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Journal articles on the topic 'MICROHETEROGENOUS SYSTEMS'

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Published: 18 May 2024

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1

Lissi, Eduardo, and M. A. Rubio. "O2(3Σ) and O2(1Δ) processes in microheterogenous systems." Pure and Applied Chemistry 62, no. 8 (January 1, 1990): 1503–10. http://dx.doi.org/10.1351/pac199062081503.

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2

Zhavoronkov, D. A., E. N. Miftakhov, S. A. Mustafina, I. Sh Nasyrov, and V. P. Zakharov. "MODELING AND THEORETICAL RESEARCH POLYMERIZATION PROCESS ISOPRENE IN PRESENCE MICROHETEROGENOUS NEODYMIUM CATALYTIC SYSTEMS." Vestnik Bashkirskogo universiteta 7, no. 4 (2018): 1079. http://dx.doi.org/10.33184/bulletin-bsu-2018.4.23.

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3

Hawlicka, E., and R. Grabowski. "The Conductance of Naland Tetraethylammonium Iodide in Mixtures of Methanol with Acetonitrile and Water." Zeitschrift für Naturforschung A 46, no. 1-2 (February 1, 1991): 122–26. http://dx.doi.org/10.1515/zna-1991-1-220.

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AbstractThe conductance of Nal and Et4NI in methanol-acetonitrile and methanol-water mixtures was measured at 25 ± 0.005 °C for the whole range of the solvent compositions, the salt molarity ranging from 5 • 10-5 up to 1 • 10-2. Several equations describing the influence of the salt concentration on the equivalent conductance are examined and the Fuoss-Hsia equation with the Fernandez-Prini parameters is found to be the most appropriate one for systems with weak ionic association. Variations with the solvent composition of the limiting equivalent conductance, the distance between ions forming ion pairs and the association constant are discussed. Nonmonotonous changes of the association constant are concluded to be a feature of microheterogenous systems.

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4

Roslyakova, Liudmila I., Galina V. Karpova, and Vasilii V. Yushin. "Experimental Verification of Additive Elasticity Model of Magnetic Fluids." Proceedings of the Southwest State University. Series: Engineering and Technologies 11, no. 4 (2021): 149–63. http://dx.doi.org/10.21869/2223-1528-2021-11-4-149-163.

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The purpose of the work is an experimental verification of additive elasticity model of magnetic fluids. Methods. To achieve the purpose of the work, methods of molecular acoustics and methods of systems analysis were used. Magnetic fluids are an example of microheterogenous medium. The small size of the magnetic particles dispersed in the carrier fluid compared to the ultrasonic wavelength makes it possible to apply certain findings of continuum mechanics to magnetic fluids. Thus elastic properties of magnetic fluids are described by the additive model, which is based on the assumption of the additivity of the specific compressibility of the components included in the system, wherein the specific compressibility means the product of the compressibility of a given component and its volume concentration. The work investigated magnetic fluids on a different basis and different concentrations. Samples with lower concentration were obtained by diluting the original ones. Investigations of the dispersion medium of all magnetic fluids were also carried out. The speed of sound was determined by the pulse-phase method, with the mode of multiple reflection from the receiving and transmitting piezoplates. Results. Comparative analysis of experimentally obtained dependences of speed of light and adiabatic compressibility of MF on solid phase concentration with theoretical data obtained in the context of additive elasticity model was conducted. This analysis made it possible to estimate the adiabatic compressibility of surface-active agent of magnetic fluids - the oleic acid. It was concluded that adiabatic compressibility of surface-active agent – the oleic acid is slightly less than adiabatic compressibility of free oleic acid. Conclusion. The conducted studies made it possible to experimentally confirm additive model of the formation of magnetic fluid elasticity экспериментально and supplement conclusions of the microheterogenous media theory.

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5

Turro, Nicholas J. "Photochecmistry in microheterogeneous systems." Journal of Colloid and Interface Science 123, no. 2 (June 1988): 548. http://dx.doi.org/10.1016/0021-9797(88)90278-0.

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6

Berchiesi, G., F. Farhat, and G. Vitali. "Amide-Electrolyte Molten Mixtures: Microheterogeneous Systems." Materials Science Forum 126-128 (January 1993): 367–70. http://dx.doi.org/10.4028/www.scientific.net/msf.126-128.367.

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7

Tovbin, Yu K. "Microheterogeneous systems and the phase rule." Russian Journal of Physical Chemistry A 87, no. 6 (May 11, 2013): 906–14. http://dx.doi.org/10.1134/s0036024413060290.

