Academic literature on the topic 'Metal wastes Environmental aspects Victoria'

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Journal articles on the topic "Metal wastes Environmental aspects Victoria"

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Ciornei, Mirela, Răzvan Ionuț Iacobici, Ionel Dănuț Savu, and Dalia Simion. "FDM 3D Printing Process - Risks and Environmental Aspects." Key Engineering Materials 890 (June 23, 2021): 152–56. http://dx.doi.org/10.4028/www.scientific.net/kem.890.152.

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The application of the 3D printing processes is continuously increasing due to their large number of technical and economic advantages when produce prototypes, but in the mass fabrication as well, especially for metal printing of low dimension products. The process produces pollution as all technological processes. Noise, fume and polymer wastes are the main elements which exit from the process and they are not products. The types and the volumes of those pollution emissions depend on the process parameters. The paper presents the results of FDM process emissions analysis. It was recorded the noise for different stages of the printer functioning. It was measured the volume and the contents of the fume produced during the extrusion of the polymer, for PLA polymer and for ABS polymer filaments. Specific risks were analysed and conclusions were reported. The measurement was done for a random chosen product and the results were compared with the pollutant emissions from traditional technological processes applied to erect the same type of product. It has been concluded that the noise emitted during the FDM printing is about 82-85% of the noise produced when apply milling to create similar shapes and dimensions (it was recorded values for the sound pressure in a large range: 42-68 dB, depending on the working regime). Regarding the fume emission, the intensity of emission was up to 40% higher in the FDM process comparing to the milling process. That was explained as being a direct result of the fluid-viscous state in which the material is put during the printing process. When discuss about the risks, most of the main identified risks in the milling and/or extrusion process were almost inexistent in the FDM printing. Electrical injuries and heat injuries are the main risks to which the operator is exposed. Mechanical injuries are sensitively lower than in the traditional processes, as milling The FDM process is safer and produces lower material wastes. It can be concluded that the FDM printing process has lower impact with the environment and with the operator.
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Sivaraman, Chandhinipriya, Shankar Vijayalakshmi, Estelle Leonard, Suresh Sagadevan, and Ranjitha Jambulingam. "Current Developments in the Effective Removal of Environmental Pollutants through Photocatalytic Degradation Using Nanomaterials." Catalysts 12, no. 5 (May 17, 2022): 544. http://dx.doi.org/10.3390/catal12050544.

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Photocatalysis plays a prominent role in the protection of the environment from recalcitrant pollutants by reducing hazardous wastes. Among the different methods of choice, photocatalysis mediated through nanomaterials is the most widely used and economical method for removing pollutants from wastewater. Recently, worldwide researchers focused their research on eco-friendly and sustainable environmental aspects. Wastewater contamination is one of the major threats coming from industrial processes, compared to other environmental issues. Much research is concerned with the advanced development of technology for treating wastewater discharged from various industries. Water treatment using photocatalysis is prominent because of its degradation capacity to convert pollutants into non-toxic biodegradable products. Photocatalysts are cheap, and are now emerging slowly in the research field. This review paper elaborates in detail on the metal oxides used as a nano photocatalysts in the various type of pollutant degradation. The progress of research into metal oxide nanoparticles, and their application as photocatalysts in organic pollutant degradation, were highlighted. As a final consideration, the challenges and future perspectives of photocatalysts were analyzed. The application of nano-based materials can be a new horizon in the use of photocatalysts in the near future for organic pollutant degradation.
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Sánchez-España, Javier, Andrey Ilin, and Iñaki Yusta. "Metallic Copper (Cu[0]) Obtained from Cu2+-Rich Acidic Mine Waters by Two Different Reduction Methods: Crystallographic and Geochemical Aspects." Minerals 12, no. 3 (March 4, 2022): 322. http://dx.doi.org/10.3390/min12030322.

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The recovery of valuable metals from different types of wastes has become of prime strategic interest given the scarcity of primary critical raw materials at international scale. Implementation of new methods or refinement of classical techniques with modern technological advances is, therefore, an active research field. Mine wastes are of special interest because their high metal concentrations make them environmentally harmful and economically profitable at the same time. In this study, we evaluated two different methods of Cu recovery from extremely acidic mine waters seeping from wastes and abandoned mines in SW Spain. Through a series of different batch experiments, we compared the method efficiency and crystallographic properties of elemental copper (Cu[0]) obtained by reduction of Cu2+ ions by (1) chemical reduction using ascorbic acid at different environmental conditions of pH (1.50–3.95), temperature (25–80 °C) and ascorbic acid concentration (10 mM to 0.1 M), and (2) classical cementation method with scrap iron at pH 1.50 and 25 °C. Our study demonstrates that the precipitation of Cu[0] can take place at pH 3.95 and low AA concentrations (0.1 M), resulting in large (µm-scale), perfectly developed crystals of copper with pseudoprismatic to acicular habit after 24 h of aging, likely through formation of a transient compound consisting in Cu2+-ascorbate and/or cuprite (Cu2O) nanocolloids. Reduction experiments at higher AA concentrations (0.1 M) showed faster precipitation kinetics and resulted in high-purity (>98%) copper suspensions formed by subrounded nanoparticles. The AA method, however, yielded very low recovery rates (15–25%) because of the low pH values considered. The cementation method, which produced tree-like aggregates formed by sub-micron crystals arranged in different directions, proved to be much more efficient (>98% recovery) and cost-effective.
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Faishal, Muhammad, Muhammad Noor Arfan, and Hayati Mukti Asih. "Reducing Environmental Impact on SME Metals Production Process Using Life Cycle Assessment and Analytical Hierarchy Process Method." Jurnal Ilmiah Teknik Industri 19, no. 1 (June 23, 2020): 84–94. http://dx.doi.org/10.23917/jiti.v19i1.10041.

