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1
Vezinet, Adrien, Emilie Thomassot, Yan Luo, Chiranjeeb Sarkar, and D. Graham Pearson. "Diachronous Redistribution of Hf and Nd Isotopes at the Crystal Scale—Consequences for the Isotopic Evolution of a Poly-Metamorphic Crustal Terrane." Geosciences 12, no. 1 (January 12, 2022): 36. http://dx.doi.org/10.3390/geosciences12010036.
Abstract:
In metamorphic rocks, mineral species react over a range of pressure–temperature conditions that do not necessarily overlap. Mineral equilibration can occur at varied points along the metamorphic pressure–temperature (PT) path, and thus at different times. The sole or dominant use of zircon isotopic compositions to constrain the evolution of metamorphic rocks might then inadvertently skew geological interpretations towards one aspect or one moment of a rock’s history. Here, we present in-situ U–Pb/Sm–Nd isotope analyses of the apatite crystals extracted from two meta-igneous rocks exposed in the Saglek Block (North Atlantic craton, Canada), an Archean metamorphic terrane, with the aim of examining the various signatures and events that they record. The data are combined with published U–Pb/Hf/O isotope compositions of zircon extracted from the same hand-specimens. We found an offset of nearly ca. 1.5 Gyr between U-Pb ages derived from the oldest zircon cores and apatite U–Pb/Sm–Nd isotopic ages, and an offset of ca. 200 Ma between the youngest zircon metamorphic overgrowths and apatite. These differences in metamorphic ages recorded by zircon and apatite mean that the redistribution of Hf isotopes (largely hosted in zircon) and Nd isotopes (largely hosted in apatite within these rocks), were not synchronous at the hand-specimen scale (≤~0.001 m3). We propose that the diachronous redistribution of Hf and Nd isotopes and their parent isotopes was caused by the different PT conditions of growth equilibration between zircon and apatite during metamorphism. These findings document the latest metamorphic evolution of the Saglek Block, highlighting the role played by intra-crustal reworking during the late-Archean regional metamorphic event.
2
Soloshenko, N. G., M. V. Streletskaya, M. V. Chervyakovskaya, and D. V. Kiseleva. "Implementation and experience of using methods for analyzing the isotopic composition of Sm and Nd, Rb and Sr in rock samples at the Geoanalitik Center for Collective Use." LITHOSPHERE (Russia) 24, no. 2 (May 7, 2024): 364–75. http://dx.doi.org/10.24930/1681-9004-2024-24-2-364-375.
Abstract:
Research subject. AGV-2 and BHVO-2 geochemical reference materials for studying the Sm, Nd and Rb, Sr isotope systems along with various rocks and mineral samples. Materials and Methods. An analysis of the isotopic composition of Sm, Nd and Rb, Sr was carried out using Neptune Plus and Triton Plus mass spectrometers. Aim. To implement analytical techniques for the isotopic composition of Sm and Nd, Rb, and Sr in various rock and mineral samples using two types of multicollector mass spectrometers – inductively coupled plasma NeptunePlus and thermal ionization TritonPlus (Thermo-Fisher), as well as a description of the procedure of processing experimental data and the experience in using techniques at the “Geoanalitik” shared research facilities of the IGG UB RAS for the period 2015-2023. Results. The analytical techniques implemented included (1) column chromatography using various ion-exchange resins, optimised for the ratio of labour costs/quality of analytical results; (2) the measurement of isotope ratios using two types of mass spectrometers; (3) the correction of mass bias of isotope ratios and the determination of Sm and Nd, Rb, and Sr concentrations by the isotope dilution method using 149Sm+150Nd and 85Rb+84Sr spikes. Testing of the techniques was carried out using the AGV-2 and BHVO-2 geochemical reference materials; their metrological characteristics were presented. When using TritonPlus, the reproducibility (BHVO-2, n=60) of measurements of 143Nd/144Nd, 147Sm/144Nd isotope ratios and Sm and Nd concentrations are ±0.000020, ±0.0004, ±1.3 and ±0.4, respectively; indicators of correctness of determining the ratios 143Nd/144Nd and 147Sm/144Nd – 0.001 and 0.25% and concentrations of Sm and Nd – 2%; the reproducibility (BHVO-2, n=63) of measurements of 87Sr/86Sr, 87Rb/86Sr isotope ratios and concentrations (Rb and Sr) are ±0.0025%, ±1.5%, ±2%, respectively. The uncertainty of a single measurement of the 143Nd/144Nd and 87Sr/86Sr isotope ratio, represented by the standard error of the average single measurement in the sample, does not exceed 0.0025%. Conclusions: the results obtained for the geochemical reference materials are in satisfactory agreement with those provided in the GeoReM database, as well as with the certified values provided by the United States Geological Survey (USGS). The described analytical techniques are used at the “Geoanalitik” shared research facilities of the IGG UB RAS to analyse various rock and mineral samples. The work presents a number of experimental results obtained, which are subsequently used in geochronological applications.
3
Chervyakovskaya, M. V., and V. S. Chervyakovskiy. "Determination of Sm/Nd and Sr isotopic composition using an ICP-MS Neptune Plus equipped with an NWR 213 attachment for laser ablation." LITHOSPHERE (Russia) 21, no. 5 (October 31, 2021): 712–23. http://dx.doi.org/10.24930/1681-9004-2021-21-5-712-723.
Abstract:
Research subject. The Sm/Nd isotope system was investigated using inter-laboratory natural samples of apatite, titanite, allanite, monazite, as well as intra-laboratory samples of apatite (from carbonatites, Ilmenogorsk massif, Ural), monazite (from pegmatites of the Aduy granite massif and its framing, Middle Urals) and titanite (from calcite veins, Saranov skoye chromite deposit, Middle Urals and from alkaline pegmatite, Shpat mine, Vishnevy mountains, South Urals). The Sr isotope system was investigated using inter-laboratory natural apatite samples and intra-laboratory apatite samples (from the apatite-carbonate vein, Slyudyanogorskoe deposit, Irkutsk region and from carbonatites, Ilmenogorsk massif, Ural).Methods. The research was carried using a Neptune Plus multicollector mass spectrometer with inductively coupled plasma (ThermoFisher) equipped with an NWR 213 (ESI) laser ablation attachment, located in a room of ISO class 7 at the “Geoanalyst” Center for Collective Use (IGG Ural Branch of the Russian Academy of Sciences, Ekaterinburg). Results. The article describes methodological approaches for studying Sm/Nd and Sr isotope systems in natural phosphate and silicate minerals by inductively coupled plasma mass spectrometry with laser ablation, implemented on the equipment of the Center for Collective Use “Geoanalyst” (IGG Ural Branch of the Russian Academy of Sciences, Ekaterinburg). A comparative analysis of the obtained results with those reported in literature showed their satisfactory agreement. The developed analytical approaches were used to study apatite samples (analysis of the Sr isotope system) and those of apatite, monazite, titanite (analysis of the Sr isotope system). Conclusions. The developed approaches to the analysis of Sm/Nd and Sr isotopic systems can be recommended for investigating such minerals, as apatite, titanite, allanite, monazite (analysis of the Sm/Nd isotope system); apatite (analysis of the Sr isotope system). The achieved analysis errors allow the results to be used for interpreting various geochemical processes.
4
Dempsey, C. S., A. N. Halliday, and I. G. Meighan. "Combined Sm-Nd and Rb-Sr isotope systematics in the Donegal granitoids and their petrogenetic implications." Geological Magazine 127, no. 1 (January 1990): 75–80. http://dx.doi.org/10.1017/s0016756800014175.
Abstract:
AbstractThe metaluminous to peraluminous granitoids of the Donegal batholith, northwest Ireland, were emplaced at c. 400 Ma into greenschist-amphibolite facies metasediments of the Dalradian Supergroup. Sm-Nd and Rb-Sr isotopic data are provided for eleven granitoid samples from six of the plutons and one specimen from the northeast granodiorite pluton of the Newry complex, Co. Down; the Donegal results reveal essentially similar initial Sr isotope ratios (0.7051–0.7068) but highly variable initial eNd values, −1.2 to −8.3 (and −0.5 for Newry). Certain granitoids have distinctive Nd isotopic compositions characteristic of the involvement of old, LREE-enriched continental crust in some cases or young crust and/or mantle-derived magmas in others. The Nd and Sr isotopic variations can be explained by a variety of mixing hypotheses.
5
Huber, Miłosz A., Stanisław Hałas, Yuri N. Neradovsky, Tamara B. Bayanova, Artem W. Mokrushin, and Lesia Lata. "Stable isotope geochemistry of sulfides from intrusion in Monchegorsk, northern part of Baltic Shield." Geochronometria 43, no. 1 (June 1, 2016): 96–101. http://dx.doi.org/10.1515/geochr-2015-0034.
Abstract:
Abstract The sulfide minerals from old mafic intrusion rocks from the Kola Peninsula were analyzed on stable sulfur isotopes. These samples were already dated by the Sm-Nd method. These sulfide samples were evaluated upon a geochemical composition by ICP-MS. The sulfide mineral samples were selected from the main ore-bearing rocks of the Monchetundra layered intrusion. The analyzed sulfides formed several generations of mineralization associated with primary and hydrothermal stage of formation of the deposits. Isotopic studies confirm a few consecutive stages of mineralization. These data were compared with the results of Sm-Nd dating of sulfide mineralization. The results of geochemical and geochronological studies indicate a complementarity in the context of determining the mineralization stages.
6
Collerson, Kenneth D., Malcolm T. McCulloch, and Allan P. Nutman. "Sr and Nd isotope systematics of polymetamorphic Archean gneisses from southern West Greenland and northern Labrador." Canadian Journal of Earth Sciences 26, no. 3 (March 1, 1989): 446–66. http://dx.doi.org/10.1139/e89-039.
