Academic literature on the topic 'Mineralogy – New England'

AbstractThe clay mineralogy of the Cretaceous strata of the British Isles is described and discussed within its lithostratigraphical and biostratigraphical framework using published and unpublished sources as well as 1400 new clay mineral analyses. The regional clay mineral variation is described systematically for the following strata:(1)Southern England — Purbeck Limestone Group (Berriasian/Ryazanian; Lulworth and Durlston formations), Wealden Group (Valanginian—Barremian/Aptian; Ashdown, Wadhurst Clay, Tunbridge Wells Sands, Grinstead Clay Member, Wealden Clay, Wessex and Vectis formations), Lower Greensand (Aptian—Lower Albian; Atherfield Clay, Hythe, Sandgate, Folkestone Sands, Ferruginous Sands, Woburn Sands and Faringdon Sponge Gravels formations), Selborne Group (Middle—Upper Albian; Gault Clay and Upper Greensand formations) and the Chalk Group (Cenomanian—Lower Maastrichtian).(2)Eastern England — Cromer Knoll Group (Ryazanian—Upper Albian; Speeton Clay, Spilsby Sandstone, Sandringham Sands, Claxby Ironstone, Tealby, Roach Ironstone, Dersingham, Carstone and Red Chalk (or Hunstanton Red Limestone) formations).(3)Scotland — Inner Hebrides Group (Cenomanian—Campanian; Morvern Greensand, Gribun Chalk, Coire Riabhach Phosphatic Hibernian Greensands formations).(4)Northern Ireland — Hibernian Greensands (Cenomanian—Santonian) and Ulster White Limestone formations (Santonian—Lower Maastrichtian).The stratigraphical patterns of clay mineral variation divide naturally into two types; firstly, the more complex pattern of the Lower Cretaceous strata and secondly, the simple pattern of the Upper Cretaceous. Clay mineral variations in the non-marine and marine Lower Cretaceous strata of England are best explained by the interplay of two main clay mineral assemblages between which all gradations occur. The assemblage which dominates the main clay formations consists of mica, kaolin and poorly defined mixed-layer smectite-mica-vermiculite minerals, and sometimes includes vermiculite and traces of chlorite. It is dominantly of detrital origin and detailed evidence indicates it is derived largely from the reworking of Mesozoic sediments although ultimately from weathered Palaeozoic sediments and metasediments. Although mainly of detrital origin, this assemblage contains a persistent component that formed coevally with the approximate depositional age of its host sediment. Whether this component is of soil origin or was neoformed in the sediment shortly after deposition is unclear. There is little firm evidence indicating the sources of this clay mineral detritus. However, in the strata of the Wealden Group of southern England, mineral trends suggest three sources; one of these was to the west (Cornubian Massif), another must have been the Anglo- Brabant landmass. In the Selborne Group (Middle—Upper Albian) and in the overlying Lower Chalk (Cenomanian) where this assemblage makes its last appearance in the Cretaceous of England, there is good evidence of easterly and south-easterly sources.The second main assemblage tends to be largely monominerallic, and usually dominated by smectite with or without small amounts of mica; less frequently, kaolin, berthierine or glauconite sensu lato is the sole or dominant component. It is considered to be of volcanogenic origin, derived from the argillization of volcanic ash under different conditions of deposition and diagenesis. The source of the ash in Berriasian—Aptian times seems to have been an extensive volcanic field in the southern part of the North Sea and in the Netherlands, whereas in the Albian (and extending into the Cenomanian) a westerly source dominated. The current controversy about the role of climate or pattern of volcanic activity controlling the clay mineral stratigraphy of the Lower Cretaceous is reviewed.In the lower part of the Upper Cretaceous strata of England, Scotland and Ireland, sand-grade glauconite is particularly abundant. Much of it represents the glauconitization of pene- contemporanous volcanic ash, possibly of basaltic origin, associated with continental breakup and the opening up of the Atlantic Ocean and the earliest stages in the development of the Hebridean Tertiary Igneous Province. The Upper Cretaceous Chalk facies of England and Ireland is dominated by a smectite-rich clay assemblage containing mica, and the various hypotheses for its origin (detrital, neoformation, volcanogenic) are reviewed in the light of available mineralogical, chemical and geological data.

