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Journal articles on the topic 'Na3V2(PO4)2F3'

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Author: Grafiati

Published: 25 May 2024

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1

Zhang, Jiexin, Congrui Zhang, Yu Han, Xingyu Zhao, Wenjie Liu, and Yi Ding. "A surface-modified Na₃V₂(PO₄)₂F₃ cathode with high rate capability and cycling stability for sodium ion batteries." RSC Advances 14, no. 20 (2024): 13703–10. http://dx.doi.org/10.1039/d4ra00427b.

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Na3V2(PO4)2F3 is an ideal cathode material for sodium-ion batteries with a high theoretical energy density. In this paper, the electronic conductivity of Na3V2(PO4)2F3 was improved by using a simple surface carbon coating method, and excellent electrochemical properties were obtained.

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2

Nowagiel, Maciej, Anton Hul, Edvardas Kazakevicius, Algimantas Kežionis, Jerzy E. Garbarczyk, and Tomasz K. Pietrzak. "Optimization of Electrical Properties of Nanocrystallized Na3M2(PO4)2F3 NASICON-like Glasses (M = V, Ti, Fe)." Coatings 13, no. 3 (February 21, 2023): 482. http://dx.doi.org/10.3390/coatings13030482.

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Recently, an interest in NASICON-type materials revived, as they are considered potential cathode materials in sodium–ion batteries used in large-scale energy storage. We applied a facile technique of thermal nanocrystallization of glassy analogs of these compounds to enhance their electrical parameters. Six nanomaterials of the Na3M2(PO4)2F3 (M = V, Ti, Fe) system were studied. Samples with nominal compositions of Na3V2(PO4)2F3, Na3Ti2(PO4)2F3, Na3Fe2(PO4)2F3, Na3TiV(PO4)2F3, Na3FeV(PO4)2F3 and Na3FeTi(PO4)2F3 have been synthesized as glasses using the melt-quenching method. X-ray diffraction measurements were conducted for as-synthesized samples and after heating at elevated temperatures to investigate the structure. Extensive impedance measurements allowed us to optimize the nanocrystallization process to enhance the electrical conductivity of cathode nanomaterials. Such a procedure resulted in samples with the conductivity at room temperature ranging from 1×10−9 up to 8×10−5 S/cm. We carried out in situ impedance spectroscopy measurements (in an ultra-high-frequency range up to 10 GHz) and compared them with thermal events observed in differential thermal analysis studies.

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3

Yu, Xiaobo, Tianyi Lu, Xiaokai Li, Jiawei Qi, Luchen Yuan, Zu Man, and Haitao Zhuo. "Realizing outstanding electrochemical performance with Na₃V₂(PO₄)₂F₃ modified with an ionic liquid for sodium-ion batteries." RSC Advances 12, no. 22 (2022): 14007–17. http://dx.doi.org/10.1039/d2ra01292h.

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4

Li, Long, Jing Zhao, Hongyang Zhao, Yuanyuan Qin, Xiaolong Zhu, Hu Wu, Zhongxiao Song, and Shujiang Ding. "Structure, composition and electrochemical performance analysis of fluorophosphates from different synthetic methods: is really Na₃V₂(PO₄)₂F₃ synthesized?" Journal of Materials Chemistry A 10, no. 16 (2022): 8877–86. http://dx.doi.org/10.1039/d2ta00565d.

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This work provides a reliable view for understanding the phase and composition of as-prepared Na3V2(PO4)2F3, showing that the proper introduction of oxygen substitution for fluorine is beneficial to the electrochemical performance.

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5

Guo, Rongting, Wei Li, Mingjun Lu, Yiju Lv, Huiting Ai, Dan Sun, Zheng Liu, and Guo-Cheng Han. "Na₃V₂(PO₄)₂F₃@bagasse carbon as cathode material for lithium/sodium hybrid ion battery." Physical Chemistry Chemical Physics 24, no. 9 (2022): 5638–45. http://dx.doi.org/10.1039/d1cp05011g.

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The biomass bagasse carbon-coated Na3V2(PO4)2F3/C with nano-scale spherical morphology, prepared by spray drying and high temperature calcination, were proved to have excellent specific capacity and good cycling performance by electrochemical testing.

