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Relevant bibliographies by topics / Metal atom chemistry

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Academic literature on the topic 'Metal atom chemistry'

Author: Grafiati

Published: 4 June 2021

Last updated: 2 February 2022

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Journal articles on the topic "Metal atom chemistry"

1

Boudalis, Athanassios K., Vassilios Nastopoulos, Aris Terzis, Catherine P. Raptopoulou, and Spyros P. Perlepes. "Reaction between Yttrium Nitrate and 2,2':6',2"-Terpyridine (terpy) in MeCN: Preparation, Crystal Structures and Spectroscopic Characterization of [Y (NO3)3(terpy)(H2O )] and [Y(NO3)3(terpy)(H2O )] · terpy · 3 MeCN." Zeitschrift für Naturforschung B 56, no. 2 (2001): 122–28. http://dx.doi.org/10.1515/znb-2001-0202.

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Abstract The reaction of Y(NO3)3 · 5H2O and 2,2':6',2"-terpyridine (terpy) in MeCN leads to [Y(N03 )3(terpy)(H2O )] (1) and [Y(N03 )3(terpy)(H2O )] terpy-3MeCN (2) in good yields depending on the isolation conditions. The structures of both complexes were determined by single-crystal X-ray crystallography. The YIII atom in 1 is 9-coordinate and ligation is provided by one terdentate terpy molecule, two chelating nitrates, one monodentate nitrate and one terminal H2O molecule; the coordination polyhedron about the metal may be viewed as a tricapped trigonal prism. The YIII atom in 2 is 10-coordinate and its coordination sphere consists of three nitrogen atoms from the terdentate terpy, six oxygen atoms from the three chelating nitrates (one of them being “anisobidentate”) and one oxygen atom from a terminal H2O molecule; the polyhedron about the metal may be viewed as a distorted sphenocorona. The interstitial terpy is strongly hydrogen-bonded to the O atom of the coordinated H2O molecule to form [Y(NO3 )3(terpy)(H20)] ··· terpy pairs. The new complexes were characterized by IR and 1H NMR spectroscopies. The YIII/NO3-/terpy chemistry is compared to the already well-developed LnIII/NO3-/terpy chemistry (Ln = lanthanide).

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Melnik, Milan, Markku Rafael Sundberg, and Rolf Uggla. "Analysis of crystallographic and structural data of polymeric iron-alkaline metal complexes." Main Group Metal Chemistry 34, no. 5-6 (2011): 93–126. http://dx.doi.org/10.1515/mgmc-2012-0900.

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Abstract The present review covers almost 100 polymeric MFe (M=Li, Na, K, Rb, and Cs) compounds. The metal atoms of group 1 as partners with iron atom build up complex polymeric chains. The iron atoms are found in the oxidation states 0, +2, and +3, of which the oxidation state +3 prevails. The coordination number of the iron atom ranges from 2 to 10 (sandwiched). The coordination sphere about the main group 1 metals varies, ranging from tetrahedral to mostly trigonal bipyramid. There are also higher coordination numbers involved, namely, from 6 to 10. The most common ligand atoms are oxygen and nitrogen. There are three compounds displaying distortion isomerism. Several relationships between structural parameters are found and discussed.

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Cabeza, Javier A., Ignacio del Río, Pablo García-Álvarez, and Daniel Miguel. "Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine Novel coordination modes for 2-imidopyridines." Canadian Journal of Chemistry 84, no. 2 (2006): 105–10. http://dx.doi.org/10.1139/v05-228.

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The hexanuclear ruthenium cluster [Ru6(µ3-H)2(µ-H)2(µ4-κ2-ampy)2(CO)14] (1) and the octanuclear one [Ru8(µ-H)(µ4-κ2-ampy)3(µ3-κ2-Hampy)(µ-CO)2(CO)15] (2) have been prepared by treating [Ru6(µ3-H)2(µ5-κ2-ampy)(µ-CO)2(CO)14] with 2-amino-6-methylpyridine (H2ampy) in decane at reflux temperature. Their metal atoms are supported by ligands that derive from the activation of one (complex 2) or both NH bonds (complexes 1 and 2) of the H2ampy amino fragment. Both contain at least one ampy ligand featuring an unprecedented coordination type: the imido N atom caps a triangle of metal atoms while the pyridine nitrogen is attached to an additional metal atom. One of the ampy ligands of cluster 2 also displays another unprecedented coordination type: it caps a distorted square of metal atoms through the imido N atom while the pyridine nitrogen is attached to one of the atoms included in that square.Key words: ruthenium, cluster compounds, amido ligands, imido ligands.

