Dissertations / Theses on the topic 'Open systems theory'

Herein we develop category-theoretic tools for understanding network-style diagrammatic languages. The archetypal network-style diagrammatic language is that of electric circuits; other examples include signal flow graphs, Markov processes, automata, Petri nets, chemical reaction networks, and so on. The key feature is that the language is comprised of a number of components with multiple (input/output) terminals, each possibly labelled with some type, that may then be connected together along these terminals to form a larger network. The components form hyperedges between labelled vertices, and so a diagram in this language forms a hypergraph. We formalise the compositional structure by introducing the notion of a hypergraph category. Network-style diagrammatic languages and their semantics thus form hypergraph categories, and semantic interpretation gives a hypergraph functor. The first part of this thesis develops the theory of hypergraph categories. In particular, we introduce the tools of decorated cospans and corelations. Decorated cospans allow straightforward construction of hypergraph categories from diagrammatic languages: the inputs, outputs, and their composition are modelled by the cospans, while the 'decorations' specify the components themselves. Not all hypergraph categories can be constructed, however, through decorated cospans. Decorated corelations are a more powerful version that permits construction of all hypergraph categories and hypergraph functors. These are often useful for constructing the semantic categories of diagrammatic languages and functors from diagrams to the semantics. To illustrate these principles, the second part of this thesis details applications to linear time-invariant dynamical systems and passive linear networks.

This thesis covers open quantum systems and information transfer in the face of dissipation and disorder through numerical simulation. In Chapter 3 we present work on an open quantum system comprising a two-level system, single bosonic mode and dissipative environment; we have included the bosonic mode in the exact system treatment. This model allows us to gain an understanding of an environment's role in small energy transfer systems. We observe how the two-level system-mode coupling strength and the spectral density form characterising the environment interplay, affecting the system's coherent behaviour. We find strong coupling and a spectral density resonantly peaked on the two-level system oscillation frequency enhances the system's coherent oscillatory dynamics. Chapter 4 focusses on a physically motivated study of chain and ladder spin geometries and their use for entanglement transfer between qubits. We consider a nitrogen vacancy centre qubit implementation with nitrogen impurity spin-channels and demonstrate how matrix product operator techniques can be used in simulations of this physical system. We investigate coupling parameters and environmental decay rates with respect to transfer efficiency effects. Then, in turn, we simulate the effects of missing channel spins and disorder in the spin-spin coupling. We conclude by highlighting where our considered channel geometries outperform each other. The work in Chapter 5 is an investigation into the feasibility of routing entanglement between distant qubits in 2D spin networks. We no longer consider a physical implementation, but keep in mind the effects of dissipative environments on entanglement transfer systems. Starting with a single sending qubit-ancilla and multiple addressable receivers, we show it is possible to target a specific receiver and establish transferred entanglement between it and the sender's ancilla through eigenstate tunnelling techniques. We proceed to show that eigenstate tunnelling-mediated entanglement transfer can be achieved simultaneously from two senders across one spin network.

Open, embedded multi-agent systems have applications in sensor and opportunistic networks, and in cloud and grid computing. Features of such systems include: no centralised control, competition for resources between autonomous agents, (un)intentional errors, and a speed and complexity of decisions beyond human capabilities. Moreover, there is a requirement to optimise performance with respect to multiple, possibly conflicting, criteria, for example longevity, occupancy and fairness. This thesis addresses the problem of engineering self-organised resource-allocation management schemes for open, embedded systems. Based on the theory of institutions for collective action as defined by political economist Elinor Ostrom, we define a formal model for self-organised resource-allocation, using the computational framework of dynamic norm-governed multi-agent systems. Our model of an electronic institution encapsulates a first-order logic axiomatisation of the principles for enduring institutions. An experimental platform for an abstract common-pool resource management situation has been developed, and the experiments show the importance of all principles in order to achieve longevity, appropriate behaviour and the right balance of membership. The results furthermore suggest that the mechanisms to design institutional rules should be made available to the system components themselves. In order to successfully self-organise, the system has to be aware of its internal state and externalities. To represent and reason about awareness, some aspects from the field of organisational justice have been formalised in the same framework. Agents will not only follow a collectively decided allocation procedure but will execute the allocation according to their own notion of fairness, and also use this notion to judge the perceived behaviour of others. Further experiments show that the ability for introspection and reflection on the perceived environment leads to an improved management profile and further enhances the system’s performance. Adaptive institutions are a key factor in dealing with resource distribution. Self-aware agents using electronic institutions in socio-technical systems could be a significant innovation in reducing the current lag between institutional and environmental change, and make an important contribution to the sustainability agenda.

Surface mining is the most common mining method worldwide, and open pit mining accounts for more than 60% of all surface output. Haulage costs account for as much as 60% of the total operating cost for these types of mines, so it is desirable to maintain an efficient haulage system. As the size of the haulage fleet being used increases, shovel productivity increases and truck productivity decreases, so an effective fleet size must be chosen that will effectively utilize all pieces of equipment. One method of fleet selection involves the application of queuing theory to the haul cycle. Queuing theory was developed to model systems that provide service for randomly arising demands and predict the behavior of such systems. A queuing system is one in which customers arrive for service, wait for service if it is not immediately available, and move on to the next server or exit the system once they have been serviced. Most mining haul routes consist of four main components: loading, loaded hauling, dumping, and unloaded hauling to return to the loader. These components can be modeled together as servers in one cyclic queuing network, or independently as individual service channels. Data from a large open pit gold mine are analyzed and applied to a multichannel queuing model representative of the loading process of the haul cycle.  The outputs of the model are compared against the actual truck data to evaluate the validity of the queuing model developed.
Master of Science

This thesis addresses the problem of a form of anomalous decoherence that sheds light into the spectroscopy of blinking quantum dots. The system studied is a two-state system, interacting with an external environment that has the effect of establishing an interaction between the two states, via a coherence generating coupling, called inphasing. The collisions with the environment produce also decoherence, named dephasing. Decoherence is interpreted as the entanglement of the coherent superposition of these two states with the environment. The joint action of inphasing and dephasing generates a Markov master equation statistically equivalent to a random walker jumping from one state to the other. This model can be used to describe intermittent fluorescence, as a sequence of "light on" and "light off" states. The experiments on blinking quantum dots indicate that the sojourn times are distributed with an inverse power law. Thus, a proposal to turn the model for Poisson fluorescence intermittency into a model for non-Poisson fluorescence intermittency is made. The collision-like interaction of the two-state system with the environment is assumed to takes place at random times rather than at regular times. The time distance between one collision and the next is given by a distribution, called the subordination distribution. If the subordination distribution is exponential, a sequence of collisions yielding no persistence is turned into a sequence of "light on" and "light off" states with significant persistence. If the subordination function is an inverse power law the sequel of "light on" and "light off" states becomes equivalent to the experimental sequences. Different conditions are considered, ranging from predominant inphasing to predominant dephasing. When dephasing is predominant the sequel of "light on" and "light off" states in the time asymptotic limit becomes an inverse power law. If the predominant dephasing involves a time scale much larger than the minimum time scale accessible to the experimental observation, thereby generating persistence, the resulting distribution becomes a Mittag-Leffler function. If dephasing is predominant, in addition to the inverse power law distribution of "light off" and "light on" time duration, a strong correlation between "light on" and "light off" state is predicted.

By means of a systemic approach toward analysis and design of complex systems, we introduce the issue of implementing open computational systems on service-oriented architectures. We start by studying general systems theory, as it accounts for analysis and modeling of complex systems, and then compare three different implementation strategies toward system implementation. As such, the comparison is grounded in the notion of supporting architectures and, more specifically, in the practical case of a service-oriented layered architecture for communicating entities (SOLACE).
More material can be found on http://www.soclab.bth.se

First-principles electronic structure theory explains properties of atoms, molecules and solids from underlying physical principles without input from empirical parameters. Time-dependent density functional theory (TDDFT) has emerged as arguably the most widely used first-principles method for describing the time-dependent quantum mechanics of many-electron systems. In this thesis, we will show how the fundamental principles of TDDFT can be extended and applied in two novel directions: The theory of open quantum systems (OQS) and quantum computation (QC). In the first part of this thesis, we prove theorems that establish the foundations of TDDFT for open quantum systems (OQS-TDDFT). OQS-TDDFT allows for a first principles description of non-equilibrium systems, in which the electronic degrees of freedom undergo relaxation and decoherence due to coupling with a thermal environment, such as a vibrational or photon bath. We then discuss properties of functionals in OQS-TDDFT and investigate how these differ from functionals in conventional TDDFT using an exactly solvable model system. Next, we formulate OQS-TDDFT in the linear-response regime, which gives access to environmentally broadened excitation spectra. Lastly, we present a hybrid approach in which TDDFT can be used to construct master equations from first-principles for describing energy transfer in condensed phase systems. In the second part of this thesis, we prove that the theorems of TDDFT can be extended to a class of qubit Hamiltonians that are universal for quantum computation. TDDFT applied to universal Hamiltonians implies that single-qubit expectation values can be used as the basic variables in quantum computation and information theory, rather than wavefunctions. This offers the possibility of simplifying computations by using the principles of TDDFT similar to how it is applied in electronic structure theory. Lastly, we discuss a related result; the computational complexity of TDDFT.
Physics

Thesis (Ph.D)--Mathematics, Georgia Institute of Technology, 2009.
Committee Chair: Bunimovich, Leonid; Committee Member: Bakhtin, Yuri; Committee Member: Cvitanovic, Predrag; Committee Member: Houdre, Christian; Committee Member: Weiss, Howard. Part of the SMARTech Electronic Thesis and Dissertation Collection.

Robust control is an aspect of control theory which explicitly considers uncertainties and how they affect robust stability in the analysis and design of control decisions. A basic requirement for optimal robust guaranteed control in a real life scenario is the stabilization of systems in the presence of uncertainties or perturbations. In this thesis, the system uncertainties are embedded into a norm bounded uncertainty elements. The perturbation function is modelled as a class of nonlinear uncertainty influencing a neutral system with infinite delay. It is assumed to have delay in state and is input dependent; which implies the effect of control action can directly or indirectly influence the nonlinear perturbation function. In recognition of the fact that stability and controllability are fundamental in obtaining the optimal robust guaranteed cost control design for neutral functional integro-differential systems with infinite delays (NFDSID), total asymptotic stability results were developed using Razumikhin technique, unique properties of eigenvalues, and the uniform stability properties of the functional difference operator for neutral systems. The new results, obtained using Razumikhin’s technique, extend and complement basic stability results in neutral systems to NFDSID. Novel sufficient conditions were developed for the null controllability of nonlinear NFDSID when the controls are constrained. By exploring the knowledge gained through other controllability results; conditions are placed on the perturbation function. This guaranteed that, if the uncontrolled system is uniformly asymptotically stable, and the controlled system satisfies a full rank condition, then the control system is null controllable with constraint if it satisfies some algebraic conditions. The investigation of optimal robust guaranteed cost control method has resulted in a novel delay dependent stability criterion for a nonlinear NFDSID with a given quadratic cost function. The new design is based on a model transformation technique, Lyapunov matrix equation and Lyapunov-Razumikhin stability approach. The Lyapunov-Razumikhin technique is adopted for this investigation because it is considered more scalable for optimal robust guaranteed cost control design for NFDSID. It is demonstrated that a memory less feedback control can be synthesized appropriately to ensure: (i) the closed-loop systems robust stability, and (ii) guarantee that the closed-loop cost function value remains within a specified bound. The problem of designing the optimal guaranteed cost controller is also realized in terms of inequalities. The Lyapunov-Krasovskii method is used to obtain stability conditions in comparison to the Razumikhin method. This method leads to linear matrix inequality (LMI) for the delay-independent case which is known to be conservative. To illustrate the potential practical applicability of the theoretical results; a cascade connection of two fully filled chemical solution mixers, and an integrated lossless transmission line which has a capacitance, inductance, resistance and terminated by a nonlinear function are modelled. A neutral control system model for NFDSID is derived from each of these systems. Simulation studies on the transmission line system confirm the theoretical robust stability results. The new results and methods of analysis expounded in this thesis are explicit, computationally more effective than existing ones and will serve as a working document for the present and future generations in the comity of researchers and industries alike.

