Relevant bibliographies by topics / Lanthanide Chemistry

Academic literature on the topic 'Lanthanide Chemistry'

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Published: 10 December 2022
Last updated: 24 February 2023

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Journal articles on the topic "Lanthanide Chemistry"

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Evans, William J., and David S. Lee. "Early developments in lanthanide-based dinitrogen reduction chemistry." Canadian Journal of Chemistry 83, no. 4 (April 1, 2005): 375–84. http://dx.doi.org/10.1139/v05-014.

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Although the first crystallographically characterized lanthanide dinitrogen complex was reported in 1988 with samarium, it is only in recent years that this field has expanded to include fully characterized examples for the entire series of lanthanides. The development of lanthanide dinitrogen chemistry has been aided by a series of unexpected results that present some good lessons in the development of science. This review presents a chronological account of the lanthanide dinitrogen chemistry discovered in our laboratory through the summer of 2004.Key words: lanthanides, dinitrogen, reduction, alkali metal, nitrogen fixation, diazenido.
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Camp, Clément, Valentin Guidal, Biplab Biswas, Jacques Pécaut, Lionel Dubois, and Marinella Mazzanti. "Multielectron redox chemistry of lanthanide Schiff-base complexes." Chemical Science 3, no. 8 (2012): 2433–48. http://dx.doi.org/10.1039/c2sc20476b.

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Liu, Juewen. "Lanthanide-dependent RNA-cleaving DNAzymes as metal biosensors." Canadian Journal of Chemistry 93, no. 3 (March 2015): 273–78. http://dx.doi.org/10.1139/cjc-2014-0465.

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Lanthanides represent a group of very important but challenging analytes for biosensor development. These 15 elements are very similar in their chemical properties. So far, limited success has been realized using the rational ligand design approach. My laboratory has successfully accomplished the task of carrying out combinatorial selection to isolate lanthanide-dependent RNA-cleaving DNAzymes. We report two new DNAzymes, each discovered in a different selection condition and both are highly specific to lanthanides. When both DNAzymes are used together, it is possible to identify the last few heavy lanthanides. Upon introducing a phosphorothioate modification, one of the abovementioned DNAzymes becomes highly active with many toxic heavy metals. With the selection of more DNAzymes with different activity patterns cross the lanthanide series, a sensor array might be produced for identifying each ion. This article is a minireview of the current developments on this topic and some of the historical aspects. It reflects the main content of the Fred Beamish Award presentation delivered at the 2014 Canadian Society for Chemistry Conference in Vancouver. Future directions in this area are also discussed.
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Weißhoff, Hardy, Katharina Janek, Peter Henklein, Herbert Schumann, and Clemens Mügge. "Elution Behavior and Structural Characterization of N- and C-functionalized DOTA Complexes for the Labelling of Biomolecules." Zeitschrift für Naturforschung B 64, no. 10 (October 1, 2009): 1159–68. http://dx.doi.org/10.1515/znb-2009-1008.

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Two types of lanthanide complexes of 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (DOTA) for the labelling of biomolecules were investigated by HPLC, MS and NMR spectroscopy. The elution behavior of lanthanide complexes of N-functionalized DOTA [1,4,7,10-tetraazacyclododecane- 1,4,7-triacetic acid-10-maleimidoethylacetamide (nDOTA-Mal) and 1-{2-[4-(maleimido- N-propylacetamidobutyl)amino]-2-oxoethyl}-1,4,7,10-tetraazacyclododecane-4,7,10-triacetic acid (nDOTA-Bu-Mal)] and C-functionalized DOTA [2-{4-(maleimido-N-propylacetamido)benzyl}-1,4, 7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (cDOTA-Bnz-Mal) and 2-(4-isothiocyanatobenzyl)- 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid (cDOTA-Bnz-NCS)] was compared. N-functionalized lanthanide DOTA complexes coelute as required for their use as ICAT-analogous reagents. The complexation of the C-functionalized DOTA with lanthanides results in two fractions separable by HPLC. Coelution is observed for the main fractions of the lanthanide complexes. The retention times of the minor fractions show a dependence on the ionic radii of the metal ions. MALDI spectra of lanthanide-DOTA-peptide conjugates including different monoisotopic lanthanides demonstrate the advantage of the mass variations for extensive peptide and protein investigations.
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Savić, Aleksandar, Anna M. Kaczmarek, Rik Van Deun, and Kristof Van Hecke. "DNA Intercalating Near-Infrared Luminescent Lanthanide Complexes Containing Dipyrido[3,2-a:2′,3′-c]phenazine (dppz) Ligands: Synthesis, Crystal Structures, Stability, Luminescence Properties and CT-DNA Interaction." Molecules 25, no. 22 (November 13, 2020): 5309. http://dx.doi.org/10.3390/molecules25225309.