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Zhao, Lili, Chaoqun Chai, Wolfgang Petz, and Gernot Frenking. "Carbones and Carbon Atom as Ligands in Transition Metal Complexes." Molecules 25, no. 21 (2020): 4943. http://dx.doi.org/10.3390/molecules25214943.

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This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL2 as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (σ and π) donation to the metal atom [M]⇇CL2. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR3 → [M]-CR2 → [M]-CR → [M]-C. This review includes some work on uranium and cerium complexes, but it does not present a complete coverage of actinide and lanthanide complexes with carbone or carbide ligands.

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Severin, Kay. "Synthetic chemistry with nitrous oxide." Chemical Society Reviews 44, no. 17 (2015): 6375–86. http://dx.doi.org/10.1039/c5cs00339c.

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Nitrous oxide (N<sub>2</sub>O, ‘laughing gas’) is a very inert molecule. Still, it can be used as a reagent in synthetic organic and inorganic chemistry, serving as O-atom donor, as N-atom donor, or as a oxidant in metal-catalyzed reactions.

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Joly, Helen A., Maria Kepes, Natalie Roy, and Jason Prpic. "The reactivity of the high-energy intermediates formed in the reactions of Group 13 metal atoms and aromatic alkenes." Canadian Journal of Chemistry 76, no. 4 (1998): 400–406. http://dx.doi.org/10.1139/v98-033.

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Group 13 metal atoms were reacted with aromatic alkenes in a specialized metal atom reactor known as a "rotating cryostat." The nature of the intermediates formed was deduced from a GC-MS study of their hydrolysis and deuterolysis products. The product studies suggest that 2-phenylaluminacyclopropane, cis- and trans-3,4-diphenylaluminacyclopentane, and cis- and trans- 2,4-diphenylaluminacyclopentane are formed when Al atoms react with styrene, and 2-methyl-2-phenylaluminacyclopropane and 3,4-dimethyl- 3,4-diphenylaluminacyclopentane are formed when Al atoms react with α -methylstyrene. These findings are consistent with the radicals detected in the EPR spectroscopic studies of Al-alkene reaction mixtures prepared under similar conditions. Mechanisms for the formation of the organoaluminium intermediates are discussed. Analogous organogallium intermediates are formed when gallium atoms react with styrene. The reductive coupling of styrene did not occur when In and Tl atoms were used. Only trace quantities of phenylethane were detected in the hydrolyzed reaction mixture.Key words: Group 13 metal atoms, aluminium atoms, organoaluminium intermediates, metal atom reactions.

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Scharfe, Sandra, and Thomas F. Fässler. "Polyhedral nine-atom clusters of tetrel elements and intermetalloid derivatives." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 368, no. 1915 (2010): 1265–84. http://dx.doi.org/10.1098/rsta.2009.0270.

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Homoatomic polyanions have the basic capability for a bottom-up synthesis of nanostructured materials. Therefore, the chemistry and the structures of polyhedral nine-atom clusters of tetrel elements [E 9 ] 4− is highlighted. The nine-atom Zintl ions are available in good quantities for E = Si–Pb as binary alkali metal (A) phases of the composition A 4 E 9 or A 12 E 17 . Dissolution or extraction of the neat solids with aprotic solvents and crystallization with alkali metal-sequestering molecules or crown ethers leads to a large variety of structures containing homoatomic clusters with up to 45 E atoms. Cluster growth occurs via oxidative coupling reactions. The clusters can further act as a donor ligand in transition metal complexes, which is a first step to the formation of bimetallic clusters. The structures and some nuclear magnetic resonance spectroscopic properties of these so-called intermetalloid clusters are reviewed, with special emphasis on tetrel clusters that are endohedrally filled with transition metal atoms.

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Hulva, Jan, Matthias Meier, Roland Bliem, et al. "Unraveling CO adsorption on model single-atom catalysts." Science 371, no. 6527 (2021): 375–79. http://dx.doi.org/10.1126/science.abe5757.

