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Academic literature on the topic 'Macromolecular Building Blocks'

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Published: 7 September 2023

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Journal articles on the topic "Macromolecular Building Blocks"

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Cornelissen, Jeroen J. L. M., Alan E. Rowan, Roeland J. M. Nolte, and Nico A. J. M. Sommerdijk. "Chiral Architectures from Macromolecular Building Blocks." Chemical Reviews 101, no. 12 (December 2001): 4039–70. http://dx.doi.org/10.1021/cr990126i.

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Cornelissen, Jeroen J. L. M., Alan E. Rowan, Roeland J. M. Nolte, and Nico A. J. M. Sommerdijk. "ChemInform Abstract: Chiral Architectures from Macromolecular Building Blocks." ChemInform 33, no. 15 (May 22, 2010): no. http://dx.doi.org/10.1002/chin.200215294.

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Peruch, Frédéric, Jean-François Lahitte, F. Isel, and Pierre J. Lutz. "Macromonomers as well-defined building blocks in macromolecular engineering." Macromolecular Symposia 183, no. 1 (July 2002): 159–64. http://dx.doi.org/10.1002/1521-3900(200207)183:1<159::aid-masy159>3.0.co;2-7.

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Depoorter, Jérémy, Xibo Yan, Biao Zhang, Guillaume Sudre, Aurélia Charlot, Etienne Fleury, and Julien Bernard. "All poly(ionic liquid) block copolymer nanoparticles from antagonistic isomeric macromolecular blocks via aqueous RAFT polymerization-induced self-assembly." Polymer Chemistry 12, no. 1 (2021): 82–91. http://dx.doi.org/10.1039/d0py00698j.

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All-poly(ionic liquid) block copolymer nanoparticles are prepared by aqueous RAFT PISA using a couple of isomeric ionic liquid monomers leading to macromolecular building blocks with antagonistic solution behavior in water.
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Wouters, Staf M. L., David E. Clarke, Hiroki Noguchi, Steven De Feyter, and Arnout R. D. Voet. "SAKe: computationally designed modular protein building blocks for macromolecular assemblies." Acta Crystallographica Section A Foundations and Advances 77, a2 (August 14, 2021): C929. http://dx.doi.org/10.1107/s0108767321087705.

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TEZUKA, Yasuyuki. "Macromonomers and Telechelics: Building Blocks for Topologically Unique Macromolecular Structures." Kobunshi 45, no. 12 (1996): 862–67. http://dx.doi.org/10.1295/kobunshi.45.862.

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Inglis, Andrew J, Sebastian Sinnwell, Martina H Stenzel, and Christopher Barner-Kowollik. "Ultrafast Click Conjugation of Macromolecular Building Blocks at Ambient Temperature." Angewandte Chemie International Edition 48, no. 13 (February 18, 2009): 2411–14. http://dx.doi.org/10.1002/anie.200805993.

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Peng, Wentao, Yingying Cai, Luise Fanslau, and Philipp Vana. "Nanoengineering with RAFT polymers: from nanocomposite design to applications." Polymer Chemistry 12, no. 43 (2021): 6198–229. http://dx.doi.org/10.1039/d1py01172c.

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Reversible addition–fragmentation chain-transfer (RAFT) polymerization is a powerful tool for the precise formation of macromolecular building blocks that can be used for the construction of well-defined nanocomposites.
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Díez-Pascual, Ana M. "Hot Topics in 2022 and Future Perspectives of Macromolecular Science." Macromol 3, no. 1 (January 16, 2023): 28–33. http://dx.doi.org/10.3390/macromol3010002.

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Moldoveanu, Costel, Dorina Amariucai-Mantu, Violeta Mangalagiu, Vasilichia Antoci, Dan Maftei, Ionel I. Mangalagiu, and Gheorghita Zbancioc. "Microwave Assisted Reactions of Fluorescent Pyrrolodiazine Building Blocks." Molecules 24, no. 20 (October 18, 2019): 3760. http://dx.doi.org/10.3390/molecules24203760.

