Academic literature on the topic 'Microbiology, n.e.c'

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Journal articles on the topic "Microbiology, n.e.c"

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Renaud, François N. R., Marianne Dutaur, Salah Daoud, Dominique Aubel, Philippe Riegel, Daniel Monget, and Jean Freney. "Differentiation of Corynebacterium amycolatum, C. minutissimum, and C. striatum by Carbon Substrate Assimilation Tests." Journal of Clinical Microbiology 36, no. 12 (1998): 3698–702. http://dx.doi.org/10.1128/jcm.36.12.3698-3702.1998.

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We tested the carbon substrate assimilation patterns of 40Corynebacterium amycolatum strains, 19 C. minutissimum strains, 50 C. striatum strains, and 1C. xerosis strain with the Biotype 100 system (bioMérieux, Marcy-l’Étoile, France). Twelve carbon substrates of 99 allowed discrimination among the species tested. Additionally, assimilation of 3 of these 12 carbon substrates (maltose, N -acetyl-d-glucosamine, and phenylacetate) was tested with the API 20 NE identification system (bioMérieux). Since concordant results were observed with the two systems for these three carbon substrates, either identification system can be used as a supplementary tool to achieve phenotypic differential identification ofC. amycolatum, C. minutissimum, and C. striatum in the clinical microbiology laboratory.
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Bastos, Margarida, Regina Adão, Kamran Nazmi, and JanG M. Bolscher. "C- and N-truncated antimicrobial peptides from LFampin 265 - 284: Biophysical versus microbiology results." Journal of Pharmacy and Bioallied Sciences 3, no. 1 (2011): 60. http://dx.doi.org/10.4103/0975-7406.76467.

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Drury, C. F., R. P. Voroney, and E. G. Beauchamp. "Availability of NH4+-N to microorganisms and the soil internal N cycle." Soil Biology and Biochemistry 23, no. 2 (January 1991): 165–69. http://dx.doi.org/10.1016/0038-0717(91)90130-c.

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Taylor-Robinson, D., J. S. Jensen, G. Fehler, F. Radebe, and R. C. Ballard. "Observations on the microbiology of urethritis in black South African men." International Journal of STD & AIDS 13, no. 5 (May 1, 2002): 323–25. http://dx.doi.org/10.1258/0956462021925144.

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The occurrence of Neisseria gonorrhoeae, Chlamydia trachomatis and Mycoplasma genitalium was determined by molecular techniques in urine specimens from 182 black South African men who had symptoms and/or overt signs of urethritis. Eighty-six (47.3%) of these men were infected with N. gonorrhoeae. There were 185 men without overt evidence of urethritis, 16 (8.6%) of whom were also infected with N. gonorrhoeae. Of the 96 men who had non-gonococcal urethritis, 14 (14.6%) were infected with C. trachomatis, 16 (16.7%) with M. genitalium and only one with both microorganisms. In comparison, 15 (8.9%) of 169 men without overt urethritis and without N. gonorrhoeae were infected with C. trachomatis and 15 (8.9%) with M. genitalium, proportions that were about half the size of those in the group with overt urethritis.
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BRUUN, S., B. STENBERG, T. BRELAND, J. GUDMUNDSSON, T. HENRIKSEN, L. JENSEN, A. KORSATH, J. LUXHOI, F. PALMASON, and A. PEDERSEN. "Empirical predictions of plant material C and N mineralization patterns from near infrared spectroscopy, stepwise chemical digestion and C/N ratios." Soil Biology and Biochemistry 37, no. 12 (December 2005): 2283–96. http://dx.doi.org/10.1016/j.soilbio.2005.04.006.

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Hopkins, D. W., L. Anderson, and S. E. Scott. "N and C mineralization in soil amended with the N immobilization inhibitor, methionine sulphoximine." Soil Biology and Biochemistry 27, no. 3 (March 1995): 377–79. http://dx.doi.org/10.1016/0038-0717(94)00180-9.

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Raubuch, Markus, and Rainer Georg Joergensen. "C and net N mineralisation in a coniferous forest soil: the contribution of the temporal variability of microbial biomass C and N." Soil Biology and Biochemistry 34, no. 6 (June 2002): 841–49. http://dx.doi.org/10.1016/s0038-0717(02)00016-0.

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Wojcik, Robin, Johanna Donhauser, Beat Frey, Stine Holm, Alexandra Holland, Alexandre M. Anesio, David A. Pearce, Lucie Malard, Dirk Wagner, and Liane G. Benning. "Linkages between geochemistry and microbiology in a proglacial terrain in the High Arctic." Annals of Glaciology 59, no. 77 (December 2018): 95–110. http://dx.doi.org/10.1017/aog.2019.1.

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ABSTRACTProglacial environments are ideal for studying the development of soils through the changes of rocks exposed by glacier retreat to weathering and microbial processes. Carbon (C) and nitrogen (N) contents as well as soil pH and soil elemental compositions are thought to be dominant factors structuring the bacterial, archaeal and fungal communities in the early stages of soil ecosystem formation. However, the functional linkages between C and N contents, soil composition and microbial community structures remain poorly understood. Here, we describe a multivariate analysis of geochemical properties and associated microbial community structures between a moraine and a glaciofluvial outwash in the proglacial area of a High Arctic glacier (Longyearbreen, Svalbard). Our results reveal distinct differences in developmental stages and heterogeneity between the moraine and the glaciofluvial outwash. We observed significant relationships between C and N contents,δ13Corgandδ15N isotopic ratios, weathering and microbial abundance and community structures. We suggest that the observed differences in microbial and geochemical parameters between the moraine and the glaciofluvial outwash are primarily a result of geomorphological variations of the proglacial terrain.
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Peltroche-Llacsahuanga, Heidrun, Norbert Schnitzler, Rudolf Lütticken, and Gerhard Haase. "Rapid Identification of Candida glabrataby Using a Dipstick To Detect Trehalase-Generated Glucose." Journal of Clinical Microbiology 37, no. 1 (1999): 202–5. http://dx.doi.org/10.1128/jcm.37.1.202-205.1999.

