Dissertations / Theses on the topic 'One-Dimensional gas'
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Tas, Murat. "Dielectric Formulation Of The One Dimensional Electron Gas." Phd thesis, METU, 2004. http://etd.lib.metu.edu.tr/upload/12604981/index.pdf.
Full textRodriguez, Carlos G. "One-Dimensional, Finite-Rate Model for Gas-Turbine Combustors." Diss., Virginia Tech, 1997. http://hdl.handle.net/10919/30672.
Full textPh. D.
Caley, Thomas. "Numerical Modeling of Gas Turbine Combustor Utilizing One-Dimensional Acoustics." University of Cincinnati / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1491562189178949.
Full textGudyma, Andrii. "Non-equilibrium dynamics of a trapped one-dimensional Bose gas." Thesis, Université Paris-Saclay (ComUE), 2015. http://www.theses.fr/2015SACLS064/document.
Full textA study of breathing oscillations of a one-dimensional trapped interacting Bose gas is presented. Oscillations are initiated by an instantaneous change of the trapping frequency. In the thesis a 1D quantum Bose gas in a parabolic trap at zero temperature is considered, and it is explained, analytically and numerically, how the oscillation frequency depends on the number of particles, their repulsive interaction, and the trap parameters. We have focused on the many-body spectral description, using the sum rules approximation. The oscillation frequency is identified as the energy difference between the ground state and a particular excited state. The existence of three regimes is demonstrated, namely the Tonks regime, the Thomas-Fermi regime and the Gaussian regime. The transition from the Tonks to the Thomas-Fermi regime is described in the terms of the local density approximation (LDA). For the description of the transition from the Thomas-Fermi to the Gaussian regime the Hartree approximation is used. In both cases the parameters where the transitions happen are found. The extensive diffusion Monte Carlo simulations for a gas containing up to N = 25 particles is performed. As the number of particles increases, predictions from the simulations converge to the ones from the Hartree and LDA in the corresponding regimes. This makes the results for the breathing mode frequency applicable for arbitrary values of the particle number and interaction. The analysis is completed with the finite N perturbative results in the limiting cases. The theory predicts the reentrant behavior of the breathing mode frequency when moving from the Tonks to the Gaussian regime and fully explains the recent experiment of the Innsbruck group
Latt, Kyaw Zin. "Interactions of Two Dimensional Surface State Electron Gas with Zero, One and Two Dimensional Structures." Ohio University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1383242271.
Full textParthangal, Prahalad Madhavan. "Synthesis and integration of one-dimensional nanostructures for chemical gas sensing applications." College Park, Md. : University of Maryland, 2007. http://hdl.handle.net/1903/6881.
Full textThesis research directed by: Mechanical Engineering. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
Tang, Zifan. "One-dimensional mechanistic modelling of gas-liquid two phase flow in pipes." Thesis, Imperial College London, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.284815.
Full textMukherjee, Tamal. "One Dimensional Air System Modeling of Advanced Technology Compressed Natural Gas Engines." The Ohio State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=osu1397776678.
Full textDe, Rosi Giulia. "Collective oscillations of a trapped atomic gas in low dimensions and thermodynamics of one-dimensional Bose gas." Doctoral thesis, Università degli studi di Trento, 2017. https://hdl.handle.net/11572/368019.
Full textDe, Rosi Giulia. "Collective oscillations of a trapped atomic gas in low dimensions and thermodynamics of one-dimensional Bose gas." Doctoral thesis, University of Trento, 2017. http://eprints-phd.biblio.unitn.it/2066/1/PhD_DeRosi.pdf.
Full textLilly, Jonathan Patrick. "One-dimensional computer modeling of electrical conductivity through methane and synthesis gas flames." Morgantown, W. Va. : [West Virginia University Libraries], 2006. https://eidr.wvu.edu/etd/documentdata.eTD?documentid=4898.
Full textTitle from document title page. Document formatted into pages; contains xvi, 291 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 289-291).
Ha, Meesoon. "Scaling and phase transitions in one-dimensional nonequilibrium driven systems /." Thesis, Connect to this title online; UW restricted, 2003. http://hdl.handle.net/1773/9758.
Full textCheng, Chi-Yuan. "Gas adsorption, diffusion, and exchange in one-dimensional nanotube systems by hyperpolarized Xe-129 NMR." [Gainesville, Fla.] : University of Florida, 2008. http://purl.fcla.edu/fcla/etd/UFE0022786.
Full textKirkpatrick, Samuel John. "An evaluation of one-dimensional simulation techniques for predicting unsteady gas flow in engine ducting." Thesis, Queen's University Belfast, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.482057.
Full textBaradaran, Amir R. "Development and Implementation of a Preconditioner for a Five-Moment One-Dimensional Moment Closure." Thesis, Université d'Ottawa / University of Ottawa, 2015. http://hdl.handle.net/10393/32225.
