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1

Morioka, Hiroyuki, Hideyuki Tagaya, Masa Karasu, Jun-ichi Kadokawa, and Koji Chiba. "Preparation of hydroxy double salts exchanged by organic compounds." Journal of Materials Research 13, no. 4 (April 1998): 848–51. http://dx.doi.org/10.1557/jmr.1998.0112.

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Hydroxy double salts (HDS's) comprise a class of layered materials that are similar to layered double hydroxides (LDH's) and show a comparable intracrystalline reactivity. Their anion exchange reactions occur with preincorporated anions in the hydroxide layer and with anions bound as gegenions of the positively charged layers, respectively. In this study, nitrate and acetate anions of HDS's were exchanged with anionic monoand di-carboxylic acids, and we confirmed that interlayer spacing of HDS's increased depending on the size of mono- and di-carboxylic acids. Moreover, we have prepared photofunctional materials by exchange reaction with azobenzene-p-carboxylic acid and 4–4′-azobenzenedicarboxylic acid.
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2

Maviş, Bora, and Mufit Akinc. "Homogeneous Precipitation of Layer Double Hydroxides." Key Engineering Materials 264-268 (May 2004): 41–44. http://dx.doi.org/10.4028/www.scientific.net/kem.264-268.41.

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3

Carneiro, Jorge, Ana F. Caetano, Alena Kuznetsova, Frederico Maia, Andrei N. Salak, João Tedim, Nico Scharnagl, Mikhail L. Zheludkevich, and Mário G. S. Ferreira. "Polyelectrolyte-modified layered double hydroxide nanocontainers as vehicles for combined inhibitors." RSC Advances 5, no. 50 (2015): 39916–29. http://dx.doi.org/10.1039/c5ra03741g.

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The dual release of Ce3+ and 2-mercaptobenzothiazole from layered double hydroxides modified by the layer-by-layer leads to an improvement of corrosion protection when compared to unmodified layered double hydroxides.
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4

Pachayappan, Latha, Supreeth Nagendran, and P. Vishnu Kamath. "Reappraisal of Polytypism in Layered Double Hydroxides: Consequences of Cation Ordering in the Metal Hydroxide Layer." Crystal Growth & Design 17, no. 5 (March 28, 2017): 2536–43. http://dx.doi.org/10.1021/acs.cgd.7b00071.

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5

Greenwell, H. Christopher, Peter J. Holliman, William Jones, and Beatriz Vaca Velasco. "Studies of the effects of synthetic procedure on base catalysis using hydroxide-intercalated layer double hydroxides." Catalysis Today 114, no. 4 (May 2006): 397–402. http://dx.doi.org/10.1016/j.cattod.2006.02.035.

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6

Richardson, Ian. "Crystal chemistry of layered single and double hydroxides." Acta Crystallographica Section A Foundations and Advances 70, a1 (August 5, 2014): C231. http://dx.doi.org/10.1107/s205327331409768x.

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Layered double hydroxides (LDH) are derived from layered single hydroxides by the substitution of a fraction (x) of the divalent metal cations by trivalent cations, with the charge balanced by anions in the space between the main hydroxide layers. LDH phases can have a range of metal cations and interlayer anions and the value of x can vary quite widely. Straightforward crystal-chemical and geometrical reasoning has resulted in new yet fundamental information about these phases [1, 2]. In particular: (1) It is now possible to calculate x from the `a' parameter of the unit cell or vice versa (whichever is known with the most confidence) for LDH phases that are based on Mg, Ni, Zn or Co; (2) The phase at x = 0 is shown to be an alpha form of M(OH)2 rather than the beta polymorph; (3) The extent to which the metal-oxygen octahedra in the main layer of LDH phases are squashed is now known to be independent of the type of the interlayer anions or the type of trivalent ion, which also has no substantial effect on the reduction in layer spacing that occurs as x increases; (4) It is now easy to create reliable structural models for hydrotalcite- and takovite-type LDH phases that have any trivalent ion (or ions) and any value of x; (5) The ordered distributions of trivalent cations that are possible in LDH phases have been clarified and a plausible explanation provided for the observed variation in the lower solid-solution limit [3]; (6) A reliable model for the crystal structure of beta-Zn(OH)2.
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7

GU, Lingzhu, Tianhang ZHANG, Kai ZHU, Daquan TANG, and Ke WU. "Effect of Various Metal Hydroxide Flame Retardants on the Rheological Properties of Asphalt Binder." Materials Science 25, no. 3 (June 12, 2019): 348–55. http://dx.doi.org/10.5755/j01.ms.25.3.21572.