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Understanding how the local environment of a “single-atom” catalyst affects stability and reactivity remains a challenge. We present an in-depth study of copper1, silver1, gold1, nickel1, palladium1, platinum1, rhodium1, and iridium1 species on Fe3O4(001), a model support in which all metals occupy the same twofold-coordinated adsorption site upon deposition at room temperature. Surface science techniques revealed that CO adsorption strength at single metal sites differs from the respective metal surfaces and supported clusters. Charge transfer into the support modifies the d-states of the metal atom and the strength of the metal–CO bond. These effects could strengthen the bond (as for Ag1–CO) or weaken it (as for Ni1–CO), but CO-induced structural distortions reduce adsorption energies from those expected on the basis of electronic structure alone. The extent of the relaxations depends on the local geometry and could be predicted by analogy to coordination chemistry.

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Chen, Taoyi, and Thomas A. Manz. "A collection of forcefield precursors for metal–organic frameworks." RSC Advances 9, no. 63 (2019): 36492–507. http://dx.doi.org/10.1039/c9ra07327b.

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Atom-in-material (AIM) partial charges, dipoles and quadrupoles, dispersion coefficients (C<sub>6</sub>, C<sub>8</sub>, C<sub>10</sub>), polarizabilities, electron cloud parameters, radial moments, and atom types were extracted from quantum chemistry calculations for >3000 MOFs.

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Klabunde, Kenneth J., Yong Xi Li, and Beng Jit Tan. "Solvated metal atom dispersed catalysts." Chemistry of Materials 3, no. 1 (1991): 30–39. http://dx.doi.org/10.1021/cm00013a013.

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Dissertations / Theses on the topic "Metal atom chemistry"

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Tovey, R. C. "Studies in metal vapour synthesis." Thesis, University of Oxford, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375325.

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Ren, Wendong. "Photoinduced Atom Transfer Radical Polymerization." University of Akron / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=akron1619122320374689.

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Harris, Neil. "A matrix isolation study of main group and transition metal atom cryochemistry." Thesis, University of Hull, 2001. http://hydra.hull.ac.uk/resources/hull:12359.

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The majority of the work described in this thesis is concerned with the isolation of transition metal and main group atoms in dilute reactive ligand matrices. The previously uncharacterised matrix isolated species were characterised using IR, UV-Vis-NIR and XAFS spectroscopic techniques. Various metal atom sources were investigated for the production and subsequent isolation of atomic species in both inert and reactive ligand matrices. Some 4d and 5d transition metals atoms were produced from a hollow cathode sputtering source (laser ablation was also employed as an atom source in some of the work) and isolated in argon matrices. The isolation of both platinum and palladium atoms in chlorine containing argon matrices has been shown to result in the formation of linear PtCl₂ and PdCl₂ molecules. The isolation of gold atoms has led to the formation of a monomeric chloride, suspected to be either AuCl3 or AuCI₂.The structure of the silver chloride remains undetennined. The pseudo-gas phase structure of these monomeric species is presented for the first time. In addition to this work tellurium atoms have been generated from the photodecomposition of matrix isolated H₂Te. The use of CO containing matrices has led to the isolation and characterisation of carbonyl telluride, OCTe, the structure and composition of which (either in the solid or gas phase) is presented for the first time. In complementary work, an investigation into carbonyl complexes formed on isolation of some 3d transition metal bromides in dilute carbon monoxide / argon matrices is also presented, together with their photochemistry in neat CO matrices.

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Yassine, T. "The hot atom chemistry of some metal complexes and its application to radio isotope production." Thesis, University of Salford, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.381739.

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King, Evan. "Metal-Ligand Multiple Bonds in High-Spin Complexes." Thesis, Harvard University, 2012. http://dissertations.umi.com/gsas.harvard:10356.