Systems Psychodynamics is unique as an approach to consulting to organisations in the way it integrates three theory streams: psychoanalysis; group relations and open systems theory. Consultants who work in this way focus on the many layers of interactions and exchanges taking place both within organisations and at the interface between an organisation and its external environment. The territory for collaborative exploration with clients extends from interpersonal and group dynamics to service and product- related systems and processes. It is a holistic approach that creates opportunities for transformational learning at every level of the organisation. As a practice, consulting with a systems psychodynamics approach is complex and difficult to master. Arguably, the most challenging dimension of this work for consultants is developing a capacity to think within a psychoanalytic conceptual framework: to discern and hypothesise about unconscious processes in organisations. But what precisely does this mean and what is this experience like for the consultants? This research project was designed to explore and describe the experience of working with a systems psychodynamic approach from the consultants' perspectives within the Australian context. To this end, 20 consultants who self-selected as working with a systems psychodynamic approach were involved in this research. From the data created in this process, what is documented in this thesis is the first detailed description of the experience of 'working in this way' taken from the combined perspectives of these 20 consultants. Further, a systems psychodynamic approach to research is defined and applied in this thesis. In this way, the systems psychodynamics within the temporary 'system' created by the research was part of the territory under investigation. This process led to an important discovery. 18 of 20 consultants strongly asserted the importance of working with colleagues in pairs or teams when adopting a systems psychodynamic approach. However, at the time of interviewing, all 20 consultants were working alone and only 3 had immediate plans to work with others. An exploration of the reasons for this gap between beliefs about best practice and actual practice became the focus for the analysis of the data. What is discovered through this analysis is that the reasons why consultants are predominantly choosing to work alone are likely to be complex and irreducible. An exploration of the issues that working together can surface for consultants who apply a systems psychodynamic approach is presented under four sub-topics: system domain issues; theory-related issues; interpersonal issues and intrapsychic issues. In this detailed analysis, what is revealed is an absence of 'good enough' containment for the anxieties that are likely to be aroused when consultants work together. To this end, four 'containers' are proposed: organisation/brand-as-container; management-as-container; supervision-as-container and theory/praxis-as container. This research has uncovered some important challenges facing the community of practitioners in Australia. It is the contention in this thesis that they need to be addressed if the practice of consulting with a systems psychodynamic approach is to flourish and continue to grow.

On etudie la contrôlabilité des systèmes quantiques dans deux contextes différents: le cadre standard fermé, dans lequel un système quantique est considéré comme isolé et le problème de contrôle est formulé sur l'équation de Schrödinger; le cadre ouvert qui décrit un système quantique en interaction avec un plus grand, dont seuls les paramètres qualitatifs sont connus, au moyen de l'équation de Lindblad sur les états.Dans le contexte des systèmes fermés on se focalise sur la classe intéressante des systèmes spin-boson, qui décrivent l'interaction entre un système quantique à deux niveaux et un nombre fini de modes distingués d'un champ bosonique. On considère deux exemples prototypiques, le modèle de Rabi et le modèle de Jaynes-Cummings qui sont encore très populaires dans plusieurs domaines de la physique quantique. Notamment, dans le contexte de la Cavity Quantum Electro Dynamics (C-QED), ils fournissent une description précise de la dynamique d'un atome à deux niveaux dans une cavité micro-onde en résonance, comme dans les expériences récentes de S. Haroche. Nous étudions les propriétés de contrôlabilité de ces modèles avec deux types différents d'opérateurs de contrôle agissant sur la partie bosonique, correspondant respectivement – dans l'application à la C-QED – à un champ électrique et magnétique externe. On passe en revue quelques résultats récents et prouvons la contrôlabilité approximative du modèle de Jaynes-Cummings avec ces contrôles. Ce résultat est basé sur une analyse spectrale exploitant les non-résonances du spectre. En ce qui concerne la relation entre l'Hamiltonien de Rabi et Jaynes-Cummings nous traitons dans un cadre rigoureux l'approximation appelée d'onde tournante. On formule le problème comme une limite adiabatique dans lequel la fréquence de detuning et le paramètre de force d'interaction tombent à zero, ce cas est connu sous le nom de régime de weak-coupling. On prouve que, sous certaines hypothèses sur le rapport entre le detuning et le couplage, la dynamique de Jaynes-Cumming et Rabi montrent le même comportement, plus précisément les opérateurs d'évolution qu'ils génèrent sont proches à la norme.Dans le cadre des systèmes quantiques ouverts nous étudions la contrôlabilité de l'équation de Lindblad. Nous considérons un contrôle agissant adiabatiquement sur la partie interne du système, que nous voyons comme un degré de liberté qui peut être utilisé pour contraster l'action de l'environnement. L'action adiabatique du contrôle est choisie pour produire une transition robuste. On prouve, dans le cas prototype d'un système à deux niveaux, que le système approche un ensemble de points d'équilibre déterminés par l'environnement, plus précisément les paramètres qui spécifient l'opérateur de Lindblad. Sur cet ensemble, le système peut être piloté adiabatiquement en choisissant un contrôle approprié. L'analyse est fondée sur l'application de méthodes de perturbation géométrique singulière
We investigate the controllability of quantum systems in two differentsettings: the standard 'closed' setting, in which a quantum system is seen as isolated, the control problem is formulated on the Schroedinger equation; the open setting that describes a quantum system in interaction with a larger one, of which just qualitative parameters are known, by means of the Lindblad equation on states.In the context of closed systems we focus our attention to an interesting class ofmodels, namely the spin-boson models. The latter describe the interaction between a 2-level quantum system and finitely many distinguished modes of a bosonic field. We discuss two prototypical examples, the Rabi model and the Jaynes-Cummings model, which despite their age are still very popular in several fields of quantum physics. Notably, in the context of cavity Quantum Electro Dynamics (C-QED) they provide an approximate yet accurate description of the dynamics of a 2-level atom in a resonant microwave cavity, as in recent experiments of S. Haroche. We investigate the controllability properties of these models, analyzing two different types of control operators acting on the bosonic part, corresponding -in the application to cavity QED- to an external electric and magnetic field, respectively. We review some recent results and prove the approximate controllability of the Jaynes-Cummings model with these controls. This result is based on a spectral analysis exploiting the non-resonances of the spectrum. As far as the relation between the Rabi andthe Jaynes-Cummings Hamiltonians concerns, we treat the so called rotating waveapproximation in a rigorous framework. We formulate the problem as an adiabaticlimit in which the detuning frequency and the interaction strength parameter goes to zero, known as the weak-coupling regime. We prove that, under certain hypothesis on the ratio between the detuning and the coupling, the Jaynes-Cumming and the Rabi dynamics exhibit the same behaviour, more precisely the evolution operators they generate are close in norm.In the framework of open quantum systems we investigate the controllability ofthe Lindblad equation. We consider a control acting adiabatically on the internal part of the system, which we see as a degree of freedom that can be used to contrast the action of the environment. The adiabatic action of the control is chosen to produce a robust transition. We prove, in the prototype case of a two-level system, that the system approach a set of equilibrium points determined by the environment, i.e. the parameters that specify the Lindblad operator. On that set the system can be adiabatically steered choosing a suitable control. The analysis is based on the application of geometrical singular perturbation methods

