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Journal articles on the topic 'Nanostructured Transition Metal Clusters'

Author: Grafiati

Published: 7 September 2023

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1

Reetz, Manfred T., and Wolfgang Helbig. "Size-Selective Synthesis of Nanostructured Transition Metal Clusters." Journal of the American Chemical Society 116, no. 16 (1994): 7401–2. http://dx.doi.org/10.1021/ja00095a051.

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2

Scharfe, Sandra, and Thomas F. Fässler. "Polyhedral nine-atom clusters of tetrel elements and intermetalloid derivatives." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 368, no. 1915 (2010): 1265–84. http://dx.doi.org/10.1098/rsta.2009.0270.

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Homoatomic polyanions have the basic capability for a bottom-up synthesis of nanostructured materials. Therefore, the chemistry and the structures of polyhedral nine-atom clusters of tetrel elements [E 9 ] 4− is highlighted. The nine-atom Zintl ions are available in good quantities for E = Si–Pb as binary alkali metal (A) phases of the composition A 4 E 9 or A 12 E 17 . Dissolution or extraction of the neat solids with aprotic solvents and crystallization with alkali metal-sequestering molecules or crown ethers leads to a large variety of structures containing homoatomic clusters with up to 45

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3

Adams, Brian D., Robert M. Asmussen, Aicheng Chen, and Robert C. Mawhinney. "Interaction of carbon monoxide with small metal clusters: a DFT, electrochemical, and FTIR study." Canadian Journal of Chemistry 89, no. 12 (2011): 1445–56. http://dx.doi.org/10.1139/v11-120.

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The adsorption of CO molecules onto small metal clusters was studied using density functional theory (DFT) calculations, and experimental electrochemical and attenuated total reflection-Fourier transform infrared spectroscopic (ATR-FTIR) techniques were used to examine CO adsorbed onto nanostructures of similar composition. The adsorption strengths and CO vibrational stretching frequencies were calculated and analyzed for clusters of the form M–CO for all of the period 4, 5, and 6 d-block transition metals. A direct link between the νCO and the population of d orbitals of the metal was observe

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4

Bulgakov, Alexander V., Nikolay Y. Bykov, Alexey I. Safonov, Yuri G. Shukhov, and Sergey V. Starinskiy. "Silver Vapor Supersonic Jets: Expansion Dynamics, Cluster Formation, and Film Deposition." Materials 16, no. 13 (2023): 4876. http://dx.doi.org/10.3390/ma16134876.

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Supersonic jets of metal vapors with carrier gas are promising for producing nanostructured metal films at relatively low source temperatures and high deposition rates. However, the effects of the carrier gas on the jet composition and expansion dynamics, as well as on film properties, remain virtually unexplored. In this work, the free-jet expansion of a mixture of silver vapor with helium in a rarefied regime at an initial temperature of 1373 K is investigated through mass spectrometry and direct-simulation Monte Carlo methods. Introducing the carrier gas into the source is found to result i

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5

Jiang, Ning, Yulong Bai, Bo Yang, Dezhi Wang, and Shifeng Zhao. "Switchable metal–insulator transition in core–shell cluster-assembled nanostructure films." Nanoscale 12, no. 35 (2020): 18144–52. http://dx.doi.org/10.1039/d0nr04681g.

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6

MELINON, P., V. PAILLARD, V. DUPUIS, et al. "FROM FREE CLUSTERS TO CLUSTER-ASSEMBLED MATERIALS." International Journal of Modern Physics B 09, no. 04n05 (1995): 339–97. http://dx.doi.org/10.1142/s021797929500015x.