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The chemistry of late first row transition metals supported by dipyrromethane and dipyrromethene ligands bearing sterically bulky substituents was explored. Transition metal complexes (Mn, Fe, Co, Ni, Zn) of the dipyrromethane ligand 1,9-dimesityl-5,5-dimethyldipyrromethane (dpma) were prepared. Structural and magnetic characterization (SQUID, EPR) of the bis-pyridine adducts \((dpma)Mn(py)_2\), \((dpma)Fe(py)_2\), and \((dpma)Co(py)_2\) showed each tetrahedral divalent ion to be high-spin, while square planar \((dpma)Ni^{II}(py)_2\) and tetrahedral \((dpma)Zn(py)_2\) were shown to be diamagnetic. Electrochemical experiments revealed oxidative events at common potentials independent of metal identity or spin state, consistent with ligand-based oxidation. Dipyrromethene ligand scaffolds were synthesized bearing large aryl \((Ar = 2,4,6-Ph_{3}C_{6}H_{2}, Mes = 2,4,6-Me_{3}C_{6}H_{2})\) or alkyl \((^{t}Bu = CMe_3, Ad = 1-adamantyl)\) flanking groups to afford three new disubstituted ligands \((^{R}dpme, 1, 9-R_2-5-mesityldipyrromethene, R = Ar, Mes, ^{t}Bu, Ad)\). While high-spin \((S=2)\), four-coordinate iron complexes of the type \((^{R}dpme)FeCl(solv)\) were obtained when R was Mes, tBu, or Ad, use of the sterically encumbered aryl-substituted ligand gave a three-coordinate high-spin \((S=2)\) complex \((^{Ar}dpme)FeCl\). Intramolecular C−H amination was discovered in the reaction of organic azides with \((^{Mes}dpme)FeCl(thf)\), though no intermediate was observed by UV/Vis, IR, or \(^{1}H\) VT-NMR experiments. Reaction of \((^{Ad}dpme)FeCl(OEt_2)\) with alkyl azides resulted in the catalytic amination of C–H bonds or aziridination of olefins at room temperature. Reaction of \(p-^{t}BuC_{6}H_{4}N_{3}\) with \((^{Ar}dpme)FeCl\) permitted isolation of a high-spin \((S=2)\) iron complex \((^{Ar}dpme)FeCl(N(p-^{t}BuC_6H_4))\), featuring a terminal imidyl radical antiferromagnetically coupled to high-spin \(Fe^{III}\), as determined by \(^{1}H\) NMR, X-ray crystallography, and \(^{57}Fe\) Mössbauer. A three-coordinate CoI complex \((^{Ar}dpme)Co(py)\) was synthesized and characterized by \(^{1}H\) NMR, SQUID magnetometry, and X-ray crystallography. Reaction of \((^{Ar}dpme)Co(py)\) with \(^{t}BuN_3\) afforded an isolable three-coordinate Co imide complex \((^{Ar}dpme)Co(N^{t}Bu)\) that exhibits spin crossover from a singlet to a quintet. Reaction of \((^{Ar}dpme)Co(py)\) with mesityl azide produces a spectroscopically observed intermediate, consistent with an \(S=1\) terminal imide complex, that converted via benzylic C–H activation into the metallacycloindoline \((^{Ar}dome)Co(\kappa^{2}-NHC_{6}H_{2}-2,4-Me_{2}-6-CH_2)\).<br>Chemistry and Chemical Biology

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Dioses, Castro Silvio, and Richard Korswagen. "Over the possible role of metal atom clusters in cosmochemistry and in the origin of life." Revista de Química, 2013. http://repositorio.pucp.edu.pe/index/handle/123456789/100714.

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We present here the hypothesis of a possible relationship between metal atom clusters and the formation of organic molecules in the interstellar medium and on small bodies as a possible pathway to the origin of such molecules. Two distinct stages are díscussed: a) the possible formation and presence of atom clusters in space and on the primitive Earth, and b) the synthesis of interstellar and terrestrial prebiotic organic molecules, a process in which metalclusters could be the active catalysts. The confirmatíon of these suggestions might be very important in arder to explain the presence of extra-terrestrial organic molecules in the interstellar medium, small bodies and planetary systems, and therefore would have great relevance in cosmochemistry and in the current theories about the origins of life.

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Ozcan, Gurbetoglu Pelin Gulistan. "Determination Of Cadmium Using Slotted Quartz Tube Atom Trap Atomic Absorption Spectrometry And Metal Coatings." Master's thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/12612212/index.pdf.

