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1

Corrêa, H. P. S., C. O. Paiva-Santos, L. F. Setz, L. G. Martinez, S. R. H. Mello-Castanho, and M. T. D. Orlando. "Crystal structure refinement of Co-doped lanthanum chromites." Powder Diffraction 23, S1 (March 2008): S18—S22. http://dx.doi.org/10.1154/1.2903501.

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Results of crystal structure refinements and phase quantification for samples of Co-doped lanthanum chromites with nominal composition LaCr1−xCoxO3, for x=0.00, 0.10, 0.20, and 0.30, prepared by combustion synthesis are presented. The resulting powders were characterized by scanning electron microscopy and X-ray diffraction (XRD). The XRD patterns were obtained with Cu Kα radiation for non-doped lanthanum chromite sample and additionally with Cr Kα radiation for Co-doped lanthanum chromites samples, in order to enhance the signal from scattering. Rietveld analysis of XRD data showed that the studied samples presented the lanthanum chromite with an orthorhombic structure (Pnma), except for the composition with x=0.30, in which the space group was found to be R3c.
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2

Murphy, Michael W., Timothy R. Armstrong, and Peter A. Smith. "Tape Casting of Lanthanum Chromite." Journal of the American Ceramic Society 80, no. 1 (January 1997): 165–70. http://dx.doi.org/10.1111/j.1151-2916.1997.tb02805.x.

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3

Suvorov, S. A., and A. P. Shevchik. "Chemical Equilibria Involving Lanthanum Chromite." Refractories and Industrial Ceramics 45, no. 2 (March 2004): 94–99. http://dx.doi.org/10.1023/b:refr.0000029615.98571.67.

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4

Yamagata, Chieko, and Sonia Regina Homem de Mello-Castanho. "Synthesis Characterization and Sintering of Cobalt-Doped Lanthanum Chromite Powders for Use in SOFCs." Materials Science Forum 660-661 (October 2010): 971–76. http://dx.doi.org/10.4028/www.scientific.net/msf.660-661.971.

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Doped lanthanum chromite is a promising as interconnect material because of its good conductivity at high temperatures and its stability in oxidizing and reducing atmospheres. Perovskite oxide powders of Co-doped lanthanum chromite were synthesized by dispersing precursor metal salt solutions in a polymer matrix followed by a thermal treatment. XRD patterns showed that a highly crystalline cobalt-doped lanthanum chromite was obtained. Fine perovskite powder with a surface area of 6.15 m2 g-1 calcined at 700oC for 1 h, were obtained. After the sample sintered at 1450oC for 3h, the powder reached high densities exceeding 97% of the theoretical density. The proposed here has proved to be a very promising technique for the synthesis of lanthanum chromite powders.
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5

Pimentel, Patrícia Mendonça, Kaique Matheus Barbosa Ferreira, Danielle Karinne Souza Gomes, Asenete Frutuoso Costa, Dulce Maria de Araújo Melo, and Rosane Maria Pessoa Betânio Oliveira. "Optical and Structural Properties of Lanthanum Chromite Synthesized by Microwave Assisted Self-Combustion Method." Materials Science Forum 881 (November 2016): 7–11. http://dx.doi.org/10.4028/www.scientific.net/msf.881.7.

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Lanthanum chromite is a perovskite oxide type, which exhibit high mechanical and chemical stability, high electric conductivity for use in SOFC and catalytic activity for the oxidation reaction. However, their optical properties have not yet been studied. The aim of this study was to synthesize lanthanum chromite by the microwave assisted self-combustion method for use as ceramic pigment. The resulting precursor powders were calcined at 800 to 1000 ° C to obtain the perovskite phase and characterized by X-ray diffraction, followed by Rietveld refinement, UV-Visible and colorimetry. The results revealed porous powders, nanometric, and single-phase with orthorhombic perovskite structure. There was few change in the colorimetric parameters, the chromites presented colours with gray tones which became darker in the calcined powder at higher temperatures.
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6

De Guire, M. R., S. E. Dorris, R. B. Poeppel, S. Morissette, and U. Balachandran. "Coprecipitation synthesis of doped lanthanum chromite." Journal of Materials Research 8, no. 9 (September 1993): 2327–35. http://dx.doi.org/10.1557/jmr.1993.2327.

