Dissertations / Theses on the topic 'Natural gas Environmental aspects Australia'

Storm water sediment runoff from disturbed landscapes has the potential to impair aquatic environments. Small construction sites of 1-5 acres in the United States are currently regulated by the United States Environmental Protection Agency to minimize storm water runoff damages to the environment. Gas well construction sites are similar to other construction sites in how the landscape is altered, but are not similarly regulated. This study identified sediment runoff from gas well development sites by collecting it in traps and weirs, and by measuring sediment debris lobes. Sediment primarily consisted of silt and clay sized particles. Sediments from two gas well sites formed five debris lobes that ranged in size from 325 to 3,290 square feet. Sediment loadings estimated from the debris lobes averaged 57.1 tons per year/acre. Future studies should focus on further quantification of sediment movement off of gas well sites and identify effective erosion control methods.

The subject of this thesis is the development of alternative approaches to environmental management and mine closure plans using case examples of the Big Bell/Cue Mining District and as a working example, an area of unconfined washout of historical gold-mine process tailings located in this arid inland region of Western Australia. This is considered appropriate in the light of the social and political thrust for industry to develop simultaneously positive economic, social and environmental outcomes from their activities. The Big Bell mining operation ceased mining in June 2003 and the Mine Closure Plan reflected a classical approach of minimization of public liability and strict compliance with legislative requirements. During the life of the modern mine the approach to rehabilitation was similarly classical in its approach It is intended for this document to inform the mining industry using the case example of the now closed Big Bell Mine as to how greater long-term outcomes may have been achieved for the State and the region for the future. This thesis specifically investigates alternative ways to approach rehabilitation in arid areas of Western Australia using the washout area as an example and trial area. This thesis has approached the issue by addressing the quantification of what has occurred through the gathering of baseline data of the case study area and then by the implementation of a series of relevant trials to identify appropriate eco-functional process-sensitive methods for rehabilitation as an alternative to current industry practice. Trials investigating the use of "retention banks" and "clay/seed balls" and the use of ex-mine milling waste carbon were conducted to investigate relevant possible techniques suitable for arid mine-site waste dump rehabilitation. Data analysis indicated that the main reason for the high level of degradation within the case study area is due to the smothering effect of the fine clayey tails cover and due to acidity of the tailings. A detailed examination of 92 soil samples found water infiltration of tails-washed areas as half that of control areas. Acidity of alluvium has declined from pH 5.2 to 3.8. The acidity has penetrated at depth to hardpan. Trials were commenced to rehabilitate the area using a combination of earthworks (retention banks and· scarification), pH- adjustment (using ex-mill carbon and crushed lime), and the use of native seed pelletised into clay-balls. The introduction of ex-mill carbon was shown to be effective in ameliorating pH in the tails wash area and improving its capacity to regenerate. Considering it is a widely available waste product with the gold mining industry it should be seriously considered in its application for rehabilitation purposes, and specifically in areas affected by severe acidification and desertification particularly by mismanaged tailings with pyrite content. The use of clay balls should also be subjected to further investigation. It is at least equal to the traditional use of raw seed and fertilizer with immediate and abundant rainfall. As this almost never occurs, it should prove to be superior, in delivering higher rates of viability for seed used. The thesis then attempts to integrate this study within the context of the wider issues of environmental management, specifically the best practice of mine closure plans and the adoption of sustainable economic, social and environmental outcomes from mining as an integral part of responsible operational environmental management plans. The thesis argues that the environmental management planning and specifically the Mine Closure Plan should not waste the myriad of opportunities that are the by-product of mining for the long-term sustainable benefit of the wider region. It is argued that if mining companies are serious about sustainability, then they cannot continue with short-term cycles of mining and closure. However to be realistic it will take concerted willingness from all stakeholders to pursue these outcomes. While a given mining operation can offer extensive resources and assets to support this approach the commercial and legislative pressures of core mining activities necessarily mean that mines are in fact encouraged to simply return the environment back to as natural state after operations are complete. Invariably this means hundreds of millions of dollars of infrastructure are levelled and scrapped to avoid all future liability, whilst the potential for sustainable outcomes is essentially ignored. The same Government that enforces the Mining Act and has a State Sustainability Strategy imposes the conditions which create unimaginative classical mine closure plans. Government, industry and the residents of regions must work together to seriously develop sustainable outcomes to mining.

Thesis (PhD)--Stellenbosch University, 2012.