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We report here the synthesis and optical spectral properties of several new pyrrolodiazine derivatives. The luminescent heterocycles were synthesized by 1,3-dipolar cycloaddition reactions between N-alkylated pyridazine and methylpropiolate or dimethyl acetylenedicarboxylate (DMAD). The pyrrolopyridazine derivatives are blue emitters with moderate quantum yields (around 25%) in the case of pyrrolopyridazines and negligible yet measurable emission for pyrrolophthalazines. In a subsequent step towards including the pyrrolodiazine moiety, given its spectral properties in various macromolecular frameworks such as biological molecules, a subset of the synthetized compounds has been subjected to α-bromination. A selective and efficient way for α-bromination in heterogeneous catalysis of pyrrolodiazine derivatives under microwave (MW) irradiation is presented. We report substantially higher yields under MW irradiation, whereas the solvent amounts required are at least five-fold less compared to classical heating.
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Dissertations / Theses on the topic "Macromolecular Building Blocks"

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Pozza, Gladys. "Tailor-made heterofunctional poly(ethylene oxide)s via living anionic polymarization as building blocks in macromolecular engineering." Thesis, Strasbourg, 2014. http://www.theses.fr/2014STRAF030/document.

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L'objectif principal de la thèse porte sur la synthèse contrôlée et la caractérisation d’architectures macromoléculaires complexes originales à base de POE. Les POEs α-undécènyle-ω-hydroxy sont obtenus par polymérisation anionique par ouverture de cycle de l’oxyde d’éthylène. Le groupement hydroxyle est modifié pour accéder à des POEs α-undécènyle-ω-méthacrylate et des POEs α-undécènyle-ω-acétylène. Ces premiers POEs sont ensuite utilisés pour préparer soit des POEs à structure en peigne par ATRP dans l'eau soit par l'intermédiaire de réaction « click », des POEs à structure en étoile tétrafonctionnelles, tandis qu’avec les seconds permettent d’obtenir des PI-b-POE par réaction « click » avec le polyisoprène ω-azoture. Les extrémités de chaîne de POE commerciaux α-méthoxy-ω-hydroxy sont modifiées en POEs α-méthoxy-ω-allyle ou en POEs α-méthoxy-ω-undécènyle pour synthétiser par réaction d’hydrosilylation des étoiles de POE à structures en étoile octafonctionnelles
The main objective of the thesis focuses on the controlled synthesis and the characterization of original and complex macromolecular architectures based on PEO. α-Undecenyl-ω-hydroxy PEOs are obtained by anionic ring opening polymerization of ethylene oxide. The hydroxyl group is modified to access to α-undecenyl-ω-methacrylate PEOs and α-undecenyl-ω-acetylene PEOs. These first PEOs are used to prepare either comb-shaped PEOs by ATRP in water or through by click reaction of tetrafunctional star-shaped PEOs. Whereas the second PEOs allow obtaining block copolymers PI-b-PEO via click reaction with ω-azide polyisoprene. The chain-ends of commercial α-methoxy-ω-hydroxy PEO are modified in α-methoxy-ω-allyl PEOs or in α-methoxy-ω-undecenyl PEOs to synthesize by hydrosilylation reaction octafunctional star-shaped PEOs
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Mousa, Kareem Mohanad. "Novel redox active building blocks for the creation of functional macromolecules." Thesis, University of Glasgow, 2013. http://theses.gla.ac.uk/4453/.

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This thesis describes an investigation into a wide range of potential materials for organic photovoltaic (PV) devices. Chapter 1 provides a general introduction relating to donor -acceptor systems and conjugated polymers with photovoltaic applications. Chapter 2 describes the design, synthesis and characterisation of new organic super-acceptors based on an NDI core. An investigation of their optical and redox properties is described. Chapter 3 describes the synthesis of new flavin-functionalised dithienylpyrrole systems. In addition, preliminary polymerisation studies are described, together with a study of their chemical and physical properties. Chapter 4 describes the synthesis and characterisation of new ferrocene and NDI functionalised polymers by ATRP and RAFT techniques. Chapter 5 describes the synthesis of new bis-acceptor systems based on NDI and TCAQ and a brief study their chemical and physical properties. Chapter 6 describes the synthesis of conjug-ated polymers featuring NDI units. Chapter 7 describes the synthesis and characterisation of novel substituted metal phthalocyanines featuring NDI units. Chapter 8 provides the experimental details and characterisation of all the compounds prepared in this thesis. Finally, chapter 9 provides the appendices and additional information.
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Bender, Timothy P. 1971 Carleton University Dissertation Chemistry. "Linear, dendritic and hyperbranched polyimides; the tetrahydro[5] helicene unit as a novel building block for an exercise in macromolecular architecture." Ottawa.:, 1999.