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Candida glabrata is a yeast frequently isolated from human specimens. Based upon its well-known ability to rapidly hydrolyze trehalose, we have developed a novel and cost-effective test incubating one yeast colony emulsified in 50 μl of citrate buffer (0.1 M [pH 5.0]) containing 4% (wt/vol) trehalose for 3 h at 37°C. Trehalase-generated glucose is detected with a commercially available dipstick (range, 1.0 to 50 g/liter). For evaluation, consecutive clinical isolates and several reference strains of C. glabrata (n = 160), C. albicans(n = 120), and other yeast species with potential ability for utilization of trehalose (C. dubliniensis,n = 11; C. famata, n = 15; C. guilliermondii, n = 5; C. lusitaniae, n = 16; C. parapsilosis,n = 20; C. tropicalis, n= 34; C. viswanathii, n = 5; Pichia angusta, n = 2; C. zeylanoides,n = 2; Saccharomyces cerevisiae,n = 16; C. neoformans, n= 7) were tested. Identification of C. glabrata is achieved within 3 h, with a specificity of 99.1% and a sensitivity of 98.8% when grown on Sabouraud dextrose agar supplemented with 4% glucose.
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Dhalluin, Anne, Ingrid Bourgeois, Martine Pestel-Caron, Emilie Camiade, Gregory Raux, Pascal Courtin, Marie-Pierre Chapot-Chartier, and Jean-Louis Pons. "Acd, a peptidoglycan hydrolase of Clostridium difficile with N-acetylglucosaminidase activity." Microbiology 151, no. 7 (July 1, 2005): 2343–51. http://dx.doi.org/10.1099/mic.0.27878-0.

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A gene encoding a putative peptidoglycan hydrolase was identified by sequence similarity searching in the Clostridium difficile 630 genome sequence, and the corresponding protein, named Acd (autolysin of C. difficile) was expressed in Escherichia coli. The deduced amino acid sequence of Acd shows a modular structure with two main domains: an N-terminal domain exhibiting repeated sequences and a C-terminal catalytic domain. The C-terminal domain exhibits sequence similarity with the glucosaminidase domains of Staphylococcus aureus Atl and Bacillus subtilis LytD autolysins. Purified recombinant Acd produced in E. coli was confirmed to be a cell-wall hydrolase with lytic activity on the peptidoglycan of several Gram-positive bacteria, including C. difficile. The hydrolytic specificity of Acd was studied by RP-HPLC analysis and MALDI-TOF MS using B. subtilis cell-wall extracts. Muropeptides generated by Acd hydrolysis demonstrated that Acd hydrolyses peptidoglycan bonds between N-acetylglucosamine and N-acetylmuramic acid, confirming that Acd is an N-acetylglucosaminidase. The transcription of the acd gene increased during vegetative cellular growth of C. difficile 630. The sequence of the acd gene appears highly conserved in C. difficile strains. Regarding deduced amino acid sequences, the C-terminal domain with enzymic function appears to be the most conserved of the two main domains. Acd is the first known autolysin involved in peptidoglycan hydrolysis of C. difficile.
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Dissertations / Theses on the topic "Microbiology, n.e.c"

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Amin, Shahreen. "Regulation of the tyrosine phosphatase SHP-1 expression by C-jun-N-terminal kinase and RFX-1 and AP-4 transcription factors in insulin-like growth factor-1 (IGF-1) stimulated breast adenocarcinoma MCF-7 cells." Thesis, University of Ottawa (Canada), 2005. http://hdl.handle.net/10393/26837.

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This thesis is devoted to reveal the negative regulators in IGF-1 (Insulin like growth factor 1) stimulated growth of a human breast adenocarcinoma cell line. It is a well established fact that increased circulating levels of IGF-1 correlate with increased risk of breast cancer. IGF-1 activation of its receptor, IGF-1R, is implicated in the progression of breast cancer, where IGF-1 stimulation leads to proliferative and anti-apoptotic responses by stimulating MAPK Erk and PI3K, respectively. In this study, IGF-1 stimulated MCF-7 cells proliferated more in the absence of MAPK JNK, implicating the involvement of MAPK JNK in the negative regulation of IGF-1 stimulated cell growth. In this research study, we show for the first time that IGF-1 stimulation of breast cancer cells induces SHP-1-expression by activating JNK, which in turn, activates RFX-1 and AP-4 transcription factors to allow them to bind to the high-expression region of the SHP-1 P-1 promoter in breast adenocarcinoma MCF-7 cells. (Abstract shortened by UMI.)
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Fontaine, Sébastien. "Rôle des composés énergétiques sur la minéralisation des matières organiques du sol : Conceptualisation, modélisation expérimentales et conséquences." Paris, Institut national d'agronomie de Paris Grignon, 2002. http://www.theses.fr/2002INAP0052.

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Alsaleh, Khaled. "Rôle des acides aminés basiques de la partie N-terminale de la protéine de capside dans l’assemblage du virus de l’hépatite C." Thesis, Lille 1, 2010. http://www.theses.fr/2010LIL10131/document.