ENGLISH ABSTRACT: World crude oil demand and production is set to increase in the long term and is projected to increase from 82 barrels per day in 2007 to an estimated 104 million barrels per day in 2030 according to the International Energy Agency. The environmental challenges posed by the current and projected increased future fuel use, with specific reference to air, aquatic and terrestrial impact, are driving producers and legislators to change fuel specifications and consequently fuel properties to be less harmful to the environment. Traditionally transportation fuels are produced through crude oil refining but in South Africa more than one third of the liquid fuels are produced synthetically through catalytic conversion of gassified coal via the Fischer-Tropsch process by Sasol. Diesel from syncrude is referred to as synthetic diesel and the refiner must blend various hydrocarbon streams, effectively tailoring the diesel to its final composition. Biodiesel from renewable sources like vegetable oils is considered environmentally more acceptable than petrodiesel because of its high biodegradability in the environment, lower sulphur and aromatic hydrocarbon content as well as lowered particulate content in the exhaust emissions. The present research was aimed at evaluating whether the composition of diesels derived from different feed stocks, that included coal, natural gas, crude oil and soybean oil, would influence its biodegradability and ecotoxicity. Acute aquatic tests that included freshwater fish, crustaceans, algae and marine bacteria were used to determine the acute toxicity of diesels. In addition, quantitative structure activity relationship models were used to estimate the biodegradation and ecotoxicity properties of the diesels in an attempt to develop a cost effective tool to determine those properties. The results indicated that the 2-D GC technique quantitatively and qualitatively identified the hydrocarbon constituents in the diesels. The relevance of using the 2-D GC technique was in identifying and quantifying the hydrocarbon breakdown products and being used in a mass balance to confirm the potential biological breakdown processes of the materials used in the present study. The differences in theoretical oxygen demand (ThOD) of the different experimental diesel blends using various blending materials and biodiesel, emphasised and confirmed the importance of calculating the ThOD for the respective blending materials when measuring the biodegradation rates. Furthermore, the biodegradation hierarchy of Pitter and Chudoba (1990) in order of decreasing biodegradability: alkanes > branched alkanes > cyclo-alkanes > aromatic hydrocarbons, could be expanded to include FAME: FAME > alkanes > branched alkanes > cyclo-alkanes > aromatic hydrocarbons. The biochemical pathways identified for the biodegradation of all the diesels was enzyme-enhanced β-oxidation. The present research also indicated that biodiesel addition to crude-derived diesels to increase the density to within the current required specifications for diesels cannot be a reality in SA because of the underdeveloped biodiesel industry. To increase the density by using biodiesel to within the specification for GTL diesel, more than 27% biodiesel would be required, which is currently is not achievable from an economic perspective as well as governmental national strategy perspective. The addition of biodiesel as lubricity enhancer seems more plausible, because less than 5% would be required for petrodiesels. The results on the ecotoxicity of the diesels and diesel blends demonstrated a general lack of acute toxic effect, especially for the fish and crustaceans used during the present study. Although algal and bacterial tests showed an effect at most of the WAF loading rates, none were high enough to enable the calculation of a median effect loading rate (EL50). QSAR‟s, like EPI Suite, together with prediction models, like the Fisk Ecotoxicity Estimation Model, can be used to screen for ecotoxicity and biodegradability of hydrocarbons found in Petrodiesels. It was less applicable for the prediction of biodiesel constituents. The use of different cut-off values for the constituents of biodiesel could be developed in future research. The use of this combination enabled the present research into the potential toxicity of hydrocarbon mixtures to be conducted, especially since tests on individual constituents are impractical. QSAR‟s may provide a relatively cost-effective way to screen for potential environmental acceptability of such mixtures. The contributors to the toxicity of mixtures of hydrocarbons found in diesels were evaluated and it appears that paraffins contribute more to the overall toxicity than previously thought and aromatics less. By putting well-defined policies and incentives in place, a robust biodiesel industry could be created that will enable SA to contribute to the mitigation of the threat of climate change, to become less dependent on foreign oil and to develop rural agriculture. The key to energy security is not one solution to South Africa‟s energy needs, but a multifaceted approach to the complex subject of sustainable energy security. The end of the hydrocarbon era of energy is not in sight, at least for the near future, but soon even hydrocarbon energy in the form of coal and crude oil will have to be re-evaluated as SA‟s major energy resource for economic and energy security. In SA the potential of developing natural gas resources through fracking, nuclear, solar, wind, biological and even wastes to energy processes as well as better energy efficiency, in a balanced and diverse energy portfolio, could pave the way toward energy security in the long run.
