Relevant bibliographies by topics / Metallo Supramolecular Self-assembly

Academic literature on the topic 'Metallo Supramolecular Self-assembly'

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Published: 7 September 2023

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Journal articles on the topic "Metallo Supramolecular Self-assembly"

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Baytekin, H. Tarik, Bilge Baytekin, Andrea Schulz, Andreas Springer, Thomas Gross, Wolfgang Unger, Marina Artamonova, Sabine Schlecht, Dieter Lentz, and Christoph A. Schalley. "Metallo-Supramolecular Nanospheres via Hierarchical Self-Assembly." Chemistry of Materials 21, no. 13 (July 14, 2009): 2980–92. http://dx.doi.org/10.1021/cm900642p.

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Baytekin, H. Tarik, Bilge Baytekin, Andrea Schulz, and Christoph A. Schalley. "Hierarchical Self-Assembly of Metallo-Supramolecular Nanospheres." Small 5, no. 2 (December 2, 2008): 194–97. http://dx.doi.org/10.1002/smll.200800507.

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Albrecht, Markus, and Roland Fröhlich. "Symmetry Driven Self-Assembly of Metallo-Supramolecular Architectures." Bulletin of the Chemical Society of Japan 80, no. 5 (May 15, 2007): 797–808. http://dx.doi.org/10.1246/bcsj.80.797.

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Lewis, James E. M., and James D. Crowley. "Metallo‐Supramolecular Self‐Assembly with Reduced‐Symmetry Ligands." ChemPlusChem 85, no. 5 (May 2020): 815–27. http://dx.doi.org/10.1002/cplu.202000153.

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Wang, Yun-Chi, Yen-Peng Liang, Jhen-Yu Cai, Yun-Jui He, Yin-Hsuan Lee, and Yi-Tsu Chan. "Metal ion-modulated self-assembly of pseudo-suit[3]anes using crown ether-based terpyridine metalloprisms." Chemical Communications 52, no. 85 (2016): 12622–25. http://dx.doi.org/10.1039/c6cc07452a.

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Zhu, Yu, Wei Zheng, Wei Wang, and Hai-Bo Yang. "When polymerization meets coordination-driven self-assembly: metallo-supramolecular polymers based on supramolecular coordination complexes." Chemical Society Reviews 50, no. 13 (2021): 7395–417. http://dx.doi.org/10.1039/d0cs00654h.

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The marriage of polymerization and coordination-driven self-assembly has given rise to novel types of metallo-supramolecular polymers with well-defined and diverse topological architectures as well as unique dynamic features.
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Cui, Yu, Zi-Man Chen, Xuan-Feng Jiang, Jin Tong, and Shu-Yan Yu. "Self-assembly and anion sensing of metal–organic [M6L2] cages from fluorescent triphenylamine tri-pyrazoles with dipalladium(ii,ii) corners." Dalton Transactions 46, no. 18 (2017): 5801–5. http://dx.doi.org/10.1039/c7dt00179g.

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Teng, Yue, Le Xin Song, Wei Liu, Juan Xia, Li Zhao, Qing Shan Wang, and Mao Mao Ruan. "Creation of hollow microtubular iron oxalate dihydrate induced by a metallo-supramolecular micelle based on the self-assembly of potassium ferrioxalate and sodium dodecyl sulphate." RSC Advances 5, no. 48 (2015): 38006–10. http://dx.doi.org/10.1039/c5ra01703c.

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Singh, Prabhpreet, Lalit Singh Mittal, Kapil Kumar, Poonam Sharma, Gaurav Bhargava, and Subodh Kumar. "Multifunctional metallo-supramolecular interlocked hexagonal microstructures for the detection of lead and thiols in water." Chemical Communications 54, no. 68 (2018): 9482–85. http://dx.doi.org/10.1039/c8cc05814h.

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Wang, Chao, Xin-Qi Hao, Ming Wang, Cunlan Guo, Bingqian Xu, Eric N. Tan, Yan-Yan Zhang, et al. "Self-assembly of giant supramolecular cubes with terpyridine ligands as vertices and metals on edges." Chem. Sci. 5, no. 3 (2014): 1221–26. http://dx.doi.org/10.1039/c3sc52965g.

