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Journal articles on the topic 'Lithium/sodium metal batteries'

Author: Grafiati

Published: 24 June 2021

Last updated: 8 February 2022

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1

Chawla, Neha, and Meer Safa. "Sodium Batteries: A Review on Sodium-Sulfur and Sodium-Air Batteries." Electronics 8, no. 10 (October 22, 2019): 1201. http://dx.doi.org/10.3390/electronics8101201.

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Lithium-ion batteries are currently used for various applications since they are lightweight, stable, and flexible. With the increased demand for portable electronics and electric vehicles, it has become necessary to develop newer, smaller, and lighter batteries with increased cycle life, high energy density, and overall better battery performance. Since the sources of lithium are limited and also because of the high cost of the metal, it is necessary to find alternatives. Sodium batteries have shown great potential, and hence several researchers are working on improving the battery performance of the various sodium batteries. This paper is a brief review of the current research in sodium-sulfur and sodium-air batteries.

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2

Xie, Xing-Chen, Ke-Jing Huang, and Xu Wu. "Metal–organic framework derived hollow materials for electrochemical energy storage." Journal of Materials Chemistry A 6, no. 16 (2018): 6754–71. http://dx.doi.org/10.1039/c8ta00612a.

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The recent progress and major challenges/opportunities of MOF-derived hollow materials for energy storage are summarized in this review, particularly for lithium-ion batteries, sodium-ion batteries, lithium–Se batteries, lithium–sulfur batteries and supercapacitor applications.

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Ma, Lianbo, Jiang Cui, Shanshan Yao, Xianming Liu, Yongsong Luo, Xiaoping Shen, and Jang-Kyo Kim. "Dendrite-free lithium metal and sodium metal batteries." Energy Storage Materials 27 (May 2020): 522–54. http://dx.doi.org/10.1016/j.ensm.2019.12.014.

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4

Wang, Yanjie, Yingjie Zhang, Hongyu Cheng, Zhicong Ni, Ying Wang, Guanghui Xia, Xue Li, and Xiaoyuan Zeng. "Research Progress toward Room Temperature Sodium Sulfur Batteries: A Review." Molecules 26, no. 6 (March 11, 2021): 1535. http://dx.doi.org/10.3390/molecules26061535.

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Lithium metal batteries have achieved large-scale application, but still have limitations such as poor safety performance and high cost, and limited lithium resources limit the production of lithium batteries. The construction of these devices is also hampered by limited lithium supplies. Therefore, it is particularly important to find alternative metals for lithium replacement. Sodium has the properties of rich in content, low cost and ability to provide high voltage, which makes it an ideal substitute for lithium. Sulfur-based materials have attributes of high energy density, high theoretical specific capacity and are easily oxidized. They may be used as cathodes matched with sodium anodes to form a sodium-sulfur battery. Traditional sodium-sulfur batteries are used at a temperature of about 300 °C. In order to solve problems associated with flammability, explosiveness and energy loss caused by high-temperature use conditions, most research is now focused on the development of room temperature sodium-sulfur batteries. Regardless of safety performance or energy storage performance, room temperature sodium-sulfur batteries have great potential as next-generation secondary batteries. This article summarizes the working principle and existing problems for room temperature sodium-sulfur battery, and summarizes the methods necessary to solve key scientific problems to improve the comprehensive energy storage performance of sodium-sulfur battery from four aspects: cathode, anode, electrolyte and separator.

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Biemolt, Jasper, Peter Jungbacker, Tess van Teijlingen, Ning Yan, and Gadi Rothenberg. "Beyond Lithium-Based Batteries." Materials 13, no. 2 (January 16, 2020): 425. http://dx.doi.org/10.3390/ma13020425.

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We discuss the latest developments in alternative battery systems based on sodium, magnesium, zinc and aluminum. In each case, we categorize the individual metals by the overarching cathode material type, focusing on the energy storage mechanism. Specifically, sodium-ion batteries are the closest in technology and chemistry to today’s lithium-ion batteries. This lowers the technology transition barrier in the short term, but their low specific capacity creates a long-term problem. The lower reactivity of magnesium makes pure Mg metal anodes much safer than alkali ones. However, these are still reactive enough to be deactivated over time. Alloying magnesium with different metals can solve this problem. Combining this with different cathodes gives good specific capacities, but with a lower voltage (<1.3 V, compared with 3.8 V for Li-ion batteries). Zinc has the lowest theoretical specific capacity, but zinc metal anodes are so stable that they can be used without alterations. This results in comparable capacities to the other materials and can be immediately used in systems where weight is not a problem. Theoretically, aluminum is the most promising alternative, with its high specific capacity thanks to its three-electron redox reaction. However, the trade-off between stability and specific capacity is a problem. After analyzing each option separately, we compare them all via a political, economic, socio-cultural and technological (PEST) analysis. The review concludes with recommendations for future applications in the mobile and stationary power sectors.

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Xu, Chenxuan, Yulu Yang, Huaping Wang, Biyi Xu, Yutao Li, Rou Tan, Xiaochuan Duan, Daxiong Wu, Ming Zhuo, and Jianmin Ma. "Electrolytes for Lithium‐ and Sodium‐Metal Batteries." Chemistry – An Asian Journal 15, no. 22 (October 14, 2020): 3584–98. http://dx.doi.org/10.1002/asia.202000851.

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7

Zhou, Jianen, Chenghui Zeng, Hong Ou, Qingyun Yang, Qiongyi Xie, Akif Zeb, Xiaoming Lin, Zeeshan Ali, and Lei Hu. "Metal–organic framework-based materials for full cell systems: a review." Journal of Materials Chemistry C 9, no. 34 (2021): 11030–58. http://dx.doi.org/10.1039/d1tc01905h.

