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Academic literature on the topic 'Magneto-dielectric Properties - Nanocomposites'

Author: Grafiati
Published: 7 September 2023

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Journal articles on the topic "Magneto-dielectric Properties - Nanocomposites"

1

Yang, Ta-I., Rene N. C. Brown, Leo C. Kempel, and Peter Kofinas. "Magneto-dielectric properties of polymer– nanocomposites." Journal of Magnetism and Magnetic Materials 320, no. 21 (2008): 2714–20. http://dx.doi.org/10.1016/j.jmmm.2008.06.008.

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2

Ivkov, Sergey A., Konstantin A. Barkov, Evelina P. Domashevskaya, et al. "Nonlinear Transport and Magnetic/Magneto-Optical Properties of Cox(MgF2)100-x Nanostructures." Applied Sciences 13, no. 5 (2023): 2992. http://dx.doi.org/10.3390/app13052992.

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The aim of this work was to comprehensively study the effect of the variable atomic composition and structural-phase state of Cox(MgF2)100-x nanocomposites on their nonlinear transport and magnetic/magneto-optical properties. Micrometer-thick nanocomposite layers on glass substrates were obtained by means of ion-beam sputtering of a composite target in the argon atmosphere in a wide range of compositions (x = 16–59 at.%). Using a low metal content in the nanocomposite, magnesium fluoride was kept in the nanocrystalline state. As the metal content increased, nanocrystalline cobalt was formed. The value of the resistive percolation threshold, xper = 37 at.%, determined from the concentration dependences of the electrical resistance of the nanocomposites coincided with the beginning of nucleation of the metallic nanocrystals in the MgF2 dielectric matrix. The absolute value of the maximum negative magnetoresistive effect in the nanocomposites was 5% in a magnetic field of 5.5 kG at a Co concentration of x = 27 at.%.
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3

Sanida, A., S. G. Stavropoulos, Th Speliotis, and G. C. Psarras. "Magneto-Dielectric Behaviour of M-Type Hexaferrite/Polymer Nanocomposites." Materials 11, no. 12 (2018): 2551. http://dx.doi.org/10.3390/ma11122551.

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In the present study two sets of nanocomposites consisting of an epoxy resin and BaFe12O19 or SrFe12O19 nanoparticles were successfully developed and characterized morphologically and structurally via scanning electron microscopy and X-ray diffraction spectra. The dielectric response of the nanocomposites was investigated by means of broadband dielectric spectroscopy and their magnetic properties were derived from magnetization tests. Experimental data imply that the incorporation of the ceramic nanoparticles enhances significantly the dielectric properties of the examined systems and their ability to store electrical energy. Dielectric spectra of all systems revealed the presence of three distinct relaxation mechanisms, which are attributed both to the polymer matrix and the nanoinclusions: Interfacial polarization, glass to rubber transition of the polymer matrix and the re-orientation of small polar side groups of the polymer chain. The magnetic measurements confirmed the ferromagnetic nature of the nanocomposites. The induced magnetic properties increase with the inclusion of hexaferrite nanoparticles. The nanocomposites with SrFe12O19 nanoparticles exhibit higher values of coercive field, magnetization, magnetic saturation and remanence magnetization. A magnetic transition was detected in the ZFC/FC curves in the case of the BaFe12O19/epoxy nanocomposites.
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4

Rana, Dhiraj Kumar, Suresh Kumar Singh, Shovan Kumar Kundu, Subir Roy, S. Angappane, and Soumen Basu. "Electrical and room temperature multiferroic properties of polyvinylidene fluoride nanocomposites doped with nickel ferrite nanoparticles." New Journal of Chemistry 43, no. 7 (2019): 3128–38. http://dx.doi.org/10.1039/c8nj04755c.

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5

Veeramani, T., C. VENKATARAJU, V. PORKALAI, and R. SAGAYARAJ. "Effect of ZnO on the Structural and Magnetodielectric Properties of MgFe2O4 Nanocomposite Prepared by Sol-Gel Method." Asian Journal of Chemistry 35, no. 9 (2023): 2069–77. http://dx.doi.org/10.14233/ajchem.2023.28041.