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Metal hydroxide has been widely used as flame retardant to reduce the hazards of tunnel fire, however, few researches investigate its effect on the rheological properties of asphalt binder systemically. This study explores and compares the effect and mechanisms of magnesium hydroxide (MH), aluminium hydroxide (ATH), hydrated lime (HL), and layer double hydroxides (LDHs) on the rutting resistance, anti-aging resistance, as well as the thermal cracking resistance of asphalt binder. Rotational viscosity (RV) test, dynamic shear rheometer (DSR) test, and bending beam rheometer (BBR) test are involved in the project. Test results indicate: (1) the addition of metal hydroxide generally improves the rutting resistance of asphalt binder during high temperatures due to the typical filler effect, while weakens the resistance to thermal cracking of binder at low temperatures because of the stress concentration; (2) HL and LDHs enhance the anti-aging resistance of asphalt binder; (3) LDHs modified binder, which is proved with better rheological properties, including great rutting resistance, anti-aging resistance and passable resistance to thermal cracking, is recommended for further use. However, the high procurement price is still a big obstacle for its wider application. DOI: http://dx.doi.org/10.5755/j01.ms.25.3.21572
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8

Krivovichev, S. V., V. N. Yakovenchuk, E. S. Zhitova, A. A. Zolotarev, Y. A. Pakhomovsky, and G. Yu Ivanyuk. "Crystal chemistry of natural layered double hydroxides. 2. Quintinite-1M: first evidence of a monoclinic polytype in M2+-M3+ layered double hydroxides." Mineralogical Magazine 74, no. 5 (October 2010): 833–40. http://dx.doi.org/10.1180/minmag.2010.074.5.833.

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AbstractQuintinite-1M, [Mg4Al2(OH)12](CO3)(H2O)3, is the first monoclinic representative of both synthetic and natural layered double hydroxides (LDHs) based on octahedrally coordinated di- and trivalent metal cations. It occurs in hydrothermal veins in the Kovdor alkaline massif, Kola peninsula, Russia. The structure was solved by direct methods and refined to R1 = 0.031 on the basis of 304 unique reflections. It is monoclinic, space group C2/m, a = 5.266(2), b = 9.114(2), c = 7.766(3) Å, β = 103.17(3)°, V = 362.9(2) Å3. The diffraction pattern of quintinite-1M contains sharp reflections corresponding to the layer stacking sequence characteristic of the 3R rhombohedral polytype, and rows of weak superlattice reflections superimposed upon a background of streaks of modulated diffuse intensity parallel to c*. These superlattice reflections indicate the formation of a 2-D superstructure due to Mg-Al ordering. The structure consists of ordered metal hydroxide layers and a disordered interlayer. As the unit cell contains exactly one layer, the polytype nomenclature dictates that the mineral be called quintinite-1M. The complete layer stacking sequence can be described as …=Ac1B=Ba1C=Cb1A=… Quintinite-1M is isostructural with the monoclinic polytype of [Li2Al4(OH)12](CO3)(H2O)3.
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9

Hines, D. R., S. A. Solin, U. Costantino, and M. Nocchetti. "Layer Rigidity in Layer Double Hydroxides Containing a Fixed Host-Layer." Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals 341, no. 2 (April 1, 2000): 377–82. http://dx.doi.org/10.1080/10587250008026169.