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8

Song, Kyeongse, Daniel Adjei Agyeman, Mihui Park, Junghoon Yang, and Yong-Mook Kang. "High-Energy-Density Metal-Oxygen Batteries: Lithium-Oxygen Batteries vs Sodium-Oxygen Batteries." Advanced Materials 29, no. 48 (September 21, 2017): 1606572. http://dx.doi.org/10.1002/adma.201606572.

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9

Eguía-Barrio, A., E. Castillo-Martínez, X. Liu, R. Dronskowski, M. Armand, and T. Rojo. "Carbodiimides: new materials applied as anode electrodes for sodium and lithium ion batteries." Journal of Materials Chemistry A 4, no. 5 (2016): 1608–11. http://dx.doi.org/10.1039/c5ta08945j.

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Carbodiimides for batteries: the family of transition-metal carbodiimides MNCN (M = Cu, Zn, Mn, Fe, Co, and Ni) are shown to be new electrochemically active materials through displacement reactions both for lithium and sodium ion batteries.

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10

Wang, Bingyan, Tingting Xu, Shaozhuan Huang, Dezhi Kong, Xinjian Li, and Ye Wang. "Recent advances in carbon-shell-based nanostructures for advanced Li/Na metal batteries." Journal of Materials Chemistry A 9, no. 10 (2021): 6070–88. http://dx.doi.org/10.1039/d0ta10884g.

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11

Shi, Wenhui, Xilian Xu, Lin Zhang, Wenxian Liu, and Xiehong Cao. "Metal-organic framework-derived structures for next-generation rechargeable batteries." Functional Materials Letters 11, no. 06 (December 2018): 1830006. http://dx.doi.org/10.1142/s1793604718300062.

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Metal-organic frameworks (MOFs) have attracted great attention as versatile precursors or sacrificial templates for the preparation of novel porous structures. Due to their tunable compositions, structures and porosities as well as high surface area, MOF-derived materials have revealed promising performance for energy storage devices. In this mini review, the recent progress of MOF-derived materials as electrodes of next-generation rechargeable batteries was summarized. We briefly introduce the preparation methods, various design strategies and the structure-dependent performance of recently reported MOF-derived materials as electrodes of post-lithium-ion batteries, focusing on lithium-sulfur (Li-S) batteries, sodium-ion batteries (SIBs) and metal–air batteries. Finally, we give the conclusion with some insights into future development of MOF-derived materials for next-generation rechargeable batteries.

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12

Li, Huan-Huan, Zi-Yao Li, Xing-Long Wu, Lin-Lin Zhang, Chao-Ying Fan, Hai-Feng Wang, Xiao-Ying Li, Kang Wang, Hai-Zhu Sun, and Jing-Ping Zhang. "Shale-like Co3O4for high performance lithium/sodium ion batteries." Journal of Materials Chemistry A 4, no. 21 (2016): 8242–48. http://dx.doi.org/10.1039/c6ta02417c.

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Shale-like Co₃O₄(S-Co₃O₄) with a micro/nano-structure was preparedviaa simple pyrolysis of synthesised layer structured metal–organic compounds. The S-Co₃O₄exhibits expected high specific capacities, excellent cycle stability, and superior rate performance for lithium/sodium-ion batteries.

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13

Kim, Donghan, Sun-Ho Kang, Michael Slater, Shawn Rood, John T. Vaughey, Naba Karan, Mahalingam Balasubramanian, and Christopher S. Johnson. "Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes." Advanced Energy Materials 1, no. 3 (February 23, 2011): 333–36. http://dx.doi.org/10.1002/aenm.201000061.

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14

Salkuti, Surender Reddy. "Electrochemical batteries for smart grid applications." International Journal of Electrical and Computer Engineering (IJECE) 11, no. 3 (June 1, 2021): 1849. http://dx.doi.org/10.11591/ijece.v11i3.pp1849-1856.

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This paper presents a comprehensive review of current trends in battery energy storage systems, focusing on electrochemical storage technologies for Smart Grid applications. Some of the batteries that are in focus for improvement include Lithium-ion, metal-air, Sodium-based batteries and flow batteries. A descriptive review of these batteries and their sub-types are explained along with their suitable applications. An overview of different types and classification of storage systems has been presented in this paper. It also presents an extensive review on different electrochemical batteries, such as lead-acid battery, lithium-based, nickel-based batteries and sodium-based and flow batteries for the purpose of using in electric vehicles in future trends. This paper is going to explore each of the available storage techniques out there based on various characteristics including cost, impact, maintenance, advantages, disadvantages, and protection and potentially make a recommendation regarding an optimal storage technique.

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15

Fang, Guozhao, Jiang Zhou, Yangsheng Cai, Sainan Liu, Xiaoping Tan, Anqiang Pan, and Shuquan Liang. "Metal–organic framework-templated two-dimensional hybrid bimetallic metal oxides with enhanced lithium/sodium storage capability." Journal of Materials Chemistry A 5, no. 27 (2017): 13983–93. http://dx.doi.org/10.1039/c7ta01961k.

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Two-dimensional porous hybrid bimetallic Co₃O₄/ZnO nanosheets were successfully fabricated by a facile strategy using bimetallic MOFs nanosheets. This hybrid anode displayed superior electrochemical performance including a high-rate capability and long-term cyclic stability for lithium/sodium ion batteries.

