organoindium Iodides." Main Group Chemistry 1, no. 1 (September 1995): 9–19. http://dx.doi.org/10.1080/13583149512331338225.

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Zhao, Kai, Liang Shen, Zhi-Liang Shen, and Teck-Peng Loh. "Transition metal-catalyzed cross-coupling reactions using organoindium reagents." Chemical Society Reviews 46, no. 3 (2017): 586–602. http://dx.doi.org/10.1039/c6cs00465b.

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This review highlights the versatility and significance of transition metal-catalyzed cross-coupling reactions employing mild and unique organoindium reagents with exceptional functional group compatibility and sometimes remarkable chemo- and stereoselectivities.
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Schumann, Herbert, Reza Mohtachemi, and Michael Schwichtenberg. "Synthese und Eigenschaften einiger neuer Organoindium-Methylenstannyl-Verbindungen / Preparation and Properties of Some New Organoindium Methylenestannyl Compounds." Zeitschrift für Naturforschung B 43, no. 11 (November 1, 1988): 1510–13. http://dx.doi.org/10.1515/znb-1988-1119.

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Abstract Me2Sn(CH2Li)2 reacts with Me2InCl or (Me2NCH2CH2O)2 InCl with formation of the new compounds Me2Sn(CH2InMe2)2 or Me2Sn(CH2In(OCH2CH2NMe2)2)2 . The compounds are characterized by elemental analyses, 1H, 13C, 119Sn NMR and IR spectra.
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Fischer, Roland A., Harald Sussek, Alexander Miehr, Hans Pritzkow, and Eberhard Herdtweck. "Organoindium azides: new precursors to indium nitride." Journal of Organometallic Chemistry 548, no. 1 (December 1997): 73–82. http://dx.doi.org/10.1016/s0022-328x(97)00333-1.

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SCHUMANN, H., TH D. SEUSS, and H. HEMLING. "ChemInform Abstract: Homoleptic Intramolecularly Stabilized Organoindium Compounds." ChemInform 24, no. 13 (August 20, 2010): no. http://dx.doi.org/10.1002/chin.199313243.

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Soulière, V., P. Abraham, M. Sacilotti, M. P. Berthet, J. Bouix, Y. Monteil, A. M. Pougnet, R. Mellet, A. Ougazzaden, and A. Mircéa. "A new organoindium precursor for electronic materials." Materials Science and Engineering: B 17, no. 1-3 (February 1993): 34–40. http://dx.doi.org/10.1016/0921-5107(93)90078-2.

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Merzweiler, Kurt, Ludwig Brands, and Jürgen Spohn. "Neue In2P2-Vierringe. Synthese und Kristallstrukturen von [{iPrIn(μ-tBu2P)Cl}2] und [{Me3SiCH2In(μ-tBu2P)Cl}2] / New Four-Membered In2P2 Rings. Snythesis and Crystal Structures of [{iPrIn(μ-tBu2P)Cl}2] and [{Me3SiCH2In(μ-tBu2P)Cl}2]." Zeitschrift für Naturforschung B 48, no. 10 (October 1, 1993): 1315–20. http://dx.doi.org/10.1515/znb-1993-1002.

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The reaction of organoindium halides RInCl2 with tBu2PSiMe3 leads to compounds of the type [{RIn(μ-tBu2P)Cl}2] (R = iPr: 1, Me3SiCH2: 2). According to the crystal structure determinations 1 and 2 contain planar In2P2 rings. The In atoms are coordinated to two bridging tBu2P groups, a terminal alkyl group and a terminal Cl atom
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Sestelo, J., R. Riveiros, D. Rodríguez, and L. Sarandeses. "Cross-Coupling of Organoindium Reagents with Propargylic Esters." Synfacts 2006, no. 6 (June 2006): 0594. http://dx.doi.org/10.1055/s-2006-934522.

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Dissertations / Theses on the topic "Organoindium"

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Beveridge, Ramsay. "One step copper-catalyzed functionalization of pyridines with alkynes and organoindium reagents." Thesis, McGill University, 2007. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=18419.