Thermalization, the evolution of an interacting many-body system towards a thermal Gibbs ensemble after initialization in an arbitrary non-equilibrium state, is currently a phenomenon of great interest, both in theory and experiment. As the time evolution of a quantum system is unitary, the proposed mechanism of thermalization in quantum many-body systems corresponds to the so-called eigenstate thermalization hypothesis (ETH) and the typicality of eigenstates. Although this formally solves the contradiction of thermalizing but unitary dynamics in a closed quantum many-body system, it does neither make any statement on the dynamical process of thermalization itself nor in which way the coupling of the system to an environment can hinder or modify the relaxation dynamics. In this thesis, we address both the question whether or not a quantum system driven away from equilibrium is able to relax to a thermal state, which fulfills detailed balance, and if one can identify universal behavior in the non-equilibrium relaxation dynamics. As a first realization of driven quantum systems out of equilibrium, we investigate a system of Ising spins, interacting with the quantized radiation field in an optical cavity. For multiple cavity modes, this system forms a highly entangled and frustrated state with infinite correlation times, known as a quantum spin glass. In the presence of drive and dissipation, introduced by coupling the intra-cavity radiation field to the photon vacuum outside the cavity via lossy mirrors, the quantum glass state is modified in a universal manner. For frequencies below the photon loss rate, the dissipation takes over and the system shows the universal behavior of a dissipative spin glass, with a characteristic spectral density $\\mathcal{A}(\\omega)\\sim\\sqrt{\\omega}$. On the other hand, for frequencies above the loss rate, the system retains the universal behavior of a zero temperature, quantum spin glass. Remarkably, at the glass transition, the two subsystems of spins and photons thermalize to a joint effective temperature, even in the presence of photon loss. This thermalization is a consequence of the strong spin-photon interactions, which favor detailed balance in the system and detain photons from escaping the cavity. In the thermalized system, the features of the spin glass are mirrored onto the photon degrees of freedom, leading to an emergent photon glass phase. Exploiting the inherent photon loss of the cavity, we make predictions of possible measurements on the escaping photons, which contain detailed information of the state inside the cavity and allow for a precise, non-destructive measurement of the glass state. As a further set of non-equilibrium systems, we consider one-dimensional quantum fluids driven out of equilibrium, whose universal low energy theory is formed by the so-called Luttinger Liquid description, which, due to its large degree of universality, is of intense theoretical and experimental interest. A set of recent experiments in research groups in Vienna, Innsbruck and Munich have probed the non-equilibrium time-evolution of one-dimensional quantum fluids for different experimental realizations and are pushing into a time regime, where thermalization is expected. From a theoretical point of view, one-dimensional quantum fluids are particular interesting, as Luttinger Liquids are integrable and therefore, due to an infinite number of constants of motion, do not thermalize. The leading order correction to the quadratic theory is irrelevant in the sense of the renormalization group and does therefore not modify static correlation functions, however, it breaks integrability and will therefore, even if irrelevant, induce a completely different non-equilibrium dynamics as the quadratic Luttinger theory alone. In this thesis, we derive for the first time a kinetic equation for interacting Luttinger Liquids, which describes the time evolution of the excitation densities for arbitrary initial states. The resonant character of the interaction makes a straightforward derivation of the kinetic equation, using Fermi\'s golden rule, impossible and we have to develop non-perturbative techniques in the Keldysh framework. We derive a closed expression for the time evolution of the excitation densities in terms of self-energies and vertex corrections. Close to equilibrium, the kinetic equation describes the exponential decay of excitations, with a decay rate $\\sigma^R=\\mbox\\Sigma^R$, determined by the self-energy at equilibrium. However, for long times $\\tau$, it also reveals the presence of dynamical slow modes, which are the consequence of exactly energy conserving dynamics and lead to an algebraic decay $\\sim\\tau^$ with $\\eta_D=0.58$. The presence of these dynamical slow modes is not contained in the equilibrium Matsubara formalism, while they emerge naturally in the non-equilibrium formalism developed in this thesis. In order to initialize a one-dimensional quantum fluid out of equilibrium, we consider an interaction quench in a model of interacting, dispersive fermions in Chap.~\\ref. In this scenario, the fermionic interaction is suddenly changed at time $t=0$, such that for $t>0$ the system is not in an eigenstate and therefore undergoes a non-trivial time evolution. For the quadratic theory, the stationary state in the limit $t\\rightarrow\\infty$ is a non-thermal, or prethermal, state, described by a generalized Gibbs ensemble (GGE). The GGE takes into account for the conservation of all integrals of motion, formed by the eigenmodes of the Hamiltonian. On the other hand, in the presence of non-linearities, the final state for $t\\rightarrow\\infty$ is a thermal state with a finite temperature $T>0$. . The spatio-temporal, dynamical thermalization process can be decomposed into three regimes: A prequench regime on the largest distances, which is determined by the initial state, a prethermal plateau for intermediate distances, which is determined by the metastable fixed point of the quadratic theory and a thermal region on the shortest distances. The latter spreads sub-ballistically $\\sim t^$ in space with $0<\\alpha<1$ depending on the quench. Until complete thermalization (i.e. for times $t<\\infty$), the thermal region contains more energy than the prethermal and prequench region, which is expressed in a larger temperature $T_{t}>T_$, decreasing towards its final value $T_$. As the system has achieved local detailed balance in the thermalized region, energy transport to the non-thermal region can only be performed by the macroscopic dynamical slow modes and the decay of the temperature $T_{t}-T_\\sim t^$ again witnesses the presence of these slow modes. The very slow spreading of thermalization is consistent with recent experiments performed in Vienna, which observe a metastable, prethermal state after a quench and only observe the onset of thermalization on much larger time scales. As an immediate indication of thermalization, we determine the time evolution of the fermionic momentum distribution after a quench from non-interacting to interacting fermions. For this quench scenario, the step in the Fermi distribution at the Fermi momentum $k\\sub$ decays to zero algebraically in the absence of a non-linearity but as a stretched exponential (the exponent being proportional to the non-linearity) in the presence of a finite non-linearity. This can serve as a proof for the presence or absence of the non-linearity even on time-scales for which thermalization can not yet be observed. Finally, we consider a bosonic quantum fluid, which is driven away from equilibrium by permanent heating. The origin of the heating is atomic spontaneous emission of laser photons, which are used to create a coherent lattice potential in optical lattice experiments. This process preserves the system\'s $U(1)$-invariance, i.e. conserves the global particle number, and the corresponding long-wavelength description is a heated, interacting Luttinger Liquid, for which phonon modes are continuously populated with a momentum dependent rate $\\partial_tn_q\\sim\\gamma |q|$. In the dynamics, we identify a quasi-thermal regime for large momenta, featuring an increasing time-dependent effective temperature. In this regime, due to fast phonon-phonon scattering, detailed balance has been achieved and is expressed by a time-local, increasing temperature. The thermal region emerges locally and spreads in space sub-ballistically according to $x_t\\sim t^{4/5}$. For larger distances, the system is described by an non-equilibrium phonon distribution $n_q\\sim |q|$, which leads to a new, non-equilibrium behavior of large distance observables. For instance, the phonon decay rate scales universally as $\\gamma_q\\sim |q|^{5/3}$, with a new non-equilibrium exponent $\\eta=5/3$, which differs from equilibrium. This new, universal behavior is guaranteed by the $U(1)$ invariant dynamics of the system and is insensitive to further subleading perturbations. The non-equilibrium long-distance behavior can be determined experimentally by measuring the static and dynamic structure factor, both of which clearly indicate the exponents for phonon decay, $\\eta=5/3$ and for the spreading of thermalization $\\eta_T=4/5$. Remarkably, even in the presence of this strong external drive, the interactions and their aim to achieve detailed balance are strong enough to establish a locally emerging and spatially spreading thermal region. The physical setups in this thesis do not only reveal interesting and new dynamical features in the out-of-equilibrium time evolution of interacting systems, but they also strongly underline the high degree of universality of thermalization for the classes of models studied here. May it be a system of coupled spins and photons, where the photons are pulled away from a thermal state by Markovian photon decay caused by a leaky cavity, a one-dimensional fermionic quantum fluid, which has been initialized in an out-of-equilibrium state by a quantum quench or a one-dimensional bosonic quantum fluid, which is driven away from equilibrium by continuous, external heating, all of these systems at the end establish a local thermal equilibrium, which spreads in space and leads to global thermalization for $t\\rightarrow\\infty$. This underpins the importance of thermalizing collisions and endorses the standard approach of equilibrium statistical mechanics, describing a physical system in its steady state by a thermal Gibbs ensemble.

Organisational research in English-speaking countries has long been focused on two main areas. Studies on micro-level have been concerned with the socio-psychological explanation of organisational phenomena, mostly on the level of the individual and groups. Macro-level studies have been concerned with structure for the explanation of organisational phenomena. Macro-level theories have mostly bracketed the individual, and neglected the psychological component or regarded the individual as an actor playing roles. Only recently has the study of organisations been extended to attempt a meso-level analysis of organisational phenomena (Rousseau 1991, 1995). These meso-level attempts have, in the eyes of the author, run into explanatory problems. These problems are mainly due to the 'new' approach being based principally on existing macro-and micro-level theory, merely marrying the two approaches and thus inheriting the apparent difficulties of the existing theory to account for the individual. Althusser and Levi-Strauss are prominent representatives of both micro-and macro-level theory. This author agrees with the notion that organisational research benefits from a meso-level approach to organisational theory. It is in the light of this approach that the author turned to a widely unknown source of theory (in the English-speaking countries) to address the existing explanatory problems in organisational research and contribute so to the field. The underlying fundamental belief of the author is that any institution can be more successfully understood in the sociological context that defines the institution. Introducing the metaphor of 'social resonance' and linking it to the social theory of Pierre Bourdieu, especially the notion of agents and fields, the author attempts to cross-fertilise the academic fields of sociological research in mainland Europe (namely France and Germany with their strong philosophical tradition) with the academic fields of organisational research in the English-speaking countries (namely Britain and the US). This thesis will discuss the organisational research literature and social theory, introduce Pierre Bourdieu's theory of practice, develop the metaphor of 'social resonance', and test the new construct in an empirical research setting. The main objective of this study is thus to explore the value of Bourdieu's theory of practice for the explanation of organisational phenomena, and to operationalise it in the metaphor of 'social resonance'. To this end, a research framework has been developed which is explained in more detail in this report.

From its infancy, environmental psychology [which concerns itself with the coinfluencing interface between people and places] has required attention to actual context, and attention to social relevance. There has always been an emphasis on research into real problems within a context of meaningful theory, and on results which have potential not only for individuals, but also for policy-makers and those who execute that policy. This environmental psychology study is about the potential role of green open space in contributing towards quality of life in the city generally. It is also about a specific, wellloved urban open space in Namibia's capital city, Windhoek, the Avis dam environment, which is often the contentious target of proposed commercial development. At the moment, the Windhoek Municipality has no well-structured urban open space policy, and possibly also no full understanding of the meanings of the Avis dam for its users. This study hopes to make contributions to both these areas of policy-making. As the applicability of research findings to the development of public policies and community interventions depends very much on the suitability of the methodology and theories chosen (Stokols, 19911), this study begins with a discussion of systemic and ecosystemic thinking [Chapter Two]. They were chosen as the guiding metatheory for this study, not only because of their recognition of the inescapable connectedness between person and environment, but because of their personal appeal too. Chapter Three examines theories and models which are compatible with systems thinking, and which help understand the potentially positive psycho-social and socio-economic roles of urban open space generally, and how the extent of that potential in a specific open space may be appreciated and described. The implications of systemic/ecosystemic metatheory for the study's methodology and research design are discussed in Chapter Four, and the data collection methods, which comprised observation and interviewing, in Chapter Five. Ecosystemic thinkers do not believe that facts can be "found" [they are not there objectively, but co-emerge subjectively from people's individual and collective experience in a place], so Chapter Six deals with a co-emergent interpretation of the data gathered. Based on that interpretation, recommendations for urban open space policy generally, and the Avis dam environment specifically, are made in Chapter Seven. AFRIKAANS : Omgewingssielkunde (wat gemoeid is met die mede-beinvloedings tussen mense en plekke) het van sy vroegste jeug aandag benodig ten opsigte van werklike verband asook maatskaplike toepaslikheid. Daar was nog altyd klem op navorsing ten opsigte van daadwerklike probleme binne die verband van ‘n betekenisvolle teorie asook op die uitslae wat potensiaal het vir die individualis sowel as die beleidsbepalers en beleidsuitvoerders. Hierdie omgewingssielkundestudie gaan oor hoe groen oop spasies moontlik kan bydra tot kwaliteit van lewensgehalte in die stad oor die algemeen. Dit gaan ook oor ‘n besondere, geliefde stedelike oop ruimte in Namibia se hoofstad, Windhoek, nl. die Avisdamomgewing, wat voortdurend ‘n teiken is vir bedryfsontwikkeling. Tans beskik die Munisipaliteit van Windhoek nie oor ‘n welsaamgestelde beleid oor oop ruimtes nie en moontlik ontbreek ook by hulle die nodige begrip van die betekenis van die dam vir sy verbruikers. Hierdie studie be-oog om ‘n bydrae in die beleidsbepalings van altwee leemtes te lewer. Die toepaslikheid van navorsingsbevindings in die ontwikkeling van openbare beleid en gemeenskapsbemiddeling hang baie van die gepastheid van die metodologie en teorië (Stokols, 1991)2 af. Hierdie studie begin met ‘n bespreking oor sistemiese en ekosistemiese denke (Hoofstuk Twee). Hulle is as die leidende metateorieë gekies, nie alleen vir hul erkenning van die onontkombare verband tussen persone en hul omgewing nie, maar ook vir hulle persoonlike aantrekkingskrag. In Hoofstuk Drie word teorië en voorbeelde bestudeer wat verenigbaar is met sistemiese denke en wat help om die potensiële positiewe psigo-sosiale en sosio-ekonomiese rolle van stedelike oop ruimtes oor die algemeen te verstaan, asook hoe om die omvang van die potensiaal van ‘n spesifieke oop ruimte te kan waardeer en te kan beskryf. In Hoofstuk Vier word die implikasies van die sistemiese/eko-sistemiese metateorie vir hierdie studie se metodologie en navorsingsplan bespreek. Die dataversamelingsmetodes wat uit waarneming en onderhoude bestaan, word in Hoofstuk Vyf hanteer. Ekosistemiese denkers glo nie dat feite “gevind” word nie (dit is nie objektiewelik daar nie maar ontstaan subjektiewelik deur persone se individuele en gesamentlike ondervindinge van ‘n plek), dus word die vertolking van die saamgestelde data in Hoofstuk Ses bespreek. In die lig van dié vertolking word aanbevelings 2 Stokols, D. (1991). Conceptual strategies of environmental psychology. In D. Stokols& I. Altman (Eds), Handbook of environmental psychology, Vol. 1 (pp. 41-70). New York: John Wiley. vir stedelike oopruimtebeleid in die algemeen asook spesifiek vir die Avisdam omgewing in Hoofstuk Sewe hanteer.
Dissertation (MA)--University of Pretoria, 1998.
Psychology
unrestricted

The objective of this thesis is to investigate the flow conditions that lead to coarse grain entrainment at near incipient motion conditions. Herein, a new conceptual approach is proposed, which in addition to the magnitude of hydrodynamic force or flow power, takes into account the duration of the flow event. Two criteria for inception of grain entrainment, namely the critical impulse and critical energy concepts, are proposed and compared. These frameworks adopt a force or energy perspective, considering the momentum or energy transfer from each flow event to the particle respectively, to describe the phenomenon. A series of conducted mobile particle experiments, are analyzed to examine the validity of the proposed approaches. First a set of bench-top experiments incorporates an electromagnet which applies pulses of known magnitude and duration to a steel spherical particle in a controlled fashion, so as to identify the critical level for entrainment. The utility of the above criteria is also demonstrated for the case of entrainment by the action of turbulent flow, via analysis of a series of flume experiments, where both the history of hydrodynamic forces exerted on the particle as well as its response are recorded simultaneously. Statistical modeling of the distribution of impulses, as well as conditional excess impulses, is performed using distributions from Extreme Value Theory to effectively model the episodic nature of the occurrence of these events. For the examined uniform and low mobility flow conditions, a power law relationship is proposed for describing the magnitude and frequency of occurrence of the impulse events. The Weibull and exponential distributions provide a good fit for the time between particle entrainments. In addition to these statistical tools, a number of Adaptive Neuro-Fuzzy Inference Systems employing different input representations are used to learn the nonlinear dynamics of the system and perform statistical prediction. The performance of these models is assessed in terms of their broad validity, efficiency and forecast accuracy. Even though the impulse and energy criteria are deeply interrelated, the latter is shown to be advantageous with regard to its performance, applicability and extension ability. The effect of single or multiple highly energetic events carried by certain coherent flow structures (mainly strong sweep events) with regard to the particle response is also investigated.
Ph. D.

