Academic literature on the topic 'Ligands; transition metal complexes'

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Journal articles on the topic "Ligands; transition metal complexes"

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Pierpont, Cortlandt G., and Attia S. Attia. "Spin Coupling Interactions in Transition Metal Complexes Containing Radical o-Semiquinone Ligands. A Review." Collection of Czechoslovak Chemical Communications 66, no. 1 (2001): 33–51. http://dx.doi.org/10.1135/cccc20010033.

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Transition metal complexes ofo-semiquinone (SQ) ligands have been studied extensively over the past 25 years. A particularly interesting aspect of this coordination chemistry concerns magnetic interactions between paramagnetic metal ions and the radical anionic ligands. In this review we begin with a survey of relatively simple complexes consisting of a paramagnetic metal ion chelated by a single SQ ligand. Recent studies have revealed the importance of SQ-SQ coupling through diamagnetic metals, and complexes of this class are described in the second section of the review. Both interactions co
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Sasmal, Ashok, Eugenio Garribba, Carlos J. Gómez-García, Cédric Desplanches, and Samiran Mitra. "Switching and redox isomerism in first-row transition metal complexes containing redox active Schiff base ligands." Dalton Trans. 43, no. 42 (2014): 15958–67. http://dx.doi.org/10.1039/c4dt01699h.

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Switching and redox isomerism in first row transition metal complexes through the metal-to-ligand or ligand-to-ligand electron transfer stabilize redox isomeric forms in transition metal complexes with redox-active ligands.
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Sellmann, Dieter, Herbert Binder, Daniel Häußinger, Frank W. Heinemann, and Jörg Sutter. "Transition metal complexes with sulfur ligands." Inorganica Chimica Acta 300-302 (April 2000): 829–36. http://dx.doi.org/10.1016/s0020-1693(99)00608-8.

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Sivaev, Igor B., Marina Yu Stogniy, and Vladimir I. Bregadze. "Transition metal complexes with carboranylphosphine ligands." Coordination Chemistry Reviews 436 (June 2021): 213795. http://dx.doi.org/10.1016/j.ccr.2021.213795.

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Sumrra, Sajjad Hussain, Muhammad Ibrahim, Sabahat Ambreen, Muhammad Imran, Muhammad Danish, and Fouzia Sultana Rehmani. "Synthesis, Spectral Characterization, and Biological Evaluation of Transition Metal Complexes of Bidentate N, O Donor Schiff Bases." Bioinorganic Chemistry and Applications 2014 (2014): 1–10. http://dx.doi.org/10.1155/2014/812924.

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New series of three bidentate N, O donor type Schiff bases(L1)–(L3)were prepared by using ethylene-1,2-diamine with 5-methyl furfural, 2-anisaldehyde, and 2-hydroxybenzaldehyde in an equimolar ratio. These ligands were further complexed with Co(II), Cu(II), Ni(II), and Zn(II) metals to produce their new metal complexes having an octahedral geometry. These compounds were characterized on the basis of their physical, spectral, and analytical data. Elemental analysis and spectral data of the uncomplexed ligands and their metal(II) complexes were found to be in good agreement with their structures
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Ye-gao, Yin, Huang Zu-yun, Cheung Kung-kai, and Wong Wing-tak. "Ligand-metal interaction in transition-metal complexes with tripodal polyaza ligands." Wuhan University Journal of Natural Sciences 4, no. 4 (1999): 477–81. http://dx.doi.org/10.1007/bf02832289.

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Zhao, Lili, Chaoqun Chai, Wolfgang Petz, and Gernot Frenking. "Carbones and Carbon Atom as Ligands in Transition Metal Complexes." Molecules 25, no. 21 (2020): 4943. http://dx.doi.org/10.3390/molecules25214943.

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This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL2 as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (σ and π) donation to the metal atom [M]⇇CL2. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR3 → [M]-CR2 → [M]-CR → [M]-C. This review includes some work on uranium and cerium complexes, but i
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Prananto, Yuniar P., Aron Urbatsch, Boujemaa Moubaraki, et al. "Transition Metal Thiocyanate Complexes of Picolylcyanoacetamides." Australian Journal of Chemistry 70, no. 5 (2017): 516. http://dx.doi.org/10.1071/ch16648.

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A variety of transition metal complexes involving picolylcyanoacetamides (pica = NCCH2CONH-R; R = 2-picolyl- (2pica), 3-picolyl- (3pica), 4-picolyl- (4pica)) and thiocyanate have been synthesised and their solid-state structures have been determined. The complexes were all obtained from reactions between the corresponding metals salts and pica ligands with sodium thiocyanate under ambient conditions. Both 3pica and 4pica coordinate to the metal solely through the nitrogen atom of the picolyl group and form discrete tetrahedral [M(NCS)2(pica)2] (3pica; M = Mn, Zn; 4pica; M = Co) and octahedral
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Salzer, A. "Nomenclature of Organometallic Compounds of the Transition Elements (IUPAC Recommendations 1999)." Pure and Applied Chemistry 71, no. 8 (1999): 1557–85. http://dx.doi.org/10.1351/pac199971081557.