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8

Gol’dshleger, N. V., V. E. Baulin, and A. Yu Tsivadze. "Phthalocyanines in organized microheterogeneous systems. Review." Protection of Metals and Physical Chemistry of Surfaces 50, no. 2 (March 2014): 135–72. http://dx.doi.org/10.1134/s2070205114020087.

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9

Lyons, Michael E. G., Cormac H. Lyons, Athanase Michas, and Philip N. Bartlett. "Amperometric chemical sensors using microheterogeneous systems." Analyst 117, no. 8 (1992): 1271. http://dx.doi.org/10.1039/an9921701271.

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10

Carraway, E. R., J. N. Demas, and B. A. DeGraff. "Luminescence quenching mechanism for microheterogeneous systems." Analytical Chemistry 63, no. 4 (February 15, 1991): 332–36. http://dx.doi.org/10.1021/ac00004a006.

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11

Colina, Ariel N., Marta S. Díaz, and María Isela Gutiérrez. "Fluorescence of berberine in microheterogeneous systems." Journal of Luminescence 144 (December 2013): 198–202. http://dx.doi.org/10.1016/j.jlumin.2013.07.023.

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12

Hébrant, Marc. "Metal ion extraction in microheterogeneous systems." Coordination Chemistry Reviews 253, no. 17-18 (September 2009): 2186–92. http://dx.doi.org/10.1016/j.ccr.2009.03.006.

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13

Duhamel, Jean, Ahmad Yekta, and Mitchell A. Winnik. "Excimer lifetime recovery: application to microheterogeneous systems." Journal of Physical Chemistry 97, no. 11 (March 1993): 2759–63. http://dx.doi.org/10.1021/j100113a044.

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14

Wang, T. C., and C. K. Tan. "Photodegradation of trichloroethylene in microheterogeneous aqueous systems." Environment International 13, no. 4-5 (January 1987): 359–62. http://dx.doi.org/10.1016/0160-4120(87)90192-9.

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15

Mejuto, Juan C., and Antonio Cid-Samamed. "Chemical Reactivity in Microheterogeneous Media." Compounds 2, no. 3 (August 2, 2022): 193–95. http://dx.doi.org/10.3390/compounds2030015.

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Since the second half of the last century, the science of colloids has undergone a true revolution, from being little more than a collection of qualitative observations of the macroscopic behavior of some complex systems to becoming a discipline with substantial theoretical foundations [...]

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16

BRITO, JULIO, ANDRÉS POZO, CRISTÓBAL GARCÍA, LUIS J. NÚÑEZ-VERGARA, JAVIER MORALES, GERMÁN GÜNTHER, and NANCY PIZARRO. "PHOTODEGRADATION OF NIMODIPINE AND FELODIPINE IN MICROHETEROGENEOUS SYSTEMS." Journal of the Chilean Chemical Society 57, no. 3 (2012): 1313–17. http://dx.doi.org/10.4067/s0717-97072012000300025.

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17

Rajendran,, Susai, R. Maria Joany,, and N. Palaniswamy,. "An Encounter with Microheterogeneous Systems As Corrosion Inhibitors." Corrosion Reviews 20, no. 3 (April 2002): 231–54. http://dx.doi.org/10.1515/corrrev.2002.20.3.231.

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18

Barzykin, A. V., K. Seki, and M. Tachiya. "Kinetics of diffusion-assisted reactions in microheterogeneous systems." Advances in Colloid and Interface Science 89-90 (January 2001): 47–140. http://dx.doi.org/10.1016/s0001-8686(00)00053-1.

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19

Agostiano, A., L. Catucci, G. Colafemmina, and M. Della Monica. "Chlorophyll a self-organization in microheterogeneous surfactant systems." Biophysical Chemistry 60, no. 1-2 (May 1996): 17–27. http://dx.doi.org/10.1016/0301-4622(96)00003-8.

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20

Carreto, María López, Soledad Rubio, and Dolores Pérez-Bendito. "Organic microheterogeneous systems in kinetic analysis. Self-assembled systems. A review." Analyst 121, no. 4 (1996): 33R—44R. http://dx.doi.org/10.1039/an996210033r.

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21

Goldshleger, N. F., A. V. Chernyak, A. S. Lobach, I. P. Kalashnikova, V. E. Baulin, and A. Yu Tsivadze. "Monomerization of crown-containing phthalocyanines in microheterogeneous organized systems." Protection of Metals and Physical Chemistry of Surfaces 51, no. 2 (March 2015): 212–20. http://dx.doi.org/10.1134/s2070205115020070.