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6

Lin, Zhi. "Phase Formation in NaH2PO4–VOSO4–NaF–H2O System and Rapid Synthesis of Na3V2O2x(PO4)2F3-2x." Crystals 14, no. 1 (December 28, 2023): 43. http://dx.doi.org/10.3390/cryst14010043.

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Renewable electricity products, for example, from wind and photovoltaic energy, need large-scale and economic energy storage systems to guarantee the requirements of our daily lives. Sodium-ion batteries are considered more economical than lithium-ion batteries in this area. Na3V2(PO4)2F3, NaVPO4F, and Na3(VO)2(PO4)2F are one type of material that may be used for Na-ion batteries. In order to better understand the synthesis of these materials, the phase formation in a NaH2PO4–VOSO4–NaF–H2O system under hydrothermal conditions was studied and is reported herein. This research focused on the influences of the sodium fluoride content and hydrothermal crystallization time on phase formation and phase purity. The phase transformation between Na(VO)2(PO4)2(H2O)4 and Na3V2O2x(PO4)2F3-2x was also studied. Na3V2O2x(PO4)2F3-2x with a high degree of crystallinity can be obtained in as short as 2 h via hydrothermal synthesis using a conventional oven at 170 °C without agitation. All compounds obtained in this research were studied mainly using powder X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectrometry, and Fourier-transform infrared spectroscopy.

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7

Olchowka, Jacob, Long H. B. Nguyen, Thibault Broux, Paula Sanz Camacho, Emmanuel Petit, François Fauth, Dany Carlier, Christian Masquelier, and Laurence Croguennec. "Aluminum substitution for vanadium in the Na3V2(PO4)2F3 and Na3V2(PO4)2FO2 type materials." Chemical Communications 55, no. 78 (2019): 11719–22. http://dx.doi.org/10.1039/c9cc05137f.

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Investigation of the effects of Al substitution for V on the structural properties and electrochemical performances for two of the most promising positive electrode materials for Na-ion batteries, Na₃V₂(PO₄)₂F₃ and Na₃V₂(PO₄)₂FO₂.

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8

Broux, Thibault, Benoît Fleutot, Rénald David, Annelise Brüll, Philippe Veber, François Fauth, Matthieu Courty, Laurence Croguennec, and Christian Masquelier. "Temperature Dependence of Structural and Transport Properties for Na3V2(PO4)2F3 and Na3V2(PO4)2F2.5O0.5." Chemistry of Materials 30, no. 2 (January 5, 2018): 358–65. http://dx.doi.org/10.1021/acs.chemmater.7b03529.

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9

Bianchini, M., N. Brisset, F. Fauth, F. Weill, E. Elkaim, E. Suard, C. Masquelier, and L. Croguennec. "Na3V2(PO4)2F3 Revisited: A High-Resolution Diffraction Study." Chemistry of Materials 26, no. 14 (June 30, 2014): 4238–47. http://dx.doi.org/10.1021/cm501644g.

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10

Yang, Ze, Guolong Li, Jingying Sun, Lixin Xie, Yan Jiang, Yunhui Huang, and Shuo Chen. "High performance cathode material based on Na3V2(PO4)2F3 and Na3V2(PO4)3 for sodium-ion batteries." Energy Storage Materials 25 (March 2020): 724–30. http://dx.doi.org/10.1016/j.ensm.2019.09.014.

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11

Bianchini, M., F. Lalère, H. B. L. Nguyen, F. Fauth, R. David, E. Suard, L. Croguennec, and C. Masquelier. "Ag3V2(PO4)2F3, a new compound obtained by Ag+/Na+ ion exchange into the Na3V2(PO4)2F3 framework." Journal of Materials Chemistry A 6, no. 22 (2018): 10340–47. http://dx.doi.org/10.1039/c8ta01095a.

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12

Bianchini, M., F. Fauth, N. Brisset, F. Weill, E. Suard, C. Masquelier, and L. Croguennec. "Comprehensive Investigation of the Na3V2(PO4)2F3–NaV2(PO4)2F3 System by Operando High Resolution Synchrotron X-ray Diffraction." Chemistry of Materials 27, no. 8 (April 7, 2015): 3009–20. http://dx.doi.org/10.1021/acs.chemmater.5b00361.