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16

Zhao, Yajun, Tao Sun, Qing Yin, Jian Zhang, Shuoxiao Zhang, Jianeng Luo, Hong Yan, Lirong Zheng, Jingbin Han, and Min Wei. "Discovery of a new intercalation-type anode for high-performance sodium ion batteries." Journal of Materials Chemistry A 7, no. 25 (2019): 15371–77. http://dx.doi.org/10.1039/c9ta03753e.

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A CoFe layered double hydroxide (LDH) pillared by nitrates as an anode for sodium ion batteries exhibits high capacity with excellent cycling stability. An exceptional intercalation/de-intercalation mechanism for Na⁺ storage has been revealed in metal hydroxides, rather than the routinely believed conversion reaction presenting in lithium ion batteries.

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17

Gerold, Eva, Stefan Luidold, and Helmut Antrekowitsch. "Separation and Efficient Recovery of Lithium from Spent Lithium-Ion Batteries." Metals 11, no. 7 (July 8, 2021): 1091. http://dx.doi.org/10.3390/met11071091.

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The consumption of lithium has increased dramatically in recent years. This can be primarily attributed to its use in lithium-ion batteries for the operation of hybrid and electric vehicles. Due to its specific properties, lithium will also continue to be an indispensable key component for rechargeable batteries in the next decades. An average lithium-ion battery contains 5–7% of lithium. These values indicate that used rechargeable batteries are a high-quality raw material for lithium recovery. Currently, the feasibility and reasonability of the hydrometallurgical recycling of lithium from spent lithium-ion batteries is still a field of research. This work is intended to compare the classic method of the precipitation of lithium from synthetic and real pregnant leaching liquors gained from spent lithium-ion batteries with sodium carbonate (state of the art) with alternative precipitation agents such as sodium phosphate and potassium phosphate. Furthermore, the correlation of the obtained product to the used type of phosphate is comprised. In addition, the influence of the process temperature (room temperature to boiling point), as well as the stoichiometric factor of the precipitant, is investigated in order to finally enable a statement about an efficient process, its parameter and the main dependencies.

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18

Wang, Jianyi, Qi Kang, Jingchao Yuan, Qianru Fu, Chunhua Chen, Zibo Zhai, Yang Liu, Wei Yan, Aijun Li, and Jiujun Zhang. "Dendrite‐free lithium and sodium metal anodes with deep plating/stripping properties for lithium and sodium batteries." Carbon Energy 3, no. 1 (January 21, 2021): 153–66. http://dx.doi.org/10.1002/cey2.94.

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19

Wu, Zhenzhen, Jian Xie, Zhichuan J. Xu, Shanqing Zhang, and Qichun Zhang. "Recent progress in metal–organic polymers as promising electrodes for lithium/sodium rechargeable batteries." Journal of Materials Chemistry A 7, no. 9 (2019): 4259–90. http://dx.doi.org/10.1039/c8ta11994e.

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Recent progress in the usage of metal organic polymers (coordination polymers (CPs), metal–organic frameworks (MOFs), Prussian blue and Prussian blue analogues (PBAs)) as electrodes in Li/Na rechargeable batteries has been reviewed.

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20

Ahn, Byeong-Min, Cheol-Woo Ahn, Byung-Dong Hahn, Jong-Jin Choi, Yang-Do Kim, Sung-Ki Lim, and Joon-Hwan Choi. "Effect of Cathode Microstructure on Electrochemical Properties of Sodium Nickel-Iron Chloride Batteries." Materials 14, no. 19 (September 27, 2021): 5605. http://dx.doi.org/10.3390/ma14195605.

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Sodium metal chloride batteries have become a substantial focus area in the research on prospective alternatives for battery energy storage systems (BESSs) since they are more stable than lithium ion batteries. This study demonstrates the effects of the cathode microstructure on the electrochemical properties of sodium metal chloride cells. The cathode powder is manufactured in the form of granules composed of a metal active material and NaCl, and the ionic conductivity is attained by filling the interiors of the granules with a second electrolyte (NaAlCl4). Thus, the microstructure of the cathode powder had to be optimized to ensure that the second electrolyte effectively penetrated the cathode granules. The microstructure was modified by selecting the NaCl size and density of the cathode granules, and the resulting Na/(Ni,Fe)Cl2 cell showed a high capacity of 224 mAh g−1 at the 100th cycle owing to microstructural improvements. These findings demonstrate that control of the cathode microstructure is essential when cathode powders are used to manufacture sodium metal chloride batteries.

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21

Lu, Yao, Meltem Yanilmaz, Chen Chen, Yeqian Ge, Mahmut Dirican, Jiadeng Zhu, Yongqiang Li, and Xiangwu Zhang. "Lithium-substituted sodium layered transition metal oxide fibers as cathodes for sodium-ion batteries." Energy Storage Materials 1 (November 2015): 74–81. http://dx.doi.org/10.1016/j.ensm.2015.09.005.

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22

Tabuyo-Martínez, Marina, Bernd Wicklein, and Pilar Aranda. "Progress and innovation of nanostructured sulfur cathodes and metal-free anodes for room-temperature Na–S batteries." Beilstein Journal of Nanotechnology 12 (September 9, 2021): 995–1020. http://dx.doi.org/10.3762/bjnano.12.75.

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Rechargeable batteries are a major element in the transition to renewable energie systems, but the current lithium-ion battery technology may face limitations in the future concerning the availability of raw materials and socio-economic insecurities. Sodium–sulfur (Na–S) batteries are a promising alternative energy storage device for small- to large-scale applications driven by more favorable environmental and economic perspectives. However, scientific and technological problems are still hindering a commercial breakthrough of these batteries. This review discusses strategies to remedy some of the current drawbacks such as the polysulfide shuttle effect, catastrophic volume expansion, Na dendrite growth, and slow reaction kinetics by nanostructuring both the sulfur cathode and the Na anode. Moreover, a survey of recent patents on room temperature (RT) Na–S batteries revealed that nanostructured sulfur and sodium electrodes are still in the minority, which suggests that much investigation and innovation is needed until RT Na–S batteries can be commercialized.