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The ABC metal SME produces some wastes, such as liquid waste, solid waste, and smoke. The problem is hazardous waste dumped directly into the environment without any waste treatments which had bad impact on the environment around its SME. Therefore, this research is proposed to improve the production process of metal that can reduce the environmental impacts. The Life Cycle Assessment (LCA) method is developed to identify all the processes that have an impact on the environment and also to calculate the energy used. The values of environmental impact are calculated using Simapro 9.0 Software. In addition, Analytical Hierarchy Process (AHP) method is employed to determine the best alternative fuel according to four criteria, such as temperature, price, emission, and fuel consumption. The results show the process that has the greatest environmental impact is the metal smelting process. It is caused by the source fuel in this process was used oil. The usage of used oil can be the sources of air pollution that causing health problems in the respiratory tract such as bronchitis and asthma. Some alternative fuel was proposed, however, fuel gas is the best alternative among others according to the expert opinions. For the managerial insight, this research can be suggestion for SME to choose the best fuel in the production process that considering economic and environmental aspects.
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Zohra, Tanzeel, Ali Talha Khalil, Faryal Saeed, Bushra Latif, Muhammad Salman, Aamer Ikram, Muhammad Ayaz, and H. C. Ananda Murthy. "Green Nano-Biotechnology: A New Sustainable Paradigm to Control Dengue Infection." Bioinorganic Chemistry and Applications 2022 (August 8, 2022): 1–21. http://dx.doi.org/10.1155/2022/3994340.

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Dengue is a growing mosquito-borne viral disease prevalent in 128 countries, while 3.9 billion people are at high risk of acquiring the infection. With no specific treatment available, the only way to mitigate the risk of dengue infection is through controlling of vector, i.e., Aedes aegypti. Nanotechnology-based prevention strategies like biopesticides with nanoformulation are now getting popular for preventing dengue fever. Metal nanoparticles (NPs) synthesized by an eco-friendly process, through extracts of medicinal plants have indicated potential anti-dengue applications. Green synthesis of metal NPs is simple, cost-effective, and devoid of hazardous wastes. The recent progress in the phyto-synthesized multifunctional metal NPs for anti-dengue applications has encouraged us to review the available literature and mechanistic aspects of the dengue control using green-synthesized NPs. Furthermore, the molecular bases of the viral inhibition through NPs and the nontarget impacts or hazards with reference to the environmental integrity are discussed in depth. Till date, major focus has been on green synthesis of silver and gold NPs, which need further extension to other innovative composite nanomaterials. Further detailed mechanistic studies are required to critically evaluate the mechanistic insights during the synthesis of the biogenic NPs. Likewise, detailed analysis of the toxicological aspects of NPs and their long-term impact in the environment should be critically assessed.
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Nester, Anatolyi, Larisa Tretyakova, Liudmyla Mitiuk, Natalya Prakhovnik, and Arkadii Husev. "Remediation of Soil Containing Sludge Generated by Printed Circuit Board Production and Electroplating." Environmental Research, Engineering and Management 76, no. 4 (December 18, 2020): 68–75. http://dx.doi.org/10.5755/j01.erem.76.4.25460.

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This paper examines the environmental conditions at the premises of printed circuit boards (PCBs) manufacturers, which have electroplating plants. It provides a brief overview of the key aspects of adverse environmental impacts of wastes generated by PCB manufacture and electroplating plants. The aim of this research was to improve the test method for evaluation of wastewater effect on the soil salinity at the premises of PCBs manufacturers. The object of research was the process of extraction and use of copper from wastewater generated by PCBs manufacture and electroplating. As an example, the process of sludge formation during PCBs etching has been reviewed. With the etching line capacity of 14 m2/h, one-shift manufacturing process will result in the production of up to 2,500 kg of sludge monthly. For enterprises with capacities of 2,000–4,000 m2 circuits, this means annual accumulation at their premises of up to 70 tons of wastes in the form of sludge. Estimates suggest that the upper half-meter layer of the aeration zone will be qualified as slightly saline in one year after accumulation of the sludge. In subsequent years, the salt content will increase and saline soil can be found at the depths of 1.5–2 m over ten years of storage. The authors of this paper propose to treat spent etching solutions applying regeneration technology in order to reduce the amount of sludge. With this technology, it is possible to use the extracted metal as a secondary raw material for copper production and re-use the regenerated solution in PCBs etching. This paper provides estimated hazard indices calculated for the storage of sludge at the manufacturer’s premises before and after the implementation of the proposed technology. With regards to findings of the study, it has been proposed to reuse copper recovered from wastes as a raw material for the industry.
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Karmee, Sanjib Kumar. "Moving towards the Application of Biocatalysis in Food Waste Biorefinery." Fermentation 9, no. 1 (January 16, 2023): 73. http://dx.doi.org/10.3390/fermentation9010073.

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Waste valorization is an important strategy to reduce environmental pollution and dependency on petroleum-based fuels. In this regard, utilization of food waste as a versatile and low-cost resource is important. Several advanced catalytic methods for the valorization of food waste have been widely investigated for the production of liquid biofuels. Along this line, chemical catalysts have been explored for the synthesis of liquid biofuels. Chemo-catalysis is mainly metal based, which requires harsh process conditions. Alternatively, biocatalysts are currently being investigated as a result of several advantages such as mild reaction conditions, recyclability, selectivity and biodegradability. In this work, recent biocatalytic technologies for the preparation of liquid biofuels through food waste valorization are discussed thoroughly. Lipases are employed for the synthesis of biodiesel and the upgradation of bio-oil, whereas methane mono-oxygenases could be explored for the production of methanol via the oxidation of methane generated from food wastes. Industrial production of ethanol from food waste using bioconversion technologies is a success story. To date, there has been no specific report on the use of food waste for propanol preparation using enzymes. The ABE process (Acetone–Butanol–Ethanol) (using suitable microorganisms) is used for butanol preparation, where the vacuum stripping system is integrated to remove butanol from the broth and circumvent inhibition. The synthesis of hydrocarbon fuels from fatty acids and triglycerides can be carried out using enzymes, such as carboxylic acid reductase and fatty acid photodecarboxylase (an algal photoenzyme). Both carboxylic acid reductase and fatty acid photodecarboxylase have not yet been applied in the direct valorization of food wastes. Furthermore, limitations of the reported methods, societal and economic aspects and a fresh perspective on the subject, along with important examples, are described.
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Giurlani, Walter, Martina Vizza, Stefano Mauro Martinuzzi, Andrea Comparini, Marco Bonechi, Margherita Verrucchi, Andrea Caneschi, and Massimo Innocenti. "New Frontiers in Electrodeposition for More Sustainable Electroplating Processes." ECS Meeting Abstracts MA2022-02, no. 23 (October 9, 2022): 956. http://dx.doi.org/10.1149/ma2022-0223956mtgabs.