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Two coprecipitation methods were used to synthesize powder precursors of doped lanthanum chromite (La, Ca)(Cr, Co)O3. The effects of synthesis method and calcination temperature on the composition, sintered density, and microstructure of pressed compacts of (La, Ca)(Cr, Co)O3 were studied by differential thermal analysis/thermogravimetric analysis, x-ray diffraction, scanning electron microscopy, and density measurement. The cation ratios in the precipitated solids were, with few exceptions, within experimental error of the desired compositions for all four components. Powders obtained by both techniques could be sintered to densities exceeding 93% at 1400 °C. The highest densities were obtained with calcining temperatures from 450 to 700 °C. The sintered microstructures exhibited uniform grain sizes averaging 3–5 μm. The Cr(vi) compounds, CaCrO4 and La2CrO6, were observed in all of the calcined powders. The possible role of these phases on chromite densification is discussed.
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7

KONNO, Hidetaka, Masahiro TOKITA, Satoru KITAZAKI, and Ryusaburo FURUICHI. "Electrochemical formation of lanthanum chromite coatings." Journal of the Surface Finishing Society of Japan 40, no. 1 (1989): 144–45. http://dx.doi.org/10.4139/sfj.40.144.

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8

Armstrong, Timothy R., Jeffry W. Stevenson, Larry R. Pederson, and Paige E. Raney. "Dimensional Instability of Doped Lanthanum Chromite." Journal of The Electrochemical Society 143, no. 9 (September 1, 1996): 2919–25. http://dx.doi.org/10.1149/1.1837127.

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9

Carter, J. D. "Solubility of Calcium in Lanthanum Chromite." ECS Proceedings Volumes 1993-4, no. 1 (January 1993): 344–53. http://dx.doi.org/10.1149/199304.0344pv.

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10

Sakai, Natsuko. "Thermodynamic Properties of Lanthanum Calcium Chromite." ECS Proceedings Volumes 1995-1, no. 1 (January 1995): 895–904. http://dx.doi.org/10.1149/199501.0895pv.

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11

Bilger, S., G. Blaβ, and R. Förthmann. "Sol-gel synthesis of lanthanum chromite powder." Journal of the European Ceramic Society 17, no. 8 (January 1997): 1027–31. http://dx.doi.org/10.1016/s0955-2219(96)00182-3.

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12

Simner, S. "Sintering of lanthanum chromite using strontium vanadate." Solid State Ionics 128, no. 1-4 (February 2000): 53–63. http://dx.doi.org/10.1016/s0167-2738(99)00310-0.

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13

MURPHY, M. W., T. R. ARMSTRONG, and P. A. SMITH. "ChemInform Abstract: Tape Casting of Lanthanum Chromite." ChemInform 28, no. 18 (August 4, 2010): no. http://dx.doi.org/10.1002/chin.199718027.

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14

Chick, L. A. "Synthesis of Air-Sinterable Lanthanum Chromite Powders." ECS Proceedings Volumes 1989-11, no. 1 (January 1989): 170–87. http://dx.doi.org/10.1149/198911.0170pv.

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15

Tien, Vu, L. F. Cabannes, and A. M. Anthony. "Joining of lanthanum chromite and zirconia ceramics." Ceramics International 11, no. 4 (October 1985): 125. http://dx.doi.org/10.1016/0272-8842(85)90041-0.

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16

Gupta, Sapna, Manoj K. Mahapatra, and Prabhakar Singh. "Lanthanum chromite based perovskites for oxygen transport membrane." Materials Science and Engineering: R: Reports 90 (April 2015): 1–36. http://dx.doi.org/10.1016/j.mser.2015.01.001.

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17

Lu, Yi, Zhenggang Fang, Chunhua Lu, Ling Wei, Yaru Ni, Zhongzi Xu, and Shunyan Tao. "High thermal radiation of Ca-doped lanthanum chromite." RSC Advances 5, no. 39 (2015): 30667–74. http://dx.doi.org/10.1039/c4ra16319b.

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18

Horita, Teruhisa, Jin-Sam Choi, You-Kee Lee, Natsuko Sakai, Tatsuya Kawada, Harumi Yokokawa, and Masayuki Dokiya. "Reaction between Calcium-Doped Lanthanum Chromite and Silica." Journal of the American Ceramic Society 78, no. 7 (July 1995): 1729–56. http://dx.doi.org/10.1111/j.1151-2916.1995.tb08882.x.

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19

Armstrong, T. R. "Instabilities in Doped Lanthanum Chromite in Reducing Environments." ECS Proceedings Volumes 1995-1, no. 1 (January 1995): 944–51. http://dx.doi.org/10.1149/199501.0944pv.