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In this paper the specific properties of free clusters and the formation of new cluster-assembled materials using the low energy cluster beam deposition (LECBD) technique are discussed. Recent results obtained for free clusters are summarized with special attention to new observed structures. As for the specific structures and properties of cluster-assembled materials, two main aspects are specially emphasized: the memory effect of the free cluster properties leading to the formation of new phases and the effect of the specific nanostructure of the cluster-assembled materials related to the ra

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7

Lu, Xizhao, Lei Kang, Binggong Yan, et al. "Evolution of a Superhydrophobic H59 Brass Surface by Using Laser Texturing via Post Thermal Annealing." Micromachines 11, no. 12 (2020): 1057. http://dx.doi.org/10.3390/mi11121057.

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To fabricate an industrial and highly efficient super-hydrophobic brass surface, annealed H59 brass samples have here been textured by using a 1064 nm wavelength nanosecond fiber laser. The effects of different laser parameters (such as laser fluence, scanning speed, and repetition frequency), on the translation to super-hydrophobic surfaces, have been of special interest to study. As a result of these studies, hydrophobic properties, with larger water contact angles (WCA), were observed to appear faster than for samples that had not been heat-treated (after an evolution time of 4 days). This

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8

Soldatov, Mikhail, Kirill Lomachenko, Nikolay Smolentsev, and Alexander Soldatov. "Determination of the local structure in metal-complexes by combining XAS and XES." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1521. http://dx.doi.org/10.1107/s2053273314084782.

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Nanoscale local atomic structure determines most of unique properties of novel materials without long range order. To study its fine details one has to use both computer nanodesign and advanced experimental methods for nanodiagnostics. The status of modern theoretical analysis of the experimental x-ray absorption spectra to extract structural parameters is presented. Novel in-situ technique for nanodiagnostics - extracting of 3D structure parameters on the basis of advanced quantitative analysis of X-ray absorption near edge structure (XANES) - has been developed. The possibility to extract in

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9

Miras, Haralampos N., Cole Mathis, Weimin Xuan, De-Liang Long, Robert Pow, and Leroy Cronin. "Spontaneous formation of autocatalytic sets with self-replicating inorganic metal oxide clusters." Proceedings of the National Academy of Sciences 117, no. 20 (2020): 10699–705. http://dx.doi.org/10.1073/pnas.1921536117.

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Here we show how a simple inorganic salt can spontaneously form autocatalytic sets of replicating inorganic molecules that work via molecular recognition based on the {PMo12} ≡ [PMo12O40]3– Keggin ion, and {Mo36} ≡ [H3Mo57M6(NO)6O183(H2O)18]22– cluster. These small clusters are able to catalyze their own formation via an autocatalytic network, which subsequently template the assembly of gigantic molybdenum-blue wheel {Mo154} ≡ [Mo154O462H14(H2O)70]14–, {Mo132} ≡ [MoVI72MoV60O372(CH3COO)30(H2O)72]42– ball-shaped species containing 154 and 132 molybdenum atoms, and a {PMo12}⊂{Mo124Ce4} ≡ [H16MoV

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10

Dupuis, V., J. P. Perez, J. Tuaillon, et al. "Magnetic properties of nanostructured thin films of transition metal obtained by low energy cluster beam deposition." Journal of Applied Physics 76, no. 10 (1994): 6676–78. http://dx.doi.org/10.1063/1.358165.

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11

Schuster, Christian, Harald Rennhofer, Heinz Amenitsch, Helga C. Lichtenegger, Alois Jungbauer, and Rupert Tscheliessing. "Metal–Insulator Transition of Ultrathin Sputtered Metals on Phenolic Resin Thin Films: Growth Morphology and Relations to Surface Free Energy and Reactivity." Nanomaterials 11, no. 3 (2021): 589. http://dx.doi.org/10.3390/nano11030589.

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Nanostructured metal assemblies on thin and ultrathin polymeric films enable state of the art technologies and have further potential in diverse fields. Rational design of the structure–function relationship is of critical importance but aggravated by the scarcity of systematic studies. Here, we studied the influence of the interplay between metal and polymer surface free energy and reactivity on the evolution of electric conductivity and the resulting morphologies. In situ resistance measurements during sputter deposition of Ag, Au, Cu and Ni films on ultrathin reticulated polymer films colle

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12

Babicheva, Viktoriia E., and Jerome V. Moloney. "Lattice Resonances in Transdimensional WS2 Nanoantenna Arrays." Applied Sciences 9, no. 10 (2019): 2005. http://dx.doi.org/10.3390/app9102005.

