Journal articles on the topic 'Mechanochemistry'

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1

Friščić, Tomislav, and Jean-Louis Do. "Chemistry 2.0: Developing a New, Solvent-Free System of Chemical Synthesis Based on Mechanochemistry." Synlett 28, no. 16 (August 17, 2017): 2066–92. http://dx.doi.org/10.1055/s-0036-1590854.

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Mechanochemistry by grinding or milling has grown from a laboratory curiosity to a versatile approach for the synthesis and discovery of molecules, materials and reactivity. Focusing on organic synthesis and the chemistry of organic solids in general, we now provide a snapshot of this exciting, rapidly developing area, with the intention to illustrate its potential in establishing a more efficient and environmentally friendly system of chemical and materials synthesis, based on solid-state transformations rather than conventional, solution-dependent chemistry.1 What is Chemistry 2.0?2 Introduction2.1 Why Mechanochemistry Now?2.2 What’s in a Mechanochemistry Laboratory?3 Liquid-Assisted Grinding (LAG): Controlling Mechanochemistry4 The Solvent-Free Research Laboratory5 Medicinal Mechanochemistry6 Exploring Molecular Recognition7 Some Myths to Dispel8 Catalytic Reactions by Mechanochemistry8.1 Catalysis and Reactivity Involving Bulk Metals8.2 Enzyme Catalysis in Mechanochemistry8.3 Coupling of Mechanochemistry, Photochemistry and Supramolecular Catalysis9 Organometallic Mechanochemistry10 New Opportunities10.1 Stoichiometric Control10.2 ‘Impossible’ Molecules10.3 Reaction Discovery by Mechanochemistry11 Energetics of Mechanochemistry12 Mechanistic Understanding13 Real-Time Reaction Monitoring14 Conclusions
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2

Pagola, Silvina. "Outstanding Advantages, Current Drawbacks, and Significant Recent Developments in Mechanochemistry: A Perspective View." Crystals 13, no. 1 (January 10, 2023): 124. http://dx.doi.org/10.3390/cryst13010124.

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Although known since antiquity, mechanochemistry has remained dormant for centuries. Nowadays, mechanochemistry is a flourishing research field at the simultaneous stages of gathering data and (often astonishing) observations, and scientific argumentation toward their analysis, for which the combination of interdisciplinary expertise is necessary. Mechanochemistry’s implementation as a synthetic method is constantly increasing, although it remains far from being fully exploited, or understood on the basis of fundamental principles. This review starts by describing many remarkable advantages of mechanochemical reactions, simplifying and “greening” chemistry in solutions. This description is followed by an overview of the current main weaknesses to be addressed in the near future toward the systematic study of its energetics and chemical mechanisms. This review finishes by describing recent breakthrough experimental advances, such as in situ kinetics monitoring using synchrotron X-ray powder diffraction and Raman spectroscopy, plus equally significant computational chemistry approaches, such as quantum mechanochemistry, used for the understanding of covalent or hydrogen bond ruptures in biomolecules or mechanophores in polymers at the single-molecule level. Combined with new technologies to control temperature and pressure in ball mills, these appealing new methods are promising tools for establishing the fundamental knowledge necessary for the understanding of mechanochemical reactivity and mechanisms.
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3

Hernández, José G. "Mechanochemistry." Beilstein Journal of Organic Chemistry 13 (November 7, 2017): 2372–73. http://dx.doi.org/10.3762/bjoc.13.234.

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4

James, Stuart L., and Tomislav Friščić. "Mechanochemistry." Chemical Society Reviews 42, no. 18 (2013): 7494. http://dx.doi.org/10.1039/c3cs90058d.

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5

Gilman, J. J. "Mechanochemistry." Science 274, no. 5284 (October 4, 1996): 65. http://dx.doi.org/10.1126/science.274.5284.65.

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6

Sebastian, K. L. "Mechanochemistry." Resonance 12, no. 5 (May 2007): 48–59. http://dx.doi.org/10.1007/s12045-007-0050-1.

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7

Lavalle, Philippe, Fouzia Boulmedais, Pierre Schaaf, and Loïc Jierry. "Soft-Mechanochemistry: Mechanochemistry Inspired by Nature." Langmuir 32, no. 29 (July 19, 2016): 7265–76. http://dx.doi.org/10.1021/acs.langmuir.6b01768.

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8

Hernández, José G. "Mechanochemistry II." Beilstein Journal of Organic Chemistry 15 (July 9, 2019): 1521–22. http://dx.doi.org/10.3762/bjoc.15.154.

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9

Bagshaw, Clive R. "Myosin Mechanochemistry." Structure 15, no. 5 (May 2007): 511–12. http://dx.doi.org/10.1016/j.str.2007.04.005.

