Journal articles: 'Metal pesticide matrix'

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Dey, Priyadarshini, Anushree Malik, Abhishek Mishra, Dileep Kumar Singh, Martin von Bergen, and Nico Jehmlich. "Mechanistic insight to mycoremediation potential of a metal resistant fungal strain for removal of hazardous metals from multimetal pesticide matrix." Environmental Pollution 262 (July 2020): 114255. http://dx.doi.org/10.1016/j.envpol.2020.114255.

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Mao, Xuejin, Weiming Xiao, Yiqun Wan, Zhanming Li, Dongmei Luo, and Hongshun Yang. "Dispersive solid-phase extraction using microporous metal-organic framework UiO-66: Improving the matrix compounds removal for assaying pesticide residues in organic and conventional vegetables." Food Chemistry 345 (May 2021): 128807. http://dx.doi.org/10.1016/j.foodchem.2020.128807.

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Mareri, B., E. Kitur, and P. Obade. "Bioaccumulation of zinc, lead, cadmium in water hyacinth, hippo grass and papyrus reed as water quality indicator in River Kisat in Kisumu County, Kenya." African Journal of Pure and Applied Sciences 2, no. 2 (June 30, 2021): 100–107. http://dx.doi.org/10.33886/ajpas.v2i2.213.

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River Kisat in Kenya is increasingly being polluted serving as a sink for waste receiving effluent from sewerage, industrial waste and agricultural pesticide residues leading to heavy metal contamination. This has led to the contamination of the aquatic ecosystem and water used by communities for consumption and farming. Little information is available on the bio-indicative aspects of water quality using bioaccumulation factor by macrophytes. This study aimed at determining concentrations of Zn, Pb and Cd in water, (Eichhornia crassipes (water hyacinth), Vossia cuspidata (hippo grass), Cyperus papyrus (papyrus reed) and bioaccumulation factors (BAF) in River Kisat, Kisumu County. This was determined following laboratory standard procedures using Atomic Absorption Spectrophotometer (AAS). Results showed mean concentrations (mg/L) of Cd (Below detectable limit), Zn (0.2 -0.15) and Pb (0.03-0.03) in water. Mean values were within allowable WHO drinking water limits except for Pb which was above acceptable limits. Zn recorded highest accumulated levels in E. crassipes (72.43mg/L), C. papyrus (70.13mg/L) and V. cuspidate (71.03mg/L). E. crassipes was observed to bioaccumulate the highest concentration of the heavy metals with C. papyrus bioaccumulating the lowest (E. crassipes > V. cuspidata> C. papyrus). Pearson matrix correlation analysis showed positive significant correlations (r = 0.621; p = 0.027) between Zn and Pb in water and the macrophytes which reflected a common source of pollution and indication of accumulation. BAF recorded for all macrophytes ranged from 2.45 to 6.85, above value of 1, indicating significant bioaccumulation for Zn and Pb. The findings from this study showed higher concentrations of Zn and Pb in the macrophytes in comparison to the water in River Kisat with BAF values >1 indicating bioaccumulation which represented poor water quality. The study recommends local authorities employ monitoring processes with incorporation of BAF as a water quality indicator where low metal concentrations in water are recorded, introduce penalties for polluters and sensitize local inhabitants on detrimental health effects of heavy metal and avoid use of River Kisat water for agricultural activities.

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Santos Barreto, Alysson, Paula de Cássia da Silva Andrade, Jéssica Meira Farias, Adalberto Menezes Filho, Gilberto Fernandes de Sá, and Severino Alves Júnior. "Characterization and application of a lanthanide-based metal-organic framework in the development and validation of a matrix solid-phase dispersion procedure for pesticide extraction on peppers (Capsicum annuum L.) with gas chromatography-mass spectrometr." Journal of Separation Science 41, no. 7 (January 26, 2018): 1593–99. http://dx.doi.org/10.1002/jssc.201700812.

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Kaur, Pawan, Rita Choudhary, Anamika Pal, Chanchal Mony, and Alok Adholeya. "Polymer - Metal Nanocomplexes Based Delivery System: A Boon for Agriculture Revolution." Current Topics in Medicinal Chemistry 20, no. 11 (June 1, 2020): 1009–28. http://dx.doi.org/10.2174/1568026620666200330160810.