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Zinc oxide doped magnesium ferrite (Mg1-xZnxFe2O4) nanocomposite was synthesized using sol-gel method and demonstrated to have a cubic spinel structure, with a range of crystallite sizes (19-40 nm) and lattice constants (8.432-8.399 Å). The material was found to have two prominent vibrational modes for tetrahedral (446 cm–1) and octahedral (584 cm–1). The dielectric constant was higher at low frequencies and decreased at higher frequencies, while the saturation magnetization decreased (16 to 6 emu/g) gradually with an increase in Zn2+, likely due to the presence of non-magnetic Zn2+. The magneto-dielectric constant was found to increase with the magnetic field for MgFe2O4 and up to a magnetic field of 2000 Oe for the zinc magnesium nanocomposites, after which it decreased for higher magnetic fields. A positive and negative change in magneto-capacitance as a function of the magnetic field was also observed. The antibacterial activity suggests that the substitution of Zn2+ into magnesium ferrite can be an effective method for improving antibacterial activity, with the potential to damage the bacterial membrane and other components through positively charged ions and ROS generated by nanoparticles. Potential uses for this synthetic material include magneto-optical recording and magnetic biosensors.
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6

Sanida, Aikaterini, Sotirios G. Stavropoulos, Thanassis Speliotis, and Georgios C. Psarras. "Investigating the Effect of Zn Ferrite Nanoparticles on the Thermomechanical, Dielectric and Magnetic Properties of Polymer Nanocomposites." Materials 12, no. 18 (2019): 3015. http://dx.doi.org/10.3390/ma12183015.

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In this study nanocomposites consisting of an epoxy resin and ceramic zinc ferrite nanoparticles have been successfully developed and investigated morphologically and structurally by means of scanning electron microscopy (SEM) images and X-ray diffraction (XRD) spectra. The thermal properties of the nanocomposites were studied via differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The thermomechanical characterization of the fabricated nanocomposites was studied via dynamic mechanical analysis (DMA) and the magneto-dielectric response was assessed by means of a broadband dielectric spectroscopy (BDS) and by employing a superconducting quantum interference device (SQUID) magnetometer. Data analysis demonstrates that the incorporation of nanoinclusions into the matrix improves both the thermomechanical and the dielectric properties of the systems, as indicated by the increase of the storage modulus, the real part of dielectric permittivity and conductivity values with filler content, while at the same time induces magnetic properties into the matrix. Zinc ferrite nanoparticles and their respective nanocomposites exhibit superparamagnetic behavior at room temperature. Three relaxations were recorded in the dielectric spectra of all systems; originating from the filler and the polymer matrix, namely interfacial polarization, glass to rubber transition of the polymer matrix and the reorientation of small polar side groups of the polymer chain.
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7

Yashin, M. M., and H. B. Mirzokulov. "Symmetrized Maxwell–Garnett Approximation as an Effective Method for Studying Nanocomposites." Russian Technological Journal 7, no. 4 (2019): 92–100. http://dx.doi.org/10.32362/2500-316x-2019-7-4-92-100.

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The symmetrized Maxwell-Garnett (SMG) approximation is considered as the most optimal method of an effective medium for the description of nanocomposite structures. This approximation takes into account the microstructure of the sample, which makes it possible to calculate the metal-dielectric system. Thus, SMG describes with good accuracy the structure of the nanocomposite. Besides, this approximation is applicable for granular alloys consisting of metal components. As a result, this technique can be considered as a universal approximation to describe a wide class of nanostructured materials. At the same time, this article discusses various methods of effective environment. In these methods, the metal component of nanocomposites and the dielectric matrix are replaced by an effective medium with effective permittivity εeff. It is necessary that the particles (granules) in such structures be small in comparison with the wavelength of electromagnetic radiation incident on the sample. Based on this, the spectral dependences of the transverse Kerr effect (TKE) in magnetic nanocomposites were calculated with (CoFeZr)(Al2O3) structure as an example at different concentrations of the magnetic component. The simulation was carried out at small and large concentrations (below and above the percolation threshold). The spectral dependences were obtained taking into account the form factor of nanoparticles and the quasi-classical size effect. Besides, the authors note and discuss in this paper the contribution of various mechanisms that affect the type of spectra of the transverse Kerr effect. Using the symmetrized Maxwell-Garnett approximation, the effective values of the granule size of the nanocomposites under study were found, and the tensor of effective dielectric permittivity (TEDP) was calculated. The obtained TEDP values allowed to simulate the spectral dependences of the magneto-optical transverse Kerr effect. The authors discuss and draw conclusions about the features of the obtained spectral dependences in both the visible and infrared regions of the spectrum. In addition, the practical and fundamental importance of the obtained results is noted. The importance of effective medium methods for the study of optical, transport and magneto-optical properties of magnetic nanocomposites is shown.
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8

Ganshina, Elena Alexandrovna, Vladimir Valentinovich Garshin, Ilya Mikhailovich Pripechenkov, Sergey Alexandrovich Ivkov, Alexander Victorovich Sitnikov, and Evelina Pavlovna Domashevskaya. "Effect of Phase Transformations of a Metal Component on the Magneto-Optical Properties of Thin-Films Nanocomposites (CoFeZr)x (MgF2)100−x." Nanomaterials 11, no. 7 (2021): 1666. http://dx.doi.org/10.3390/nano11071666.