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In order to create near-infrared (NIR) luminescent lanthanide complexes suitable for DNA-interaction, novel lanthanide dppz complexes with general formula [Ln(NO3)3(dppz)2] (Ln = Nd3+, Er3+ and Yb3+; dppz = dipyrido[3,2-a:2′,3′-c]phenazine) were synthesized, characterized and their luminescence properties were investigated. In addition, analogous compounds with other lanthanide ions (Ln = Ce3+, Pr3+, Sm3+, Eu3+, Tb3+, Dy3+, Ho3+, Tm3+, Lu3+) were prepared. All complexes were characterized by IR spectroscopy and elemental analysis. Single-crystal X-ray diffraction analysis of the complexes (Ln = La3+, Ce3+, Pr3+, Nd3+, Eu3+, Er3+, Yb3+, Lu3+) showed that the lanthanide’s first coordination sphere can be described as a bicapped dodecahedron, made up of two bidentate dppz ligands and three bidentate-coordinating nitrate anions. Efficient energy transfer was observed from the dppz ligand to the lanthanide ion (Nd3+, Er3+ and Yb3+), while relatively high luminescence lifetimes were detected for these complexes. In their excitation spectra, the maximum of the strong broad band is located at around 385 nm and this wavelength was further used for excitation of the chosen complexes. In their emission spectra, the following characteristic NIR emission peaks were observed: for a) Nd3+: 4F3/2 → 4I9/2 (870.8 nm), 4F3/2 → 4I11/2 (1052.7 nm) and 4F3/2 → 4I13/2 (1334.5 nm); b) Er3+: 4I13/2 → 4I15/2 (1529.0 nm) c) Yb3+: 2F5/2 → 2F7/2 (977.6 nm). While its low triplet energy level is ideally suited for efficient sensitization of Nd3+ and Er3+, the dppz ligand is considered not favorable as a sensitizer for most of the visible emitting lanthanide ions, due to its low-lying triplet level, which is too low for the accepting levels of most visible emitting lanthanides. Furthermore, the DNA intercalation ability of the [Nd(NO3)3(dppz)2] complex with calf thymus DNA (CT-DNA) was confirmed using fluorescence spectroscopy.
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Xu, Hengbin, Jiamiao Qu, Milin Zhang, Yongde Yan, Xin Sun, Yanghai Zheng, Min Qiu, and Li Liu. "The linear relationship derived from the deposition potential of Pb–Ln alloy and atomic radius." New Journal of Chemistry 42, no. 20 (2018): 16533–41. http://dx.doi.org/10.1039/c8nj03342k.

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Pereira, Cláudia C. L., José M. Carretas, Bernardo Monteiro, and João P. Leal. "Luminescent Ln-Ionic Liquids beyond Europium." Molecules 26, no. 16 (August 10, 2021): 4834. http://dx.doi.org/10.3390/molecules26164834.

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Searching in the Web of Knowledge for “ionic liquids” AND “luminescence” AND “lanthanide”, around 260 entries can be found, of which a considerable number refer solely or primarily to europium (90%, ~234). Europium has been deemed the best lanthanide for luminescent applications, mainly due to its efficiency in sensitization, longest decay times, and the ability to use its luminescence spectra to probe the coordination geometry around the metal. The remaining lanthanides can also be of crucial importance due to their different colors, sensitivity, and capability as probes. In this manuscript, we intend to shed some light on the existing published work on the remaining lanthanides. In some cases, they appear in papers with europium, but frequently in a subordinate position, and in fewer cases then the main protagonist of the study. All of them will be assessed and presented in a concise manner; they will be divided into two main categories: lanthanide compounds dissolved in ionic liquids, and lanthanide-based ionic liquids. Finally, some analysis of future trends is carried out highlighting some future promising fields, such as ionogels.
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Vassiliev, Valery P., Valery A. Lysenko, and Marcelle Gaune-Escard. "Relationship of thermodynamic data with Periodic Law." Pure and Applied Chemistry 91, no. 6 (June 26, 2019): 879–93. http://dx.doi.org/10.1515/pac-2018-0717.