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La fonction majeure de la protéine de capside (C) du virus de l’hépatite C (HCV) est d’interagir avec l’ARN génomique pour former la nucléocapside, un élément essentiel de la particule virale. Les études menées pour identifier les résidus basiques de la protéine C du HCV ont été principalement réalisées à l’aide d’un système acellulaire mais celui-ci ne permettait pas d’évaluer leur effet sur l’infectiosité du HCV. Le développement du système infectieux en culture cellulaire du HCV (HCVcc) permet de préciser le rôle de ces résidus pendant le cycle viral. Dans notre travail, le rôle de ces résidus basiques a été étudié par mutagenèse dirigée en utilisant le système HCVcc. Nous avons modifié les résidus basiques contenus dans deux régions (région 1, aa 6 à 23 et région 2, aa 39 à 62), situés au sein des 62 aa N-terminaux de la protéine C du HCV. Nos résultats ont montré que les résidus de la première région ont un effet mineur sur la réplication virale et qu’ils ne sont pas nécessaires à l’infectiosité du HCV. Par contre, quatre résidus basiques de la deuxième région se sont révélés être essentiels pour la production de particules virales infectieuses. La modification de ces résidus n’a pas d’effet sur la localisation subcellulaire de la protéine C, l’interaction protéine capside-ARN, l’oligomerisation de la protéine de capside et son enveloppement par les membranes intracellulaires. Dans l’ensemble, nos données suggèrent que les résidus basiques R50, K51, R59 et R62 jouent un rôle majeur dans la formation des particules virales infectieuses à une étape précoce, ultérieure à l’assemblage de la nucléocapside virale
A major function of the hepatitis C virus (HCV) core protein is the interaction with genomic RNA to form the nucleocapsid, an essential component of the virus particle. Analyses to identify basic amino acid residues of HCV core protein, important for capsid assembly, were initially performed with a cell-free system, which did not indicate the importance of these residues for HCV infectivity. The development of a cell culture system for HCV (HCVcc) allows a more precise analysis of these core protein amino acids during the HCV life cycle. In the present study, we used a mutational analysis in the context of the HCVcc system to determine the role of the basic amino acid residues of the core protein in HCV infectivity. We focused our analysis on basic residues located in two clusters (cluster 1, amino acids [aa]6 to 23; cluster 2, aa 39 to 62) within the N-terminal 62 amino acids of the HCV core protein. Our data indicate that basic residues of the first cluster have little impact on replication and are dispensable for infectivity. Furthermore, only four basic amino acids residues of the second cluster (R50, K51, R59, and R62) were essential for the production of infectious viral particles. Mutation of these residues did not interfere with core protein subcellular localization, core protein-RNA interaction, or core protein oligomerization. Moreover, these mutations had no effect on core protein envelopment by intracellular membranes. Together, these data indicate that R50, K51, R59, and R62 residues play a major role in the formation of infectious viral particles at a post-nucleocapsid assembly step
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Ahern, J. M. "Radical hydroacylation of C-C and N-N double bonds in air." Thesis, University College London (University of London), 2011. http://discovery.ucl.ac.uk/1309819/.

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The formation of C-C and C-N bonds in modern organic synthesis is a key target for methodological advancement. Current methods of C-C and C-N bond formation often involve the use of expensive catalysts, or sub-stoichiometric reagents, which can lead to the generation of undesirable waste products. This thesis describes a novel and environmentally benign set of reaction conditions for the formation of C-C and C-N bonds by hydroacylation and this is promoted by mixing two reagents, an aldehyde and an electron-deficient double bond, under freely available atmospheric oxygen at room temperature Chapter 1 will provide an introduction to the thesis and mainly discusses methods for C-C bond formation, in particular, radical chemistry and hydroacylation. Chapter 2 describes the hydroacylation of vinyl sulfonates and vinyl sulfones (C-C double bonds) with aliphatic and aromatic aldehydes with a discussion and evidence for the mechanism of the transformation. Chapter 3 details the synthesis of precursors for intramolecular cyclisations and studies into aerobic intramolecular cyclisations. Chapter 4 describes the hydroacylation of vinyl phosphonates (C-C double bonds) and diazocarboxylates (N-N double bonds) with aliphatic and aromatic aldehydes bearing functional groups. In addition, the hydroacylation of diazocarboxylates with chiral aldehydes will be discussed. In conclusion, a new, facile and clean set of reaction conditions for the formation of C-C and C-N bonds has been developed via aerobic C-H activation of aldehydes providing access to unsymmetrical ketones.
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Qian, Xin. "Cobalt-Catalyzed C-C and C-N Coupling reactions." Phd thesis, Ecole Polytechnique X, 2013. http://pastel.archives-ouvertes.fr/pastel-00943479.

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Ce travail de these a permis le déveloippement de nouvelles reactions de couplage catalysées par des sels de cobalt(II) Le premier chapitre décrit l'allylation cobalta catalysée d'halogénures d'alkyles. La méthode est facile à mettre en œuvre, efficace avec une grande variété d'halogénures d'alkyes et des acétates ou carbonates d'allyle substitués. Les rendements vont de bons à excellents et la tolérance fonctionnelle élevée. Dans le cas d'acétates d'allyle substitués le produit linéaire est obtenu majoritairement ou exclusivement. Quelques expériences ont permis de mettre en lumière la formation d'espèce radicalaire lors du cycle catalytique. Les premiers essais pour étendre cette méthodologie aux couplages allyle-allyle et alkyle-alkyle sont également décrits. Le deuxième chapitre porte sur l'amination catalysée au cobalt d'organozinciques fonctionnalisés en utilisant des N-chloroamines. La procédure est simple et générale et demande des conditions plus douces que celles précédemment décrite, tout en tolérant un très large éventail de substrats, avec une bonne tolérance à de nombreux groupes fonctionnels. Les premiers essais pour étendre la méthodologie à la réaction entre un organozincique et une source électrophile de soufre en vue de former des liaisons C-S sont également exposés. Enfin le dernier chapitre décrit la réaction d'organozinciques engendrés par catalyse au cobalt avec une source " verte " de cyanure électrophile, N-cyano-N-phenyl-p-methyl-benzenesulfonamide (NCTS), pour conduire avec de bons rendements aux arylnitriles correspondants. Des sources analogues de CN+ ont également été testées.
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Simayi, Rena. "Synthesis and reaction chemistry of various N,N,C- and O,N,C- palladium pincer complexes." Thesis, University of Leicester, 2017. http://hdl.handle.net/2381/39392.