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10

Zhong, Pei, Xinhong Qiu, and Jinyi Chen. "Removal of bisphenol A using Mg-Al-layer double hydroxide and Mg-Al calined layer double hydroxide." Separation Science and Technology 55, no. 3 (February 17, 2019): 501–12. http://dx.doi.org/10.1080/01496395.2019.1577265.

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11

Solin, S. A., D. Hines, S. K. Yun, T. J. Pinnavaia, and M. F. Thorpe. "Layer rigidity in 2D disordered NiAl layer double hydroxides." Journal of Non-Crystalline Solids 182, no. 1-2 (March 1995): 212–20. http://dx.doi.org/10.1016/0022-3093(94)00541-9.

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12

Hines, D. R., S. A. Solin, Umberto Costantino, and Morena Nocchetti. "Physical properties of fixed-charge layer double hydroxides." Physical Review B 61, no. 17 (May 1, 2000): 11348–58. http://dx.doi.org/10.1103/physrevb.61.11348.

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13

Li, Xiaohai, Lin Chen, Qiulong Li, Jinjin Zhang, Zheng Su, Xian Zhang, Kang Zheng, and Xingyou Tian. "Double glass transitions in exfoliated poly(methyl methacrylate)/organically modified MgAl layered double hydroxide nanocomposites." RSC Advances 6, no. 104 (2016): 101941–47. http://dx.doi.org/10.1039/c6ra15172h.

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14

Xu, Xiaozhi, Lumei Wang, Jiajie Wang, Qing Yin, Siyuan Dong, Jingbin Han, and Min Wei. "Hydroxide-ion-conductive gas barrier films based on layered double hydroxide/polysulfone multilayers." Chemical Communications 54, no. 56 (2018): 7778–81. http://dx.doi.org/10.1039/c8cc02900h.

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Hybrid films were fabricated via the layer-by-layer assembly of layered double hydroxide (LDH) nanoplates and quaternary ammonium grafted polysulfone (QAPSF), and showed dual functionality with both gas barrier and hydroxide ion conductivity properties.
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15

Zhou, Yi, Jialai Hu, Dan Li, and Qingsheng Gao. "Single-layer CoFe hydroxides for efficient electrocatalytic oxygen evolution." Chemical Communications 57, no. 62 (2021): 7653–56. http://dx.doi.org/10.1039/d1cc03253d.

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16

Lee, Jong Hyeon, Seog Woo Rhee, and Duk-Young Jung. "Selective Layer Reaction of Layer-by-Layer Assembled Layered Double-Hydroxide Nanocrystals." Journal of the American Chemical Society 129, no. 12 (March 2007): 3522–23. http://dx.doi.org/10.1021/ja070512e.

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17

Pan, Haifeng, Wei Wang, Qi Shen, Ying Pan, Lei Song, Yuan Hu, and Yushi Lu. "Fabrication of flame retardant coating on cotton fabric by alternate assembly of exfoliated layered double hydroxides and alginate." RSC Advances 6, no. 113 (2016): 111950–58. http://dx.doi.org/10.1039/c6ra21804k.

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In our current work, a layer-by-layer flame retardant coating, assembled from MgAl layered double hydroxides (MgAl-LDH) and alginate, was firstly fabricated onto the surface of cotton fabric for the purpose of reducing its flammability.
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18

Marappa, Shivanna, and P. Vishnu Kamath. "Water Molecules in Hydrotalcite-like Layered Double Hydroxides: Interplay between the Hydration of the Anions and the Metal Hydroxide Layer." Zeitschrift für anorganische und allgemeine Chemie 641, no. 5 (March 18, 2015): 927–34. http://dx.doi.org/10.1002/zaac.201500065.

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19

Kulandaivalu, Shalini, Mohd Zobir Hussein, Adila Mohamad Jaafar, Muhammad Amirul Aizat Mohd Abdah, Nur Hawa Nabilah Azman, and Yusran Sulaiman. "A simple strategy to prepare a layer-by-layer assembled composite of Ni–Co LDHs on polypyrrole/rGO for a high specific capacitance supercapacitor." RSC Advances 9, no. 69 (2019): 40478–86. http://dx.doi.org/10.1039/c9ra08134h.