Formal course instruction in mineralogy and geology began in Harvard College in 1788 with Benjamin Waterhouse. He also assembled in the 1780's a reference and teaching collection of minerals, rocks, and ores—the first natural history collection at Harvard—that, following a gift by an English friend, J. C. Lettsom, became a cynosure of the College. Following Waterhouse's dismissal in 1812, the instruction was carried on by John Gorham until 1824. Waterhouse, his colleague Aaron Dexter, and Gorham all were professors in the Harvard Medical School, established 1782. The latter two men successively held an endowed chair therein, the Erving Professorship of Chemistry and Materia Medica. They produced some notable graduates: Parker Cleaveland in 1799, Lyman Spalding in 1797, Joseph Green Cogswell in 1806, John White Webster in 1811, John Fothergill Waterhouse in 1813, and Samuel Luther Dana and James Freeman Dana in 1813. Following years of futile effort by the Administration to establish a professorship of mineralogy and geology, with Cogswell as the selected candidate, the instruction in mineralogy and geology fell to John White Webster in 1824 in the Chemistry Department. The Erving Professorship also passed to him, with a change in title to Professor of Chemistry and Mineralogy. Webster's death in 1850, following his conviction for murder in a famous trial, terminated the first period of development of the geological sciences at Harvard. In this period, in spite of the early start by Waterhouse, Harvard lagged much behind the developments at Yale and other colleges in New England and beyond. The main period of development of the geological sciences at Harvard come in the latter 1800's. It was a consequence primarily of the founding of the the Lawrence Scientific School in 1848, with its emphasis on the applied aspects of the sciences, the appointments of Josiah Dwight Whitney and Raphael Pumpelly in 1865 and 1866, respectively to a School of Mines and Practical Geology endowed as a sub-unit therein, and the appointment of Josiah Parsons Cooke in 1850 as successor to Webster in the Chemistry Department.

AbstractThe nature and origin of the clay mineralogy of the Jurassic strata of the British Isles are described and discussed within their lithological and biostratigraphical framework using published and unpublished sources as well as 1800 new clay mineral analyses. Regional clay mineral variation is described systematically for the following formations or groups:England and Wales(i)Hettangian-Toarcian strata (Lias Group): Redcar Mudstone Fm.; Staithes Sandstone Fm.; Cleveland Ironstone Fm.; Whitby Mudstone Fm.; Scunthorpe Mudstone Fm.; Blue Lias Fm.; Charmouth Mudstone Fm.; Marlstone Rock Fm.; Dyrham Fm.; Beacon Limestone Fm.; Bridport Sand Fm.(ii)Aalenian-Bajocian (Inferior Oolite Group): Dogger Fm.; Saltwick Fm.; Eller Beck Fm.; Cloughton Fm.; Scarborough Fm.; Scalby Fm. (in part); Northampton Sand Fm.; Grantham Fm.; Lincolnshire Limestone Fm.; Rutland Fm. (in part); Inferior Oolite of southern England.(iii)Bathonian (Great Oolite Group): Scalby Fm. (in part); Rutland Fm. (in part); Blisworth Limestone Fm.; Great Oolite Group of southern England; Forest Marble Fm.; Cornbrash Fm. (in part).(iv)Callovian-Oxfordian: Cornbrash Fm. (in part); Kellaways Fm.; Oxford Clay Fm.; Corallian Beds and West Walton Beds; Ampthill Clay Fm.(v)Kimmeridgian-Tithonian: Kimmeridge Clay Fm.; Portland Sandstone Fm.; Portland Limestone Fm.; Lulworth Fm.; Spilsby Sandstone Fm. (in part). Scotland(vi)Hettangian-Toarcian: Broadfoot Beds, Dunrobin Bay Fm. Aalenian-Portlandian: Great Estuarine Group (Dunkulm, Kilmaluag and Studiburgh Fm.s); Staffin Shale Fm.; Brora Coal Fm.; Brora Argillaceous Fm.; Balintore Fm.; Helmsdale Boulder Beds (Kimmeridge Clay Fm.).Dominating the Jurassic successions are the great marine mudstone formations — the Lias Group, Oxford Clay, Ampthill Clay and Kimmeridge Clay. These are typically characterized by a detrital clay mineral assemblage of mica, kaolin and poorly defined mixed-layer smectite-mica-vermiculite minerals with traces of chlorite. Detailed evidence suggests that this assemblage is derived ultimately from weathered Palaeozoic sediments and metasediments either directly or by being recycled from earlier Mesozoic sediments. A potassium-bearing clay is a persistent component and formed at approximately the same time as the deposition of the host sediment, either in coeval soils or during very early diagenesis.At three periods during the deposition of the Jurassic (Bajocian-Bathonian, Oxfordian and late Kimmeridgian-Tithonian), the detrital clay assemblage was completely or partially replaced by authigenic clay mineral assemblages rich in kaolin, berthierine, glauconite or smectite minerals. Associated with these changes are major changes in the lithofacies, with the incoming of non-marine and proximal marine strata. The authigenic clay assemblages rich in kaolin and berthierine are generally restricted to the non-marine and very proximal marine beds, those rich in glauconite or smectite are typical of the marine lithofacies. Clay mineral assemblages containing vermiculite and mixed-layer vermiculite-chlorite sometimes occur in the non-marine and proximal marine facies. The causes of these major changes in lithofacies and clay mineralogy are discussed, and present evidence favours an important volcanogenic influence and not climatic control. It is suggested that the Bajocian-Bathonian, Oxfordian and Late Kimmeridgian-Tithonian were periods of enhanced volcanic activity, with centres probably located in the North Sea and linked to regional tectonic changes which caused major modifications of the palaeogeography of the British Isles. The most important of these changes was the development of the central North Sea Rift Dome during the Bajocian and Bathonian. Volcanic ash was widespread in both the non-marine and marine environments and its argillization under different conditions provided the wide range of authigenic clay mineral assemblages.Metre-scale clay mineral cyclicity is widespread in most of the Jurassic mudstone formations that have been examined in sufficient detail. The cyclicity is defined by systematic variations in the mica/ collapsible minerals (mixed-layer smectite-mica-vermiculite) ratio. This variation is unrelated to changes in lithology and its possible origins are discussed in detail using data from the Kimmeridge Clay provided by Reading University's contribution to the Rapid Global Geological Events (RGGE) Project.