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In this thesis, the synthesis, characterisation and complexation chemistry of a series of related NNC and ONC pyridine based pincer ligands, together with some reaction chemistry of the metal complexes is described. The pro-ligands and the metal complexes have been characterised by a combination of multinuclear NMR spectroscopic techniques, IR spectroscopy, mass spectrometry and, for selected examples, by single crystal X-ray crystallography; remarkable spectroscopic and structural data are discussed. In Chapter 2, the synthesis and characterization of thirteen NNC and ONC pyridine based pincer ligands is described, including nine novel pincer ligands and four pyridine based pincers which have been previously reported. In Chapter 3, the palladium/platinum chemistry of NNCaryl and ONCaryl pyridine based pincer ligands is explored. Variation on the donor atoms has allowed an investigation of donor property influences on C-H activation, by giving peri-activated palladium pincer complexes for the ketimine-, aldimine-, amine- and biyridine-armed ligands and generating ortho-activated ONC palladium pincer complexes in the case of the alcohol-armed pro-ligand. Use of different palladium salts also led to different regioselective C-H activations. With the ketimine-armed naphthyl ligand (HL1ket-nap) as the example, the interconversion chemistry between the ortho- and peri-C-H activated products is also explored. In Chapter 4, sp3 C-H activation of the Et-armed ligand HL4Et with both palladium acetate and palladium chlorides has been unsuccessful, giving the N,N-coordinated bidentate species. The reaction of palladium acetate with the iPr-armed pro-ligand HL4iPr has resulted in minor amounts of C-H activated vinyl species with the major product being the non-activated palladium diacetate complex. Noticeably, upon reaction with Na2PdCl4, a mixture of the non-activated bis-chloride palladium complex and the sp3 C-H activated NNC-tridentate palladium species has been obtained, in a ratio of 1:1.5. Moreover, the sp3 C-H activation and the isolation of a rare sp3 C-H activated palladium complex have been achieved by reacting the tBu-armed pro-ligand HL4tBu with palladium acetate. The reaction of this ligand with Na2PdCl4 also resulted in the successful C-H activation of the tBu-arm to give a palladium pincer complex with a yield of 95%. Other than the NMR and FABMS analyses, the solid state X-ray structure of the latter complex confirmed the formation of the material as a rare sp3 C-H activated palladium complex. The stoichiometric reactivity of the (NNC/ONC)PdCl species towards AgBF4/AgPF6, and the subsequent ligand exchange reactions are disclosed in Chapter 5, together with the application of twelve palladium complexes as a series of promising catalysts in the allylic arylation of various allylic acetates with sodium tetraphenylborate.
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Huang, Xiaohua 1973. "Palladium-catalyzed C-C, C-N and C-O bond formation." Thesis, Massachusetts Institute of Technology, 2003. http://hdl.handle.net/1721.1/29639.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2003.
Vita.
Includes bibliographical references.
New methods for Pd-catalyzed cross-coupling reactions of aryl halides or arenesulfonates are described. Key to the success of these transformations is the proper choice of ligand and reaction conditions. Palladium catalysts supported by bulky, monodentate phosphine ligands with a biaryl backbone or the bidentate ligand, Xantphos, effectively promote the formation of ca-aryl carbonyl compounds. Base-sensitive functional groups are better tolerated when a weak base, such as K3PO4, is used. One of the most difficult transformations in Pd catalysis, the intermolecular C-O bond formation between primary alcohols and electron-neutral or even electron-rich aryl halides, was effectively promoted by the use of a new generation of ligands, 3-methyl-2-di-t-butylphosphinobiaryl. The one-step synthesis of ligands from cheap starting materials, as well as the mild reaction conditions employed for the coupling reactions, enables the practical use of Pd catalysis to access aryl alkyl ethers for the first time. Continuing study of Pd-catalyzed C-N bond-forming processes using biaryl monophosphine ligands led to the discovery of a structural derivative of these ligands, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl. This ligand, in combination with a Pd source, produces a catalyst system with both a greater degree of activity and of stability than those that use our previous ligands. Substrates that were not amenable to Pd catalysis previously are reexamined using this new catalyst system, and excellent results are obtained.
by Xiaohua Huang.
Ph.D.
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Williams, Monique J. "Conditions affecting ergothioneine levels in Mycobacterium smegmatis & the attempted isolation of α-N, N, N-Histidine methyltransferase, the first enzyme in ergothioneine biosynthesis." Doctoral thesis, University of Cape Town, 2007. http://hdl.handle.net/11427/14800.

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Includes bibliographical references (leaves 120-133).
Ergothioneine and mycothiol are the two major low molecular weight thiols present in mycobacteria. The generation of mycothiol-deficient mutants has demonstrated its role in protecting M tuberculosis against oxidative and nitrosative stress. To date, no ergothioneine-deficient mutants have been identified and the role of ergothioneine in mycobacteria remains unknown. The work in this thesis was performed with the aim of better understanding the function of ergothioneine in mycobacteria, by studying its biosynthesis and the conditions affecting its production.
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Cómbita, Merchán Diego Fernando. "Formación de enlaces C-C, C-N y N-N con catalizadores de óxido de cerio y de oro/óxido de cerio." Doctoral thesis, Universitat Politècnica de València, 2016. http://hdl.handle.net/10251/62780.