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10

Degnan, Tom. "Catalytic mechanochemistry." Focus on Catalysts 2023, no. 4 (April 2023): 1–2. http://dx.doi.org/10.1016/j.focat.2023.03.001.

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11

Hernández, José G. "Polymer and small molecule mechanochemistry: closer than ever." Beilstein Journal of Organic Chemistry 18 (September 14, 2022): 1225–35. http://dx.doi.org/10.3762/bjoc.18.128.

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The formation and scission of chemical bonds facilitated by mechanical force (mechanochemistry) can be accomplished through various experimental strategies. Among them, ultrasonication of polymeric matrices and ball milling of reaction partners have become the two leading approaches to carry out polymer and small molecule mechanochemistry, respectively. Often, the methodological differences between these practical strategies seem to have created two seemingly distinct lines of thought within the field of mechanochemistry. However, in this Perspective article, the reader will encounter a series of studies in which some aspects believed to be inherently related to either polymer or small molecule mechanochemistry sometimes overlap, evidencing the connection between both approaches.
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12

Gečiauskaitė, Agota A., and Felipe García. "Main group mechanochemistry." Beilstein Journal of Organic Chemistry 13 (October 5, 2017): 2068–77. http://dx.doi.org/10.3762/bjoc.13.204.

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Over the past decade, mechanochemistry has emerged as a powerful methodology in the search for sustainable alternatives to conventional solvent-based synthetic routes. Mechanochemistry has already been successfully applied to the synthesis of active pharmaceutical ingredients (APIs), organic compounds, metal oxides, coordination compounds and organometallic complexes. In the main group arena, examples of synthetic mechanochemical methodologies, whilst still relatively sporadic, are on the rise. This short review provides an overview of recent advances and achievements in this area that further validate mechanochemistry as a credible alternative to solution-based methods for the synthesis of main group compounds and frameworks.
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13

Tongjun, Wang, and Liu Xiuzhen. "Research Progress in Mechanochemistry of Inorganic Materials." Expert Review of Chinese Chemical 2, no. 1 (February 20, 2024): 36–38. http://dx.doi.org/10.62022/ercc.issn3006-0095.2024.01.008.

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With the progress of science and technology, China has gradually attached importance to research and exploration in chemistry, and the achievements in exploring mechanochemistry are also quite significant. Therefore, it is necessary to study and explore mechanochemistry. This article mainly discusses the application of mechanochemistry in powder and some silicate materials, as well as in special ceramics, and provides a brief introduction to provide reference for relevant researchers.
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14

Tan, Davin, Leigh Loots, and Tomislav Friščić. "Towards medicinal mechanochemistry: evolution of milling from pharmaceutical solid form screening to the synthesis of active pharmaceutical ingredients (APIs)." Chemical Communications 52, no. 50 (2016): 7760–81. http://dx.doi.org/10.1039/c6cc02015a.

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Development of mechanochemistry for API synthesis and pharmaceutical solid form screening signals the emergence of medicinal mechanochemistry – a discipline at the interface of medicinal chemistry and sustainable synthesis.
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15

Boldyrev, V., and E. Boldyreva. "Mechanochemistry of Interfaces." Materials Science Forum 88-90 (January 1992): 711–14. http://dx.doi.org/10.4028/www.scientific.net/msf.88-90.711.

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16

Borchardt, Lars, and José G. Hernández. "Dissecting Mechanochemistry III." Beilstein Journal of Organic Chemistry 18 (October 12, 2022): 1454–56. http://dx.doi.org/10.3762/bjoc.18.150.

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17

Michael McCoy. "Cinthesis advances mechanochemistry." C&EN Global Enterprise 100, no. 14 (April 25, 2022): 10. http://dx.doi.org/10.1021/cen-10014-buscon11.

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18

Bose, Anima, and Prasenjit Mal. "Mechanochemistry of supramolecules." Beilstein Journal of Organic Chemistry 15 (April 12, 2019): 881–900. http://dx.doi.org/10.3762/bjoc.15.86.

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The urge to use alternative energy sources has gained significant attention in the eye of chemists in recent years. Solution-based traditional syntheses are extremely useful, although they are often associated with certain disadvantages like generation of waste as by-products, use of large quantities of solvents which causes environmental hazard, etc. Contrastingly, achieving syntheses through mechanochemical methods are generally time-saving, environmentally friendly and more economical. This review is written to shed some light on supramolecular chemistry and the synthesis of various supramolecules through mechanochemistry.
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19

Colacino, Evelina, Francesco Delogu, and Timothy Hanusa. "Advances in Mechanochemistry." ACS Sustainable Chemistry & Engineering 9, no. 32 (August 16, 2021): 10662–63. http://dx.doi.org/10.1021/acssuschemeng.1c04390.