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A facile and novel electrode material of nickel–cobalt layered double hydroxides (Ni–Co LDHs) layered on polypyrrole/reduced graphene oxide (PPy/rGO) is fabricated for a symmetrical supercapacitor via chemical polymerization, hydrothermal and vacuum filtration.
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20

Mills, S. J., A. G. Christy, J. M. R. Génin, T. Kameda, and F. Colombo. "Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides." Mineralogical Magazine 76, no. 5 (October 2012): 1289–336. http://dx.doi.org/10.1180/minmag.2012.076.5.10.

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AbstractLayered double hydroxide (LDH) compounds are characterized by structures in which layers with a brucite-like structure carry a net positive charge, usually due to the partial substitution of trivalent octahedrally coordinated cations for divalent cations, giving a general layer formula [(M1–x2+M3+x)(OH)2]x+. This positive charge is balanced by anions which are intercalated between the layers. Intercalated molecular water typically provides hydrogen bonding between the brucite layers. In addition to synthetic compounds, some of which have significant industrial applications, more than 40 mineral species conform to this description. Hydrotalcite, Mg6Al2(OH)16[CO3]·4H2O, as the longest-known example, is the archetype of this supergroup of minerals. We review the history, chemistry, crystal structure, polytypic variation and status of all hydrotalcite-supergroup species reported to date. The dominant divalent cations,M2+, that have been reported in hydrotalcite supergroup minerals are Mg, Ca, Mn, Fe, Ni, Cu and Zn; the dominant trivalent cations,M3+, are Al, Mn, Fe, Co and Ni. The most common intercalated anions are (CO3)2–, (SO4)2–and Cl–; and OH–, S2–and [Sb(OH)6]– have also been reported. Some species contain intercalated cationic or neutral complexes such as [Na(H2O)6]+or [MgSO4]0. We define eight groups within the supergroup on the basis of a combination of criteria. These are (1) the hydrotalcite group, withM2+:M3+= 3:1 (layer spacing ∼7.8 Å); (2) the quintinite group, withM2+:M3+= 2:1 (layer spacing ∼7.8 Å); (3) the fougèrite group, withM2+= Fe2+,M3+= Fe3+in a range of ratios, and with O2– replacing OH– in the brucite module to maintain charge balance (layer spacing ∼7.8 Å); (4) the woodwardite group, with variableM2+:M3+and interlayer [SO4]2 –, leading to an expanded layer spacing of ∼8.9 Å; (5) the cualstibite group, with interlayer [Sb(OH)6]– and a layer spacing of ∼9.7 Å; (6) the glaucocerinite group, with interlayer [SO4]2– as in the woodwardite group, and with additional interlayer H2O molecules that further expand the layer spacing to ∼11 Å; (7) the wermlandite group, with a layer spacing of ∼11 Å, in which cationic complexes occur with anions between the brucite-like layers; and (8) the hydrocalumite group, withM2+= Ca2+andM3+= Al, which contains brucite-like layers in which the Ca:Al ratio is 2:1 and the large cation, Ca2+, is coordinated to a seventh ligand of 'interlayer' water.The principal mineral status changes are as follows. (1) The names manasseite, sjögrenite and barbertonite are discredited; these minerals are the 2H polytypes of hydrotalcite, pyroaurite and stichtite, respectively. Cyanophyllite is discredited as it is the 1M polytype of cualstibite. (2) The mineral formerly described as fougèrite has been found to be an intimate intergrowth of two phases with distinct Fe2+:Fe3+ratios. The phase with Fe2+:Fe3+= 2:1 retains the name fougèrite; that with Fe2+:Fe3+= 1:2 is defined as the new species trébeurdenite. (3) The new minerals omsite (IMA2012-025), Ni2Fe3+(OH)6[Sb(OH)6], and mössbauerite (IMA2012-049), Fe3+6O4(OH)8[CO3]·3H2O, which are both in the hydrotalcite supergroup are included in the discussion. (4) Jamborite, carrboydite, zincaluminite, motukoreaite, natroglaucocerinite, brugnatellite and muskoxite are identified as questionable species which need further investigation in order to verify their structure and composition. (5) The ranges of compositions currently ascribed to motukoreaite and muskoxite may each represent more than one species. The same applies to the approved species hydrowoodwardite and hydrocalumite. (6) Several unnamed minerals have been reported which are likely to represent additional species within the supergroup.This report has been approved by the Commission on New Minerals, Nomenclature and Classification (CNMNC) of the International Mineralogical Association, voting proposal 12-B.We also propose a compact notation for identifying synthetic LDH phases, for use by chemists as a preferred alternative to the current widespread misuse of mineral names.
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Lv, Weiyang, Qingqing Mei, Huakang Fu, Jianliang Xiao, Miao Du, and Qiang Zheng. "A general strategy for the synthesis of layered double hydroxide nanoscrolls on arbitrary substrates: its formation and multifunction." Journal of Materials Chemistry A 5, no. 36 (2017): 19079–90. http://dx.doi.org/10.1039/c7ta05556k.

