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Journal articles on the topic 'Nanoscale metal organic frameworks (nanoMOFs)'

Author: Grafiati

Published: 25 January 2025

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1

Oggianu, Mariangela, Valentina Mameli, Noemi Monni, Suchithra Ashoka Sahadevan, Marco Sanna Angotzi, Carla Cannas, and Maria Laura Mercuri. "Nanoscaled Metal-Organic Frameworks: Challenges Towards Biomedical Applications." Journal of Nanoscience and Nanotechnology 21, no. 5 (May 1, 2021): 2922–29. http://dx.doi.org/10.1166/jnn.2021.19043.

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Achieving metal-organic frameworks (MOFs) in the form of nanoparticles (NanoMOFs) represents a recent challenge due to the possibility to combine the intrinsic porosity of these materials with the nanometric dimension, a fundamental requirement for strategic biomedical applications. In this outlook we envision the current/future opportunities of the NanoMOFs in the field of biomedicine, with particular emphasis on (i) biocompatible MOFs composition; (ii) MOFs miniaturization and (iii) nanoMOFs applications.

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Li, Xue, Marianna Porcino, Jingwen Qiu, Doru Constantin, Charlotte Martineau-Corcos, and Ruxandra Gref. "Doxorubicin-Loaded Metal-Organic Frameworks Nanoparticles with Engineered Cyclodextrin Coatings: Insights on Drug Location by Solid State NMR Spectroscopy." Nanomaterials 11, no. 4 (April 8, 2021): 945. http://dx.doi.org/10.3390/nano11040945.

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Recently developed, nanoscale metal-organic frameworks (nanoMOFs) functionalized with versatile coatings are drawing special attention in the nanomedicine field. Here we show the preparation of core–shell MIL-100(Al) nanoMOFs for the delivery of the anticancer drug doxorubicin (DOX). DOX was efficiently incorporated in the MOFs and was released in a progressive manner, depending on the initial loading. Besides, the coatings were made of biodegradable γ-cyclodextrin-citrate oligomers (CD-CO) with affinity for both DOX and the MOF cores. DOX was incorporated and released faster due to its affinity for the coating material. A set of complementary solid state nuclear magnetic resonance (ssNMR) experiments including 1H-1H and 13C-27Al two-dimensional NMR, was used to gain a deep understanding on the multiple interactions involved in the MIL-100(Al) core–shell system. To do so, 13C-labelled shells were synthesized. This study paves the way towards a methodology to assess the nanoMOF component localization at a molecular scale and to investigate the nanoMOF physicochemical properties, which play a main role on their biological applications.

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Christodoulou, Ioanna, Pengbo Lyu, Carla Vieira Soares, Gilles Patriarche, Christian Serre, Guillaume Maurin, and Ruxandra Gref. "Nanoscale Iron-Based Metal–Organic Frameworks: Incorporation of Functionalized Drugs and Degradation in Biological Media." International Journal of Molecular Sciences 24, no. 4 (February 8, 2023): 3362. http://dx.doi.org/10.3390/ijms24043362.

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Metal–organic frameworks (MOFs) attract growing interest in biomedical applications. Among thousands of MOF structures, the mesoporous iron(III) carboxylate MIL-100(Fe) (MIL stands for the Materials of Lavoisier Institute) is among the most studied MOF nanocarrier, owing to its high porosity, biodegradability, and lack of toxicity. Nanosized MIL-100(Fe) particles (nanoMOFs) readily coordinate with drugs leading to unprecedented payloads and controlled release. Here, we show how the functional groups of the challenging anticancer drug prednisolone influence their interactions with the nanoMOFs and their release in various media. Molecular modeling enabled predicting the strength of interactions between prednisolone-bearing or not phosphate or sulfate moieties (PP and PS, respectively) and the oxo-trimer of MIL-100(Fe) as well as understanding the pore filling of MIL-100(Fe). Noticeably, PP showed the strongest interactions (drug loading up to 30 wt %, encapsulation efficiency > 98%) and slowed down the nanoMOFs’ degradation in simulated body fluid. This drug was shown to bind to the iron Lewis acid sites and was not displaced by other ions in the suspension media. On the contrary, PS was entrapped with lower efficiencies and was easily displaced by phosphates in the release media. Noticeably, the nanoMOFs maintained their size and faceted structures after drug loading and even after degradation in blood or serum after losing almost the totality of the constitutive trimesate ligands. Scanning electron microscopy with high annular dark field (STEM-HAADF) in conjunction with X-Ray energy-dispersive spectrometry (XEDS) was a powerful tool enabling the unraveling of the main elements to gain insights on the MOF structural evolution after drug loading and/or upon degradation.