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Bender, Timothy P. "Linear, dendritic and hyperbranched polyimides, the tetrahydro[5]helicene unit as a novel building block for an exercise in macromolecular architecture." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0020/NQ48342.pdf.

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Barriau, Emilie [Verfasser]. "Hyperbranched polyether polyols as building blocks for complex macromolecular architectures / Emilie Barriau." 2005. http://d-nb.info/1011899914/34.

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Valiyaveettil, Suresh. "Molecular Engineering Approaches to Highly Structured Materials." 2003. http://hdl.handle.net/1721.1/3933.

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Design and synthesis of novel supramolecular architectures is an interesting area of research in the last two decades. Intermolecular interactions assisted self-assembly of molecular and macromolecular building blocks play an important role in obtaining the desired shape and function of the supramolecular architectures. A combination of the classical covalent synthesis with the self-assembly assisted formation of well-defined architectures (noncovalent synthesis) allows us to develop novel multifunctional materials. Our approach in this area is focused on the design of novel molecular and biomolecular building blocks and the optimization of structure-property relationship of the materials using self-assembly approach. This presentation will focus on our recent efforts on the design and synthesis of polymers and oligopeptides for investigation of the self-assembly and fine-tuning the structure-property relationship. Also, some highlights will be given on our initial investigation on how hard minerals are synthesized by natural molecules through the self-assembly processes.
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Books on the topic "Macromolecular Building Blocks"

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Vögtle, Fritz, and Christoph A. Schalley. Dendrimers V: Functional and Hyperbranched Building Blocks, Photophysical Properties, Applications in Materials and Life Sciences. Springer, 2010.

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Book chapters on the topic "Macromolecular Building Blocks"

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Wallace, Gordon G. "Communicating with the Building Blocks of Life Using Advanced Macromolecular Transducers." In Advanced Biomaterials in Biomedical Engineering and Drug Delivery Systems, 13–17. Tokyo: Springer Japan, 1996. http://dx.doi.org/10.1007/978-4-431-65883-2_3.

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Aimoto, Saburo, and Hironobu Hojo. "Development of a Rapid and Facile Method for Protein Synthesis Using Partially Protected Peptide Thioesters as Building Blocks." In New Macromolecular Architecture and Functions, 189–98. Berlin, Heidelberg: Springer Berlin Heidelberg, 1996. http://dx.doi.org/10.1007/978-3-642-80289-8_20.

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Ariga, Katsuhiko, Ajayan Vinu, Jonathan P. Hill, Pavuluri Srinivasu, Somobrata Acharya, and Qingmin Ji. "Supramolecular Structures and Functions with Inorganic Building Blocks." In Macromolecules Containing Metal and Metal-Like Elements, 1–33. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2009. http://dx.doi.org/10.1002/9780470527085.ch1.

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Häußler, Matthias, and Ben Zhong Tang. "Functional Hyperbranched Macromolecules Constructed from Acetylenic Triple-Bond Building Blocks." In Functional Materials and Biomaterials, 1–58. Berlin, Heidelberg: Springer Berlin Heidelberg, 2007. http://dx.doi.org/10.1007/12_2007_112.

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Schubert, Ulrich. "Metal Oxide Clusters As Building Blocks for Inorganic-Organic Hybrid Polymers." In Macromolecules Containing Metal and Metal-Like Elements, 55–71. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2005. http://dx.doi.org/10.1002/0471773263.ch2.

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Liu, Shiqi, Zengyin Li, Huiwei Tong, Yong Zhong, and Feng Bai. "Porphyrin Self-Assembled Nanostructures and Applications." In Self-Assembly of Materials and Supramolecular Structures [Working Title]. IntechOpen, 2022. http://dx.doi.org/10.5772/intechopen.108627.