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Layered double hydroxides with various morphologies were fabricated on arbitrary substrate surfaces via a mussel-inspired intermediate layer, which exhibited versatile and comprehensive performance for water remediation.
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22

Zhang, Ping, Hailong Li, Jingjing Shi, and Jun Lu. "Assembly of neutral conjugated polymers with layered double hydroxide nanosheets by the layer-by-layer method." RSC Advances 6, no. 97 (2016): 94739–47. http://dx.doi.org/10.1039/c6ra17924j.

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This article reports that the neutral conjugated polymers (NCPs) can also be assembled with exfoliated MgAl-layered double hydroxide (LDH) nanosheets to form the ordered inorganic/organic hybrid ultrathin films via the LbL assembly technique.
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23

Solin, S. A., D. R. Hines, G. T. Seidler, and M. M. J. Treacy. "Novel structural properties of Ni1 − x Alx layer double hydroxides." Journal of Physics and Chemistry of Solids 57, no. 6-8 (June 1996): 1043–48. http://dx.doi.org/10.1016/0022-3697(95)00393-2.

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24

Yu, Jingfang, Benjamin R. Martin, Abraham Clearfield, Zhiping Luo, and Luyi Sun. "One-step direct synthesis of layered double hydroxide single-layer nanosheets." Nanoscale 7, no. 21 (2015): 9448–51. http://dx.doi.org/10.1039/c5nr01077b.

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Liu, Xiaoxi, Awu Zhou, Yibo Dou, Ting Pan, Mingfei Shao, Jingbin Han, and Min Wei. "Ultrafast switching of an electrochromic device based on layered double hydroxide/Prussian blue multilayered films." Nanoscale 7, no. 40 (2015): 17088–95. http://dx.doi.org/10.1039/c5nr04458h.

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Multilayered films are fabricated via layer-by-layer assembly of layered double hydroxide (LDH) nanosheets and Prussian blue (PB) nanoparticles, which exhibit superior electrochromic performance, including ultrafast switching and excellent cycling stability.
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Gao, Rui, Minjun Zhao, Yan Guan, Xiaoyu Fang, Xiaohong Li, and Dongpeng Yan. "Ordered and flexible lanthanide complex thin films showing up-conversion and color-tunable luminescence." J. Mater. Chem. C 2, no. 45 (2014): 9579–86. http://dx.doi.org/10.1039/c4tc01213e.

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Ordered transparent thin films based on alternate layer-by-layer assembly of lanthanide complexes and layered double hydroxide nanosheets have been fabricated, which exhibit up-conversion emission and tunable two-color luminescence.
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27

Zhang, Wenjun, Yi Chen, Yanlin Li, Sumin Guan, Yan Chen, Qian-Qian Yang, Lu Liu, Qing-Chen Xue, and Yu-Cui Guang. "Intercalation of Europium Inclusion Complex of β-Cyclodextrin into Layered Double Hydroxides Through Layer-By-Layer Assembly and Its Luminescent Properties." Nano 12, no. 10 (October 2017): 1750126. http://dx.doi.org/10.1142/s1793292017501260.