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The results of complex studies of structural-phase transformations and magneto-optical properties of nanocomposites (CoFeZr)x (MgF2)100−x depending on the metal alloy content in the dielectric matrix are presented. Nanocomposites were deposited by ion-beam sputtering onto glass and glass-ceramic substrate. By studying the spectral and field dependences of the transversal Kerr effect (TKE), it was found that the transition of nanocomposites from superparamagnetic to the ferromagnetic state occurs in the region of xfm~30 at%, that corresponds to the onset the formation of ferromagnetic nanocrystals CoFeZr with hexagonal syngony in amorphous dielectric matrix of MgF2. With an increase of concentrations of the metal alloy for x > xfm, the features associated with structural transitions in magnetic granules are revealed in the TKE spectra. Comparison of the spectral and concentration dependences of TKE for nanocomposites on the glass and glass-ceramics substrates showed that the strongest differences occur in the region of the phase structural transition of CoFeZr nanocrystals from a hexagonal to a body-centered cubic structure at x = 38 at.% on the glass substrates and at x = 46 at.% on glass-ceramics substrates, due to different diffusion rates and different size of metal nanocrystals on amorphous glass substrates and more rough polycrystalline glass-ceramics substrates.
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9

Bajpai, O. P., J. B. Kamdi, M. Selvakumar, S. Ram, D. Khastgir, and S. Chattopadhyay. "Effect of surface modification of BiFeO3 on the dielectric, ferroelectric, magneto-dielectric properties of polyvinylacetate/BiFeO3 nanocomposites." Express Polymer Letters 8, no. 9 (2014): 669–81. http://dx.doi.org/10.3144/expresspolymlett.2014.70.

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10

Domashevskaya, Evelina P., Sergey A. Ivkov, Pavel V. Seredin, et al. "Nonlinear Electromagnetic Properties of Thinfilm Nanocomposites (CoFeZr)x(MgF2)100−x." Magnetochemistry 9, no. 6 (2023): 160. http://dx.doi.org/10.3390/magnetochemistry9060160.

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The aim of this work is a comprehensive study of the effect of variable atomic composition and structural-phase state of (CoFeZr)x(MgF2)100−x nanocomposites (NCs) on their nonlinear electronic and magnetic/magneto-optical properties. Micrometer-thick nanocomposite layers on the glass substrates were obtained by ion-beam sputtering of a composite target in the argon atmosphere in a wide range of compositions x = 9–51 at·%. The value of the resistive percolation threshold, xper = 34 at·%, determined from the concentration dependencies of the electrical resistance of NCs, coincides with the beginning of nucleation of metallic nanocrystals CoFeZr in MgF2 dielectric matrix. The absolute value of maximum magnetoresistance of NCs is 2.4% in a magnetic field of 5.5 kG at x = 25 at·%, up to the percolation threshold. Two maxima appear in the concentration dependencies of magneto-optical transversal Kerr effect, one of which, at x = 34 at·%, corresponds to the formation of CoFeZr alloy nanocrystals of a hexagonal structure, and the second one at x = 45 at·% corresponds to the phase transition of nanocrystals from a hexagonal to a cubic body-centered structure. The magnetic percolation threshold in (CoFeZr)x(MgF2)100−x system at xfm = 34 at·%, with the appearance of a hysteresis loop and a coercive force of Hc ≈ 8 Oe, coincides with the resistive percolation threshold xper = 34 at·%. Concentration dependence of the coercive force showed that at low contents of metallic alloy x < 30 at·%, NCs are superparamagnetic (Hc = 0). With an increase of the alloy content, in the region of magnetic and resistive percolation thresholds, NCs exhibit a magnetically soft ferromagnetic character and do not change it far beyond the percolation threshold, with the maximum value of the coercive force Hc < 30 Oe.
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