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[EN] Heterogeneous catalysis is one of the most important tools in the advancement of green chemistry, understood it as one that efficiently uses (preferably renewable) raw materials, eliminate waste and avoids the use of toxic and/or dangerous reagents and solvents in chemicals production and application. In this thesis we have investigated the reaction mechanisms and the nature of the active centers in C-C, C-N and N-N bond forming reactions over cerium oxide and over gold nanoparticles supported on cerium oxide heterogeneous catalysts. As C-C bond formation reaction, we had been studied Sonogashira reaction catalyzed by a heterogeneous Au/CeO2 catalyst, wherein the CeO2 nanoparticle is about 5 nm in diameter. The second part of the thesis comprises the study of C-N bonds formation during carbamoylation reaction between diaminotoluene and dimethyl carbonate, catalyzed by cerium oxide, studying the effect over the reaction of the crystal planes available for reactants adsorption. In a third part, the N-N bond formation in the reductive coupling reaction of nitrocompounds to obtain azocompounds was studied, using Au/CeO2 as heterogeneous catalyst. Also in this section we report, by first time, an active and selective heterogeneous catalyst for the Mills reaction between nitroso compounds and anilines to obtain symmetric and asymmetric azocompounds.
[ES] La catálisis heterogénea es una de las más importantes herramientas para el desarrollo de la Química Sostenible, entendida como aquella que utiliza eficientemente las materias primas (preferiblemente renovables), elimina los desechos y evita el uso de reactivos y solventes tóxicos y/o peligrosos en la manufactura y aplicación de los productos químicos. En esta tesis doctoral se han investigado los mecanismos de reacción y la naturaleza de los centros activos, en reacciones de formación de enlaces C-C, C-N, y N-N sobre catalizadores heterogéneos de óxido de cerio y de nanopartículas de oro soportadas en óxido de cerio. Como reacción de formación de enlaces C-C se ha estudiado la reacción de Sonogashira catalizada con un catalizador heterogéneo de Au/CeO2, en donde el CeO2 está en forma de nanopartículas de cerca de 5nm de diámetro. En la segunda parte de la tesis se profundiza en el estudio de la formación de enlaces C-N durante la reacción de carbamoilación del diaminotolueno con dimetilcarbonato catalizada por el óxido de cerio, estudiando el efecto que tiene sobre la reacción la naturaleza de los planos cristalinos disponibles para la adsorción de los reactivos. En una tercera parte se estudia la formación de enlaces N-N en la reacción de acoplamiento reductivo de nitrocompuestos para obtener azocompuestos en presencia de un catalizador heterogéneo de Au/CeO2. Es este mismo apartado se reporta por primera vez un catalizador heterogéneo de alta actividad y selectividad para la Reacción de Mills entre un nitrosocompuesto y una anilina para obtener azocompuestos simétricos y asimétricos.
[CAT] La catàlisi heterogènia és una de les ferramentes més importants per al desenvolupament de la Química Sostenible, entesa com aquella que utilitza eficientment les matèries pimes (preferiblement renovables), elimina els rebutjos i evita l'ús de reactius i dissolvents tòxics i/o perillosos en la manufactura i aplicació dels productes químics. En esta tesi doctoral s'han investigat els mecanismes de reacció i la natura dels centres actius, en reaccions de formació d'enllaços C-C, C-N i N-N sobre catalitzadors heterogenis d'òxid de ceri i nanopartícules d'or suportades en òxid de ceri. Com reacció de formació d'enllaços C-C s'ha estudiat la reacció de Sonogashira catalitzada amb un catalitzador heterogeni d'Au/CeO2, on el CeO2 està en forma de nanopartícules amb un diàmetre proper als 5nm. En la segona part de la tesi s'aprofundeix en l'estudi de la formació d'enllaços C-N durant la reacció de carbamilació del diaminotoluè amb dimetilcarbonat catalitzada per l'òxid de ceri, estudiant l'efecte que té sobre la reacció la natura dels plans cristal·lins disponibles per a l'adsorció dels reactius. En una tercera part s'estudia la formació d'enllaços N-N en la reacció d'acoblament reductiu de nitrocompostos per a obtenir azocompostos en presència d'un catalitzador heterogeni d'Au/CeO2. En aquest mateix apartat es reporta per primera vegada un catalitzador heterogeni d'alta activitat i selectivitat per a la Reacció de Mills entre un nitrocompost i una anilina per a obtenir azocompostos simètrics i asimètrics.
Cómbita Merchán, DF. (2016). Formación de enlaces C-C, C-N y N-N con catalizadores de óxido de cerio y de oro/óxido de cerio [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/62780
TESIS
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Roberts, Deborah Elizabeth. "Palladium N-neterocyclic carbene complexes as catalysts for C-N, C-Si and C-S bond formations." Thesis, University of Sussex, 2013. http://sro.sussex.ac.uk/id/eprint/45342/.

