Academic literature on the topic 'Molecular and optical physics not elsewhere classified'

Floods are among the costliest natural hazards, in Australia and globally. In this study, we used an indicator-based method to assess flood hazard risk in Australia’s Hawkesbury-Nepean catchment (HNC). Australian flood risk assessments are typically spatially constrained through the common use of resource-intensive flood modelling. The large spatial scale of this study area is the primary element of novelty in this research. The indicators of maximum 3-day precipitation (M3DP), distance to river—elevation weighted (DREW), and soil moisture (SM) were used to create the final Flood Hazard Index (FHI). The 17–26 March 2021 flood event in the HNC was used as a case study. It was found that almost 85% of the HNC was classified by the FHI at ‘severe’ or ‘extreme’ level, illustrating the extremity of the studied event. The urbanised floodplain area in the central-east of the HNC had the highest FHI values. Conversely, regions along the western border of the catchment had the lowest flood hazard risk. The DREW indicator strongly correlated with the FHI. The M3DP indicator displayed strong trends of extreme rainfall totals increasing towards the eastern catchment border. The SM indicator was highly variable, but featured extreme values in conservation areas of the HNC. This study introduces a method of large-scale proxy flood hazard assessment that is novel in an Australian context. A proof-of-concept methodology of flood hazard assessment developed for the HNC is replicable and could be applied to other flood-prone areas elsewhere.

PurposeTo evaluate the utility of widefield optical coherence tomography angiography (WF-OCTA) compared with clinical examination in grading diabetic retinopathy in patients diagnosed clinically with proliferative diabetic retinopathy (PDR) or severe non-proliferative diabetic retinopathy (NPDR).DesignThis retrospective observational case series included patients diagnosed clinically with PDR or severe NPDR. Patients underwent standard clinical examination and WF-OCTA imaging (PLEX Elite 9000, Carl Zeiss Meditec AG) using 12×12 montage scans between August 2018 and January 2019. Two trained graders identified neovascularisation at the disc (NVD) and neovascularisation elsewhere (NVE) on WF-OCTA which were compared with the clinical examination, and to ultra-widefield fluorescein angiography (UWFA) when available.ResultsSeventy-nine eyes of 46 patients were evaluated. Of those, 57 eyes were diagnosed clinically with PDR, and 22 with severe NPDR. NVD was detected on OCTA-B scan as preretinal hyperreflective material (PRHM) in 39 eyes (100%) with evident flow signals in 79.5% compared with 51.3% detected clinically. We further classified NVD on OCTA into four subtypes and found that subtypes 1 and 2 could not be seen on clinical examination alone. WF-OCTA detected NVE in 81% of the cases compared with 55.7% detected clinically. Using WF-OCTA resulted in a higher percentage of PDR grading (88.6%) than on clinical examination (72.2%). When available, UWFA confirmed the WF-OCTA diagnosis in the majority of cases.ConclusionThis study demonstrates that WF-OCTA has a higher detection rate of PDR than clinical examination. This suggests that this modality could be used non-invasively for the purpose of early detection and characterisation of neovascularisation.

Different experimental strategies towards the 3-dimensional photonic crystals operating at optical wavelength are classified. The detailed discussion is devoted to the recent progress in photonic crystals fabricated by template method — the photonic band gap materials on the base of opal. The control of photonic properties of opal-based gratings is achieved through impregnating the opal with high refractive index semiconductors and dielectrics. Experimental study demonstrated the dependence of the stop band behaviour upon the type of impregnation (complete or partial) and showed a way for approaching complete photonic band gap. The photoluminescence from opal- semiconductor gratings revealed suppression of spontaneous emission in the gap region with following enhancement of the emission efficiency at the low-energy edge of the gap.

Al x Ga 1-x Sb films in the regime 0 ≤ x ≤ 0.30 have been grown by metalorganic chemical vapor deposition on GaAs and GaSb substrates using TMAl , TMGa and TMSb precursors. We report the effects of growth conditions on the optical properties. Samples grown at temperatures of 540°C, 580°C and 600°C and a V/III ratio of 1 have been investigated. The Al x Ga 1-x Sb layers grown at 580°C and 600°C with a V/III ratio of 1 and Al content in the range of 0.5% to 25% were found to exhibit excellent optical quality with a very high optical transmission at energies below the bandgap. The principle photoluminescence features observed are attributed to bound exciton and donor-acceptor transitions with FWHM comparable to the best values reported elsewhere.

The paper reviews the current status and designs of all-optical gates. Various schemes with and without semiconductor optical amplifiers are discussed and compared. The optical gates are classified according to their design structures. It is divided into two major divisions that is, nonsemiconductor optical amplifier based gates and semiconductor optical amplifier based gates. In nonsemiconductor optical amplifier based gates, different schemes have been proposed to create non-linearity which is discussed. The semiconductor optical amplifier based gates of different design structures are discussed to show the probe pulse that is modulated in different ways to obtain results.