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The copper-catalyzed synthesis of functionalized pyridines and partially reduced pyridine derivatives has been developed and the results are presented herein. These studies have shown that pyridines (and related aromatic heterocycles) in the presence of chloroformates will undergo effective coupling with terminal alkynes and organoindium reagents using simple copper (I) salt catalysts to give good yields of dihydropyridine products. In addition, performing these reactions in tandem with base or oxidative additives has led to the copper-catalyzed one-pot preparation of substituted aromatic pyridines.
Une méthode catalytique médiée par le cuivre pour la synthèse des dérivés de pyridines ainsi que celles partiellement réduites est décrite dans le texte qui suit. Cette étude démontre que les pyridines (et autres hétérocycles aromatiques reliés), lorsque quaternisées in-situ par des réactifs tel que les chloroformates, celles-ci peuvent être couplées avec des alcynes terminaux ou des réactifs organo-indium au moyen de simple sels de cuivre (I) pour générer, bon rendement, des dihydropyridines. De plus, lorsque cette réaction est effectuée en tandem, soit avec l'ajout d'une base ou d'un agent oxydant, ce processus nous offre une méthodologie en un pot envers la synthèse de pyridines substituées.
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Méndez-Andino, José Luis. "New fields in organic chemistry : developments in aqueous organoindium chemistry and ring closing olefin metathesis /." The Ohio State University, 2001. http://rave.ohiolink.edu/etdc/view?acc_num=osu1488204276534782.

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Hirayama, Lacie C. "Novel reactions of organoindium compounds : the synthesis of chiral alcohols, allylboron reagents and identification of the reactive intermediates /." Diss., Digital Dissertations Database. Restricted to UC campuses, 2007. http://uclibs.org/PID/11984.

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Bernhardt, Sebastian Verfasser], and Paul [Akademischer Betreuer] [Knochel. "Magnesium halide-mediated addition of functionalized organozinc reagents to aldehydes, ketones and carbon dioxide : preparation of solid salt-stabilized organozinc reagents ; preparation of functionalized organoindium reagents via magnesium insertion in the presence of InCl3 / Sebastian Bernhardt. Betreuer: Paul Knochel." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2012. http://d-nb.info/1025822005/34.

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Chagas, Rafael Pavão das. "Estudo da Aplicação de Brometo de Índio(I) em Reações para Formação de Ligações Carbono-Carbono." Universidade Federal de Santa Maria, 2011. http://repositorio.ufsm.br/handle/1/4206.

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Conselho Nacional de Desenvolvimento Científico e Tecnológico
This PhD thesis describes our results on the application of indium(I) bromide in carbon-carbon bond forming reactions. Indium enolates, generated in situ from the reaction between indium(I) bromide and α,α-dichloroketones, react with carbonyl compounds and electron-deficient alkenes. Reactions of indium enolate with α,α-dichloroketones, in presence of extra InBr, leads to the formation of 1,4-diketones. The coupling with aldehydes leads alternatively, according as the stoichiometry, to the diastereoselective synthesis of (syn+anti)-2-chloro-3-hydroxy-propan-1-ones (which can be converted to the respective trans-epoxyketones), (E)-α,β-unsaturated ketones and cyclopropanes, upon a sequenced reaction mechanism. We also have developed a methodology for the preparation of cyclopropanes through the reaction of the indium enolate and other organoindium(III) compounds, derived from the reactions between InBr and α,α-dihalo carbonyl compounds and halo-acetonitriles, with electron-deficient alkenes.
Este trabalho descreve os resultados dos estudos realizados sobre aplicações de brometo de índio(I) em reações para formação de ligações carbono-carbono. A reação entre brometo de índio(I) e α,α-diclorocetonas produz, in situ, enolatos de índio que reagem com compostos carbonílicos e alcenos deficientes em elétrons. As reações do enolato de índio com outras moléculas de α,α-diclorocetonas, na presença de InBr em excesso, leva à formação de 1,4-dicetonas. O acoplamento com aldeídos leva alternativamente, conforme a estequiometria, à formação diastereosseletiva de (syn+anti)-α-cloro-β-hidróxi-cetonas (que podem ser convertidas às respectivas trans-epóxi-cetonas), cetonas (E)-α,β-insaturadas e ciclopropanos, segundo um mecanismo de reações sequenciais. Ainda foi desenvolvida uma metodologia para preparação de ciclopropanos através da reação do enolato de índio e de outros compostos organoíndio(III), derivados da reação entre InBr e vários compostos carbonílicos α,α-di-halogenados e halogeno-acetonitrilas, com alcenos deficientes em elétrons.
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Books on the topic "Organoindium"