Full textAbbaspour, Mohammad. "Simulation and optimization of non-isothermal, one-dimensional single/two-phase flow in natural gas pipeline /." Search for this dissertation online, 2005. http://wwwlib.umi.com/cr/ksu/main.
Full textMcMackin, Martin. "A one-dimensional model of the unsteady gas dynamics and surface relations within an automotive catalyst." Thesis, Queen's University Belfast, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.486531.
Full textGabrielyan, Nare. "Low temperature fabrication of one-dimensional nanostructures and their potential application in gas sensors and biosensors." Thesis, De Montfort University, 2013. http://hdl.handle.net/2086/9607.
Full textGallucci, Donatello. "Ab initio modelling of quasi-one-dimensional Bose gas experiments via the stochastic Gross-Pitaevskii equation." Thesis, University of Newcastle upon Tyne, 2013. http://hdl.handle.net/10443/1858.
Full textKratschun, Filipp, Jens Köhne, Peter Kloft, Heiko Baum, and Katharina Schmitz. "One dimensional unsteady model of a hydropneumatic piston accumulator based on finite volume method." Technische Universität Dresden, 2020. https://tud.qucosa.de/id/qucosa%3A71089.
Full textPriščák, Juraj. "Charakterizace senzitivních nanomateriálů pro MOX senzory plynů." Master's thesis, Vysoké učení technické v Brně. Fakulta elektrotechniky a komunikačních technologií, 2021. http://www.nusl.cz/ntk/nusl-442521.
Full textIsaksson, Frida. "Pressure loss characterization for cooling and secondary air system components in gas turbines." Thesis, Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-64528.
Full textYoung, Alexander L., and Alexander L. Young. "Three Essays on Complex Systems: Self-Sorting in a One-Dimensional Gas, Collective Motion in a Two-Dimensional Ensemble of Disks, and Environment-Driven Seasonality of Mosquito Abundance." Diss., The University of Arizona, 2017. http://hdl.handle.net/10150/624567.
Full textHändestam, Jacob, and Eric Jacobson. "Investigation and Validation of Cooling Loss Models for Axial Gas Turbines." Thesis, KTH, Energiteknik, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-211696.
Full textThis thesis concerns the investigation and validation of the cooling loss model in newly developed one-dimensional turbine design tool, Mean Line Tool (MLT), of Siemens Industrial Turbomachinery AB (SIT). The main objective is to investigate how accurately MLT can predict the additional aerodynamic losses due to cooling ejection in a turbine blade passage. To validate the cooling loss model of MLT, existing results from an annular sector cascade rig at KTH were used, where the additional losses due to cooling ejection were presented for several cooling locations on a stator vane profile. Local flow- and geometrical parameters from the cascade rig were set in MLT to enable a fair comparison. Moreover, a Siemens test based correlation was used, which is a data collection based on tests using various cooled components of SIT. Cooling ejection on a stator vane profile, stator vane platform and rotor blade profile was investigated, where an increase in coolant mass-flow was related to a change in stage efficiency. The results, when comparing data from the KTH cascade rig against calculations of MLT, show that MLT is able to accurately predict the additional loss due to cooling ejection on a stator vane profile. However, the comparison presents that the calculated loss for trailing edge cooling by MLT is lower than the results from the cascade rig. Therefore, a modified trailing edge cooling correlation is presented, which predicts the results from the cascade rig with better accuracy. Furthermore, comparisons between MLT calculations and the Siemens correlation present that MLT cannot predict the change in stage efficiency, due to added coolant mass-flow, accurately. However, due to several uncertainties, these results are qualitatively used to understand sources of prediction error in the cooling loss model of MLT. Having this in mind, it is established that hub platform cooling at the front part of a blade passage might be greatly overpredicted by MLT. The general conclusion is that MLT predicts the change in cascade efficiency due to coolant ejection with good accuracy for a stator vane profile, except for cooling at the trailing edge. However, MLT is not able to predict the change in stage efficiency, due to added coolant mass-flow, with good accuracy for various cooled components from the SIT gas turbine product portfolio. Thus, MLT needs further validation before it can be implemented into the SIT design system.
Almstetter, Martin F. [Verfasser], and Frank-Michael [Akademischer Betreuer] Matysik. "Tools and applications for one- and two-dimensional gas chromatography – time-of-flight mass spectrometry-based metabolomics / Martin F. Almstetter. Betreuer: Frank-Michael Matysik." Regensburg : Universitätsbibliothek Regensburg, 2012. http://d-nb.info/1023312379/34.
Full textPentland, Ian Alisdair. "A phonon emission study of quasi-1D electron gases." Thesis, University of Nottingham, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.325695.