The relaxation of international boundaries has enabled the globalisation of markets making available an ever increasing number of specialised suppliers and markets. Inevitably this results in supply chains sharing suppliers and customers reflected in a network of relationships. Within this context firms buyers configure their supply relationships based on their perception of supply risk. Risk is managed by either increasing trust or commitment or by increasing the number of suppliers. Increasing trust and commitment facilitates collaboration and reduces the propensity for a supplier to exit the relationship. Conversely, increasing the number of suppliers reduces dependency and increases the ease of making alternative supply arrangements. The emergent network of relationships is dynamic and complex, and due in no small part to the influence of inventory management practices, tightly coupled. This critical organization of the network describes a system that contrary to existing supply chain conceptualisation exists far from equilibrium, requiring a different more appropriate theoretical lens through which to view them. This thesis adopts a Complex Adaptive Systems (CAS) perspective to position supply networks as tightly coupled complex systems which according to Normal Accident Theory (NAT) are vulnerable to disruptions as a consequence of normal operations. The consequential boundless and emergent nature of supply networks makes them difficult to research using traditional empirical methods, instead this research builds a generalised supply network agent based computer model, allowing network constituents (agents) to take autonomous parallel action reflecting the true emergent nature of supply networks. This thesis uses the results from a series of carefully designed computer experiments to elucidate how supply networks respond to a variety of market structures and permitted agent behaviours. Market structures define the vertical (between tier) and horizontal (within tier) levels of price differentiation. Within each structure agents are permitted to autonomously modify their prices (constrained by market structure) and collaborate by sharing demand information. By examining how supply networks respond to different permitted agent behaviours in a range of market structures this thesis makes 4 contributions. Firstly, it extends NAT by incorporating the adaptive nature of supply network constituents. Secondly it extends supply chain management by specifying supply networks as dynamic not static phenomena. Thirdly it extends supply chain risk management through developing an understanding of the impact different permitted behaviour combinations on the networks vulnerability to disruptions in the context of normal operations. Finally by developing the understanding how normal operations impact a supply networks vulnerability to disruptions it informs the practice of supply chain risk management.

This research explores the development of a framework appropriate to evaluate the readiness of a university to engage with knowledge management. Many universities are evolving from traditional bureaucratic, hierarchical structures to become more flexible, adaptable, commercially viable and competitive and knowledge management is becoming increasingly important in this respect. An over view of knowledge management clarifies what the concept is, and a critical review of current frameworks and models identifies gaps and weaknesses specifically in relation to empirical testing, theoretical underpinning and a holistic approach. This framework addresses those gaps and weaknesses and draws on organisational management, strategy, structure and culture, and systems thinking to ensure a holistic approach. These key elements provide the basis upon which a knowledge management framework is developed. A Soft Systems Methodological approach with a critical dimension is used to underpin this research because enquiry into organisational problem situations is complex and unstructured, based on human activity and social systems. The framework is innovative and offers contributions to knowledge because it: - is a new development within the domain of knowledge management. (it is intended to help evaluate the readiness of universities to engage in knowledge management); - provides a new application of critical systems thinking (critical systems thinking is applied to knowledge management); - uses a new synthesis (it was developed using a synthesis of soft systems principles, knowledge management concepts, and organisational theory); - enables organisations to consider their situations in new ways (by enabling self-critique of KM readiness); - offers new insights into the domain of knowledge management by means of the comprehensive and substantial literature review that helped its development.

This research explores how an open strategy approach can be used to manage organisational legitimacy in a pluralistic context, characterised by the competing demands of key stakeholders. Open strategy demonstrates an interest in strategising processes becoming more inclusive and transparent (Hautz et al., 2016). Open strategy work to date has focused on its uses and implications, and how strategic inclusion and transparency are being displayed in different organisational contexts. Much open strategy literature also associates the central purpose of open strategising activity with organisations seeking to manage legitimacy (e.g. Chesbrough and Appleyard, 2007; Whittington et al., 2011; Tavakoli et al., 2017), particularly through ensuring that their actions are desirable in the opinion of key stakeholders (Suchman, 1995). Whilst a small number of studies have explicitly focused on open strategy and legitimacy, these do not go beyond illuminating legitimacy as a potential effect (Gegenhuber and Dobusch, 2017) or outcome (Luedicke et al., 2017). Absent has been research attempting to specifically understand open strategy as a process of legitimation (Uberbacher, 2014), and there remains a need to unpack and elevate the significant potential of open strategy approaches for managing legitimacy further. To address this gap, this research presents an in-depth single case analysis of an organisation undertaking the development of a new four-year strategic plan using an open strategy approach. A number of data collection methods were used, including completion of 30 semi-structured interviews, participant observations, and collection of significant social media and documentation data, to explicate the concepts of open strategy and organisational legitimacy, addressing the question; How does an open strategy approach represent a process of legitimation for managing the competing demands of organisational stakeholders? . A pluralistic context, a UK-based professional body, is the basis for the empirical work. It is acknowledged that interrogating the intricacies of strategising in pluralistic contexts, and the inherent competing demands of stakeholders, might offer new perspectives, and a useful means of expanding the contextual base of practice-based strategy work (Jarzabkowski and Fenton, 2006). However, studies of open strategy in pluralistic contexts remain near non-existent in the literature (Lusiani and Langley, 2013). In the organisational legitimacy literature, there is much discourse on how legitimacy is managed and gained through specific legitimation processes and strategies, and increasingly such a focus has been adopted to recognise how organisations might manage legitimacy demands in contexts defined by plurality, amidst diffuse power and divergent objectives (Denis et al., 2007). In this study, a practice-based activity theory framework is used (Jarzabkowski 2005; Jarzabkowski and Wolf, 2015) to explore legitimacy in relation to organisational direction and priorities, and as a means of redefining the organisation s core goals in an enactment of strategic openness. The work here conceptualises how the case organisation has adopted a plethora of open strategising practices for legitimacy effects (Suddaby et al., 2013), providing a detailed account of how different dynamics of open strategising activity connect to specific forms of legitimation over time. The findings indicate that different open strategy dynamics represent the case organisation switching between distinct approaches to legitimation, as a means of managing the competing legitimacy demands of organisational stakeholders in a flow of activity. Through this narrative, a greater perception of legitimation as a core purpose of open strategy is provided. Overall, this research offers an important contribution by accentuating the principal relevance of organisational legitimacy in open strategising, particularly through elevating legitimacy beyond being understood as an effect or outcome in open strategy work. Further, this more explicitly brings open strategy into close alignment with the organisational legitimacy literature and its theoretical conceptions (Lawrence et al., 2009; Suddaby et al., 2013), which is imperative for understanding the potential importance of open strategy as a means of legitimation.

In a complex adaptive system, diverse agents perform various actions without adherence to a predefined structure. The achievement of collaborative actions will be the result of continual interactions among them that shape a dynamic network. Agents may form an ad hoc organization based on the dynamic network of interactions for the purpose of achieving a long-term objective, which we termed a Network Organization (NO). Fervent and agile communication on social networking sites provides opportunities for potential issues to trigger individuals into individual actions as well as the attraction and mobilization of like-minded individuals into an NO that is both physically and virtually emergent. Examples are the rapid pace of Arab Spring proliferation and the diffusion rate of the Occupy Movement. We are motivated by a spontaneously formed NO as well as the quality of plasticity that enables the organization to change rapidly to describe an NO. Thus, we present a paradigm that serves as a reference model for organizations of socially networked individuals. This paradigm suggests modular components that can be combined to form an ad hoc network organization of agents. We touch on how this model accounts for external change in an environment through internal adjustment. For the predominant influences of the network substrate in an NO, multiple effects of it have an impact on the NO behaviors and directions. We envisioned several dimensions of such effects to include synergy, social capital, externality, influence, etc. A special focus in this work is measuring synergy and social capital as two predominant network effects. Synergy is perceived as different modalities of compatibility among agents when performing a set of coherent and correspondingly different actions. When agents are under no structural obligation to contribute, synergy is quantified through multiple forms of serendipitous agent chosen benevolence among them. The approach is to measure four types of benevolence and the pursuant synergies stemming from agent interactions. Social capital is another effect of networking that describes the accumulation of positive values of social flow and perceived trust plus abundance of communication over the common topic of NO. We provide measurement of social capital based on an agents’ expected benevolence. We examine those two effects in two different case studies — one case of a virtual organization and another of a real world terrorist organization — that best illustrate the main tenets of our conceptualization.

Thesis (Ph. D.)--Georgia State University, 2007.
Title from file title page. Philo A. Hutcheson, committee chair; Theophus Smith, Susan Talburt, Douglas R. Davis, committee members. Electronic text (355 p.) : digital, PDF file. Description based on contents viewed Nov. 1, 2007. Includes bibliographical references (p. 348-355).

In the first part of the dissertation, we develop a theoretical approach to analyze nonlinear spectroscopy experiments based on the formalism of quantum state (QST) and process tomography (QPT). In it, a quantum system is regarded as a black box which can be systematically tested in its performance, very much like an electric circuit is tested by sending a series of inputs and measuring the corresponding outputs, but in the quantum sense. We show how to collect a series of pump-probe or photon-echo experiments, and by varying polarizations and frequency components of the perturbations, reconstruct the quantum state (density matrix) of the probed system for a set of different initial conditions, hence simultaneously achieving QST and QPT. Furthermore, we establish the conditions under which a set of two-dimensional optical spectra also yield the desired results. Simulations of noisy experiments with inhomogeneous broadening show the feasibility of the protocol. A spin-off of this work is our suggestion of a witness that distinguishes between spectroscopic time-oscillations corresponding to vibronic only coherences against their electronic counterparts. We conclude by noting that the QST/QPT approach to nonlinear spectroscopy sheds light on the amount of quantum information contained in the output of an experiment, and hence, is a convenient theoretical and experimental paradigm even when the goal is not to perform a full QPT. In the second part of the thesis, we discuss a methodology to study the electronic dynamics of complex molecular systems, such as photosynthetic units, in the framework of time-dependent density functional theory (TD-DFT). By treating the electronic degrees of freedom as the system and the nuclear ones as the bath, we develop an open quantum systems (OQS) approach to TD-DFT. We formally extend the theoretical backbone of TD-DFT to OQS, and suggest a Markovian bath functional which can be readily included in electronic structure codes.