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In this work, organic–inorganic hybrid ultrathin transparent films (UTFs), produced by layer-by-layer (LBL) assembly of the europium inclusion complex of [Formula: see text]-cyclodextrin ([Formula: see text]-CD) and Mg–Al-layered double hydroxide (MgAl–NO3–LDHs) nanosheets, are reported. UV-visible (UV-Vis) absorption and fluorescence spectroscopy show orderly growth of the europium inclusion complex of [Formula: see text]-CD/layered double hydroxide (EICC/LDH) films with an increasing number of deposition cycles. X-ray diffraction and scanning electron microscopy measurements indicate that the films feature periodic layered structures with uniform surface morphology. Moreover, when EICC is assembled with inorganic rigid LDH nanosheets, the lifetimes are prolonged due to the isolation effect, and the UTFs are transparent with high brightness, which indicate that these films could serve as new optical materials.
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Baek, Seong-Ho, Gwang-Hee Nam, and Il-Kyu Park. "Morphology controlled growth of ZnAl-layered double hydroxide and ZnO nanorod hybrid nanostructures by solution method." RSC Advances 5, no. 74 (2015): 59823–29. http://dx.doi.org/10.1039/c5ra10374f.

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Morphological evolution of ZnAl-based hybrid nanostructures from ZnAl layered double hydroxide to ZnO nanorods grown by a hydrothermal method depending on the thickness of the Al2O3/ZnO double seed layer.
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29

Halma, Matilte, Aicha Khenifi, Martine Sancelme, Pascale Besse-Hoggan, Pierre-Olivier Bussière, Vanessa Prévot, and Christine Mousty. "Thin bacteria/Layered Double Hydroxide films using a layer-by-layer approach." Journal of Colloid and Interface Science 474 (July 2016): 151–58. http://dx.doi.org/10.1016/j.jcis.2016.04.023.

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30

Liu, Lei, Wei Wang, and Yuan Hu. "Layered double hydroxide-decorated flexible polyurethane foam: significantly improved toxic effluent elimination." RSC Advances 5, no. 118 (2015): 97458–66. http://dx.doi.org/10.1039/c5ra19414h.

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A layered double hydroxide-based fire-blocking coating was deposited on the surface of a flexible polyurethane foam using a layer-by-layer method to improve its thermal stability, flame retardancy and smoke suppression properties.
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Zhang, Ping, Yuehua Hu, Ruili Ma, Ling Li, and Jun Lu. "Enhanced green fluorescence protein/layered double hydroxide composite ultrathin films: bio-hybrid assembly and potential application as a fluorescent biosensor." Journal of Materials Chemistry B 5, no. 1 (2017): 160–66. http://dx.doi.org/10.1039/c6tb02638a.

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This article reports the fabrication and application of enhanced green fluorescent protein/layered double hydroxide nanosheet (EGFP/LDH)n ultrathin films via layer-by-layer assembly technique based on electrostatic and hydrogen-bond interactions.
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32

Hanifa, Yuliza, and Neza Rahayu Palapa. "Mg/Al double layer hydroxides: intercalation with H3[α-PW12O40]•nH2O." Science & Technology Indonesia 1, no. 1 (October 14, 2016): 16–19. http://dx.doi.org/10.26554/sti.2016.1.1.16-19.

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Guo, Zhenhu, Wensheng Xie, Jingsong Lu, Xiaoxiao Guo, Yongjie Chi, Dan Wang, Nonaka Takuya, et al. "Ferrous ions doped layered double hydroxide: smart 2D nanotheranostic platform with imaging-guided synergistic chemo/photothermal therapy for breast cancer." Biomaterials Science 9, no. 17 (2021): 5928–38. http://dx.doi.org/10.1039/d1bm00765c.