Microcavity surface plasmon resonance sensors (MSPRSs) develop out of the classic surface plasmon resonance technologies and aim at producing novel lab-on-a-chip devices. MSPRSs generate a series of spectral resonances sensitive to minute changes in the refractive index. Related sensitivity studies and biosensing applications are published elsewhere. The goal of this work is to test the hypothesis that MSPRS resonances are standing surface plasmon waves excited at the surface of the sensor that decay back into propagating photons. Their optical properties (mean wavelength, peak width, and peak intensity) appear highly dependent on the internal morphology of the sensor and the underlying subwavelength aperture architecture in particular. Numerous optical experiments were designed to investigate trends that confirm this hypothesis. An extensive study of prior works was supportive of our findings and interpretations. A complete understanding of those mechanisms and parameters driving the formations of the MSPRS resonances would allow further improvement in sensor sensitivity, reliability, and manufacturability.

It is of great significance to measure the residual stress distribution accurately for optical elements and evaluate its influence on the performance of optical instruments in optical imaging, aviation remote sensing, semiconductor manufacturing, and other fields. The stress of optical elements can be closely related to birefringence based on photoelasticity. Thus, the method of quantifying birefringence to obtain the stress becomes the main method of stress measurement technologies for optical elements. This paper first introduces the basic principle of stress measurement based on photoelasticity. Then, the research progress of stress measurement technologies based on this principle is reviewed, which can be classified into two methods: polarization method and interference method. Meanwhile, the advantages and disadvantages of various stress measurement technologies are analyzed and compared. Finally, the developing trend of stress measurement technologies for optical elements is summarized and prospected.

This review summarizes the leading advancements in porous silicon (PSi) optical-biosensors, achieved over the past five years. The cost-effective fabrication process, the high internal surface area, the tunable pore size, and the photonic properties made the PSi an appealing transducing substrate for biosensing purposes, with applications in different research fields. Different optical PSi biosensors are reviewed and classified into four classes, based on the different biorecognition elements immobilized on the surface of the transducing material. The PL signal modulation and the effective refractive index changes of the porous matrix are the main optical transduction mechanisms discussed herein. The approaches that are commonly employed to chemically stabilize and functionalize the PSi surface are described.

Bridging the gap between the classical and quantum regimes has consequences not only for fundamental tests of quantum theory, but for the relation between quantum mechanics and gravity. The field of levito-dynamics provides a promising platform for testing the hypotheses of the works investigating these ideas. By manipulating a macroscopic particle's motion to the scale of its ground state wavefunction, levito-dynamics offers insight into the macroscopic-quantum regime.

Ardent and promising research has brought the field of levito-dynamics to a state in which these tests are available. Recent work has brought a mesoscopic particle's motion to near the ground state. Several factors of decoherence are limiting efficient testing of these fundamental theories which implies the need for alternative strategies for achieving the same goal. This thesis is concerned with investigating alternative methods that may enable a mesoscopic particle to reach the quantum regime. 

In this thesis, three theoretical proposals are studied as a means for a mesoscopic particle to reach the quantum regime as well as a detailed study into one of the most important factors of heating and decoherence for optical trapping. The first study of cooling a particle's motion highlights that the rotational degrees of freedom of a levitated symmetric-top particle leads to large harmonic frequencies compared to the translational motion, offering a more accessible ground state temperature after feedback cooling is applied. An analysis of a recent experiment under similar conditions is compared with the theoretical findings and found to be consistent. 

The second method of cooling takes advantage of the decades long knowledge of atom trapping and cooling. By coupling a spin-polarized, continuously Doppler cooled atomic gas to a magnetic nanoparticle through the dipole-dipole interaction, motional energy is able to be removed from the nanoparticle. Through this method, the particle is able to reach near its quantum ground state provided the atoms are at a temperature below the nanoparticle ground state temperature and the atom number is sufficiently large.
The final investigation presents the dynamics of an optically levitated dielectric disk in a Gaussian standing wave. Though few studies have been performed on disks both theoretically and experimentally, our findings show that the stable couplings between the translational and rotational degrees of freedom offer a possibility for cooling several degrees of freedom simultaneously by actively cooling a single degree freedom.

