Academic literature on the topic 'Metallic soap'

Mature fruits of Telfairia occidentalis were purchased from a local market in Ikono Local Government Area of Akwa Ibom State, Nigeria. The seeds were separated from the fleshy mesocarp, washed with water and sundried. The cotyledons were separated from the seed coat and then oven-dried at 105 – 110 °C for 24 hours. The dry seeds were blended into powder and the oil cold-extracted with n-hexane. The oil extracted was used to prepare copper, nickel and zinc soaps. The soaps were characterised using standard methods and then applied as additives in the production of body pomades. Several tests were performed on the control and the metallic soap pomades to establish the effectiveness of the metallic soaps in pomade production. All the prepared metallic soaps were sparingly soluble in kerosene and methanol and exhibited no foaming characteristics. The properties of the pomades imply that the metallic soaps of T. occidentalis have good potential in the cosmetics industry.

Introduction:Biologically potent compounds are one of the most important classes of materials for the upcoming generations. Increasing number of microbial infectious diseases and resistant pathogens create a demand and urgency to develop novel, potent, safe and improved variety of antimicrobial agents. This initiates a task for current chemistry to synthesize compounds that show promising activity as therapeutic agents with lower toxicity. Therefore, a substantial research is needed for their discovery and improvement. Chemistry of present era aims to build a pollution free environment. For the same, it targets to create some alternativeswhich are eco-friendly and nature loving. Present research work is a step towards achieving such alternatives.Method:For this the metallic soaps of copper (derived from common edible oils) were synthesized. The synthesized copper soaps have been confirmed by elemental analysis, UV, and IR spectroscopic technique. The fungicidal activities of copper soaps derived from soyabean, sesame oils have been evaluated by testing against Alternaria alternate and Aspergillus niger by P.D.A. technique.Result:The fungi toxicity results indicate that the strain of fungal species are susceptible towards these soaps and suggests that with the increase in concentration of copper soap it may increase further. The transition metallic soaps showed good antifungal activity because chelation increases the anti-microbial potency.

This paper focuses on the hardness distribution in the AA2014-T6 ring specimens upset under rigid dies. Three different types of lubricants namely soap, boric acid and vaseline were employed as lubricants and the friction factor corresponding to the lubricant employed was evaluated using standard ‘Ring compression test’. The strain distributions obtained from the simulation studies were used to predict the hardness inside the ring specimen. The hardness measured experimentally was validated with the predicted hardness and it was found that the errors in the predicted results were less than 10%. The hardness variations inside the upset metallic ring specimens were compared with the deformed solid cylinders to understand the behavior of differential strain hardening. It can be reported from the experimental and predicted results that the hardness is not uniform inside the deformed ring specimen and it varies at the bulge head; on the surface and along the neutral plane.

The characteristics of armour paints, historically used to protect ferrous industrial heritage, are explored. Amour paints contain lamellar and highly reflexive pigments of micaceous iron oxide (MIO) and metallic, leafing aluminium, bound in linseed oil and linseed oil–tung oil mixtures, on an inhibitive and soap-forming linseed oil primer (red lead). It is the first study of the binding media used for historical armour paints and investigates the chemical and physical ageing of armour paints using a multianalytical approach. Naturally aged examples are compared to accelerated aged replica armour paint, and to historical paints. The ageing and degradation reactions are assessed by complementary GC–MS and FTIR, together with measurements of wettability, hardness and surface colour. The historical paint formulations include linseed oils and alkyd binders. The results confirm that the leafing effect of aluminium pigments results in only a small concentration of binder at the surface: the paints studied reflect light and form a strong chemical and physical barrier. Linseed oils and tung oil mixtures have been proven to be suitable for the production of armour paints, but the evaluation of ageing and assessment of physical changes will require further investigation.

Semiconducting metal oxide nanocrystals are an important class of materials that have versatile applications because of their useful properties and high stability. Here, we developed a simple route to synthesize nanocrystals (NCs) of copper oxides such as Cu2O and CuO using a hot-soap method, and applied them to H2S sensing. Cu2O NCs were synthesized by simply heating a copper precursor in oleylamine in the presence of diol at 160 °C under an Ar flow. X-ray diffractometry (XRD), dynamic light scattering (DLS), and transmission electron microscopy (TEM) results indicated the formation of monodispersed Cu2O NCs having approximately 5 nm in crystallite size and 12 nm in colloidal size. The conversion of the Cu2O NCs to CuO NCs was undertaken by straightforward air oxidation at room temperature, as confirmed by XRD and UV-vis analyses. A thin film Cu2O NC sensor fabricated by spin coating showed responses to H2S in dilute concentrations (1–8 ppm) at 50–150 °C, but the stability was poor because of the formation of metallic Cu2S in a H2S atmosphere. We found that Pd loading improved the stability of the sensor response. The Pd-loaded Cu2O NC sensor exhibited reproducible responses to H2S at 200 °C. Based on the gas sensing mechanism, it is suggested that Pd loading facilitates the reaction of adsorbed oxygen with H2S and suppresses the irreversible formation of Cu2S.