AFRIKAANSE OPSOMMING: Ru-olie aanvraag en produksie wêreldwyd is besig om toe te neem en die Internasionale Energie Agentskap projekteer dat wêreld ru-olie verbruik sal toeneem van 82 vate per dag in 2007 tot „n beraamde 104 vate per dag in 2030. Die omgewings uitdagings wat huidige en toekomstige toename in brandstof verbruik, spesifiek die impak op lug gehalte, water- en grond, mag hê, is dryfvere vir produseerders en reguleerders om brandstof spesifikasies te verander om minder omgewings impak te veroorsaak. Brandstof vir vervoer doeleindes word oor die algemeen van ru-olie gemaak, maar in Suid Afrika word ongeveer „n derde van die vloeibare brandtof gemaak deur middel van gekatiliseerde omskakeling van vergasde steenkool via die Fischer-Tropsch proses by Sasol. Diesel wat uit sintetiese ru-olie gemaak is, is sinteties en die raffineerder moet verskillende koolwaterstof strome meng om „n finale produk te lewer. Biodiesel wat uit hernubare hulpbronne soos plant-olies en diervet gemaak word, kan oorweeg word vir die vervaardiging van meer omgewings aanvaarbare brandstof met laer swael en aromatiese koolwaterstof inhoud en ook minder partikel inhoud in die uitlaatgas. Die huidige navorsing het beoog om te evalueer of die samestelling van diesels wat vervaardig is uit verskillende hulpbronne, wat steenkool, aardgas, ru-olie en sojaboon olie ingesluit het, die biodegradeerbaarheid en ekotoksisiteit kan beïnvloed. Akute akwatiese toetse wat varswater vis, krustaseë, alge en marine bakterieë ingesluit het, was aangewend om die akute toksisiteit van die diesels te bepaal. Kwantitatiewe struktuur aktiwiteit verwantskaps modelle is ook gebruik om die biodegradeerbaarheid en ekotoksisiteits eienskappe van die diesels te beraam om vas te stel of 'n bekostigbare alternatief beskikbaar is om daardie eienskappe te bepaal. Die resultate het aangedui dat die 2D GC tegniek kwantitatief en kwalitatief gebruik kan word om die koolwaterstowwe in die diesels te identifiseer. Die benutting van die 2D GC tegnieke is egter om die koolwaterstof afbraak produkte te identifiseer en ook om die massa balans gedurende die biodegradering te bevestig. Die verskil in teoretiese suurstof aanvraag van die verskillende diesels het die belangrikheid daarvan blemtoon en bevestig om die teoretiese suurstof aanvraag korrek te bereken en sodoende die biodegradasie korrek te bepaal. Verder kan die biodegradasie hierargie van Pitter en Chudoba (1990) volgens afnemende biodegradasie: alkane > vertakte alkane > siklo-alkane > aromatiese koolwaterstowwe, uitgebrei word om vetsuur-metielesters in te sluit: vetsuur-metielesters > alkane > vertakte alkane > siklo-alkane > aromatiese koolwaterstowwe. Die biochemiese roetes wat geïdentifiseer is vir die biodegradasie van die diesels, was ensiem-verbeterde β-oksidasie. Die huidige navorsing het ook aangedui dat biodiesel toevoeging tot ru-olie vervaardigde diesel om die digtheid te verhoog to binne huidige spesifikasies is nog nie lewensvatbaar in Suid Afrika nie as gevolg van die onderontwikkelde biodiesel industrie. Om die digtheid te verhoog met biodiesel tot binne spesifikasie verg meer as 27% biodiesel en is huidiglik nie haalbaar vanuit 'n ekonomiese persketief en ook nie vanuit 'n regerings nasionale strategie perspektief nie. Die toevoeging van biodiesel as lubrisiteits vervetering blyk meer van toepassing te wees aangesien minder as 5% biodiesel toevoeging benodig sou wees. Die resultate van die ekotoksisiteits toetse het 'n algemene gebrek aan akute toksisiteits effek aangedui, veral vir vis en skaaldiere wat in die huidige studie gebruik is. Howel alge en bakteriële toetse daarop gedui het dat 'n toksiese effek wel aanwesig was, was dit gering en kon die median effektiewe ladings koers (EL50) nie bepaal word nie. QSARs, soos Epi Suite, tesame met voospellings modelle, soos die Fisk Ecotoxicity Estimation Model, kan gebruik word om ekotoksisiteit en biodegradeerbaarheid van koolwaterstowwe in petrodiesels te beraam, alhoewel dit minder van toepassing was op biodiesel. Die gebruik van ander afsny waardes spesifiek vir biodiesel kan oorweeg word in toekomstige navorsing. Die molecules wat bygedra het tot die toksisiteit van die koolwaterstof mengsels was geëvalueeren daar is gevind dat die paraffiniese molekules meer begedra het tot die totale toksisiteit en die aromate minder. Deur goed gedefinieerde beleid en aansporings meganismes inplek te