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Oggianu, Mariangela, Noemi Monni, Valentina Mameli, Carla Cannas, Suchithra Ashoka Sahadevan, and Maria Laura Mercuri. "Designing Magnetic NanoMOFs for Biomedicine: Current Trends and Applications." Magnetochemistry 6, no. 3 (September 1, 2020): 39. http://dx.doi.org/10.3390/magnetochemistry6030039.

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Metal–organic frameworks (MOFs) have shown a great potential in biomedicine due to their promising applications in different fields, including drug delivery, thermometry, theranostics etc. In this context, the development of magnetic sub-micrometric or nanometric MOFs through miniaturization approaches of magnetic MOFs up to the nanoscale still represents a crucial step to fabricate biomedical probes, especially in the field of theranostic nanomedicine. Miniaturization processes have to be properly designed to tailor the size and shape of particles and to retain magnetic properties and high porosity in the same material, fundamental prerequisites to develop smart nanocarriers integrating simultaneously therapeutic and contrast agents for targeted chemotherapy or other specific clinical use. An overview of current trends on the design of magnetic nanoMOFs in the field of biomedicine, with particular emphasis on theranostics and bioimaging, is herein envisioned.

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5

Luo, Jia, Michael Florian Peter Wagner, Nils Ulrich, Peter Kopold, Christina Trautmann, and Maria Eugenia Toimil Molares. "(Digital Presentation) Electrochemical Conversion of Cu Nanowires Synthesized By Electrodeposition in Track-Etched Templates to HKUST-1." ECS Meeting Abstracts MA2022-02, no. 23 (October 9, 2022): 977. http://dx.doi.org/10.1149/ma2022-0223977mtgabs.

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Metal-organic frameworks (MOFs) are a novel type of nanoporous materials that have attracted widespread attention over the past two decades [1]. Cu-based metal-organic frameworks such as Cu3(BTC)2 (also known as HKUST-1) are one of the most famous MOF representatives, which exhibit a huge open porosity and thus a remarkably capacity to store and uptake different gases [2, 3]. Recently, increasing efforts are devoted toward finding synthetic routes that enable downsizing MOF crystals to the nanoscale. Achieving control over the size and shape of nanoMOFs and finding ways to assemble them is essential for their exploitation in integrated devices such as sensors, gas separation membranes or photoelectrodes. In this study we explore the conversion of free-standing arrays Cu nanowires with controlled diameter and length synthesized by electrodeposition in etched ion-track membranes into HKUST-1. In a first process step, free-standing Cu wires are produced by dissolving the ion-track polymer template. In a second step, the wires are converted into HKUST-1 structures by electrochemical oxidation. Applying 2.5 V versus a Cu counter electrode, the Cu nanowires are oxidatively dissolved and the MOF is built up as the as-formed Cu2+ ions bind to the BTC3− ligands in the electrolyte solution. The morphology and crystallinity of the samples at different transformation stages is investigated by scanning electron microscopy (Fig. 1) and transmission electron microscopy, respectively. X-ray diffraction spectra measured at different conversion times reveal the appearance of the characteristic reflections of HKUST-1. These results will be compared with previous studies of the transformation of Cu nanowires to HKUST-1 nanowires inside the polymer membrane [4]. Figure 1: SEM images of cylindrical Cu nanowires (a) before and (b) during the electrochemical conversion process, and (c) of a representative octahedral particle after complete conversion to HKUST-1. References [1] Freund R, Canossa S, Cohen SM, Yan W, Deng et al. Angewandte Chemie International Edition. (2021) 2: 23946-23974 [2] Chui SS-Y, Lo SM-F, Charmant JP, Orpen AG, Williams ID. Science. (1999) 283:1148-50. [3] Li H, Li L, Lin R-B, Zhou W, Zhang Z, Xiang S, et al. EnergyChem. (2019) 1:100006. [4] Caddeo F, Vogt R, Weil D, Sigle W, Toimil-Molares ME, Maijenburg AW. ACS applied materials & interfaces . (2019)11:25378-87. Figure 1