Lignites and coals, because of their low sedimentation rates of terrigenous detritus, may preserve a record of volcanic ash fall. Lignite from the Lower Cretaceous Chaswood Formation in central Nova Scotia was studied to identify whether any volcanic ash is present and can be correlated to known Early Cretaceous volcanism in southeastern Canada and adjacent New England. The bulk mineralogy and geochemistry of lignite and lignitic mudstones was determined by X-ray diffraction and whole-rock geochemical analysis of ashed samples; selected samples were examined by electron microprobe and scanning electron microscope. Much of the terrigenous component of some lignites consists of detrital sediments. In some lignites, distinctive rare earth element patterns are due to leaching from monazite and concentration in organic matter. Some lignites, however, lack illite and (or) quartz indicative of detrital sources, but show unusual abundance of stable high-field-strength elements such as Nb, Ta, and Hf, suggesting a volcanic source. Wood or charcoal fragments appear mineralized and diagenetic talc is present. Most of any ash component has been altered to kaolinite. Bulk composition of original ash ranges from basaltic to rhyolitic and matches chemically with subalkaline volcanic rocks on the SW Grand Banks and Orpheus graben. Coeval volcanic rocks on the U.S. continental margin and the New England–Quebec igneous province are more alkaline. Altered ash in lignite in the lower member of the Chaswood Formation correlates with Neocomian volcanism on the SW Grand Banks; and in the middle and upper members with Aptian–Albian volcanism in Orpheus graben.