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23

Obrezkov, Filipp A., Alexander F. Shestakov, Valerii F. Traven, Keith J. Stevenson, and Pavel A. Troshin. "An ultrafast charging polyphenylamine-based cathode material for high rate lithium, sodium and potassium batteries." Journal of Materials Chemistry A 7, no. 18 (2019): 11430–37. http://dx.doi.org/10.1039/c8ta11572a.

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24

Pham, Viet Hung, J. Anibal Boscoboinik, Dario J. Stacchiola, Ethan C. Self, Palanisamy Manikandan, Sudhan Nagarajan, Yixian Wang, et al. "Selenium-sulfur (SeS) fast charging cathode for sodium and lithium metal batteries." Energy Storage Materials 20 (July 2019): 71–79. http://dx.doi.org/10.1016/j.ensm.2019.04.021.

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25

Jiang, Bowen, Ying Wei, Jingyi Wu, Hang Cheng, Lixia Yuan, Zhen Li, Henghui Xu, and Yunhui Huang. "Recent progress of asymmetric solid-state electrolytes for lithium/sodium-metal batteries." EnergyChem 3, no. 5 (September 2021): 100058. http://dx.doi.org/10.1016/j.enchem.2021.100058.

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26

Malovanyy, Sergiy. "CATHODE MATERIALS OF ROCK SALT DERIVATIVE STRUCTURES FOR SODIUM-ION SECONDARY POWER SOURCES." Ukrainian Chemistry Journal 85, no. 9 (October 16, 2019): 44–57. http://dx.doi.org/10.33609/0041-6045.85.9.2019.44-57.

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The rechargeable lithium-ion batteries have been dominating the portable electronic market for the past two decades with high energy density and long cycle-life. However, applications of lithium-ion batteries in large-scale stationary energy storage are likely to be limited by the high cost and availability of lithium resources. The room temperature Na-ion secondary battery have received extensive investigations for large-scale energy storage systems (EESs) and smart grids lately due to similar chemistry of “rocking-chair” sodium storage mechanism, lower price and huge abundance. They are considered as an alternative to lithium-ion batteries for large-scale applications, bringing an increasing research interests in materials for sodium-ion batteries. Although there are many obstacles to overcome before the Na-ion battery becomes commercially available, recent research discoveries corroborate that some of the cathode materials for the Na-ion battery have indeed advantages over its Li-ion competitors. Layered oxides are promising cathode materials for sodium ion batteries because of their high theoretical capacities. In this publication, a review of layered oxides (NaxMO2, M = V, Cr, Mn, Fe, Co, Ni, and a mixture of 2 or 3 elements) as a Na-ion battery cathode is presented. O3 and P2 layered sodium transition metal oxides NaxMO2 are a promising class of cathode materials for Na secondary battery applications. These materials, however, all suffer from capacity decline when the extraction of Na exceeds certain capacity limits. Understanding the causes of this capacity decay is critical to unlocking the potential of these materials for battery applications. Single layered oxide systems are well characterized not only for their electrochemical performance, but also for their structural transitions during the cycle. Binary oxides systems are investigated in order to address issues regarding low reversible capacity, capacity retention, operating voltage, and structural stability. Some materials already have reached high energy density, which is comparable to that of LiFePO4. On the other hand, the carefully chosen elements in the electrodes also largely determine the cost of SIBs. Therefore, earth abundant-based compounds are ideal candidates for reducing the cost of electrodes. Among all low-cost metal elements, cathodes containing iron, chromium and manganese are the most representative ones. The aim of the article is to present the development of Na layered oxide materials in the past as well as the state of the art today.

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Mongird, Kendall, Vilayanur Viswanathan, Patrick Balducci, Jan Alam, Vanshika Fotedar, Vladimir Koritarov, and Boualem Hadjerioua. "An Evaluation of Energy Storage Cost and Performance Characteristics." Energies 13, no. 13 (June 28, 2020): 3307. http://dx.doi.org/10.3390/en13133307.

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The energy storage industry has expanded globally as costs continue to fall and opportunities in consumer, transportation, and grid applications are defined. As the rapid evolution of the industry continues, it has become increasingly important to understand how varying technologies compare in terms of cost and performance. This paper defines and evaluates cost and performance parameters of six battery energy storage technologies (BESS)—lithium-ion batteries, lead-acid batteries, redox flow batteries, sodium-sulfur batteries, sodium-metal halide batteries, and zinc-hybrid cathode batteries—four non-BESS storage systems—pumped storage hydropower, flywheels, compressed air energy storage, and ultracapacitors—and combustion turbines. Cost and performance information was compiled based on an extensive literature review, conversations with vendors and stakeholders, and costs of systems procured at sites across the United States. Detailed cost and performance estimates are presented for 2018 and projected out to 2025. Annualized costs were also calculated for each technology.

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28

Wu, Na, Yu-Jing Yang, Ting Jia, Tao-Hai Li, Feng Li, and Zhe Wang. "Sodium–tin metal–organic framework anode material with advanced lithium storage properties for lithium-ion batteries." Journal of Materials Science 55, no. 14 (February 18, 2020): 6030–36. http://dx.doi.org/10.1007/s10853-020-04436-6.

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29

Wang, Haidong, Qiong Wu, Yunong Wang, Xiaoling Lv, and Heng-guo Wang. "A redox-active metal–organic compound for lithium/sodium-based dual-ion batteries." Journal of Colloid and Interface Science 606 (January 2022): 1024–30. http://dx.doi.org/10.1016/j.jcis.2021.08.113.