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Dissertations / Theses on the topic "Metallo Supramolecular Self-assembly"

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Argent, Stephen Paul. "Self-assembly of metallo-supramolecular coordination complexes." Thesis, University of Sheffield, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.434997.

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Zheng, Keqin. "Design and Construction of Metallo-Supramolecular Terpyridine Possessing Higher Order Structure." University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1375283764.

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Hytteballe, Sophie [Verfasser]. "Synthesis of ligands for self-assembly of discrete metallo-supramolecular complexes / Sophie Hytteballe." Bonn : Universitäts- und Landesbibliothek Bonn, 2016. http://d-nb.info/1096329891/34.

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Hristova, Yana Roumenova. "Subcomponent self-assembly of diverse metallo-supramolecular systems from 3,3'-bipyridine-6,6'-dicarboxaldehyde." Thesis, University of Cambridge, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.610122.

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Ludlow, James M. III. "Design and Synthesis of Terpyridine based Metallo-Supramolecular Architectures." University of Akron / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=akron1444989836.

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Troff, Ralf Wilhelm [Verfasser]. "Self-assembly of metallo-supramolecular architectures and mass spectrometry of bismuth oxido clusters / Ralf Wilhelm Troff." Berlin : Freie Universität Berlin, 2012. http://d-nb.info/1027498582/34.

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Tanh, Jeazet Harold Brice. "Metallo-supramolecular Architectures based on Multifunctional N-Donor Ligands." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-39665.

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Self-assembly processes were used to construct supramolecular architectures based on metal-ligand interactions. The structures formed strongly depend on the used metal ion, the ligand type, the chosen counter ion and solvent as well as on the experimental conditions. The focus of the studies was the design of multifunctional N-donor ligands and the characterization of their complexing and structural properties. This work was divided into three distinct main parts: The bis(2-pyridylimine), the bis(2-hydroxyaryl) imine and the tripodal imine / amine ligand approach. In the first part a series of bis(2-pyridylimine) derivatives having different linking elements were employed as building blocks for novel supramolecular architectures. Reaction of individual d-block metal salts with these ligands has led to the isolation of coordination polymers, a metallamacrocycle, double-stranded helicates, triple-stranded helicates as well as of circular meso-helicates. The nature of the spacer in the Schiff base ligands, the noncovalent weak interactions, such as hydrogen bond, face-to-face π-π and edge-to-face CH-π interactions, are all important factors influencing the architecture of the final products. Topological control of the assembly process of the hexanuclear meso-helicates is clearly associated with the bidentate coordination of the sulfate anion which directs the formation of a double- rather than a triple-stranded helicate around the octahedrally coordinated Cu(II). Surprisingly, the variation of the linker function in the ligands, which significantly changes the linking angle of the pyridylimine strands, has only a little influence of the resulting structure. Also the use of a mixture of ligands does not influence the meso-helicate topology; the result is the symmetrically mixed meso-helicate. The new iron(II) triple helicate [Fe2(L5)3](PF6)4 14 {L5 = bis[4-(2-pyridylmethyleneimino)phenyl]-1,1-cyclohexane} in its chloride form binds strongly to DNA as confirmed by induced circular dichroism signals in both the metal-to-ligand charge transfer (MLCT) and in-ligand bands of the helicate. The induced CD spectrum gives some evidence that [Fe2(L5)3]4+ interacts with the DNA in a single binding mode, which is consistent with major groove binding. The cytotoxicity of the new iron(II) triple helicate 14 was evaluated on human lung cancer A549 cells and compared with that of cisplatin and that of the previously reported iron(II) triple helicate [Fe2(L1)3]4+{L1 = bis[4-(2-pyridylmethyleneimino)phenyl]methane}. The first results show some distinguishing features for 14 obviously caused by the existing structural differences of the complexes. In the second part of the thesis, novel uranyl complexes of the bis(2-hydroxyaryl) imine ligands have been synthesized and characterized. 1D coordination polymers and mononuclear structures were formed. In all complexes a distorted hexagonal bipyramidal coordination geometry around the uranyl centre is observed. The imine nitrogen atoms of the ligands do not bind to the metal centre but interact strongly with the hydroxy group via H-bonding. DFT calculations made with L8 ( α,α’-Bis(salicylimino)-m-xylene) are in good agreement with the X-ray crystal structure data. Liquid-liquid extraction studies involving selected ligands and Eu(III) or U(VI) indicate remarkably high selectivity for U(VI) over Eu(III) at weak acidic pH conditions. We believe that the study made opens up new possibilities for uranyl ion extraction which could be interesting in view of the treatment of nuclear waste. In the third part of the thesis, a series of multifunctional tripodal ligands with different N-donor centres were used for U(VI) and lanthanide, Nd(III), Eu(III) and Yb(III), binding and extraction. Reaction of these metal ions with selected tripodal ligands afforded complexes which were characterized by ESI mass spectroscopy. The complex composition was found to be 1:1 in all cases. The extraction behaviour of the tripodal ligands towards Eu(III) and U(VI) was studied both in the absence and presence of octanoic acid as co-ligand using the extraction system Eu(NO3)3 or UO2(NO3)2–buffer–H2O/ ligand–CHCl3. These separation systems show a remarkably high selectivity for U(VI) over Eu(III). It is interesting to note that the addition of the octanoic acid to the extraction system leads to high synergistic effects. A series of Eu(III) extraction experiments were done to clarify the composition of the extracted complexes. The results clearly point to the formation of various species with changing composition.
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Baytekin, Bilge [Verfasser]. "An easily accessible toolbox of functionalized macrocycles and rotaxanes : a (tandem) ESI-FTICR mass spectrometric study on Fréchet-type dendrimers with ammonium cores and hierarchical self-assembly of metallo-supramolecular nano-spheres / Bilge Baytekin." Berlin : Freie Universität Berlin, 2008. http://d-nb.info/1023331306/34.