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ABSTRACT DETERMINATION OF CADMIUM USING SLOTTED QUARTZ TUBE ATOM TRAP ATOMIC ABSORPTION SPECTROMETRY AND METAL COATINGS &Ouml<br>zcan Gurbetoglu, G. Pelin M.S., Department of Chemistry Supervisor: Prof. Dr. O. Yavuz Ataman July 2010, 76 pages Flame atomic absorption spectroscopy (FAAS) is a common technique for detecting metals and metalloids in environmental, biological and metallurgical samples. Although it is a rather old technique, it is still very reliable, simple to use and inexpensive. The technique can be used to determine the concentration of over 70 different metals in a solution. However, it has detection limits at mg/L levels. Some atom trapping methods have been developed to reach the detection limits of ng/mL levels. Slotted quartz tube (SQT) is one of these atom trapping methods. It is an important technique, since it is easy to use, applicable in all laboratories, commercially available and economical. This thesis consists of development of a sensitive method for cadmium with the help of SQT atom trap. In this study, it was used for two different purposes. One was for keeping the analyte atoms more in the light path<br>in other words, for increasing the residence times of analyte atoms in the measurement zone. This first application was provided a 2.9 times enhancement with respect to conventional FAAS. Second application was for trapping the analyte on the surface of the SQT, in other words, for performing on-line preconcentration of cadmium in SQT. In the presence of a lean flame, analyte samples were trapped and collected for a few minutes at a low suction rate. After finishing the collection period, analyte atoms were revolatilized with the help of a small volume of (10-50 &micro<br>L) methyl isobutyl ketone (MIBK) and a rapid atomization occurred. This introduction also altered the flame composition momentarily and analyte atoms were released from the surface of the SQT. Application of this method enhanced the sensitivity 2065 times with respect to conventional FAAS. Another approach to this type of atom trapping has been investigated also in this study, which was coating of SQT with some metals having low volatility. Therefore, some transition metals were coated to the surface of SQT and among them zirconium was selected as the best coating material as having the most sensitivity enhancement factor. That is why, rest of the study was performed with the Zr coated SQT. The enhancement was 3368 as compared with FAAS. Cd determination with this method provides LOD value of 8 pg/mL and Co value of 19 pg/mL. In order to see the effect of some other type of elements or ions on determination of cadmium, interference study was done.

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Demirtas, Ilknur. "Lead Determination By Flame Atomic Absorption Spectrometry Using A Slotted Quartz Tube Atom Trap And Metal Coatings." Master's thesis, METU, 2009. http://etd.lib.metu.edu.tr/upload/3/12610794/index.pdf.

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Flame Atomic Absorption Spectrometry (FAAS) still keeps its importance despite the relatively low sensitivity<br>because it is a simple and economical technique for determination of metals. In recent years atom traps have been developed to increase the sensitivity of FAAS. Although the detection limit of FAAS is only at the level of mg/L, with the use of atom traps it can reach to ng/mL. Slotted quartz tube (SQT) is one of these atom traps, it is applied for determination of volatile elements<br>it is economical, commercially available and easy to use. In this study, a sensitive analytical method has been developed for the determination of lead with the help of SQT. Regarding the angle between the two slots of SQT, 120&deg<br>and 180&deg<br>configurations were used and the results were compared. There were three modes of SQT used. The first application was for providing longer residence time of analyte atoms in the measurement zone<br>3 fold sensitivity enhancement was observed. The second mode was the usage of SQT for preconcentration of lead atoms. In the presence of a lean air-acetylene flame, analyte atoms were trapped in the inner surface of SQT for a few minutes. Then, by the help of a small volume (10-50 &amp<br>#956<br>L) of Methyl isobutyl ketone (MIBK), analyte atoms were revolatilized and a rapid atomization took place. Using this mode, a sensitivity enhancement of 574 was obtained at a rather low (3.9 mL/min) suction rate<br>1320 fold improvement was reached at higher sample suction rate (7.4 mL/min) for 5.0 min collection. The last mode involves coating of the inner surface of SQT with several kinds of transition metals. The best sensitivity enhancement, 1650 fold, was obtained by the Ta coated SQT. In addition, effects of some elements and anions on Pb signal in Tacoated-SQT-AT-FAAS were examined. Final step consists of surface analysis<br>chemical nature of Pb trapped on quartz and Ta surface, and the chemical nature of Ta on quartz surface were investigated by X-ray Photoelectron Spectroscopy (XPS) and Raman Spectroscopy.

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Osmanbasoglu, Mahmut. "Tellurium Determination By Flame Atomic Absorption Spectrometry Using A Slotted Quartz Tube Atom Trap And Metal Coatings." Master's thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12613029/index.pdf.