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13

Li, Wei, Xiaoyun Jing, Kai Jiang, and Dihua Wang. "Observation of Structural Decomposition of Na3V2(PO4)3 and Na3V2(PO4)2F3 as Cathodes for Aqueous Zn-Ion Batteries." ACS Applied Energy Materials 4, no. 3 (February 11, 2021): 2797–807. http://dx.doi.org/10.1021/acsaem.1c00067.

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14

GOVER, R., A. BRYAN, P. BURNS, and J. BARKER. "The electrochemical insertion properties of sodium vanadium fluorophosphate, Na3V2(PO4)2F3." Solid State Ionics 177, no. 17-18 (July 2006): 1495–500. http://dx.doi.org/10.1016/j.ssi.2006.07.028.

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15

Xun, Jiahong, Yu Zhang, and Huayun Xu. "One step synthesis of vesicular Na3V2(PO4)2F3 and network of Na3V2(PO4)2F3@graphene nanosheets with improved electrochemical performance as cathode material for sodium ion battery." Inorganic Chemistry Communications 115 (May 2020): 107884. http://dx.doi.org/10.1016/j.inoche.2020.107884.

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16

James Abraham, Jeffin, Buzaina Moossa, Hanan Abdurehman Tariq, Ramazan Kahraman, Siham Al-Qaradawi, and R. A. Shakoor. "Electrochemical Performance of Na3V2(PO4)2F3 Electrode Material in a Symmetric Cell." International Journal of Molecular Sciences 22, no. 21 (November 7, 2021): 12045. http://dx.doi.org/10.3390/ijms222112045.

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A NASICON-based Na3V2(PO4)2F3 (NVPF) cathode material is reported herein as a potential symmetric cell electrode material. The symmetric cell was active from 0 to 3.5 V and showed a capacity of 85 mAh/g at 0.1 C. With cycling, the NVPF symmetric cell showed a very long and stable cycle life, having a capacity retention of 61% after 1000 cycles at 1 C. The diffusion coefficient calculated from cyclic voltammetry (CV) and the galvanostatic intermittent titration technique (GITT) was found to be ~10−9–10−11, suggesting a smooth diffusion of Na+ in the NVPF symmetric cell. The electrochemical impedance spectroscopy (EIS) carried out during cycling showed increases in bulk resistance, solid electrolyte interphase (SEI) resistance, and charge transfer resistance with the number of cycles, explaining the origin of capacity fade in the NVPF symmetric cell. Finally, the postmortem analysis of the symmetric cell after 1000 cycles at a 1 C rate indicated that the intercalation/de-intercalation of sodium into/from the host structure occurred without any major structural destabilization in both the cathode and anode. However, there was slight distortion in the cathode structure observed, which resulted in capacity loss of the symmetric cell. The promising electrochemical performance of NVPF in the symmetric cell makes it attractive for developing long-life and cost-effective batteries.

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17

Kosova, Nina, Daria Rezepova, and Nicolas Montroussier. "Effect of La3+ Modification on the Electrochemical Performance of Na3V2(PO4)2F3." Batteries 4, no. 3 (July 9, 2018): 32. http://dx.doi.org/10.3390/batteries4030032.

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18

Song, Weixin, Xiaobo Ji, Jun Chen, Zhengping Wu, Yirong Zhu, Kefen Ye, Hongshuai Hou, Mingjun Jing, and Craig E. Banks. "Mechanistic investigation of ion migration in Na3V2(PO4)2F3 hybrid-ion batteries." Physical Chemistry Chemical Physics 17, no. 1 (2015): 159–65. http://dx.doi.org/10.1039/c4cp04649h.

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The ion-migration mechanism of Na₃V₂(PO₄)₂F₃ is investigated in Na₃V₂(PO₄)₂F₃–Li hybrid-ion batteries through a combined computational and experimental study.

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19

Pianta, Nicolò, Davide Locatelli, and Riccardo Ruffo. "Cycling properties of Na3V2(PO4)2F3 as positive material for sodium-ion batteries." Ionics 27, no. 5 (April 2, 2021): 1853–60. http://dx.doi.org/10.1007/s11581-021-04015-y.