Full textHåkansson, David. "Aerothermal and Kinetic Modelling of a Gas Turbine Dry Low Emission Combustion System." Thesis, KTH, Strömningsmekanik och Teknisk Akustik, 2021. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-298477.
Full textEn växande medvetenhet kring klimatfrågan, har medfört stora förändringar i energibranschen. I och med detta behöver även gasturbinindustrin förbättra de nuvarande dry-low emissions systemen och göra det möjligt för gasturbiner att förbränna gröna bränslen som väte. Samtidigt måste också utsläppen av NOx hållas nere. För att kunna utforma dessa system behövs en fullständig förståelse för de aerotermiska och kinetiska processerna i en gasturbins förbränningskammare. Målet med detta examensarbete var att utveckla en endimensionell generell nätverksmodell för förbränningssystemet i Siemens Energys SGT-700. Modellen skulle noggrant kunna förutsäga tryckförluster, massflöden, viktiga temperaturer samt utsläpp. Tre modeller utvärderades och en kod som emulerade vissa aspekter av styrsystemet utvecklades också. Modellerna och koden utvärderades och jämfördes mot varandra och även mot testdata från tidigare testserier som utfördes på SGT-700 och SGT-600. Simuleringar utfördes också med väte som bränsle. Slutligen levererades en modell av SGT-700 förbränningskammaren till Siemens Energy. Modellen har verifierats för en rad olika lastfall, mot testdata och data som genererats av andra termodynamisk beräkningsprogram som utvecklats av Siemens Energy. Hur modellen uppförde sig när väte var introducerat in i olika lastfall jämfördes också mot testdata
Ballu, Manon. "Production d’un gaz de Bose unidimensionnel, résonances de Feshbach micro-onde et dynamique hors équilibre." Electronic Thesis or Diss., Paris 13, 2024. http://www.theses.fr/2024PA131033.
Full textIn this thesis, we present an experiment producing sodium Bose-Einstein condensates. The use of an atom chip, giving access to highly elongated magnetic traps, allows to produce one-dimensional quantum gases in the quasi-condensate regime. We optimized evaporative cooling and atom transfer in the magnetic trap of the atom chip. We then turned to microwave Feshbach resonances, with the aim of controlling the interactions between atoms, which requires high microwave power. To achieve this, the atom chip encompasses a coplanar waveguide. Rabi oscillations measurements between the two hyperfine levels of the sodium ground state f=1 and f=2 show that we can achieve magnetic amplitudes of several gauss for the oscillating field. We have performed microwave spectroscopy of the molecular states in the [f1=1, f2=2] branch closest to the dissociation limit. The rapid loss of atoms observed close to the molecular resonances seems to limit their use as a tool for interaction control.In a second part, we numerically study the non-equilibrium dynamics of a one-dimensional Bose gas in a box, by solving the 1D Gross-Pitaevskii equation. The system is driven out of equilibrium using an oscillating external potential. We focused on density profiles, energies and momentum distributions. Inverse scattering transform methods, with the calculation of the Lax spectrum, are used to study the solitons of the system
BAKHTIARI, MOHAMMAD REZA. "Quantum gases in quasi-one dimensional arrays." Doctoral thesis, Scuola Normale Superiore, 2007. http://hdl.handle.net/11384/85849.
Full textPerez, Florent. "Plasmons dans un potentiel unidimensionnelEtude par spectroscopie Raman de fils quantiques gravés." Phd thesis, Université Pierre et Marie Curie - Paris VI, 1998. http://tel.archives-ouvertes.fr/tel-00285443.
Full textNous avons cherché à déterminer la contribution de la forte illumination dans les conclusions précédentes. Nous avons utilisé pour cela la spectroscopie de magnéto-transmission infra-rouge qui ne modifie pas les conditions d'équilibre du gaz d'électrons. Une largeur critique de 130 nm a été extraite, en dessous de laquelle nous n'avons plus aucun signe de la présence d'électrons libres. La comparaison des mesures Raman et infra-rouge a permis l'établissement et la validation d'un modèle microscopique du potentiel de confinement présent dans les fils. Enfin nous avons fabriqués des échantillons de géométries plus complexes. L'observation et l'analyse par diffusion Raman des plasmons dans ces fils a montré que nous pouvions contrôler la géométrie du potentiel confinant les électrons et a mis en évidence des effets nouveaux tels que le repliement et le confinement de plasmons unidimensionnels.
Klochan, Oleh V. Physics Faculty of Science UNSW. "Ballistic transport in one-dimensional p-type GaAs devices." Awarded by:University of New South Wales, 2007. http://handle.unsw.edu.au/1959.4/35186.
Full textGao, Jian. "Fluorescence Enhancement using One-dimensional Photonic Band Gap Multilayer Structure." University of Dayton / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=dayton1343753064.
