Academic literature on the topic 'Metal-mediated'

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Journal articles on the topic "Metal-mediated"

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Arnold, Frances H., and Ji-Hu Zhang. "Metal-mediated protein stabilization." Trends in Biotechnology 12, no. 5 (May 1994): 189–92. http://dx.doi.org/10.1016/0167-7799(94)90081-7.

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Boyarskiy, Vadim P., Nadezhda A. Bokach, Konstantin V. Luzyanin, and Vadim Yu Kukushkin. "Metal-Mediated and Metal-Catalyzed Reactions of Isocyanides." Chemical Reviews 115, no. 7 (March 5, 2015): 2698–779. http://dx.doi.org/10.1021/cr500380d.

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Kukushkin, Vadim Yu, and Armando J. L. Pombeiro. "Metal-mediated and metal-catalyzed hydrolysis of nitriles." Inorganica Chimica Acta 358, no. 1 (January 2005): 1–21. http://dx.doi.org/10.1016/j.ica.2004.04.029.

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Hwang, Shyh-Lung, Pouyan Shen, Tzen-Fu Yui, and Hao-Tsu Chu. "Metal-sulfur-COH-silicate fluid mediated diamond nucleation in Kokchetav ultrahigh-pressure gneiss." European Journal of Mineralogy 15, no. 3 (June 10, 2003): 503–11. http://dx.doi.org/10.1127/0935-1221/2003/0015-0503.

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R. Cook, Gregory. "Transition Metal-Mediated Kinetic Resolution." Current Organic Chemistry 4, no. 8 (August 1, 2000): 869–85. http://dx.doi.org/10.2174/1385272810004080869.

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Cook, G. R. "Transition Metal-Mediated Kinetic Resolution." Current Organic Chemistry 4, no. 8 (August 1, 2000): 2. http://dx.doi.org/10.2174/1385272003376021.

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Sabatino, Valerio, V. B. Unnikrishnan, and Gonçalo J. L. Bernardes. "Transition metal mediated bioorthogonal release." Chem Catalysis 2, no. 1 (January 2022): 39–51. http://dx.doi.org/10.1016/j.checat.2021.12.007.

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Silver, S., and T. K. Misra. "Plasmid-Mediated Heavy Metal Resistances." Annual Review of Microbiology 42, no. 1 (October 1988): 717–43. http://dx.doi.org/10.1146/annurev.mi.42.100188.003441.

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Hernández, Laura P., Almudena González-Álvarez, Ana I. Oliva, and Pablo Ballester. "Metal-mediated multiporphyrin functional assemblies." Journal of Porphyrins and Phthalocyanines 13, no. 04n05 (April 2009): 481–93. http://dx.doi.org/10.1142/s1088424609000693.

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During the last ten years, our research group has been applying metal-mediated self-assembly processes to the construction of multiporphyrin functional assemblies. The construction of well-defined and discrete supramolecular structures resulting from self-assembly requires the use of multiple and separated connections operating in one or more closed loops. Consequently, the great majority of the multiporphyrin assemblies that we have prepared are of cyclic nature. We have placed special emphasis not only on the characterization in solution of the formed assemblies but also on the thermodynamic characterization of the assembly process and in the assessment of cooperativity. Finally, we also present examples in which functionality has been derived from the three-dimensional structures of multicomponent assemblies.
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Garnovskii, D. A., and Vadim Yu Kukushkin. "Metal-mediated reactions of oximes." Russian Chemical Reviews 75, no. 2 (February 28, 2006): 111–24. http://dx.doi.org/10.1070/rc2006v075n02abeh001188.

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Dissertations / Theses on the topic "Metal-mediated"

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Howgego, David Christopher. "Metal-mediated molecular machines." Thesis, University of Edinburgh, 2013. http://hdl.handle.net/1842/7619.