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AbstractThe research into sodium-ion battery requires the development of high voltage cathodic materials to compensate for the potential of the negative electrode materials which is usually higher than the lithium counterparts. In this framework, the polyanionic compound Na3V2(PO4)2F3 was prepared by an easy-to-scale-up carbothermal method and characterized to evaluate its electrochemical performances in half cell vs. metallic sodium. The material shows a specific capacity (115 mAh g−1) close to the theoretical limit, good coulombic efficiency (>99%) and an excellent stability over several hundred cycles at high rate. High-loading free-standing electrodes were also tested, which showed interesting performances in terms of areal capacity and cyclability.

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20

Samarin, Aleksandr Sh, Alexey V. Ivanov, and Stanislav S. Fedotov. "Toward Efficient Recycling of Vanadium Phosphate-Based Sodium-Ion Batteries: A Review." Clean Technologies 5, no. 3 (July 6, 2023): 881–900. http://dx.doi.org/10.3390/cleantechnol5030044.

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Sodium-ion batteries (SIBs) have demonstrated noticeable development since the 2010s, being complementary to the lithium-ion technology in predominantly large-scale application niches. The projected SIB market growth will inevitably lead to the generation of tons of spent cells, posing a notorious issue for proper battery lifecycle management, which requires both the establishment of a regulatory framework and development of technologies for recovery of valuable elements from battery waste. While lithium-ion batteries are mainly based on layered oxides and lithium iron phosphate chemistries, the variety of sodium-ion batteries is much more diverse, extended by a number of other polyanionic families (crystal types), such as NASICON (Na3V2(PO4)3), Na3V2(PO4)2F3−yOy, (0 ≤ y ≤ 2), KTiOPO4-type AVPO4X (A—alkali metal cation, X = O, F) and β-NaVP2O7, with all of them relying on vanadium and phosphorous—critical elements in a myriad of industrial processes and technologies. Overall, the greater chemical complexity of these vanadium-containing phosphate materials highlights the need for designing specific recycling approaches based on distinctive features of vanadium and phosphorus solution chemistry, fine-tuned for the particular electrodes used. In this paper, an overview of recycling methods is presented with a focus on emerging chemistries for SIBs.

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21

Semykina, Daria O., Maria A. Kirsanova, Yury M. Volfkovich, Valentin E. Sosenkin, and Nina V. Kosova. "Porosity, microstructure and electrochemistry of Na3V2(PO4)2F3/C prepared by mechanical activation." Journal of Solid State Chemistry 297 (May 2021): 122041. http://dx.doi.org/10.1016/j.jssc.2021.122041.

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22

Li, Wei, Kangli Wang, Shijie Cheng, and Kai Jiang. "A long-life aqueous Zn-ion battery based on Na3V2(PO4)2F3 cathode." Energy Storage Materials 15 (November 2018): 14–21. http://dx.doi.org/10.1016/j.ensm.2018.03.003.

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23

Wang, Jie, Qiming Liu, Shiyue Cao, Huijuan Zhu, and Yilin Wang. "Boosting sodium-ion battery performance with binary metal-doped Na3V2(PO4)2F3 cathodes." Journal of Colloid and Interface Science 665 (July 2024): 1043–53. http://dx.doi.org/10.1016/j.jcis.2024.04.003.

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24

Hu, Fangdong, and Xiaolei Jiang. "Superior performance of carbon modified Na3V2(PO4)2F3 cathode material for sodium-ion batteries." Inorganic Chemistry Communications 129 (July 2021): 108653. http://dx.doi.org/10.1016/j.inoche.2021.108653.

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25

Vali, R., P. Moller, and A. Janes. "Synthesis and Characterization of Na3V2(PO4)2F3 Based Cathode Material for Sodium Ion Batteries." ECS Transactions 69, no. 39 (December 28, 2015): 27–36. http://dx.doi.org/10.1149/06939.0027ecst.

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26

Zhu, Lin, Hong Wang, Dan Sun, Yougen Tang, and Haiyan Wang. "A comprehensive review on the fabrication, modification and applications of Na3V2(PO4)2F3 cathodes." Journal of Materials Chemistry A 8, no. 41 (2020): 21387–407. http://dx.doi.org/10.1039/d0ta07872g.

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This review provides a specialized summary of Na₃V₂(PO₄)₂F₃ cathodes for the first time, including an in-depth discussion of fabrication methods, modification strategies and applications.