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20

Surkov, G. M., T. I. Borodina, G. E. Val'yano, T. I. Gordeeva, and Yu D. Novov. "Unfired electric conducting material based on lanthanum chromite." Refractories 30, no. 11-12 (November 1989): 671–75. http://dx.doi.org/10.1007/bf01288267.

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21

Montross, Charles S., Harumi Yokokawa, and Masayuki Dokiya. "Toughening in lanthanum chromite due to metastable phase." Scripta Materialia 34, no. 6 (March 1996): 913–17. http://dx.doi.org/10.1016/1359-6462(95)00616-8.

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22

Suvorov, S. A., and A. Yu Nikiforov. "Investigating the solid phase synthesis of lanthanum chromite." Refractories 31, no. 3-4 (March 1990): 141–45. http://dx.doi.org/10.1007/bf01282352.

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23

Shevchik, A. P., and S. A. Suvorov. "Microstructure of refractories with participation of lanthanum chromite." Refractories and Industrial Ceramics 50, no. 4 (July 2009): 266–72. http://dx.doi.org/10.1007/s11148-009-9198-4.

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24

Zhu, Xin De, Sheng Li Li, Jian Hua Zhang, and Qing Ao. "Effects of Doped AE (Ca, Sr) on Synthesis and Structure of Lanthanum Chromite-Based Nano-Powder." Advanced Materials Research 602-604 (December 2012): 249–53. http://dx.doi.org/10.4028/www.scientific.net/amr.602-604.249.

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Using sol-gel method, a series of nanocrystalline materials La1-xAExCrO3(AE=Ca, Sr) were synthesized. Difference between Ca- and Sr-doped lanthanum chromites were investigated by carrying out differential scanning calorimetry (DSC), thermogravimetric analysis (TG), X-ray diffraction (XRD) and high resolution transmission electron microscope (HRTEM). It was found that the synthesis temperature (1-xCaxCrO3, and CaCrO4as the second phase (x≥0.2) at the room temperature. LSC is composed of single orthorhombic perovskite phase for x=0.1, while the orthorhombic and rhombohedral perovskite phases coexist for x=0.2, and only rhombohedral perovskite phase for x=0.3. Further studies showed that the maximum solubility of Sr was lower than that of Ca in lanthanum chromite.
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25

Setz, Luiz Fernando Grespan, and Sonia Regina Homem de Mello-Castanho. "Determining the Lanthanum Chromite Zeta Potential in Aqueous Media." Materials Science Forum 660-661 (October 2010): 1145–50. http://dx.doi.org/10.4028/www.scientific.net/msf.660-661.1145.

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Lanthanum Chromite may used as interconnect for SOFC’s applications due its particular intrinsic properties as stability in both oxidant and reducing environments and electrical conductivity. However to manufacture these devices that generally present complex shapes as grooved plates and fine pipes, they are necessary the use of the conformation techniques such as screen printing, slip casting, tape casting, extrusion moulding, etc. that are related with colloid processing. Independent of the processing techniques chosen the control of the suspension conditions is important to obtain reproducibility and homogeneous products as final result. In this sense, all contribution to understand the behaviour of the LaCrO3 fine particles in liquid suspension as the surface state using the Zeta’s Potential concepts may supplies information by the forecast of the behaviour during the shaped processing. The aqueous suspensions behaviour was studied utilizing doped lanthanum chromite powders, attained by combustion synthesis. The eletrophoretic mobility measurements of particles in suspension, prepared with the different conditioned powders were made. The electrolyte compositions as function of the pH varying from 2 to 12 were tested. The Zeta potentials and the stability conditions for stable suspensions prepared were determined. The viscosity curves are also appraised.
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26

Setz, L. F. G., H. P. S. Corrêa, Carlos de Oliveira Paiva-Santos, and Sonia Regina Homem de Mello-Castanho. "Sintering of Cobalt and Strontium Doped Lanthanum Chromite Obtained by Combustion Synthesis." Materials Science Forum 530-531 (November 2006): 671–76. http://dx.doi.org/10.4028/www.scientific.net/msf.530-531.671.