Atomic parity violation measurements provide a way to probe physics beyond the Standard Model. They can provide constraints on conjectures of a massive Z′ bosonor a light boson, or searches of dark energy. Using the two-pathway coherent control technique, our group plans to make a new measurement of the weak interaction induced parity non-conservation (PNC) transition moment (E_PNC) on the cesium 6S→7S transition. We will coherently interfere a 2-photon transition with the Stark and PNC transitions to amplify and extract the PNC amplitude. Previously, our lab has measured the magnetic dipole transition moment on the same 6S→7S transition to about 0.4% uncertainty using this technique. In this dissertation, I discuss improvements made to the system, and review what future upgrades are needed for a new E_PNC measurement. Key systematics are also described. For an accurate determination of E_PNC, properties of cesium such as the scalar (α) and vector (β) transition polarizabilities are needed. I present improved determinations of keyelectric dipole matrix elements, and calculate new high precision determinations of α and β. Finally, using β and the previously measured value of E_PNC/β, I calculate new values for the weak charge of the cesium nucleus Q_w.

The development of solution-processable semiconducting polymers has brought mankind’s long-sought dream of plastic electronics to fruition. Their potential in the manufacturing of lightweight, flexible yet robust, and biocompatible electronics has spurred their use in organic transistors, photovoltaics, electrochromic devices, batteries, and sensors for wearable electronics. Yet, despite the successful engineering of semiconducting polymers, we do not fully understand their molecular behavior and how it influences their doping (oxidation/reduction) properties. This is especially true for donor-acceptor (D-A) p-systems which have proven to be very efficient at tuning the electronic properties of organic semiconductors. Historically, chain-length dependent studies have been essential in uncovering the relationship between the molecular structure and polymer properties. Discussed here is the systematic investigation of a complete D-A molecular series composed of monodispersed and well-defined conjugated molecules ranging from oligomer (n=3-21) to polymer scale lengths. Structure-property relationships are established between the molecular structure, chain conformation, and redox-active opto-electronic properties for the molecular series in solution. This research reveals a rod-to-coil transition at the 15 unit chain length, or 4500 Da, in solution. The redox-active optical and electronic properties are investigated as a function of increasing chain-length, giving insight into the nature of charge carriers in a D-A conjugated system. This research aids in understanding the solution behavior of conjugated organic materials.

Metasurfaces are broadly defined as artificially engineered material interfaces that have the ability to determinately control the amplitude and phase signatures of an incident electromagnetic wave. Subwavelength sized optical scatterers employed at the planar interface of two media, introduce abrupt modifications to impinged light characteristics. Arbitrary engineering of the optical interactions and the arrangement of the scatterers on plane, enable ultra-compact, miniaturized optical systems with a wide array of applications (e.g. nanoscale and nonlinear optics, sensing, detection, energy harvesting, information processing and so on) realizable by the metasurfaces. However, maturation from the laboratory to industry scale realistic systems remain largely elusive despite the expanding reach and vast domains of functionalities demonstrated by researchers. A large part of this multi-faceted problem stems from the practical constraints posed by the commonly used plasmonic materials that limit their applicability in devices requiring high temperature stability, robustness in varying ambient, mechanical durability, stable growth into nanoscale films, CMOS process compatibility, stable bio-compatibility, and so on.

Aiming to create a whole-some solution, my research has focused on developing novel, high-performance, functional plasmonic metasurface devices that utilize the inherent benefits of various emerging and alternative material platforms. Among these, the two-dimensional MXenes and the refractory transition metal nitrides are of particular importance. By exploiting the plasmonic response of thin films of the titanium carbide MXene (Ti₃C₂T_x) in the near infrared spectral window, a highly broadband metamaterial absorber has been designed, fabricated and experimentally demonstrated. In another work, high efficiency photonic spin Hall Effect has been experimentally realized in robust phase gradient metasurface devices based on two different refractory transition metal nitrides –titanium nitride (TiN) and zirconium nitride (ZrN). Further, taking advantage of the refractory nature of these plasmonic nitrides, a metasurface based temperature sensor has been developed that is capable of remote, optical sensing of very high temperatures ranging up to 1200^oC.

The present thesis shows how versatile and important the field of gas-phase spectroscopy under supersonic expansion conditions can be to understand fundamental intermolecular and intramolecular interactions. We have employed spectroscopic techniques over a very broad range spanning from microwave (2-18 GHz), through infrared (2600-4000 cm-1) and ultraviolet (350-250 nm) region, studying therotational, vibrational and electronic properties,respectively. These techniques use either chirped-pulse based (broadband rotational spectroscopy) or laser based methods (vibrational and electronic spectroscopy), and their usage depends on the types of information of particular interest and the chemical system requirements of specific techniques. The analytes are brought into the gas phase and supersonically cooled to their zero-point vibrational level to perform rotational and vibrationallyresolved IR/UV spectroscopy, including conformer-specific techniques. The variety of small organic molecular systemsstudied include phenyl-containing hydrocarbons, water containing clusters, heteroatom containing organic molecules with and without phenyl ring, fused aromatic molecules, bichromophoric molecules and pyrolysis reaction intermediates. Apart from gaining invaluable fundamental knowledge of the various interactions, we also observe interesting quantum-physical phenomena like tunneling and large amplitude motions that provide further insight into the molecular world.