Abstract:
Sr and Nd isotopic data for middle to late Archean polymetamorphic felsic gneisses from localities in the Nuuk area, West Greenland, are compared and contrasted with new isotopic results for early Archean Amîtsoq gneisses and with data for isotopically reworked Kiyuktok gneisses from the Saglek area, Labrador. Sr isotopic data for individual suites of felsic gneisses record the time-integrated effect of variable Rb–Sr fractionation during prograde and retrograde events as well as the effect of source inhomogeneity.Contrasting petrologic and Sr–Nd isotopic characteristics are the result of differences in level of exposure, caused partially by juxtaposition of terranes of different metamorphic character by movement on ductile shear zones and post-shearing folding deformation. Sm–Nd systematics of felsic gneisses from Nordafar, Ikerasakitsup akornga, Tinissaq, and Kangimut sammisoq – Qasigianguit define a geologically meaningless ca. 3280 Ma Nd "isochron", which is the result of mixing of samples from unrelated suites and the effect of open-system behaviour. Gneisses lying on this pseudoisochron were variably affected by ca. 2800–2900 Ma prograde granulite-facies metamorphism and structurally controlled retrogression under amphibolite- to greenschist-facies conditions.The study shows that Sr–Nd isotope systematics of geologically identifiable units may be modified by open-system behaviour during prograde and retrograde metamorphism. Isotopic data from gneiss complexes metamorphosed under granulite-facies conditions may therefore yield equivocal information concerning isochron interpretation, significance of model ages, and estimates of crustal residence time.
7
Nedosekova, I. L., V. A. Koroteev, T. B. Bayanova, P. A. Serov, V. I. Popova, and M. V. Chervyakovskaya. "On the age of pyrochlore carbonatites from the Ilmeno-Vishnevogorsky Alkaline Complex, the Southern Urals (insights from Rb-Sr and Sm-Nd isotopic data)." LITHOSPHERE (Russia) 20, no. 4 (August 31, 2020): 486–98. http://dx.doi.org/10.24930/1681-9004-2020-20-4-486-498.
Abstract:
Research subject. In this research, we carried out Sm-Nd- и Rb-Sr-dating of pyrochlore carbonatite from the Vishnevogorsky niobium deposit, Ilmeno-Vishnevogorsky Alkaline Complex, Southern Urals. IVC is located in the Ural fold region and is a carbonatite complex of the linear type. Rare metal (Nb-Zr-TR) deposits and occurrences are related to IVC. The age and the duration of IVC deposits formation remains a matter of debate. To determine the age of IVC carbonatites and related niobium ore, we measured Sm-Nd and Rb-Sr isotopic compositions and concentrations of the elements in the minerals (pyrochlore, calcite, apatite, biotite) and bulk sample of pyrochlore carbonatite. Materials and methods. The Sm and Nd isotopic compositions and concentrations were determined on a Finnigan MAT-262L (RPQ) seven-collector mass spectrometer in the static regime at the Geological Institute of the Kola Scientific Center, Apatity, Russia. The Sr and Rb isotopic compositions and concentrations were determined on thermos-ionization mass spectrometer Triton Plus (“Geoanalitik”, IGG UD RAN, Ekaterinburg, Russia). Results. Age of pyrochlore carbonatites from ore zone 140 (Vishnevogorsky deposit, IVC) defined by Sm-Nd and Rb-Sr isotopic methods. Mineral Sm-Nd-isochron (5 points) indicated age 229 ± 16 Ma, mineral Rb-Sr-isochron (5 points) showed similar age 250.5 ± 1.2 Ma. Conclusions. Results Sm-Nd и Rb-Sr dating indicate that the pyrochlore сarbonatites of ore zone 140 crystallized ≈ 250 Ma ago, at the stage of the postcollisional extension, possibly, in connection with exhumation complex, which was accompanied by decompression, partial melting of rocks, involving fluids, dissolution and precipitation of Ordovician-Silurian alkaline-carbonatitе complex. Thus, the formation of the IVC carbonatites and related Nb-ore, which began in Silurian (S), continued in Permian (P) and Triassic (T1-2) and was associated with the post-collision stage of tectonic activity in the Ural Fold Belt.
8
DICKIN, ALAN P. "The Chondritic Moon: a solution to the 142Nd conundrum and implications for terrestrial mantle evolution." Geological Magazine 153, no. 3 (January 8, 2016): 548–55. http://dx.doi.org/10.1017/s0016756815000990.
Abstract:
AbstractRecent discoveries that the Earth has a supra-chondritic 142Nd signature have thrown chondritic geochemical Earth models into doubt. Several solutions have been proposed to explain this discrepancy but none has been widely accepted. This paper reviews Nd isotope data for the Moon which bridge the gap between the 142Nd signatures of chondritic meteorites and the accessible Earth. Different chondrite classes define a 142Nd–148Nd correlation line attributed to incomplete mixing of nucleosynthetic components in the solar nebula. Terrestrial standards have 142Nd signatures well above this correlation line, but the 142Nd signature of the Bulk Moon is c. 6 ppm lower than terrestrial (assuming a chondritic Sm/Nd ratio) and falls within error of enstatite chondrites. In view of the demonstrated isotopic similarity between the Earth and Moon, giant impact models require the Moon to be a sample of the early Earth. Therefore, it is inferred that the Earth–Moon system was generated from material similar to enstatite chondrites, but Earth's mantle experienced Sm/Nd fractionation very soon after the Moon-forming collision. Such fractionation processes have been attributed to subduction of early Fe-enriched crust into a deep mantle storage reservoir. Because Sm/Nd fractionation occurred when most 146Sm had already decayed, the hidden incompatible-element-enriched reservoir only became slightly depressed in its 142Nd signature, explaining why this signal has not yet been detected in ocean island basalt sources.
9
Carlson, Richard W., Lars E. Borg, Amy M. Gaffney, and Maud Boyet. "Rb-Sr, Sm-Nd and Lu-Hf isotope systematics of the lunar Mg-suite: the age of the lunar crust and its relation to the time of Moon formation." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 372, no. 2024 (September 13, 2014): 20130246. http://dx.doi.org/10.1098/rsta.2013.0246.
Abstract:
New Rb-Sr, 146,147 Sm- 142,143 Nd and Lu-Hf isotopic analyses of Mg-suite lunar crustal rocks 67667, 76335, 77215 and 78238, including an internal isochron for norite 77215, were undertaken to better define the time and duration of lunar crust formation and the history of the source materials of the Mg-suite. Isochron ages determined in this study for 77215 are: Rb-Sr=4450±270 Ma, 147 Sm- 143 Nd=4283±23 Ma and Lu-Hf=4421±68 Ma. The data define an initial 146 Sm/ 144 Sm ratio of 0.00193±0.00092 corresponding to ages between 4348 and 4413 Ma depending on the half-life and initial abundance used for 146 Sm. The initial Nd and Hf isotopic compositions of all samples indicate a source region with slight enrichment in the incompatible elements in accord with previous suggestions that the Mg-suite crustal rocks contain a component of KREEP. The Sm/Nd— 142 Nd/ 144 Nd correlation shown by both ferroan anorthosite and Mg-suite rocks is coincident with the trend defined by mare and KREEP basalts, the slope of which corresponds to ages between 4.35 and 4.45 Ga. These data, along with similar ages for various early Earth differentiation events, are in accord with the model of lunar formation via giant impact into Earth at ca 4.4 Ga.
10
Sakhno, V. G., and L. S. Tsurikova. "Isotopic and geochemical features of the genesis of igneous complexes and ore-magmatic systems in the Chukotka sector of the Russian Arctic coast." LITHOSPHERE (Russia) 20, no. 2 (April 25, 2020): 196–211. http://dx.doi.org/10.24930/1681-9004-2020-20-2-196-211.
Abstract:
Research subject. The isotopic composition (Pb-Pb, Sm-Nd, Rb-Sr, Os/Os, Hf/Hf, 3 He/4 He, etc.) of magmatic complexes and ore-magmatic systems (OMS) of two ore clusters (Kupolsky and Ilirneysky) located in the subpolar Western Chukotka was studied. These ore clusters differ from each other both in their structural position and the age of their magmatic complexes, within which the largest deposits of Au-Ag type are known. Materials and methods. The Pb-Pb, Rb-Sr, SmNd, Re-Os, Lu-Hf, 3 He/4 He, 40Ar/36Ar and sulphur isotopic systems were studied at the VSEGEI centre for isotopic studies (St. Petersburg), as well as at the Institute of Geology, Geochemistry and Ore Deposits (IGEM, Moscow) and the Laboratory of Stable Isotopes of the Far Eastern Geological Institute (FEGI, Vladivostok). Re and Os were measured using an ELEMENT-2 inductively coupled plasma single-collector mass spectrometer. Sulphur isotopic ratios were measured using a Finnigan MAT 253 isotope mass spectrometer. Results and conclusions. On the basis of the isotope-geochemical data obtained, an assumption was made that various deep sources participated in the magma generation, and the differentiated composition of late melts may reflect the melting processes of the crust upper horizons. When comparing the data on the magmatism of the Ilirneysky and Kupolsky ore clusters, a different degree of crustal rock influence on melt generation was revealed. The Kupolsky ore cluster is characterised by a large influence of mantle sources in intraplate magmatism associated with ore formation processes. This is likely to have determined a greater amount of mineralisation in the Kupolsky cluster compared to the Ilirneysky ore cluster.
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Sommer, Carlos Augusto, Felipe Padilha Leitzke, Evandro Fernandes de Lima, Carla Joana Santos Barreto, Jean Michel Lafon, Vinicius Matté, Ruy Paulo Philipp, Rommulo Vieira Conceição, and Miguel Ângelo Stipp Basei. "Zircon U-Pb geochronology, Sm-Nd and Pb-Pb isotope systematics of Ediacaran post-collisional high-silica Acampamento Velho volcanism at the Tupanci area, NW of the Sul-Rio-Grandense Shield, Brazil." Brazilian Journal of Geology 47, no. 4 (December 2017): 545–60. http://dx.doi.org/10.1590/2317-4889201720170064.