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Wu, Lihong, Xuechun Zhou, Gengping Wan, Yulin Tang, Shaohua Shi, Xuefei Xu, and Guizhen Wang. "Novel hierarchical CuNiAl LDH nanotubes with excellent peroxidase-like activity for wide-range detection of glucose." Dalton Transactions 50, no. 1 (2021): 95–102. http://dx.doi.org/10.1039/d0dt03288c.

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Xue, Yudong, Zachary S. Fishman, Jason A. Röhr, Zhenhua Pan, Yunting Wang, Chunhui Zhang, Shili Zheng, Yi Zhang, and Shu Hu. "Tunable nano-interfaces between MnOx and layered double hydroxides boost oxygen evolving electrocatalysis." Journal of Materials Chemistry A 6, no. 44 (2018): 21918–26. http://dx.doi.org/10.1039/c8ta07508e.

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36

Imron, Muhammad, and Muhammad Said. "Adsorption of procion red using layer double hydroxide Mg/Al." Science and Technology Indonesia 2, no. 3 (July 8, 2017): 64–67. http://dx.doi.org/10.26554/sti.2017.2.3.64-67.

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37

Yu, Jingfang, Jingjing Liu, Abraham Clearfield, Johnathan E. Sims, Michael T. Speiegle, Steven L. Suib, and Luyi Sun. "Synthesis of Layered Double Hydroxide Single-Layer Nanosheets in Formamide." Inorganic Chemistry 55, no. 22 (November 2016): 12036–41. http://dx.doi.org/10.1021/acs.inorgchem.6b02203.

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Sun, Chaoyang, Hui Wang, Shan Ji, Xuyun Wang, Vladimir Linkov, Xinlong Tian, Long Yao, Jiarui Zhao, and Rongfang Wang. "Layer-structured FeCo bihydroxide as an ultra-stable bifunctional electrocatalyst for water splitting at high current densities." Sustainable Energy & Fuels 5, no. 10 (2021): 2747–52. http://dx.doi.org/10.1039/d1se00380a.

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Chen, Dan, Shu Huang, Chao Zhang, Weizhi Wang, and Tianxi Liu. "Layer-by-layer self-assembly of polyimide precursor/layered double hydroxide ultrathin films." Thin Solid Films 518, no. 23 (September 2010): 7081–85. http://dx.doi.org/10.1016/j.tsf.2010.05.121.

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40

Wijitwongwan, Rattanawadee (Ploy), Soontaree (Grace) Intasa-ard, and Makoto Ogawa. "Preparation of MgGa Layered Double Hydroxides and Possible Compositional Variation." Nanomaterials 11, no. 5 (May 1, 2021): 1206. http://dx.doi.org/10.3390/nano11051206.

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Layered double hydroxides (LDHs), shown as the general formula of [M2+1−xM3+x(OH)2]x+(An−)x/n∙yH2O, are useful for various applications such as anion exchangers/adsorbents, catalysts and catalysts’ supports, and drug/gene carriers due to their structural, compositional and morphological characteristics and their variation. The x value (M3+/(M2+ + M3+) ratio) in layered double hydroxides (LDHs), corresponding to the layer charge density, is one of the important parameters for controlling the properties of LDHs. The x values in commonly available LDHs are limited (0.2 < x < 0.3). In order to obtain LDHs with x < 0.2, Mg2+ Ga3+–LDHs with interlayer iodide were examined. The linear correlation between lattice parameter a and x value in the products with x of 0.06–0.24 was seen, suggesting the successful substitution of Mg2+ in the brucite-like sheet with Ga3+. Carbonate and dodecyl sulfate types MgGa–LDH were prepared by ion exchange with carbonate anion and reconstruction in aqueous solution of sodium dodecyl sulfate. The products with x of 0.06 were dispersed in water and hexanol better than those with x of 0.24 for MgGa–LDHs containing carbonate and dodecyl sulfate, respectively, suggesting effects of the lower layer charge density on the dispersion.
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41

Radha, Shivaramaiah, Churchil A. Antonyraj, P. Vishnu Kamath, and Srinivasan Kannan. "Polytype Transformations in the SO42- Containing Layered Double Hydroxides of Zinc with Aluminum and Chromium: The Metal Hydroxide Layer as a Structural Synthon." Zeitschrift für anorganische und allgemeine Chemie 636, no. 15 (August 20, 2010): 2658–64. http://dx.doi.org/10.1002/zaac.201000126.