One of the main goals of the theory of open quantum systems is to devise methods which help preserve the quantum properties of a system interacting with its environment. One possible pathway to achieve this goal is to use non-Markovian reservoirs, characterized by information backflows and revivals of certain quantum properties. These reservoirs usually require advanced engineering techniques, which may turn their implementation impractical. In this dissertation we propose an alternative technique: the injection of a classical colored noise, which induces the desired quantum non-Markovianity. In order to do that, we investigate the dynamics of a quantum system interacting with its surrounding environment and under the injection of a classical stochastic colored noise. A time-local master equation for the system is derived by using the stochastic wave function formalism and functional calculus. Afterwards, the non-Markovianity of the evolution is detected by using the Andersson, Cresser, Hall and Li measure, which is based on the decay rates of the master equation in canonical Lindblad-like form. Finally, we evaluate the measure for three different colored noises and study the interplay between environment and noise pump necessary to induce quantum non-Markovianity, as well as the energy balance of the system.
Um dos objetivos principais da teoria de sistemas quânticos abertos é desenvolver métodos que ajudem a preservar as propriedades quânticas de um sistema interagindo com o ambiente. Um possível caminho para alcançar essa meta é usar reservatórios não-Markovianos, caracterizados por refluxos de informação e renascimento de certas propriedades quânticas. Esses reservatóris geralmente requerem o uso de técnicas avançadas de engenharia, o que pode tornar sua implementação impraticável. Nessa dissertação nós propomos uma técnica alternativa: a injeção de um ruído colorido clássico, o qual induz a desejada não-Markovianidade quântica. De modo a fazer isso, nós investigamos a dinâmica de um sistema quântico interagindo com o ambiente e sob a injeção de um ruído colorido clássico estocástico. Uma equação mestra local no tempo é derivada usando-se do formalismo da função de onda estocástica e de técnicas de cálculo funcional. Após isso, a não-Markovianidade da evolução é detectada através da medida de Andersson, Cresser, Hall e Li, a qual é baseada nos coeficientes da equação mestra na forma de Lindblad-like canônica. Finalmente, nós calculamos a medida para três diferentes ruídos coloridos e estudamos a relação entre o ambiente e o bombeio estocástico necessária para induzir não-Markovianidade quântica, assim como o balanço de energia do sistema.

Cette thèse analyse certains aspects de la dynamique hors équilibre de systèmes quantiques unidimensionnels lorsqu’ils sont soumis à des champs externes dépendant du temps. Nous considérons plus particulièrement le cas des forçages périodiques, et le cas d’une variation temporelle lente d’un paramètre de l’Hamiltonien qui permet de traverser une transition de phase quantique. La première partie contient une présentation des notions, des modèles et des outils nécessaires pour comprendre la suite de la thèse, avec notamment des rappels sur les modèles quantiques critiques (en particulier sur les chaines de spin et sur le modèle de Bose-Hubbard), le mécanisme de Kibble-Zurek, et la théorie de Floquet. Ensuite, nous étudions la dynamique hors équilibre des gaz de Tonks-Girardeau dans un potentiel harmonique dépendant du temps par différentes techniques : développements perturbatifs, diagonalisation numérique exacte et solutions analytiques exactes basées sur la théorie des invariants dynamiques d’Ermakov-Lewis. Enfin, nous analysons la dynamique hors équilibre des systèmes quantiques ouverts markoviens soumis à des variations périodiques des paramètres du système et de l’environnement. Nous formulons une théorie de Floquet afin d’obtenir des solutions exactes des équations de Lindblad périodiques. Ce formalisme de Lindblad-Floquet est utilisé pour obtenir une caractérisation exacte du fonctionnement en temps fini des machines thermiques quantiques
This thesis analyzes some aspects regarding the dynamics of one-dimensional quantum systems which are driven out-of-equilibrium by the presence of time- dependent external fields. Among the possible kinds of driven systems, our focus is dedicated to the slow variation of a Hamiltonian’s parameter across a quantum phase transition and to the case of a time-periodic forcing. To begin with, we prepare the background and the tools needed in the following. This includes a brief introduction to quantum critical models (in particular to the xy spin chain and to the Bose-Hubbard model), the Kibble-Zurek mechanism and Floquet theory. Next, we consider the non-equilibrium dynamics of Tonks-Girardeau gases in time-dependent harmonic trap potentials. The analysis is made with different techniques: perturbative expansions, numerical exact diagonalization and exact methods based on the theory of Ermakov-Lewis dynamical invariants. The last part of the thesis deals instead with the non-equilibrium dynamics of markovian open quantum systems subject to time-periodic perturbations of the system parameters and of the environment. This has led to an exact formulation of Floquet theory for a Lindblad dynamics. Moreover, within the Lindblad-Floquet framework it is possible to have an exact characterization ofthe finite-time operation of quantum heat-engines

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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
A teoria de informação e computação quântica é uma área de pesquisa que vem crescendo de maneira acentuada nos últimos anos devido aos inúmeros avanços tecnológicos que a acompanham. Neste mestrado começamos nossos estudos nesta área de pesquisa onde nos introduzimos e aprofundamos em seus aspectos intrigantes e peculiares. Dada nossa formação inicial na área de ciências da computação, inicialmente nos dedicamos a entender os aspectos fundamentais da mecânica quântica, assim como da teoria de informação e computação quântica. Focamos principalmente nos sistemas quânticos abertos, visto que o maior obstáculo a ser superado para o desenvolvimento destes computadores é o efeito deletério do meio ambiente. A princípio, concentramos nossos estudos nos ditos processos não-Markovianos, que apresentam efeitos de memória. Aprendemos sobre as novas medidas de não-Markovianidade, principalmente as medidas baseadas na dinâmica do emaranhamento e na dinâmica da informação mútua. Conseguimos publicar nosso primeiro resultado, onde provamos a inequivalência destas duas medidas de não-Markovianidade. De fato, mostramos que tais medidas, em geral, podem discordar sobre o tipo de processo dissipativo, sendo que uma pode reconhecê-lo como Markoviano enquanto outra pode reconhecê-lo como não-Markoviano. Como mostramos, esta inequivalência está diretamente relacionada com o refluxo de informação do meio ambiente para o sistema, e como mensuramos tal informação nestas duas medidas distintas de não-Markovianidade. Finalmente, na fase final de nossos estudos, tivemos como objetivo encontrar um meio de otimizar o controle das operações lógicas. Especificamente, trabalhamos com um método numérico utilizado em sistemas fechados para otimizar sistemas abertos Markovianos. Observamos que a eficácia deste método depende do tipo e intensidade da interferência do ambiente e das condições iniciais do sistema, obtendo melhores resultados em casos específicos.
Quantum information theory and computation is a field of research that has been growing acutely in the past few years due to the many technological improvements it follows. In this masters’ course, we began our studies in this area of research where we were introduced and immersed in its intriguing and peculiar aspects. Given our initial formation in computer science, we initially dedicated ourselves to understanding the fundamentals of quantum mechanics, as well as of information theory and quantum computation. Our main focus were open quantum systems, since the greatest obstacle to the development of these computers is the harmful effect of the environment. At first, we concentrated our studies in the so called non-Markovian processes, that show memory effects. We learned about the new non-Markovianity measurements, mainly those based on the dynamics of entanglement and mutual information. We managed to publish our first result, where we proved the inequivalence of these two measurements of non-Markovianity. Indeed, we showed that such measurements, in general, can disagree about the dissipative process, so that one can regard it as Markovian and the other as non-Markovian. As we demonstrated, this inequivalence is directly related to the information back-flow from the environment to the system, and how this information is measured by each of the two distinct measurements. Finally, in the last stage of our studies, our goal was to find a way to optimize the control of the logical operations. Specifically, we worked with a numeric method used in closed systems to optimize Markovian open systems. We have observed that the effectiveness of this method depends on the type and intensity of the interference of the environment and of its initial conditions, attaining better results for specific cases.

Zusammenfassung in PostScript In dieser Arbeit wird die photoinduzierte Dynamik offener Molekularsysteme unter dem Einfluß intensiver und ultrakurzer Laserpulse untersucht. Die Anregung eines Moleküls durch einen optischen ultrakurzen Laserpuls führt zu Übergängen zwischen verschiedenen elektronischen Zuständen. Dieser Anregungsprozeß wird begleitet von dissipativen Vorgängen wie Energie-- und Phasenrelaxation. Die Beschreibung dieser photoinduzierten Dynamik erfolgt mit Hilfe der Methode der Dichtematrixtheorie. Dabei zeigt die Ableitung der Quanten--Master--Gleichung im Rahmen des Projektionsoperator--Formalismus, daß die wirkenden äußeren Felder einmal direkt im reversiblen Anteil der Bewegungsgleichung auftreten, aber auch einen indirekten Einfluß über den die Dissipation beschreibenden Dissipations--Superoperator ausüben. In dieser Arbeit wird zum ersten Mal die durch ultrakurze Laserpulse induzierte Feldabhängigkeit des Dissipations--Superoperators berücksichtigt. Im Rahmen der Darstellung der Quanten--Master--Gleichung im Floquetbild kann eine anschauliche Deutung dieses feldabhängigen Effektes gegeben werden: die die Dissipation beschreibende frequenzabhängige Spektraldichte der Umgebungsmoden wird feldabhängig bei verschiedenen Frequenzen abgefragt. Analytische Untersuchungen zum Zwei--Niveau--System zeigen, daß die Feldabhängigkeit dann relevant wird, wenn die Pulslänge vergleichbar ist mit der Zeitskala, auf der die Autokorrelationsfunktion der Umgebungsfreiheitsgrade abklingt. Um den Einfluß auf experimentelle Größen zu untersuchen, wird ein zweifarbiges Pump--Test--Experiment zum Laserfarbstoffmolekül IR 125 betrachtet, bei welchem die spektral und zeitlich aufgelöste Transmission auf einer Femtosekunden-- und Pikosekunden--Zeitskala gemessen wurde. Im Rahmen des Modells einer effektiven Schwingungsmode wird eine Anpassungsrechnung an das Experiment vorgenommen. Dabei wird zunächst die Standard-Redfield-Theorie verwendet, um ein Referenzmodell zu gewinnen. Es gelingt, eine gute Übereinstimmung mit dem Experiment zu erreichen. Die exakte Berücksichtigung des Einflusses der internen Konversion zwischen den angeregten elektronischen Zuständen führt zu einem Anstieg der Transmission innnerhalb einer Pikosekunde. Es ist notwendig, die Dichtematrixgleichungen exakt zu lösen, da eine vergleichende Untersuchung mit Hilfe der nichtlinearen Suszeptibilität dritter Ordnung eine deutliche Abweichung zum exakten Resultat zeigt. Ausgehend vom Referenzfall feldunabhängiger Dissipation wird dann die Feldabhängigkeit der Relaxationsraten bestimmt sowie der Einfluß auf Observablen wie der relativen Transmission untersucht. In Übereinstimmung mit den analytischen Ergebnissen zeigt sich, daß der feldabhängige Effekt am größen ausgeprägt ist, wenn die Pulslänge kleiner als die Korrelationszeit der Umgebungsfreiheitsgrade wird und die wirkenden Felder hinreichend intensiv sind.Damit wird eine Kontrolle von Dissipation möglich. Ein Einfluß des feldabhängigen Effektes auf experimentelle Observablen wird vorhergesagt.
abstract in PostScript This thesis investigates the influence of intense and ultrashort laser pulses on the photoinduced dynamics of open molecular systems. The excitation of a molecule by an optical ultrashort laser pulse induces transitions between different electronic states. This excitation process is accompanied by the dissipative processes of energy and vibrational relaxation. This excitation process is described within the method of the density matrix theory. Thereby, the derivation of the quantum master equation in the framework of the projection operator formalism demonstrates that the external fields are present in the reversible part of the equation of motion and also exert an indirect influence by acting on the dissipation superoperator which accounts for dissipation. In this thesis the field--dependency of the dissipation superoperator which is induced by the external fields is considered for the first time. By a representation of the quantum master equation in the Floquet picture, an interpretation of this field--dependent effect can be given: the frequency--dependent spectral density of the environmental modes which describe dissipation is determined at different field--dependent frequencies. Analytical investigations for the two level system demonstrate that the field dependence becomes relevant if the pulse length is comparable with the time scale on which the autocorrelation function of the environmental degrees of freedom decays.To investigate the influence on experimental quantities, a two--color pump--probe experiment for the laser dye molecule IR 125 is considered for which the spectrally and temporally resolved transmission on a femtosecond and picosecond time scale has been measured. Within the model of one effective vibrational mode the experimental data is fitted. The standard Redfield theory is used to provide a reference model. A high degree of concurrence between the theory and the results of the experiment is achieved. The exact treatment of internal conversion between the excited electronic states leads to a rise in transmission within one picosecond. It is necessary to solve the density matrix equations exactly because a comparative investigation with the nonlinear susceptibility of third order leads to a clear viation from the exact result. Starting from the reference case of field--independent dissipation, the field--dependency of the relaxation rates is determined and the influence on observables for example the relative transmission is investigated. The analytical results show that the field--dependent effect is strongest if the pulse length becomes smaller than the correlation time of the environmental modes and if the acting fields are sufficiently strong. Thereby, a control of dissipation becomes possible. An influence of the field--dependent effect on experimental observables is predicted.