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6

Hidalgo, T., M. Alonso-Nocelo, B. L. Bouzo, S. Reimondez-Troitiño, C. Abuin-Redondo, M. de la Fuente, and P. Horcajada. "Biocompatible iron(iii) carboxylate metal–organic frameworks as promising RNA nanocarriers." Nanoscale 12, no. 8 (2020): 4839–45. http://dx.doi.org/10.1039/c9nr08127e.

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7

Porcino, Marianna, Ioanna Christodoulou, Mai Dang Le Vuong, Ruxandra Gref, and Charlotte Martineau-Corcos. "New insights on the supramolecular structure of highly porous core–shell drug nanocarriers using solid-state NMR spectroscopy." RSC Advances 9, no. 56 (2019): 32472–75. http://dx.doi.org/10.1039/c9ra07383c.

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8

Cutrone, Li, Casas-Solvas, Menendez-Miranda, Qiu, Benkovics, Constantin, et al. "Design of Engineered Cyclodextrin Derivatives for Spontaneous Coating of Highly Porous Metal-Organic Framework Nanoparticles in Aqueous Media." Nanomaterials 9, no. 8 (August 1, 2019): 1103. http://dx.doi.org/10.3390/nano9081103.

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Nanosized metal-organic frameworks (nanoMOFs) MIL-100(Fe) are highly porous and biodegradable materials that have emerged as promising drug nanocarriers. A challenging issue concerns their surface functionalization in order to evade the immune system and to provide molecular recognition ability, so that they can be used for specific targeting. A convenient method for their coating with tetraethylene glycol, polyethylene glycol, and mannose residues is reported herein. The method consists of the organic solvent-free self-assembly on the nanoMOFs of building blocks based on β-cyclodextrin facially derivatized with the referred functional moieties, and multiple phosphate groups to anchor to the nanoparticles’ surface. The coating of nanoMOFs with cyclodextrin phosphate without further functional groups led to a significant decrease of macrophage uptake, slightly improved by polyethylene glycol or mannose-containing cyclodextrin phosphate coating. More notably, nanoMOFs modified with tetraethylene glycol-containing cyclodextrin phosphate displayed the most efficient “stealth” effect. Mannose-coated nanoMOFs displayed a remarkably enhanced binding affinity towards a specific mannose receptor, such as Concanavalin A, due to the multivalent display of the monosaccharide, as well as reduced macrophage internalization. Coating with tetraethylente glycol of nanoMOFs after loading with doxorubicin is also described. Therefore, phosphorylated cyclodextrins offer a versatile platform to coat nanoMOFs in an organic solvent-free, one step manner, providing them with new biorecognition and/or “stealth” properties.

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9

Marshall, Checkers R., Emma E. Timmel, Sara A. Staudhammer, and Carl K. Brozek. "Experimental evidence for a general model of modulated MOF nanoparticle growth." Chemical Science 11, no. 42 (2020): 11539–47. http://dx.doi.org/10.1039/d0sc04845c.

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10

Zhang, Xuanjun, Mohamed Ali Ballem, Zhang-Jun Hu, Peder Bergman, and Kajsa Uvdal. "Nanoscale Light-Harvesting Metal-Organic Frameworks." Angewandte Chemie International Edition 50, no. 25 (May 9, 2011): 5729–33. http://dx.doi.org/10.1002/anie.201007277.