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Porphyrins are a class of macromolecular heterocyclic compounds formed by the inter-carbon atoms of four pyrrole-like subunits through the submethyl bridge (〓CH▬). Porphyrin rings have 26 electrons in highly conjugated system and are easily modified peripheral structures, often serve as ideal building blocks to construct self-assembled nanostructures with excellent physical and chemical properties. Porphyrin nanostructures have excellent visible light absorption properties, which will significantly improve the efficiency of electron–hole separation, and are also commonly used in photocatalysis fields. Porphyrin photosensitizers have superior strong phototoxicity and little side effects, and are widely used in tumor photothermal/photodynamic treatment. This chapter summarizes the self-assembly methods of porphyrins, the applications progress of porphyrin self-assembled nanomaterials in photocatalysis and tumor therapy, and discusses the development trend in future of porphyrin nanomaterials.
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"Thermally Responsive Materials." In Stimuli-Responsive Materials: From Molecules to Nature Mimicking Materials Design, 55–93. The Royal Society of Chemistry, 2016. http://dx.doi.org/10.1039/bk9781849736565-00055.

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This chapter focuses on thermally responsive polymers and their building blocks. Starting from polymeric assemblies in solutions, going into solids with stimuli-responsive transitions, a comprehensive summary of existing monomers capable of thermal responses is provided. The attractiveness of temperature-responsive homo- and copolymers is primarily driven by the ability of macromolecular segments to undergo conformational changes at a designated temperature. The earliest reports of the thermal phase transitions in poly(N-isopropylacrylamide) (PNIPAM) go back to the late 1960s, and this still continues to be an important and advantageous area in controlled drug delivery, bioseparation, enzyme activity, filtration, and mediating surface/interfacial properties. The last section of this chapter focuses in the thermally responsive peptides, their stimuli-responsiveness, selected applications, and examining the general principles governing the role of entropic contributions to stimuli-responsiveness.
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Arkenberg, Matthew R., Min Hee Kim, and Chien-Chi Lin. "Click Hydrogels for Biomedical Applications." In Multicomponent Hydrogels, 155–91. The Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781837670055-00155.

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Hydrogels crosslinked by homopolymerization of single component acrylate/methacrylate terminated polymers (e.g., poly(ethylene glycol) diacrylate, or PEGDA) were once the dominant biomaterials in biomedical applications, including the encapsulation of therapeutic agents and biological molecules. However, accumulating evidence has revealed many disadvantages of homopolymerized hydrogels, including heterogeneity of the crosslinking that adversely impacted the bioactivity of the encapsulated molecules. As such, recent years have witnessed the expansive use of modular click chemistry for the crosslinking of multicomponent hydrogels, typically consisting of two or more functionally distinct macromolecular building blocks. This chapter provides an overview of the crosslinking and applications of multicomponent hydrogels, focusing on those crosslinked by strain-promoted alkyne–azide cycloaddition (SPAAC), Michael-type addition, Diels–Alder (DA) reactions, inverse electron-demand Diels–Alder (iEDDA), thiol–ene polymerizations, and imine/hydrazone/oxime click reactions. This chapter also summarizes information regarding the characteristics, advantages, and limitations of commonly used synthetic (e.g., PEG, poly(acrylate), poly(vinyl alcohol), etc.) and naturally-derived macromers (e.g., gelatin, hyaluronic acid, etc.) for forming multicomponent hydrogels. Finally, an overview is given on the applications of multicomponent hydrogels in drug delivery, biofabrication, and 3D/4D cell culture.
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Yup Lee, Sang, Si Jae Park, and Soon Ho Hong. "Polymerization of Building Blocks to Macromolecules." In The Metabolic Pathway Engineering Handbook. CRC Press, 2009. http://dx.doi.org/10.1201/9781439802977.ch4.

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Bryce, Martin R., and Wayne Devonport. "Redox-active dendrimers, related building blocks, and oligomers." In Advances in Dendritic Macromolecules, 115–49. Elsevier, 1996. http://dx.doi.org/10.1016/s1874-5229(96)80006-2.

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