O processamento de informação quântica requer medidas, muitas vezes precedidas devoluções unitárias. Uma descrição realista de um computador quântico também deve levar em conta que o sistema interage com um ambiente externo - distinto do observador - que o remove de sua evolução ideal, gerando erros. Neste trabalho, fazemos um estudo da dinâmica de sistemas quânticos observados múltiplas vezes ou continuamente, enquanto interagem com ambientes externos. Para tanto, empregamos uma equação mestra híbrida, que permite modelar uma interação contínua e markoviana do sistema com o medidor, enquanto o ruído do ambiente apresenta características não markovianas. O estudo da dinâmica de uma medida contínua ruidosa revela que o sistema melhor preserva suas populações iniciais quando é realizada a medida de uma observável que não comuta com os operadores do ruído produzido pelo ambiente. Estes resultados, já conhecidos para o caso simples de um qubit de memória interagindo com o vácuo, são generalizados para uma temperatura inicial superior a zero e para um qubit submetido a uma porta quântica. A universalidade destes fenômenos de preservação da população inicial permite fazer analogia com o efeito Zenão quântico. Mantendo o mesmo formalismo, mas adaptando a interação com o ambiente para descrever um decaimento verificamos que o efeito Zenão quântico é observado para acoplamentos fracos com o ambiente. Tratamos também de como tal conhecimento sobre a preservação das populações pela medida auxilia na elaboração de melhores formas de preservar a informação em códigos quânticos. Com o auxílio da teoria das medidas fracas, propomos um possível método experimental simples para o teste da validade dos modelos de descrição de medidas contínuas. Com este estudo da dinâmica de uma medida quântica, esperamos elucidar questões de ordem prática no processamento de informação quântica, assim como ajudar no melhor entendimento de questões fundamentais, como o postulado da medida.
The processing of quantum information requires measurements, often preceded by unitary evolutions. A faithful description of a quantum computer should also take into account that the system interacts with an external environment - other than the observer - that removes it from its ideal evolution, causing errors. Here, we study the dynamics of quantum systems observed multiple times or continuously, while they interact with external environments. To do this, we employ a hybrid master equation, which allows us to model a continuous, Markovian interaction between the system and the measurement apparatus, while the environmental noise presents non-Markovian features. This study of the dynamics of the noisy continuous measurement reveals that the system better preserves its initial populations when the observable measured does not commute with the environmental noise operators. These results, already known for the simpler case of a memory qubit interacting with vacuum, are generalized for an initial temperature above zero and a qubit undergoing a quantum gate. The universality of these phenomena of preservation of the initial populations allows an analogy with the Quantum Zeno Effect. Keeping the same formalism, but adapting the environmental interaction to describe a decay, we verify that the quantum Zeno effect is observed for weak coupling with the environment. We also deal with how the knowledge about the preservation of the populations by the measurement helps in creating better ways to preserve the information in quantum codes. With the help of the weak measurement theory, we propose a simple experimental method to test the validity of models that describe a continuous measurement. With this study of the dynamics of a quantum measurement, we hope to help solve practical issues in quantum information processing, as well as provide greater insight into fundamental questions, such as the measurement postulate.

Denial of service attacks (DoS) are a common threat to many online services. These attacks aim to overcome the availability of an online service with massive traffic from multiple sources. By spoofing legitimate users, an attacker floods a target system with a high quantity of packets or connections to crash its network resources, bandwidth, equipment, or servers. Packet filtering methods are the most known way to prevent these attacks via identifying and blocking the spoofed attack from reaching its target. In this project, the extent of the DoS attacks problem and attempts to prevent it are explored. The attacks categories and existing countermeasures based on preventing, detecting, and responding are reviewed. Henceforward, a neural network learning algorithms and statistical analysis are utilized into the designing of our proposed packet filtering system.

Die Arbeit ist der regelungstheoretischen Betrachtung von mechanischen Systemen mit mehr Freiheitsgraden als Stellgrößen gewidmet. Dabei werden Aspekte aus den Teilgebieten Modellbildung, Systemanalyse, Steuerungsentwurf und Reglerentwurf behandelt. Den Ausgangspunkt bilden die aus dem Lagrange-Formalismus resultierenden Bewegungsgleichungen, für welche neben verschiedene partiell linearisierten Zustandsdarstellungen auch eine spezielle Byrnes-Isidori-Normalform eingeführt wird. Im Unterschied zu einer früher vorgeschlagenen ähnliche Normalform existiert diese "Lagrange-Byrnes-Isidori-Normalform" immer. Weiterhin wird die bedeutende Eigenschaft der differentiellen Flachheit im Zusammenhang mit mechanischen Systemen untersucht. Die bestehende Lücke zwischen den bekannten notwendigen und hinreichenden Flachheitsbedingungen bildet die Motivation zur Anpassung der Regelflächenbedingung auf mechanische Systeme in Lagrange-Byrnes-Isidori-Normalform. Parallel dazu wird die Flachheitsanalyse auf Basis des sogenannten Variationssystems betrachtet. Dabei handelt es sich um ein System von 1-Formen, die durch Anwendung der äußeren Ableitung auf die impliziten Systemgleichungen entstehen. Äquivalent dazu können auch die in einer rechteckigen Polynommatrix bezüglich des Zeitableitungsoperators zusammengefassten Koeffizienten der Basisformen untersucht werden. Die Flachheit eines Systems ist nun gerade äquivalent zur Existenz einer unimodularen Vervollständigung dieser Matrix, welche zudem noch eine bestimmte Integrabilitätsbedingung erfüllen muss. Durch Anwendung des Satzes von Frobenius können aus diesen in der bisherigen Formulierung nur schwer überprüfbaren Bedingungen deutlich einfachere hergeleitet werden. Für den Eingrößenfall ergibt sich dadurch eine erheblich Verringerung des Rechenaufwandes im Vergleich zum Referenzansatz. Im Mehrgrößenfall ist die Situation komplizierter: Durch das Fallenlassen der Unimodularitätsforderung und die Ausnutzung der speziellen Struktur mechanischer Systeme erhält man eine neue notwendige Bedingung für Flachheit, welche sich in endlich vielen Schritten auswerten lässt. Allerdings konnte mit dieser die vermutete Nichtflachheit für die untersuchten mechanischen Beispielsysteme nicht nachgewiesen werden. Einen weiteren Untersuchungsgegenstand bildet das Konzept der Konfigurationsflachheit. Für diese Eigenschaft ist gefordert, dass ein flacher Ausgang existieren muss, der nur von den Konfigurationskoordinaten abhängt. Basierend auf theoretischen Überlungen und dem Fehlen von Gegenbeispielen wird die Hypothese aufgestellt, dass für konservative mechanische Systeme Flachheit und Konfigurationsflachheit äquivalent sind. Für lineare mechanische Systeme kann diese Hypothese mit Hilfe der Kronecker-Normalform von Matrizenscharen verifiziert werden. Bezüglich des Entwurfs von Solltrajektorien werden neben der Darstellung bekannter Verfahren für lineare und für flache Systeme zwei weitere Ansätze genauer diskutiert. Der erste basiert auf der numerischen Lösung des aus dem Steuerungsentwurf resultierenden Randwertproblems. Dazu wird ein angepasstes Kollokationsverfahren konstruiert, welches die Elimination von Systemgrößen durch die explizite Berücksichtigung von Integratorketten ermöglicht, die bei partiell linearisierten Systemen stets auftreten. Unter bestimmten Bedingungen bewirkt dies eine erhebliche Reduktion der Rechenzeit. Der zweite Ansatz betrachtet die Überführung zwischen zwei Ruhelagen und beruht auf der Zeitumkehrsymmetrie, die alle konservativen mechanischen Systeme aufweisen. Er besteht aus mehreren Schritten: Zunächst wird für beide Ruhelagen eine Rückführung mit möglichst großem Attraktivitätsgebiet entworfen. Danach wird das System simulativ ausgehend von der Zielruhelage in der Startruhelage stabilisiert. Die so erhaltene Eingangstrajektorie kann dann bezüglich der Zeit invertiert werden, um das System aus der Startruhelage in die Nähe der Zielruhelage zu überführen, wo schließlich der entsprechende Regler aktiviert wird. In praktischen Realisierungen von unteraktuierten Regelungssystemen treten auf Grund von Effekten wie trockener Reibung und Getriebespiel oft Dauerschwingungen mit schwer vorhersagbaren und beeinflussbaren Parametern auf. Als Alternative zur klassischen Stabilisierung einer (theoretischen) Ruhelage wird deshalb eine Rückführung hergeleitet, welche für ein gegebenes lineares System einen stabilen Grenzzyklus mit vorgebbarer Frequenz und Amplitude asymptotisch stabilisiert.

In this thesis, the implementation of the incremental scheme for open-shell systems with unrestricted Hartree-Fock reference wave functions is described. The implemented scheme is tested within robustness and performance with respect to the accuracy in the energy and the computation times. New approaches are discussed to implement a fully automated incremental scheme in combination with the domain-specific basis set approximation. The alpha Domain Partitioning and Template Equalization are presented to handle unrestricted wave functions for the local correlation treatment. Both orbital schemes are analyzed with a test set of structures and reactions. As a further goal, the DSBSenv orbital basis sets and auxiliary basis sets are optimized to be used as environmental basis in the domain-specific basis set approach. The performance with respect to the accuracy and computation times is analyzed with a test set of structures and reactions. In another project, a scheme for the optimization of auxiliary basis sets for uranium is presented. This scheme was used to optimize the MP2Fit auxiliary basis sets for uranium. These auxiliary basis enable density fitting in quantum chemical methods and the application of the incremental scheme for systems containing uranium. Another project was the systematical analysis of the binding energies of four water dodecamers. The incremental scheme in combination with the CCSD(T) and CCSD(T)(F12*) method were used to calculate benchmark energies for these large clusters.

We show that the nonadditive open systems can be studied in a consistent manner by using a generalized version of S-theorem. This new generalized S-theorem can further be considered as an indication of self-organization in nonadditive open systems as prescribed by Haken. The nonadditive S-theorem is then illustrated by using the modified Van der Pol oscillator. Finally, Tsallis entropy as an equilibrium entropy is studied by using Boltzmann's method of orthodes. This part of dissertation shows that Tsallis ensemble is on equal footing with the microcanonical, canonical and grand canonical ensembles. However, the associated entropy turns out to be Renyi entropy.