Full textMassaro, Loredana Maria. "Multimodal one-dimensional photonic crystal cavities." Electronic Thesis or Diss., université Paris-Saclay, 2024. http://www.theses.fr/2024UPASP035.
Full textIntegrated photonics research focuses its efforts in developing miniaturised and efficient devices for applications in quantum information, metrology and medicine. In this context, photonic crystal cavities occupy a leading position in the integration of photonic structures owning small footprint and tailorable spectral properties. Special attention in recent years is given to photonic crystal cavities consisting of III-V semiconductor materials, as their nonlinear properties are an asset for further development in complex circuitry of coherent states of light through nonlinear interactions. In this thesis, we present the design, fabrication and experimental characterisation of high-Q one-dimensional photonic crystal cavities integrated on silicon on insulator. First, we detail the design of our cavities which is based on the gentle confinement of the field. We show that our design technique allows the devising of multimodal as well as single-mode photonic crystal cavities working at telecom window. The introduced design technique is versatile and easily tailorable to devise cavities of different materials, as InGaP, Si, or InP. Then, we detail the fabrication of III-V photonic structures heterogeneously integrated on silicon on insulator. From the adhesive bonding of the two levels to the final integrated device, fabrication process flow is reported and main challenges encountered commented. Fabrication of silicon-based cavities is also reported. Experimental characterisation of the cavities is conducted by measuring the transmission of the samples. We present how to tailor the spectral properties of the cavities through nanometric variation of their geometrical parameters, and comment on some peculiarities of multimodal coupling
Patel, Nalin Kumar. "Observations of confinement in quasi-one- and -zero-dimensional GaAs/AlGaAs structures." Thesis, University of Cambridge, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.386352.
Full textKhodami, Maryam. "Dispersion Characteristics of One-dimensional Photonic Band Gap Structures Composed of Metallic Inclusions." Thèse, Université d'Ottawa / University of Ottawa, 2012. http://hdl.handle.net/10393/23179.
Full textBarnwell, Ellis. "One and two-dimensional propagation of waves in periodic heterogeneous media : transient effects and band gap tuning." Thesis, University of Manchester, 2015. https://www.research.manchester.ac.uk/portal/en/theses/one-and-twodimensional-propagation-of-waves-in-periodic-heterogeneous-media-transient-effects-and-band-gap-tuning(9a5bd9d7-09da-46a8-ae57-b63d9d815f10).html.
Full textTuenter, Hans J. H. "Worst-case bounds for bin-packing heuristics with applications to the duality gap of the one-dimensional cutting stock problem." Thesis, University of Birmingham, 1997. http://etheses.bham.ac.uk//id/eprint/266/.
Full textTanner, Matthew Wilder. "Multidimensional Modeling of Solid Propellant Burning Rates and Aluminum Agglomeration and One-Dimensional Modeling of RDX/GAP and AP/HTPB." Diss., CLICK HERE for online access, 2008. http://contentdm.lib.byu.edu/ETD/image/etd2706.pdf.
Full textBHANDARI, CHURNA B. "FIRST-PRINCIPLES STUDY OF ELECTRONIC AND VIBRATIONAL PROPERTIES OF BULK AND MONOLAYER V2O5." Case Western Reserve University School of Graduate Studies / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=case1459296089.
Full textShulenburger, Luke Nathan. "Correlation in the one dimensional electron gas /." 2008. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3337923.
Full textSource: Dissertation Abstracts International, Volume: 69-11, Section: B, page: 6872. Adviser: Richard M. Martin. Includes bibliographical references (leaves 104-109) Available on microfilm from Pro Quest Information and Learning.
Cheng, Hsien-Lung, and 鄭憲隆. "One-dimensional silicon nanostructure for hydrogen gas sensor." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/82604143772786903888.
Full text國立臺灣科技大學
電子工程系
100
There are many technologies to fabricate one-dimensional silicon nanostructure. The silicon nanostructures were used for many applications. For example, the silicon nanostructures have high reflection property in solar cell. In the electron field emission, the silicon nanostructures possess the higher aspect ratio and numerous emission sites. For sensor researching, it has higher surface area to volume ratio that can improve the sensitivity. We fabricated the one dimension silicon nanostructure for hydrogen sensor. In this research, we synthesized different morphology of silicon nanostructure using wet electroless etching technique. The field emission scanning electron microscopy (FE-SEM) was used to observe the surface morphology of silicon nanostructure. The micro-Raman and Fourier transform infrared (FT-IR) was used to investigate the bonding of silicon nanostructure. Finally, we carried out the electrical analyze of gas sensor system with hydrogen sensing. In this study, we use the two-step wet electroless etching technique to form the straw-like silicon nanowire. It can be observed that some different layers in SEM photographs. The top layer was straw-like silicon nanowire, and the middle layer was straight aligned silicon nanowire, and the bottom layer was silicon base which is the bulk silicon. The straw-like silicon nanowire was found the the bonding of Si-O-Si about 1173cm-1 in FT-IR spectrum. And it also observed some red shift in Raman spectrum. Because of the higher surface area to volume ratio and Si-O-Si bonding, the performance of this straw-like structure hydrogen sensor was improved. Moreover, this hydrogen gas sensor was also modified with Pt nanoparticles, which can enhance the ratio of hydrogen gas dissolve into the metal-semiconductor interface. Finally we tried to make the porous structure with high density and high aspect ratio also by wet electroless etching technique. This porous possessed the high surface area which had the superior sensitivity.