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22

Lyons, Michael E. G. "Electrocatalysis using electroactive polymers, electroactive composites and microheterogeneous systems." Analyst 119, no. 5 (1994): 805. http://dx.doi.org/10.1039/an9941900805.

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23

Wang, Sheng, Isao Tabata, Kenji Hisada, and Teruo Hori. "Hydrogen evolution sensitized by tin-porphyrin in microheterogeneous systems." Dyes and Pigments 55, no. 1 (October 2002): 27–33. http://dx.doi.org/10.1016/s0143-7208(02)00069-4.

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24

Salhi, S., C. Bied-Charreton, R. Pansu, and J. Faure. "Studies of energy transfer of porphyrins in microheterogeneous systems." Journal of Photochemistry and Photobiology B: Biology 23, no. 2-3 (May 1994): 253–60. http://dx.doi.org/10.1016/1011-1344(94)07003-2.

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25

Mattay, Jochen. "Book Review: Photochemistry in Microheterogeneous Systems. By K. Kalyanasundaram." Angewandte Chemie International Edition in English 27, no. 5 (May 1988): 722. http://dx.doi.org/10.1002/anie.198807221.

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26

RÖDER, BEATE, TH HANKE, ST OELCKERS, ST HACKBARTH, and CH SYMIETZ. "Photophysical properties of pheophorbide a in solution and in model membrane systems." Journal of Porphyrins and Phthalocyanines 04, no. 01 (January 2000): 37–44. http://dx.doi.org/10.1002/(sici)1099-1409(200001/02)4:1<37::aid-jpp183>3.0.co;2-o.

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Pheophorbide a (Pheo) is a well-known hydrophobic photosensitizer used for photodynamic treatment of various diseases. The influence of the surroundings on the electronic properties of photosensitizers mainly accumulating in membrane structures is of relevance for their photoactivity. In this paper the current knowledge about the electronic properties of Pheo in different microheterogeneous environments is summarized and new findings about its incorparation in different model membranes are discussed.

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27

Wang, Sheng, and Teruo Hori. "Oxygen evolution sensitized by tin porphyrin in microheterogeneous system and membrane systems." Journal of Porphyrins and Phthalocyanines 07, no. 01 (January 2003): 37–41. http://dx.doi.org/10.1142/s1088424603000069.

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Tin porphyrin ( SnTPP ) was applied to two new types of photoinduced oxygen evolution systems by visible light irradiation. In microheterogeneous system, tin porphyrin was dispersed by a nonionic surfactant and the system could efficiently oxidize water to evolve oxygen when compared with the conventional system. In addition, two types of tin porphyrin fixed PVC membranes, porous and homogeneous, were prepared and applied to a photoinduced oxygen evolution membrane system. SEM images of two types of tin porphyrin fixed PVC membranes also show differences in both morphologies.

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28

Gerola, Adriana P., Tayana M. Tsubone, Amanda Santana, Hueder P. M. de Oliveira, Noboru Hioka, and Wilker Caetano. "Properties of Chlorophyll and Derivatives in Homogeneous and Microheterogeneous Systems." Journal of Physical Chemistry B 115, no. 22 (June 9, 2011): 7364–73. http://dx.doi.org/10.1021/jp201278b.

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29

Encinas, M. V., E. A. Lissi, and J. Alvarez. "FLUORESCENCE QUENCHING OF PYRENE DERIVATIVES BY NITROXIDES IN MICROHETEROGENEOUS SYSTEMS." Photochemistry and Photobiology 59, no. 1 (January 1994): 30–34. http://dx.doi.org/10.1111/j.1751-1097.1994.tb04997.x.

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30

Tovbin, Yu K. "Fluctuation theory of microheterogeneous systems in the molecular-field approximation." Protection of Metals and Physical Chemistry of Surfaces 47, no. 2 (March 2011): 141–49. http://dx.doi.org/10.1134/s2070205111020201.

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31

Romani, Ana Paula, and Amando Siuiti Ito. "Interaction of adrenocorticotropin peptides with microheterogeneous systems — A fluorescence study." Biophysical Chemistry 139, no. 2-3 (February 2009): 92–98. http://dx.doi.org/10.1016/j.bpc.2008.10.009.