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Abstract Relationships between the various physical and chemical properties of isostructural compounds take place according to the Periodic Table that is a fundamental basis of Chemistry. The systematization of this approach, data vs. the Periodic Table, will contribute to further development of the solid state chemistry theory. The lanthanides and the actinides make up the f block of the Periodic Table. The lanthanides are the elements produced as the 4f sublevel is filled with electrons and the actinides are formed while filling the 5f sublevel. In this paper, we analyze some classes of compounds formed by the lanthanides with other elements of the Periodic Table, which can count into the thousands of binary compounds. The special place of lanthanides in the Periodic System of Elements made it possible to establish strict nonlinear relationships between the standard entropy and the lanthanide atomic number of the compounds Ln2X3 (X = O, S, Se, Te), LnN, LnB4, and LnF3 in the solid state. This relationship, based on tetrad-effect, can be applied to other physical and chemical properties of the isostructural compounds. The thermodynamic properties of actinides have been studied much less than lanthanides, but the similarity of physicochemical properties makes it possible for us to estimate, with sufficient accuracy, unexplored properties using fundamental laws. One of these laws is the tetrad-effect concept that is an effective tool to predict missing thermodynamic values for lanthanide and actinide compounds and to rationally plan experiments.
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Nielsen, Lea Gundorff, Anne Kathrine R. Junker, and Thomas Just Sørensen. "Composed in the f-block: solution structure and function of kinetically inert lanthanide(iii) complexes." Dalton Transactions 47, no. 31 (2018): 10360–76. http://dx.doi.org/10.1039/c8dt01501e.

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Wong-Ng, Winnie, Boris Paretzkin, and Edwin R. Fuller. "Crystal Chemistry and Phase Equilibria of the BaO-R2O3-CuO Systems." Advances in X-ray Analysis 33 (1989): 453–65. http://dx.doi.org/10.1154/s0376030800019881.

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AbstractTwo important factors, the progressively decreasing size of the lanthanides, which is known as the lanthanide contraction, as well as the stability of different oxidation states of these elements influence the prediction of compound formation in the Ba-R-Cu-O systems. A systematic investigation of these lanthanide systems and comparison with the Y system has revealed a correlation of the effect of the above factors, in particular the size factor, on the trend of phase formation, solid solution formation and phase compatibility diagrams of the Ba-R-Cu-O systems. For example, it has been found that the smaller the size of R3+ or the greater the mismatch betwaen Ba2+ and R3+ in the solid solution series Ba2-ZR1+lCu3O6+x, the smaller the extent of solid solution formation. This differing extent of solid solution formation influences the ternary phase relationships.
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Dissertations / Theses on the topic "Lanthanide Chemistry"

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Liu, Sung Ying. "Steric effects in Lanthanide pyrazolylborate chemistry." Thesis, University College London (University of London), 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.561271.

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Creaser, Dale Abel. "Aspects of composite lanthanide oxide chemistry." Thesis, University of Nottingham, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.334547.

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Jayasundera, Anil. "Solvothermal chemistry of luminescent lanthanide fluorides." Thesis, University of St Andrews, 2009. http://hdl.handle.net/10023/2125.