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Riello, Massimo. "Using electrostatic interactions to control supramolecular self-assembly on metallic surfaces." Thesis, King's College London (University of London), 2014. https://kclpure.kcl.ac.uk/portal/en/theses/using-electrostatic-interactions-to-control-supramolecular-selfassembly-on-metallic-surfaces(21253b66-5b2c-4aa9-8bf2-36025282a95e).html.

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Supramolecular self-assembly on metallic surfaces is the ideal playground for studying a variety of physical and chemical phenomena. Adsorbed molecules will diffuse and self-organise to form assemblies dictated by their functionalities, while the more or less pronounced metal reactivity will accordingly affect both the supramolecular patterns and the interfacial chemistry. Besides structural aspects, electronic properties are central in determining the energy level alignment at the heterojunction and, thus, the performance of organic-based devices. Notably, charge reorganisation at the metal-organic interface will produce surface dipoles, whose effect is to add electrostatic repulsion to the dispersion-driven supramolecular self-assembly and to change the work function of the surface. Herein, the relation between charge migration (i.e., the creation of surface dipoles) and molecular self-assembly is addressed by studying the behaviour of on-purpose designed molecular units on selected metals. We will show that choosing the substrate on the basis of its work function can selectively allow or inhibit the transfer of charge from the organic material to the electrode. When charge transfer occurs, the growing supramolecular structures exhibit a phase modulation driven by the presence of competing interactions. Moreover, the introduction of reactive moieties in formerly inert tectons will be identified as a suitable strategy for promoting the formation of interfacial dipoles upon surface-mediated chemical reactions. Our work paves the way for a more rational approach to the design of metal-organic systems, as we speculate that charge transfer effects and surface chemistry can be predicted at the stage of molecular design, at variance with the current trial and error approach used in the field of organic electronics. This thesis is based on multiscale theoretical modelling of selected metalmolecule couples and it is the result of a fruitful collaboration with the groups of Prof Davide Bonifazi (Université de Namur) and Prof Giovanni Costantini (University of Warwick).
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Wu, Xiaolei. "COORDINATION-DRIVEN SELF-ASSEMBLY OF TERPYRIDINE-BASED SUPRAMOLECULES." University of Akron / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=akron1490372164176458.

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Books on the topic "Metallo Supramolecular Self-assembly"

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Lin, Nian, and Sebastian Stepanow. Designing low-dimensional nanostructures at surfaces by supramolecular chemistry. Edited by A. V. Narlikar and Y. Y. Fu. Oxford University Press, 2017. http://dx.doi.org/10.1093/oxfordhb/9780199533046.013.10.