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Weidlein, Johann. In Organoindium Compounds. Edited by Wolfgang Petz. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9.

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1944-, McKillop A., Smith J. D, and Worrall I. J. 1933-, eds. Organometallic compounds of aluminum, gallium, indium, and thallium. London: Chapman and Hall, 1985.

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F, Hepp Aloysius, and United States. National Aeronautics and Space Administration., eds. Room-temperature synthesis of CuInQ₂(Q=S or Se) in non-aqueous solution using an organoindium reagent. [Washington, DC]: National Aeronautics and Space Administration, 1993.

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F, Hepp Aloysius, and United States. National Aeronautics and Space Administration., eds. Room-temperature synthesis of CuInQ₂(Q=S or Se) in non-aqueous solution using an organoindium reagent. [Washington, DC]: National Aeronautics and Space Administration, 1993.

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F, Hepp Aloysius, and United States. National Aeronautics and Space Administration., eds. Room-temperature synthesis of CuInQ₂(Q=S or Se) in non-aqueous solution using an organoindium reagent. [Washington, DC]: National Aeronautics and Space Administration, 1993.

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F, Hepp Aloysius, and United States. National Aeronautics and Space Administration., eds. Room-temperature synthesis of CuInQb□-s□b2b□-s□s(Q=S or Se) in non-aqueous solution using an organoindium reagent. [Washington, DC]: National Aeronautics and Space Administration, 1993.

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Gmelin, Leopold. Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th Edition Element I-N In. Indium (System-NR. 37) Ergdnzungsband 1- Organoindium Compound. Springer, 1991.

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Book chapters on the topic "Organoindium"

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Weidlein, Johann. "Organoindium Halogenides." In In Organoindium Compounds, 116–76. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_2.

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Weidlein, Johann. "Organoindium Pseudohalogenides." In In Organoindium Compounds, 176–80. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_3.

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Weidlein, Johann. "Organoindium-Oxygen Compounds." In In Organoindium Compounds, 180–239. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_4.

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Weidlein, Johann. "Organoindium-Sulfur Compounds." In In Organoindium Compounds, 239–52. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_5.

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Weidlein, Johann. "Organoindium-Selenium Compounds." In In Organoindium Compounds, 252. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_6.

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Weidlein, Johann. "Organoindium-Nitrogen Compounds." In In Organoindium Compounds, 252–312. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_7.

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Weidlein, Johann. "Organoindium-Boron Compounds." In In Organoindium Compounds, 326–29. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_9.

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Weidlein, Johann. "Indium Triorganyls." In In Organoindium Compounds, 1–116. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_1.

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Weidlein, Johann. "Organoindium-Transition Metal Compounds." In In Organoindium Compounds, 329–36. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_10.

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Weidlein, Johann. "Compounds with Organoindium Ions." In In Organoindium Compounds, 336–70. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-662-09144-9_11.

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Reports on the topic "Organoindium"

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Wells, R. L., A. T. McPhail, and M. F. Self. Synthesis and Structural Characterization of Organoindium-Phosphorus Complexes Containing a Four-Membered In-P-In-Cl or In-P-In-P Ring: Crystal Structures of (Me3SiCH2)2InP(SiMe3)2In(CH2SiMe3)2Cl and ((Me3SiCH2)2InP(SiMe3)2) 2. Fort Belvoir, VA: Defense Technical Information Center, July 1991. http://dx.doi.org/10.21236/ada239170.

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