sit, kan 'n biodiesel industrie in SA geskep word wat SA sal help om by te dra tot die bekamping van klimaats vendering en sodoende minder afhanklik te wees van buitelandse olie en ook landbou in SA te bevorder. Die sluetel tot energie sekuriteit is nie een oplossing vir SA se energie aanvraag nie, maar eerder 'n veelsydige benadering tot die komplekse onderwerp van volhoubare energie sekuriteit. Die einde van koolwaterstof energie is nog nie in sig nie, ten miste nie in die nabye toekoms nie, maar binnekort sal selfs koolwaterstof energie in die vorm van steenkool en ru-olie heroorweeg moet word as SA se hoof energie hulpbronne vir ekonomiese en energie sekuriteit. In SA moet die potensiaal van natuurlike gas ontginning deur middel van hidrauliese breking, kernkrag, wind energie, biologiese energie en selfs afval tot energie prosesse bestudeer word, so-ook beter energie doeltreffendheid om sodoende 'n gebalansweerde energie portefuelje te skep wat die weg sal baan na energie sekuriteit op die lang termyn.

The differential role that airborne particulate matter (PM) size fractions, sources, and components play in producing adverse health effects is not fully understood. Specific gaps include the role of PM generated by traffic and the effects of PMs generated by natural sources. Source specific air pollution epidemiological research still lacks integration in the risk assessment process, a fundamental tool to inform policy makers and the public about the current situation or the impact of future or past air pollution policies. This thesis addresses both these gaps. To explore the effects of PM from different sources, we investigated the association between different PM size fractions and mortality in Barcelona, Spain and used PM chemical composition data to help determine the different sources and components linked to toxicity. To illustrate that local air pollution risk assessments are useful tools in evidence-based public health, we estimated the health and economic benefits that would result from different scenario of improved air quality in the Barcelona metropolitan area and in two communities of Southern California. These case studies include new methods to integrate into the risk assessment process the recent epidemiological evidence related to the effects of traffic exposure.This thesis contributes to a better understanding of the link between particulate matter size fraction, sources, and components and health effects, and to improve air pollution health impact assessment methods. Both contributions have important implications for public health and air pollution public policy.
El papel diferencial en que las diferentes fracciones de partículas en suspensión en el aire (PMs), sus fuentes y componentes producen efectos adversos para la salud no está completamente entendido. Las lagunas actuales incluyen el papel de las PMs generadas por el tráfico y los efectos de las PMs generadas por fuentes naturales. La investigación epidemiológica relacionada con fuentes todavía falta ser integrada en el proceso de evaluación de impacto, una herramienta fundamental para informar a los tomadores de decisiones y el público sobre la situación actual o el impacto de futuras o pasadas políticas de contaminación atmosférica. Esta tesis trata estas áreas. Para explorar el papel de las PMs generadas por diferentes fuentes, se ha investigado la asociación entre diferentes fracciones de PMs y mortalidad en Barcelona (España) y se ha usado datos de composición química de PMs para identificar las fuentes y los componentes relacionados con la toxicidad. Para ilustrar que las evaluaciones de impacto a nivel local son herramientas útiles en salud pública, se ha estimado el beneficio en salud y económico que resultaría de diferentes escenarios de mejora de la calidad del aire en el área metropolitana de Barcelona y en dos comunidades de California del Sur. Estos estudios de casos incluyen nuevos métodos para integrar en las evaluaciones de impacto las nuevas evidencias epidemiológicas que relacionan la exposición al tráfico con los efectos en salud. Esta tesis contribuye a un mayor entendimiento del vínculo entre las fracciones de PM, sus fuentes y componentes y los efectos en salud así como a la mejora de los métodos de las evaluaciones de impacto. Estas contribuciones tienen importantes implicaciones para la salud pública y las políticas públicas de contaminación atmosférica.