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Although technological and processing advancements occurred in the past forty years, industrial firms are still struggling to provide solutions to corrosion protection as well as reduction of toxic wastes. Specifically, large-scale industrialization of electroplating techniques will continue to be limited by strict environmental regulations. Moreover, price volatility of the highly demanding electroplated materials like gold, palladium, copper and nickel will heavily impact the market in the next years. In that respect, alloy plating offers better answers in terms of economic growth and environmental sustainability due to fine tuning composition, morphology and crystallinity [1]. The main categories of alloy compounds are presented and the most important properties for the manufacturing process discussed. Particular attention is devoted to advances in industrial quality control and viable solutions for the reduction of precious metal content in electroplated accessories as well as replacement of cyanide and nickel baths with non-toxic compounds, also considering the commercial needs of wear resistance and aesthetic characteristics of gloss. The electrodeposition of Cu-Sn alloys (bronze) has earned considerable interest thanks to the chemical-physical properties of this alloy, which make it a valid substitute for nickel in fashion industry. Generally, most of the bronze coatings are electroplated starting from baths containing cyanides, and the metal precursors are selected as cyanide compounds. Free cyanide is a well-known problem in the galvanic production cycle both in terms of toxicity for the workers as well as for the environment, and in terms of costs associated with its disposal. The aim of this study is to develop an electroplating bath totally cyanide-free, therefore formulated in an innovative way and which, in addition to being free from this dangerous species, has an eco-friendly support electrolyte. To achieve this goal, methanesulfonic acid (MSA) was chosen as electrolyte, which is biodegradable as part of the natural sulfur cycle. We've studied different formulations in terms of metal precursors, organic additives and their concentrations [2-3]. The same cyanide issue is present also in for the electrodeposition of silver, for this reason the influence of polyethyleneimine (PEI) as additive for cyanide-free silver bath, in combination with 5,5-dimethylhydantoin (DMH) as complexing agent, was studied [4]. Chronoamperometry was used to investigate the electrodeposition mechanism, which is found to be a three-dimensional diffusion-controlled nucleation and growth mechanism, according to the Scharifker–Mostany’s model. Smoother, brighter and blue colored silver deposits are obtained in the presence of PEI in a Hull’s cell test, at low density current. Eventually, the influence of nitrate anion is also investigated. The presence of nitrate increases the range of current density allowing for an effective Ag deposition. We also investigated the use of modulated currents to increase the throwing power of electroplating, obtaining a more uniform deposition and reducing the amount of metals but maintaining the required characteristics. Pulsed current justifies its practical application mainly through its ability to influence the mechanisms of electrocrystallisation, which in turn control the mechanical and physical properties of the deposited metal. By simply adjusting the amplitude and length of the pulses, it is possible to control not only the composition and thickness, in atomic order, of the deposits, but to improve their characteristics such as grain size, porosity and homogeneity [5]. The authors acknowledge Regione Toscana POR CreO FESR 2014-2020 – azione 1.1.5 sub-azione a1 – Bando 1 “Progetti Strategici di ricerca e sviluppo” which made possible the projects “A.C.A.L. 4.0” (CUP 3553.04032020.158000165_1385), “A.M.P.E.R.E.” (CUP 3553.04032020.158000223_1538) and “GoodGalv” (3647.04032020.157000060). References [1] Giurlani, W.; Zangari, G.; Gambinossi, F.; Passaponti, M.; Salvietti, E.; Di Benedetto, F.; Caporali, S.; Innocenti, M. Electroplating for Decorative Applications: Recent Trends in Research and Development. Coatings 2018, 8, 260, doi:10.3390/coatings8080260. [2] Fabbri, L.; Sun, Y.; Piciollo, E.; Salvietti, E.; Zangari, G.; Passaponti, M.; Innocenti, M. Electrodeposition of White Bronzes on the Way to CZTS Absorber Films. J. Electrochem. Soc. 2020 , 167, 022513, doi: 10.1149/1945-7111/ab6c59. [3] Fabbri, L.; Giurlani, W.; Mencherini, G.; De Luca, A.; Passaponti, M.; Piciollo, E.; Fontanesi, C.; Caneschi, A.; Innocenti, M. Optimisation of Thiourea Concentration in a Decorative Copper Plating Acid Bath Based on Methanesulfonic Electrolyte. Coatings 2022, 12, 376, doi:10.3390/coatings12030376. [4] Pizzetti, F.; Salvietti, E.; Giurlani, W.; Emanuele, R.; Fontanesi, C.; Innocenti, M. Cyanide-free silver electrodeposition with polyethyleneimine and 5,5-dimethylhydantoin as organic additives for an environmentally friendly formulation. J. Electroanal. Chem. 2022, 911, 116196, doi:10.1016/j.jelechem.2022.116196. [5] Popov, K.I.; Nikolić, N.D. General Theory of Disperse Metal Electrodeposits Formation. In; Djokić, S.S., Ed.; Modern Aspects of Electrochemistry; Springer US: Boston, MA, 2012; Vol. 54, pp. 1–62 ISBN 978-1-4614-2379-9.
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Wieczorek, Daria, and Dobrawa Kwaśniewska. "Economic aspects of metals recover." Physical Sciences Reviews 3, no. 4 (March 9, 2018). http://dx.doi.org/10.1515/psr-2018-0027.

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Abstract One of the modern economy models is circular economy in which wastes should be considered as resource and used in an efficient and sustainable way. This also concerns to metals included in scraps. However, the need for metal recovery from waste is not only the result of the latest economic trends but also the result of large and constantly changing demand for metals. Shrinking natural sources of metals, concentrations of ores in small number of countries in the world and resulting from this dependence on import, geopolitical situation, new technologies demands are only a few most important determinants that have been changing the structure of the metal market over years. In this chapter, authors focused on the presentation of economic aspects of metal recovery from various sources. The chapter presents the characteristic of metal market elements (supply, demand and price) and changes that took place over decades, underlining the structure of precious and highly desirable metal market elements. Balance between the demand and supply ensures price stability and rationalizes inflation. However, growing demand on many means that secure supply chains, such as recycling and material recovery, are essential to ensure continuity in the supply chain and guarantee unrestricted technological progress and innovation. The data included in this chapter presents also the concentration of different metals and group of metals in wastes pointing that recycling of waste can become one of the possibilities of acquiring missing and critical metals. Metal-laden wastes include a few groups: waste electrical and electronic equipments, catalysts of different application, introduced on chemical, petrochemical or automotive market, galvanic wastes and wastewaters. The profitability assessment of recycling processes is very complicated. Nevertheless cited data shows that profitability of recovery depends on the metal analyzed and the type of waste. It must be underline that an optimized management of wastes is of a great importance for the global economy and allow achieving not only economic but also environmental and social benefits.
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"Supercapacitors by Recycling Technologies: Economic and Environmental Aspects." ARID International Journal for Science and Technology, June 15, 2020, 74–83. http://dx.doi.org/10.36772/arid.aijst.2020.355.