Denna uppsats behandlar ämnet internkommunikation. Vi har valt att genomföra en undersökning om Polismyndigheten Värmlands internkommunikation då de innehar ett stort ansvar att bevara trygghet och säkerhet i samhället. Polismyndigheten har även stora krav på sig idag gällande dialog och grad av kommunikation inom organisationen för att effektivisera det polisiära arbetet. Syftet med denna uppsats är att erhålla en insikt om den interna kommunikationens funktion och hur den gestaltas utifrån chefernas och de anställdas perspektiv. I denna uppsats använder vi oss utav relevanta teorier inom organisationskommunikation, internkommunikation, organisationsidentitet, organisationskultur och kommunikationsmodeller. Vårt tillvägagångssätt för att besvara uppsatsens syfte var att använda oss utav två skräddarsydda frågeställningar för att möjliggöra en helhetsbild och en djupare insikt på våra utvalda teoretiska områden. ”Hur upplever cheferna på polismyndigheten Värmland internkommunikationen?” ”Hur upplever de anställda på polismyndigheten Värmland internkommunikationen?” I denna undersökning använde vi oss av kvalitativa samtalsintervjuer och en kvalitativ fokusgrupp. Det resultat vi lyckades utvinna visade att internkommunikationen hos de utvalda cheferna och anställda upplevdes som både positiv och negativ. Polismyndighetens internkommunikation har enligt cheferna genomgått en positiv utveckling. Enligt chefernas utsagor är polismyndigheten en arbetsplats med goda möjligheter för dialog mellan ledning och anställda och klara riktlinjer för hur internkommunikation ska bedrivas. Dock finns det rum för förbättring då det upplevs vara svårt att förmedla information som även filtreras på ett felaktigt sätt och skapar missförstånd. De anställda på polismyndigheten Värmland gav en helt annan bild då det dagliga arbetet präglas av orättvisor, bristfällig internkommunikation som skapar förvirring och svårigheter att överblicka vem som har ansvar för vad inom organisationen.
This bachelor thesis treats the subject of internal communication. We have chosen to carry through a research about the police department of Värmland's internal communication since they have big responsibility to preserve safety and security in society. The police department has these days greater demands regarding how to conduct dialogue and the level of communication within the organization to further the efficiency of police work. The main purpose of this bachelor thesis is to obtain insight about the internal communication functions and how it is presented from the managers as well as the employees perspective. In this thesis we are using relevant theories regarding organizational communication, internal communication, organization identity, organization culture and communication models. Our approach to answer the purpose of this thesis was to use two customized questions to enable us to get a overall view and a deeper insight of our chosen theoretical framework. “How do the managers perceive the internal communication in the police department of Värmland?” “How do the employees perceive the internal communication in the police department of Värmland?” In this study we used qualitative interviews and a qualitative focus group. The result we obtained, showed that, internal communication with the chosen managers and the employees had both positive and negative experiences. The police department of Värmland's internal communication has gone through a positive development according to the managers. According to the managers, the police department of Värmland has a healthy working environment that offers good possibilities for dialogue between management and employees, and also clear guidelines for how the internal communication has to be conducted. However, there is room for improvement, since some experience it to be hard to communicate information that filters wrongly and creates misunderstanding. But the employees gave us a completely different picture since the daily work characterized in injustice, faulty internal communication that creates confusion and difficulties to get an overview about who has what responsibilities in the organization.

Les chambres réverbérantes à brassage de modes (CRBM) utilisées dans l'industrie pour tester l'immunité ou la susceptibilité des systèmes électroniques embarqués (avion, automobile , smartphone,...) vis-à-vis des ondes électromagnétiques (EM) présentes dans leur environnement. Les CRBM doivent toutes répondre à un certain nombre de critères statistiques fixés par une norme internationale. Le critère principale étant l'obtention d'un champ statistiquement uniforme et isotrope autour de l'objet sous test. Afin améliorer et de mieux maîtriser les propriétés statistiques de ces systèmes pour des fréquences proches de leur fréquence minimale d'utilisation, nous proposons de les rendre chaotiques afin de profiter des propriétés statistiques universelles des résonances des cavités chaotiques. Nous commencerons par montrer comment rendre chaotique, par des modifications simples, des chambres réverbérantes conventionnelles, et comment étendre les prédictions de la théorie des matrices aléatoire appliquée (TMA) à l'hamiltonien effectif, permettant de décrire les systèmes chaotiques ouverts, au cas de systèmes décrits par des champs vectoriels. Ensuite, nous comparerons, au moyen de simulations et d’expériences, les distributions d'intensité et les fluctuations des maxima du champ EM dans une CRBM conventionnelle et dans une CR chaotique au voisinage de la fréquence minimale d’utilisation. Ce travail illustre que les propriétés statistiques spectrales et spatiales universelles des CR chaotiques permettent de mieux répondre aux critères exigés par la norme internationale pour réaliser des tests de compatibilité électromagnétiques
Mode-stirred reverberation chambers (RC) are used in the industry to test the immunity or the susceptibility of on-board electronic systems (plane, automobile, smartphone) towards the electromagnetic waves present in their environment. Mode-stirred RCs have to comply with a number of statistical criteria fixed by international standards. The chief criterion relies on a statistically uniform and isotropic field around the object under test. In order to improve and master the statistical properties of these systems for frequencies close to their lowest useable frequency, we suggest making them chaotic to take advantage of universal statistical properties of the resonances of chaotic cavities. We first show how to make chaotic RCs by simple modifications of a conventional RC and how to extend the predictions of the random matrix theory applied to the effective hamiltonien describing the open chaotic systems, to the case of vectorial fields. Then, we compare, by means of simulations and experiments, the distributions of intensity and the fluctuations of the maxima of the field in a conventional RC and in a chaotic RC close to the lowest useable frequency. This work illustrates that the universal spectral and spatial statistical properties of chaotic RCs allow to better comply with the criteria required by the international standards

The selective infrared (IR) excitation of molecular vibrations is a powerful tool to control the photoreactivity prior to electronic excitation in the ultraviolet / visible (UV/Vis) light regime ("vibrationally mediated chemistry"). For adsorbates on surfaces it has been theoretically predicted that IR preexcitation will lead to higher UV/Vis photodesorption yields and larger cross sections for other photoreactions. In a recent experiment, IR-mediated desorption of molecular hydrogen from a Si(111) surface on which atomic hydrogen and deuterium were co-adsorbed was achieved, following a vibrational mechanism as indicated by the isotope-selectivity. In the present work, selective vibrational IR excitation of adsorbate molecules, treated as multi-dimensional oscillators on dissipative surfaces, has been simulated within the framework of open-system density matrix theory. Not only potential-mediated, inter-mode coupling poses an obstacle to selective excitation but also the coupling of the adsorbate ("system") modes to the electronic and phononic degrees of freedom of the surface ("bath") does. Vibrational relaxation thereby takes place, depending on the availabilty of energetically fitting electron-hole (e/h) pairs and/or phonons (lattice vibrations) in the surface, on time-scales ranging from milliseconds to several hundreds of femtoseconds. On metal surfaces, where the relaxation process of the adsorbate via the e/h pair mechanism dominates, vibrational lifetimes are usually shorter than on insulator or semiconductor surfaces, in the range of picoseconds, being also the timescale of the IR pulses used here. Further inhibiting factors for selectivity can be the harmonicity of a mode and weak dipole activities ("dark modes") rendering vibrational excitation with moderate field intensities difficult. In addition to simple analytical pulses, optimal control theory (OCT) has been employed here to generate a suitable electric field to populate the target state/mode maximally. The complex OCT fields were analyzed by Husimi transformation, resolving the control field in time and energy. The adsorbate/surface systems investigated were CO/Cu(100), H/Si(100) and 2H/Ru(0001). These systems proved to be suitable models to study the above mentioned effects. Further, effects of temperature, pure dephasing (elastic scattering processes), pulse duration and dimensionality (up to four degrees of freedom) were studied. It was possible to selectively excite single vibrational modes, often even state-selective. Special processes like hot-band excitation, vibrationally mediated desorption and the excitation of "dark modes" were simulated. Finally, a novel OCT algorithm in density matrix representation has been developed which allows for time-dependent target operators and thus enables to control the excitation mechanism instead of only the final state. The algorithm is based on a combination of global (iterative) and local (non-iterative) OCT schemes, such that short, globally controlled time-intervals are coupled locally in time. Its numerical performance and accuracy were tested and verified and it was successfully applied to stabilize a two-state linear-combination and to enforce a successive "ladder climbing" in a rather harmonic system, where monochromatic, analytical pulses simultaneously excited several states, leading to a population loss in the target state.
Die selektive Anregung von Molekülschwingungen mittels Infrarotlicht (IR) ist vorteilhaft, um die Wirkungsquerschnitte nachfolgender photochemischer oder photophysikalischer Prozesse zu steigern, welche durch Elektronenanregung mittels ultraviolettem (UV) bzw. sichtbarem (Vis) Licht ausgelöst werden. Für Adsorbatmoleküle auf Oberflächen wurden theoretische Vorhersagen getroffen, dass eine kombinierte (IR plus UV)-Strategie ("schwingungsvermittelte Chemie") die Ausbeute bei Photodesorption und anderen Photoreaktionen deutlich zu erhöhen vermag. Kürzlich wurde im Experiment gezeigt, dass eine rein IR-vermittelte Desorption möglich ist, welche über einen schwingungsangeregten Mechanismus erfolgt. Hierbei wurde molekularer Wasserstoff von einer Si(111)-Oberfläche desorbiert, an der atomarer Wasserstoff und atomares Deuterium gebunden waren. Eine thermische Anregung, die zum Bindungsbruch führt, konnte hierbei wegen der Isotopenselektivität ausgeschlossen werden. In der vorliegenden Arbeit wurde die selektive IR-Schwingungsanregung von Adsorbaten, die als multidimensionale Oszillatoren auf dissipativen Oberflächen behandelt wurden, mit Hilfe der Dichtematrixtheorie für offene Systeme simuliert. Nicht nur die potentialvermittelte Kopplung zwischen den einzelnen Moden ist ein Hindernis für selektive Anregung, sondern auch die Kopplung der Moden des Adsorbats ("Systems") an elektronische und phononische Freiheitsgrade des Substrats ("Bades"). Die Schwingungsrelaxation verläuft hierbei auf Zeitskalen, die von Millisekunden bis hin zu wenigen hundert Femtosekunden reichen, je nach Verfügbarkeit energetisch geeigneter Elektron-Loch-Paar-Anregungen bzw. Phononen (Gitterschwingungen) in der Oberfläche. Auf Metalloberflächen, bei denen die Schwingungrelaxation des Adsorbats zumeist von einem Elektronen-Loch-Paar-Mechanismus dominiert wird, sind die Schwingungslebensdauern normalerweise kürzer als auf Isolator- oder Halbleiteroberflächen und betragen einige Picosekunden, ebenso wie die Zeitskala der hier gewählten IR-Pulse. Weitere Faktoren, die die selektive Anregung behindern können sind die Harmonizität einer Mode und die geringe Dipolaktivität sogenannter "dunkler Moden", die eine Anregung mit moderat intensiven Feldern erschweren. Zusätzlich zu einfachen analytischen Pulsen wurden Felder mittels Optimaler Kontrolltheorie (OCT) erzeugt, um eine(n) Zielzustand/-mode maximal zu populieren. Komplexe OCT Pulse wurden mit Hilfe der Husimi-Transformation analysiert, welche das Kontrollfeld im Zeit- und Energieraum aufzulösen vermag. Die in dieser Arbeit untersuchten Adsorbat/Oberflächen-Systeme waren CO/Cu(100), H/Si(100) und 2H/Ru(0001), die sich als passende Modelle erwiesen, um oben genannte Faktoren zu untersuchen. Desweiteren wurden die Auswirkungen von Temperatur, reiner Dephasierung (elastische Streuprozesse), Dauer des IR-Pulses und Systemdimensionalit"at (Behandlung von bis zu vier Freiheitsgraden) studiert. Einzelne Schwingungsmoden konnten angeregt werden, in vielen Fällen sogar zustandsselektiv. Spezielle Prozesse wie die Anregung "heißer Banden", Desorption via alleiniger Schwingungsanregung und die Anregung "dunkler Moden" wurden simuliert. Schließlich wurde ein neuer OCT-Algorithmus in Dichtematrixdarstellung entwickelt, der es erlaubt, zeitabhängige Zieloperatoren einzuführen, um nicht nur Kontrolle über den Endzustand einer Anregung, sondern auch über den Anregungsmechanismus zu erlangen. Der Algorithmus basiert auf einer Kombination von globaler (iterativer) und lokaler (nicht-iterativer) optimaler Kontrollschemata in der Art, dass kurze, global kontrollierte Intervalle zeitlich lokal miteinander gekoppelt werden. Nach numerischen Tests wurde der Algorithmus erfolgreich angewandt, um eine Linearkombination aus zwei Zuständen zu stabilisieren, sowie um eine schrittweise "Leiteranregung" in einem harmonischen System zu forcieren, bei dem monochromatische, analytische Pulse mehrere Zustände zugleich anregen und somit einen Populationsverlust im angestrebten Zielzustand zur Folge haben.