In order to better understand runoff characteristics from natural gas well sites in north central Texas, the City of Denton, with assistance through an EPA funded 104b3 Water Quality Cooperative Agreement, monitored storm water runoff from local natural gas well sites. Storm water runoff was found to contain high concentrations of total suspended solids (TSS). Observed TSS concentrations resulted in sediment loading rates that are similar to those observed from typical construction activities. Petroleum hydrocarbons, in contrast, were rarely detected in runoff samples. Heavy metals were detected in concentrations similar to those observed in typical urban runoff. However, the concentrations observed at the gas well sites were higher than those measured at nearby reference sites. Storm water runoff data collected from these sites were used to evaluate the effectiveness of the water erosion prediction project (WEPP) model for predicting runoff and sediment from these sites. Runoff and sediment predictions were adequate; however, rainfall simulation experiments were used to further characterize the portion of the site where drilling and extraction operations are performed, referred to as the "pad site." These experiments were used to develop specific pad site erosion parameters for the WEPP model. Finally, version 2 of the revised universal soil loss equation (RUSLE 2.0) was used to evaluate the efficiency of best management practices (BMPs) for natural gas well sites. BMP efficiency ratings, which ranged from 52 to 93%, were also evaluated in the context of site management goals and implementation cost, demonstrating a practical approach for managing soil loss and understanding the importance of selecting appropriate site-specific BMPs.

Farmers in Australia and elsewhere face the challenge of remaining profitable whilst dealing with adverse structural arrangements and public expectations to better manage environmental degradation. This thesis draws on arguments that dominant paradigms in agricultural science and environmental management have often been ineffective in addressing these apparently competing demands and appear poorly suited to ‘messy’ situations characterized by uncertainty and complexity, and in which diverse stakeholders are motivated by varying goals and values. Engaging with such situations requires a philosophy and methodology that accepts a multiplicity of perspectives and which seeks to learn about and reflect upon novel ways of thinking and acting. Among the underlying ideas that have shaped this project is the importance of recognising the assumptions and commitments that researchers bring to their practice in order that traditions are not uncritically reproduced and that the products of our thinking are not reified. Regarding farming as less a set of technical practices and more as a human activity taking place within broader economic, social, cultural and ecological contexts, I sought to engage a group of farmers in southern Western Australia in a process of taking action to address an issue of common concern that would help them to live and farm well in their district. My role as both researcher and facilitator of conversations was driven by a commitment to dialogue as a process of meaning making and relationship building. Together we explored some of the broader contexts within which the narrower conceptions of economic and ecological problems are often uncritically placed. Taking concrete action together however proved beyond the scope of my research. The challenge of feeding ourselves while better caring for the land and each other will require imaginative as well as technical resources. To this end I have also sought to sketch out some of the creative possibilities contained within the health metaphor as it is applied to soil, arguing that its use as a proxy for quality or condition fails to utilize its disruptive potential.

Environmentalists see the protest against the Jabiluka uranium mine in Australia's Northern Territory as an example of positive green-black relations. The formation of an alliance between Aboriginal owners and greens to protest against the mine resulted in a lengthy campaign that included maintaining a camp near the leasesite and organising a long series of mass protest actions in a remote location over an extended period from March to October 1998. However, some tensions between greens and the traditional Aboriginal owners became evident as the campaign went on. This thesis traces the origins of these tensions to past conflicts between environmentalists and Aboriginal people and shows that they are largely related to their conflicting perceptions of the environment. Those perceptions arise from different knowledge systems and are encapsulated in the terms 'wilderness' and 'country', used to describe the physical world by environmentalists and Aboriginal owners respectively. I discuss the attitudes towards the environment that accompany those perceptions and consider the way they were manifest in some of the tensions that arose at Jabiluka. The close relationship between influential strands of environmentalism and Western science is a related source of conflict. My analysis of that relationship shows that environmentalism, via 'green science' is more closely aligned with the developmentalist worldview than the Aboriginal worldview. The thesis is an analytical reflection upon the Jabiluka Protesters' Camp based on the personal experience I gained from my fieldwork there and informed by the literature of feminism, ecofeminism, social constructionism and anthropology. I discuss the manifestations of ecofeminism I observed at Jabiluka. I argue that the Jabiluka Protesters' Camp functioned successfully because it utilised ecofeminist principles and practices, that as a consequence the relationship between greens and blacks has been strengthened and therefore that ecofeminism can continue to have a positive effect on those relations in the future.