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27

Park, Min Je, and Arumugam Manthiram. "Unveiling the Charge Storage Mechanism in Nonaqueous and Aqueous Zn/Na3V2(PO4)2F3 Batteries." ACS Applied Energy Materials 3, no. 5 (April 14, 2020): 5015–23. http://dx.doi.org/10.1021/acsaem.0c00505.

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28

Peng, Manhua, Xiayan Wang, and Guangsheng Guo. "Synthesis of nano-Na3V2(PO4)2F3 cathodes with excess Na+ intercalation for enhanced capacity." Applied Materials Today 19 (June 2020): 100554. http://dx.doi.org/10.1016/j.apmt.2020.100554.

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29

Su, Renyuan, Weikai Zhu, Kang Liang, Peng Wei, Jianbin Li, Wenjun Liu, and Yurong Ren. "Mnx+ Substitution to Improve Na3V2(PO4)2F3-Based Electrodes for Sodium-Ion Battery Cathode." Molecules 28, no. 3 (February 1, 2023): 1409. http://dx.doi.org/10.3390/molecules28031409.

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Na3V2(PO4)2F3 (NVPF) is an extremely promising sodium storage cathode material for sodium-ion batteries because of its stable structure, wide electrochemical window, and excellent electrochemical properties. Nevertheless, the low ionic and electronic conductivity resulting from the insulated PO43− structure limits its further development. In this work, the different valence states of Mnx+ ions (x = 2, 3, 4) doped NVPF were synthesized by the hydrothermal method. A series of tests and characterizations reveals that the doping of Mn ions (Mn2+, Mn3+, Mn4+) changes the crystal structure and also affects the residual carbon content, which further influences the electrochemical properties of NVPF-based materials. The sodiation/desodiation mechanism was also investigated. Among them, the as-prepared NVPF doped with Mn2+ delivers a high reversible discharge capacity (116.2 mAh g−1 at 0.2 C), and the capacity retention of 67.7% after 400 cycles at 1 C was obtained. Such excellent performance and facile modified methods will provide new design ideas for the development of secondary batteries.

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30

Geng, Jiguo, Feng Li, Shengqian Ma, Jing Xiao, and Manling Sui. "First Principle Study of Na3V2(PO4)2F3 for Na Batteries Application and Experimental Investigation." International Journal of Electrochemical Science 11, no. 5 (May 2016): 3815–23. http://dx.doi.org/10.1016/s1452-3981(23)17439-6.

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31

Nguyen, Long H. B., Thibault Broux, Paula Sanz Camacho, Dominique Denux, Lydie Bourgeois, Stéphanie Belin, Antonella Iadecola, et al. "Stability in water and electrochemical properties of the Na3V2(PO4)2F3 – Na3(VO)2(PO4)2F solid solution." Energy Storage Materials 20 (July 2019): 324–34. http://dx.doi.org/10.1016/j.ensm.2019.04.010.

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32

Cheng, Jun, Yanjun Chen, Shiqi Sun, Zeyi Tian, Yaoyao Linghu, Zhen Tian, Chao Wang, Zhenfeng He, and Li Guo. "Na3V2(PO4)3/C·Na3V2(PO4)2F3/C@rGO blended cathode material with elevated energy density for sodium ion batteries." Ceramics International 47, no. 13 (July 2021): 18065–74. http://dx.doi.org/10.1016/j.ceramint.2021.03.122.

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33

Li, Feng, Yifei Zhao, Lishuang Xia, Zhendong Yang, Jinping Wei, and Zhen Zhou. "Well-dispersed Na3V2(PO4)2F3@rGO with improved kinetics for high-power sodium-ion batteries." Journal of Materials Chemistry A 8, no. 25 (2020): 12391–97. http://dx.doi.org/10.1039/d0ta00130a.

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Well-dispersed Na₃V₂(PO₄)₂F₃@rGO is proposed to improve the kinetics of Na₃V₂(PO₄)₂F₃ cathode materials for high-power sodium-ion batteries.

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34

Shakoor, R. A., Dong-Hwa Seo, Hyungsub Kim, Young-Uk Park, Jongsoon Kim, Sung-Wook Kim, Hyeokjo Gwon, Seongsu Lee, and Kisuk Kang. "A combined first principles and experimental study on Na3V2(PO4)2F3 for rechargeable Na batteries." Journal of Materials Chemistry 22, no. 38 (2012): 20535. http://dx.doi.org/10.1039/c2jm33862a.