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This article describes the use of supramolecular chemistry to design low-dimensional nanostructures at surfaces. In particular, it discusses the design strategies of two types of low-dimensional supramolecular nanostructures: structures stabilized by hydrogen bonds and structures stabilized by metal-ligand co-ordination interactions. After providing an overview of hydrogen-bond systems such as 0D discrete clusters, 1D chains, and 2D open networks and close-packed arrays, the article considers metal-co-ordination systems. It also presents experimental results showing that both hydrogen bonds and metal co-ordination offer protocols to achieve unique nanostructured systems on 2D surfaces or interfaces. Noting that the conventional 3D supramolecular self-assembly has generated a vast number of nanostructures revealing high complexity and functionality, the article suggests that 2D approaches can be applied to substrates with different symmetries as well as physical and chemical properties.
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Book chapters on the topic "Metallo Supramolecular Self-assembly"

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Williams, A. F., C. Piguet, and R. F. Carina. "Following the Self-Assembly Process in Solution." In Transition Metals in Supramolecular Chemistry, 409–23. Dordrecht: Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-015-8380-0_22.

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Constable, E. C. "Metal-Ions: A Self-Assembly Motif in Supramolecular Oligomers." In Transition Metals in Supramolecular Chemistry, 81–99. Dordrecht: Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-015-8380-0_4.

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Feringa, Ben L., Onko-Jan Gelling, Minze T. Rispens, and Marcel Lubben. "Self-Assembly of Mono- and Dinuclear Metal Complexes; Oxidation Catalysis and Metalloenzyme Models." In Transition Metals in Supramolecular Chemistry, 171–90. Dordrecht: Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-015-8380-0_9.

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Xiong, Zushuang, Lanhai Lai, and Tianfeng Chen. "Self-Assembled Copper Polypyridyl Supramolecular Metallopolymer Achieving Enhanced Anticancer Efficacy." In Self-Assembly of Nanostructures and Patchy Nanoparticles. IntechOpen, 2020. http://dx.doi.org/10.5772/intechopen.92708.

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Metallopolymers, a combination of organic polymers and metal center, contain metal atoms in repeating monomers can change its dynamic and thermodynamic properties through the directionality of coordination bonds and chemical tailoring of ligands. In the past decade, self-assembled functional supramolecular metallopolymers have aroused a surge of research interest, and have demonstrated application potential in cancer therapy. In this chapter, we have summarized the progress in the rational design of biological application of different metallopolymers. Especially, a copper polypyridyl complex was found be able to self-assemble into a supramolecular metallopolymer driven by the intermolecular interactions, which could enhance the uptake in cancer cells through endocytosis, thus effectively inhibit tumor growth in vivo without damage to the major organs. This study may provide a good example to use self-assembled metallopolymer to achieve enhanced anticancer efficacy.
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Velayudham, Murugesan, and Pounraj Thanasekaran. "Rhenium(I)-Based Metallacycles for Sensing Applications." In Photophysics of Supramolecular Architectures, 137–80. BENTHAM SCIENCE PUBLISHERS, 2022. http://dx.doi.org/10.2174/9789815049190122010009.

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<div>Coordination-driven self-assembly provides unique opportunities to prepare</div><div>highly complex chemical systems from simple components and has led to significant</div><div>progress in the construction of supramolecular materials with novel topologies and</div><div>exploitable functions. During the past few decades, metallacycles have captured</div><div>widespread interests due to their wide applications in catalysis, sensor, and biological</div><div>relevant applications. Thus, exploring new metallacycles, studying their physical and</div><div>chemical properties and applications have become one of the most attractive and</div><div>exciting areas of inorganic chemistry and supramolecular chemistry. Among which,</div><div>rhenium(I)-based metallacycles, constructed from the rhenium metal ions and a variety</div><div>of aromatic ligands, have attracted considerable attention because of their unique</div><div>potentials in light-harvesting, catalysis, sensing, biomedical, etc. In this chapter, we</div><div>summarize the recent research progress in rhenium-based metallacycles with their</div><div>synthesis, properties and potential application in host-guest chemistry.</div>
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Conference papers on the topic "Metallo Supramolecular Self-assembly"

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Chen, S. G., X. D. Chai, Y. W. Cao, R. Lu, Y. Y. Zhao, Y. S. Jiang, and T. J. Li. "Formation of non-centrosymmetric supramolecular structure by hydrogen-bonding control of molecular self-assembly." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835777.

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