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11

Zhang, Xuanjun, Mohamed Ali Ballem, Zhang-Jun Hu, Peder Bergman, and Kajsa Uvdal. "Nanoscale Light-Harvesting Metal-Organic Frameworks." Angewandte Chemie 123, no. 25 (May 9, 2011): 5847–51. http://dx.doi.org/10.1002/ange.201007277.

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12

Huang, Xuan, Xu Sun, Weili Wang, Qing Shen, Qian Shen, Xuna Tang, and Jinjun Shao. "Nanoscale metal–organic frameworks for tumor phototherapy." Journal of Materials Chemistry B 9, no. 18 (2021): 3756–77. http://dx.doi.org/10.1039/d1tb00349f.

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13

Ni, Kaiyuan, Taokun Luo, Geoffrey T. Nash, and Wenbin Lin. "Nanoscale Metal–Organic Frameworks for Cancer Immunotherapy." Accounts of Chemical Research 53, no. 9 (August 18, 2020): 1739–48. http://dx.doi.org/10.1021/acs.accounts.0c00313.

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14

Zhang, Xiaofei, Jianyu Han, Jun Guo, and Zhiyong Tang. "Engineering Nanoscale Metal‐Organic Frameworks for Heterogeneous Catalysis." Small Structures 2, no. 6 (March 17, 2021): 2000141. http://dx.doi.org/10.1002/sstr.202000141.

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15

Afreen, Sadia, Zhimei He, Yan Xiao, and Jun-Jie Zhu. "Nanoscale metal–organic frameworks in detecting cancer biomarkers." Journal of Materials Chemistry B 8, no. 7 (2020): 1338–49. http://dx.doi.org/10.1039/c9tb02579k.

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16

Lan, Guangxu, Kaiyuan Ni, and Wenbin Lin. "Nanoscale metal–organic frameworks for phototherapy of cancer." Coordination Chemistry Reviews 379 (January 2019): 65–81. http://dx.doi.org/10.1016/j.ccr.2017.09.007.

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17

Bhakta, Raghunandan K., Julie L. Herberg, Benjamin Jacobs, Aaron Highley, Richard Behrens, Nathan W. Ockwig, Jeffery A. Greathouse, and Mark D. Allendorf. "Metal−Organic Frameworks As Templates for Nanoscale NaAlH4." Journal of the American Chemical Society 131, no. 37 (September 23, 2009): 13198–99. http://dx.doi.org/10.1021/ja904431x.

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18

Sajid, Muhammad. "Toxicity of nanoscale metal organic frameworks: a perspective." Environmental Science and Pollution Research 23, no. 15 (June 14, 2016): 14805–7. http://dx.doi.org/10.1007/s11356-016-7053-y.

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19

Ren, Xiao-Yan, and Le-Hui Lu. "Luminescent nanoscale metal–organic frameworks for chemical sensing." Chinese Chemical Letters 26, no. 12 (December 2015): 1439–45. http://dx.doi.org/10.1016/j.cclet.2015.10.014.

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20

Wang, Shunzhi, William Morris, Yangyang Liu, C. Michael McGuirk, Yu Zhou, Joseph T. Hupp, Omar K. Farha, and Chad A. Mirkin. "Surface-Specific Functionalization of Nanoscale Metal-Organic Frameworks." Angewandte Chemie International Edition 54, no. 49 (October 23, 2015): 14738–42. http://dx.doi.org/10.1002/anie.201506888.

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21

Wang, Shunzhi, William Morris, Yangyang Liu, C. Michael McGuirk, Yu Zhou, Joseph T. Hupp, Omar K. Farha, and Chad A. Mirkin. "Surface-Specific Functionalization of Nanoscale Metal-Organic Frameworks." Angewandte Chemie 127, no. 49 (October 23, 2015): 14951–55. http://dx.doi.org/10.1002/ange.201506888.

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22

Mao, Jianming, Ziwan Xu, and Wenbin Lin. "Nanoscale metal–organic frameworks for photodynamic therapy and radiotherapy." Current Opinion in Chemical Engineering 38 (December 2022): 100871. http://dx.doi.org/10.1016/j.coche.2022.100871.