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Lanthanum chromite (LaCrO3) is one of the most adequate materials for use as interconnector in solid oxide fuel cell (SOFC) applications, due to its intrinsic properties, namely its good electrical conductivity and resistance to environment conditions in fuel cell operations. Due to difficulties in sintering, additives are usually added to help in the densification process. In this work, the influence of added cobalt and strontium, in the sintering of LaCrO3 obtained by combustion synthesis was studied. The starting materials were respectively nitrates of chromium, lanthanum, cobalt and strontium, and urea was used as fuel. The results show that by increasing the strontium and cobalt concentrations it is possible to reduce the temperature of sintering. Using both additives, the sintering processes took place in lesser times than normally used for this material, as well as greater values of density were attained.
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27

Montross, Charles S. "Elastic modulus versus bond length in lanthanum chromite ceramics." Journal of the European Ceramic Society 18, no. 4 (April 1998): 353–58. http://dx.doi.org/10.1016/s0955-2219(97)00143-x.

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28

Smith, David S., Michael Sayer, P. Roeder, A. Smith, and P. Odier. "Bonding of Zirconia and Lanthanum Chromite by Co-firing." Journal of the American Ceramic Society 72, no. 2 (February 1989): 308–11. http://dx.doi.org/10.1111/j.1151-2916.1989.tb06121.x.

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29

Shevchik, A. P., and S. A. Suvorov. "Surface phenomena in conducting materials based on lanthanum chromite." Russian Journal of General Chemistry 77, no. 4 (April 2007): 509–16. http://dx.doi.org/10.1134/s1070363207040032.

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30

Deshpande, Kishori, Alexander Mukasyan, and Arvind Varma. "Aqueous Combustion Synthesis of Strontium-Doped Lanthanum Chromite Ceramics." Journal of the American Ceramic Society 86, no. 7 (July 2003): 1149–54. http://dx.doi.org/10.1111/j.1151-2916.2003.tb03439.x.

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31

Montross, Charles S., Harumi Yokokawa, Masayuki Dokiya, and Lambert Bekessy. "Mechanical Properties of Magnesia-Doped Lanthanum Chromite versus Temperature." Journal of the American Ceramic Society 78, no. 7 (July 1995): 1869–72. http://dx.doi.org/10.1111/j.1151-2916.1995.tb08902.x.

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32

Paulik, S. W., S. Baskaran, and S. W. Paulik. "Mechanical properties of calcium- and strontium-substituted lanthanum chromite." Journal of Materials Science 33, no. 9 (May 1998): 2397–404. http://dx.doi.org/10.1023/a:1004359925766.

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33

Suvorov, S. A., and A. P. Shevchik. "A Heating Module Equipped with Lanthanum Chromite-Based Heaters." Refractories and Industrial Ceramics 45, no. 3 (May 2004): 196–200. http://dx.doi.org/10.1023/b:refr.0000036729.24986.e3.

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34

Christiansen, Niels. "Synthesis and Stability of Cobalt-Substituted Lanthanum Calcium Chromite." ECS Proceedings Volumes 1993-4, no. 1 (January 1993): 401–13. http://dx.doi.org/10.1149/199304.0401pv.

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35

Sakai, N. "SIMS Analysis of Materials Transport in Lanthanum Chromite Interconnects." ECS Proceedings Volumes 1997-40, no. 1 (January 1997): 1283–90. http://dx.doi.org/10.1149/199740.1283pv.

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36

Williford, R. E. "Atomistic Modeling of Defect Induced Dilations in Lanthanum Chromite." ECS Proceedings Volumes 1999-19, no. 1 (January 1999): 687–95. http://dx.doi.org/10.1149/199919.0687pv.

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37

Simner, S. P. "Sintering and Property Characterization of Strontium-Doped Lanthanum Chromite." ECS Proceedings Volumes 1999-19, no. 1 (January 1999): 696–705. http://dx.doi.org/10.1149/199919.0696pv.

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38

Armstrong, T. R. "Optimizing Lanthanum Chromite Interconnects for Solid Oxide Fuel Cells." ECS Proceedings Volumes 1999-19, no. 1 (January 1999): 706–15. http://dx.doi.org/10.1149/199919.0706pv.

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39

Zhigalkina, I. A., T. D. Nikolaeva, Yu L. Suponitskii, and B. I. Polyak. "Synthesis of lanthanum chromite using the sol-gel method." Glass and Ceramics 55, no. 5-6 (May 1998): 182–85. http://dx.doi.org/10.1007/bf02694738.

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40

Sudrajat, Hanggara, Sri Hartuti, and Truong Khang Nguyen. "Lanthanum chromite for visible light-driven photocatalytic hydrogen evolution." Optik 207 (April 2020): 163807. http://dx.doi.org/10.1016/j.ijleo.2019.163807.