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Nowadays, mankind is in urgent need of energy generation and storage systems. The supercapacitor is one of the important types of storage systems. The high cost of obtaining capacitor electrodes is the reason behind the researchers’ attempts to find low-cost sources. The researchers have prepared a variety of single component and hybrid electrodes by recycling various environmental wastes. The obtained materials exhibited excellent behavior in the storage of electrical energy. In this paper, we reviewed various methods of some metal oxides (such as manganese and cobalt oxides) and carbon nanosphere from environmental wastes. For example, nanoflower manganese dioxide was prepared by electrodeposition of a solution prepared from the dry batteries and gave a specific capacitance of 208.5 F/g. Carbon nanosphere was also prepared by recycling agricultural palm leaves residues and gave a specific capacitance of 309 F/g.
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Dissertations / Theses on the topic "Metal wastes Environmental aspects Victoria"

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Leung, Oi-kwan Winnie, and 梁愛群. "A preliminary study on the Hong Kong external trade of non-ferrous metal waste (and scrap) and other potentially hazardous wastematerials." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1995. http://hub.hku.hk/bib/B31253180.

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Kotze, Petrus Jacobus. "Aspects of water quality, metal contamination of sediment and fish in the Olifants River, Mpumalanga." Thesis, 2012. http://hdl.handle.net/10210/6074.

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M.Sc.
Pollution of the earth is presently one of the most important environmental issues of the world and various attempts, including creation of public awareness have been initiated over the past few years to address this situation. There is especially a global concern about the progressive pollution of valuable freshwater systems which most organisms, including humans, are reliant upon. This includes South Africa's aquatic ecosystems, many of which have been degraded over the past few decades. The Olifants River in Mpumalanga is one of the most threatened river systems in South Africa. It is impacted by various anthropogenic activities, particularly mining in the upper catchment, and urbanisation, industrial and agricultural activities in the upper and lower catchments. Previous investigations have shown that these activities are responsible for the degradation of this river system. The broad objective of this study was to obtain data on water and sediment quality, as well as bioaccumulation of metals in fish via monitoring of the Olifants River. It formed part of a major study concerned with the experimental investigation of lethal and sub-lethal effects of metals on fish physiology, supported by a field investigation into the water quality and metal contamination of the biotic and abiotic components of the Olifants River system. Physico-chemical properties of the water as well as the concentrations of some metals (Al, Fe, Cu, Zn, Ni, Mn, Pb & Cr) in the water and sediment were seasonally investigated. The extent of bioaccumulation of these metals in selected organs/tissues (muscle, gills, liver & skin) of Oreochromis mossambicus and Clarias gariepinus from Loskop Dam (upper catchment) and Mamba Weir, Kruger National Park (lower catchment) was also investigated. High levels of various macro-constituents and metals were detected at many sites in the study area and in many cases they exceeded the guideline limits set for aquatic ecosystems. Localities 2, 3, 6, 8, 10, 12 and 17 were observed to be severely impacted (see Chapter 9- Table 9.1) by elevated concentrations of pollutants influencing variables such as TDS and sulphates. This confirms that these sites are being impacted by mining. This was further confirmed by low pH-values at localities 3, 5, 8, 9, 10 and 12 which indicate on acid mine drainage originating from the many coal mines in the upper catchment of the Olifants River. Nutrient enrichment (elevated levels of phosphates, nitrates and nitrites) occurred at many sites in the catchment but in particular at localities 3, 4, 6, 10, 11, 14, 15 and 17. Point source pollution from sewage treatment works and non-point sources from agricultural runoff and informal settlements are the main contributors to these elevated levels of nutrients. The Selati River, impacted in particular by elevated phosphate levels, is the main contributor to the high nutrient levels detected at locality 17. It is evident from the evaluation of the metal concentrations in the water and sediment (Table 9.2) that most of the sites in the Olifants River catchment are being impacted by metal pollution. Oreochromis mossamhicus and C gariepinus sampled at selected sites in the Olifants River accumulated selected metals in the following order; Fe>Zn>Al>Cr>Ni>Pb>Mn>Cu. Levels were generally high in the liver and gills, while much lower levels were detected in the skin and muscle tissues. Gill tissue is in direct contact with the aqueous environment and therefore gives a good indication of the extent of exposure. Skin tissues usually contained relatively low levels of metals (except for Zn). Although muscle tissues usually accumulated low metal concentrations it is an important tissue to monitor in bioaccumulation studies as it can lead to metal poisoning if contaminated muscle tissues are consumed by humans. Adult specimens were mostly sampled and within this range there was a slight decrease in Cu, Al, Fe, Ni, Mn and Cr concentrations with increasing age. Temporal variation in metal accumulation by fish possibly occurred due to variations in metal concentrations in the water and sediment at a locality. These differences were caused by seasonal variation in climatical conditions (eg. rainfall, temperature), as well as temporal fluctuations of pollutant inputs into the river system. Aquatic organisms at both localities 15 (Loskop Dam) in the upper catchment and 17 (Mamba weir, Kruger National Park) in the lower catchment are at present being chronically exposed to elevated levels of the investigated metals, compared to both the control site and results in literature. The impact of the highly polluted Selati River in the lower catchment was evident in the difference between metal concentrations detected in fish at locality 17, and at locality 19 (Phalaborwa Barrage) upstream of the Olifants-Selati confluence. The present study clearly indicates that the Olifants River is subjected to various sources of pollution which could be detrimental to the health of this aquatic ecosystem. It is recommended (see Chapter 9) that a multi-disciplinary approach including a biomonitoring programme, should be followed to ensure a sustainable freshwater ecosystem.
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Meyer, Izak Johannes. "The use of bioaccumulation in weaver feathers and biomarkers as bioindicators of metal contamination." Thesis, 2008. http://hdl.handle.net/10210/1200.