Abstract:
ABSTRACT: We present new U-Pb zircon ages and Sm-Nd-Pb isotopic data for volcanic and hypabyssal acid rocks from the northernmost exposure of the Acampamento Velho Formation in the NW portion of the Sul-Rio-Grandense Shield, Brazil. The first volcanic episode, grouped in the high-Ti rhyolites from the Tupanci hill, shows age of 579 ± 5.6 Ma, which is in agreement with the post-collisional Acampamento Velho Formation volcanism in the Bom Jardim Group of the Camaquã Basin. A poorly constrained age of 558 +/- 39 Ma was obtained for rhyolites from the low-Ti group at the Picados Hill, which may indicate a younger acid volcanism, or a greater time span for the volcanism of the Acampamento Velho Formation in southernmost Brazil. Regarding magmatic sources, Sm/Nd isotopic data coupled to Pb isotopes and a review of trace element geochemistry indicate different amounts of Paleoproterozoic (Dom Feliciano, Pinheiro Machado Suite) to Neoproterozoic (Rio Vacacaí terrane) lower crust melting. Our data, coupled with literature data, contribute to a better understanding of the stratigraphic evolution for the Neoproterozoic post-collisional volcanic successions of the Camaquã Basin in the Sul-Rio-Grandense Shield.
12
SHELLNUTT, J. GREGORY, TUNG-YI LEE, CHIH-CHENG YANG, SHIN-TAI HU, JONG-CHANG WU, KUO-LUNG WANG, and CHING-HUA LO. "Late Permian mafic rocks identified within the Doba basin of southern Chad and their relationship to the boundary of the Saharan Metacraton." Geological Magazine 152, no. 6 (May 6, 2015): 1073–84. http://dx.doi.org/10.1017/s0016756815000217.
Abstract:
AbstractThe Doba gabbro was collected from an exploration well through the Cretaceous Doba basin of southern Chad. The gabbro is composed mostly of plagioclase, clinopyroxene and Fe–Ti oxide minerals and displays cumulus mineral textures. Whole-rock40Ar–39Ar step-heating geochronology yielded a Late Permian plateau age of 257 ± 1 Ma. The major and trace elemental geochemistry shows that the gabbro is tholeiitic in composition and has trace element ratios (i.e. La/YbN> 7; Sm/YbPM> 3.4; Nb/Y > 1; Zr/Y > 5) indicative of a basaltic melt derived from a garnet-bearing mantle source. The moderately enriched Sr–Nd isotopes (i.e. ISr= 0.70495 to 0.70839; ɛNd(T)= −1.0 to −1.3) fall within the mantle array (i.e. OIB-like) and are similar to other Late Permian plutonic rocks of North-Central Africa (i.e. ISr= 0.7040 to 0.7070). The enriched isotopic composition of the Doba gabbro contrasts with the more depleted compositions of the spatially associated Neoproterozoic post-Pan-African within-plate granites. The contrasting Nd isotope composition between the older within-plate granites and the younger Doba gabbro indicates that different mantle sources produced the rocks and thus may mark the southern boundary of the Saharan Metacraton.
13
Li, Piyou, Yuzhao Hu, Zhendong Tian, Shenjin Guan, and Huijun Fan. "Multi-Phase Hydrothermal Fluid Events in the Giant Lannigou Gold Deposit, SW China: Insights from Calcite Sm–Nd Age, Trace Elements, and C-O-Sr Isotopes." Minerals 13, no. 11 (November 8, 2023): 1420. http://dx.doi.org/10.3390/min13111420.
Abstract:
The Nanpanjiang basin hosts the world’s second-largest concentration of Carlin-type gold deposits. To decipher the origin and evolution of hydrothermal fluid, this study conducted Sm–Nd dating, in-situ trace element, and C-O-Sr isotopic analyses on three types of calcite samples from the giant Lannigou gold deposit in the Nanpanjiang basin, SW China. The type-I calcite, intergrown with Au-bearing arsenian pyrite, has an Sm–Nd isochron age of 213 ± 7 Ma (MSWD = 0.81), indicating that gold mineralization occurred in Late Triassic. The type-II calcite, which coexists with high-maturity bitumens and cut through the main-stage gold orebodies, yields an Sm–Nd age of 188 ± 14 Ma (MSWD = 0.34), representing a post-ore hydrocarbon accumulation event. The type-I and type-II calcite samples have low REE contents (5.28–51.6 ppm) and exhibit MREE-enriched and LREE-/HREE-depleted patterns. Combined with their identical C-O-Sr isotopes, we suggest that hydrothermal fluids responsible for the precipitation of type-I and type-II calcite samples were derived from a mixed metamorphic fluid and meteoric water source. In contrast, the type-III calcite samples, associated with realgar and orpiment, have distinct Mn, Sr, and As contents, REE patterns, and C-O-Sr isotopic composition from the type-I and II calcites, suggestive of different fluid sources. Based on our and previously published data, we propose that the fluid evolution, gold mineralization, and hydrocarbon accumulation in the Nanpanjiang basin are closely related to the Indosinian and Yanshanian orogenies in South China.
14
Jie-Dong, Yang, Sun Wei-Guo, Wang Zong-Zhe, and Wang Yin-Xi. "Sm—Nd isotopic age of Precambrian—Cambrian boundary in China." Geological Magazine 133, no. 1 (January 1996): 53–61. http://dx.doi.org/10.1017/s001675680000724x.
Abstract:
AbstractBy the new method of Sm—Nd isotopic dating on phosphatic small skeletal fossils and collo-phanite minerals, the Zhongyicun Member of the earliest Cambrian Meishucun Stage at Meishucun in Yunnan, southern China, has been dated at 562.8 ± 7.9 Ma and 562.1 ± 5.7 Ma. Another Sm—Nd age, 570.3 ± 17.1 Ma, has been obtained with samples from the Zhongyicun Member in Yunnan and its stratigraphic equivalents in Sichuan and Xinjiang. These data tend to suggest that the best age estimate of the Precambrian—Cambrian boundary is very likely within the range of 560–570 Ma. As biophosphates and sedimentary phosphates are widely distributed in sequences of the Precambrian—Cambrian transition, the Sm-Nd isotopic method is recommended as an effective approach for precise dating of the initial Cambrian boundary.
15
Serov, P. A., R. I. Kadyrov, and A. O. Kalashnikov. "X-RAY COMPUTED MICROTOMOGRAPHY OF SULFIDE MINERALS: MICROINCLUSION STUDIES AND IMPLICATIONS FOR ORE GENESIS Sm–Nd DATING." Доклады Российской академии наук. Науки о Земле 508, no. 2 (February 1, 2023): 216–22. http://dx.doi.org/10.31857/s2686739722601855.
Abstract:
A microtomographic study of the internal structure of sulfide minerals from ore varieties of rocks of two industrial deposits of the Arctic zone of the Russian Federation – disseminated ore of the Pilgujarvi Cu–Ni deposit of Pechenga and ore gabbronorites of the platinum-bearing Fedorovo-Pansky complex (Kola Peninsula) was carried out. It is shown that all studied sulfide samples have a homogeneous structure without obvious defects or silicate inclusions larger than 1 µm. The absence of silicate microinclusions larger than one micron in sulfides suggests an isomorphic form of REE occurrence in sulfides and, to some extent, eliminates the debatable problem of the influence of microinclusions on the results of Sm–Nd isotope-geochronological studies of sulfides. The presence of smaller (10–500 nm) silicate microinclusions is highly likely to be unable to control the total REE budget in a sulfide mineral. The conclusion about the absence of a significant effect of microinclusions on the obtained ages is confirmed by the results of Sm–Nd dating using sulfides from the same mineral samples: the Sm–Nd ages of the ores of the Pilgujarvi Cu–Ni deposit were 1965 ± 87 Ma; ore gabbronorites of the Fedorovo-Pansky complex – 2482 ± 61 Ma, which is in good agreement with the dates obtained earlier using other isotopic systems (U–Pb, Re–Os).
16
Li, Yihong, Shanshan Wang, Yu Yan, Jinpei Yan, Ruilian Yu, and Gongren Hu. "Characteristics and Provenance Implications of Rare Earth Elements and Nd Isotope in PM2.5 in a Coastal City of Southeastern China." Atmosphere 13, no. 9 (August 26, 2022): 1367. http://dx.doi.org/10.3390/atmos13091367.
Abstract:
The source apportionment of fine particulate matters, especially PM2.5, has drawn great attention worldwide. Since rare earth elements (REEs) and Nd isotopes can serve as source tracers, in this study, the characteristics and provenance implications of REEs and Nd isotopes in PM2.5 of four seasons in Xiamen city, China, were investigated. The range of the ratios of ΣREE to PM2.5 was 1.04 × 10−5 to 8.06 × 10−4, and the mean concentration of REEs in PM2.5 were in the order of spring > autumn > winter > summer. According to the geoaccumulation index (Igeo), spring was the season in which anthropogenic sources had the greatest impact on the REEs in PM2.5. The chondrite-normalized REE distribution patterns exhibited light rare earth elements (LREEs, including La, Ce, Pr, Nd, Pm, Sm and Eu) enrichment and a flat heavy rare earth elements (HREEs, including Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) pattern. Significant negative Eu anomalies and no significant Ce anomalies were observed in the PM2.5. The results of La-Ce-Sm ternary plots indicated that the REEs in the PM2.5 might be related to both natural and anthropogenic sources. Combined with the Nd isotope, the 143Nd/144Nd versus Ce/Ce* plot further illustrated that the REEs in the PM2.5 seemed to mostly originate from multiple potential sources, in which vehicle exhaust emissions, coal burning and cement dust made a great contribution to REEs in PM2.5.
17
Huang, Chao, Yue-Heng Yang, Jin-Hui Yang, and Lie-Wen Xie. "In situ simultaneous measurement of Rb–Sr/Sm–Nd or Sm–Nd/Lu–Hf isotopes in natural minerals using laser ablation multi-collector ICP-MS." Journal of Analytical Atomic Spectrometry 30, no. 4 (2015): 994–1000. http://dx.doi.org/10.1039/c4ja00449c.
Abstract:
This study presents a combined methodology of simultaneously measuring Rb–Sr/Sm–Nd or Sm–Nd/Lu–Hf isotopes in natural minerals by a means of two multiple collector inductively coupled plasma mass spectrometers connected to a 193 nm excimer laser ablation system.