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Metal nanoparticles are well known for their antimicrobial properties. The use of metalbased nanoparticles in the agricultural field has considerably increased globally by both direct and indirect means for the management of plant diseases. In this context, the development of controlled delivery systems for slow and sustained release of metal nanoparticles is crucial for prolonged antimicrobial activity. Polymers have emerged as a valuable carrier for controlled delivery of metal nanoparticles as agrochemicals because of their distinctive properties. The most significant benefits of encapsulating metal nanoparticles in a polymer matrix include the ability to function as a protector of metal nanoparticles and their controlled release with prolonged efficacy. This review focuses on loading strategies and releasing behavior of metal nanoparticles in the polymer matrix as antimicrobial agents for plant diseases. The Polymer-metal nanocomplexes (PMNs) comprise a biocompatible polymeric matrix and metal nanoparticles as active components of an antimicrobial agent, pesticides and plant growth regulators used to enhance the crop productivity.

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Aquino, Adriano, Jordana Alves Ferreira, Sandro Navickiene, Kaline A. Wanderley, Gilberto F. de Sá, and Severino A. Júnior. "Investigating the Potential of Metal-Organic Framework Material as an Adsorbent for Matrix Solid-Phase Dispersion Extraction of Pesticides During Analysis of Dehydrated Hyptis pectinata Medicinal Plant by GC/MS." Journal of AOAC INTERNATIONAL 95, no. 5 (September 1, 2012): 1338–42. http://dx.doi.org/10.5740/jaoacint.sge_aquino.

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Abstract Metal-organic frameworks aluminum terephthalate MIL-53 and Cu-benzene-1,3,5-tricarboxylate (BTC) were tested for extraction of pyrimethanil, ametryn, dichlofluanid, tetraconazole, flumetralin, kresoxim-methyl, and tebuconazole from the medicinal plant Hyptis pectinata, with analysis using GC/MS in the selected ion monitoring mode. Experiments carried out at different fortification levels (0.1, 0.5, and 1.0 μg/g) resulted in recoveries in the range 61 to 107% with RSD values between 3 and 12% for the metal-organic framework materials. Detection and quantification limits ranged from 0.02 to 0.07 and 0.05 to 0.1 μg/g, respectively, for the different pesticides studied. The method developed was linear over the range tested (0.04–20.0 μg/g), with correlation coefficients ranging from 0.9987 to 0.9998. Comparison of MIL-53 and Cu-BTC with C18-bonded silica showed good performance of the MIL-53 metal-organic framework as a sorbent for the pesticides tested.

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Scott, J. A., and A. M. Karanjkar. "Immobilized biofilms on granular activated carbon for removal and accumulation of heavy metals from contaminated streams." Water Science and Technology 38, no. 8-9 (October 1, 1998): 197–204. http://dx.doi.org/10.2166/wst.1998.0807.

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Biofilms consisting of a matrix of exopolysaccharide and microorganisms developed over granular activated carbon (GAC) enhance metal uptake from solution several times more than that achieved by GAC alone. By specifically employing GAC, there is also the opportunity of developing biofilm/GAC systems that can both entrap metals and also adsorb, and ultimately degrade, polluting organic residues such as pesticides. Targets for this type of process could be dump site leachates, mine tailings and other industrial wastes. The conditions under which the biofilm is developed, including pH and temperature have, therefore, been studied in terms of subsequent influence on metal bisorption.

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Djeddi, Hamssa, Saliha Kherief Nacereddine, Dounia Keddari, and Fatima-Zohra Afri-Mehennaoui. "Teneurs Des Éléments Traces Métalliques Cu, Zn Et Pb Des Sédiments Du Barrage Béni Haroun (Nord-Est De l’Algérie)." European Scientific Journal, ESJ 14, no. 15 (May 31, 2018): 269. http://dx.doi.org/10.19044/esj.2018.v14n15p269.