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35

Criado, A., P. Lavela, G. Ortiz, J. L. Tirado, C. Pérez-Vicente, N. Bahrou, and Z. Edfouf. "Highly dispersed oleic-induced nanometric C@Na3V2(PO4)2F3 composites for efficient Na-ion batteries." Electrochimica Acta 332 (February 2020): 135502. http://dx.doi.org/10.1016/j.electacta.2019.135502.

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36

Liu, Zigeng, Yan-Yan Hu, Matthew T. Dunstan, Hua Huo, Xiaogang Hao, Huan Zou, Guiming Zhong, Yong Yang, and Clare P. Grey. "Local Structure and Dynamics in the Na Ion Battery Positive Electrode Material Na3V2(PO4)2F3." Chemistry of Materials 26, no. 8 (April 11, 2014): 2513–21. http://dx.doi.org/10.1021/cm403728w.

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37

Zhu, Lin, Qi Zhang, Dan Sun, Qi Wang, Nana Weng, Yougen Tang, and Haiyan Wang. "Engineering the crystal orientation of Na3V2(PO4)2F3@rGO microcuboids for advanced sodium-ion batteries." Materials Chemistry Frontiers 4, no. 10 (2020): 2932–42. http://dx.doi.org/10.1039/d0qm00364f.

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Na₃V₂(PO₄)₂F₃@rGO can expose different crystal facets and exhibit excellent electrochemical performance via guiding the crystal growth orientation.

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38

Hu, Yu, Peiyu Chen, Fanfan Liu, Xiaolong Cheng, Yu Shao, Peng Lu, Hui Zhang, Shikuo Li, Fangzhi Huang, and Yu Jiang. "Dual-anion ether electrolyte enables stable high-voltage Na3V2(PO4)2F3 cathode under wide temperatures." Journal of Power Sources 602 (May 2024): 234405. http://dx.doi.org/10.1016/j.jpowsour.2024.234405.

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39

Puspitasari, Diah Agustina, Jagabandhu Patra, I.-Ming Hung, Dominic Bresser, Tai-Chou Lee, and Jeng-Kuei Chang. "Optimizing the Mg Doping Concentration of Na3V2–xMgx(PO4)2F3/C for Enhanced Sodiation/Desodiation Properties." ACS Sustainable Chemistry & Engineering 9, no. 20 (May 11, 2021): 6962–71. http://dx.doi.org/10.1021/acssuschemeng.1c00418.

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40

Zhu, Pengfei, Wenjie Peng, Huajun Guo, Xinhai Li, Zhixing Wang, Ding Wang, Jianguo Duan, Jiexi Wang, and Guochun Yan. "Toward high-performance sodium storage cathode: Construction and purification of carbon-coated Na3V2(PO4)2F3 materials." Journal of Power Sources 546 (October 2022): 231986. http://dx.doi.org/10.1016/j.jpowsour.2022.231986.

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41

Kosova, Nina V., Daria O. Rezepova, Sergey A. Petrov, and Arseny B. Slobodyuk. "Electrochemical and Chemical Na+/Li+Ion Exchange in Na-Based Cathode Materials: Na1.56Fe1.22P2O7and Na3V2(PO4)2F3." Journal of The Electrochemical Society 164, no. 1 (December 7, 2016): A6192—A6200. http://dx.doi.org/10.1149/2.0301701jes.

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42

Yi, Hongming, Le Lin, Moxiang Ling, Zhiqiang Lv, Rui Li, Qiang Fu, Huamin Zhang, Qiong Zheng, and Xianfeng Li. "Scalable and Economic Synthesis of High-Performance Na3V2(PO4)2F3 by a Solvothermal–Ball-Milling Method." ACS Energy Letters 4, no. 7 (June 11, 2019): 1565–71. http://dx.doi.org/10.1021/acsenergylett.9b00748.

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43

Liu, Shuang, Liubin Wang, Jian Liu, Meng Zhou, Qingshun Nian, Yazhi Feng, Zhanliang Tao, and Lianyi Shao. "Na3V2(PO4)2F3–SWCNT: a high voltage cathode for non-aqueous and aqueous sodium-ion batteries." Journal of Materials Chemistry A 7, no. 1 (2019): 248–56. http://dx.doi.org/10.1039/c8ta09194c.