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M.Sc.
The recognition of the occurrence, importance and effects of contaminants on food chains and ecosystems has led to the development of biomonitoring programmes that use indicator species to estimate the levels in other parts of the ecosystem. There has been an increased awareness of potential pollution of ecosystems in Gauteng, South Africa, because of increased formal and informal urbanization, industrialization and mining activities. It is essential to obtain clear indications of metal pollution cause-effect relationships at ecosystem level in order to carry out effective management of these ecosystems. The objective was to investigate the application of an ecotoxicologically-based investigation of metals in selected bird species as bioindicators of metal pollution of ecosystems in Gauteng. Three passerine species were used, the Southern Masked Weaver (Ploceus velatus), the Red Bishop (Euplectes orix) and the Red-billed Quelea (Quelea quelea). The sites were selected to represent a theoretical pollution gradient from severely contaminated wetlands in the Vaal Triangle, to moderately contaminated wetlands in the Witwatersrand and Pretoria. A nature reserve in North West Province was chosen as reference site. The sites were Rietvlei in Tshwane, Roodekrans and Olifantsvlei in Johannesburg, Holfontein in the Vaal Triangle and Barberspan in North West Province. Two sampling surveys were carried out, one in 2002 and one in 2005. Feathers were collected for metal analyses. Blood samples were collected for biomarker (oxidative stress and DNA damage) and haematological analyses. The samples were digested using the microwave destruction technique. The metal analyses were carried out using ICP-MS. Oxidative stress enzymes (reduced glutathione content and catalase activity) were analysed in plasma samples and DNA damage was evaluated in red blood cells using the average base-pair length comparisontechnique. Haematological studies were done on the blood samples. The results were compared between the sites and surveys. The levels of stress correlated well with the levels of metals in the feathers. Sites with higher metal levels had higher levels of organism stress. Thus the study showed that the feathers can indeed be used in biomonitoring. Internationally there is a trend to incorporate Ecological Quality Objectives (EcoQOs) into legislation, especially when dealing with metal contamination. Within the framework of EcoQOs developed for birds the monitoring of contaminants forms a specific category of EcoQOs. However, due to a lack of available data, Reference and Target Levels still need to be set. The development of EcoQOs is especially important at this stage in South Africa. The recently promulgated National Biodiversity Act (10 of 2004) specifically provides for the preparation of conservation plans for identified ecosystems that are important because of their goods and services that they provide. Since there is no management tool available at present to develop a suitable management plan, the setting of EcoQOs that are in line with international standards and practices will be of immeasurable value to implementing the Act. Feathers from museum specimens were used to determine the Reference Levels for the various metals in the feathers. The Target Levels were calculated from the Reference Levels. These were compared to the Current Levels and the EcoQOs were determined for the metal levels in the feathers in weaver in Gauteng, South Africa.
Prof. V. Wepener
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Watson, Raylene Mullineux. "Metal bioaccumulation in Clarias gariepinus in the Olifants River catchment area." Thesis, 2012. http://hdl.handle.net/10210/7723.

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M.Sc.
A comparative study was undertaken in the Olifants River catchment, to determine the water quality at two dam sites, namely, Bronkhorstspruit Dam (control) and Loskop Dam (polluted) in the upper Olifants River system and two river point, namely, at Mamba and Balule in the Kruger National Park, in the lower Olifants River system. Data was obtained during the physical and chemical analysis of water and sediment samples, and during bioaccumulation studies using Atomic Absorption spectrometry, testing for aluminium, chromium, copper, iron, lead, manganese, nickel, strontium and zinc. These tests were conducted on the liver, skin, muscle and gills of Clarias gariepinus. The information collected from Mamba and Balule, was compared with a previous study carried out primarily in the Kruger National Park by Marx, (1996). The study undertaken by Marx (1996) was carried out during a drought period, which allowed for the comparison with results recorded after flooding during the present study. This current research project therefore allowed for the comparison between two different water sources, namely, that of dams and rivers, and under varying environmental conditions. The Aquatic Toxicity index (ATI) developed by Wepener et al. (1992) was employed to facilitate the comparison between the water physical and chemical parameters that were measured, at each sample site, with a single variable being calculated for each sample site per survey. The water quality (ATI values) at the two control sites namely, Bronkhorstspruit Dam and Balule deteriorated substantially after the floods. High water levels due to the floods had a dilution effect on the concentration of pollutants however, toxicants were washed in from upstream and due to surface runoff. The removal of the purifying reed beds upstream of Balule and at the inflow to Bronkhorstspruit Dam, resulted in the release of latent sludge containing metals and organic pollutants into the water column. The ATI value's obtained for the two control points were similar or even higher than those obtained for the two polluted sites namely at, Loskop Dam and Mamba for the autumn and winter sampling periods. During following surveys the water quality at all four sample sites improved, returning to pre flood values by the last survey in summer, namely reflecting similar values as those recorded by Marx (1996) at Balule, Mamba and Loskop Dam for the same period. Sediment concentrations recorded a similar trend to that for water at all four sample sites throughout the study. The bioaccumulation study indicated that the gill concentrations recorded were generally the highest, followed by the liver concentrations. From this one may deduce that gills were the dominant site for metal absorption by the fish, with the excretion of metals also taking place via this route. Liver concentrations are an indication of the activation of protective _mechanisms in the fish sampled, the high concentrations recorded indicate the high physiological response the fish have had to the various levels of exposure. The low concentrations recorded in the muscle indicates the effectiveness of the liver in the detoxification of the fish, indicating that only limited storage of the various metals tested for took place at this site. Skin concentrations were quite high, these concentrations represent the products of an excretory process, which takes place via the skin. The order of concentrations recorded during the present study, were similar to the orders recorded by Marx, (1996) and other authors, however, the order of the skin and muscle concentrations were often reversed. This may be due to the increased excretion of these metals via the skin, resulting from increased exposure to these metals after the floods. Thus the increased exposure
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5

Marx, Hazel Mary. "Evaluation of a health assessment index with reference to metal bioaccumulation in Clarias gariepinus and aspects of the biology of the parasite Lamproglena clariae." Thesis, 2012. http://hdl.handle.net/10210/5703.