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Flame Atomic Absorption Spectroscopy (FAAS) has lover sensitivity than similar analytical methods, however it has an important place for analysis due to its easy application and economic practicability especially in metal determinations. In order to increase the sensitivity of FAAS from mg/L level to ng/L level, various atom trap systems have been used. One of these atom traps, Slotted Quartz Tube (SQT), which is easy, economical and useful for volatile element determination, is used in this study as a sensitive analytical method for determination of tellurium. In the study, determination of Te by SQT is handled in three different modules. First, only with SQT itself, longer residence time for Te atoms in the measurement zone is provided and consequently 3.2 fold sensitivity enhancement is obtained both for Te (VI) and Te (IV). In the second module, SQT is used for concentration of tellurium species in a lean flame by sending the analyte into SQT for a definite time and trapping them on the inner surface of the SQT. After trapping the analyte, in order to determine the Te concentration, a small volume (10-50 &micro<br>L) of organic solvent such as methyl ethyl ketone (MEK) is introduced to the flame for revolatilization and a rapid atomization of Te on the surface is provided. In this trapping method, for 5 minutes collection with a 6 mL/min suction rate, 143 fold enhancement for Te (VI) and 142 fold enhancement for Te (IV) were obtained. In the third module, different from the second one, the inner surface of the SQT is coated with different metals for increasing the amount of Te trapped on the surface and the best enhancement for tellurium is obtained with Tantalum-coated SQT with 252 fold enhancement for Te (VI) and 246 fold enhancements for Te (IV). All improvements are calculated according to the signals obtained in FAAS method. Separate calibration plots were used for Te (IV) and Te (VI).

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O'Hare, D. M. "Activation of carbon hydrogen bonds by metal atoms." Thesis, University of Oxford, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.355789.

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Books on the topic "Metal atom chemistry"

1

Yassine, Taufik. The hot atom chemistry of some metal complexes and its application to radio isotope production. University of Salford, 1987.

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Martin, T. P. Large Clusters of Atoms and Molecules. Springer Netherlands, 1996.

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Sugano, Satoru. Microcluster physics. 2nd ed. Springer, 1998.

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Sugano, Satoru. Microcluster physics. Springer-Verlag, 1991.

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Coskuner, Orkid, Thomas Clayton Allison, and Carlos A. González. Metallic systems: A quantum chemist's perspective. Taylor & Francis, 2011.

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Clusters of Atoms and Molecules: Theory, Experiment, and Clusters of Atoms. Brand: Springer, 2011.

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1939-, Haberland Hellmut, ed. Clusters of atoms and molecules: Theory, experiment, and clusters of atoms. Springer-Verlag, 1994.

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Li, Wai-Kee, Hung Kay Lee, Dennis Kee Pui Ng, Yu-San Cheung, Kendrew Kin Wah Mak, and Thomas Chung Wai Mak. Problems in Structural Inorganic Chemistry. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780198823902.001.0001.

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The First Edition of this book, which appeared in 2013, serves as a problem text for Part I (Fundamentals of Chemical Bonding) and Part II (Symmetry in Chemistry) of the book Advanced Structural Inorganic Chemistry published by Oxford University Press in 2008. A Chinese edition was published by Peking University Press in August in the same year. Since then the authors have received much feedback from users and reviewers, which prompted them to prepare a Second Edition for students ranging from freshmen to senior undergraduates who aspire to attend graduate school after finishing their first degree in Chemistry. Four new chapters are added to this expanded Second Edition, which now contains over 400 problems and their solutions. The topics covered in 13 chapters follow the sequence: electronic states and configurations of atoms and molecules, introductory quantum chemistry, atomic orbitals, hybrid orbitals, molecular symmetry, molecular geometry and bonding, crystal field theory, molecular orbital theory, vibrational spectroscopy, crystal structure, transition metal chemistry, metal clusters: bonding and reactivity, and bioinorganic chemistry. The problems collected in this volume originate from examination papers and take-home assignments that have been part of the teaching program conducted by senior authors at The Chinese University of Hong Kong over nearly a half-century. Whenever appropriate, source references in the chemical literature are given for readers who wish to delve deeper into the subject. Eight Appendices and a Bibliography listing 157 reference books are provided to students and teachers who wish to look up comprehensive presentations of specific topics.

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1939-, Haberland Hellmut, ed. Clusters of atoms and molecules II: Solvation and chemistry of free clusters, and embedded, supported, and compressed clusters. Springer-Verlag, 1994.

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Yuryea, Elmira I. Quantum Chemistry and Nuclear Resonance Spectroscopy Data of Natural and Synthetic Nanotechnological Materials With Nd-metal Atoms Participations. Nova Science Pub Inc, 2007.