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30

Allan, Phoebe, John Griffin, Olaf Borkiewicz, Kamila Wiaderek, Ali Darwiche, Joshua Stratford, Karena Chapman, Peter Chupas, Laure Monconduit, and Clare Grey. "In situ PDF and solid-state NMR studies of antimony anodes for Na-ion batteries." Acta Crystallographica Section A Foundations and Advances 70, a1 (August 5, 2014): C354. http://dx.doi.org/10.1107/s2053273314096454.

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Sodium-ion batteries have attracted attention in recent years because of the natural abundance of sodium compared to lithium, making them particularly attractive in applications such as large-scale grid storage where low cost and sustainability, rather than light weight is the key issue [1]. Several materials have been suggested as cathodes but far fewer studies have been done on anode materials and, because of the reluctance of sodium to intercalate into graphite, the anode material of choice in commercial lithium-ion batteries, the anode represents a significant challenge to this technology. Materials which form alloys with sodium, particularly tin and antimony, have been suggested as anode materials; their ability to react with multiple sodium ions per metal-atom give potential for high gravimetric capacities[2]. However, relatively little is known about the reaction mechanism in the battery, primarily due to drastic reduction in crystallinity during (dis)charging conditions, but also because the structures formed on electrochemical cycling may not be alloys known to exist under ambient conditions. In this study, we present a study of antimony as an anode in sodium-ion batteries, using in situ pair distribution function (PDF) analysis combined with ex situ solid-state nuclear magnetic resonance studies. PDF experiments were performed at 11-ID-B, APS using the AMPIX electrochemical cell [3], cycling against sodium metal. Inclusion of diffuse scattering in analysis is able to circumvent some of the issues of crystallinity loss, and gain information about the local structure in all regions, independent of the presence of long-range order in the material. This approach has been used to probe local correlations in previously uncharacterised regions of the electrochemical profile and analyse phase progression over the full charge cycle. This analysis has been linked with ex situ 23Na solid-state NMR experiments to examine the local environment of the sodium; these show evidence of known NaxSb phases but indicate additional metastable phases may be present at partial discharge.

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Mauger, Alain, and Christian M. Julien. "State-of-the-Art Electrode Materials for Sodium-Ion Batteries." Materials 13, no. 16 (August 5, 2020): 3453. http://dx.doi.org/10.3390/ma13163453.

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Sodium-ion batteries (SIBs) were investigated as recently as in the seventies. However, they have been overshadowed for decades, due to the success of lithium-ion batteries that demonstrated higher energy densities and longer cycle lives. Since then, the witness a re-emergence of the SIBs and renewed interest evidenced by an exponential increase of the publications devoted to them (about 9000 publications in 2019, more than 6000 in the first six months this year). This huge effort in research has led and is leading to an important and constant progress in the performance of the SIBs, which have conquered an industrial market and are now commercialized. This progress concerns all the elements of the batteries. We have already recently reviewed the salts and electrolytes, including solid electrolytes to build all-solid-state SIBs. The present review is then devoted to the electrode materials. For anodes, they include carbons, metal chalcogenide-based materials, intercalation-based and conversion reaction compounds (transition metal oxides and sulfides), intermetallic compounds serving as functional alloying elements. For cathodes, layered oxide materials, polyionic compounds, sulfates, pyrophosphates and Prussian blue analogs are reviewed. The electrode structuring is also discussed, as it impacts, importantly, the electrochemical performance. Attention is focused on the progress made in the last five years to report the state-of-the-art in the performance of the SIBs and justify the efforts of research.

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Ponrouch, Alexandre, and M. Rosa Palacín. "Post-Li batteries: promises and challenges." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 377, no. 2152 (July 8, 2019): 20180297. http://dx.doi.org/10.1098/rsta.2018.0297.

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Current societal challenges in terms of energy storage have prompted an intensification in the research aiming at unravelling new high energy density battery technologies. These would have the potential of having disruptive effects in the world transition towards a less carbon-dependent energy economy through transport, both by electrification and renewable energy integration. Aside from controversial debates on lithium supply, the development of new sustainable battery chemistries based on abundant elements is appealing, especially for large-scale stationary applications. Interesting alternatives are to use sodium, magnesium or calcium instead of lithium. While for the Na-ion case, fast progresses are expected as a result of chemical similarities with lithium and the cumulated Li-ion battery know-how over the years, for Ca and Mg the situation is radically different. On the one hand, the possibility to use Ca or Mg metal anodes would bring a breakthrough in terms of energy density; on the other, development of suitable electrolytes and cathodes with efficient multivalent ion migration are bottlenecks to overcome. This article is part of a discussion meeting issue ‘Energy materials for a low carbon future’.

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Matsukawa, Yuko, Fabian Linsenmann, Maximilian Arthur Plass, George Hasegawa, Katsuro Hayashi, and Tim-Patrick Fellinger. "Gas sorption porosimetry for the evaluation of hard carbons as anodes for Li- and Na-ion batteries." Beilstein Journal of Nanotechnology 11 (August 14, 2020): 1217–29. http://dx.doi.org/10.3762/bjnano.11.106.