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Abstract:
M.Sc.
The catchment area of the Olifants River has, over a number of years, been exposed to extensive mining, agriculture and urbanisation activities in the Witbank-Middelburg and Phalaborwa regions which has largely contributed to the deterioration of water quality. Of major concern is the influence anthropogenic activities have on the aquatic ecosystem of the Olifants River within the Kruger National Park and how me health of fish residing In these waters is affected. To determine fish health, a biological monitoring method, the Health Assessment Index (H41), was tested for the first time In South Africa. Four surveys were conducted at Mamba and Balule In the Olifants River, Kruger National Park during 1994 (February, May, July and November). An additional survey was conducted in February 1995 at Loskop Dam. Samples of water and sediment were taken for analysis of metals and physical and chemical water parameters. A maximum of 20 Clarias gariepinus fish were sampled at each location. Evaluation of the fish was done according to guidelines set in the HAI and parasite population composition (prevalence, abundance, mean intensity) was determined. Organ and tissue samples including gills, liver, muscle and skin were analysed for the bioaccumulation of chromium, copper, Iron, manganese, nickel, lead, strontium and zinc, using atomic absorption spectrophotomeby. Metal concentrations in the water at Mamba and Balule were within guideline limits, whereas concentrations at Loskop Dam were above guidelines. As reflected by the application of the Aquatic toxicity Index, Loskop Dam presented with the poorest water quality followed by Mamba then Balule. It was found that certain physical and chemical variables namely fluoride, potassium, sulphate and total dissolved solids concentrations at Mamba and Balule were relatively high, particularly during drier months. Metals accumulated in organs and tissues, with the highest concentrations In the gills followed by the liver, skin and muscle. The discriminant analysis, utilising metal bloaccumulation, discriminates between water quality at Mamba and Balule, revealing a 100 % classification probability for each survey. Values obtained In the application of the HAI indicated that variables with good predictor accuracy were plasma protein, all parasites, endoparasites, liver, white blood cell counts, ectoparasites, skin, fins and gills. The discriminant function for the HAI generally Indicated variables similar to those exhibiting high predictor accuracy. The discriminant function showed relatively low classification probability for each survey. In case 1, where separate endo- and ectoparasite variables were Included in the determination of me discriminant function, probability for me entire study ranged between 47.5 % and 84.2 %. In case 2, where endo- and ectoparasite variables were given a refined score rating system, probability ranged between 62.5 % and 100 %. The low classification probability Indicates either the Importance of repetitive testing for this technique or a total departure from it. Results showed that fish populations with higher HAI values are found in water of poorer quality (Mamba), while healthier fish populations i.e. with lower RAI values are found In water of better quality (Balule). Parasite data shows a similar tendency by indicating that ectoparasites are abundant in water of higher quality, while endoparasftes increase in water of poorer quality. The HAI reflects the condition of fish populations in relation to their aquatic environment, therefore, the HA/ gives an indication of water quality and should be used as a first level screening tool. If complemented by a parasite survey, distinguishing between endoand ectoparasites, the results from the HAI will be enhanced.
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6

Barnhoorn, Irene Ellen Jane. "Effects of manganese on the haematology of Oreochromis mossambicus and the bioaccumulation of metals in Labeo umbratus." Thesis, 2012. http://hdl.handle.net/10210/6928.

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Abstract:
M.Sc.
Metal ions have become an increasing source of pollution in the natural waters of South Africa. This phenomenon is related to the rapid industrial, mining and agricultural activity growth along rivers, especially in the Upper catchment of the Olifants River, Mpumalanga. In general, metal ions have - negative effects on the physiology of fish and other aquatic biota in metal polluted waters. In this study. the sublethal effects of, manganese were determined by exposing the freshwater fish, Oreochromis mossambicus, to this metal in an experimental flow-through system. The exposure times were divided in acute (96 hours) and chronic (26 days) exposures, both at 23 ± 1°C. The results obtained showed changes in the general, haematological, metabolic, osmoregulatory variables, as well as the differential white blood cell counts. These changes indicated several effects in the physiology of a mossainblais after sublethal manganese exposure. Significant differences (P < 0.05) were found between the haematological variables of the control and exposed fish. During chronic exposure, an oxygen deficiency developed due to , the epithelial lifting of gill lamellae. As a result of hypoxia the red blood cell numbers, haemoglobin-, haematocrit and lactate concentrations increased to uplift the depleted oxygen situation. The significant differences (P < 0.05) found in the sodium, potassium,. calcium and chloride concentrations are mainly as a result of gill damage. Manganese showed a disruptive influence on the structural organization of the gill. The differential white blood cell counts performed , showed significant fluctuations. This leucocytosis and leucopenia are normal reactions of the fishes’ body against infections of foreign substances, such as metal ions. It was concluded that the general haematology, metabolism, osmoregulation and differential white blood cell counts can, be used as indicators in detecting the effects of sublethal manganese exposure on fish.
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7

Wepener, Victor. "Metal ecotoxicology of the Olifants River in the Kruger National Park and the effect thereof on fish haematology." Thesis, 2012. http://hdl.handle.net/10210/7334.