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This paper focuses on evaluating the degree of three metal pollution (Cu, Zn and Pb) in the sediments of Béni Haroun dam, located in northeastern of Algeria. For this reason, the superficial sediments were sampled at five stations, and the samples were taken at different seasons of the year. The results show low Cu and Zn levels which reflect natural conditions in relation to the area of geological nature. It also highlights the presence of Pb contamination (2.29 to 91.86µg/g). This result was also confirmed by various indices, including the geoaccumulation index (Igeo) and the contamination factor (FC). The Igeo values for Pb show moderate contamination of the Bge2 and Bge3 stations. CF values indicate moderate to considerable contamination for most stations by Pb. However, low or absent of Zn contamination was noted in all stations except for the Bge5. The correlation matrix and the PCA between all metal elements indicates that they were derived from similar sources. The contamination sources would probably establish a significant relationship between runoff and the erosion of agricultural lands. It is therefore an anthropogenic metal pollution related to agricultural activity using fertilizers and pesticides.

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Xu, Yi, Felix Y. H. Kutsanedzie, Md Mehedi Hassan, Jiaji Zhu, Huanhuan Li, and Quansheng Chen. "Functionalized hollow Au@Ag nanoflower SERS matrix for pesticide sensing in food." Sensors and Actuators B: Chemical 324 (December 2020): 128718. http://dx.doi.org/10.1016/j.snb.2020.128718.

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Karpachev, V., N. Voropaeva, A. Tkachev, V. Muhin, V. Varlamov, and Oleg L. Figovsky. "Innovative Application Technology for Challenging Inducers of Disease Resistance in Spring Rape in (Nano) Chips." International Letters of Chemistry, Physics and Astronomy 42 (December 31, 2014): 36–44. http://dx.doi.org/10.56431/p-x1h39m.

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The present level of development of agricultural science has led to the emergence of a new method of plant protection, it is based on improving the immune potential of plants using elicitors, but not on the destruction of pathogens using pesticides. We have studied the effect of disease resistance inducers based on chitosan, organic acids and other substances with elicitor activity, being part of (nano) chips of different composition (matrix carrier - modified natural minerals, activated carbons, nanotubes, graphene, etc..) for pre-sowing seed treatment and for foliar fertilizing. We have studied their influence on growth, development, the incidence of rape plants, the quantity and quality of their crop. We have also determined the efficiency of (nano) chips depending upon their nature and carrier matrix composition.

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Du, Dan, Xi Huang, Jie Cai, and Aidong Zhang. "Amperometric detection of triazophos pesticide using acetylcholinesterase biosensor based on multiwall carbon nanotube–chitosan matrix." Sensors and Actuators B: Chemical 127, no. 2 (November 15, 2007): 531–35. http://dx.doi.org/10.1016/j.snb.2007.05.006.

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Xiong, Jincheng, Huixia Zhang, Linqian Qin, Shuai Zhang, Jiyue Cao, and Haiyang Jiang. "Magnetic Fluorescent Quantum Dots Nanocomposites in Food Contaminants Analysis: Current Challenges and Opportunities." International Journal of Molecular Sciences 23, no. 8 (April 7, 2022): 4088. http://dx.doi.org/10.3390/ijms23084088.

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The presence of food contaminants can cause foodborne illnesses, posing a severe threat to human health. Therefore, a rapid, sensitive, and convenient method for monitoring food contaminants is eagerly needed. The complex matrix interferences of food samples and poor performance of existing sensing probes bring significant challenges to improving detection performances. Nanocomposites with multifunctional features provide a solution to these problems. The combination of the superior characteristics of magnetic nanoparticles (MNPs) and quantum dots (QDs) to fabricate magnetic fluorescent quantum dots (MNPs@QDs) nanocomposites are regarded as an ideal multifunctional probe for food contaminants analysis. The high-efficiency pretreatment and rapid fluorescence detection are concurrently integrated into one sensing platform using MNPs@QDs nanocomposites. In this review, the contemporary synthetic strategies to fabricate MNPs@QDs, including hetero-crystalline growth, template embedding, layer-by-layer assembly, microemulsion technique, and one-pot method, are described in detail, and their advantages and limitations are discussed. The recent advances of MNPs@QDs nanocomposites in detecting metal ions, foodborne pathogens, toxins, pesticides, antibiotics, and illegal additives are comprehensively introduced from the perspectives of modes and detection performances. The review ends with current challenges and opportunities in practical applications and prospects in food contaminants analysis, aiming to promote the enthusiasm for multifunctional sensing platform research.