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20

Bowmaker, Graham A. "Solvent-assisted mechanochemistry." Chem. Commun. 49, no. 4 (2013): 334–48. http://dx.doi.org/10.1039/c2cc35694e.

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21

Ausman, Kevin D., Henry W. Rohrs, MinFeng Yu, and Rodney S. Ruoff. "Nanostressing and mechanochemistry." Nanotechnology 10, no. 3 (August 12, 1999): 258–62. http://dx.doi.org/10.1088/0957-4484/10/3/306.

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22

Juhász, Zoltán A., and Ludmilla Opoczky. "Mechanochemistry and agglomeration." Epitoanyag - Journal of Silicate Based and Composite Materials 55, no. 3 (2003): 86–90. http://dx.doi.org/10.14382/epitoanyag-jsbcm.2003.16.

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23

Molchanov, Viktor V., and Roman A. Buyanov. "Mechanochemistry of catalysts." Russian Chemical Reviews 69, no. 5 (May 31, 2000): 435–50. http://dx.doi.org/10.1070/rc2000v069n05abeh000555.

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24

Leininger, Sarah E., Karthik Narayan, Carol Deutsch, and Edward P. O’Brien. "Mechanochemistry in Translation." Biochemistry 58, no. 47 (May 28, 2019): 4657–66. http://dx.doi.org/10.1021/acs.biochem.9b00260.

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25

Boldyrev, V. V. "Mechanochemistry in Siberia." Herald of the Russian Academy of Sciences 88, no. 2 (March 2018): 142–50. http://dx.doi.org/10.1134/s1019331618020016.

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26

Comyns, Alan. "Mechanochemistry and catalysis." Focus on Catalysts 2014, no. 11 (November 2014): 1. http://dx.doi.org/10.1016/s1351-4180(14)70393-9.

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27

Boldyrev, V. V. "Mechanochemistry and sonochemistry." Ultrasonics Sonochemistry 2, no. 2 (1995): S143—S145. http://dx.doi.org/10.1016/1350-4177(95)00019-3.

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28

Kuga, Shigenori, and Min Wu. "Mechanochemistry of cellulose." Cellulose 26, no. 1 (January 2019): 215–25. http://dx.doi.org/10.1007/s10570-018-2197-1.

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29

Baláž, P. "Mechanochemistry of sulphides." Journal of Materials Science 39, no. 16/17 (August 2004): 5097–102. http://dx.doi.org/10.1023/b:jmsc.0000039190.72325.cf.

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30

Fernández-Bertran, J. F. "Mechanochemistry: an overview." Pure and Applied Chemistry 71, no. 4 (January 1, 1999): 581–86. http://dx.doi.org/10.1351/pac199971040581.

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31

Baláž, P., and E. Dutková. "Mechanochemistry of sulphides." Journal of Thermal Analysis and Calorimetry 90, no. 1 (September 22, 2007): 85–92. http://dx.doi.org/10.1007/s10973-007-8480-2.

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32

Sohma, Junkichi. "Mechanochemistry of polymers." Progress in Polymer Science 14, no. 4 (January 1989): 451–596. http://dx.doi.org/10.1016/0079-6700(89)90004-x.

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33

Friščić, Tomislav, Cristina Mottillo, and Hatem M. Titi. "Mechanochemistry for Synthesis." Angewandte Chemie International Edition 59, no. 3 (September 24, 2019): 1018–29. http://dx.doi.org/10.1002/anie.201906755.

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34

Friščić, Tomislav, Cristina Mottillo, and Hatem M. Titi. "Mechanochemistry for Synthesis." Angewandte Chemie 132, no. 3 (September 24, 2019): 1030–41. http://dx.doi.org/10.1002/ange.201906755.

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35

Ribas-Arino, Jordi, Motoyuki Shiga, and Dominik Marx. "Understanding Covalent Mechanochemistry." Angewandte Chemie International Edition 48, no. 23 (May 25, 2009): 4190–93. http://dx.doi.org/10.1002/anie.200900673.

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36

Ribas-Arino, Jordi, Motoyuki Shiga, and Dominik Marx. "Understanding Covalent Mechanochemistry." Angewandte Chemie 121, no. 23 (May 25, 2009): 4254–57. http://dx.doi.org/10.1002/ange.200900673.

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37

Suslick, Kenneth S. "Mechanochemistry and sonochemistry: concluding remarks." Faraday Discuss. 170 (2014): 411–22. http://dx.doi.org/10.1039/c4fd00148f.