Psychrotrophic microorganisms, especially Pseudomonas spp., are present in the microbiota of refrigerated milk as they can grow at refrigeration temperatures irrespective of their optimal growth temperature. Psychrotrophic counts ranging from 105 to 108 CFU/mL in refrigerated raw milk effect cheese quality, since the synthesized thermoresistant enzymes affect the nutritional value, sensory properties, and texture. Cheese is the dairy product with the highest growth rate in the food industry in Brazil in recent years and meets the current consumption trends of nutritious and practical foods. The objective of this review was to address the importance and influence of the psychrotrophic raw milk microbiota on the quality and sensory properties of cheese. The enzymes produced by psychrotrophic microorganisms lead to taste changes, undesirable clotting times, increased concentrations of free fatty acids and free amino acids, and a reduced shelf-life, in addition to negatively affecting cheese yields. Proteases from psychrotrophs are also associated with slicing problems and progressive loss of the elasticity of cheese, a bitter taste, and increased clotting times of cheese produced with pasteurized milk. On the other hand, their lipases increase the clotting time and have a negative effect on the sensory properties by providing a rancid, soap, metallic, or oxidized smell and taste. The control of the psychrotrophic population found in refrigerated raw milk contributes to better cheese production yields and desirable texture and sensory properties, which extends the shelf-life of cheese and improves consumer acceptance.

Thesis (Master)--İzmir Institute of Technology, İzmir, 2005.
Keywords: Electrical conductivity, langmuir blodgett technique, metal soaps, nanofilms, moisture adsorption. Includes bibliographical references (leaves. 127-132).

In this thesis, geometry is used as a basis for conducting experiments aimed at growing and arranging inorganic minerals on curved interfaces. Mineralisation is directed using crystalline and liquid-crystalline metallic soaps and surfactant/water systems as templates.¶ A review of the history, syntheses, structure and liquid crystallinity of metallic soaps and other amphiphiles is presented as a foundation to understanding the interfacial architectures in mesostructured template systems in general.¶ In this study, a range of metallic soaps of varying chain length and cation type are synthesised and characterised to find potentially useful templates for mineral growth. These include alkaline-earth, transition metal, heavy metal and lanthanide soaps. These are systematically characterised using a variety of analytical techniques, including chemical analyses, x-ray diffraction (XRD) infrared spectroscopy (IR) and differential scanning calorimetry (DSC). Their molecular and crystal structures are studied using transmission electron microscopy (TEM), cryo-TEM, electron diffraction (ED), electron paramagnetic spin resonance (EPR), absorption spectroscopy (UV-VIS), high resolution laser spectroscopy, atomic force microscopy (AFM), nuclear magnetic resonance spectroscopy, scanning electron microscopy (SEM), electron dispersive x-ray analysis (EDXA), thermal gravimetric analysis (TGA) and magnetic measurements. Models for the molecular and crystal structures of metallic soaps are proposed. The soaps are predominantly lamellar crystalline or liquid crystalline lamellar rotor phases with tilted and/or untilted molecular constituents. These display evidence of varying degrees of headgroup organisation, including superstructuring and polymerisation. A single crystal structure is presented for a complex of pyridine with cobalt soap. Simple models for their structure are discussed in terms of their swelling properties in water and oils. Experiments are also presented to demonstrate the sorbent properties of aluminium soaps on oil spills.¶ The thermotropic liquid crystallinity of alkaline earth, transition metal, heavy metal and lanthanide soaps is investigated in detail. This is done to assess their suitability as templates, and to document their novel thermotropic behaviour, particularly the relatively unknown lanthanide soaps. Liquid crystalline behaviours are studied using high-temperature XRD (HTXRD), hot-stage optical microscopy and DSC. Models for a liquid crystalline phase progression from crystals to anisotropic liquids are discussed in terms of theories of self-assembly and interfacial curvature. The terminology required for this is drawn from various nomenclature systems for amphiphilic crystals and liquid crystals. General agreement with previous studies is reported for known soaps, while liquid crystallinity is demonstrated in the lanthanide and some non-lanthanide soaps for the first time. A general phase progression of crystalline lamellar through liquid crystalline lamellar to non-lamellar liquid crystalline is discussed in terms of models concerned with the molecular and crystal structures of the soaps and their phase transitions via headgroup and chain re-arrangements.¶ Experiments aimed at guiding growth of metal sulfides using metallic soaps as templates are described, and a model for this growth is discussed. Metal sulfides have been successfully grown by reacting crystalline and liquid crystalline transition metal and heavy metal soaps with H2S gas at room temperature and at elevated temperature. These have been characterised using XRD, TEM, ED and IR. Sulfide growth is demonstrated to be restricted and guided by the reacting soap template architecture. Zinc, cadmium, indium and lead soaps formed confined nanoparticles within the matrix of their reacting soap template. In contrast, curved and flat sheet-like structures, some resembling sponges were found in the products of sulfided iron, cobalt, nickel, copper, tin and bismuth soaps. A model to explain this behaviour is developed in terms of the crystal and liquid crystal structures of the soaps and the crystal structures of the metal sulfide particles.¶ Liquid crystalline iron soaps have been subjected to controlled thermal degradation yielding magnetic iron oxide nanoparticles. Some XRD and TEM evidence has been found for formation of magnetic mesostructures in heat-treated iron soaps. Models for the molecular and liquid crystalline structure of iron soaps, their thermotropic phase progression and eventual conversion to these magnetic products are discussed. Systematic syntheses of mesoporous silicates from sheeted clays are discussed.¶The templates that have been used are cationic surfactants and small, organic molecular salts. Experiments are reported where a cooperative self-assembly of surfactant/water/kanemite plus or minus salt and oils yields 'folded sheet materials' (FSM'S). Templating of kanemite has also been achieved using cobalt cage surfactants. A theoretical prediction of the specific surface areas and specific volumes of homologous sets of FSM's gave excellent agreement with measured values. The geometry and topology of the mesostructures are discussed. A theoretical model is also discussed regarding the curvature found in the sheets of natural clays , and results of templating clays and silica using metallic soaps are presented. Experiments and a model for low temperature nucleation and growth of microporous silicalite-1 are described in terms of silica templating by water clathrates.¶ Finally, the problem of finding minimal surface descriptions of crystal networks is addressed. Combinatoric methods are used to disprove the existence of possible embeddings of type I and II clathrate networks in non-self intersecting periodic minimal surfaces. The crystal network of the clathrate silicate, melanophlogite is successfully embedded in the WI-10 self-intersecting surface. Details of a previously unreported, genus-25 periodic surface with symmetry Im3m are discussed.