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This work is foremost a study of various palladium-bearing N-heterocyclic carbenes complexes and their catalytic potential to form C-N bonds. Both alkyl amination and aryl amination are considered. Further elucidation on the mechanism of such catalytic activity is investigated. The viability of alkyl amination using palladium complexes bearing the ligands, ITMe, 1,2,3,4- tetramethylimidazol-2-ylidene, and ICy, 1,3- bis-cyclohexylimidazol-2-ylidene, as catalysts, is investigated. This includes the synthesis of [Pd(ITMe)(neopentyl)Cl]2,[Pd(ITMe)2(neopentyl)Cl], [Pd(ITMe)(neopentyl)(tbutylamine)Cl], [Pd(ITMe)(neopentyl)(hexylamine)Cl], with successful elimination of the alkyl-amination reaction product in low yield from the latter complex. [Pd(ICy)(neopentyl)Cl]2, [Pd(ICy)2(neopentyl)Cl] are also isolated. Unsuccessful attempts were made to vary the electronic properties of the complexes by replacing the amine with a hydrazine. Work was also done on indirect alkylation using tBuLi which led to a new method for synthesis of [Pd(ItBu)2] and novel complex, [Pd(ItBu)Cl3. ItBuH] (ItBu = 1,3- bis-tertbutylimidazol-2-ylidene). Aryl amination catalysed by complexes of palladium bearing the ligand, ITMe, is considered. This includes an improved synthesis of [Pd(ITMe)2] and synthesis of [Pd(ITMe)2(anisole)Cl]. Unsuccessful attempts at the elucidation of the mechanism of [Pd(ITMe)2(anisole)] formation led to the unexpected formation of [Pd(ITMe)2(SiMe3)(Si(SiMe3)3)] and [Pd(ITMe)2(SiMe3)2]. Aryl amination with using [Pd(ITMe)2(SiMe3)2] led to two aryl amination products, 4-ortho-methoxyphenyl morpholine as well as the expected para isomer. The use of complexes [Pd(ItBu)2] and [Pd(SIPr)2] (SIPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) in C-S bond formation was explored. Addition of mesityl magnesium bromide to Pd(1,5-COD)Cl2 led to addition of mesityl substrate across 1,5-COD double bond and the addition of ITMe formed the Heck cycle intermediate [Pd(8-mesityl-1,4,5-η3 – C8H12)X2] (X=Cl, Br). Addition of 4-tolyl magnesium chloride resulting in the formation of Pd(ItBu)2(tolyl)Cl via an indirect route.
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Books on the topic "Microbiology, n.e.c"

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Souci, Robert D. San. N. C. Wyeth's pilgrims. San Francisco: Chronicle books, 1991.

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Weyn, Suzanne. The N-C zone. New York, NY: Macmillan McGraw-Hill, 1998.

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i, Hung Kha. Khu c tie u ai oa n: Truye n kich. [s.l.]: ♯o i Nay, 1988.

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Va n Xua n Nhi Ho . Ho n em hanh phu c: Ta p truye n. Los Alamitos, Calif: Xua n Thu, 1988.

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Anh, Phan. Con lo c ©ʻoi: Tuye n ta p truye n. Los Alamitos, Calif: Xua n Thu, 1987.

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Shubin, V. G. A N C: A view from Moscow. Bellville, South Africa: Mayibuye, 1999.

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Tran, Tieu. Ky u c cua con ve n. Glendale, Ca: Dai Nam, 1987.

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Binh Nguye n. Lo c. Ky tha c: Ta p truye n. Westminster, Calif: Va n Nghe, 1986.

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Tortora, Gerard J. Microbiology C/C. Pearson Education, Limited, 2003.

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Burdick, Michael. C 'N' P. AuthorHouse, 2006.

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Book chapters on the topic "Microbiology, n.e.c"

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Krystal, G., J. Way, and J. Battey. "Comparison of c-, N-, and L-myc Transcriptional Regulation." In Current Topics in Microbiology and Immunology, 274–81. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-74006-0_37.

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Dean, M., J. Cleveland, H. Y. Kim, J. Campisi, R. A. Levine, J. N. Ihle, and U. Rapp. "Deregulation of the c-myc and N-myc Genes in Transformed Cells." In Current Topics in Microbiology and Immunology, 216–22. Berlin, Heidelberg: Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-74006-0_29.

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Silva, S., Y. Wang, M. Babonits, H. Axelson, F. Wiener, and G. Klein. "An Exceptional Mouse Plasmacytoma with a New Kappa/N-myc [T(6; 12) (C1; B)] Translocation Expresses N-myc But Not c-myc." In Current Topics in Microbiology and Immunology, 251–59. Berlin, Heidelberg: Springer Berlin Heidelberg, 1992. http://dx.doi.org/10.1007/978-3-642-77633-5_31.

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Sumegi, J., T. Sejersen, H. Björklund, G. Klein, and N. R. Ringertz. "Differential Expression of N-myc, c-myc and c-src Proto-oncogenes During the Course of Induced Differentiation of Murine Embryonal Carcinoma Cells." In Current Topics in Microbiology and Immunology, 297–304. Berlin, Heidelberg: Springer Berlin Heidelberg, 1986. http://dx.doi.org/10.1007/978-3-642-71562-4_44.

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Yousuf, Sufiara, Nafiaah Naqash, and Rahul Singh. "Nutrient Cycling: An Approach for Environmental Sustainability." In Environmental Microbiology: Advanced Research and Multidisciplinary Applications, 77–104. BENTHAM SCIENCE PUBLISHERS, 2022. http://dx.doi.org/10.2174/9781681089584122010007.

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Nutrient cycling is an important environmental process and has been the focus of ecological research. Nutrient cycling refers to the sufficient supply of key elements provided through the ecological processes within and between various biotic or abiotic components of a cell, community, or ecosystem. Nutrient cycling also includes the recovery and reuse of industrial, agricultural, and municipal organic debris that are considered wastes. Nutrient cycles include biotic and abiotic components involved in biological, geological, and chemical processes known as biogeochemical cycles. Changes occurring in such cycles may indicate or even alter the functioning of the ecosystem. Plants take up soil nutrients in terrestrial ecosystems for healthy growth and development, wherein soil acts as a nutrient reservoir. Nutrients are lost from such sites due to soil erosion, denitrification, and food production, which cause reduced availability of nutrients. Therefore, analyzing nutrients’ assimilation, transport through biota, and their release for subsequent re-assimilation is mandatory. Nutrients to be recycled essentially for the survival of organisms include macronutrients (C, O, H, N, K, P, Ca, Mg, S, and Cl) and micronutrients (Fe, Mn, Mo, Cu, Zn, Bo, Ni, Co, Na, Se, and I). This chapter presents the role of nutrients and nutrient cycling for environmental sustainability
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Aggarwal, P., and M. W. P. Bebbington. "Fragments N—N, C—C, C—N." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-117-00227.