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Hard carbons are promising candidates for high-capacity anode materials in alkali metal-ion batteries, such as lithium- and sodium-ion batteries. High reversible capacities are often coming along with high irreversible capacity losses during the first cycles, limiting commercial viability. The trade-off to maximize the reversible capacities and simultaneously minimizing irreversible losses can be achieved by tuning the exact architecture of the subnanometric pore system inside the carbon particles. Since the characterization of small pores is nontrivial, we herein employ Kr, N2 and CO2 gas sorption porosimetry, as well as H2O vapor sorption porosimetry, to investigate eight hard carbons. Electrochemical lithium as well as sodium storage tests are compared to the obtained apparent surface areas and pore volumes. H2O, and more importantly CO2, sorption porosimetry turned out to be the preferred methods to evaluate the likelihood for excessive irreversible capacities. The methods are also useful to select the relatively most promising active materials within chemically similar materials. A quantitative relation of porosity descriptors to the obtained capacities remains a scientific challenge.

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Fang, Shan, Dominic Bresser, and Stefano Passerini. "Transition Metal Oxide Anodes for Electrochemical Energy Storage in Lithium‐ and Sodium‐Ion Batteries." Advanced Energy Materials 10, no. 1 (November 18, 2019): 1902485. http://dx.doi.org/10.1002/aenm.201902485.

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35

Hou, Tianyi, Borui Liu, Xiaohong Sun, Anran Fan, Zhongkai Xu, Shu Cai, Chunming Zheng, Guihua Yu, and Antonio Tricoli. "Covalent Coupling-Stabilized Transition-Metal Sulfide/Carbon Nanotube Composites for Lithium/Sodium-Ion Batteries." ACS Nano 15, no. 4 (March 19, 2021): 6735–46. http://dx.doi.org/10.1021/acsnano.0c10121.

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36

Dranka, Maciej, and Janusz Zachara. "Coordination modes of novel 4,5-dicyanoimidazolato ligand in alkali metal salts." Acta Crystallographica Section A Foundations and Advances 70, a1 (August 5, 2014): C650. http://dx.doi.org/10.1107/s2053273314093498.

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As the use of lithium batteries became more and more wide-spread, the importance of the research on novel salts for batteries' electrolytes grew more and more important. The focus has been put on designing novel lithium and sodium salts which dissociate well in aprotic solvents and are electrochemically and thermally stable. Salts with heteroaromatic anions such as 2-trifluoromethane-4,5-dicyanoimidazolate (LiTDI) [1,2] are a promising alternative for the salts commonly used as charge carriers in lithium and sodium batteries. The class of new 4,5-dicyanoimidazolates ligands is based on N-heterocyclic five-membered ring substituted with nitrile group. Such a type of anions possesses four nitrogen donor centers able to coordinate cation, and is characterized by charge delocalization, both on imidazole ring and cyano substituents resulting in extended π electron system. In solid as well as liquid electrolytes one should expect the co-existence of a variety of ionic species, such as iosolated anions and cations solvated by solvent molecules, ionic pairs, for which the coordination sphere of cations is completed with solvent molecules, as well as dimers and aggregates with varied stoichiometry. The observed degree of aggregation depends mostly on the coordination properties of anions, their ability to form hydrogen bonds and their compatibility with the acidic properties of cations. The increase of the salt concentration should result in association process and the emergence of higher aggregates, up to polymeric systems, possessing structure of chains, ribbons, layers or networks. In order to define the coordination ability of the class of new ligands, we examined their organization modes in the alkali metal salts and have found a wide variety of mentioned motifs. Discovering and understanding the phenomena related to the organization of such systems in the solid state is crucial for the elaboration of novel electrolytes and should give information about cation and anion coordination in electrolytes. Our single-crystal diffraction studies have shown that new salts comprising 4,5-dicyano-2-(trifluoromethyl)imidazolato anion are interesting from the point of view of their crystalline structure, offering variety of possible coordination modes and are, therefore, worthy of examination.

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Xu, Qian, Yifu Yang, and Huixia Shao. "Enhanced cycleability and dendrite-free lithium deposition by addition of sodium ion in electrolyte for lithium metal batteries." Electrochimica Acta 271 (May 2018): 617–23. http://dx.doi.org/10.1016/j.electacta.2018.03.182.

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38

Chen, Yalan, Jingtong Zhang, Haijun Liu, and Zhaojie Wang. "Controlled Synthesis of FeSe2 Nanoflakes Toward Advanced Sodium Storage Behavior Integrated with Ether-Based Electrolyte." Nano 13, no. 12 (December 2018): 1850141. http://dx.doi.org/10.1142/s1793292018501412.

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Sodium ion batteries based on the more sodium source reserve than that of lithium have been designed as promising alternatives to lithium ion batteries. However, several problems including unsatisfied specific capacity and serious cyclic stability must be solved before the reality. One of the effective approaches to solve the abovementioned problems is to search for suitable anode materials. In this work, we designed and prepared FeSe2 nanoflakes via a simple hydrothermal method which can be adjusted in composition by Fe precursor. As a potential anode for sodium storage, the optimized FeSe2 electrode was further evaluated in different electrolytes of NaClO4 in propylene carbonate/fluoroethylene carbonate and NaCF3SO3 in diethylene glycol dimethyl ether. The capacity was about 470[Formula: see text]mAh[Formula: see text]g[Formula: see text] and 535[Formula: see text]mAh[Formula: see text]g[Formula: see text] at 0.5[Formula: see text]A[Formula: see text]g[Formula: see text], respectively, in the voltage between 0.5[Formula: see text]V and 2.9[Formula: see text]V in the cycle of stabilization phase. Superior performance both in capacity and in stability was obtained in ether-based electrolyte, which affords the property without plugging the intermediates of transition metal dichalcogenides during charge/discharge processes.

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Dong, Caifu, and Liqiang Xu. "Cobalt- and Cadmium-Based Metal–Organic Frameworks as High-Performance Anodes for Sodium Ion Batteries and Lithium Ion Batteries." ACS Applied Materials & Interfaces 9, no. 8 (February 16, 2017): 7160–68. http://dx.doi.org/10.1021/acsami.6b15757.