Emissions of air pollutants from non-conventional sources have been on the rise in the North Texas area over the past decade. These include primary pollutants such as volatile organic compound (VOC) and oxides of nitrogen (NOx) which also act as precursors in the formation of ozone. Most of these have been attributed to a significant increase in oil and gas production activities since 2000 within the Barnett Shale region adjacent to the Dallas-Fort Worth metroplex region. In this study, air quality concentrations measured at the Denton Airport and Dallas Hinton monitoring sites operated by the Texas Commission on Environmental Quality (TCEQ) were evaluated. VOC concentration data from canister-based sampling along with continuous measurement of oxides of nitrogen (NOx), ozone (O3), particulate matter (PM2.5), and meteorological conditions at these two sites spanning from 2000 through 2014 were employed in this study. The Dallas site is located within the urban core of one of the fastest growing cities in the United States, while the Denton site is an exurban site with rural characteristics to it. The Denton Airport site was influenced by natural gas pads surrounding it while there are very few natural gas production facilities within close proximity to the Dallas Hinton site. As of 2013, there were 1362 gas pads within a 10 mile radius to the Denton Airport site but there were only 2 within a 10 mile radius to Dallas Hinton site. The Dallas site displayed higher concentrations of NOx and much lower concentrations of VOC than the Denton site. Extremely high levels of VOC measured at the Denton site corresponded with the increase in oil and gas production activities in close proximity to the monitoring site. Ethane and propane are two major contributors to the measured VOC concentration, suggesting the influence of fugitive emissions of natural gas. In Dallas, the mean and maximum values of ozone had decreased since 2000 by about 2% and 25%, respectively. Similarly NOx decreased by 50% and 18% in the mean and maximum values. However, the mean VOC value showed a 21% decrease while the maximum value increased by about 46%. In Denton, the change in percentage of ozone and NOx were similar to Dallas but the mean VOC concentration increased by about 620% while the max value increased 1960%. Source apportionment analysis confirmed the findings by identifying the production of natural gas to be the primary source of VOC emissions in Denton, while traffic sources were more influential near the Dallas site. In light of the recent proposal by EPA to revise the ozone standard, the influence of these new unconventional sources should be further evaluated.

Natural gas flaring from oil production is a pervasive yet understudied environmental issue. Recently available satellite imagery of gas flares has increased public awareness and concern over the severity and ubiquity of the problem. In the US, the relatively recent combination of hydraulic fracturing and horizontal drilling sparked the shale boom, leading to hundreds of thousands of wells being drilled within a decade, often in close proximity to residential populations. A major oil state that has emerged from the shale boom is North Dakota. In 2014, state regulators introduced a policy to limit the percentage of produced gas that oil-extracting companies are allowed to flare. Like many other places where flaring takes place, flared volumes are reported by oil companies themselves. What was the effect of North Dakota’s regulation on gas flaring according to self-reported and satellite data? What was the effect of the regulation on self-reporting behavior? In such a tight oil setting, how well does the prevailing satellite product used to monitor gas flares perform? This dissertation uses new data and methodologies from several disciplines to study these important questions around gas flaring. The results find that the predominant satellite product does not perform well in the on-shore oil production context. While regulation has reduced flaring in a major oil state, the reduction is smaller than thought because of underreporting by oil well operators. Further, the underreporting is associated with political economy and corporate culture factors.