Developpement d'un reseau local a insertion de registres proposant une strategie deterministe d'acces a la voie et pour l'etablissement des liaisons de donnees. Le determinisme d'acces au support de communication est assure par la technique d'insertion de registre. Le retrait du registre se fait au retour de la trame emise. La circonference de l'anneau varie selon sa charge. La fiabilite est garantie par un protocole gerant deux redondances: l'une globale porte sur l'ensemble des informations echangees, l'autre est reservee aux adresses vehiculees par la trame. Le temps de transit de l'information est connu des communicateurs grace a la circulation d'une trame "reference temporelle" sur l'anneau; ceci permet une gestion dynamique des delais

ICT development and deployment and supporting policies take place within a fiercely contested globalised political economy. For organisations there is a pervasiveness of change processes, often externally imposed, which are rising with these globalising effects. This not only implies that the context in which organisations are situated is continuously changing, but also that the nature of the organisation itself is subject to change (Van Tonder, 2004). However, the external influences imposed on an organisation are often heterogeneous and make the management of adapting to the external environment extremely complex. This thesis explores such an externally imposed change on an organisation around the implementation of a contentious national policy. This entails not only dealing with the more usual dimensions of change in an organisation, but also the implications of the national debate and contentions around the national policy playing out in the local setting of the organisation. In this thesis the change explored is within a government department from a proprietary Enterprise Content Management (ECM) system to an open source ECM system. An interpretative approach was followed, using a longitudinal case study. Two main aspects of this change process are explored. The first is the impact of the national open source policy on government departments - an externally imposed change of mission, vision and values. The second is how internally the government department changed its internal work processes and information systems to comply with that policy. These two aspects are intertwined. Alignment of the organisation mission, values and objectives, with the proposed technological innovation and change management models emerges as a necessary condition for managing change. However, what emerged as a more challenging issue was whether internal organisational changes can be aligned with contentious national policy imperatives. Three theoretical lenses are used to explore this contentious issue: the HEM model of Du Plooy’s (1998); the improvisational change management model of Orlikowski and Hofman (1997); and institutional theory as it applies to Information Systems. The improvisational change model of Orlikowski and Hofman (1997) in combination with Du Plooy’s (1998) HEM model, was used to understand the change process unfolding in the implementation of an OS ECM system in a Government department in SA. The result of this application is some practical recommendations for government officials on future OS implementations, as well as a theoretical add-on to extend the change management model applied. The researcher found that models can increase our understanding and reveal how one can ‘cultivate’ the human environment within which technology is to be implemented. However, the process of developing an understanding of how national policy was developed and the rationale for it was also found to be important, as is developing an understanding of the rationale of this particular department for choosing to implement the OS ECM system. By adding to, or expanding on Orlikowski and Hoffman’s (1997) model to include a fourth element, indicating the external forces in the environment, such as government regulations; government policy; and the debate on global and national FOSS versus PS, highlights the need for this external alignment as well as prevents the focus on internal alignment only. Institutional theory was consequently applied in an attempt to unpack the organisational and change management dimensions of the change model, aiming at understanding the institutional forces which legitimates or contradicts the technical/rational ideas and actions of the change. The findings were threefold. Firstly, the role played by IS as an institutional process in and of itself and the way in which this could have affected the implementation of the new OS ECM system was discussed, pointing to the possibility that the new system was not necessarily being implemented to streamline the work practices, but rather due to its institutional status of being a ‘rational myth’; something which had to be done as ‘it’s just the right thing to do.” Secondly, OSS and PS were argued to be different ‘types’ of institutions. Using the institutional pillars it was argued that OSS and PS were driven by different institutional forces, with PS leaning towards the regulative pillar and OSS being more in line with the normative pillar. These two institutions were found to mainly differ with regard to their basis of compliance and the logic behind them. The insights offered by this argument revealed that when changing from OSS to PS, it would be very valuable to recognise that OSS and PS are two different ‘types’ of institutions, and to not only understand that the new system could therefore change the organisational processes when it is implemented, but to also acknowledge the change which will take place within the IS/IT institution itself – moving from the regulative to the normative. The change should thus be understood both within the two different IS innovations themselves, and in how these two innovations interact. Lastly, the research in this thesis went beyond the technical/rational actions of the stakeholders, and included an in depth analysis of the institutional forces at play in the broader social context of the Government department. It explained the institutions which were at play on the international, national and organisational levels, pointing out which of these forces worked in favour of or against the technical/rational actions, and in the process contributed to the unexpected outcome of the new OS ECM implementation process.
Thesis (PhD-- University of Pretoria, 2014
Informatics
unrestricted

Orientadores: Amir Ordacgi Caldeira, Eduardo Peres Novais de Sá
Tese (doutorado) - Universidade Estadual de Campinas, Instituto de Física Gleb Wataghin
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Resumo: A criação de um computador quântico é um projeto que guia, ao mesmo tempo, avanços tecnológicos e um melhor entendimento das propriedades de sistemas quânticos e da Mecânica Quântica em geral. O teorema do limiar é derivado da teoria quântica de correção de erros e garante que, se o ruido estocástico que afeta os componentes de um computador quântico encontra-se abaixo de um valor limite, podemos operar esse computador quântico confiavelmente. Investigamos como esse teorema é modificado quando consideramos uma memória quântica (a qual usa o código de superfície para corrigir erros) acoplada a um ambiente correlacionado. O limiar de erros nesse caso é relacionado à transição de fase ordem-desordem de um sistema de spin equivalente
Abstract: The design of a quantum computer is a project which drives, at the same time, technological advancement and a better understanding of the properties of quantum systems and of Quantum Mechanics in general. The threshold theorem comes from quantum error correction theory and it guarantees that, if stochastic noise affecting the components of a quantum computer is below some threshold value, we can operate this quantum computer reliably. We investigate how this theorem is modified when we consider a quantum memory (which uses the surface code to correct errors) coupled to a correlated environment. The error threshold in this case is related the order-disorder phase transition of an equivalent spin system
Doutorado
Física
Doutor em Ciências

The problem under consideration in the thesis is a two level atom in a photonic crystal and a pumping laser. The photonic crystal provides an environment for the atom, that modifies the decay of the exited state, especially if the atom frequency is close to the band gap. The population inversion is investigated als well as the emission spectrum. The dynamics is analysed in the context of open quantum systems. Due to the multiple reflections in the photonic crystal, the system has a finite memory that inhibits the Markovian approximation. In the Heisenberg picture the equations of motion for the system variables form a infinite hierarchy of integro-differential equations. To get a closed system, approximations like a weak coupling approximation are needed. The thesis starts with a simple photonic crystal that is amenable to analytic calculations: a one-dimensional photonic crystal, that consists of alternating layers. The Bloch modes inside and the vacuum modes outside a finite crystal are linked with a transformation matrix that is interpreted as a transfer matrix. Formulas for the band structure, the reflection from a semi-infinite crystal, and the local density of states in absorbing crystals are found; defect modes and negative refraction are discussed. The quantum optics section of the work starts with the discussion of three problems, that are related to the full resonance fluorescence problem: a pure dephasing model, the driven atom and resonance fluorescence in free space. In the lowest order of the system-environment coupling, the one-time expectation values for the full problem are calculated analytically and the stationary states are discussed for certain cases. For the calculation of the two time correlation functions and spectra, the additional problem of correlations between the two times appears. In the Markovian case, the quantum regression theorem is valid. In the general case, the fluctuation dissipation theorem can be used instead. The two-time correlation functions are calculated by the two different methods. Within the chosen approximations, both methods deliver the same result. Several plots show the dependence of the spectrum on the parameters. Some examples for squeezing spectra are shown with different approximations. A projection operator method is used to establish two kinds of Markovian expansion with and without time convolution. The lowest order is identical with the lowest order of system environment coupling, but higher orders give different results.
Die Arbeit befasst sich mit der Emission eines 2-Niveau-Atoms in einem photonischen Kristall mit einem treibenden Laser. Der photonische Kristall stellt für das Atom eine Umgebung dar, die seinen Zerfall verändert, insbesondere wenn die Übergangsfrequenz des Atoms nahe an der Bandkante ist. Es werden sowohl die Besetzungen als auch das Emissionsspektrum untersucht. Die Dynamik wird im Kontext offener Quantensysteme analysiert. Durch die vielfachen Reflexionen im photonischen Kristall hat das System ein endliches Gedächtnis, das die Markov-Näherung verhindert. Im Heisenberg-Bild stellen die Bewegungsgleichungen für die Systemvariablen eineunendliche Hierachie von Integro-Differentialgleichungen dar. Um ein geschlossenes System zu erhalten, sind Näherungen wie eine schwache Kopplung nötig. Zunächst wird ein einfacher photonischer Kristall betrachtet.: Der eindimensionale photonische Kristall, der aus wechselnden Lagen besteht. Die Blochmoden innerhalb und die Vakuummoden außerhalb des endlichen photonischen Kristalls sind durch eine Transformationsmatrix, die als Transfermatrix interpretiert werden kann, miteinander verbunden. Einfache Formeln für die Bandstruktur, Reflexion eines halb-unendlichen Kristalls, die lokale Zustandsdichte im absorbierenden Kristall werden gefunden; außerdem werden Defektmoden und negative Brechung diskutiert. Im quantenoptischen Teil der Arbeit werden zu Anfang drei Probleme diskutiert, die im Zusammenhang zum Problem der Resonanzfluoreszenz stehen und die analytisch berechnet werden können: Ein Dephasierungsmodell, das getriebenen Atom und Resonanzfluoreszenz im freien Raum. In der niedrigsten Ordnung der System-Bad-Kopplung werden die Erwartungswerte analytisch berechnet und die stationären Zustände werden für bestimmte Fälle diskutiert. Bei der Berechnung der Zweizeitkorrelationsfunktion und der Spektren taucht das zusätzliche Problem der Korrelationen zwischen den beiden Zeiten auf. Im Markov-Fall gilt das Quantenregressionstheorem. Im allgemeinen Fall kann stattdessen das Fluktuations-Dissipations-Theorem benutzt werden. Die Korrelationsfunktionen werden mit zwei verschiedenen Methoden berechnet. Innerhalb der gewählten Näherungen liefern beide Methoden dasselbe Resultat. Einige Plots zeigen die Abhängigkeit des Spektrums von den verschiedenen Parametern. Mehrere Beispiele für Squeezing-Spektren werden mit den verschiedenen Näherungen gezeigt. Eine Projektions-Operator-Methode wird benutzt, um zwei Arten einer Markov-Entwicklung zu implementieren, mit und ohne Faltungsintegral. Die niedrigste Ordnung ist identisch mit der niedrigsten Ordnung der System-Bad-Kopplung, wohingegen höhere Ordnungen andere Resultate ergeben.