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Akhtar, Naseem, Muhammad Izzuddin Syakir Ishak, Showkat Ahmad Bhawani, and Khalid Umar. "Various Natural and Anthropogenic Factors Responsible for Water Quality Degradation: A Review." Water 13, no. 19 (September 27, 2021): 2660. http://dx.doi.org/10.3390/w13192660.

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Recognition of sustainability issues around water resource consumption is gaining traction under global warming and land utilization complexities. These concerns increase the challenge of gaining an appropriate comprehension of the anthropogenic activities and natural processes, as well as how they influence the quality of surface water and groundwater systems. The characteristics of water resources cause difficulties in the comprehensive assessment regarding the source types, pathways, and pollutants behaviors. As the behavior and prediction of widely known contaminants in the water resources remain challenging, some new issues have developed regarding heavy metal pollutants. The main aim of this review is to focus on certain essential pollutants’ discharge from anthropogenic activities categorized based on land-use sectors such as industrial applications (solid/liquid wastes, chemical compounds, mining activities, spills, and leaks), urban development (municipal wastes, land use practices, and others), and agricultural practices (pesticides and fertilizers). Further, important pollutants released from natural processes classified based on climate change, natural disasters, geological factors, soil/matrix, and hyporheic exchange in the aquatic environment, are also discussed. Moreover, this study addresses the major inorganic substances (nitrogen, fluoride, and heavy metals concentrations). This study also emphasizes the necessity of transdisciplinary research and cross-border communication to achieve sustainable water quality using sound science, adaptable legislation, and management systems.

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Zhang, Long, Xianfeng Tan, Hongnian Chen, Yalin Liu, and Zhaojie Cui. "Effects of Agriculture and Animal Husbandry on Heavy Metal Contamination in the Aquatic Environment and Human Health in Huangshui River Basin." Water 14, no. 4 (February 12, 2022): 549. http://dx.doi.org/10.3390/w14040549.

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Huangshui River (HSR) is the mother river of Qinghai province. Croplands and grasslands cover more than 76% of the total area, and highland agriculture and animal husbandry are the dominant industries. The use of pesticides, fertilizers, and feed additives increases the risk of heavy metal (HM) contamination. In this study, the concentration of HMs in the main stream and tributaries of HSR were investigated. The Positive Matrix Factorization model was used for source apportionment, and Health Risk Assessment method was used to assess the human health risks. To further analyze the effect of agriculture and animal husbandry on aquatic environment and human health, we considered agriculture and animal husbandry as two factors in the source apportionment process, defined the effect of the factors, established the calculation formula, and quantified the effects. The results show that the overall situation of aquatic environment in HSR is good; natural processes, traffic tail gas and atmospheric deposition, agricultural planting, industrial wastewater discharge, and animal husbandry are the main sources of HMs in the water. These HMs present noncarcinogenic and carcinogenic risks for infants. A total effect of agricultural and animal husbandry on HMs or HI in HSRB is approximately 20%, while on TCR is 40%. However, the effects of agriculture on the hazard quotient of arsenic, carcinogenic risk of nickel and lead, and that of animal husbandry on carcinogenic risk of cadmium were significant. This study can provide a theoretical basis for local managers of agriculture and animal husbandry to perform their work effectively.

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Bayandina, E. A., G. G. Glebov, M. S. Kuyukina, and I. B. Ivshina. "Resistance of <i>Rhodococcus ruber</i> biofilms to CuO nanoparticles depending on exopolymer matrix composition." Acta Biomedica Scientifica 7, no. 5-1 (December 7, 2022): 100–109. http://dx.doi.org/10.29413/abs.2022-7.5-1.11.