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Exploration of novel lanthanide fluoride framework materials in inorganic-organic hybrid systems under solvothermal conditions towards development of new luminescent materials is discussed. X-ray single crystal and powder diffraction methods have been used as crystallographic characterisation techniques. Determination and study of luminescence properties for selected hybrid materials has also been carried out. The first organically templated luminescent lanthanide fluoride framework, [C₂N₂H₁₀]₀.₅ [Ln₂F₇] (Ln= Nd, Tb, Dy, Ho, Er, Yb and Lu), has been synthesised and characterised. This structure type consists of a three-dimensional yttrium fluoride framework incorporating two similar, but crystallographically distinct, yttrium sites. Photoluminescence studies of [C₂N₂H₁₀]₀.₅ [Y₂F₇]: Ln³⁺ (Ln³⁺ = Gd³⁺, Eu³⁺ and Tb³⁺) have been explored and characteristic luminescence emissions are reported. An inorganic-organic hybrid indium fluoride and its scandium fluoride analogue, [C₄H₁₄N₂][MF₅](M=In and Sc) is reported. The structure consists of infinite trans vertex sharing (InF₅)[subscript(∞)] chains, which are linked via H-bonded organic moieties. The scandium and fluorine local environments of [C₄H₁₄N₂][ScF₅] are characterised by ¹⁹F, and ⁴⁵Sc solid-state MAS NMR spectroscopies. A single scandium site has been confirmed by ⁴⁵Sc MAS NMR. ¹⁹F MAS NMR clearly differentiates between bridging and terminal fluorine. The photoluminescence properties of these complexes, [C₄H₁₄N₂][In[subscript(1-x)] Ln[subscript(x)]F₅] (Ln=Tb and/or Eu), have been explored. The optimum composition for Eu³⁺ doped samples occurs at x = 0.05 Eu³⁺ and the “asymmetry ratio” of R = I₅₉₀/I₆₁₅ ( ⁵D₀ → ⁷F₂ and ⁵D₀ → ⁷F₁) gives a clear picture of the sensitivity for crystal field of the compound. For x = 0.08 Tb³⁺, a strong down-conversion fluorescence corresponding to ⁵D₄ → ⁷F₅ (green at 543.5 nm) occurs. In addition, a Tb³⁺/Eu³⁺ co-doped sample exhibits a combination of green (Tb³⁺) and orange (Eu³⁺) luminescence, with Tb³⁺ enhancing the emission of Eu³⁺ in this host. Exploration of novel indium, aluminium, and zirconium fluoride crystal structures with potential luminescent properties has also been undertaken. A chiolite-like phase K₅In₃F₁₄ (space group P4/mnc) has been synthesised. No phase transition occurs over the temperature range 113K< T< 293 K, as has been seen in other chiolite-like structures. An organically templated indium fluoride, [NH₄]₃[C₆H₂₁N₄]₂[In₄F₂₁] has been prepared; this features the trimeric unit [In₃F₁₅]³⁻ which appears to be the first of its type in a metal fluoride. A new hybrid fluoride, Sr[N₂C₂H₁₀]₂[Al₂F₁₂].H₂O has been synthesised. Because the ionic radius of Eu²⁺ is similar to that of Sr ²⁺ this may be a potential host for blue luminescent Eu²⁺. The new material KZrF₅.H₂O shows pentagonal-bipyramidal geometry of Zr⁴⁺ with a polar space group, Pb2₁m, which may potentially have ferroelectric properties.
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Xu, Xiaohan. "Acidity of Lanthanide Clusters." University of Akron / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=akron1619532111562154.

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Farkas, Ildiko. "Coordination Chemistry of Actinide and Lanthanide Ions." Doctoral thesis, KTH, Chemistry, 2001. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3236.

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Farkas, Ildikó. "Coordination chemistry of actinide and lanthanide ions /." Stockholm, 2001. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3236.

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Affholter, Kathleen. "Synthesis and crystal chemistry of lanthanide allanites." Diss., Virginia Tech, 1987. http://hdl.handle.net/10919/37332.

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Metamictization and complex chemistry are major obstacles to the crystal chemical characterization of natural allanites. To overcome these problems, allanites, Ca(REE)Fe²+Al₂Si₃O₁₂(OH), where REE = La, La-Ce, Ce, Nd, Sm, Eu, Gd, Er, Dy, Yb and Y have been synthesized hydrothermally from unbuffered and buffered oxide mixes at 500 to 650°C, 5.5 kbar (550 MPa), and 700 to 725°C, 4 kbar (400 MPa). Although allanite is readily synthesized, high yields are obtained only for allanite-(LREE) compositions, and end"member composition is obtained only for allanite-(La). Er and Yb ions are too small to substitute at the A(2) site in allanite, but a small amount can substitute at the VI~coordinated M(3) site. Fe²+ in the M(3) site favors LREE substitution, which supports the contention that allanite is Ce'selective.
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Timmins, Phillipa L. "Dinuclear luminescent lanthanide complexes." Thesis, University of York, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.274520.

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Lilley, Johnathon Robert. "Lanthanide nanoparticles in immunodiagnostics." Thesis, University of Birmingham, 2018. http://etheses.bham.ac.uk//id/eprint/8157/.