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Organometallic compounds are defined as containing at least one metal-carbon bond between an organic molecule, ion, or radical and a metal. Organometallic nomenclature therefore usually combines the nomenclature of organic chemisty and that of coordination chemistry. Provisional rules outlining nomenclature for such compounds are found both in Nomenclature of Organic Chemistry, 1979 and in Nomenclature of Inorganic Chemistry, 1990This document describes the nomenclature for organometallic compounds of the transition elements, that is compounds with metal-carbon single bonds, metal-carbon multi
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Leovac, V. M., E. Z. Ivegeš, K. Mészáros Szécsényi, K. Tomor, G. Pokol, and S. Gal. "Transition metal complexes with thiosemicarbazide-based ligands." Journal of thermal analysis 50, no. 3 (1997): 431–40. http://dx.doi.org/10.1007/bf01980503.

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Dissertations / Theses on the topic "Ligands; transition metal complexes"

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Cheung, Wai Man. "Transition metal complexes with dichalcogenoimidodiphosphinate ligands /." View abstract or full-text, 2007. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202007%20CHEUNG.

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Skinner, Michael E. G. "Transition metal complexes of diamide-diamine ligands." Thesis, University of Oxford, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.365390.

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Seidel, Scott William 1971. "Transition metal complexes containing chelating amido ligands." Thesis, Massachusetts Institute of Technology, 1998. http://hdl.handle.net/1721.1/47411.

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Olson, Michael David. "Pyrazolyl based ligands in transition metal complexes." Thesis, University of British Columbia, 1989. http://hdl.handle.net/2429/27610.

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Several uninegative/ multidentate pyrazolyl based ligands were synthesized [eg. HBPZ₃₋, HBpz”₃₋, MeGapz₃₋/ MeGapz” ₃₋, H2BpZ₂₋/ Me2Bpz₂₋/ Me2GapZ₂₋/ Me2Gapz"₂₋/ Me₂Gapz(OCH₂CH₂NH₂)⁻Me₂Gapz(OCH₂CH₂CH=CH₂)⁻ ; pz pyrazolyl/ pz" = 3, 5 dimethylpyrazolyl]. These ligands were reacted with the sterically hindered metal complex, HBpz*₃MCl (M = Co, Ni; pz* = 3-iPr-4-Br-pyrazolyl) and the mixed-ligand transition metal complexes of general formulae, HBpz*₃ML, were isolated. The X-ray crystal structure of one such complex, HBpz*₃Nipz"₃BH was determined showing a near octahedral arrangement of ligands abo
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Lawrence, Sally. "Early transition metal complexes of pyrazole-derived ligands." Thesis, University of Oxford, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.433560.

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Franks, Mark A. "Transition metal complexes containing phenylthiolate and phenolate ligands." Thesis, University of Nottingham, 2011. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.580393.

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Chapter 1 provides an introduction to metalloenzymes that either feature active sites containing Ni-thiolate ligation or utilise phenoxyl radicals to perform their catalytic function, with a particular emphasis on the enzymatic active sites of Ni-containing superoxide dismutase (Ni SOD), [NiFe] hydrogenase and galactose oxidase. Studies concerning low molecular weight complexes of each active site are reviewed and their relevance with respect to enzyme function discussed. Details of the project outline conclude the chapter. Chapter 2 details the syntheses and characterisation of the [Zn(tsalen
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Rivers, Christopher John. "Transition metal complexes incorporating trialkylsilyl substituted pentalene ligands." Thesis, University of Sussex, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.289228.

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Herring, A. M. "New transition metal complexes containing functionalised phosphine ligands." Thesis, University of Leeds, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383967.

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Ivison, Peter. "Transition metal complexes of hard-soft donor ligands." Thesis, Kingston University, 1992. http://eprints.kingston.ac.uk/20562/.

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Ghebregziabiher, Berhe Haile. "Synthesis of chiral thiourea ligands and their transition metal complexes." Thesis, Stellenbosch : Stellenbosch University, 2003. http://hdl.handle.net/10019.1/53610.