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Background. The widespread use of copper oxide nanoparticles (CuO NPs) increases their release into the environment, which leads to accumulation in trophic chains. Bacterial biofilms are more resistant to physico-chemical factors compared to planktonic cells due to an exopolymer matrix (EPM) consisting of polysaccharides, proteins, lipids and nucleic acids. Rhodococcus actinobacteria are promising for environmental biotechnology due to biodegradation of petroleum products, pesticides and other organic pollutants, as well as bioaccumulation of heavy metals. The aim. To investigate effects of CuO NPs on the viability of Rhodococcus ruber IEGM 231 cells in biofilms and the dynamics of EPM components. Methods. R. ruber biofilms were grown on microscopy cover glass with CuO NPs and EPM components were studied using confocal laser scanning microscopy (CLSM) by differentiating staining with LIVE/DEAD to determine the number of living and dead cells, Nile Red for lipids, FITC for proteins and Calcofluor White for betapolysaccharides. Results. It was found that R. ruber biofilms grown in a mineral medium with1.0 vol.% n-hexadecane are more resistant to CuO NPs compared to biofilms growing in a rich culture medium (meat-peptone broth). This was due to more intensive EPM formation, which plays a major role in protecting cells from the bactericidal action of nanometals. A weak stimulating effect of a low (0.001 g/l) concentration of CuO NPs on biofilm formation was registered. Dynamics and localization of main EPM components were monitored during prolonged (24–72 h) biofilm cultivation with CuO NPs. When exposed to high (0.01–0.1 g/l) concentrations of CuO NPs, a consistently high lipid content and an increase in concentrations of polysaccharides and proteins were revealed. Conclusion. Understanding the complex interaction mechanisms of nanometals and biofilms will contribute to the development of effective biocatalysts based on immobilized bacterial cells. Also, the obtained data can be used to combat unwanted biofilms with the help of metal nanoparticles.

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de Jesus, Jemmyson Romário, Kaline Amaral Wanderley, Severino Alves Júnior, and Sandro Navickiene. "Evaluation of a novel metal-organic framework as an adsorbent for the extraction of multiclass pesticides from coconut palm (Cocos nucifera L.): An analytical approach using matrix solid-phase dispersion and liquid chromatography." Journal of Separation Science 40, no. 16 (July 17, 2017): 3327–34. http://dx.doi.org/10.1002/jssc.201700501.

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Nguyen, Truong Giang, Cao Cuong Ngo, Tat Thinh Do, and Trong Dan Nguyen. "Nghiên cứu chế tạo viên xử lý nước trong tình huống khẩn cấp." Tạp chí Khoa học và Công nghệ nhiệt đới, July 2019. http://dx.doi.org/10.58334/vrtc.jtst.n18.09.

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In this study, a tablet for emergency water treatment was fabricated, with components: coagulant-precipitant (aluminum sulfate), pH regulator (sodium bicarbonat), primary colloidal flocculant (carboxylmethyl cellulose), secondary colloidal flocculant (cationic polyacrylamide), agglomeration matrix (microcrystalline cellulose), adsorbent of heavy metal ions and pesticide content (zeolite), disinfectant-sanitizer (sodium dichlorisocyanurate), each tablet weighs about 570 - 590 mg, treating for 1 liter of river or lake water. Water after treatment meets National technical regulation on drinking water quality - QCVN 01:2009/BYT, which is issued by Ministry of Public Health, Vietnam.

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Li, Yan, Zhiqiang Xu, Hanhan Ren, Dong Wang, Jian Wang, Zhen Wu, and Pengjie Cai. "Spatial Distribution and Source Apportionment of Heavy Metals in the Topsoil of Weifang City, East China." Frontiers in Environmental Science 10 (April 29, 2022). http://dx.doi.org/10.3389/fenvs.2022.893938.