18
Moorbath, S., and M. J. Whitehouse. "Sm-Nd Isotopic Data and Earth's Evolution." Science 273, no. 5283 (September 27, 1996): 1878. http://dx.doi.org/10.1126/science.273.5283.1878-a.
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Moorbath, S., and M. J. Whitehouse. "Sm-Nd Isotopic Data and Earth's Evolution." Science 273, no. 5283 (September 27, 1996): 1878a. http://dx.doi.org/10.1126/science.273.5283.1878a.
20
Azovskova, O. B., E. I. Soroka, M. Yu Rovnushkin, and N. G. Soloshenko. "Sm-Nd isotopy of the dykes of the Vorontsovskoe gold-ore deposit (Northern Urals)." Vestnik of Geosciences 9 (2020): 3–6. http://dx.doi.org/10.19110/geov.2020.9.1.
Abstract:
The Vorontsovskoye gold-ore deposit (Northern Urals) generally corresponds to the Carlin-type. One of the deposit features is the presence of numerous dykes of mafic and middle chemical composition, of normal and increased alkalinity. Sm-Nd isotope studies for the first time confirmed the dykes formation age 340 ± 35 Ma. These data can be indicative of the post-collisional stage of magmatism in this area. The positive Nd values suggest a probable abyssal magmatic source of Nd.
21
Frost, C. D., and R. A. Burwash. "Nd evidence for extensive Archean basement in the western Churchill Province, Canada." Canadian Journal of Earth Sciences 23, no. 9 (September 1, 1986): 1433–37. http://dx.doi.org/10.1139/e86-135.
Abstract:
To determine the extent of reworked Archean crust in the western Churchill Province, we have examined Sm–Nd crustal residence ages of basement cores in southern Alberta and southwestern Saskatchewan along with crustal residence ages calculated for other Sm–Nd data available from the Churchill Province. The deep drill hole samples from the Interior Platform give Sm–Nd crustal residence ages that average 2.8 Ga. Granulites from northeastern Alberta and composite gneisses from northern Saskatchewan also provide Archean crustal residence ages. These data demonstrate that the presence of reworked Archean crust in the western Churchill Province is more widespread than has been confirmed previously. We suggest that Sm–Nd crustal residence ages are valuable estimates of crust formation times, especially in orogenic areas where other isotope systems have been disturbed.
22
Wang, Da, Steven B. Shirey, Richard W. Carlson, Christopher M. Fisher, Anthony I. S. Kemp, and Marion E. Bickford. "Comparative Sm-Nd isotope behavior of accessory minerals: Reconstructing the Sm-Nd isotope evolution of early Archean rocks." Geochimica et Cosmochimica Acta 318 (February 2022): 190–212. http://dx.doi.org/10.1016/j.gca.2021.11.031.
23
Castorina, F., F. Stoppa, A. Cundari, and M. Barbieri. "An enriched mantle source for Italy's melilitite-carbonatite association as inferred by its Nd-Sr isotope signature." Mineralogical Magazine 64, no. 4 (August 2000): 625–39. http://dx.doi.org/10.1180/002646100549652.
Abstract:
AbstractNew Sr-Nd isotope data were obtained from Late Pleistocene carbonatite-kamafugite associations from the Umbria-Latium Ultra-Alkaline District of Italy (ULUD) with the aim of constraining their origin and possible mantle source(s). This is relevant to the origin and evolution of ultrapotassic (K/Na ≫2) and associated rocks generally, notably the occurrences from Ugandan kamafugites,Western Australian lamproites and South African orangeites. The selected ULUD samples yielded 87Sr/86Sr and 143Nd/144Nd ranging from 0.7100 to 0.7112 and from 0.5119 to 0.5121 respectively, similar to cratonic potassic volcanic rocks with higher Rb/Sr and lower Sm/Nd ratios than Bulk Earth. Silicate and carbonate fractions separated from melilitite are in isotopic equilibrium, supporting the view that they are cogenetic. The ULUD carbonatites yielded the highest radiogenic Sr so far reported for carbonatites. In contrast, sedimentary limestones from ULUD basement formations are lower in radiogenic Sr, i.e. 87Sr/86Sr = 0.70745–0.70735. The variation trend of ULUD isotopic compositions is similar to that reported for Ugandan kamafugites and Western Australian lamproites and overlaps the values for South African orangeites in the εSr-εNd diagram. A poor correlation between Sr/Nd and 87Sr/86Sr ratios in ULUD rocks is inconsistent with a mantle source generated by subduction-driven processes, while the negligible Sr and LREE in sedimentary limestones from the ULUD region fail to account for a hypothetical limestone assimilation process. The Nd model ages of 1.5–1.9 Ga have been inferred for a possible metasomatic event, allowing further radiogenic evolution of the source, a process which may have occurred in isolation until eruption time. While the origin of this component remains speculative, the Sr-Nd isotope trend is consistent with a simple mixing process involving an OIB-type mantle and a component with low εNd and high εSr.
24
Tan, Xia, Xie, Wang, Wei, Zhao, Yan, and Li. "Two Hydrothermal Events at the Shuiyindong Carlin-Type Gold Deposit in Southwestern China: Insight from Sm–Nd Dating of Fluorite and Calcite." Minerals 9, no. 4 (April 12, 2019): 230. http://dx.doi.org/10.3390/min9040230.
Abstract:
The Shuiyindong Gold Mine hosts one of the largest and highest-grade, strata-bound Carlin-type gold deposits discovered to date in Southwestern China. The outcrop stratigraphy and drill core data of the deposit reveal Middle–Upper Permian and Lower Triassic formations. The ore is mainly hosted in Upper Permian bioclastic limestone near the axis of an anticline. The gold is mainly hosted in arsenian pyrite and arsenopyrite, mainly existing in the form of crystal lattice gold, submicroscopic particles and nanoparticles. Fluorite commonly occurs at the vicinity of an unconformity between the Middle–Upper Permian formations, which is proposed to be the structural conduit that fed the ore fluids. Calcite commonly fills fractures at the periphery of decarbonated rocks, which contain high grade orebodies. This study aimed to verify the occurrence of two distinct hydrothermal events at the Shuiyindong, based on Sm–Nd isotope dating of the fluorite and calcite. For this purpose, rare-earth element (REE) concentrations, Sm/Nd isotope ratios, and Sm–Nd isochron ages of the fluorite and calcite were determined. The fluorite and calcite contain relatively high total concentrations of REE (12.3–25.6 μg/g and 5.71–31.7 μg/g, respectively), exhibit variable Sm/Nd ratios (0.52–1.03 and 0.57–1.71, respectively), and yield Sm–Nd isochron ages of 200.1 ± 8.6 Ma and 150.2 ± 2.2 Ma, with slightly different initial εNd(t) values of −4.4 and −1.1, respectively. These two groups of Sm–Nd isochron ages suggest two episodes of hydrothermal events at the Shuiyindong gold deposit. The age of the calcite probably represents the late stage of the gold mineralization period. The initial εNd(t) values of the fluorite and calcite indicate that the Nd was probably derived from mixtures of basaltic volcanic tuff and bioclastic limestone from the Permian formations.
25
Pimentel, Márcio M., and Maria da Glória Silva. "Sm-Nd age of the fazenda brasileiro gabbro, Bahia, Brazil: example of robust behavior of the Sm-Nd isotopic system under extreme hydrothermal alteration." Anais da Academia Brasileira de Ciências 75, no. 3 (September 2003): 383–92. http://dx.doi.org/10.1590/s0001-37652003000300009.
Abstract:
The Fazenda Brasileiro gold mineralization is hosted by a gabbroic sill, intrusive into metavolcanicmetasedimentary rocks of the Rio Itapicuru Greenstone Belt, São Francisco Craton. The 2.05 Ga old mineralization is associated with intense shearing and hydrothermal alteration, and the host gabbro is altered to a series of rocks rich in sericite, chlorite, actinolite, carbonate and quartz. Twelve whole-rock samples of the gold mineralization, representing varied degrees of alteration, from rocks with preserved igneous textures to the ore (quartz-carbonate-sulfide-chlorite), were studied by the Sm-Nd method. All analytical points resulted in an isochron (MSWD = 1.9) indicating the age of 2142 +/- 47 Ma (1s) and Epsilon Nd (T) of +1.2. Chlorite-sericite-carbonate rich hydrothermal rocks indicate the age of 2148 +/- 57 Ma and Epsilon Nd (T) of +1.1. The positive Epsilon Nd (T) suggest limited or no contamination with older continental crust, compatible with an oceanic setting for the tholeiites. Combined withREEdata, the Sm-Nd isotopic results reveal that the hydrothermal alteration, although intense, was unable to alter significantly the Sm/Nd ratios of the original igneous rocks and did not cause important scatter of the analytical points, providing a rare example of robust behavior of the isotopic system, even under intense hydrothermal alteration.
26
Kostitsyn, Y. A., A. R. Tskhovrebova, I. T. Rass, and M. O. Anosova. "Sr–Nd Isotopic Evidence of a Heterogeneous Magmatic Source of Alkaline–Carbonatite Rocks of the Odikhincha Alkaline–Carbonatite Massif (Maimecha-Kotui Province, Siberia)." Geochemistry International 61, no. 12 (December 2023): 1221–40. http://dx.doi.org/10.1134/s0016702923120030.