Yeh, Li-Ko, and 葉禮閣. "One-Dimensional and Two-Dimensional Materials for Solar Cells and Gas Sensors." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/ab8rfy.
Full text國立臺灣大學
電子工程學研究所
105
Particular physical and chemical properties of nanomaterials have promised and exhibited great applications in manufacturing various nanodevices such as electron field emitters, sensors, photovoltaics and other electronic components. In this thesis, I will experimentally explore three topics which realize the improvement of solar cells and gas sensors. The first topic is that ZnO nanostructure as an anti-reflectance coating for commercial GaInP/GaAs/Ge triple-junction solar cells. Covered by the unique tapered nanoneedles, the efficiency of the tandem solar cell coated with the ZnO nanoneedles is effectively improved 45.8 % higher than that with bare surface. The excellent omnidirectionality and heat sustainability demonstrated here bring promising potential for multi-junction concentrator solar cells. The second topic is a simple and low cost hydrothermal process was adopted to synthesize corals-like ZnO for gas sensors applications. Toluene was detected with the photoactivated gas detector by 2μW/cm2 ultraviolet (UV) illumination. Giant sensitivity enhancement of the detector is due to the high surface area/volume ratio morphology of corals-like ZnO nanorod arrays (NRAs) and photoinduced oxygen ions increasing by UV illumination. The corresponding sensitivity (ΔR/R0) of ZnO corals-like NRAs based detector was approximately enhanced 1022 % than ZnO thin film sensors. The third topic is about two-dimensional (2D) nanomaterials atomic MoS2 gas sensors. A highly sensitive gas sensor based on the chemical vapor deposition synthesized MoS2 was developed. The target gas was methanol. We demonstrated the highly enhanced performance of atomic trilayer MoS2 gas sensor by oxygen plasma treatment. During the plasma treatment 40s, the response of MoS2 gas sensor is more 500 % higher than original MoS2 (from 5% to 27.2%) and increase the limit of detection from 2000 ppm to 100 ppm. Photoluminescence (PL) clearly reveals the number of defects which contribute the ability of gas adsorption. This result can improve the device performance which has the same mechanism of 2D nanomaterials.
Wenger, Trevor. "Experiments on a one-dimensional Bose gas Thomas Fermi to Tonks-Girardeau /." 2007. http://www.etda.libraries.psu.edu/theses/approved/WorldWideIndex/ETD-1758/index.html.
Full textChang, Tsu-Ming, and 張祖明. "One-Dimensional Bose Gas with Delta Function Interactions in an Infinite Well." Thesis, 1996. http://ndltd.ncl.edu.tw/handle/66068703691602136222.
Full text國立清華大學
物理研究所
84
One-dimensional bosons with a delta function interaction in an infinite well is analyzed. Its wave function, energy spectrum, and other thermodynamic properties are obtained. First, for comparison, we deal with the problem that iti- nerant particles interact with a point defect via a delta function interaction in an infinite well in chapter 2, and we find perturbation results to be a good approximation. Secondly, we suppose that the bose gas interact with a delta function interaction in an infinite well, and then we analyze the wavefunction and spectrum. In chapter 3 we deal with two bosons case, and in chapter 4 we generalize the re- sults to many bosons. When we take the thermodynamic limit, we get the results which are the same as those employed by the periodic boundary condition.
Chen, Hsin-Li, and 陳新立. "Electrical measurement of one-dimensional composite nanowires and its application for gas sensor." Thesis, 2005. http://ndltd.ncl.edu.tw/handle/44562460085124743491.
Full text國立雲林科技大學
電子與資訊工程研究所
93
In the this work, one-dimensional composite materials of the gold nanopartical embedded in an amorphous silicon nanowire was synthesized by microwave plasma enhance chemical vapor deposition (MWPECVD) system on the SiNx thin film with coating a gold film. Growth of the one-dimensional composite nanowires is not easy, because the plasma environment in the chamber with a little variation, the silica nanowires will be synthesized instead of the composite nanowires. We used the silica nanowires of the different conditions to detect nitrogen and oxygen respectively, and High Resolution Scanning Electron Microscopy (HRSEM), Electron Beam Lithography (EBL) were used for fabrication electrode and electrical measurement of one-dimensional composite nanowires and silica nanowire.