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The distribution of heavy metals in topsoil can have a significant impact on human health. A total of 1, 556 samples were collected from the topsoil of Weifang, China. Various indices, including the pollution index (PI), the Nemerow integrated pollution index (PN), and the potential ecological risk index (RI), were used to analyze the heavy metal pollution levels. The sources of heavy metals were analyzed using the positive matrix factorization (PMF) model. The results are as follows: (1) the ecological risk level of Cu, Pb, Zn, Ni, Cr, and As in the study area is relatively safe, but the ecological risk level of Cd and Hg is relatively high, leading to an increase in the ecological risk level of heavy metals in the study area and (2) the PMF results show that there are six main sources of the eight heavy metals. Cr and Ni come from soil parent material and nonferrous metal industrial activities; As is closely related to fossil fuel (coal)-related industrial activities; Cu originated from diesel fuel-related transportation and agricultural machinery activities; Pb is derived from gasoline transportation activities; Hg is closely related to the application of pesticides in agricultural production; Cd and Zn originated from organic fertilizers used in agricultural activities.

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Fawzy, Ahmad, Hasna Muthi' Nurhanifa, and Ismiralda Oke Putranti. "Potential Delayed Healing in Wounds with Scabies Comorbidity: A Review about Immunological State and Oxidative Stress in Scabies Infestation." International Journal Of Medical Science And Clinical Research Studies 03, no. 05 (May 31, 2023). http://dx.doi.org/10.47191/ijmscrs/v3-i5-52.

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Scabies is a highly contagious skin disease caused by the human itch mite Sarcoptes scabiei var. hominid. Having scabies infestation coexisting in the same human body with a wound potentially lead to delayed wound healing. We constituted this literature review discussing wound healing in relation woth immunological state and oxidative stress in scabies infestation using information from literatures obtained from Google Scholar and PubMed. The immune response to scabies infection involves multiple layers of defense mechanisms, including the skin's defense mechanisms, T-cells, keratinocytes, and cytokines. Scabies mites can trigger upregulation of pro-inflammatory cytokines interleukins-1α (IL-1α) and interleukins-1β (IL-1β), which play a critical role in the early phases of wound healing by promoting the recruitment of immune cells and stimulating the production of growth factors and extracellular matrix proteins. Scabies mite infestation also triggers a sustained release of reactive oxygen species (ROS) from neutrophils which later becomes an oxidative stress leading to delayed healing and chronic inflammation. Topical treatment for scabies usually involves pesticide substances which, despite its therapeutic effect, have side effect of triggering ROS production. Comprehending the immunological state and oxidative stress in scabies infestation is essential in planning proper management for every wound with scabies comorbidity.

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Singh, Himshweta, and Gaurav Pant. "Phytoremediation: Low input-based ecological approach for sustainable environment." Applied Water Science 13, no. 3 (February 28, 2023). http://dx.doi.org/10.1007/s13201-023-01898-2.

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AbstractIn today's fast-paced society, environmental breakdown is an ecumenical concern. This dilemma is tangled up with the unaccountable anthropogenic activities that are causing significant public health issues. Because of the rapid pace of development, urban soil and water pollution is progressively acting as a sink for a variety of contaminants, including heavy metals, pesticides, petroleum waste, radioactive moieties, etc. Phytoremediation is a low-cost, high-efficient method of extracting or removing pollutants from the environment. Water is transpired by green plants in order to move nutrients from the soil to the site of photosynthesis. During this process, pollutants in the water are also taken up and sequestered, digested, or drained out. This technique has many benefits over conventional approaches which is aesthetically pleasing and has long-term applicability. Phytoremediation could be a viable option to decontaminate heavy metal-polluted sites, particularly when the biomass produced during the process could be economically utilized in the form of bioenergy. Depending on the method used and nature of the contaminant involved, phytoremediating areas where metals and other inorganic compounds exist may utilize one of several techniques as discussed in the present study which are phytodegradation, phytoextraction, phytostimulation, phytostabilization, phytofiltration, phytovolatalization, etc. Phytoremediation is an emerging technology that employs the natural, biological, chemical, or physical processes of plants to remove, detoxify, or immobilize environmental contaminants in a growth matrix. This approach is hence an innovative tool with a great potential to decontaminate soil and water. Phytoremediation is a promising technique for ensuring the sustainability of future generations and reducing pollution.

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Journal articles on the topic 'Metal pesticide matrix'

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