ABSTRACTA strong correlation exists between the Li isotopic compositions of CarboniferousTriassic granites from the New England Batholith, and the previously inferred involvement of sedimentary and mantle/infracrustal source components. Isotopically (Nd and Sr) juvenile, low-K, Cordilleran I-type granites of the Clarence River supersuite have δ7 Li= +2·2 to +8‰ similar to those of arc magmas, the inferred source of these granites (Bryant et al. 1997). Isotopic variability within this supersuite probably arises from heterogeneity within primary mantle-derived magmas, combined with subsequent modifications through interactions with crustal materials. Oxidised, high-K granites of the Moonbi Supersuite have more homogenous and slightly lighter Li isotopic compositions (δ7 Li= +1·9 to +4·2‰). The observed range of values lies within the range of arc magmas, and is consistent with partial melting of arc shoshonites within the crust (cf. Chappell 1978) or the involvement of high-K mantle-derived magmas (cf. Shaw & Flood 1981; Landenberger & Collins 1998). S-type granites of the Bundarra (δ7 Li= −0·1 to +2·1‰; average= +1˙3‰; n=6) and Hillgrove supersuites (δ7 Li= +0·4 to +1·7‰; average= +0·8‰) define a narrow range of isotopic compositions which are, overall, lower than those observed in NEB I-type granites or generally observed in primary arc magmas. Their isotopic compositions are equivalent to those typically observed in shales (primarily δ7 Li= −3·2 to +2·0‰; Moriguti & Nakamura 1998; Teng et al. 2004). No difference is evident in the isotopic compositions of the two S-type supersuites despite inferred differences in the degree of weathering experienced by the sedimentary protolith, or differences in mineralogy of the granites. Granites of the Uralla Supersuite, which have been have formed from mixtures of local meta-igneous and meta-sedimentary components, span a broad range of values (δ7 Li= −1·3 to +3·9‰) which overlap with both the sediment-poor New England Batholith I-type intrusions of the Clarence River and Moonbi supersuites, and the S-type granites of the Bundarra and Hillgrove supersuites. Lower δ7 Li values primarily occur in lower-K plutons from the northern portion of the Uralla Supersuite.Overall, anatexis and magma differentiation do not appear to contribute to significant fractionation of Li isotopes relative to the inferred source components. However, subtly lower δ7 Li values, evident in the three leucogranites analysed herein, imply that subtle Li isotopic fractionation may occur in association with the exsolution of an aqueous fluid. Like most isotopic systems, the Li isotopic composition of rocks is not a definitive guide to source rock compositions, but given the results herein, the present authors suggest that it may play a very useful role in understanding crustal processes.

Abstract Die Arbeit verdeutlicht und erschließt das Verfahren wissenschaftlicher Entdeckungen im 18. Jahrhundert am Beispiel von Johann Reinhold Forster, Vater des Abgeordneten der Mainzer Republik. Georg. Johann Reinold (1729–1798) wurde in Dirschau (heute Tczew) an der Weichsel geboren. Der Vater war Bürgermeister dieser Stadt, die damals wie heute zu Polen gehörte, aber 1772 von Preußen annektiert wurde. Der Sohn studierte Theologie in Halle und wurde Pfarrer, nahm aber 1765 einen Auftrag Katharinas II. an, über die Wolgakolonien zu berichten. Da sein Bericht kritisch ausfiel, erhielt er in Petersburg kein Honorar, und da er seine Pfarrstelle durch die Abwesenheit verloren hatte, ging er 1766 nach England. Er lehrte an der Dissenters Academy in Warrington Naturgeschichte und wurde für sein Buch über die Natur der Wolgaregion zum Fellow der Royal Society gewählt. 1772 bestimmte man ihn als offiziellen Naturforscher für die 2. Weltreise Cooks mit Georg als Gehilfen. Nach der Rückkehr stritten sich Cook und Forster über die Rechte an der Edition, der Auftrag zur Publikation wurde ihm entzogen und die Admiralität verbot ihm den Druck. Johann Reinold brachte die Schriften auf eigene Kosten unter dem Namen seines Sohnes heraus, aber ,,Das auf Patronage basierende Wissenschaftssystem verzieh diesen Fauxpas nicht …“ (S. 36) und die Auflage wurde boykottiert. Deutsche Freimaurer (Friedrich II., Herzog Ferdinand von Braunschweig und andere) zahlten die Schulden, so dass Forster 1779 zum Professor für Naturgeschichte und Mineralogie in Halle berufen werden konnte.

The Mercia Mudstone Group (MMG) crops out extensively across England and Wales and its thermal properties are required for the design of infrastructure such as ground source heating and cooling schemes and electrical cable conduits. Data from the literature and new data from a borehole core have been compiled to generate an updated range of thermal conductivities related to rock type and the lithostratigraphy. These indicate a total range in saturated vertical thermal conductivity of 1.67–3.24 W m−1 K−1, comprising 1.67–2.81 W m−1 K−1 for mudstones, 2.12–2.41 W m−1 K−1 for siltstones and 2.3–3.24 W m−1 K−1 for sandstones. These data are all from measurements on samples and there will be uncertainty when considering the thermal properties of the rock mass owing to micro- and macrostructural features. Geometric mean modelling of thermal conductivity based on mineralogy has overestimated the thermal conductivity. Correction factors for the modelled thermal conductivities have been calculated to allow a first estimate of MMG thermal conductivities when only mineralogical data are available. Measured thermal diffusivities from the borehole core were in the range of 0.63–3.07 × 10−6 m2 s−1 and are the first measured thermal diffusivities to be reported for the MMG.