Chen, Li-Chun, and 陳立鈞. "The preparation of gas diffusion electrodes using one-dimensional carbon substrate and Pt sols." Thesis, 2008. http://ndltd.ncl.edu.tw/handle/40974120787323380194.
Full text元智大學
化學工程與材料科學學系
96
In this research, a carbon membrane with well-aligned pore structure is synthesized by template method. This carbon membrane is used together with Pt sols for improving performance of PEMFCs. Epoxy solution is deposited into pore of a commercially available AAO (anodic aluminum oxide) membrane. After carbonization under N2 environment at elevated temperature, the carbon-AAO composite is subjected to a 2-step AAO removal procedure. By controlling the extent of AAO removal in the first step, and the use of a second carbon-filling-and-carbonization procedure, we achieve a continuous carbon membrane with pore structure replicating that of AAO template. In this study, we use different solvents and additivies (involved Nafion and Carbon) over Pt sols to compare the ink stability. We use Contact angle, precipitation, Particle size distribution and Zata potential to analyze the stability of ink. The result shows that the addition of IPA and MeOH over Pt sols forces quick precipitation. We prepared thinner electrode made of Pt sols, but its performance decreases quickly from 35 to 70oC.However, the trend is reverse compared to Pt/C. The preparation of the electrode in combination with Pt sols and One-dimensional carbon material improves mass transport limitation.
Mehta, Abhijit C. "Zigzag Phase Transition in Quantum Wires and Localization in the Inhomogeneous One-Dimensional Electron Gas." Diss., 2013. http://hdl.handle.net/10161/7191.
Full textIn this work, we study two important themes in the physics of the interacting one-dimensional (1D) electron gas: the transition from one-dimensional to higher dimensional behavior, and the role of inhomogeneity. The interplay between interactions, reduced dimensionality, and inhomogeneity drives a rich variety of phenomena in mesoscopic physics. In 1D, interactions fundamentally alter the nature of the electron gas, and the homogeneous 1D electron gas is described by Luttinger Liquid theory. We use Quantum Monte Carlo methods to study two situations that are beyond Luttinger Liquid theory --- the quantum phase transition from a linear 1D electron system to a quasi-1D zigzag arrangement, and electron localization in quantum point contacts.
Since the interacting electron gas has fundamentally different behavior in one dimension than in higher dimensions, the transition from 1D to higher dimensional behavior is of both practical and theoretical interest. We study the first stage in such a transition; the quantum phase transition from a 1D linear arrangement of electrons in a quantum wire to a quasi-1D zigzag configuration, and then to a liquid-like phase at higher densities. As the density increases from its lowest values, first, the electrons form a linear Wigner crystal; then, the symmetry about the axis of the wire is broken as the electrons order in a quasi-1D zigzag phase; and, finally, the electrons form a disordered liquid-like phase. We show that the linear to zigzag phase transition occurs even in narrow wires with strong quantum fluctuations, and that it has characteristics which are qualitatively different from the classical transition.
Experiments in quantum point contacts (QPC's) show an unexplained feature in the conductance known as the ``0.7 Effect''. The presence of the 0.7 effect is an indication of the rich physics present in inhomogeneous systems, and we study electron localization in quantum point contacts to evaluate several different proposed mechanisms for the 0.7 effect. We show that electrons form a Wigner crystal in a 1D constriction; for sharp constriction potentials the localized electrons are separated from the leads by a gap in the density, while for smoother potentials, the Wigner crystal is smoothly connected to the leads. Isolated bound states can also form in smooth constrictions if they are sufficiently long. We thus show that localization can occur in QPC's for a variety of potential shapes and at a variety of electron densities. These results are consistent with the idea that the 0.7 effect and bound states observed in quantum point contacts are two distinct phenomena.
Dissertation
Dong, Yao-Jhong, and 董耀中. "Growth mechanism of CuO one-dimensional nanostructures by thermal oxidation process and their CO gas sensing properties." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/95176930067603502799.
Full text國立中興大學
材料科學與工程學系所
98
We have successfully synthesized one-dimensional CuO nanowires by thermal oxidation and observed their growth mechanism. The CuO nanowires were adopted to fabricate a simple gas sensor which can be used for detecting low concentration CO. In the atmosphere at temperatures between 300℃ to 600℃, CuO nanowires could be grown. Once the annealing temperature was higher than 700℃or lower than 200℃, no CuO nanowires could be formed. The varieties of synthesis temperature would affect the diameters of CuO nanowires, and the lengths of nanowires would increase with increasing synthesis time. The diameters of CuO nanowires synthesized at 450℃for 6 hours were approximately 130 nm, and the lengths could be up to 15μm or longer. It was found that the number of nanowires synthesized by thermal oxidation would decrease when the substrate was annealed for longer time, which suggests that the CuO nanowires might be grown by the anisotropic atomic diffusion mechanism. The as-synthesized CuO nanowires were indentified as a monoclinic crystal structure and cumulated along with (110) by XRD and TEM analysis. The gas sensor device fabricated by CuO nanowires exhibited good response capacity for detecting low CO concentration at an operating temperature of 300℃. The sensitivity of the gas sensor could be up to 181% at CO concentration of 50ppm, and could still reach 138% even if the CO concentration was as low as 5ppm. At low CO concentration, the response and recovery times for the gas sensor device were on average about 180 seconds and 220 seconds, respectively. Therefore, CuO nanowires have great potential for low- concentration CO gas sensor device.