A general finding from the growing literature applying 'real options' theory to investment under carbon emission pricing schemes (CEPSs), is that the level of uncertainty in the expected price of carbon is a key factor in the extent to which a CEPS's design provides incentives for a firm to invest in lower carbon emissions technologies. Notwithstanding this finding, major public policy analyses of CEPSs have not utilised real options analysis to gain insights into the effect of a scheme's design on the likely investment behaviour of firms. This thesis argues that real options analysis should be included in the suite of tools for informing public policy on the design of a CEPS. This thesis contributes to understanding the features of a CEPS's design on the decision of a firm in an energy-intensive sector to invest in new lower-carbon emitting plant, when the investment decision lends itself to being characterised as a real option. In contrast to existing real options studies in this area, a simpler analytic approach is adopted based on a model by Cortazar et al. (1998). The approach captures output price and carbon price uncertainties and is solved using contingent claims analysis to find the critical price of output required to trigger the decision to invest. Two empirical applications examine in detail a representative electricity generator's decision to invest in a range of low carbon-emitting and non-carbon emitting electricity generation technologies. The analysis of both a hypothetical CEPS's design in general, and the post-2015 carbon emissions trading scheme under Australia's Clean Energy Future package (CEFETS) in particular, show that there are four effects on the threshold required by a generator to trigger investment in a technology that are attributable to the design of a scheme. In addition to the impact of volatility in the carbon price and its correlation with the output price (the volatility effect) highlighted in other real options studies, three additional investment threshold effects are found that may jointly impact on a firm's decision to invest in a particular technology depending on the design of a CEPS. The three effects consist of the cost effect, the negative cost effect and the subsidy effect. The cost effect arises from the level of the carbon price and impacts only carbon emitting technologies. The negative cost effect and subsidy effect arise from allocations of free carbon emissions rights under a CETS that directly subsidises either a plant's operating costs or investment cost, respectively, and may apply to all technologies.

Anthropogenic greenhouse gas emissions (GHG) contribute to global warming, and must be mitigated. With GHG mitigation as an overarching goal, this research aims to study the potential for newfound and abundant sources of natural gas to play a role as part of a GHG mitigation strategy. However, recent work suggests that methane leakage in the current natural gas system may inhibit end-use natural gas as a robust mitigation strategy, but that natural gas as a feedstock for other forms of energy, such as electricity generation or liquid fuels, may support natural-gas based mitigation efforts. Flaring of uneconomic natural gas, or outright loss of natural gas to the atmosphere results in greenhouse gas emissions that could be avoided and which today are very large in aggregate. A central part of this study is to look at a new technology for converting natural gas into methanol at a unit scale that is matched to the size of individual natural gas wells. The goal is to convert stranded or otherwise flared natural gas into a commercially valuable product and thereby avoid any unnecessary emission to the atmosphere. A major part of this study is to contribute to the development of a novel approach for converting natural gas into methanol and to assess the environmental impact (for better or for worse) of this new technology. This Ph.D. research contributes to the development of such a system and provides a comprehensive techno-economic and environmental assessment of this technology. Recognizing the distributed nature of methane leakage associated with the natural gas system, this work is also intended to advance previous research at the Lenfest Center for Sustainable Energy that aims to show that small, modular energy systems can be made economic. This thesis contributes to and analyzes the development of a small-scale gas-to-liquids (GTL) system aimed at addressing flared natural gas from gas and oil wells. This thesis includes system engineering around a design that converts natural gas to synthesis gas (syngas) in a reciprocating internal combustion engine and then converts the syngas into methanol in a small-scale reactor. With methanol as the product, this research aims to show that such a system can not only address current and future natural gas flaring regulation, but eventually can compete economically with historically large-scale, centralized methanol production infrastructure. If successful, such systems could contribute to a shift away from large, multi-billion dollar capital cost chemical plants towards smaller systems with shorter lifetimes that may decrease the time to transition to more sustainable forms of energy and chemical conversion technologies. This research also quantifies the potential for such a system to contribute to mitigating GHG emissions, not only by addressing flared gas in the near-term, but also supporting future natural gas infrastructure ideas that may help to redefine the way the current natural gas pipeline system is used. The introduction of new, small-scale, distributed energy and chemical conversion systems located closer to the point of extraction may contribute to reducing methane leakage throughout the natural gas distribution system by reducing the reliance and risks associated with the aging natural gas pipeline infrastructure. The outcome of this thesis will result in several areas for future work. From an economic perspective, factors that contribute to overall system cost, such as operation and maintenance (O&M) and capital cost multiplier (referred to as the Lang Factor for large-scale petro-chemical plants), are not yet known for novel systems such as the technology presented here. From a technical perspective, commercialization of small-scale, distributed chemical conversion systems may create a demand for economical compression and air-separation technologies at this scale that do not currently exist. Further, new business cases may arise aimed at utilizing small, remote sources of methane, such as biogas from agricultural and municipal waste. Finally, while methanol was selected as the end-product for this thesis, future applications of this technology may consider methane conversion to hydrogen, ammonia, and ethylene for example, challenging the orthodoxy in the chemical industry that “bigger is better.”