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Aggarwal, P., and M. W. P. Bebbington. "Fragment C—C—N—N—C—N." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-117-00242.

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Aggarwal, P., and M. W. P. Bebbington. "Fragment C—N—C—C—N—N." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-117-00244.

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Lindsley, C. W., and M. E. Layton. "Fragment N—C—N—C—C—N." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-00676.

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Lindsley, C. W., and M. E. Layton. "Fragment N—N—C—N—C—C." In Six-Membered Hetarenes with Two Unlike or More than Two Heteroatoms and Fully Unsaturated Larger-Ring Heterocycles, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-017-00680.

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Conference papers on the topic "Microbiology, n.e.c"

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Carvalho, Keyla Maciel, NAIRA SULANY OLIVEIRA DE SOUSA, and JOÃO VICENTE BRAGA DE SOUZA. "TESTE DE SENSIBILIDADE PELO MÉTODO DE MICRODILUIÇÃO EM CALDO: PROPOSTA DE UM MEIO ALTERNATIVO." In II Congresso Nacional de Microbiologia Clínica On-line. Revista Multidisciplinar em Saúde, 2022. http://dx.doi.org/10.51161/ii-conamic/08.

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Introdução: Através do método de referência padrão desenvolvido pelo Clinical and Laboratory Standards Institute (CLSI) é possível realizar o teste de susceptibilidade antifúngica e determinar a concentração inibitória mínima (CIM) de leveduras que causam infecções fúngicas invasivas, incluindo as espécies de Candida e Cryptococcus neoformans. No entanto, alguns problemas limitam esse teste, como o uso do meio de cultura RPMI-1640 e o tampão MOPS [ácido3- (N-morfolino) propanosulfônico], que possuem um alto custo, tornando o teste inviável para laboratórios com recursos limitados. Objetivo: O objetivo deste trabalho foi comparar a concentração inibitória mínima de Candidas spp. frente ao antifúngico fluconazol, nos meios de cultura RPMI-1640 (protocolo M27-A4) e Sabouraud dextrose modificado. Material e métodos: O meio Sabouraud dextrose modificado (glicose 5 g/L e peptona de soja 10 g/L) foi tamponado com Tris-HCl e o RPMI-1640, conforme recomendação na Norma M27-A4, tamponado com o tampão MOPS. Ambos os meios foram tamponados na concentração final de 0,165 mol/L, pH 7,0. Os microrganismos testados frente a fluconazol foram C. albicans ATCC 36232, C. glabrata ATCC 2001, C. guilliermondi ATCC 6260 e C. tropicalis ATCC 13803. A temperatura de incubação foi de 35 °C e o tempo de incubação de 24 horas. Resultados: Neste estudo, Sabouraud dextrose modificado mostrou uma capacidade equivalente ao uso do meio RPMI-1640 para determinar a concentração inibitória mínima das leveduras patogênicas testadas. Conclusão: Para o teste de microdiluição em caldo (protocolo M27-A4), ambos os meios demostraram o mesmo resultado frente ao antifúngico fluconazol, demostrando a possibilidade do uso do meio Sabouraud modificado tamponado com Tris- HCl em laboratórios com recursos limitados.
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Davis, Philip, Stewart Novick, Stephen Kukolich, Adam Daly, Kexin Li, Ian Dorell, and Lu Kang. "THE ROTATIONAL SPECTRA OF CYANOACETYLENE DIMER, H-C-C-C-N ••• H-C-C-C-N." In 71st International Symposium on Molecular Spectroscopy. Urbana, Illinois: University of Illinois at Urbana-Champaign, 2016. http://dx.doi.org/10.15278/isms.2016.wa09.

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Maziero, João Pedro, Carolina Toledo Santos, Pricila Veiga dos Santos, and Juliano Gonçalves Pereira. "Avaliação do uso de ozônio em temperaturas de leite cru refrigerado na contagem de psicrotróficos." In Semana Online Científica de Veterinária. CONGRESSE.ME, 2021. http://dx.doi.org/10.54265/gsri7118.

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A qualidade do leite cru está associada às boas práticas de ordenha proveniente de rebanhos sadios e com refrigeração obrigatória do leite cru na granja leiteira entre 4 e 7° C, podendo chegar até, no máximo, 9° C durante a coleta final (BRASIL 2018). Embora a refrigeração seja eficaz para aumentar a vida útil do leite cru, a manutenção das baixas temperaturas favorece a multiplicação de bactérias psicrotróficas, que produzem proteases e lipases termorresistentes, que permanecendo ativas mesmo após a pasteurização, podem afetar negativamente, tanto o próprio leite, quanto seus derivados (RIBEIRO et al., 2018). Visando reduzir a contagem de microrganismos psicrotróficos no leite cru, o presente trabalho avaliou a eficácia da aplicação de ozônio, considerado um bactericida verde por não ser poluente e não deixar resíduos no alimento, diretamente no tanque de resfriamento. As amostras de leite cru foram obtidas de um rebanho saudável e recolhidas diretamente do tanque de resfriamento da propriedade e armazenadas em frascos estéreis com volume de 6 litros sob refrigeração (4 e 9° C). A aplicação do ozônio seguiu delineamento fatorial com variáveis independentes sendo as temperaturas do leite (4 e 9° C) e os tempos de exposição ao ozônio (5 e 15 minutos) utilizando Gerador de Ozônio N202F Bivolt 500mg/h O³ Disinfector - Diluka Power. Foram retiradas amostras antes e após a ozonização. As amostras foram então armazenadas por 48 horas sob refrigeração (4° C) para permitir a proliferação da flora psicrotrófica. O teor de psicrotróficos e a contagem bacteriana total das amostras e do grupo controle foram avaliados em meio ágar bacteriológico PCA por 10 dias a 7° C e a 36° C por 24 horas, respectivamente. A aplicação de ozônio foi eficaz em reduzir a contagem de microrganismos psicrotróficos no tempo de 5 minutos a 4° C, esse resultado é extremamente satisfatório, visto que, a temperatura de aplicação é a mesma aplicada aos tanques de refrigeração nas propriedades, o que permitiria, facilmente, a aplicação nas próprias fazendas. Agradecimentos Agradecemos à equipe do Serviço de Orientação à Alimentação Pública da FMVZ-Unesp e ao proprietário da fazenda por disponilibizar o material utilizado na pesquisa. Referências BRASIL. Ministério da Agricultura, Pecuária e Abastecimento. Instrução normativa nº 76, de 26 de novembro de 2018. Regulamentos Técnicos que fixam a identidade e as características de qualidade que devem apresentar o leite cru refrigerado, o leite pasteurizado e o leite pasteurizado tipo A. Diário Oficial da União, Brasília, 2018. RIBEIRO JÚNIOR, J. C.et al. The main spoilage1 related psychrotrophic bacteria in refrigerated raw milk. Journal of dairy science, v. 101, n. 1, p. 75-83, 2018. PALAVRAS-CHAVE: Microbiologia dos alimentos, Qualidade do leite, Tecnologia verde
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Jenkins, Elizabeth E., and Marvin L. Marshak. "Large N[sub c]." In 10TH CONFERENCE ON THE INTERSECTIONS OF PARTICLE AND NUCLEAR PHYSICS. AIP, 2009. http://dx.doi.org/10.1063/1.3293846.