Abstract:
Abstract This study focuses on the igneous rocks composing the Odikhincha massif. The massif is typical ring alkaline–ultrabasic massif with carbonatites, second largest in the Maimecha-Kotui province. The Sr-Nd isotopic values of the traps of the Arydzhang Formation and the host dolomites were also determined for comparison. The Rb–Sr isotope system of phlogopite and calcite from the Od-16-19 carbonatite of the Odikhincha massif is disturbed; the obtained age on the mineral isochrone (245 ± 3 Ma) is close to the time of formation of the Siberian traps and rocks of the ultrabasic–alkaline Maimecha-Kotui complex, but the large scatter of analytical points (MSWD = 22) does not allow this date to be considered as reliable. The disturbance of the isotope system is probably related to the fact that the strontium isotope ratio in the fluid was not constant during autometasomatic phlogopitization of carbonatite. The U–Pb isotopic system of titanite and perovskite from the same carbonatite sample Od-16-19 also appeared to be disturbed, since data points formed discordia. The U–Pb age obtained for titanite and perovskite are 244 ± 5 Ma (MSWD = 1.8) and 247 ± 18 Ma (MSWD = 4), respectively. Apparently, the age values provided by the two isotopic systems (245 ± 3 Ma by Rb–Sr and 247 ± 18 and 244 ± 5 Ma by U–Pb) are consistent with each other and reflect the time of metasomatic processes, i.e., phlogopitization and iolitization. Rb–Sr and Sm–Nd isotope data for ultrabasic–alkaline intrusive rocks with carbonatites of the Odikhincha massif and volcanics of the Arydzhang Formation indicate an enriched, relative to the composition of the convecting mantle, isotopically heterogeneous source of their parent melts. This source could be a combination of ultrabasic mantle rocks and rocks of basic composition (basites). The latter played the role of an enriched component. No signs of contamination of the melts with the host sedimentary rocks in situ were found, however, variations of Sr and Nd isotopic ratios in the rocks of the Odikhincha massif may indicate that during the introduction of deep magmas their interaction and substance exchange with the surrounding rocks of the lithosphere continued up to complete solidification of the melts, as indicated by the nature of local isotopic heterogeneity within the Odikhincha intrusion.
27
Armstrong, Richard Lee, Randall R. Parrish, Peter van der Heyden, Krista Scott, Dita Runkle, and Richard L. Brown. "Early Proterozoic basement exposures in the southern Canadian Cordillera: core gneiss of Frenchman Cap, Unit I of the Grand Forks Gneiss, and the Vaseaux Formation." Canadian Journal of Earth Sciences 28, no. 8 (August 1, 1991): 1169–201. http://dx.doi.org/10.1139/e91-107.
Abstract:
The protolith age of high-grade metamorphic rocks exposed in structurally deep parts of the Omineca Crystalline Belt has been the subject of investigation and controversy for decades. We have applied multiple isotopic dating techniques to rocks of three structural culminations: the Monashee complex (which includes the Frenchman Cap and Thor–Odin gneiss domes), the Grand Forks horst, and the Vaseaux Formation, which lies in the footwall of the Okanagan Valley fault.Frenchman Cap core gneisses contain highly radiogenic Sr that scatters about a 2206 ± 117 Ma (1σ) Rb–Sr isochron with 87Sr/86Sr initial ratio of 0.700 ± 0.002. Monazite and zircon dates for the same rocks are 1851 ± 7 to 2103 ± 16 Ma (only U–Pb dates are given with 2σ errors), with lower intercepts from about 100 to 300 Ma. Sm–Nd whole-rock and crustal-residence (TDM) dates are 2.3 ± 0.2 Ga. Mafic–felsic layering in the core gneiss is also of Early Proterozoic age. There is no geochronometric evidence for Late Proterozoic or Mesozoic migmatization.Frenchman Cap mantling gneisses, including samples from above the Monashee décollement, have radiogenic Sr and unradiogenic Nd compositions that are not consistent with current inferences of a Late Proterozoic to Paleozoic depositional age. Two intrusive granitic rocks, which cut mantling gneiss, are either Early Proterozoic or Mesozoic–Cenozoic with a Proterozoic Sr isotopic signature acquired by assimilation of core gneiss. One other intrusive studied is probably Paleocene Ladybird granite. The age of the mantling gneiss is not yet consistently resolved.Grand Forks Gneiss Unit I paragneiss gives radiogenic whole-rock Sr, zircon U–Pb upper intercept, and Sm–Nd whole-rock crustal-residence dates of 1.7 ± 0.4 Ga, 1681 ± 3 Ma (2σ, but the apparent high precision is very dependent on the assumption made about the time of Pb loss), and 1.9 ± 0.3 Ga, respectively. Unit II and younger Grand Forks Gneiss units are Late Proterozoic or Phanerozoic. All isotope systems have been considerably reset on a centimetre to metre scale by Mesozoic–Cenozoic regional metamorphism. Grand Forks Sr, Pb, and Nd isotope data are much like those for Spokane area pre-Purcell basement.Vaseaux Formation micaceous schist and gneiss give radiogenic whole-rock Sr, zircon U–Pb upper intercept, and Sm–Nd crustal-residence dates of 2.1 ± 0.6 Ga, 1899 ± 49 Ma (2σ), and 2.2 ± 0.1 Ga, respectively. Hornblende-bearing schist and gneiss contain much less radiogenic Sr and more radiogenic Nd. The latter are either tectonic intercalations of Late Proterozoic to Paleozoic eugeosynclinal rocks or Mesozoic–Cenozoic mixtures of mantle-derived magma and older crustal rock. The Vaseaux Formation paragneiss is similar isotopically to paragneiss in the Frenchman Cap core gneiss. This may indicate a similar age, or that Vaseaux sedimentary rocks could be much younger and isochemically derived from a basement of Frenchman Cap character. The first alternative is favored because the three isotope systems are usually not preserved in unison through sedimentary processes. Sr isotopes, in particular, do not usually preserve a provenance age.In all three areas, late Mesozoic to early Cenozoic metamorphic monazite, hornblende, muscovite, and biotite dates provide a record of cooling from a Cretaceous to Paleocene culmination of regional metamorphism, with particularly rapid cooling during Paleocene to Eocene crustal extension and tectonic unroofing.The localities studied are tectonic windows on structural culminations that expose basement that we infer to be part of North America. Their ages fit the pattern of basement ages established for the stable craton. Their extent is consistent with the reconstruction of compressed miogeoclinal rocks. The eastern half of the Cordilleran region on both sides of the United States – Canada border is underlain by Early Proterozoic basement that was attenuated in Late Proterozoic time, compressed during Mesozoic–Cenozoic orogeny, and finally extended in early Cenozoic collapse of the thickened crust. During Mesozoic–Cenozoic orogeny the sedimentary cover of that basement was pushed approximately 200 km eastward and replaced by allochthonous terranes. The tectonic displacements documented in the southern Canadian Cordillera are truly exceptional.
28
Li, Zhuang. "Editorial for the Special Issue “Isotopic Tracers of Mantle and Magma Evolution”." Minerals 13, no. 10 (September 29, 2023): 1271. http://dx.doi.org/10.3390/min13101271.
29
Hyung, Eugenia, and François L. H. Tissot. "Routine high-precision Nd isotope analyses: an optimized chromatographic purification scheme." Journal of Analytical Atomic Spectrometry 36, no. 9 (2021): 1946–59. http://dx.doi.org/10.1039/d1ja00169h.
Abstract:
We present an optimized α-HIBA column chromatography method for Nd for high-precision isotope analyses (±2–5 ppm). It produces consistently high yields (>95%) and extremely good separation of Ce, Pr and Sm from Nd.
30
Pollock, J. C., P. J. Sylvester, and S. M. Barr. "Lu–Hf zircon and Sm–Nd whole-rock isotope constraints on the extent of juvenile arc crust in Avalonia: examples from Newfoundland and Nova Scotia, Canada." Canadian Journal of Earth Sciences 52, no. 3 (March 2015): 161–81. http://dx.doi.org/10.1139/cjes-2014-0157.
Abstract:
Avalonia, the largest accreted crustal block in the Appalachian orogen, consists of Neoproterozoic magmatic arc sequences that represent protracted and episodic subduction-related magmatism before deposition of an Ediacaran–Ordovician cover sequence including siliciclastic rocks. Zircon crystals were obtained from arc-related magmatic rocks and from clastic sedimentary sequences and analyzed in situ for their Hf-isotope composition. The majority of magmatic and detrital zircons are dominated by initial 176Hf/177Hf values that are more radiogenic than chondritic uniform reservoir (CHUR) with calculated crust formation Hf–TDM model ages that range from 0.84 to 1.30 Ga. These results suggest formation by partial melting of juvenile mantle in a Neoproterozoic continental arc. Some zircons have Hf–TDM model ages ca. 1.39–3.09 Ga with εHf values of –33.9 to –0.5 and more clearly indicate involvement of older lithosphere in their petrogenesis. Whole-rock Sm–Nd isotopic compositions from felsic volcanic rocks are characterized by positive initial εNd values with Mesoproterozoic depleted mantle model ages consistent with juvenile extraction. Results suggest a dominant mantle component with long-term light rare earth element (LREE) depletion mixed with an older crustal component with long-term LREE enrichment. The pattern of TDM model ages and variations in Lu–Hf and Sm–Nd isotopic character are compatible with a ca. 1.0–1.2 Ga igneous tectonomagmatic event that formed basement to Neoproterozoic magmatic arcs in Avalonia. The presence of evolved isotopic signatures, however, indicates that significant older Proterozoic crust is present locally beneath Avalonia, suggesting that Avalonia formed in a single Neoproterozoic arc system that generated juvenile mantle-derived crust, coupled with lesser anatectic reworking of significantly older crust.
31
Bowring, S. A., and T. Housh. "Response: Sm-Nd Isotopic Data and Earth's Evolution." Science 273, no. 5283 (September 27, 1996): 1878b—1879b. http://dx.doi.org/10.1126/science.273.5283.1878b.
32
Kotov, A. B., E. B. Sal’nikova, V. A. Glebovitsky, V. P. Kovach, A. M. Larin, S. D. Velikoslavinsky, and N. Yu Zagornaya. "Sm-Nd isotopic provinces of the Aldan Shield." Doklady Earth Sciences 410, no. 1 (October 2006): 1066–69. http://dx.doi.org/10.1134/s1028334x06070142.
33
Ovchinnikov, R. O., A. A. Sorokin, N. M. Kudryashov, V. P. Kovach, J. V. Plotkina, and T. M. Skovitina. "Age of the Early Paleozoic granitoid magmatismin the central part of the Bureya continental massif, Central Asian Fold Belt." Geodynamics & Tectonophysics 11, no. 1 (March 19, 2020): 89–106. http://dx.doi.org/10.5800/gt-2020-11-1-0465.