Recently, additional scrutiny is being placed on all vapor releases to the environment from the fuel system of an automobile. In an effort to lower the overall release of fuel vapor, a preliminary study of the vapor formation processes that occur in a low pressure supply fuel rail was undertaken. The first objective of this work was to determine the means by which fuel vapor is generated within the fuel rail, particularly during hot soak conditions. Then, using this information, the next task was to develop a computational fluid dynamics (CFD) code which would model the vapor formation in the rail. An investigation of the fuel rail material and design revealed that the probable mechanism for vapor formation is nucleate boiling from cavities in the fuel rail surface and at the o-ring connections with the fuel injectors. Therefore, an experiment was constructed to investigate the vapor formation from artificial cavities on a metallic surface and at an o-ring interface. The data collected from the experiment included the departure diameter of the vapor bubbles, the bubble frequency, and the bubble rise velocity. These values, which are used to determine the vapor generation rate, were compared to the results predicted by various correlations available in the literature. Subsequently, a CFD model was constructed of the fuel rail, using Star-CD, by incorporating the appropriate vapor generation correlations as user-defined subroutines. The experimental observations clearly demonstrated that a large amount of vapor was generated at the o-ring interface and, to a lesser degree, from the cavities in the metallic surface. A CFD model was constructed to predict the vapor generated in a fuel rail from these cavities. Existing correlations that describe nucleate boiling adequately model this generation mechanism in the fuel rail. This CFD code can be used to determine the amount of vapor formed under various hot soak conditions. An analytical means of predicting the vapor formation at the o-ring interface will have to be developed in order to complete the CFD model.

Variations in spectral emissivity of Usibor® 1500P steel during a two-step austenitization and in two different heating atmospheres, argon and air, are measured in-situ using a near infrared spectrometer and ex-situ with a Fourier transform infrared reflectometer. Phase transformations of the Al-Si coating and surface oxidation lead to the changes in surface phase composition and surface roughness, which in turn influences the spectral emissivity. In the first step heating at 610°C, the abrupt increase of spectral emissivity in argon and air is due to the transformation of the Al-Si metallic surface into the Al7Fe2Si intermetallic surface and an increase in surface roughness. Through the second step heating at 900°C, the progressive decrease of spectral emissivity with soak time in argon is caused by the surface phase transformation from Al5Fe2 into AlFe with a decrease in surface roughness. In contrast, surface oxidization with an increase in surface roughness significantly increases the spectral emissivity after two minutes soaking in air.