In most areas of the world, high population centres and heavy industry are located along river systems and provide a catchment wide source of heavy metal pollution along the length of the river system. These anthropogenically derived heavy metal pollutants enter the freshwater river systems and are transported downstream as part of the suspended sediment load. Such metals combine with the suspended sediment such that there is a higher concentration of heavy metals with the finer grained, clay-rich component of the transported sediment. In such cases, the ultimate depositional environment of contaminated sediments bears little relation to the distant source regions of anthropogenic pollution. In an arid country like Australia, there are numerous coastal estuaries that are supplied with sediment transported down catchments that lack both industry and significant population centres. However such coastal estuaries are undergoing rapid population growth, even though in such regions the upstream catchment is notably lacking in population centres and industry. This provides an opportunity to study heavy metal additions and contamination in a post-depositional estuarine saline environment, in which relatively uncontaminated freshwater sediments are input into the system, mainly during seasonal flood events. This study demonstrates that transported sediments, derived from upcatchment, undergo post depositional transformations across the freshwater-marine boundary. As a result of these terrigenous, biogenic, authigenic and anthropogenic changes, estuarine sediments do not necessarily reflect the original source composition. Conservative elements, especially rare earth elements, were used to differentiate between original and post-depositional additions and transformations to the sediments of an estuarine system on the south coast of New South Wales, Australia, to show that metal contamination does not correlate wholly with sediment grain size, but also correlates with proximity to local townships surrounding part of an estuary. Metals such as Pb have been discriminated in terms of original, transported sediment compositions and local pollutant sources. Furthermore, analyses of baseline, spatial and temporal data has generated a methodology and conceptual framework for assessing anomalies, even when concentrations are low within apparently 'pristine' settings. This thesis identifies both natural and anthropogenic processes and contributions to estuarine sediments, and presents a methodology by which metal contamination of sediments and the potential future risks from remobilisation can be quantified.

Australian public awareness of natural resource management (NRM) issues relating to environmental conditions has been heightened in recent years. However, due to government budget limitations only some of the environmental problems can be addressed. This raises the question of how available funds should be allocated in order to achieve improved resource use efficiency. The motivation for this research arises from the need for a better understanding of how non-market values can be used in the NRM investment prioritisation processes to enable a comprehensive cost benefit analysis of different resource allocation options. The objective of this research was to explore the application of choice modelling (CM) to elicit the values of New South Wales (NSW) residents for a range of environmental and social changes provided by potential NRM investments in NSW catchments. The estimated environmental and social values are inputs to bio-economic optimisation modelling tools used by Catchment Management Authorities to determine land use changes that can provide improved net benefits to society over time. A further objective of this research was to explore scope, scale effects, the distance effect and ways of improving incentive compatibility of the CM technique. These three methodological issues were investigated to ensure an appropriate use of non-market values for NRM assessments at both catchment and farm levels as well as more accurate extrapolations of non-market values from the case studies to wider application. In order to provide improved result credibility for the policy process, the inclusion of a provision rule directed at incentive compatibility was also tested. Fourteen sub-samples for three case study catchments - Namoi, Lachlan and Hawkesbury-Nepean - were used for the analysis. The results of this study highlight the importance of accounting for variations in values held by different respondent community locations. Most of the differences in preferences for NRM changes were found between rural and urban communities. The semi-rural characteristics of the Hawkesbury-Nepean catchment community and the close proximity of this catchment to the Sydney urban centre exhibit similar views on NRM actions in this catchment. The results show a higher per unit willingness to pay for a greater scale of provision of non-market attributes, as well as when the good is presented at a smaller scope. The results of this study have not shown a significant impact for including a provision rule on respondent preferences, suggesting a further investigation of a stronger provision rule with a combination of different elicitation formats. The CM application presented for NRM and the three methodological issues investigated in this study provide a significant contribution to more comprehensive and accurate cost benefit analyses of NRM investments in NSW catchments and beyond. The CM approach to eliciting non-market values is suitable for NRM assessments and provides a basis for benefit transfer of these values to similar studies across Australia. Clarifications of scope, scale, location and distance effect terminologies contribute to non-market valuation knowledge of the use of these terminologies so often confused in the literature and provide a clearer understanding of their practical implications in NRM assessments. Investigation of new ways of dealing with incentive compatibility in CM field experiments undertaken in this study also opens opportunities for future research in this area.