Abstract:
The article presents new age data on the ‘key’ Early Paleozoic igneous complexes located in the central part of the Bureya continental massif of the Central Asian Fold Belt. Porphyroblastic quartz monzonites of the Kivili complex are dated to 453±2 Ma. The age of gneissic granites of the Sularin complex is ~481 Ma. The Sm-Nd isotope studies show that Late Ordovician quartz monzonites were formed mainly from crustal sources with Paleoproterozoic Nd model isotopic ages. Both ancient (Paleoproterozoic?) and younger sources were involved in the formation of Cambrian granites. Our data, as well as previously published materials, suggest several stages of the Early Paleozoic magmatism in the evolution of the Bureya continental massif: ~541, ~504–500, ~487, ~474 and ~453 Ma. Early Paleozoic magmatism developed under a similar scenario in the Jiamusi continental massif. In addition to the synchronism of Neoproterozoic magmatism within these continental massifs, this feature testifies to their common geological history.
34
Serov, Pavel A., Tamara B. Bayanova, Ekaterina N. Steshenko, Evgeniy L. Kunakkuzin, and Elena S. Borisenko. "Metallogenic Setting and Evolution of the Pados-Tundra Cr-Bearing Ultramafic Complex, Kola Peninsula: Evidence from Sm–Nd and U–Pb Isotopes." Minerals 10, no. 2 (February 19, 2020): 186. http://dx.doi.org/10.3390/min10020186.
Abstract:
The article presents new Sm–Nd and U–Pb geochronological data on rocks of the poorly studied Pados-Tundra Cr-bearing complex. It is part of the Notozero mafic–ultramafic complex (western Kola Peninsula) and occurs at the border of the Paleoproterozoic Lapland Granulite Belt and the Archean Belomorian composite terrain. The Pados-Tundra complex hosts two major zones, the Dunite and Orthopyroxenite Blocks. Dunites are associated with four levels of chromite mineralization. Isotope Sm–Nd studies of dunites, harzburgites, and orthopyroxenites from the central part of the complex have been carried out. The isochron Sm–Nd age on 11 whole-rock samples from a rhythmically layered series of the complex is 2485 ± 38 Ma; the mineral Sm–Nd isochron for harzburgites shows the age of 2475 ± 38 Ma. It corresponds with the time of large-scale rifting that originated in the Fennoscandian Shield. When the rhythmically layered series of the intrusion and its chromite mineralization were formed, hornblendite dykes intruded. The U–Pb and Sm–Nd research has estimated their age at ca. 2080 Ma, which is likely to correspond with the occurrence of the Lapland–Kola Ocean. According to isotope Sm–Nd dating on metamorphic minerals (rutile, amphibole), the age of postmetamorphic cooling of rocks in the complex to 650–600 °C is 1872 ± 76 Ma. The U–Pb age on rutile from a hornblendite dyke (1804 ± 10 Ma) indicates further cooling to 450–400 °C. The conducted research has determined the early Proterozoic age of rocks in the rhythmically layered series in the Pados-Tundra complex. It is close to the age of the Paleoproterozoic ore magmatic system in the Fennoscandian Shield that developed 2.53–2.40 Ga ago. Later episodes of alterations in rocks are directly related to main metamorphic episodes in the region at the turn of 1.9 Ga. Results of the current study expand the geography of the vast Paleoproterozoic East Scandinavian Large Igneous Province and can be applied for further studies of similar mafic–ultramafic complexes.
35
Steshenko, Ekaterina N., Tamara B. Bayanova, and Pavel A. Serov. "The Paleoproterozoic Kandalaksha-Kolvitsa Gabbro-Anorthosite Complex (Fennoscandian Shield): New U–Pb, Sm–Nd, and Nd–Sr (ID-TIMS) Isotope Data on the Age of Formation, Metamorphism, and Geochemical Features of Zircon (LA-ICP-MS)." Minerals 10, no. 3 (March 10, 2020): 254. http://dx.doi.org/10.3390/min10030254.
Abstract:
The paper provides new U–Pb, Sm–Nd, and Nd–Sr isotope-geochronological data on rocks of the Paleoproterozoic Kandalaksha-Kolvitsa gabbro-anorthosite complex. Rare earth element (REE) contents in zircons from basic rock varieties of the Kandalaksha-Kolvitsa area were analyzed in situ using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Plots of REE distribution were constructed, confirming the magmatic origin of zircon. Temperatures of zircon crystallization were estimated using a Ti-in-zircon geochronometer. The U–Pb method with a 205Pb artificial tracer was first applied to date single zircon grains (2448 ± 5 Ma) from metagabbro of the Kolvitsa massif. The U–Pb analysis of zircon from anorthosites of the Kandalaksha massif dated the early stage of the granulite metamorphism at 2230 ± 10 Ma. The Sm–Nd isotope age was estimated on metamorphic minerals (apatite, garnet, sulfides) and whole rock at 1985 ± 17 Ma (granulite metamorphism) for the Kolvitsa massif and at 1887 ± 37 Ma (high-temperature metasomatic transformations) and 1692 ± 71 Ma (regional fluid reworking) for the Kandalaksha massif. The Sm–Nd model age of metagabbro was 3.3 Ga with a negative value of εNd = 4.6, which corresponds with either processes of crustal contamination or primary enriched mantle reservoir of primary magmas.
36
Stevenson, Ross K., P. J. Patchett, and R. F. Martin. "Sm–Nd isochron from a granodiorite–granite complex in the Portman Lake region, Northwest Territories." Canadian Journal of Earth Sciences 26, no. 12 (December 1, 1989): 2724–29. http://dx.doi.org/10.1139/e89-232.
Abstract:
Whole-rock samples for a granodiorite–granite intrusion in the Portman Lake area of the Northwest Territories yield an Sm–Nd isochron with an age of 2577 ± 36 Ma. The addition of a garnet analysis results in an age of 2562 ± 21 Ma. An Sm–Nd isochron is rare for granitic samples because of small ranges in 147Sm/144Nd values and variability in the initial Nd isotopic ratios. A wide range in 147Sm/144Nd values among samples in this study is considered a result of garnet fractionation and (or) variable concentrations of titanite in the samples. The εNd values for the initial Nd isotopic ratios of the isochrons are essentially zero or bulk Earth values. The evolution of the intrusion at 2.56 Ga reflects either the remelting of (2.7–2.8 Ga) preexisting continental crust or the mixing of depleted mantle material and crust older than 2.8 Ga. In either case, the data argue for a crustal history of at least 200 Ma prior to the intrusion of the complex in this section of the Churchill Province.
37
Serov, Pavel A. "Selective Neodymium Enrichment of Sulfides as a “Fingerprint” of Late Processes of Ore-Formation: Insight into Sm-Nd Isotopes for Sulfides from Magmatic Cu-Ni-PGE Complexes and Hydrothermal Pb-Zn, Au-Mo, and Gold Deposits." Minerals 12, no. 12 (December 19, 2022): 1634. http://dx.doi.org/10.3390/min12121634.
Abstract:
The effect of enrichment with Nd in sulfides from magmatic Cu-Ni-PGE complexes and sulfide ores from hydrothermal Pb-Zn, Au-Mo, and gold deposits was found and characterized. This paper concerns the report and analysis of isotopic geochemical data on the sulfide ores from the large Paleoproterozoic mafic–ultramafic magmatic Cu-Ni-PGE complexes of Fennoscandia and the literature data on sulfide ores from the Qingchengzi Pb-Zn deposit (northeastern China), Tokuzbay gold deposit (southern Altai, northwestern China), and Dahu Au-Mo deposit (central China). The mineral/rock partition coefficients for Nd and Sm (the DNd/DSm ratio) are defined as a prospective tool for the reconstruction of the sulfide mineral formation and geochemical substantiation of possible sources of ore-forming fluids for deposits of various genetic types. The observed selective Nd accumulation indicates either hydrothermal or metamorphic (metasomatic) impact, which is associated with increased Nd mobility and its migration or diffusion. Due to this process, there is a relative Nd accumulation in comparison with Sm and a consequent increase in the DNd/DSm ratio. At the isotopic system level, this leads to a sufficient decrease in the Sm/Nd ratio for the secondary sulfides of such kind. The revealed effect may serve as an isotopic geochemical marker of recent processes. These processes are quite frequently associated with the most important ore formation stages, which bear the commercially valuable concentrations of ore components. Sulfides from magmatic Cu-Ni-PGE complexes are more characterized by the selective accumulation of Nd in the sequential sulfide mineral formation. For sulfides from hydrothermal deposits, the effect of Nd enrichment is more intense and closely related to ore-forming fluids, under the influence of which sulfide mineralization is formed in multiple stages. The study aims at expanding the knowledge about fractionation and the behavior of lanthanides in ore-forming processes and allows the development of additional criteria for the evaluation of the ore potential of deposits with different geneses, ages, and formation conditions.
38
Su, Zhi-Kun, Xin-Fu Zhao, Xiao-Chun Li, Mei-Fu Zhou, Allen K. Kennedy, Jian-Wei Zi, Carl Spandler, and Yue-Heng Yang. "UNRAVELING MINERALIZATION AND MULTISTAGE HYDROTHERMAL OVERPRINTING HISTORIES BY INTEGRATED IN SITU U-Pb AND Sm-Nd ISOTOPES IN A PALEOPROTEROZOIC BRECCIA-HOSTED IOCG DEPOSIT, SW CHINA." Economic Geology 116, no. 7 (November 1, 2021): 1687–710. http://dx.doi.org/10.5382/econgeo.4840.