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Nature abounds with ingenious nanoscopic machines employed to carry out all of the requisite tasks that collectively contribute to the molecular basis of life. This thesis focuses primarily on a sub-set known as "molecular walkers" which can perambulate along intracellular molecular motorways carrying out such essential tasks as vesicle transport and muscle contraction. A summary of these incredible natural motors is presented in Chapter I along with a review of the artificial small-molecule mimics reported to date. When elucidating a set of design principles for synthetic analogues, inspiration is taken from the mechanism of the biological bipedal motor protein kinesin with a focus on potential strategies to enable directional walking. Transition metal-ligand chemistry is utilised as one such strategy in Chapter II through the governance of walker-track interactions in the design, synthesis and operation of a bimetallic molecular biped. A palladium(II) moiety is selectively and intramolecularly stepped between pyridine-derivative binding sites in the track using a thermal stimulus in the presence of a coordinating solvent. Acid-base manipulations facilitate directional stepping by means of an energy ratchet mechanism allowing the track to do work on the biped unit and ultimately drive it away from equilibrium. The potential of malleable transition metal binding-event energetics is explored further in Chapter III with the design and synthesis of a platinum(II)-complexed [2]rotaxane. Thermodynamic and kinetic stimuli are investigated as means to mediate selective shuttling of a Pt-complexed macrocycle between two ligand binding sites in the thread. The substitution pattern of the ligands and the kinetic stability of the metal-ligand bonds afford exceptional metastability to the co-conformers of the molecule in the absence of an external stimulus providing the possibility for long-term information storage. In Chapter IV, a novel macrocycle is used to demonstrate the chemical orthogonality of acid-mediated hydrazone exchange with respect to the palladium(II) stepping mechanism described in Chapter II and show that two such motifs can be independently addressed within a single molecule. These linkages are then utilised as mutually exclusive chemo-selective switches to individually operate opposing feet in an unprecedented first-generation small-molecule walker-track system.
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Butters, Christopher. "Metal mediated organic transformations." Thesis, University of Bath, 1995. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.260230.

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Trussell, Stephen John. "Transition metal-mediated organosilicon chemistry." Thesis, Imperial College London, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.298136.

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Lindup, Richard J. "Metal-mediated borylation of fluorocarbons." Thesis, University of York, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.434017.

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Baxter, John S. "Transition metal mediated annulation reactions." Thesis, University of Bristol, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324243.

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Warner, Benjamin Peter. "Mechanisms of metal-mediated cyclizations." Thesis, Massachusetts Institute of Technology, 1995. http://hdl.handle.net/1721.1/36008.

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Eriksson, Ludvig. "Transition Metal Mediated Transformations of Carboranes." Doctoral thesis, Uppsala University, Organic Chemistry, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-3324.

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This thesis describes the use of copper and palladium to mediate transformations of carboranes, especially p-carborane.

1-(1-p-carboranyl)-N-methyl-N-(2-butyl)-3-isoquinolinecarboxamide, a carborane containing analogue of the peripheral benzodiazepine receptor (PBR) ligand PK11195, has been synthesised. A key step in the reaction is the copper (I) mediated coupling of p-carborane with ethyl 1-bromo-isoquinoline-3-carboxylate.

p-Carborane has been arylated on the 2-B-atom in high yields, using the Suzuki–Miyaura reaction. Thus the reaction between 2-I-p-carborane and various arylboronic acids [1-naphthyl-, phenyl-, 4-MeO-C6H4-, 3-CH3CONH-C6H4-, 4-NC-C6H4-, 3-NO2-C6H4-], gave the corresponding 2-aryl-p-carboranes in DME solution when reacted in the presence of cesium fluoride and the catalytic Pd2(dba)3–dppb system. Under the same conditions, the boron-boron bond forming reaction of two p-carboranylboronic esters (2-[(pinacolato)boron]-p-carborane and 2-[(neopentyl glycolato)boron]-p-carborane) was also shown feasible.

p-Carborane has been vinylated on the 2-B-atom in high yields by use of the Heck reaction. The coupling between 2-I-p-carborane and various styrenes [4-H-, 4-C6H4-, 4-Cl , 4-Br-, 4-NO2-, 4-CH3O- and 4 CH3 ] resulted in the formation of the correspondingtrans-β-(2-B-p-carboranyl) styrene in DMF solution when reacted in the presence of silver phosphate and the palladacycle Herrmann´s catalyst. The reaction was shown to proceed at higher rate with electron rich than with electron deficient olefins.