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32

Levashov, A. V. "Microheterogeneous surfactant-based systems as the media for enzymatic reactions." Pure and Applied Chemistry 64, no. 8 (January 1, 1992): 1125–28. http://dx.doi.org/10.1351/pac199264081125.

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33

Barzykin, A. V., K. Seki, and M. Tachiya. "ChemInform Abstract: Kinetics of Diffusion-Assisted Reactions in Microheterogeneous Systems." ChemInform 32, no. 20 (May 15, 2001): no. http://dx.doi.org/10.1002/chin.200120308.

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34

Galdina, A. N. "Supercritical behavior of thermodynamic systems." Journal of Physics and Electronics 27, no. 1 (October 17, 2019): 19–26. http://dx.doi.org/10.15421/331903.

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It is known that basic stability characteristics of a system are inversely proportional to fluctuations of external parameters. Above the critical point there is a region remaining homogeneous macroscopically, but becoming microheterogeneous within an interval of thermodynamic forces. Within this interval thermodynamic coefficients of stability pass finite non-zero minima. This corresponds to the considerable growth of fluctuations and indicates the occurrence of supercritical transition of continuous kind. The limit case of such continuous phase transitions is the critical state, which is also the limit point of some first-kind transitions (the limit point of phase equilibrium curve).In this paper we consider the relation between thermodynamic stability conditions and fluctuations of external parameters of the system. We study the behavior of a simple one-component thermodynamic system (liquid, magnet, and ferroelectric) in the supercritical region and derive the equation of the line of supercritical transition for this system.

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35

Soffietti, Jésica B., Claudia G. Adam, and Claudia D. Della Rosa. "Effect on Cycloaddition Reactions of Aqueous Micellar Systems Formed by Amphiphilic Imidazolium Ionic Liquids." Chemistry Proceedings 3, no. 1 (November 14, 2020): 142. http://dx.doi.org/10.3390/ecsoc-24-08338.

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The micellar effect on Diels–Alder (DA) reaction was analyzed taking advantage of the property presented by ionic liquids (ILs) based on 1-alkyl-3-methylimidazolium cations by having amphiphilic character when the alkyl group is a long hydrocarbon chain-12 carbon atoms [C12mim]. These ILs can act as surfactants forming micelles in aqueous solution. The reactive system studied consists of nitrofuran and isoprene which allows obtaining benzofuran through green synthetic strategies. These “new microheterogeneous systems” would allow a better solubilization of non-polar substrates and to adopt reaction conditions softer than the traditional thermal.

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36

Sechkarev, A. V. "Vibrational spectra and constitution of disordered systems with microheterogeneous associative structure." Journal of Optical Technology 74, no. 2 (February 1, 2007): 77. http://dx.doi.org/10.1364/jot.74.000077.

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37

Vorobiev, P. D., S. V. Bucha, Yu V. Lipai, D. V. Cherednichenko, and N. P. Krutko. "Influence of polyelectrolytes and surfactants on the stability of microheterogeneous systems." Proceedings of the National Academy of Sciences of Belarus, Chemical Series 56, no. 3 (August 29, 2020): 271–77. http://dx.doi.org/10.29235/1561-8331-2020-56-3-271-277.

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38

Zakharova, Lucia Ya, Alsu R. Ibragimova, Farida G. Valeeva, Andrey V. Zakharov, Asiya R. Mustafina, Lyudmila A. Kudryavtseva, Harlampy E. Harlampidi, and Alexander I. Konovalov. "Nanosized Reactors Based on Polyethyleneimines: From Microheterogeneous Systems to Immobilized Catalysts." Langmuir 23, no. 6 (March 2007): 3214–24. http://dx.doi.org/10.1021/la0629633.

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39

Ozturk, Turan, Andrey S. Klymchenko, Asli Capan, Sule Oncul, Simay Cikrikci, Sule Taskiran, Bahar Tasan, F. Betul Kaynak, Suheyla Ozbey, and Alexander P. Demchenko. "New 3-hydroxyflavone derivatives for probing hydrophobic sites in microheterogeneous systems." Tetrahedron 63, no. 41 (October 2007): 10290–99. http://dx.doi.org/10.1016/j.tet.2007.07.074.

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40

Gutiérrez, María Isela, Claudia G. Martínez, David García-Fresnadillo, Ana M. Castro, Guillermo Orellana, André M. Braun, and Esther Oliveros. "Singlet Oxygen (1Δg) Production by Ruthenium(II) Complexes in Microheterogeneous Systems†." Journal of Physical Chemistry A 107, no. 18 (May 2003): 3397–403. http://dx.doi.org/10.1021/jp021923e.