Abstract:
Abstract Precambrian iron oxide copper-gold (IOCG) deposits are generally encountered with multistage hydrothermal overprints and hence have complex isotopic records. Precise dating of ore-forming and overprinting events and assessment of time-resolved metal sources are fundamental for understanding ore genesis. Here, we quantify the evolution history by integrating in situ U-Pb dating of texturally constrained allanite and Sm-Nd isotope data of ores and major rare earth element (REE) minerals in the breccia-hosted Lanniping Fe-Cu deposit in Kangdian region, southwestern China. The economically mineralized breccia in Lanniping Fe-Cu deposit is characterized by pervasive and texturally destructive replacement of polymictic clasts, including host metasedimentary packages, the intruded dolerite, and pre-ore halokinetic breccia. Ore minerals in cements are mainly composed of magnetite, chalcopyrite, bornite, and variable amounts of REE-rich minerals (e.g., apatite and allanite/epidote). Two types of allanite were identified in ores. Type I prismatic allanite texturally intergrown with magnetite has a SHRIMP U-Pb age of 1728 ± 20 Ma (1σ), which matches a zircon U-Pb age of 1713 ± 14 Ma (2σ) for the dolerite clasts and provides the direct age constraint on the Fe-Cu mineralization event. Type II anhedral allanite shows complex zoning and is spatially associated with, but texturally later than, magnetite, apatite, and chalcopyrite. This type of allanite yields significantly younger SHRIMP dates of 1015 ± 33 (1σ) and 800 ± 16 Ma (1σ) for cores and rims, respectively, which correspond to discrete regional magmatic events and hence record hydrothermal overprint/remobilization events of ore minerals in the deposit. Integrated Sm-Nd isotope compositions of type I allanite, apatite, and whole ores generally align along the reference Sm-Nd isochron of 1728 Ma, further confirming the primary ore formation at ~1.7 Ga. Corresponding εNd(1728 Ma) values ranging from –2.8 to 0.3 are significantly higher than those of the host metasedimentary rocks (–9.5 to –6.2) but comparable to those of contemporaneous igneous intrusions (–0.3 to 5.3) in the region, demonstrating that REE components of the primary ores were dominantly sourced from rocks of mantle-derived affinity. Both cores and rims of the younger type II allanite grains have Nd isotope compositions consistent with the unique time-evolved line of the ~1.7 Ga ores, implying that REEs incorporated into type II allanite were ultimately sourced from the primary ores in this deposit. The combined texture, chemical, U-Pb, and Sm-Nd isotope data thus demonstrate that REE remobilization was localized during post-ore hydrothermal overprint with negligible external inputs of REEs to the primary ores in the Lanniping deposit. In this contribution, we not only date primary ore formation but also recognize several younger allanite generations that record internal metal redistributions in response to post-ore tectonothermal events. Our study highlights the potential of ore-associated REE minerals such as allanite for resolving the age of multiple stages of hydrothermal events in complex ore deposits by ion probe, provided that careful examination of textural and paragenetic relationship of ores is conducted. Our finding of these younger allanite generations also exemplifies the significance of evaluation on time-resolved metal input for better characterizing the evolution history of the IOCG deposits.
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Zhang, Zhiyuan, Guiqing Xie, Jingwen Mao, Wengang Liu, Paul Olin, and Wei Li. "Sm-Nd Dating and In-Situ LA-ICP-MS Trace Element Analyses of Scheelite from the Longshan Sb-Au Deposit, Xiangzhong Metallogenic Province, South China." Minerals 9, no. 2 (January 30, 2019): 87. http://dx.doi.org/10.3390/min9020087.
Abstract:
Longshan is an important Sb-Au ore deposit (3.7 Mt @4.5 wt. % Sb and 4.6 g/t Au) in the Xiangzhong metallogenic province (XZMP), South China. In the present work, trace element composition, Sm-Nd isotope dating, and Sr isotope of scheelite from the Longshan Sb-Au deposit are used to constrain the genesis of the deposit. Based on mineral assemblages and geological characteristics, two types of scheelites can be distinguished (Sch1 and Sch2). Sch1 is granular and cemented by stibnite, while Sch2 is commonly present in stibnite, pyrite, calcite, and quartz veins, indicating that Sch2 is later than Sch1. The Sm-Nd isochron age defined by Sch1 is 210 ± 2 Ma (MSWD = 1.0, n = 4). This age is interpreted as the age of Sb-Au mineralization and overlaps with the 201–228 Ma granitic rocks in the XZMP. Sch1 exhibits high ΣREE + Y contents (43.5 to 104 ppm), low Sr values (2687 to 6318 ppm, average of 4018 ppm), and a narrow range of 87Sr/86Sr values (0.7209 to 0.7210, average of 0.7209). In contrast, the elevated Sr abundance (4525 to 11,040 ppm, average of 6874 ppm) and wide 87Sr/86Sr ratios (0.7209 to 0.7228, average of 0.7214) in Sch2 were possibly caused by fluid-rock interaction mixing with Sr-enriched basement rocks. Sulfides have a narrow range of δ34S values of −1.8‰ to 3.2‰, with an average value of 1.1‰ (n = 7). Geochronological, geochemical and isotopic data suggest that the Longshan Sb-Au deposit is possible genetically related to the Late Triassic granitic intrusion in the XZMP.
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Kalsbeek, F. "Use of Rb-Sr isotope data to constrain the time of deposition of Precambrian metasediments: an example from Hamborgerland, West Greenland." Rapport Grønlands Geologiske Undersøgelse 159 (January 1, 1993): 95–100. http://dx.doi.org/10.34194/rapggu.v159.8216.
Abstract:
In high-grade metamorphic terrains it is often not possible to determine the relative age of metasedimentary units by field investigation. However, the time of deposition of the original sediment can be constrained by consideration of the Sr-isotopic evolution of the rocks on the scale of an outcrop. An outline of the method is given, and Rb-Sr data for high-grade (granulite facies) metasediments from HamborgerIand, West Greenland, are discussed as an example. Sm-Nd model age data indicate that these rocks were derived by erosion of a 3000–3200 Ma basement. Deposition took place not long before 2700 Ma ago, and closure of the Rb-Sr isotope system after high-grade metamorphism occurred at about 2600 Ma.
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Hu, J. Y., N. Dauphas, F. L. H. Tissot, R. Yokochi, T. J. Ireland, Z. Zhang, A. M. Davis, et al. "Heating events in the nascent solar system recorded by rare earth element isotopic fractionation in refractory inclusions." Science Advances 7, no. 2 (January 2021): eabc2962. http://dx.doi.org/10.1126/sciadv.abc2962.
Abstract:
Equilibrium condensation of solar gas is often invoked to explain the abundance of refractory elements in planets and meteorites. This is partly motivated, by the observation that the depletions in both the least and most refractory rare earth elements (REEs) in meteoritic group II calcium-aluminum–rich inclusions (CAIs) can be reproduced by thermodynamic models of solar nebula condensation. We measured the isotopic compositions of Ce, Nd, Sm, Eu, Gd, Dy, Er, and Yb in eight CAIs to test this scenario. Contrary to expectation for equilibrium condensation, we find light isotope enrichment for the most refractory REEs and more subdued isotopic variations for the least refractory REEs. This suggests that group II CAIs formed by a two-stage process involving fast evaporation of preexisting materials, followed by near-equilibrium recondensation. The calculated time scales are consistent with heating in events akin to FU Orionis– or EX Lupi–type outbursts of eruptive pre–main-sequence stars.
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Gao, Jian, Sheng He, Jian-xin Zhao, Zhiliang He, Changwu Wu, Yuexing Feng, Ai Duc Nguyen, Jiaxi Zhou, and Zhixing Yi. "Sm-Nd isochron dating and geochemical (rare earth elements, 87Sr/86Sr, δ18O, δ13C) characterization of calcite veins in the Jiaoshiba shale gas field, China: Implications for the mechanisms of vein formation in shale gas systems." GSA Bulletin 132, no. 7-8 (December 17, 2019): 1722–40. http://dx.doi.org/10.1130/b32015.1.
Abstract:
Abstract The Wufeng and Longmaxi organic-rich shales host the largest shale gas plays in China. This study examined the petrography, rare earth element (REE) and other trace-element geochemistry, Sm-Nd geochronology, and isotope geochemistry (87Sr/86Sr, δ18O, δ13C) of fracture-cementing minerals within core samples of the Wufeng and Longmaxi Formations from the Jiaoshiba shale gas field in order to (1) characterize the mineral phases occurring in the veins (mineralized fractures); (2) determine the ages of the calcite by the Sm-Nd isochron dating method; (3) understand the sources of calcite-precipitating fluids; and (4) explore the possible mechanisms responsible for calcite vein formation in shale gas systems. The fractures hosted in the Longmaxi Formation are mineralized with quartz as the predominant fracture cement, and calcite as an intracementation phase postdating the earlier quartz cement. In contrast, the fractures hosted in the Wufeng Formation are dominantly mineralized by calcite, which occurs either as the only cement present or as a cement phase predating later quartz cement. Calcite veins within the Longmaxi Formation have a Sm-Nd isochron age of 160 ± 13 Ma and δ13C values of –4.71‰ to –3.11‰, δ18O values of 17.1‰–17.4‰, and 87Sr/86Sr values of 0.72437–0.72869. Calcite veins within the Wufeng Formation yielded a Sm-Nd isochron age of 133 ± 15 Ma and are characterized by δ13C values of –2.29‰ to –1.03‰, δ18O values of 17.3‰–17.7‰, and 87Sr/86Sr values of 0.72202–0.72648. The similarity between 87Sr/86Sr values of the calcite and those of their respective surrounding host rocks (0.72670–0.72875 of the Longmaxi shales; 0.72030–0.72648 of the Wufeng shales), combined with relatively depleted δ13C and uniform fluid δ18O isotopic features, indicates that the calcite-precipitating fluids within the Wufeng and Longmaxi Formations were derived largely from their respective surrounding host-rock sources. REE data equally indicate that the distinguishable Eu anomalies (6.20–19.35; 4.45–11.91), Y anomalies (1.03–1.50; 1.44–1.70), and Y/Ho ratios (28.80–39.16; 38.86–45.18) of calcite veins within the Longmaxi and Wufeng Formations were controlled by their respective surrounding host rocks. The Sm-Nd isochron ages and fluid inclusion data of fracture cements suggest that fracture opening and calcite precipitation in composite veins within the Wufeng and Longmaxi Formations were triggered by gas generation overpressurization.
