Academic literature on the topic 'Metal-Organic Polyhedron'

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Journal articles on the topic "Metal-Organic Polyhedron"

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Lian, Ting-Ting, Shu-Mei Chen, Fei Wang, and Jian Zhang. "Metal–organic framework architecture with polyhedron-in-polyhedron and further polyhedral assembly." CrystEngComm 15, no. 6 (2013): 1036–38. http://dx.doi.org/10.1039/c2ce26611c.

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Kim, Hyehyun, Minhak Oh, Dongwook Kim, et al. "Single crystalline hollow metal–organic frameworks: a metal–organic polyhedron single crystal as a sacrificial template." Chemical Communications 51, no. 17 (2015): 3678–81. http://dx.doi.org/10.1039/c4cc10051d.

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Single crystalline hollow MOFs with cavity dimensions on the order of several micrometers and hundreds of micrometers were prepared using a metal–organic polyhedron single crystal as a sacrificial hard template.
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Park, M., Y. Zou, S. Hong, and M. S. Lah. "A designed metal-organic framework based on a metal-organic polyhedron." Acta Crystallographica Section A Foundations of Crystallography 64, a1 (2008): C474. http://dx.doi.org/10.1107/s0108767308084766.

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Wu, Jian, Jing-Wen Xu, Wei-Cong Liu, et al. "Designed metal–organic framework based on metal–organic polyhedron: Drug delivery." Inorganic Chemistry Communications 71 (September 2016): 32–34. http://dx.doi.org/10.1016/j.inoche.2016.06.023.

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Zou, Yang, Mira Park, Seunghee Hong, and Myoung Soo Lah. "A designed metal–organic framework based on a metal–organic polyhedron." Chemical Communications, no. 20 (2008): 2340. http://dx.doi.org/10.1039/b801103f.

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Guo, Xiangyu, Shanshan Xu, Yuxiu Sun, Zhihua Qiao, Hongliang Huang, and Chongli Zhong. "Metal-organic polyhedron membranes for molecular separation." Journal of Membrane Science 632 (August 2021): 119354. http://dx.doi.org/10.1016/j.memsci.2021.119354.

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Li, Mu, Mingxin Zhang, Yuyan Lai, et al. "Solvated and Deformed Hairy Metal–Organic Polyhedron." Journal of Physical Chemistry C 124, no. 28 (2020): 15656–62. http://dx.doi.org/10.1021/acs.jpcc.0c05544.

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Gong, Ya-Ru, Zhong-Min Su, and Xin-Long Wang. "A polyoxometalate-based metal–organic polyhedron constructed from a {V5O9Cl} building unit with rhombicuboctahedral geometry." Acta Crystallographica Section C Structural Chemistry 74, no. 11 (2018): 1243–47. http://dx.doi.org/10.1107/s2053229618010689.

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The design and construction of metal–organic polyhedra has received much attention by chemists due to the intriguing diversity of architectures and topologies that can be achieved. There are several crucial factors which should be considered for the construction of metal–organic polyhedra, such as the starting materials, reaction time and temperature, solvent and suitable organic ligands. Recently, polyoxometalates (POMs), serving as secondary building units to construct POM-based metal–organic polyhedra, have been the subject of much interest. The title compound, dodecakis(dimethylammonium) o
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Mallick, Arijit, Bikash Garai, David Díaz Díaz, and Rahul Banerjee. "Hydrolytic Conversion of a Metal-Organic Polyhedron into a Metal-Organic Framework." Angewandte Chemie 125, no. 51 (2013): 14000–14004. http://dx.doi.org/10.1002/ange.201307486.

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Mallick, Arijit, Bikash Garai, David Díaz Díaz, and Rahul Banerjee. "Hydrolytic Conversion of a Metal-Organic Polyhedron into a Metal-Organic Framework." Angewandte Chemie International Edition 52, no. 51 (2013): 13755–59. http://dx.doi.org/10.1002/anie.201307486.