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23

Wang, Weiqi, Lei Wang, Zhensheng Li, and Zhigang Xie. "BODIPY-containing nanoscale metal–organic frameworks for photodynamic therapy." Chemical Communications 52, no. 31 (2016): 5402–5. http://dx.doi.org/10.1039/c6cc01048b.

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24

Gong, Teng, Yanli Li, Bin Lv, Han Wang, Yanyan Liu, Wei Yang, Yelin Wu, et al. "Full-Process Radiosensitization Based on Nanoscale Metal–Organic Frameworks." ACS Nano 14, no. 3 (March 9, 2020): 3032–40. http://dx.doi.org/10.1021/acsnano.9b07898.

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25

Otsubo, Kazuya, Tomoyuki Haraguchi, and Hiroshi Kitagawa. "Nanoscale crystalline architectures of Hofmann-type metal–organic frameworks." Coordination Chemistry Reviews 346 (September 2017): 123–38. http://dx.doi.org/10.1016/j.ccr.2017.03.022.

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26

Yan, Peijuan, Jinjie Fan, Yalan Ji, Ruikang Zhang, Yuze Dong, and Yingnan Zhu. "Photodynamic therapy strategy based on nanoscale metal-organic frameworks." Next Materials 2 (January 2024): 100111. http://dx.doi.org/10.1016/j.nxmate.2024.100111.

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27

Hu, Xuefu, Zhiye Wang, Yuming Su, Peican Chen, Jiawei Chen, Cankun Zhang, and Cheng Wang. "Nanoscale Metal–Organic Frameworks and Metal–Organic Layers with Two-Photon-Excited Fluorescence." Inorganic Chemistry 59, no. 7 (March 13, 2020): 4181–85. http://dx.doi.org/10.1021/acs.inorgchem.0c00373.

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28

Xiao, Heting, Hebin Jiang, Haixia Yin, and Yueting Sun. "Nanofluidic Attenuation of Metal-Organic Frameworks." INTER-NOISE and NOISE-CON Congress and Conference Proceedings 265, no. 1 (February 1, 2023): 6314–21. http://dx.doi.org/10.3397/in_2022_0938.

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Porous materials with energy absorption characteristics have been used for attenuation against hazardous vibrations and noises. The intrusion of liquid water and aqueous solutions into hydrophobic nanoporous materials such as metal-organic frameworks (MOFs) present an attractive pathway to engineering new attenuation technologies. In this process, hydrostatic pressure forces water to intrude hydrophobic nanopores, thereby converting mechanical work into interfacial energy through nanoscale interfacial interactions. Once the external pressure is removed, water molecules can flow out of the nanopores spontaneously, making the system reversible. We envision that this mechanism has the potential of innovating attenuation technologies, so in this work we provided a preliminary study in this direction. We investigated a material system consisting of water and a commonly used MOF, zeolitic imidazolate framework-8 (ZIF-8), and demonstrated its reversibility and stability under cyclic pressurization, considered its performance at various peak pressures and frequencies, its tunability in terms of intrusion pressure, and its potential in hydrogel forms. These features are important for potential attenuation technologies based on this novel mechanism.

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29

Kuyuldar, Seher, Douglas T. Genna, and Clemens Burda. "On the potential for nanoscale metal–organic frameworks for energy applications." Journal of Materials Chemistry A 7, no. 38 (2019): 21545–76. http://dx.doi.org/10.1039/c9ta09896h.

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30

Dou, Xilin, Kai Sun, Haobin Chen, Yifei Jiang, Li Wu, Jun Mei, Zhaoyang Ding, and Jing Xie. "Nanoscale Metal-Organic Frameworks as Fluorescence Sensors for Food Safety." Antibiotics 10, no. 4 (March 28, 2021): 358. http://dx.doi.org/10.3390/antibiotics10040358.