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40

Huang, Long, Peng Huang, Peng Chen, and Yuan-Li Ding. "Metal nanodots anchored on carbon nanotubes prepared by a facile solid-state redox strategy for superior lithium storage." Functional Materials Letters 13, no. 06 (July 30, 2020): 2051039. http://dx.doi.org/10.1142/s179360472051039x.

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Alloying-based electrode materials (e.g. Si, Sn, Sb, Bi, etc.) are the promising anode candidates for next-generation lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) owing to their high specific capacities, but they suffer from huge volume changes upon lithium/sodium insertion/extraction processes. On the other hand, such alloying anodes usually require a complicated and high energy-consumption synthesis process (e.g. Si anode by a magnesiothermic reduction at over [Formula: see text]C, Sn, Sb and Bi anodes by a high-temperature carbothermic reduction at 600–[Formula: see text]C), thus limiting their practical application for replacing low-cost graphite. In this work, we develop a straightforward solid-state strategy for a general synthesis of metal nanodots (Sn, Sb and Bi) supported on carbon nanotubes (CNTs) by using the reduction potential differences of metal salts and NaBH4 as the reaction power at room temperature. Owing to the very mild reaction, the resulted active component is small enough (2–5[Formula: see text]nm) with diffusion-less and nucleation-less barriers upon alloying/dealloying reaction, thus enabling high electrode stability and high capacity retention. Taking Sn anode as an example, the obtained Sn/CNTs deliver a high reversible capacity of 415[Formula: see text]mAh g[Formula: see text] at 0.5[Formula: see text]A g[Formula: see text] after 1000 cycles without obvious capacity decay. Such findings indicate that the proposed solid-state synthetic method could offer a great potential for realizing large-scale and economic applications of energy storage materials.

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Santangelo, Saveria. "Electrospun Nanomaterials for Energy Applications: Recent Advances." Applied Sciences 9, no. 6 (March 13, 2019): 1049. http://dx.doi.org/10.3390/app9061049.

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Electrospinning is a simple, versatile, cost-effective, and scalable technique for the growth of highly porous nanofibers. These nanostructures, featured by high aspect ratio, may exhibit a large variety of different sizes, morphologies, composition, and physicochemical properties. By proper post-spinning heat treatment(s), self-standing fibrous mats can also be produced. Large surface area and high porosity make electrospun nanomaterials (both fibers and three-dimensional fiber networks) particularly suitable to numerous energy-related applications. Relevant results and recent advances achieved by their use in rechargeable lithium- and sodium-ion batteries, redox flow batteries, metal-air batteries, supercapacitors, reactors for water desalination via capacitive deionization and for hydrogen production by water splitting, as well as nanogenerators for energy harvesting, and textiles for energy saving will be presented and the future prospects for the large-scale application of electrospun nanomaterials will be discussed.

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42

Sun, Jinhua, Matthew Sadd, Philip Edenborg, Henrik Grönbeck, Peter H. Thiesen, Zhenyuan Xia, Vanesa Quintano, Ren Qiu, Aleksandar Matic, and Vincenzo Palermo. "Real-time imaging of Na+ reversible intercalation in “Janus” graphene stacks for battery applications." Science Advances 7, no. 22 (May 2021): eabf0812. http://dx.doi.org/10.1126/sciadv.abf0812.

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Sodium, in contrast to other metals, cannot intercalate in graphite, hindering the use of this cheap, abundant element in rechargeable batteries. Here, we report a nanometric graphite-like anode for Na+ storage, formed by stacked graphene sheets functionalized only on one side, termed Janus graphene. The asymmetric functionalization allows reversible intercalation of Na+, as monitored by operando Raman spectroelectrochemistry and visualized by imaging ellipsometry. Our Janus graphene has uniform pore size, controllable functionalization density, and few edges; it can store Na+ differently from graphite and stacked graphene. Density functional theory calculations demonstrate that Na+ preferably rests close to -NH2 group forming synergic ionic bonds to graphene, making the interaction process energetically favorable. The estimated sodium storage up to C6.9Na is comparable to graphite for standard lithium ion batteries. Given such encouraging Na+ reversible intercalation behavior, our approach provides a way to design carbon-based materials for sodium ion batteries.

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43

Zhao, Weijie. "A forum on batteries: from lithium-ion to the next generation." National Science Review 7, no. 7 (April 17, 2020): 1263–68. http://dx.doi.org/10.1093/nsr/nwaa068.

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ABSTRACT The 2019 Nobel Prize in Chemistry was awarded to three pioneers of lithium-ion batteries (LIBs)—Prof. John B. Goodenough at the University of Texas, Prof. M. Stanley Whittingham at the State University of New York and Mr. Akira Yoshino at the Asahi Corporation of Japan, which is a great encouragement to the whole field. LIBs have been developed for several decades with the progress slowing down and their performances approaching some theoretical limits. On the other hand, new types of batteries or power systems, including solid-state batteries, sodium-ion batteries, lithium-sulfur batteries and fuel cells, are being steadily developed, offering new choices for divergent applications. In this panel discussion chaired by NSR editorial board member Huiming Cheng, battery experts gather to discuss the challenges and trends of LIBs, the developments and applications of next-generation batteries, as well as the status quo of the battery research and industry in China. Jun Chen Professor of the College of Chemistry, Nankai University, Tianjin, China Yunhui Huang Professor of the School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, China Hong Li Professor of the Institute of Physics, Chinese Academy of Sciences, Beijing, China Shigang Sun Professor of the College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China Hongli Zhang Director of the R&D Institute of Battery, Gotion High-Tech Power Energy Co., Ltd., Hefei, China Huiming Cheng (Chair) Professor of the Shenzhen Geim Graphene Center, Tsinghua-Berkeley Shenzhen Institute, Tsinghua University, Shenzhen, China; Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, China

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44

Tao, Shi, Dajun Wu, Shuangming Chen, Bin Qian, Wangsheng Chu, and Li Song. "A versatile strategy for ultrathin SnS2 nanosheets confined in a N-doped graphene sheet composite for high performance lithium and sodium-ion batteries." Chemical Communications 54, no. 60 (2018): 8379–82. http://dx.doi.org/10.1039/c8cc04255a.