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Book chapters on the topic "Metal atom chemistry"

1

Creutz, Carol. "Intrinsic Barriers to Atom Transfer Between Transition-Metal Centers." In Advances in Chemistry. American Chemical Society, 1997. http://dx.doi.org/10.1021/ba-1997-0253.ch009.

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Osakada, Kohtaro. "Chapter 11. Chemistry of Transition Metal Complexes with Group 16 Elements: Transition Metal Complexes with Two Lone Pairs of Electrons on the Coordinating Atom." In Organometallic Chemistry. Royal Society of Chemistry, 2021. http://dx.doi.org/10.1039/9781839164200-00203.

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Matsuzaka, Hiroyuki, and Tsutomu Mizuta. "Chapter 10. Chemistry of Transition Metal Complexes with Group 15 Elements: Transition Metal Complexes with One Lone Pair of Electrons on the Coordinating Atom." In Organometallic Chemistry. Royal Society of Chemistry, 2021. http://dx.doi.org/10.1039/9781839164200-00176.

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Strich, Alain. "A Miscellany of AB Initio Quantum Chemistry the Helium Atom Studied by Various Methods." In Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2698-4_17.

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Riley, S. J. "The Chemistry of Transition Metal Clusters." In Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2822-3_2.

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Jeung, G. H. "Scandium Atom Interacting with Diatomic Groups." In Quantum Chemistry: The Challenge of Transition Metals and Coordination Chemistry. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4656-9_8.

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Dedieu, A., C. Bo, and F. Ingold. "Carbon Dioxide Organometallic Chemistry: Theoretical Developments." In Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2822-3_9.

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8

Gingerich, K. A. "The Maximum Strength of the Chemical Bond between Two Metal Atoms." In Metal-Metal Bonds and Clusters in Chemistry and Catalysis. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2492-6_28.

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Li, Jin‑Cheng, Zidong Wei, Dong Liu, Dan Du, Yuehe Lin, and Minhua Shao. "Dispersive Single‑Atom Metals Anchored on Functionalized Nanocarbons for Electrochemical Reactions." In Topics in Current Chemistry Collections. Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-43294-2_5.

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Sachtler, W. M. H. "Transition Metal Clusters and Isolated Atoms in Zeolite Cages." In Chemistry and Physics of Solid Surfaces VIII. Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-75762-4_5.

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Conference papers on the topic "Metal atom chemistry"

1

Lu, Junqing. "Numerical estimates of metal atom energy in reactive sputter deposition of TiN and TaN thin films." In THE 6TH INTERNATIONAL CONFERENCE ON SCIENCE & ENGINEERING IN MATHEMATICS, CHEMISTRY AND PHYSICS: ScieTech18: The Nature Math - The Science. Author(s), 2018. http://dx.doi.org/10.1063/1.5080020.

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Watson, Isaac, Angelika Sebald, and Susan Stepney. "A Meta-Atom Based Sub-Symbolic Artificial Chemistry." In The 2019 Conference on Artificial Life. MIT Press, 2019. http://dx.doi.org/10.1162/isal_a_00151.

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Watson, Isaac, Angelika Sebald, and Susan Stepney. "A Meta-Atom Based Sub-Symbolic Artificial Chemistry." In The 2019 Conference on Artificial Life. MIT Press, 2019. http://dx.doi.org/10.1162/isal_a_00151.xml.

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Majid, Abdul, and Suyono Suyono. "Misconception Analysis Based On Students Mental Model In Atom Structure Materials." In Seminar Nasional Kimia - National Seminar on Chemistry (SNK 2018). Atlantis Press, 2018. http://dx.doi.org/10.2991/snk-18.2018.53.

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Sitorus, Berlian, Charlotte Pughe, Arin Mizouri, Andrew M. Ellis, and Shengfu Yang. "Ion-molecule reactions of organic molecules with noble metal atoms in superfluid helium droplets." In THE 3RD INTERNATIONAL SEMINAR ON CHEMISTRY: Green Chemistry and its Role for Sustainability. Author(s), 2018. http://dx.doi.org/10.1063/1.5082471.

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Gildenast, Hans, Franziska Busse, and Ulli Englert. "Competition of the Donor Atoms - Coordination Chemistry of a O,P,N tritopic Ligand - Complexes, Supramolecules and Metal-Organic Frameworks." In The 2nd International Online Conference on Crystals. MDPI, 2020. http://dx.doi.org/10.3390/iocc_2020-07321.

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