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Mie resonances in high-refractive-index nanoparticles have been known for a long time but only recently have they became actively explored for control of light in nanostructures, ultra-thin optical components, and metasurfaces. Silicon nanoparticles have been widely studied mainly because of well-established fabrication technology, and other high-index materials remain overlooked. Transition metal dichalcogenides, such as tungsten or molybdenum disulfides and diselenides, are known as van der Waals materials because of the type of force holding material layers together. Transition metal dichal

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13

Ku, Ruiqi, Guangtao Yu, Jing Gao, Xuri Huang, and Wei Chen. "Embedding tetrahedral 3d transition metal TM4 clusters into the cavity of two-dimensional graphdiyne to construct highly efficient and nonprecious electrocatalysts for hydrogen evolution reaction." Physical Chemistry Chemical Physics 22, no. 6 (2020): 3254–63. http://dx.doi.org/10.1039/c9cp06057j.

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Coupled with the high structural stability and good conductivity, all the new 2D composite nanostructures TM<sub>4</sub>@GDY (TM = Sc, Ti, Mn, Fe, Co, Ni and Cu) can uniformly exhibit considerably high catalytic activity for hydrogen evolution reaction.

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14

Jaksic, Jelena, Diamantoula Labou, and Georgos Papakonstantinou. "Phenomena and significance of intermediate spillover in electrocatalysis of oxygen and hydrogen electrode reactions." Chemical Industry 66, no. 4 (2012): 425–53. http://dx.doi.org/10.2298/hemind110826005j.

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Altervalent hypo-d-oxides of transition metal series impose spontaneous dissociative adsorption of water molecules and pronounced membrane spillover transferring properties instantaneously resulting with corresponding bronze type (Pt/HxWO3) under cathodic, and/or its hydrated state (Pt/W(OH)6) responsible for the primary oxide (Pt-OH) effusion, under anodic polarization, this way establishing instantaneous reversibly revertible alterpolar bronze features (Pt/H0.35WO3 Pt/W(OH)6), and substantially advanced electrocatalytic properties of these composite interactive electrocatalysts. As the conse

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15

Hill, Jonathan P. "Chromophore Nanohybrids for Sensing and Singlet Oxygen Generation." ECS Meeting Abstracts MA2022-01, no. 14 (2022): 938. http://dx.doi.org/10.1149/ma2022-0114938mtgabs.

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Nanohybrid materials can exhibit the physical properties of their components and be used in various applications. Also, novel chromophores involving synthetically flexible molecules such as pyrazinacenes1 and porphyrins2 can be incorporated into these structures by different means in particular as MOFs or COFs, while other components include simple transition metal salts or oligonuclear metal-oxo clusters. In this work, we discuss nanohybrids materials containing oxoporphyrinogen (OxP), tetrapyrroles or fullerene as the organic component, with hybridization using respectively Ag(I) salt or oxo

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16

Zaporotskova, Irina V., Daniel P. Radchenko, Lev V. Kozhitov, Pavel A. Zaporotskov, and Alena V. Popkova. "Theoretical study of metal composite based on pyrolyzed polyacrylonitrile monolayer containing Fe-Co, Ni-Co and Fe-Ni metal atom pairs and silicon amorphizing admixture." Modern Electronic Materials 6, no. 3 (2020): 95–99. http://dx.doi.org/10.3897/j.moem.6.3.63308.