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This thesis shows the surface functionalisation of gold nanoparticles with surface active, luminescent Eu complexes and free light chain antibodies, to produce free light chain antibody functionalised gold nanoparticles which show characteristic, Eu luminescence. We show how these particles can be used in the development of a novel FRET based assay whereby the Eu luminescence is quenched on addition of free light chain specific antibody, labelled with a suitable organic FRET acceptor for Eu luminescence as measured by lifetime measurements. We show how these particles can be used to develop a competitive immunoassay to measure the concentration of free light chain antibodies. We also report the preparation of a novel functionalised dibenzoylmethane molecule with a thiol surface active group as to functionalise gold nanoparticles which can bind and sensitize Eu ions.
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Sudhakaran, Pillai S. "Luminescent materials based on Lanthanide ions." Thesis, Kingston University, 2010. http://eprints.kingston.ac.uk/20413/.

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The inclusion of lanthanide (III) (Ln[sup]3+) ions into polymers by “covalent” bonding has applications. Heteroleptic hydrotris(pyrazolyl)borate crotonate and cinnamate complexes were synthesised for reasons that, firstly, knowledge of the polymerisable double bond was helpful in establishing the conditions of any copolymerisation reaction; secondly, the chosen ligands are very good at receiving energy in the UV region; and thirdly, lanthanide complexes might undergo changes in properties, on moving between adjacent lanthanide ions, allowing potentially convenient isolations of pure materials at the monomer production stage, or even at the polymerisation stage. For both complexes, two classes of target complex were identified: the mononuclear (Er-Lu) and dinuclear (La-Ho). Mononuclear forms were identified by MS, [sup]1H NMR and elemental analysis and dinuclear forms were characterised by X-ray crystallography. For heteroleptic hydrotris(pyrazolyl)borate crotonate and cinnamate complexes, the ligands act as antennae for receiving and then transferring energy to metal ions and these complexes were studied in several homogeneous and heterogeneous copolymers as well as in rigid PMMA or polystyrene matrices. Luminescence decay of these complexes depends on the distance between the metal and C-H oscillators so the cinnamate complexes showed better luminescence life-times compared to crotonate complexes. The copolymer system helped to reduce the concentration quenching compared to corresponding metal complex / polymer blend systems. The thermal stabilities of the complex monomers were increased by incorporating them into polymer chains. Europium crotonate and cinnamate complexes in the poly(p-phenylenevinylene) (PPV) precursor blends showed the characteristic emission of europium, and the emission from PPV was quenched by increasing the europium content in the PPV precursor blends.
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Books on the topic "Lanthanide Chemistry"

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Lanthanide and actinide chemistry. Hoboken, NJ: Wiley, 2006.

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Cotton, Simon. Lanthanide and Actinide Chemistry. Chichester, UK: John Wiley & Sons, Ltd, 2006. http://dx.doi.org/10.1002/0470010088.

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Dolg, Michael, ed. Computational Methods in Lanthanide and Actinide Chemistry. Chichester, UK: John Wiley & Sons Ltd, 2015. http://dx.doi.org/10.1002/9781118688304.

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Dolg, Michael. Computational methods in lanthanide and actinide chemistry. Chichester, West Sussex: John Wiley & Sons, Inc., 2015.

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Hänninen, Pekka. Lanthanide Luminescence: Photophysical, Analytical and Biological Aspects. Berlin, Heidelberg: Springer-Verlag Berlin Heidelberg, 2011.

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R, Choppin Gregory, Navratil James D. 1941-, and Schulz Wallace W, eds. Proceedings of the International Symposium on Actinide/Lanthanide Separations, Honolulu, Hawaii, USA, 16-22 December 1984. Singapore: World Scientific, 1985.

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1959-, Kobayashi S., and Anwander R, eds. Lanthanides: Chemistry and use in organic synthesis. Berlin: Springer, 1999.

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Kobayashi, Shū, ed. Lanthanides: Chemistry and Use in Organic Synthesis. Berlin, Heidelberg: Springer Berlin Heidelberg, 1999. http://dx.doi.org/10.1007/3-540-69801-9.

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Optical spectroscopy of lanthanides: Magnetic and hyperfine interactions. Boca Raton, FL: CRC Press, 2008.