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McCoy-West, Alex J., Marc-Alban Millet, Geoff M. Nowell, Oliver Nebel, and Kevin W. Burton. "Simultaneous measurement of neodymium stable and radiogenic isotopes from a single aliquot using a double spike." Journal of Analytical Atomic Spectrometry 35, no. 2 (2020): 388–402. http://dx.doi.org/10.1039/c9ja00308h.
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Stevenson, R. K., X. W. Meng, and C. Hillaire-Marcel. "Impact of melting of the Laurentide Ice Sheet on sediments from the upper continental slope off southeastern Canada: evidence from Sm–Nd isotopesThis article is one of a series of papers published in this Special Issue on the theme Polar Climate Stability Network." Canadian Journal of Earth Sciences 45, no. 11 (November 2008): 1243–52. http://dx.doi.org/10.1139/e08-031.
Abstract:
We present new Sm–Nd isotope data for sediments from a core located on the continental slope of the St. Pierre Bank of Canada’s east coast. The Nd analyses indicate that the sediments were derived from two principal sources: the North American Shield that yields an average early Proterozoic isotopic signature and a younger Proterozoic signature attributed to Appalachian crustal sources. The Appalachian-sourced sediments predominated during the last glacial maximum (LGM) and were associated with low sedimentation rates (<30 cm/ka), with the exception of a strong North American Shield signature present in a detrital carbonate layer that corresponds to Heinrich Layer 1 (H1). The dominance of the Appalachian signature decreased subsequent to H1. The Appalachian signatures closely follow the distribution of sediments interpreted as locally derived glacial tills, while the North American Shield signatures follow the distribution of hemipelagic mud that was likely deposited by the Labrador Current. The Nd data are consistent with the persistence of the Wisconsinan Ice Sheet coverage of Newfoundland and the Grand Banks after the LGM, although the coverage began to wane prior to 12.5 ka as evidenced by the increasing influence of the Labrador Current. However, an increase in the Appalachian isotope signature at the close of the Younger Dryas event likely indicates the final melting of the ice sheet covering the Grand Banks and the Avalon Peninsula, and the initiation of the Labrador Current’s modern circulation pathway.
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Jahn, Bor-ming, Fuyuan Wu, and Bin Chen. "Granitoids of the Central Asian Orogenic Belt and continental growth in the Phanerozoic." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 91, no. 1-2 (2000): 181–93. http://dx.doi.org/10.1017/s0263593300007367.
Abstract:
The Central Asian Orogenic Belt (CAOB), also known as the Altaid Tectonic Collage, is characterised by a vast distribution of Paleozoic and Mesozoic granitic intrusions. The granitoids have a wide range of compositions and roughly show a temporal evolution from calcalkaline to alkaline to peralkaline series. The emplacement times for most granitic plutons fall between 500 Ma and 100 Ma, but only a small proportion of plutons have been precisely dated. The Nd-Sr isotopic compositions of these granitoids suggest their juvenile characteristics, hence implying a massive addition of new continental crust in the Phanerozoic. In this paper we document the available isotopic data to support this conclusion.Most Phanerozoic granitoids of Central Asia are characterised by low initial Sr isotopic ratios, positive εNd(T) values and young Sm—Nd model ages (TDM) of 300-1200 Ma. This is in strong contrast with the coeval granitoids emplaced in the European Caledonides and Hercynides. The isotope data indicate their ‘juvenile’ character and suggest their derivation from source rocks or magmas separated shortly before from the upper mantle. Granitoids with negative εNd(T) values also exist, but they occur in the environs of Precambrian microcontinental blocks and their isotope compositions may reflect contamination by the older crust in the magma generation processes.The evolution of the CAOB is probably related to accretion of young arc complexes and old terranes (microcontinents). However, the emplacement of large volumes of post-tectonic granites requires another mechanism, probably through a series of processes including underplating of massive basaltic magma, intercalation of basaltic magma with lower crustal granulites, partial melting of the mixed lithologic assemblages leading to generation of granitic liquids, followed by extensive fractional crystallisation. The proportions of the juvenile or mantle component for most granitoids of Central Asia are estimated to vary from 70% to 100%.
46
FISCHEL, DANIELLE P., MÁRCIO M. PIMENTEL, REINHARDT A. FUCK, and RICHARD ARMSTRONG. "U-Pb SHRIMP and Sm-Nd geochronology of the Silvânia Volcanics and Jurubatuba Granite: juvenile Paleoproterozoic crust in the basement of the Neoproterozoic Brasília Belt, Goiás, central Brazil." Anais da Academia Brasileira de Ciências 73, no. 3 (September 2001): 445–60. http://dx.doi.org/10.1590/s0001-37652001000300012.
Abstract:
U-Pb SHRIMP and Sm-Nd isotopic ages were determined for felsic metavolcanic rocks from the Silvânia Sequence and Jurubatuba Granite in the central part of the Brasília Belt. Zircon grains from a metavolcanic sample yielded 2115 ± 23 Ma and from the granite yielded 2089 ± 14 Ma, interpreted as crystallization ages of these rocks. Six metavolcanic samples of the Silvânia Sequence yielded a six-point whole-rock Sm-Nd isochron indicating a crystallization age of 2262 ± 110 Ma and positive epsilonNd(T) = +3.0 interpreted as a juvenile magmatic event. Nd isotopic analyses on samples from the Jurubatuba Granite have Paleoproterozoic T DM model ages between 2.30 and 2.42 Ga and epsilonNd(T) values vary between -0.22 and -0.58. The oldest T DM value refers to a sedimentary xenolith in the granite. These results suggest crystallization ages of Silvânia volcanics and Jurubatuba Granite are the first evidence of a ca. 2.14-2.08 juvenile magmatic event in the basement of the central part of the Brasília Belt that implies the presence of arc/suture hidden in reworked basement of the Brasília Belt.
47
ALI, K., A. ANDRESEN, W. I. MANTON, R. J. STERN, S. A. OMAR, and A. E. MAURICE. "U–Pb zircon dating and Sr–Nd–Hf isotopic evidence to support a juvenile origin of the ~ 634 Ma El Shalul granitic gneiss dome, Arabian–Nubian Shield." Geological Magazine 149, no. 5 (December 16, 2011): 783–97. http://dx.doi.org/10.1017/s0016756811000975.
Abstract:
AbstractThe calc-alkaline, gneissic El Shalul granite is the westernmost gneiss dome or core complex within the Arabian–Nubian Shield. Previous studies have indicated that it represents either a window into the underlying pre-Neoproterozoic Sahara metacraton or a melt derived from the metacraton. U–Pb LA-ICP-MS dating of magmatic zircons from two samples of the variably foliated El Shalul pluton gives ages of 637 ± 5 Ma and 630 ± 6 Ma, excluding it from representing exhumed cratonic rocks. The ages are, however, indistinguishable from the age of the Um Ba'anib pluton, constituting the core of the Meatiq Gneiss Dome, as well as several other plutons in the Eastern Desert, indicating an important magmatic pulse in the Arabian–Nubian Shield in Late Cryogenian time. Major and trace element data indicate a within-plate setting. Bulk rock Nd-isotope and Hf-isotope data on zircons from the El Shalul pluton indicate derivation of the primary melt from a relatively juvenile source, either the lower crust of a mid-Neoproterozoic volcanic arc or as a result of fractionation of a mantle-derived mafic melt. Sm–Nd bulk rock isotopic data indicate a model age of c. 720 Ma for the protolith from which the melt was derived. Time-corrected Hf-isotope data obtained on the magmatic zircons indicate that the bulk of the source rock was extracted from the mantle around 810 Ma.
48
Goodrich, Cyrena Anne, P. Jonathan Patchett, Gunter W. Lugmair, and Michael J. Drake. "Sm-Nd and Rb-Sr isotopic systematics of ureilites." Geochimica et Cosmochimica Acta 55, no. 3 (March 1991): 829–48. http://dx.doi.org/10.1016/0016-7037(91)90345-6.
49
Mørk, Mai Britt E., and Euan W. Mearns. "SmNd isotopic systematics of a gabbro-eclogite transition." Lithos 19, no. 3-4 (October 1986): 255–67. http://dx.doi.org/10.1016/0024-4937(86)90026-5.
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Badanina, E. V., L. F. Syritso, A. A. Ivanova, and N. G. Rizvanova. "Age and Isotope-Geochemical Characteristics of Ta, Nb, W, Sn Mineralization Associated with Rare-Metal Granites (Khangilay Ore District, Eastern Transbaikalia)." Петрология 31, no. 4 (July 1, 2023): 376–87. http://dx.doi.org/10.31857/s0869590323040039.
Abstract:
The age relations between the formation of the parent massif and the time of crystallization of the associated ore mineralization were established on the basis of isotope-geochronological study of the massifs-deposits of the Khangily ore district with various metallogenic specialization in Eastern Transbaikalia. In the Orlovka massif of Li-F granites, the crystallization time of columbite-tantalite (145 ± 1 Ma) and cassiterite (144.2 ± 0.3 Ma) (U-Pb, ID-TIMS) is almost identical to the crystallization time of zircon (140.6 ± 2.9 Ма (U-Pb, SHRIMP) and 145 ± 1 Ma (U-Pb, CA-ID-TIMS)) – an age marker of the formation of massifs. This fact testifies to the magmatogenic nature of rare-metal mineralization. In the Spokojnoye massif – the “standard type” of rare-metal peraluminous granites – a time gap with an interval of 0.6–3.8 Ma was revealed between the time of formation of the massif (141.3 ± 1.8 Ма, U-Pb, SHRIMP, 146.9 ± 0.7 Ма, Rb-Sr isotopic system) and crystallization of wolframite (141.8 ± 0.6, Rb-Sr isotopic system and 140.1 ± 1.4 Ма, Sm-Nd isotopic system). Perhaps this interval corresponds to the time of formation of the hydrothermal system, with which tungsten mineralization is genetically related.