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An urgent problem of radio engineering and radioelectronics nowadays is the synthesis of composite materials with preset parameters that can be used as electronics engineering materials. Of special interest are MW range wide-band electromagnetic radiation absorbers. Special attention is paid to materials on the basis of ferromagnetic metals that are capable of effectively absorbing and reflecting incident waves and having a clear nanostructure. Development of nanocapsulated metals will allow controlling the parameters of newly designed materials. This is achieved with the use of polymer matric

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17

Zaporotskova, I. V., D. P. Radchenko, L. V. Kozitov, P. A. Zaporotskov, and A. V. Popkova. "Theoretical studies of a metal composite based on a monolayer of pyrolyzed polyacrylonitrile containing paired metal atoms Cu—Co, Ni—Co, Ni—Cu, Ni—Fe and an amorphizing silicon additive." Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering 23, no. 3 (2020): 196–202. http://dx.doi.org/10.17073/1609-3577-2020-3-196-202.

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An urgent problem of radio engineering and radioelectronics nowadays is the synthesis of composite materials with preset parameters that can be used as electronics engineering materials. Of special interest are MW range wide-band electromagnetic radiation absorbers. Special attention is paid to materials on the basis of ferromagnetic metals that are capable of effectively absorbing and reflecting incident waves and having a clear nanostructure. Development of nanocapsulated metals will allow controlling the parameters of newly designed materials. This is achieved with the use of polymer matric

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18

Rudman, Kelly, Seyyedamirhossein Hosseini, and Dennis G. Peters. "Novel Approach for the Electrosynthesis of Copper Nanoparticles." ECS Meeting Abstracts MA2019-01, no. 20 (2019): 1102. http://dx.doi.org/10.1149/ma2019-01/20/1102.

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In recent decades, nanoparticles have become a prominent research topic due to their increased catalytic activity, which is attributed to their high surface areas. Although typical synthesis methods yield highly ordered monodispersed particles, they often require harsh synthesis conditions, such as high pressure or temperatures, and the use of high-purity reagents. Moreover, these syntheses are conducted on a microliter basis and are not easily scaled-up.1 Electrochemistry offers an alternative approach for the synthesis of nanoparticles under mild conditions, since most metal reduction potent

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19

Reetz, Manfred T., Stefan A. Quaiser, Martin Winter, et al. "Nanostructured Metal Oxide Clusters by Oxidation of Stabilized Metal Clusters with Air." Angewandte Chemie International Edition in English 35, no. 18 (1996): 2092–94. http://dx.doi.org/10.1002/anie.199620921.

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20

Whittlesey, Bruce R. "Xenophilic transition metal clusters." Coordination Chemistry Reviews 206-207 (September 2000): 395–418. http://dx.doi.org/10.1016/s0010-8545(00)00340-4.

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21

El-Sayed, Mostafa A. "Preface." Pure and Applied Chemistry 72, no. 1-2 (2000): vii. http://dx.doi.org/10.1351/pac20007201ii.

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This issue of Pure Appl. Chem. is devoted to papers based upon invited lectures delivered at the first IUPAC-sponsored Workshop on Advanced Material, "WAM1: Nanostructured Systems", held at the Hong Kong University for Science and Technology (HKUST) on July 14-18, 1999.The Topic Why nanostructured material? Chemists contribute to the well-being of society by exploiting the properties of the elements of the periodic table, or various forms of combination of elements, to make materials that are useful for "better living through chemistry." What happens if we use all the possible combinations tha

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22

Wales, David J., and Anthony J. Stone. "Bonding in transition-metal clusters." Inorganic Chemistry 28, no. 16 (1989): 3120–27. http://dx.doi.org/10.1021/ic00315a011.

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23

Morse, Michael D. "Clusters of transition-metal atoms." Chemical Reviews 86, no. 6 (1986): 1049–109. http://dx.doi.org/10.1021/cr00076a005.

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24

Duffy, D. M., J. A. Blackman, P. A. Mulheran, and S. A. Williams. "Transition metal clusters on graphite." Journal of Magnetism and Magnetic Materials 177-181 (January 1998): 953–54. http://dx.doi.org/10.1016/s0304-8853(97)00757-9.