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Cotruvo, Joseph A. Lanthanide Biochemistry. Elsevier Science & Technology, 2021.

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Book chapters on the topic "Lanthanide Chemistry"

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Müller, Bernd G. "Lanthanide Fluorides." In Topics in f-Element Chemistry, 55–65. Dordrecht: Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3758-4_2.

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Coutsolelos, A. G. "Artificial Batteries with Lanthanide Porphyrins?" In Bioinorganic Chemistry, 349–57. Dordrecht: Springer Netherlands, 1995. http://dx.doi.org/10.1007/978-94-011-0255-1_26.

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Wang, Kezhi. "β-Diketonate Lanthanide Complexes." In Rare Earth Coordination Chemistry, 41–89. Chichester, UK: John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470824870.ch2.

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Chen, Xueyuan, Yongsheng Liu, and Datao Tu. "Surface Modification Chemistry of Lanthanide-Doped Nanoparticles." In Lanthanide-Doped Luminescent Nanomaterials, 59–74. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-40364-4_4.

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Bian, Zuqiang, and Chunhui Huang. "Electroluminescence Based on Lanthanide Complexes." In Rare Earth Coordination Chemistry, 435–72. Chichester, UK: John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470824870.ch11.

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Wang, Bingwu, Shangda Jiang, Xiuteng Wang, and Song Gao. "Lanthanide Based Magnetic Molecular Materials." In Rare Earth Coordination Chemistry, 355–405. Chichester, UK: John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470824870.ch9.

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Yao, Yingming, and Qi Shen. "Organometallic Chemistry of the Lanthanide Metals." In Rare Earth Coordination Chemistry, 309–53. Chichester, UK: John Wiley & Sons, Ltd, 2010. http://dx.doi.org/10.1002/9780470824870.ch8.

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Mills, David P., and Stephen T. Liddle. "Ligand Design in Modern Lanthanide Chemistry." In Ligand Design in Metal Chemistry, 330–63. Chichester, UK: John Wiley & Sons, Ltd, 2016. http://dx.doi.org/10.1002/9781118839621.ch12.

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Hoppe, Rudolf, and Stephan Voigt. "Polynary Alkali-Metal Lanthanide Oxides." In Topics in f-Element Chemistry, 225–35. Dordrecht: Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3758-4_9.

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Gomes, André Severo Pereira, Florent Réal, Bernd Schimmelpfennig, Ulf Wahlgren, and Valérie Vallet. "Applied Computational Actinide Chemistry." In Computational Methods in Lanthanide and Actinide Chemistry, 269–98. Chichester, UK: John Wiley & Sons Ltd, 2015. http://dx.doi.org/10.1002/9781118688304.ch11.

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Conference papers on the topic "Lanthanide Chemistry"

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SILVA, Andrei Marcelino Sá Pires, Edna Aparecida Faria de ALMEIDA, and Jorge Fernando Silva de MENEZES. "EXTRACTION, PURIFICATION, AND COMBINATION OF LAPACHOL IN NOVEL EUROPIUM COMPLEX." In SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 2021 INTERNATIONAL VIRTUAL CONFERENCE. DR. D. SCIENTIFIC CONSULTING, 2022. http://dx.doi.org/10.48141/sbjchem.21scon.38_abstract_silva.pdf.

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Lapachol belongs to the group of 1,4-naphthoquinones, with the addition of a hydroxide group attached to carbon 2 and a branched alkene nomenclature 3-methyl-2-butenyl attached to carbon 3, with final nomenclature 2-hydroxy-3 -(3-methyl-2-butenyl)-1,4-naphthoquinone. As a chromophore, it exhibits near-ultraviolet absorption, one of the important characteristics in the process of choosing ligands to integrate photoluminescent lanthanide complexes. Photoluminescent materials are currently widely used in the market for making plates, paints, plates, tapes, pigments, and other luminescent equipment. The use of what are called DMCLs (Molecular Light Converting Devices) is increasing in Photovoltaic Cells, Optical Luminescent Tracers, Forensic Chemistry, Fluoroimmunoassays, and more. Knowing the great demand for these devices, it is feasible to study and characterize new compounds that have favorable emission characteristics and that allow their use in the aforementioned categories. For this, the use of lanthanides is a great proposal, and the application of a chromophore ligand, such as Lapachol, aims to provide an increase in the emission of the final product. In the present work, the extraction, a new purification process of Lapachol from its natural source, the Ipê Roxo wood, is reported, as well as the characterizations that attest to the feasibility of the new process, in addition to the use of the material as a binder in lanthanide complexes.
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Chang, Woo Je, Shawn Irgen-Gioro, Suyog Padgaonkar, Rafael López-Arteaga, and Emily A. Weiss. "Charge transfer-mediated sensitization of lanthanide dopants by perovskite quantum dots." In Physical Chemistry of Semiconductor Materials and Interfaces XX, edited by Daniel Congreve, Christian Nielsen, Andrew J. Musser, and Derya Baran. SPIE, 2021. http://dx.doi.org/10.1117/12.2593678.