Gouws, Johannes Jacobus. "Combining a one-dimensional empirical and network solver with computational fluid dynamics to investigate possible modifications to a commercial gas turbine combustor." Diss., 2007. http://upetd.up.ac.za/thesis/available/etd-04212008-074344/.
Full textKo, Rong-Ming, and 柯榮明. "Study on the Growth Mechanisms of One-Dimensional Tungsten Oxide Nanostructures and Their Applications in Gas Sensors and Field Emitters." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/82952078034745784202.
Full text國立成功大學
微電子工程研究所碩博士班
97
In this thesis, study on the growth mechanisms of the evolution of one-dimensional tungsten oxide (TO) nanostructures from nanowires to nanosheets and their applications in gas sensors and field emitters were proposed and investigated. Nanowires and nanobelts were self-synthesized on sputter-deposited tungsten-based thin film by a simple thermal annealing process in N2 ambient. Techniques of various analysis including FESEM, HRTEM, SAED, XRD and XPS were employed to characterize the growing conditions and properties of nanostructures. In addition, a measurement system consists of Agilent 34970A, E3646A and HP 4284A LCR meter, was used for gas sensing measurement. In addition, Keitheley 237 was also used to measure the field-emission characteristics, which was carried out at room temperature in a vacuum chamber with a pressure of 5×10-6 torr. The dependences of the field enhancement factor (β), driving current, and turn-on voltage were extracted by current-voltage characteristic based on Fowler-Nordheim equation. First, a possible mechanism for the transformation of nanomorphology from wires to sheet is reported. In experiments, a simple thermal annealing process was employed to self-synthesize TOs nanostructures on sputtering-deposited tungsten films in N2 ambient with thermal budgets of 750°C for 0.5~3 h and 650~900°C for 0.5 h, respectively. Based on experimental results, the lower limit of temperature for the self-synthesis of tungsten oxide nanowires (TONWs) from sputtering-deposited W films might lie in the range of 500~600°C, which could be related to the temperature necessary to provide enough activation energy for the formation of WOx nanocrystallites and W18O49 nucleation sites. For samples annealed at 750°C for 0.5 and 1 h, dense and uniformly distributed TONWs with typical diameters of 15~25 nm, typical lengths of 0.15~0.30 μm, and typical densities of 250~300 μm-2 were obtained. The self-synthesis of TONWs can be related to the formation of WOx nanocrystallites caused by chemical reaction of tungsten and oxygen contained in the film and then commenced from the nucleus sites of W18O49 crystallites at the grain boundaries of WOx nanocrystallites on the surface of samples during thermal annealing. Oxygen might be from impurities in the tungsten target and/or the exposure of tungsten films to air. Further increases the thermal budgets, which samples annealed at 750°C for >2 h or >850°C for 0.5 h, a drastic change in surface morphologies of the annealed samples with both the density and size of the nanosheets are seen increasing accompanied with the decrease in the wire density is observed. Both the self-synthesis of the TO nanowires and nanobelts have been identified that comprise the major crystallization phase of monoclinic W18O49 (JCPDS No. 36-0101) with a growth direction of [010]. In addition, based on experimental results that show the formation and re-crystallization of an amorphous interface layer between two neighboring nanowires which were linked together by their (502) planes, a possible mechanism for the transformation of nanomorphology from wires to sheet was proposed. First, neighboring nanowires might connect to each other with misalignments along their [010] direction because the nanowires are dense (250~300 μm-2) and random in orientation. Then, a twist and/or rotation misalignment ent between their (502) planes might be presented. However, the boundary is not stable, which should give it a higher surface energy. Accordingly, the divergence of the crystallography was tailored during thermal annealing and led to the formation of an amorphous interface. Once the thermal budget was high enough, the amorphous interface re-crystallized to further reduce the surface energy of the two amorphous/ (502) interfaces. Finally, all interfaces or boundaries disappeared and nanosheets with the same crystallography of W18O49 was formed. The same evolution process is also applicable to the formation of nanobundles from more than two neighboring nanowires, which were also found in samples annealed at a high thermal budget. Essentially, the use of TONWs as gas sensing materials is very attractive because they exhibit physical and chemical properties that are very different from those of their bulk or film counterparts. In addition, the sensitivity of TONW sensors to gases can be substantially improved and