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Food safety has attracted attention worldwide, and how to detect various kinds of hazardous substances in an efficient way has always been a focus. Metal-Organic Frameworks (MOFs) are a class of hybrid porous materials formed by organic ligand and metal ions. Nanoscale MOFs (NMOFs) exhibit great potential in serving as fluorescence sensors for food safety due to their superior properties including high accuracy, great stability, fast response, etc. In this review, we focus on the recent development of NMOFs sensing for food safety. Several typical methods of NMOFs synthesis are presented. NMOFs-based fluorescence sensors for contaminants and adulterants, such as antibiotics, food additives, ions and mycotoxin etc. are summarized, and the sensing mechanisms are also presented. We explore these challenges in detail and provide suggestions about how they may be surmounted. This review could help the exploration of NMOFs sensors in food related work.

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Li, Qing, Ying Liu, Yanru Zhang, and Wei Jiang. "Immunogenicity-boosted cancer immunotherapy based on nanoscale metal-organic frameworks." Journal of Controlled Release 347 (July 2022): 183–98. http://dx.doi.org/10.1016/j.jconrel.2022.05.003.

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32

Meng, Hong-Min, Xiao-Xiao Hu, Ge-Zhi Kong, Chan Yang, Ting Fu, Zhao-Hui Li, and Xiao-Bing Zhang. "Aptamer-functionalized nanoscale metal-organic frameworks for targeted photodynamic therapy." Theranostics 8, no. 16 (2018): 4332–44. http://dx.doi.org/10.7150/thno.26768.

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33

Rieter, William J., Kathryn M. L. Taylor, Hongyu An, Weili Lin, and Wenbin Lin. "Nanoscale Metal−Organic Frameworks as Potential Multimodal Contrast Enhancing Agents." Journal of the American Chemical Society 128, no. 28 (July 2006): 9024–25. http://dx.doi.org/10.1021/ja0627444.

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34

Taylor, Kathryn M. L., William J. Rieter, and Wenbin Lin. "Manganese-Based Nanoscale Metal−Organic Frameworks for Magnetic Resonance Imaging." Journal of the American Chemical Society 130, no. 44 (November 5, 2008): 14358–59. http://dx.doi.org/10.1021/ja803777x.

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35

Della Rocca, Joseph, Demin Liu, and Wenbin Lin. "Nanoscale Metal–Organic Frameworks for Biomedical Imaging and Drug Delivery." Accounts of Chemical Research 44, no. 10 (October 18, 2011): 957–68. http://dx.doi.org/10.1021/ar200028a.

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36

Chen, Peican, Zeyu Tang, Zhongming Zeng, Xuefu Hu, Liangping Xiao, Yi Liu, Xudong Qian, et al. "Machine-Learning-Guided Morphology Engineering of Nanoscale Metal-Organic Frameworks." Matter 2, no. 6 (June 2020): 1651–66. http://dx.doi.org/10.1016/j.matt.2020.04.021.

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37

Liu, Ming, Lei Wang, Xiaohua Zheng, Shi Liu, and Zhigang Xie. "Hypoxia-Triggered Nanoscale Metal–Organic Frameworks for Enhanced Anticancer Activity." ACS Applied Materials & Interfaces 10, no. 29 (June 29, 2018): 24638–47. http://dx.doi.org/10.1021/acsami.8b07570.

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Zhong, Xiao-fang, and Xun Sun. "Nanomedicines based on nanoscale metal-organic frameworks for cancer immunotherapy." Acta Pharmacologica Sinica 41, no. 7 (April 30, 2020): 928–35. http://dx.doi.org/10.1038/s41401-020-0414-6.

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Li, Fei-Long, Qi Shao, Xiaoqing Huang, and Jian-Ping Lang. "Nanoscale Trimetallic Metal-Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis." Angewandte Chemie 130, no. 7 (December 13, 2017): 1906–10. http://dx.doi.org/10.1002/ange.201711376.

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40

Ren, Xiao-Yan, and Le-Hui Lu. "ChemInform Abstract: Luminescent Nanoscale Metal-Organic Frameworks for Chemical Sensing." ChemInform 47, no. 7 (January 2016): no. http://dx.doi.org/10.1002/chin.201607277.

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41

Lu, Kuangda, Theint Aung, Nining Guo, Ralph Weichselbaum, and Wenbin Lin. "Nanoscale Metal-Organic Frameworks for Therapeutic, Imaging, and Sensing Applications." Advanced Materials 30, no. 37 (July 4, 2018): 1707634. http://dx.doi.org/10.1002/adma.201707634.