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42

Hines, D. R., G. T. Seidler, M. M. J. Treacy, and S. A. Solin. "Random stacking of a commensurate guest layer in an ordered host: NiAl layer-double-hydroxides." Solid State Communications 101, no. 11 (March 1997): 835–39. http://dx.doi.org/10.1016/s0038-1098(96)00682-5.

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43

ZHANG, Ping, Xue DUAN, and Jun LU. "Progress in layer-by-layer assembly method of nanocomposite film based on layered double hydroxides." Chinese Science Bulletin 60, no. 35 (December 1, 2015): 3454–64. http://dx.doi.org/10.1360/n972015-00838.

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44

Hines, D. R., S. A. Solin, U. Costantino, and M. Nocchetti. "Unique composition-dependent basal expansion of CO3–Cl (H2O) layer double hydroxides." Solid State Communications 108, no. 12 (November 1998): 971–76. http://dx.doi.org/10.1016/s0038-1098(98)00466-9.

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45

Mavis, Bora, and Mufit Akinc. "Three-component layer double hydroxides by urea precipitation: structural stability and electrochemistry." Journal of Power Sources 134, no. 2 (August 2004): 308–17. http://dx.doi.org/10.1016/j.jpowsour.2004.03.056.

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46

Dong, Chaoqun, Qiuxuan Ge, Yu Li, and Jiawei Zhang. "Boosting Honeycomb-like Layer Double Hydroxides Nanosheets as advanced Electrode for Supercapacitors." Thin Solid Films 715 (December 2020): 138439. http://dx.doi.org/10.1016/j.tsf.2020.138439.

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47

Dagnon, Koffi L., Clark Robinson, Hua H. Chen, David C. Garrett, Lucia H. Innocentini-Mei, and Nandika A. D'Souza. "Layer double hydroxides for enhanced poly(3-hydroxybutyrate-co-3-hydroxyvalerate) crystallization." Journal of Applied Polymer Science 127, no. 5 (May 22, 2012): 3395–406. http://dx.doi.org/10.1002/app.37646.

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48

Huang, Peipei, Jian Liu, Fang Wei, Yanan Zhu, Xiaoshi Wang, Changyan Cao, and Weiguo Song. "Size-selective adsorption of anionic dyes induced by the layer space in layered double hydroxide hollow microspheres." Materials Chemistry Frontiers 1, no. 8 (2017): 1550–55. http://dx.doi.org/10.1039/c7qm00079k.

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Flower-like cobalt aluminum layered double hydroxide hollow microspheres showed high adsorption capacity for methyl orange and exhibited size-selective adsorption properties towards different kinds of anionic dyes.
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49

Zhang, Gen, Liang Wu, Aitao Tang, Bo Weng, Andrej Atrens, Shida Ma, Lei Liu, and Fusheng Pan. "Sealing of anodized magnesium alloy AZ31 with MgAl layered double hydroxides layers." RSC Advances 8, no. 5 (2018): 2248–59. http://dx.doi.org/10.1039/c7ra11683g.

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In this work anodized magnesium alloy AZ31 with and without boiling water sealing was pre-prepared, and then MgAl-layered double hydroxide (LDH) films were fabricated on it through hydrothermal chemical conversion of the pre-prepared anodic layer.
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50

Zhao, Zhiping, Yonglian Qi, Min Wei, Fazhi Zhang, and Sailong Xu. "Layer-by-layer assembly and morphological characterizations of DNA/layered double hydroxide thin films." Materials Letters 78 (July 2012): 62–65. http://dx.doi.org/10.1016/j.matlet.2012.03.064.

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