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Abstract:
D.Phil.
By virtue of its position on the eastern border of South Africa, the Kruger National Park (KNP) receives the flow of six main riven, of which the greater part of the specific catchment areas are situated upstream from the park itself. The Olifants River has the largest catchment area both in size and in proportion of catchment area beyond the park boundary. Increased competing demand for water by the urban, industrial, mining and agricultural sectors within the catchment boundaries of the Olifants River has focused attention on the ecological water requirements of the river. Of particular concern was the high degree of mineralisation of the Olifants River due to mining activities on the western boundary of the KNP. When one considers the demand for water by the Kruger National Park it is evident that water is required for more than one use, i.e. for potable use, game watering and ecosystem (aquatic and riparian) maintenance. In order to facilitate proper water quality management it is necessary to develop a comprehensive water quality management plan for the river. The development of such a plan requires a thorough understanding of the fate and effects of pollutants in the environment. It is furthermore important to have reliable information on the trends and status of important water quality determinants in these systems. This study was therefore aimed at investigating the metal ecotoxicology of the lower Olifants River and the Selati River, a tributary of the Olifants River which flows through the Phalaborwa area. Water quality is a driving variable in aquatic ecosystems. Full assessment of water quality of the Olifants River included evaluation of the physical, chemical and biological attributes of the system. The difference between the physical/chemical and biological attributes is that the former provide an instantaneous and often specific assessment of the water quality, whereas the latter integrate changes in the system over time. Water and sediment samples were collected bi-monthly from February 1990 to February 1992 at six stations along the lower Olifants River, one in the Selati River and one in the Letaba River. At each of these sites physical and chemical water quality characteristics were measured. Two metal bioaccumulation indicator species, Labeo rosae and Oreochromis mossambicus, were also sampled during the same period at three stations in the Olifants River and at the Selati River sampling station. Two additional surveys were undertaken to reference sites in the KNP (i.e. Pioneer Dam, and Nhlanganini Dam) during February 1992 and April 1992 respectively. Tissue samples (muscle, gill, liver, gonads, fat and blood) were collected and analysed for Cr, Cu, Fe, Mn, Ni, Pb and Zn using atomic absorption spectrophotometry. The routine monitoring of chemical and physical water quality attributes produces large quantities of complex data which are often difficult to interpret. To reduce the complexity, data may be standardised and summarised into an index. The Aquatic Toxicity Index (ATI) that was developed Metal Ecotoxicology in the Olifants River it Summary during this study presented the water quality of all the sampling stations, during each survey as a single value. This value reflected the water quality's suitability-for-use by fish at the different sampling stations. The ATI showed definite temporal and spatial trends in water quality in the Olifants River. The Selati River was the main contributing factor to the poor water quality measured in the Olifants River within the KNP. This was due to high TDS, metal and fluoride concentrations. Deterioration of the water quality was experienced during flood conditions when the turbidities and total metal concentrations increased. The water quality generally increased between summer and winter surveys (February to June). Bioindicators are species used to quantify biologically available level of metals in the aquatic ecosystem. These organisms take up metals from the ambient water and from food, and the concentrations in their tissues (or changes in concentrations) provide a time integrated measure of metal bioavailability. Temporal bioavailability of metals in the tissues of the bioindicators showed similar trends to the water quality. Highest metal concentrations were measured in fish tissue samples collected during flood conditions (December 1990) and during low-flow conditions (June to October). This was attributed to increased exposure due to metal adsorption to suspended sediments during the flood conditions and to increased ambient metal concentrations during lowflow conditions. The distribution of metals in tissues varied based on the uptake, depuration and metabolism strategies for each metal. In general the gill tissue bioaccumulated the highest metal concentrations, with only Cu and Fe occurring in higher concentrations in liver tissue. Significant positive correlation's were found between bioaccumulation in muscle tissue and the other tissues: Space-bulking and time-bulking of results were carried out to elucidate spatial bioaccumulation patterns. The highest bioaccumulation of Cu, Pb and Ni were recorded in samples from the Selati River, whereas Zn and Cr concentrations were the highest in the Olifants River. An equilibrium partitioning (EP) technique was used to integrate bioaccumulation data and metal concentrations in different phases of the water and sediment and produce specific Cu and Zn criteria for the Olifants and Selati rivers. Although there is a multitude of data available for Cu and Zn toxicity and BCF's, the quality criteria produced during this study, for the first time, made use of results obtained under local conditions. The results from bioaccumulation studies carried out in the field can not provide information regarding the potential effects or the risks the metals may pose to the exposed organisms. Therefore the susceptibility of the organisms to metal contamination can be determined using laboratory studies. Physiology is toxicology's closest relative and contributes markedly in assessing the toxicological risk of metals. Bioassays were conducted to determine the uptake kinetics, acid-base disturbances and haematological effects of a metal mixture containing Cu, Fe and Zn on Tilapia sparrmanii. The effects of the individual metals (Cu, Fe and Zn) and different Metal Ecotoxicology
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8

Nussey, Gail. "Metal ecotoxicology of the Upper Olifants River at selected localities and the effect of copper and zinc on fish blood physiology." Thesis, 2012. http://hdl.handle.net/10210/7393.

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Abstract:
D.Phil.
The entire Olifants . River Catchment is subjected to increasing afforestation, agricultural, domestic, mining, industrial, irrigation and urbanisation activities. These activities have a profound effect on the water quality of the river and its tributaries. This is cause for concern for the water users in the upper catchment, and because the Kruger National Park, one of its downstream water users, is extremely dependent on water of a satisfactory quality to sustain its various ecosystems. It is therefore vitally important to determine to what extent activities in the Upper Catchment of the Olifants River (Mpumalanga), especially in the Witbank and Middelburg areas, influence the water quality of the river. Point sources of pollution in the upper reaches include mining and industrial activities as well as water care works located at various points along the river. These were addressed in a Water Research Commission Project (No. 608/1/97) titled "Lethal and sublethal effects of metals on the physiology of fish: An experimental approach with monitoring support". Although sixteen localities were chosen for the initial project, this study only focussed around the metal ecotoxicology at two localities (Steenkool Spruit and Witbank Dam) in the upper catchment and the effect of metals (copper and zinc) on fish blood physiology. In aquatic ecosystems water quality is an important variable and full assessment of water quality, of Steenkool Spruit (locality 3) and Witbank Dam (locality 7), included evaluation of the chemical, physical and biological characteristics at each of the localities. Water and sediment samples were collected seasonally during the study period, February 1994 to May 1995, and the chemical and physical water quality variables were measured. During the study period three metal bioaccumulation indicator species, Labeo umbratus, Clarias gariepinus and Labeo capensis, were captured from which tissue (gills, liver, muscle and skin) samples were collected. These samples as well as water and sediment samples, were analysed for aluminium, chromium, copper, iron, manganese, nickel, lead and zinc concentrations, using atomic absorption spectrophotometry. In the past routine monitoring of chemical and physical water quality characteristics left scientists and managers with a sizeable pool of data which is often difficult but not impossible to interpret. To standardise and summarise this collection of data an aquatic toxicity index (ATI), WATER2 was developed by Wepener et at (1992). The present study attempted to expand and refine WATER2, which has resulted in the establishment of a new ATI, RAUWater.
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Books on the topic "Metal wastes Environmental aspects Victoria"

1

United States. Environmental Protection Agency. Office of Solid Waste and Emergency Response and United States. Environmental Protection Agency. Office of Research and Development, eds. Considerations for evaluating the impact of metals partitioning during the incineration of contaminated soils from Superfund sites. Cincinnati, OH: U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Remedial Response, 1992.