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41

Hayashi, Shinsuke, Kenji Fukaya, and Hajime Saito. "Sintering of lanthanum chromite doped with zinc or copper." Journal of Materials Science Letters 7, no. 5 (May 1988): 457–58. http://dx.doi.org/10.1007/bf01730687.

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42

Suvorov, S. A., and A. P. Shevchik. "Sintering capacity of refractory composites based on lanthanum chromite." Refractories and Industrial Ceramics 49, no. 4 (July 2008): 304–6. http://dx.doi.org/10.1007/s11148-008-9086-3.

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43

Williford, R. E., T. R. Armstrong, and J. D. Gale. "Chemical and Thermal Expansion of Calcium-Doped Lanthanum Chromite." Journal of Solid State Chemistry 149, no. 2 (February 2000): 320–26. http://dx.doi.org/10.1006/jssc.1999.8533.

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44

Nishiyama, Haruo, Masanobu Aizawa, Harumi Yokokawa, Teruhisa Horita, Natsuko Sakai, Masayuki Dokiya, and Tatsuya Kawada. "Stability of Lanthanum Calcium Chromite‐Lanthanum Strontium Manganite Interfaces in Solid Oxide Fuel Cells." Journal of The Electrochemical Society 143, no. 7 (July 1, 1996): 2332–41. http://dx.doi.org/10.1149/1.1837002.

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45

Thenmozhi, N., R. Saravanan, and Yen-Pei Fu. "Crystal Structure and Bonding Analysis of (La0.8Ca0.2)(Cr0.9−x Co0.1Cux)O3 Ceramics." Zeitschrift für Naturforschung A 72, no. 4 (April 1, 2017): 383–95. http://dx.doi.org/10.1515/zna-2016-0474.

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AbstractIn this article, structural properties and bonding behaviours of codoped lanthanum chromites (La0.8Ca0.2)(Cr0.9−x Co0.1Cux)O3 (x=0.00, 0.03, and 0.12) were investigated in detail. Polycrystalline chromite samples (La0.8Ca0.2)(Cr0.9−x Co0.1Cux)O3 (x=0.00, 0.03, and 0.12) were prepared by a standard solid-state reaction process. The synthesised samples were characterised for their structural, morphological, optical, and magnetic properties using powder XRD, SEM/EDS, UV–Vis, and VSM. XRD data showed that the samples were crystallised into a single phase with orthorhombic structure. Powder profile refinement analysis suggested the reduction in lattice parameters and cell volume with the addition of Cu. The electron density distributions and the bonding features of the prepared samples have been investigated using maximum entropy method (MEM). The mid bond electron density values revealed the enhancement of ionic nature between lanthanum and oxygen ions and a reduction in covalent nature between chromium and oxygen ions. Heterogeneous distribution of particles with different sizes was observed through SEM micrographs. EDS spectra confirms the presence of constituent elements in the prepared samples. Optical band gap values are decreasing with the addition of Cu. Antiferromagnetic ordering was observed from M–H curves obtained at room temperature. The structural and the magnetic properties are correlated.
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46

Yasuda, I., and T. Hikita. "Formation of calcium chromate hydroxylapatite on the surface of a calcium-doped lanthanum chromite sintered body." Journal of Materials Science 29, no. 10 (May 1994): 2801–5. http://dx.doi.org/10.1007/bf00356836.

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47

Yang, Y. "Characteristics of lanthanum strontium chromite prepared by glycine nitrate process." Solid State Ionics 135, no. 1-4 (November 1, 2000): 475–79. http://dx.doi.org/10.1016/s0167-2738(00)00402-1.

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48

Suzuki, M. "Oxide ionic conductivity of doped lanthanum chromite thin film interconnectors." Solid State Ionics 96, no. 1-2 (March 2, 1997): 83–88. http://dx.doi.org/10.1016/s0167-2738(97)00007-6.

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49

FERGUS, J. "Lanthanum chromite-based materials for solid oxide fuel cell interconnects." Solid State Ionics 171, no. 1-2 (June 2004): 1–15. http://dx.doi.org/10.1016/j.ssi.2004.04.010.

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50

ZHONG, Z. "Stoichiometric lanthanum chromite based ceramic interconnects with low sintering temperature." Solid State Ionics 177, no. 7-8 (March 15, 2006): 757–64. http://dx.doi.org/10.1016/j.ssi.2006.01.023.

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