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FETTOUCH, Souad, Omar CHERKAOUI, Rachida ELOUATIB, and Mohamed TAHIRI. "Water Soluble Materials based on Phtalocyanine and Tetrapyridylporphyrin Triple Decker Lanthanide Complexes." In Annual International Conference on Chemistry, Chemical Engineering and Chemical Process. Global Science & Technology Forum (GSTF), 2015. http://dx.doi.org/10.5176/2301-3761_ccecp15.24.

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SHI, JINGSHENG, SHIHONG ZHONG, and SIYUAN ZHANG. "CALCULATION OF THE ELECTROSTATIC ENERGY He(fd) ON 4fN−15d CONFIGURATION OF LANTHANIDE IONS." In Proceedings of the International Symposium on Solid State Chemistry in China. WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812776846_0079.

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Pedraza, Francisco J., Julio C. Avalos, Lawrence C. Mimun, Brian G. Yust, Andrew Tsin, and Dhiraj Kumar Sardar. "Effects of surface chemistry on the optical properties and cellular interaction of lanthanide-based nanoparticles." In SPIE BiOS, edited by Samuel Achilefu and Ramesh Raghavachari. SPIE, 2015. http://dx.doi.org/10.1117/12.2079943.

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Pérez-Mayoral, Elena, Elena Soriano, Sebastián Cerdán, and Paloma Ballesteros. "Experimental and Theoretical Study of Lanthanide Complexes Based on Linear and Macrocyclic Polyaminopolycarboxylic Acids with Pyrazolylethyl Arms." In The 9th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01506.

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Zhao, Yan-Fang, Jing-Jing Li, and Yong-Liang Zhao. "Antibacterial Activities and Interactions Study of Ternary Lanthanide Schiff Base and Nitrogen-heterocyclic Complexes Bind to DNA." In 2015 4th International Conference on Mechatronics, Materials, Chemistry and Computer Engineering. Paris, France: Atlantis Press, 2015. http://dx.doi.org/10.2991/icmmcce-15.2015.192.

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GAPONENKO, N. V. "ENHANCED LUMINESCENCE OF LANTHANIDES FROM XEROGELS IN POROUS ANODIC ALUMINA." In Physics, Chemistry and Application of Nanostructures - Reviews and Short Notes to Nanomeeting 2003. WORLD SCIENTIFIC, 2003. http://dx.doi.org/10.1142/9789812796738_0105.

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Reports on the topic "Lanthanide Chemistry"

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Payne, G. (Lanthanide and actinide organometallic chemistry). Office of Scientific and Technical Information (OSTI), January 1987. http://dx.doi.org/10.2172/6751202.

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Evans, W. J. Synthesis and chemistry of yttrium and lanthanide metal complexes. Office of Scientific and Technical Information (OSTI), September 1991. http://dx.doi.org/10.2172/6267724.

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Evans, William John. Advancing Chemistry with the Lanthanide and Actinide Elements: Final Report, September 2013. Office of Scientific and Technical Information (OSTI), September 2013. http://dx.doi.org/10.2172/1147800.

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Evans, W. J. Synthesis and chemistry of yttrium and lanthanide metal complexes. Progress report, March 15, 1991--March 14, 1992. Office of Scientific and Technical Information (OSTI), September 1991. http://dx.doi.org/10.2172/10104789.

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Marino, Maria, M. and Walter C. Ermler. Reliable Electronic Structure Calculations for Heavy Element Chemistry: Molecules Containing Actinides, Lanthanides, and Transition Metals. Office of Scientific and Technical Information (OSTI), January 2006. http://dx.doi.org/10.2172/875418.

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