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Thesis (MSc)--Stellenbosch University, 2003.<br>ENGLISH ABSTRACT: Modification of chitosan with benzoylisothiocyanate was attempted, however due to solvent problem the study was left incomplete till appropriate solvent is designed. N,N-diethyl-N -camphanoylthiourea (HL8), N-piperidyl-N '-camphanoylthiourea (HL9), N-pyrrolidyl-N -camphanoylthiourea (HL10) and N,N-diethyl-N -adamantylcarbonyl thiourea (HL11)have been synthesised and characterised for the first time. Two of these ligands HL8 and HL11, were used to form a number of transition metal complexes, namely H30+{fae-[Co(L8-S,Obn, c
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Books on the topic "Ligands; transition metal complexes"

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Lane, H. P. Transition metal complexes of group fifteen donor ligands. UMIST, 1994.

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Chauvin, Remi, and Yves Canac, eds. Transition Metal Complexes of Neutral eta1-Carbon Ligands. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-04722-0.

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Nugent, William A. Metal-ligand multiple bonds: The chemistry of transition metal complexes containing oxo, nitrido, imido, alkylidene, or alkylidyne ligands. Wiley, 1988.

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Transition metal complexes of neutral [Eta]1-carbon ligands. Springer Verlag, 2010.

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Hawkins, Ian Michael. New transition metal complexes containing phosphine and sulphur ligands. University of East Anglia, 1988.

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Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Wiley, 2009.

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Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Wiley, 2010.

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Functionalised N-heterocyclic carbene complexes. Wiley, 2009.

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Kühl, Olaf. Functionalised N-heterocyclic carbene complexes. Wiley, 2009.

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Nugent, William A. Metal-ligandmultiple bonds: The chemistry of transition metal complexes containing oxo, nitrido, imido, alkylidene, or alkylidyne ligands. Wiley, 1988.

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Book chapters on the topic "Ligands; transition metal complexes"

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Cotton, F. A., and C. M. Lukehart. "Transition Metal Complexes Containing Carbenoid Ligands." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166178.ch3.

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Mayr, A. "The Role of Nucleophiles and Electrophiles in Coupling Reactions of Alkylidyne Ligands." In Transition Metal Carbyne Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_25.

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Lungwitz, B., and A. C. Filippou. "Electron-Rich Tungsten Aminocarbyne Complexes with Cp* Ligands Synthesis and Protonation Reactions." In Transition Metal Carbyne Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_28.

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Gilje, John W., and Roger E. Cramer. "Double and Triple Bonds to f-Elements: Structure and Chemistry of Actinide Complexes of Multielectron Pair Donor Ligands." In Transition Metal Carbyne Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_22.

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Hahn, James E. "Transition Metal Complexes Containing Bridging Alkylidene Ligands." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166321.ch3.

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Angelici, R. J. "Binding and Reactivity of Thiophene-Type Ligands in Transition Metal Complexes and Clusters." In Transition Metal Sulphides. Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-017-3577-3_4.

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Kaden, Th A. "Homo- and Heterobinuclear Metal Complexes with Bismacrocyclic Ligands." In Transition Metals in Supramolecular Chemistry. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-015-8380-0_11.

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Schrock, Richard R. "Alkylidene Complexes of the Earlier Transition Metals." In Reactions of Coordinated Ligands. Springer US, 1986. http://dx.doi.org/10.1007/978-1-4613-1785-2_3.

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Churchill, Melvyn R. "Transition Metal Complexes of Azulene and Related Ligands." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166123.ch2.

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Okuda, Jun. "Transition metal complexes of sterically demanding cyclopentadienyl ligands." In Topics in Current Chemistry. Springer Berlin Heidelberg, 1992. http://dx.doi.org/10.1007/3-540-54324-4_3.

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Conference papers on the topic "Ligands; transition metal complexes"

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Záliš, S., R. S. Winter, M. Linseis, et al. "DFT modeling of Spectral and Redox Properties of Di-and Tetranuclear Ruthenium Transition Metal Complexes with Bridging Ligands." In COMPUTATIONAL METHODS IN SCIENCE AND ENGINEERING: Advances in Computational Science: Lectures presented at the International Conference on Computational Methods in Sciences and Engineering 2008 (ICCMSE 2008). AIP, 2009. http://dx.doi.org/10.1063/1.3225297.

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Herber, Rolfe H. "Variable Temperature FTIR Spectroscopy Of Transition Metal Complexes Using The SCN Reporter Ligand." In Intl Conf on Fourier and Computerized Infrared Spectroscopy, edited by David G. Cameron. SPIE, 1989. http://dx.doi.org/10.1117/12.969550.

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Akbar, Himyan, Salma Habib, Mohammed Mahroof Tahir, and Lakshmaiah Sreerama. "Synthesis and Characterization of Vanadium (IV)-Flavonoid Complexes and its Antioxidant ability toward Superoxide and Radical Scavenging." In Qatar University Annual Research Forum & Exhibition. Qatar University Press, 2020. http://dx.doi.org/10.29117/quarfe.2020.0109.