the working temperature can also be reduced because of the large surface to volume ratio (SVR) as well as the enormous number of surface atoms and/or dimensional confinement of electrons. Therefore, a three-layer structure TONW-based gas sensor was fabricated and its sensing performance for NO2 of different concentrations at different working temperatures was also investigated. During the fabrication processes of the proposed TONW-based gas sensor. N-type Si wafers and WCx (W:C=70:30 wt%) target were used. RF sputtering and plasma-enhanced chemical vapor deposition (PECVD) were employed for the deposition of WCx (W:C=70:30 wt%) electrodes and the SiO2 layer, respectively. The thicknesses of the bottom electrodes, middle SiO2 layer and top electrodes were 60, 300 and 120 nm, respectively. Then, the devices were patterned by reactive ion etching (RIE)and subjected to buffer oxide wet etching for 90 s to remove the SiO2 layer from the periphery. Finally, thermal annealing at 750°C in N2 (60 sccm) ambient for 30 min was conducted for the self-growth of TONWs in the window area created by the side etching of the SiO2 layer. Experimental results showed that self-growth TONWs have main phase of W18O49(010) and typical lengths and diameters of 0.15~0.4 μm and 17~25 nm, respectively. The present sandwich structure allows TONWs to firmly link the top and bottom electrodes without the use of submicron photolithography. The monoclinic W18O49 behaves as an n-type semiconductor with oxygen vacancies. Essentially, a single TONW has SVRs of around (1.6~2.35)×106 cm-1, which was found to be about 7.5~11.6 times higher than those of the film WO3 sensors prepared at a firing temperature of 700°C. Because of the presence of oxide vacancies and large SVR of TONWs for gas absorption, good sensor performance with a sensitivity as high as 9.3, a short response time (about 9 s), and a detectability of 2 ppm of NO2 was achieved using eight sensors in a series connection. It is expected that the sensitivity of gas sensors can be further increased by increasing the number of TONWs in each cell in series-connected sensors. In addition, the self-synthesis of TONWs with a high aspect ratio had been obtained from our previous studies, which exhibit good electron field emission characteristics with a typical turn-on field of about 1.7 V/μm were comparable with CNTs. In order to expand its application into low voltage vacuum operable microelectronics, use of current fusing method for the fabrication of lateral W18O49 nanowires in a tip-to-tip configuration with a nanogap is proposed for the first time. The key fabrication processes of the proposed lateral-type field emission device is divided into two main stages. Firstly, n-type 0.01 Ω-cm <100> silicon wafers were used and the 500-nm-thick wet SiO2 layer was grown at 1050°C for 1 h. In this stage, silicon-on-insulator (SOI) substrates were obtained. Secondary, 50-nm-thick patterned W films with tunnel length of 20 μm and width of 5 μm were sputter-deposited on the SOI substrate by photolithography and dc sputtering method. Then, current densities ranging from 220 to 280 mA/μm2 were applied to the W films on SOI for current fusing in atmospheric air. It was found that, for 50-nm-thick patterned W films, the critical current density for the generation of nanogap is about 220 mA/μm2. The nanogaps were observed widening as the current density was further increased. When the density was driven over 280 mA/μm2, it might cause an instant over-heating and destroy the W thin film on the edge of the nanogaps. Based on our experimental results, under an optimized current density of 240 mA/μm2 for 10 s, nanogap in the range of 0.2~0.4 μm could be obtained. Finally, all fused samples were subjected to thermal annealing from 750 to 850°C temperature in N2 ambient for 30 min. It was found that the sample annealed at 800°C exhibited uniform morphology of TONWs on the edges of the nanogap. The typical length, diameter, and aspect ratio of TONWs grown on the sample annealed at 800°C were 125~220 nm, 17~25 nm, and 5~13, respectively, while the effective nanogap of the lateral TONWs in tip-to-tip configuration were further reduced to be of about 0.18 μm. A comparison for the 750°C and 850°C samples, it reveals that the turn-on voltage is quite high (about 16.5 and 12 V, respectively) at 1 μA and the field enhancement factor is very low (about 56 and 340 μm-1 respectively). However, the 800°C-annealed sample exhibited a fairly good field emission characteristics with a low turn-on voltage of 2.7 V at 1 μA and a high electric field enhancement factor of ~ 660 μm-1. Stable and profound Fowler-Nordheim characteristics were observed at around 81.8 V with the FE current in excess of 8 mA. The relatively low turn-on voltage might be attributed to the high aspect ratio of TONWs and the realization of the nanogap of the lateral TONWs in tip-to-tip configuration.