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Polo-Ces, Paula, Pablo Frieiro-Gomis, Fátima Lucio-Martínez, Paula Munín, Pablo Romarís, M. Pereira, and J. Vila. "Palladacycles derivates of diimines ligands [N,C,C,N]." In The 21st International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04760.

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Menga, Davide, and Tim Fellinger. "Fe-N-C electrocatalysts synthesized from Zn-N-C materials via an imprinting strategy." In Materials for Sustainable Development Conference (MAT-SUS). València: FUNDACIO DE LA COMUNITAT VALENCIANA SCITO, 2022. http://dx.doi.org/10.29363/nanoge.nfm.2022.270.

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Georgier, Georgi Nikolov, and Mariana Nikolova Georgiera-Grosse. "Theorem for the relation between the L1(c, n) and L2(c,ρ, n) numbers." In 2014 XXXIth URSI General Assembly and Scientific Symposium (URSI GASS). IEEE, 2014. http://dx.doi.org/10.1109/ursigass.2014.6929203.

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Jakes, P. "Synthesis and EPR studies of N@C[sub 60] and N@C[sub 70] radical anions." In The 14th international winterschool on electronic properties of novel materials - molecular nanostructures. AIP, 2000. http://dx.doi.org/10.1063/1.1342493.

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Plank, W. "Thermal stability of the heterofullerene (C[sub 59]N)X for X=C[sub 59]N,H." In ELECTRONIC PROPERTIES OF MOLECULAR NANOSTRUCTURES: XV International Winterschool/Euroconference. AIP, 2001. http://dx.doi.org/10.1063/1.1426811.

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Lingyun Li, Junqing Li, Shengxian Xie, and Huishan Yu. "The implications between C-SPR and CRn (n′, n) visited." In 2012 IEEE 14th International Conference on Communication Technology (ICCT). IEEE, 2012. http://dx.doi.org/10.1109/icct.2012.6511314.

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Reports on the topic "Microbiology, n.e.c"

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Gland, J. L. Hydrogen induced C-C, C-N, and C-S bond activation on Pt and Ni surfaces. Office of Scientific and Technical Information (OSTI), December 1992. http://dx.doi.org/10.2172/10102894.

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Gland, J. L. Hydrogen induced C-C, C-N, and C-S bond activation on Pt and Ni surfaces. Office of Scientific and Technical Information (OSTI), January 1992. http://dx.doi.org/10.2172/6915688.

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Gland, J. L. Hydrogen Induced C-C, C-N, & C-S Bond Activation on Pt & Ni Surfaces. Office of Scientific and Technical Information (OSTI), July 2004. http://dx.doi.org/10.2172/830711.

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Gland, J. L. [Hydrogen induced C-C, C-N, and C-S bond activities on Pi and Ni surfaces]: Summary. Office of Scientific and Technical Information (OSTI), December 1994. http://dx.doi.org/10.2172/10110807.

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Friend, J. P. High-speed tapping for N/C machining centers. Office of Scientific and Technical Information (OSTI), November 1991. http://dx.doi.org/10.2172/6114424.

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Ball, J. Timothy. Running Title: C and N Allocation in Pine. Office of Scientific and Technical Information (OSTI), December 1996. http://dx.doi.org/10.2172/762784.

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Joyner, Rex W. Diffractive Processes in 200-GeV/c $\pi^- N \to \pi^- \pi^- \pi^+ N$ Interactions. Office of Scientific and Technical Information (OSTI), August 1987. http://dx.doi.org/10.2172/1433220.

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Karl, G., and H. J. Lipkin. Flavor symmetry in the large N{sub c} limit. Office of Scientific and Technical Information (OSTI), December 1991. http://dx.doi.org/10.2172/10107252.

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Karl, G., and H. J. Lipkin. Flavor symmetry in the large N sub c limit. Office of Scientific and Technical Information (OSTI), January 1991. http://dx.doi.org/10.2172/6138160.

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McGuigan, M., and C. B. Thorn. Quark-antiquark Regge trajectories in large N{sub c}QCD. Office of Scientific and Technical Information (OSTI), July 1992. http://dx.doi.org/10.2172/10155611.

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