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Dissertations / Theses on the topic "Metal-Organic Polyhedron"

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Yan, Yong. "Metal-organic polyhedral framework materials for hydrogen storage." Thesis, University of Nottingham, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.555387.

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This thesis describes the design, synthesis and characterisation of a series of novel metal-organic frameworks constructed from Cu(II) paddlewheels and polydentate aromatic carboxylate ligands. Gas sorption applications of these porous materials have been studied, with an emphasis on hydrogen storage. The effects of cage wall functionalisation within the frameworks, internal BET surface areas and pore volumes, and open Cu(II) sites on H2 adsorption by these materials are investigated. Chapter 1 introduces the current status of H2 storage in metal-organic framework materials. Extended metal-org
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Albalad, Alcalá Jorge. "Post-Synthetic Modification of Metal-Organic Frameworks (MOFs) and Polyhedra (MOPs)." Doctoral thesis, Universitat Autònoma de Barcelona, 2019. http://hdl.handle.net/10803/670090.

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Aquesta Tesi ha estat dedicada al disseny i implementació de noves tècniques de modificació post-sintètica (PSM) aplicades a material metal·loorgànics, principalment polímers de coordinació (CPs), xarxes metal·loorgàniques (MOFs) i políedres metal·loorgànics (MOPs), per tal de modificar les seves propietats fisicoquímiques a nivells inaccessibles a través de metodologies comuns de síntesi directa. La Tesi comença oferint una breu recapitulació bibliogràfica del camp dels materials metal·loorgànics, des dels seus inicis fins a la seva aplicació actual i perspectives de futur. Aquest capí
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Stoeck, Ulrich, Irena Senkoska, Volodymyr Bon, Simon Krause, and Stefan Kaskel. "Assembly of metal–organic polyhedra into highly porous frameworks for ethene delivery." Royal Society of Chemistry, 2015. https://tud.qucosa.de/id/qucosa%3A36046.

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Two new mesoporous metal–organic frameworks (DUT-75 and DUT-76) with exceptional ethene uptake were obtained using carbazole dicarboxylate based metal–organic polyhedra as supermolecular building blocks. The compounds have a total pore volume of 1.84 and 3.25 cm³ gˉ¹ and a specific BET surface area of 4081 and 6344 m² gˉ¹, respectively, and high gas uptake at room temperature and high pressure.
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Meng, Wenjing. "Metal-organic polyhedra : subcomponent self-assembly, structural properties, host-guest behavior and system chemistry." Thesis, University of Cambridge, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.610719.

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Perry, John Jackson. "Hierarchical complexity in metal-organic materials : from layers to polyhedra to supermolecular building blocks." [Tampa, Fla] : University of South Florida, 2009. http://purl.fcla.edu/usf/dc/et/SFE0003227.

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Tonigold, Markus [Verfasser]. "Novel copper- and cobalt-based metal-organic polyhedra and frameworks : synthesis, structure, properties and applications / Markus Stefan Tonigold." Ulm : Universität Ulm. Fakultät für Naturwissenschaften, 2012. http://d-nb.info/1019563249/34.

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Tessarolo, J. "Design and synthesis of metallo-supramolecular architectures towards advanced materials." Doctoral thesis, Università degli studi di Padova, 2017. http://hdl.handle.net/11577/3422402.

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Self-assembly is a key step to obtain functional supramolecular objects towards complex matter. With self-assembly of metal ions and well-designed polytopic ligands is possible to access a particular class of supramolecular functional materials: metal-organic polygons and polyhedra endowed with confined space, and functional properties deriving from the building blocks. Herein, firstly is presented a system that in solution self-assembles in a collection of Cu(II) based boxes: a rhomboid and a triangle in dynamic equilibrium. This system is a small constitutional dynamic library (CDL). The des
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Stoeck, Ulrich, Simon Krause, Volodymyr Bon, Irena Senkovska, and Stefan Kaskel. "A highly porous metal–organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2014. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-138864.