The feasibility of palladium-catalysed isotopic exchange of an iodinated closo-carborane with a radioisotope of iodine has been studied. 2-I-p-carborane was selected as a model compound. It was shown, that such isotopic exchange is possible and provides a high yield (83 ± 4.2 %) during 40 min long reaction. The reaction conditions were optimised, and it was demonstrated that presence of the tetra n-butylammonium hydrogensulphate is important in order to stabilise catalyst and provide reproducibility of labelling. In this work we have modified the methodology and extended the application to a wider range of iodinated carboranes. By the use of Herrmann’s catalyst in toluene at 100 °C this [125I]-iodide labelling could be improved and extended. 2-I-p- 9-I-m-, 9-I-o-, 3-I-o-carborane, 1-phenyl-3-I-o-carborane and 1,2-diphenyl-3-I-o-carborane could be [125I]-iodide labelled in high to excellent yields within 5 minutes.This reported palladium catalyzed radio-iodination of the uncharged closo-carboranes might find use in pharmacokinetic studies of carborane derivatives.

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McAlonan, Helena M. "Transition metal mediated approaches to pumiliotoxins." Thesis, Queen's University Belfast, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.318792.

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Shaw, Graham Andrew. "Solvent mediated synthesis of metal chalcogenides." Thesis, University College London (University of London), 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326065.

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Hunter, Rupert Alexander. "Transition metal mediated synthesis of heterocycles." Thesis, University of Southampton, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.402426.

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Books on the topic "Metal-mediated"

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Tanaka, Ken, ed. Transition-Metal-Mediated Aromatic Ring Construction. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118629871.

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Khosravi, Ezat, Yusuf Yagci, and Yuri Savelyev, eds. New Smart Materials via Metal Mediated Macromolecular Engineering. Dordrecht: Springer Netherlands, 2009. http://dx.doi.org/10.1007/978-90-481-3278-2.

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Fergani, Hadi Khamis. Metal-atom mediated chemical transformations: The reaction of group 13 metal atoms with arenes. Sudbury, Ont: Laurentian University, Chemistry and Biochemistry Department, 1999.

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Evangelos, Manias, Malliaras George G, and Symposium A, "Defect Mediated Phenomena in Ordered Polymers" (2002 : Boston, Mass.), eds. Polymer/metal interfaces and defect mediated phenomena in ordered polymers: Symposia held December 2-6, 2002, Boston, Massachusetts, U.S.A. Warrendale, Pa: Materials Research Society, 2003.

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I. Radical Cyclizations Mediated by Transition Metal Hydrides II. Study toward the Total Synthesis of Pluraflavin A III. Cytoprotective Polyacetylenes Inspired by Panaxytriol. [New York, N.Y.?]: [publisher not identified], 2012.

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Tanaka, Ken. Transition-Metal-Mediated Aromatic Ring Construction. Wiley & Sons, Limited, John, 2013.

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Tanaka, Ken. Transition-Metal-Mediated Aromatic Ring Construction. Wiley & Sons, Incorporated, John, 2013.

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Tanaka, Ken. Transition-Metal-Mediated Aromatic Ring Construction. Wiley & Sons, Incorporated, John, 2013.

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Metal Mediated Template Synthesis of Ligands. World Scientific Publishing Company, 2004.

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Tanaka, Ken. Transition-Metal-Mediated Aromatic Ring Construction. Wiley & Sons, Incorporated, John, 2013.