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Due to the merits of low cost, safety, environmental friendliness, and abundant sodium reserves, non-aqueous and aqueous sodium-ion batteries are wonderful alternatives for large-scale energy storage.

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44

Guo, Biao, Wenyu Diao, Tingting Yuan, Yuan Liu, Qi Yuan, Guannan Li, and Jingang Yang. "Enhanced electrochemical performance of Na3V2(PO4)2F3 for Na-ion batteries with nanostructure and carbon coating." Journal of Materials Science: Materials in Electronics 29, no. 19 (July 23, 2018): 16325–29. http://dx.doi.org/10.1007/s10854-018-9722-8.

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45

Zhang, Yusheng, Youzuo Hu, Tingting Feng, Ziqiang Xu, and Mengqiang Wu. "Mg-doped Na3V2-xMgx(PO4)2F3@C sodium ion cathodes with enhanced stability and rate capability." Journal of Power Sources 602 (May 2024): 234337. http://dx.doi.org/10.1016/j.jpowsour.2024.234337.

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46

Hwang, Jinkwang, Ikuma Aoyagi, Masaya Takiyama, Kazuhiko Matsumoto, and Rika Hagiwara. "Inhibition of Aluminum Corrosion with the Addition of the Tris(pentafluoroethyl)trifluorophosphate Anion to a Sulfonylamide-Based Ionic Liquid for Sodium-Ion Batteries." Journal of The Electrochemical Society 169, no. 8 (August 1, 2022): 080522. http://dx.doi.org/10.1149/1945-7111/ac8a1f.

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Ionic liquids (ILs) based on sulfonylamide-type anions have gained widespread utility as electrolytes for secondary batteries. Although sulfonylamide-based IL electrolytes are known to form a stable passivation layer that prevents Al corrosion, the Al electrode in the Na[FSA]-[C2C1im][FSA] ([FSA] = bis(fluorosulfonyl)amide and [C2C1im] = 1-ethyl-3-methylimidazolium) IL, is found to be afflicted by pitting corrosion at potentials above 4 V vs Na+/Na during electrochemical measurement at 90 °C. Therefore, this study investigates the suppressive effect of [FAP]− (FAP = tris(pentafluoroethyl)trifluorophosphate) on the Al corrosion behavior of the IL electrolyte. Here, the inhibited corrosion of the Al electrode is confirmed through a series of cyclic voltammetry measurements, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. Charge-discharge tests performed using a Na3V2(PO4)2F3 positive electrode demonstrates that the addition of [FAP]– into the IL enhances cycling performance at the intermediate temperature of 90 °C.

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47

Zhu, Weikai, Kang Liang, and Yurong Ren. "Modification of the morphology of Na3V2(PO4)2F3 as cathode material for sodium-ion batteries by polyvinylpyrrolidone." Ceramics International 47, no. 12 (June 2021): 17192–201. http://dx.doi.org/10.1016/j.ceramint.2021.03.030.

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48

Nongkynrih, Jeffry, Abhinanda Sengupta, Brindaban Modak, Sagar Mitra, A. K. Tyagi, and Dimple P. Dutta. "Enhanced electrochemical properties of W-doped Na3V2(PO4)2F3@C as cathode material in sodium ion batteries." Electrochimica Acta 415 (May 2022): 140256. http://dx.doi.org/10.1016/j.electacta.2022.140256.

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49

Wang, Mingxue, Xiaobing Huang, Haiyan Wang, Tao Zhou, Huasheng Xie, and Yurong Ren. "Synthesis and electrochemical performances of Na3V2(PO4)2F3/C composites as cathode materials for sodium ion batteries." RSC Advances 9, no. 53 (2019): 30628–36. http://dx.doi.org/10.1039/c9ra05089b.

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Na₃V₂(PO₄)₂F₃/C composites were synthesized by a solid-state reaction method using pitch as the carbon source, the as-prepared sample with the carbon content of 12.14% possesses an excellent rate performance and cycle stability.

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Yan, Guochun, Romain Dugas, and Jean-Marie Tarascon. "The Na3V2(PO4)2F3/Carbon Na-Ion Battery: Its Performance Understanding as Deduced from Differential Voltage Analysis." Journal of The Electrochemical Society 165, no. 2 (2018): A220—A227. http://dx.doi.org/10.1149/2.0831802jes.

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