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Li, Fei-Long, Qi Shao, Xiaoqing Huang, and Jian-Ping Lang. "Nanoscale Trimetallic Metal-Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis." Angewandte Chemie International Edition 57, no. 7 (December 13, 2017): 1888–92. http://dx.doi.org/10.1002/anie.201711376.

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43

Wang, Lei, Min Zheng, and Zhigang Xie. "Nanoscale metal–organic frameworks for drug delivery: a conventional platform with new promise." Journal of Materials Chemistry B 6, no. 5 (2018): 707–17. http://dx.doi.org/10.1039/c7tb02970e.

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Sharma, Shalini, Komal Sethi, and Indrajit Roy. "Magnetic nanoscale metal–organic frameworks for magnetically aided drug delivery and photodynamic therapy." New Journal of Chemistry 41, no. 20 (2017): 11860–66. http://dx.doi.org/10.1039/c7nj02032e.

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45

Xu, Longhua, Guozhen Fang, Jifeng Liu, Mingfei Pan, Ranran Wang, and Shuo Wang. "One-pot synthesis of nanoscale carbon dots-embedded metal–organic frameworks at room temperature for enhanced chemical sensing." Journal of Materials Chemistry A 4, no. 41 (2016): 15880–87. http://dx.doi.org/10.1039/c6ta06403e.

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46

Wu, Jieyun, Wanying Zhang, Ying Wang, Binghui Li, Ting Hao, Youbin Zheng, Lianzhong Jiang, Kaixin Chen, and Kin Seng Chiang. "Nanoscale light–matter interactions in metal–organic frameworks cladding optical fibers." Nanoscale 12, no. 18 (2020): 9991–10000. http://dx.doi.org/10.1039/c9nr09061d.

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47

Lu, Ye, and Bing Yan. "Luminescent lanthanide barcodes based on postsynthetic modified nanoscale metal–organic frameworks." J. Mater. Chem. C 2, no. 35 (2014): 7411–16. http://dx.doi.org/10.1039/c4tc01077a.

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A new method for producing luminescent barcodes based on nanoscale MOFs (MOF-253) and postsynthetic method (PSM) is reported. The synthesized barcoded material is successfully applied in marking a functional ionic liquid and preparing a luminescent thin film.

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48

Sethi, Komal, Shalini Sharma, and Indrajit Roy. "Nanoscale iron carboxylate metal organic frameworks as drug carriers for magnetically aided intracellular delivery." RSC Advances 6, no. 80 (2016): 76861–66. http://dx.doi.org/10.1039/c6ra18480d.

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49

Zhang, Yang. "Advanced metal-organic frameworks materials for drug delivery." Applied and Computational Engineering 7, no. 1 (July 21, 2023): 412–18. http://dx.doi.org/10.54254/2755-2721/7/20230389.

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Metal-organic frameworks (MOFs) are porous crystalline polymers composed of coordination reactions between organic ligands and metal ions. They have high loading capacity, high specific surface area, high flexibility and a variety of different material preparation options. In different fields, MOFs also play different roles. It has been employed as a promising material for efficient drug delivery systems due to its unique characteristic and structures. This paper discusses the application of nanoscale MOFs (NMOFs) in the field of drug delivery and introduces its advantages and disadvantages compared with traditional DDSs materials, as well as different methods used as carriers for different therapeutic gases (CO, NO, O2), thereby achieve targeted delivery of drugs. The different biological toxicity, structural stability, morphology under physiological conditions, and control of pore channels caused by different metal linkers and organic ligands are studied and analyzed, which provides the future development of new drug-carrying systems and MOFs in other drug fields. Insights and guidance.

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Gu, Yuling. "The Properties, Synthesis, and Medical Applications of Nanoscale Metal Organic Frameworks." Journal of Physics: Conference Series 1948, no. 1 (June 1, 2021): 012175. http://dx.doi.org/10.1088/1742-6596/1948/1/012175.

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