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25

Sawada, S., and S. Sugano. "Dynamics of transition-metal clusters." Zeitschrift f�r Physik D Atoms, Molecules and Clusters 12, no. 1-4 (1989): 189–91. http://dx.doi.org/10.1007/bf01426935.

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26

Kraatz, Heinz-Bernhard, Michael J. Went, and John C. Jeffery. "Heteronuclear transition metal-alkyne clusters." Journal of Organometallic Chemistry 394, no. 1-3 (1990): 167–75. http://dx.doi.org/10.1016/0022-328x(90)87231-2.

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27

Guirado-López, R., D. Spanjaard, and M. C. Desjonquères. "Magnetic-nonmagnetic transition in fcc4d-transition-metal clusters." Physical Review B 57, no. 11 (1998): 6305–8. http://dx.doi.org/10.1103/physrevb.57.6305.

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28

Chia, Xinyi, Alex Yong Sheng Eng, Adriano Ambrosi, Shu Min Tan, and Martin Pumera. "Electrochemistry of Nanostructured Layered Transition-Metal Dichalcogenides." Chemical Reviews 115, no. 21 (2015): 11941–66. http://dx.doi.org/10.1021/acs.chemrev.5b00287.

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29

Plăiașu, Adriana Gabriela, Marian Cătălin Ducu, Sorin Georgian Moga, Aurelian Denis Negrea, and Ecaterina Magdalena Modan. "Nanostructured transition metal oxides obtained by SPVD." Manufacturing Review 7 (2020): 12. http://dx.doi.org/10.1051/mfreview/2020009.

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The interest in the unique properties associated with materials having structures on a nanometer scale has been increasing at an exponential rate in last decade. Transition metal oxides are preferred materials for catalytic applications due to their half-filled d orbitals that make them exist in different oxidation states. Transition metal oxides show a broad structural variety due to their ability to form phases of varying metal to oxygen ratios reflecting multiple stable oxidation states of the metal ions. The Solar Physical Vapor Deposition (SPVD) presented in the paper as elaboration metho

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30

Zheng, Mingbo, Xiao Xiao, Lulu Li, et al. "Hierarchically nanostructured transition metal oxides for supercapacitors." Science China Materials 61, no. 2 (2017): 185–209. http://dx.doi.org/10.1007/s40843-017-9095-4.

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31

Zhao, Jijun, Xiaoshuang Chen, and Guanghou Wang. "Critical size for a metal-nonmetal transition in transition-metal clusters." Physical Review B 50, no. 20 (1994): 15424–26. http://dx.doi.org/10.1103/physrevb.50.15424.

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32

D'Agostino, Gregorio. "Icosahedral Order in Transition Metal Clusters." Materials Science Forum 195 (November 1995): 149–54. http://dx.doi.org/10.4028/www.scientific.net/msf.195.149.

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33

Belyakova, O. A., and Yu L. Slovokhotov. "Structures of large transition metal clusters." Russian Chemical Bulletin 52, no. 11 (2003): 2299–327. http://dx.doi.org/10.1023/b:rucb.0000012351.07223.d4.

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34

Pasynskii, Alexander A., and Igor L. Eremenko. "Heterometallic sulphide-bridged transition metal clusters." Russian Chemical Reviews 58, no. 2 (1989): 181–99. http://dx.doi.org/10.1070/rc1989v058n02abeh003434.

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35

Benito, Mónica, Oriol Rossell, Miquel Seco, and Glòria Segalés. "Transition metal clusters containing carbosilane dendrimers." Journal of Organometallic Chemistry 619, no. 1-2 (2001): 245–51. http://dx.doi.org/10.1016/s0022-328x(00)00697-5.