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In this project Vanadium complex -Vanadium (IV) - flavone was synthesized using vanadium (IV) acetylacetonate (VO(acac)2) complex and 3-hydroxy-6-methyl flavone ligand. The complex stability was checked using FTIR and UV-vis spectroscopies. Peackes around 990 cm-1 conforms the formation of (V=O) in the complex, as well as (V-O) around 790 cm-1. In UV-Vis spectrum peak around 400-450 nm was noticed, which conforms the formation of the vanadium complex that correspond to the ligand to metal charge transfer (LMCT) transition. The radical scavenging abilities of vanadium complex were investigated
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Ayadi, A., K. El Korchi, D. Guichaoua, S. Taboukhat, and A. El-Ghayoury. "Azo-Based Ligands and Metal Complexes for NLO Applications." In 2019 21st International Conference on Transparent Optical Networks (ICTON). IEEE, 2019. http://dx.doi.org/10.1109/icton.2019.8840333.

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Palopoli, Stephen F., and Thomas B. Brill. "Synthesis And Thermolysis Of Metal Complexes Containing Energetic Ligands." In 1988 Los Angeles Symposium--O-E/LASE '88, edited by Joseph Flanagan. SPIE, 1988. http://dx.doi.org/10.1117/12.943744.

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Lee, Taewoo, Christian Reich, Christopher M. Laperle, et al. "Ultrafast XAFS of transition metal complexes." In International Conference on Ultrafast Phenomena. OSA, 2006. http://dx.doi.org/10.1364/up.2006.wd4.

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Sahraoui, Bouchta, Konstantinos Iliopoulos, and Abdelkrim El-Ghayoury. "NLO investigations of electroactive ligands and of their electroactive metal complexes." In 2013 15th International Conference on Transparent Optical Networks (ICTON). IEEE, 2013. http://dx.doi.org/10.1109/icton.2013.6602961.

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Gale, David C., Gary M. Gray, and Christopher M. Lawson. "Nonlinear optical properties of metal-organic complexes with phosphorous-donor ligands." In Optical Science, Engineering and Instrumentation '97, edited by Christopher M. Lawson. SPIE, 1997. http://dx.doi.org/10.1117/12.284168.

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Slinker, Jason, Dan Bernards, Samuel Flores-Torres, et al. "Light emitting diodes from transition metal complexes." In Frontiers in Optics. OSA, 2003. http://dx.doi.org/10.1364/fio.2003.wnn2.

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Latouche, Camille, Vincenzo Barone, and Julien Bloino. "ANHARMONIC VIBRATIONAL SPECTROSCOPY ON METAL TRANSITION COMPLEXES." In 69th International Symposium on Molecular Spectroscopy. University of Illinois at Urbana-Champaign, 2014. http://dx.doi.org/10.15278/isms.2014.rc08.

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Reports on the topic "Ligands; transition metal complexes"

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Reynolds, Michael. Transition Metal Complexes of Cr, Mo, W and Mn Containing η1(S)-2,5-Dimethylthiophene, Benzothiophene and Dibenzothiophene Ligands. Office of Scientific and Technical Information (OSTI), 2000. http://dx.doi.org/10.2172/764616.

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Kubas, G. J., J. Eckert, and X. L. Luo. Binding of hydrocarbons and other extremely weak ligands to transition metal complexes that coordinate hydrogen: Investigation of cis-interactions and delocalized bonding involving sigma bonds. Office of Scientific and Technical Information (OSTI), 1997. http://dx.doi.org/10.2172/505275.

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White, Carter James. Selenophene transition metal complexes. Office of Scientific and Technical Information (OSTI), 1994. http://dx.doi.org/10.2172/10190649.

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Sharp, P. R. Late transition metal oxo and imido complexes. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/7017245.

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Rakowski-DuBois, Mary C. Aspects of C-H Activation in Metal Complexes Containing Sulfur Ligands. Office of Scientific and Technical Information (OSTI), 2004. http://dx.doi.org/10.2172/833244.

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Author, Not Given. Metal alkoxides: Models for metal oxides: Alkoxide ligands in early transition metal organometallic chemistry. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/7151593.

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Sharp, P. R. Late transition metal. mu. -oxo and. mu. -imido complexes. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6332549.

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Sharp, P. Late transition metal. mu. -oxo and. mu. -imido complexes. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/7003275.

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Norton, Jack. The Activation of Hydrogen by First-Row Transition-Metal Complexes. Office of Scientific and Technical Information (OSTI), 2020. http://dx.doi.org/10.2172/1604425.

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Du, Guodong. Group 4 Metalloporphyrin diolato Complexes and Catalytic Application of Metalloporphyrins and Related Transition Metal Complexes. Office of Scientific and Technical Information (OSTI), 2003. http://dx.doi.org/10.2172/835301.

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