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Book chapters on the topic "Metal-mediated"

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Ciofi-Baffoni, Simone. "Metal-Mediated Interactions." In NMR of Biomolecules, 196–203. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2012. http://dx.doi.org/10.1002/9783527644506.ch10.

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Chen, Chuan-Feng, and Yun Shen. "Metal-Mediated Reactions." In Helicene Chemistry, 87–115. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-53168-6_5.

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Chalker, Justin M. "Metal-Mediated Bioconjugation." In Chemoselective and Bioorthogonal Ligation Reactions, 231–70. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527683451.ch8.

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Farrell, Nicholas. "Metal-Mediated Antibiotic Action." In Transition Metal Complexes as Drugs and Chemotherapeutic Agents, 168–82. Dordrecht: Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-011-7568-5_8.

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Hong, Jing, Olesya A. Kharenko, Mikhail V. Tsurkan, and Michael Y. Ogawa. "Metal-Mediated Peptide Assembly." In ACS Symposium Series, 167–82. Washington, DC: American Chemical Society, 2009. http://dx.doi.org/10.1021/bk-2009-1012.ch011.

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Shimizu, Makoto, Iwao Hachiya, and Junji Inanaga. "Metal Iodides-Mediated Reaction." In Iodine Chemistry and Applications, 329–51. Hoboken, NJ: John Wiley & Sons, Inc, 2014. http://dx.doi.org/10.1002/9781118909911.ch18.

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Pandey, Vidya Dhar. "Cyanobacteria-Mediated Heavy Metal Remediation." In Agro-Environmental Sustainability, 105–21. Cham: Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-49727-3_6.

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Herndon, James Wallace. "Utilization of Transition-Metal Carbenoids." In Transition-Metal-Mediated Aromatic Ring Construction, 425–53. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118629871.ch17.

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Nishibayashi, Yoshiaki. "Cycloaromatization via Transition Metal-Cumulenylidenes." In Transition-Metal-Mediated Aromatic Ring Construction, 549–69. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118629871.ch21.

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Gandon, Vincent. "Cobalt-Mediated [2 + 2 + 2] Cycloaddition." In Transition-Metal-Mediated Aromatic Ring Construction, 1–35. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118629871.ch1.

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Conference papers on the topic "Metal-mediated"

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Sun, Yugang, and Younan Xia. "Polymer-mediated synthesis of metal nanostructures." In Optical Science and Technology, SPIE's 48th Annual Meeting, edited by Guozhong Cao, Younan Xia, and Paul V. Braun. SPIE, 2003. http://dx.doi.org/10.1117/12.504822.

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Shahbazyan, Tigran V., and Vitaliy N. Pustovit. "Surface-plasmon-mediated energy transfer near metal nanoparticles." In SPIE NanoScience + Engineering, edited by Mark I. Stockman. SPIE, 2011. http://dx.doi.org/10.1117/12.893232.

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Su, Ding, Tian Yanhong, and He Xiaobin. "Polyol synthesis of silver nanowires with metal ions mediated." In 2013 14th International Conference on Electronic Packaging Technology (ICEPT). IEEE, 2013. http://dx.doi.org/10.1109/icept.2013.6756688.

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Naik, Gururaj V., Alex A. Welch, and Jennifer A. Dionne. "Hot-carrier mediated photon upconversion in metal/semiconductor heterostructure." In CLEO: QELS_Fundamental Science. Washington, D.C.: OSA, 2016. http://dx.doi.org/10.1364/cleo_qels.2016.fw1b.1.

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Zhang, Minchang, Trevor Allen, and Ray DeCorby. "Admittance-matched plasmon-mediated tunneling through dielectric-metal-dielectric multilayers." In Optical Interference Coatings. Washington, D.C.: OSA, 2013. http://dx.doi.org/10.1364/oic.2013.ta.8.

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Yang, Ziming, Yiju Liao, and Alexandria Aspin. "Dissolved metal-mediated organic carbon transformations in oceanic hydrothermal systems." In Goldschmidt2022. France: European Association of Geochemistry, 2022. http://dx.doi.org/10.46427/gold2022.9958.