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This paper offers a perspective on mechanochemistry and offers summarizing commentary on the Faraday Discussion170, “Mechanochemistry: From Functional Solids to Single Molecules”. The connection between the mechanical and the chemical worlds dates back to our earliest written records and beyond, but its renaissance over the past decade or so has had an impact on a huge swathe of modern science and engineering: from metallurgists to polymer scientists to synthetic organic and inorganic chemists to cellular biologists. Connections among the different subfields of mechanochemistry (tribochemistry, trituration, macromolecular, and sonochemistry) are drawn out and the common themes and open questions are considered.
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38

Felderhoff, Michael. "Ammonia Synthesis and Mechanochemistry." Joule 5, no. 2 (February 2021): 297–99. http://dx.doi.org/10.1016/j.joule.2021.01.009.

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39

Ishihara, Keiichi. "Mechanical Alloying and Mechanochemistry." Journal of the Japan Society of Powder and Powder Metallurgy 53, no. 1 (2006): 44. http://dx.doi.org/10.2497/jjspm.53.44.

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40

Boldyrev, Vladimir V. "Mechanochemistry and Mechanical Activation." Materials Science Forum 225-227 (July 1996): 511–20. http://dx.doi.org/10.4028/www.scientific.net/msf.225-227.511.

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41

Šepelák, Vladimir, M. Menzel, and K. D. Becker. "Mössbauer Studies in Mechanochemistry." Journal of Metastable and Nanocrystalline Materials 15-16 (April 2003): 537–44. http://dx.doi.org/10.4028/www.scientific.net/jmnm.15-16.537.

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42

Schrettl, Stephen, Diederik W. R. Balkenende, Céline Calvino, Marc Karman, Anna Lavrenova, Laura N. Neumann, Yoshimitsu Sagara, et al. "Functional Polymers Through Mechanochemistry." CHIMIA International Journal for Chemistry 73, no. 1 (February 27, 2019): 7–11. http://dx.doi.org/10.2533/chimia.2019.7.

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43

Senna, Mamoru. "The role of mechanochemistry." Bulletin of the Japan Institute of Metals 27, no. 10 (1988): 802–4. http://dx.doi.org/10.2320/materia1962.27.802.

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44

Veljkovic, Ivana, Dejan Poleti, Miodrag Zdujic, and Ljiljana Karanovic. "Mechanochemistry of titanium oxides." Chemical Industry 63, no. 3 (2009): 247–51. http://dx.doi.org/10.2298/hemind0903247v.

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Mechanochemistry represents an alternative route in synthesis of nanomaterials. Mechanochemical routes are attractive because of their simplicity, flexibility, and ability to prepare materials by solid state reactions at room temperature. The aim of this work is the mechanochemical synthesis of nanostructured titanium oxides of different composition starting from mixtures of Ti and TiO2, TiO and TiO2 or Ti2O3 and TiO2. Emphasis is on the Magneli phases Ti4O7 and Ti5O9 because their mixture is commercially known as EBONEX material. The materials prepared were characterized by XRPD, TG/DTA analysis, SEM and optical microscopy. Titanium monoxide and several Magneli oxides, Ti4O7, Ti5O9 and Ti6O11, are successfully prepared. The results are very interesting because the EBONEX materials were prepared at lower than usual temperature, which would decrease the effective cost of production.
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45

Balkenende, Diederik W. R., Souleymane Coulibaly, Sandor Balog, Yoan C. Simon, Gina L. Fiore, and Christoph Weder. "Mechanochemistry with Metallosupramolecular Polymers." Journal of the American Chemical Society 136, no. 29 (July 10, 2014): 10493–98. http://dx.doi.org/10.1021/ja5051633.

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46

Field, Leslie D., Sever Sternhell, and Howard V. Wilton. "Mechanochemistry of some hydrocarbons." Tetrahedron 53, no. 11 (March 1997): 4051–62. http://dx.doi.org/10.1016/s0040-4020(97)00017-3.

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47

Liu, Jian, Yidi Sun, David G. Drubin, and George F. Oster. "The Mechanochemistry of Endocytosis." PLoS Biology 7, no. 9 (September 29, 2009): e1000204. http://dx.doi.org/10.1371/journal.pbio.1000204.

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48

Mitchenko, S. A. "Mechanochemistry in heterogeneous catalysis." Theoretical and Experimental Chemistry 43, no. 4 (July 2007): 211–28. http://dx.doi.org/10.1007/s11237-007-0025-z.

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49

Boldyrev, V. V. "Mechanochemistry of inorganic solids." Thermochimica Acta 110 (February 1987): 303–17. http://dx.doi.org/10.1016/0040-6031(87)88239-4.

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50

Weissmüller, Jörg. "Mechanochemistry breaks with expectations." Nature Catalysis 1, no. 4 (April 2018): 238–39. http://dx.doi.org/10.1038/s41929-018-0061-1.

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