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36

Aguilera-Granja, F., S. Bouarab, A. Vega, J. A. Alonso, and J. M. Montejano-Carrizales. "Nonmetal-metal transition in Ni clusters." Solid State Communications 104, no. 10 (1997): 635–39. http://dx.doi.org/10.1016/s0038-1098(97)00380-3.

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37

Wang, Q., Q. Sun, J. Z. Yu, and Y. Kawazoe. "Nonmetal–metal transition in Ban clusters." Solid State Communications 117, no. 11 (2001): 635–39. http://dx.doi.org/10.1016/s0038-1098(01)00009-6.

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38

Riley, S. J. "Chemistry of Isolated Transition Metal Clusters." JOM 40, no. 1 (1988): 52–53. http://dx.doi.org/10.1007/bf03258019.

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39

Luh, Tien-Yau, Henry N. C. Wong, and Brian F. G. Johnson. "Spatial notation for transition-metal clusters." Polyhedron 5, no. 5 (1986): 1111–18. http://dx.doi.org/10.1016/s0277-5387(00)84310-7.

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40

Smirnov, B. M., and H. Weidele. "Radiative transition mechanisms in metal clusters." Journal of Experimental and Theoretical Physics 89, no. 6 (1999): 1030–34. http://dx.doi.org/10.1134/1.559048.

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41

Ceulemans, A., and P. W. Fowler. "Bonding patterns in transition metal clusters." Inorganica Chimica Acta 105, no. 1 (1985): 75–82. http://dx.doi.org/10.1016/s0020-1693(00)85248-2.

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42

Zhao, J. J., M. Han, and G. H. Wang. "Ionization potentials of transition-metal clusters." Physical Review B 48, no. 20 (1993): 15297–300. http://dx.doi.org/10.1103/physrevb.48.15297.

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43

Cox, A. J., J. G. Louderback, S. E. Apsel, and L. A. Bloomfield. "Magnetism in 4d-transition metal clusters." Physical Review B 49, no. 17 (1994): 12295–98. http://dx.doi.org/10.1103/physrevb.49.12295.

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44

Wang, Lai-Sheng, and Hongbin Wu. "Photoelectron Spectroscopy of Transition Metal Clusters." Zeitschrift für Physikalische Chemie 203, Part_1_2 (1998): 45–55. http://dx.doi.org/10.1524/zpch.1998.203.part_1_2.045.

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45

Geusic, M. E., M. D. Morse, and R. E. Smalley. "Hydrogen chemisorption on transition metal clusters." Journal of Chemical Physics 82, no. 1 (1985): 590–91. http://dx.doi.org/10.1063/1.448732.

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46

D'agostino, Gregorio. "Phonon properties of transition-metal clusters." Philosophical Magazine B 76, no. 4 (1997): 433–40. http://dx.doi.org/10.1080/01418639708241107.

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47

Persson, J. L., M. Andersson, and A. Ros�n. "Reactivity of small transition metal clusters." Zeitschrift f�r Physik D Atoms, Molecules and Clusters 26, no. 1-4 (1993): 334–36. http://dx.doi.org/10.1007/bf01429186.

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48

Andersson, M., J. L. Persson, and A. Rosén. "Oxidation of small transition metal clusters." Nanostructured Materials 3, no. 1-6 (1993): 337–44. http://dx.doi.org/10.1016/0965-9773(93)90096-t.

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49

Whittlesey Bruce R., Whittlesey Bruce R. "ChemInform Abstract: Xenophilic Transition Metal Clusters." ChemInform 31, no. 51 (2000): no. http://dx.doi.org/10.1002/chin.200051238.

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50

Lei, Xinjian, Eduardo E. Wolf, and Thomas P. Fehlner. "Clusters as Ligands – Large Assemblies of Transition Metal Clusters." European Journal of Inorganic Chemistry 1998, no. 12 (1998): 1835–46. http://dx.doi.org/10.1002/(sici)1099-0682(199812)1998:12<1835::aid-ejic1835>3.0.co;2-y.

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