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Le Guevel, Xavier, Benjamin Musnier, Karl D. Wegner, Maxime Henry, Agnes Desroches-Castan, Ute Resch-Genger, Sabine Bailly, Yves Usson, Véronique Josserand, and Jean-Luc Coll. "Surface chemistry-mediated metal nanoclusters for in vivo shortwave infrared imaging." In Colloidal Nanoparticles for Biomedical Applications XVI, edited by Marek Osiński and Antonios G. Kanaras. SPIE, 2021. http://dx.doi.org/10.1117/12.2577451.

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Ciattoni, Alessandro, Andrea Marini, and Claudio Conti. "Phase-matching-free parametric oscillation mediated by monolayer transition metal dichalcogenides." In Nonlinear Optics. Washington, D.C.: OSA, 2019. http://dx.doi.org/10.1364/nlo.2019.nf1a.2.

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Ono, Akira, Itaru Okamoto, Hideo Urata, Hidetake Torigoe, Hisao Saneyoshia, Jiro Kondo, and Yoshiyuki Tanaka. "Syntheses and characterizations of DNA duplexes having metal ion mediated base pairs." In XVIth Symposium on Chemistry of Nucleic Acid Components. Prague: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2014. http://dx.doi.org/10.1135/css201414014.

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Hayashi, Gosuke, and Akimitsu Okamoto. "Metal-mediated reactions to detect 5-methylcytosine and 5-hydroxymethylcytosine in DNA." In XVIth Symposium on Chemistry of Nucleic Acid Components. Prague: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2014. http://dx.doi.org/10.1135/css201414088.

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Reports on the topic "Metal-mediated"

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Baker, R. T. Tandem metal-mediated synthesis. Office of Scientific and Technical Information (OSTI), December 1998. http://dx.doi.org/10.2172/350837.

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Sen, Ayusman. Transition metal mediated transformations of small molecules. Office of Scientific and Technical Information (OSTI), March 2017. http://dx.doi.org/10.2172/1346019.

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Sen, A. [Transition metal mediated transformations of small molecules]. Office of Scientific and Technical Information (OSTI), January 1992. http://dx.doi.org/10.2172/6915678.

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Sen, A. Transition metal mediated transformations of small molecules. Office of Scientific and Technical Information (OSTI), May 1990. http://dx.doi.org/10.2172/6971891.

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Sen, A. [Transition metal mediated transformations of small molecules]. Progress report. Office of Scientific and Technical Information (OSTI), October 1992. http://dx.doi.org/10.2172/10188286.

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Nicholas, Kenneth M. Transition metal-mediated thermal and photochemical carbon dioxide conversion. Office of Scientific and Technical Information (OSTI), January 2000. http://dx.doi.org/10.2172/765234.

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Dentinger, Paul M., and Srikant Pathak. Highly specific electronic signal transduction mediated by DNA/metal self-assembly. Office of Scientific and Technical Information (OSTI), November 2003. http://dx.doi.org/10.2172/918237.

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Gmeiner, William H. Metal Occupancy of Zinc Finger Motifs as Determinants for Zn2+-Mediated Chemosensitization of Prostate Cancer Cells. Fort Belvoir, VA: Defense Technical Information Center, December 2013. http://dx.doi.org/10.21236/ada596731.

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Nicholas, Kenneth M. Transition Metal-Mediated Thermal and Photochemical Carbon Dioxide Conversion. Final report, March 15, 1995-March 14, 1998. Office of Scientific and Technical Information (OSTI), November 1995. http://dx.doi.org/10.2172/761340.

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Nicholas, K. M. Transition metal-mediated thermal and photochemical carbon dioxide activation. Progress report, March 15, 1990--March 14, 1991. Office of Scientific and Technical Information (OSTI), December 1990. http://dx.doi.org/10.2172/10172147.

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