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A highly porous metal–organic framework Cu2(BBCDC) (BBCDC = 9,9′-([1,1′-[b with combining low line]iphenyl]-4,4′-diyl)[b with combining low line]is(9H-[c with combining low line]arbazole-3,6-[d with combining low line]i[c with combining low line]arboxylate) (DUT-49) with a specific surface area of 5476 m2 g−1, a pore volume of 2.91 cm3 g−1, a H2 excess uptake of 80 mg g−1 (77 K, 50 bar), a CO2 excess uptake of 2.01 g g−1 (298 K, 50 bar) and an exceptionally high excess methane storage capacity of 308 mg g−1 (298 K, 110 bar) was obtained using an extended tetratopic linker<br>Dieser Beitrag ist
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Stoeck, Ulrich, Simon Krause, Volodymyr Bon, Irena Senkovska, and Stefan Kaskel. "A highly porous metal–organic framework, constructed from a cuboctahedral super-molecular building block, with exceptionally high methane uptake." Royal Society of Chemistry, 2012. https://tud.qucosa.de/id/qucosa%3A27787.

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A highly porous metal–organic framework Cu2(BBCDC) (BBCDC = 9,9′-([1,1′-[b with combining low line]iphenyl]-4,4′-diyl)[b with combining low line]is(9H-[c with combining low line]arbazole-3,6-[d with combining low line]i[c with combining low line]arboxylate) (DUT-49) with a specific surface area of 5476 m2 g−1, a pore volume of 2.91 cm3 g−1, a H2 excess uptake of 80 mg g−1 (77 K, 50 bar), a CO2 excess uptake of 2.01 g g−1 (298 K, 50 bar) and an exceptionally high excess methane storage capacity of 308 mg g−1 (298 K, 110 bar) was obtained using an extended tetratopic linker.<br>Dieser Beitrag is
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Vetromile, Carissa Marie. "Probing Molecules in Confined Space." Scholar Commons, 2011. http://scholarcommons.usf.edu/etd/3393.

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Despite the plethora of information regarding cellular crowding and its importance on modulating protein function the effects of confinement on biological molecules are often overlooked when investigating their physiological function. Recently however, the encapsulation of biomolecules in solid state matrices (NafionTM, sol-gels, zirconium phosphate,etc.) has increased in importance as a method for examining protein conformation and dynamics in confined space as well as novel applications in biotechnology. Biotechnological applications include, but are not limited to, bioremediation, biosensor
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Book chapters on the topic "Metal-Organic Polyhedron"

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"The Polytopes of the Higher Dimension in Physics and Chemistry and Construction of Spaces of the Higher Dimension." In The Classes of Higher Dimensional Polytopes in Chemical, Physical, and Biological Systems. IGI Global, 2022. http://dx.doi.org/10.4018/978-1-7998-8374-6.ch009.

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Polytopes of the highest dimension of molecules of compounds of inorganic and organic chemistry are considered on specific examples. It is shown that they all have dimensions greater than three. They may include polytopes of a known shape, discussed in previous chapters, but in general they differ significantly from the standard shapes. These include linear and nonlinear chains of metal atoms with ligands, closed chains of metal atoms with ligands, clusters with ligands and a metal polyhedral backbone. A class of polytopic prismahedrons (a special type of polytopes of higher dimension) is considered, from which parallelotopes of higher dimension are formed, which are necessary for constructing n-dimensional spaces, using them to create extended nanomaterials based on clusters of chemical compounds.
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"Condensation of WO42- Polyhedra Units on Layered Rare Earth Hydroxides Nanosheets: Hierarchical Channels and Heavy Metal Adsorption." In Metal-Organic Framework Composites - Volume I. Materials Research Forum LLC, 2019. http://dx.doi.org/10.21741/9781644900291-6.

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