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Wahl, George. Considerations for evaluating the impact of metals partitioning during the incineration of contaminated soils from Superfund sites. Cincinnati, OH: U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Remedial Response, 1992.

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Wahl, Georg. Considerations for evaluating the impact of metals partitioning during the incineration of contaminated soils from Superfund sites. Cincinnati, OH: U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Remedial Response, 1992.

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Wahl, George. Considerations for evaluating the impact of metals partitioning during the incineration of contaminated soils from Superfund sites. Cincinnati, OH: U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Remedial Response, 1992.

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Iaconianni, Frank J. Destruction of PCBs: Environmental applications of alkali metal polyethylene glycolate complexes. Cincinnati, Ohio: U.S. Environmental Protection Agency, Hazardous Waste Engineering Research Laboratory, 1985.

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Litt, Robert D. Trace metal retention when firing hazardous waste in a fluidized-bed incinerator. Research Triangle Park, NC: U.S. Environmental Protection Agency, Air and Energy Engineering Research Laboratory, 1985.

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Arnold, Karen. Household battery recycling and disposal study. St. Paul, MN: Minnesota Pollution Control Agency, 1991.

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Vandenbosch, Mary. Household battery report: To the Legislative Commission on Waste Management. St. Paul (1350 Energy Lane, St. Paul 55108): Minnesota Office of Waste Management, 1991.

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Desborough, George A. Mineralogical characteristics and acid-neutralizing potential of drill core samples from eight sites considered for metal-mine related waste repositories in northern Jefferson, Powell, and Lewis and Clark counties, Montana. [Denver, CO]: U.S. Dept. of the Interior, U.S. Geological Survey, 1998.

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Desborough, George A. Preliminary characterization of acid-generating potential and toxic metal solubility of some abandoned metal-mining related wastes in the Boulder River headwaters, northern Jefferson County, Montana. [Denver, CO]: U.S. Geological Survey, 1997.

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Conference papers on the topic "Metal wastes Environmental aspects Victoria"

1

Heep, Walter. "The ZWILAG Interim Storage Plasma Plant: Technology to Handle Operational Waste From Nuclear Plants." In The 11th International Conference on Environmental Remediation and Radioactive Waste Management. ASMEDC, 2007. http://dx.doi.org/10.1115/icem2007-7242.

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The first processing of low level radioactive wastes from Swiss nuclear power plants marks the successful completion of commissioning in March 2004 of a treatment facility for low and intermediate level radioactive wastes, which is operated with the help of plasma technology. The theoretical principles of this metallurgy-derived process technology are based on plasma technology, which has already been used for a considerable period outside of nuclear technology for the production of highly pure metal alloys and for the plasma synthesis of acetylene. The commercial operation of the Plasma Plant owned by Zwischenlager Wuerenlingen AG (ZWILAG) has also enabled this technology to be used successfully for the first time in the nuclear field, especially in compliance with radiation protection aspects. In addition to a brief presentation of the technology used in the plant, the melting process under operating conditions will be explained in more detail. The separation factors attained and volume reductions achieved open interesting perspectives for the further optimisation of the entire process in the future.
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Oskolkov, Borys Ya, Yuri A. Neretin, Valeryi P. Saliy, Valeryi A. Seyda, and Vyascheslav V. Fomin. "Problems of Radioactive Waste Management at Chornobyl Nuclear Power Plant (ChNPP)." In ASME 2003 9th International Conference on Radioactive Waste Management and Environmental Remediation. ASMEDC, 2003. http://dx.doi.org/10.1115/icem2003-4827.

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According to the assessments the overall amount of radioactive waste (RAW) to be reprocessed and buried at the Chornobyl NPP site amounts to 1,696,738 m3 (without regard for reactor metal structures, dismantling of building structures and plan constructions, and the Unit Shelter building). The overall activity of radioactive waste are evaluated at 1,640,504.64 ΤBq. The RAW management activities are implemented at the Chornoby1 NPP within the frame of several programs of different hierarchy including the State Comprehensive Program for RAW Management in Ukraine, Integrated Program of RAW Management at the Chornoby1 NPP Shutdown Stage and Transformation of the Unit Shelter into an Ecologically Safe System. At the present time a number of key RAW management facilities are being constructed within the frame of the international aid to Ukraine. They are the Liquid Radioactive Waste Plant and Solid Radioactive Waste Reprocessing Complex. As of now, the issues concerning RAW utilization at the Unit Shelter are resolved at a conceptual level. There has not practical decision in relation to a geologic facility. The complexity and scale of ChNPP RAW management problems will require significant efforts of both Ukraine and the whole world community to solve these issues. The task related to removal and final burial of accumulated and generating radioactive waste is one of the main aspects of decommissioning activities at any nuclear power plant. RAW management work is the most important and complicated work performed at the Chornoby1 NPP. The specific features of ChNPP RAW management are as follows: • Variety of RAW generation sources, their types, physical and chemical properties. • Large amount of radioactive wastes which already exist and those generated in the decommissioning process. • Presence of disorganized RAW characterized by wide spatial distribution within the Unit Shelter and at the plant site. • Need to apply a very wide spectrum of various RAW management techniques depending on their location and type. • Need in developing unique techniques to manage special types of RAW located at the site (fuel containing masses of the Unit Shelter). • Large amount and variety of facilities required for RAW final storage. • Absence of reliable and serviceable instrumental procedures and necessary equipment to define RAW properties for RAW separation and classification. • Ecological peculiarities of RAW management within the Chornoby1 zone. • Multiphase decontamination and restoration processes resulting in RAW formation. • Need in integrating RAW management problems at the ChNPP and within the Chornoby1 Exclusion Zone taken as whole. • Long time period required for implementing the whole program of RAW management at the ChNPP. • Large quantity of people involved in RAW management process (local and foreign participants, different organization operated by various departments).
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