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Ultrathin SnS₂ nanosheets confined in N-doped graphene sheets composite is synthesized by using a simple thermal decomposition method and as excellent electrodes for lithium/sodium-ion batteries.

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45

Zhang, Qiu, Yanying Lu, Licheng Miao, Qing Zhao, Kexin Xia, Jing Liang, Shu-Lei Chou, and Jun Chen. "An Alternative to Lithium Metal Anodes: Non-dendritic and Highly Reversible Sodium Metal Anodes for Li-Na Hybrid Batteries." Angewandte Chemie 130, no. 45 (October 9, 2018): 15012–16. http://dx.doi.org/10.1002/ange.201808592.

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46

Zhang, Qiu, Yanying Lu, Licheng Miao, Qing Zhao, Kexin Xia, Jing Liang, Shu-Lei Chou, and Jun Chen. "An Alternative to Lithium Metal Anodes: Non-dendritic and Highly Reversible Sodium Metal Anodes for Li-Na Hybrid Batteries." Angewandte Chemie International Edition 57, no. 45 (October 9, 2018): 14796–800. http://dx.doi.org/10.1002/anie.201808592.

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47

Wang, Ji Eun, Young Hwa Jung, and Do-Kyung Kim. "Exploring Lithium Doping in the Layered Transition-Metal Oxides As Cathode Materials for Sodium-Ion Batteries." ECS Meeting Abstracts MA2020-02, no. 1 (November 23, 2020): 107. http://dx.doi.org/10.1149/ma2020-021107mtgabs.

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48

Wang, Lei, Xuan Xie, Khang Ngoc Dinh, Qingyu Yan, and Jianmin Ma. "Synthesis, characterizations, and utilization of oxygen-deficient metal oxides for lithium/sodium-ion batteries and supercapacitors." Coordination Chemistry Reviews 397 (October 2019): 138–67. http://dx.doi.org/10.1016/j.ccr.2019.06.015.

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49

Pendashteh, Afshin, Brahim Orayech, Jon Ajuria, María Jáuregui, and Damien Saurel. "Exploring Vinyl Polymers as Soft Carbon Precursors for M-Ion (M = Na, Li) Batteries and Hybrid Capacitors." Energies 13, no. 16 (August 13, 2020): 4189. http://dx.doi.org/10.3390/en13164189.

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The viability of the sodium-ion batteries as a post-lithium storage technology is strongly tied to the development of high-performance carbonaceous anode materials. This requires screening novel precursors, and tuning their electrochemical properties. Soft carbons as promising anode materials, not only for batteries, but also in hybrid capacitors, have drawn great attention, due to safe operation voltage and high-power properties. Herein, several vinyl polymer-derived soft carbons have been prepared via pyrolysis, and their physicochemical and sodium storage properties have been evaluated. According to the obtained results, vinyl polymers are a promising source for preparation of soft carbon anode materials for sodium-ion battery application. In addition, their applicability towards Li-ion battery and hybrid capacitors (e.g., Li ion capacitors, LICs) has been examined. This work not only contrasts the carbonization products of these polymers with relevant physicochemical characterization, but also screens potential precursors for soft carbons with interesting alkali metal-ion (e.g., Na or Li, with an emphasis on Na) storage properties. This can stimulate further research to tune and improve the electrochemical properties of the soft carbons for energy storage applications.

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Zhu, Na, Kun Zhang, Feng Wu, Ying Bai, and Chuan Wu. "Ionic Liquid-Based Electrolytes for Aluminum/Magnesium/Sodium-Ion Batteries." Energy Material Advances 2021 (February 17, 2021): 1–29. http://dx.doi.org/10.34133/2021/9204217.

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Developing post-lithium-ion battery technology featured with high raw material abundance and low cost is extremely important for the large-scale energy storage applications, especially for the metal-based battery systems such as aluminum, sodium, and magnesium ion batteries. However, their developments are still in early stages, and one of the major challenges is to explore a safe and reliable electrolyte. An ionic liquid-based electrolyte is attractive and promising for developing safe and nonflammable devices with wide temperature ranges owing to their several unique properties such as ultralow volatility, high ionic conductivity, good thermal stability, low flammability, a wide electrochemical window, and tunable polarity and basicity/acidity. In this review, the recent emerging limitations and strategies of ionic liquid-based electrolytes in the above battery systems are summarized. In particular, for aluminum-ion batteries, the interfacial reaction between ionic liquid-based electrolytes and the electrode, the mechanism of aluminum storage, and the optimization of electrolyte composition are fully discussed. Moreover, the strategies to solve the problems of electrolyte corrosion and battery system side reactions are also highlighted. Finally, a general conclusion and a perspective focusing on the current development limitations and directions of ionic liquid-based electrolytes are proposed along with an outlook. In order to develop novel high-performance ionic liquid electrolytes, we need in-depth understanding and research on their fundamentals, paving the way for designing next-generation products.

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