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41

Remizov, S. "Structural and rheological properties of microheterogeneous systems 'solid hydrocarbons–liquid hydrocarbons'." Colloids and Surfaces A: Physicochemical and Engineering Aspects 175, no. 3 (December 30, 2000): 271–75. http://dx.doi.org/10.1016/s0927-7757(99)00522-1.

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42

Gradova, M. A., K. A. Zhdanova, N. A. Bragina, A. V. Lobanov, and M. Ya Mel´nikov. "Aggregation state of amphiphilic cationic tetraphenylporphyrin derivatives in aqueous microheterogeneous systems." Russian Chemical Bulletin 64, no. 4 (April 2015): 806–11. http://dx.doi.org/10.1007/s11172-015-0937-z.

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43

Valduga, Giuliana, Elena Reddi, and Giulio Jori. "Spectroscopic studies on Zn(II)-phthalocyanine in homogeneous and microheterogeneous systems." Journal of Inorganic Biochemistry 29, no. 1 (January 1987): 59–65. http://dx.doi.org/10.1016/0162-0134(87)80012-0.

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44

Sukhorukov, Gleb B. "Controlled Synthesis of Nanoparticles in Microheterogeneous Systems. Von Vincenzo Turco Liveri." Angewandte Chemie 118, no. 42 (October 27, 2006): 7105. http://dx.doi.org/10.1002/ange.200685415.

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45

Sukhorukov, Gleb B. "Controlled Synthesis of Nanoparticles in Microheterogeneous Systems. By Vincenzo Turco Liveri." Angewandte Chemie International Edition 45, no. 42 (October 27, 2006): 6949–50. http://dx.doi.org/10.1002/anie.200685415.

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46

Kablov, Victor F., Oksana M. Novopoltseva, Daria A. Kryukova, Natalia A. Keibal, Vladimir Burmistrov, and Vladimir G. Kochetkov. "Functionally Active Microheterogeneous Systems for Elastomer Fire- and Heat-Protective Materials." Molecules 28, no. 13 (July 7, 2023): 5267. http://dx.doi.org/10.3390/molecules28135267.

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Elastomeric materials are utilized for the short-term protection of products and structures operating under extreme conditions in the aerospace, marine, and oil and gas industries. This research aims to study the influence of functionally active structures on the physical, mechanical, thermophysical, and fire- and heat-protective characteristics of elastomer compositions. The physical and mechanical properties of elastomer samples were determined using Shimazu AG-Xplus, while morphological research into microheterogeneous systems and coke structures was carried out on a scanning electronic microscope, Versa 3D. Differential thermal and thermogravimetric analyses of the samples were conducted on derivatograph Q-1500D. The presence of aluminosilicate microspheres, carbon microfibers, and a phosphor–nitrogen–organic modifier as part of the aforementioned structures contributes to the appearance of a synergetic effect, which results in an increase in the heat-protective properties of a material due to the enhancement in coke strength and intensification of material carbonization processes. The results indicate an 8–17% increase in the heating time of the unheated surface of a sample and a decrease in its linear burning speed by 6–17% compared to known analogues. In conclusion, microspheres compensate for the negative impact of microfibers on the density and thermal conductivity of a composition.

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47

Witula, Tomasz, and Krister Holmberg. "Liquid Crystalline Phases and Other Microheterogeneous Systems as Media for Organic Synthesis." Journal of Dispersion Science and Technology 28, no. 1 (February 2007): 73–79. http://dx.doi.org/10.1080/01932690600992142.

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48

Lin, J. "Microheterogeneous systems of micelles and microemulsions as reaction media in chemiluminescent analysis." TrAC Trends in Analytical Chemistry 22, no. 2 (February 2003): 99–107. http://dx.doi.org/10.1016/s0165-9936(03)00203-6.

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49

Mirgorodskaya, A. B., L. A. Kudryavtseva, N. N. Vylegzhanina, Yu F. Zuev, and B. Z. Idiyatullin. "Catalytic properties of microheterogeneous systems based on cationic surfactants in transesterification processes." Kinetics and Catalysis 47, no. 1 (January 2006): 5–11. http://dx.doi.org/10.1134/s0023158406010022.

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50

LEVASHOV, A. V. "ChemInform Abstract: Microheterogeneous Surfactant-Based Systems as the Media for Enzymatic Reactions." ChemInform 23, no. 43 (August 21, 2010): no. http://dx.doi.org/10.1002/chin.199243295.

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