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1
Pierre, G., A. Valentin, and L. Henry. "Étude par transformée de Fourier, du spectre, du silane dans la région de 1000 cm−1. Analyse de la diade ν2 et ν4." Canadian Journal of Physics 64, no. 3 (March 1, 1986): 341–50. http://dx.doi.org/10.1139/p86-060.
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A Fourier-transform absorption spectrum of the three silicium isotopes of silane in natural abundance have been recorded from 840 to 1040 cm−1. The line width is 3 × 10−3 cm−1 and the absolute accuracy is estimated to be about 2 × 10−4 cm−1 for non-saturated and non-overlapped lines. The analysis of this spectrum is achieved, using a Hamiltonian, formulated with an irreducible tensorial set in the Td group.For the dyad ν2 and ν4 and for each isotopic species, 30 reduced effective Hamiltonian parameters are determined, giving the line wave numbers with 2.5 × 10−4 cm−1 for 28SiH4, 3.4 × 10−4 cm−1 for 29SiH4, and 5.5 × 10−4 cm−1 for 30SiH4 as the standard deviation for J = 0–20.
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Hendry, Katharine R., Melanie J. Leng, Laura F. Robinson, Hilary J. Sloane, Jerzy Blusztjan, Rosalind E. M. Rickaby, R. Bastian Georg, and Alex N. Halliday. "Silicon isotopes in Antarctic sponges: an interlaboratory comparison." Antarctic Science 23, no. 1 (August 20, 2010): 34–42. http://dx.doi.org/10.1017/s0954102010000593.
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AbstractCycling of deepwater silicon (Si) within the Southern Ocean, and its transport into other ocean basins, may be an important player in the uptake of atmospheric carbon, and global climate. Recent work has shown that the Si isotope (denoted by δ29Si or δ30Si) composition of deep sea sponges reflects the availability of dissolved Si during growth, and is a potential proxy for past deep and intermediate water silicic acid concentrations. As with any geochemical tool, it is essential to ensure analytical precision and accuracy, and consistency between methodologies and laboratories. Analytical bias may exist between laboratories, and sponge material may have matrix effects leading to offsets between samples and standards. Here, we report an interlaboratory evaluation of Si isotopes in Antarctic and sub-Antarctic sponges. We review independent methods for measuring Si isotopes in sponge spicules. Our results show that separate subsamples of non-homogenized sponges measured by three methods yield isotopic values within analytical error for over 80% of specimens. The relationship between δ29Si and δ30Si in sponges is consistent with kinetic fractionation during biomineralization. Sponge Si isotope analyses show potential as palaeoceaongraphic archives, and we suggest Southern Ocean sponge material would form a useful additional reference standard for future spicule analyses.
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Antonelli, Michael A., Tushar Mittal, Anders McCarthy, Barbara Tripoli, James M. Watkins, and Donald J. DePaolo. "Ca isotopes record rapid crystal growth in volcanic and subvolcanic systems." Proceedings of the National Academy of Sciences 116, no. 41 (September 23, 2019): 20315–21. http://dx.doi.org/10.1073/pnas.1908921116.
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Kinetic calcium isotope effects can be used as growth-rate proxies for volcanic and subvolcanic minerals. Here, we analyze Ca isotopic compositions in experimental and natural samples and confirm that large kinetic effects (>2‰) can occur during magmatic plagioclase crystallization. Experiments confirm theoretical predictions that disequilibrium isotope effects depend mainly on the rates for crystal growth relative to liquid phase Ca diffusivity (R/D). Plagioclase phenocrysts from the 1915 Mount Lassen rhyodacite eruption, the ∼650-y-old Deadman Creek Dome eruption, and several mafic subvolcanic orbicules and plagioclase comb layers from Northern California have disequilibrium Ca isotopic compositions that suggest rapid crystal growth rates (>1 cm/y to 15 cm/y). The Ca isotope results, combined with complementary crystal-size distribution analyses, suggest that magmatic rejuvenation (and eruption) events, as reflected in crystal growth times, can be as short as ∼10−3 y. Although mafic systems are predicted to have shorter magmatic rejuvenation periods, we find similarly short timescales in both mafic and silicic systems. These results are consistent with a growing body of evidence suggesting that dominantly crystalline volcanic magma reservoirs can be rapidly reactivated by the injection of fresh magma prior to eruption. By focusing on a common mineral such as plagioclase, this approach can be applied across all major magmatic compositions, suggesting that Ca isotopes can be used as a tool for investigating the dynamics and timing of volcanic eruptions.
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Codnia, J., V. D'Accurso, and M. L. Azcárate. "Silicon isotopes enrichment." Anales AFA 27, no. 1 (April 20, 2016): 35–39. http://dx.doi.org/10.31527/analesafa.2016.27.1.35.
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Hendry, K. R., G. E. A. Swann, M. J. Leng, H. J. Sloane, C. Goodwin, J. Berman, and M. Maldonado. "Technical Note: Silica stable isotopes and silicification in a carnivorous sponge \\textit{Asbestopluma} sp." Biogeosciences Discussions 11, no. 12 (December 2, 2014): 16573–97. http://dx.doi.org/10.5194/bgd-11-16573-2014.
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Abstract. The stable isotope composition of benthic sponge spicule silica is a potential source of palaeoceanographic information about past deep seawater chemistry. The silicon isotopic composition of spicules has been shown to relate to the silicic acid concentration of ambient water, although existing calibrations do exhibit a degree of scatter in the relationship. Less is known about how the oxygen isotope composition of sponge spicule silica relates to environmental conditions during growth. Here, we investigate the biological vital effects on silica silicon and oxygen isotope composition in a carnivorous sponge, Asbestopluma sp., from the Southern Ocean. We find significant variations in silicon and oxygen isotopic composition within the specimen that appear related to unusual spicule silicification. The largest variation in both isotope systems was associated to the differential distribution of an unconventional, hypersilicified spicule type (desma) along the sponge body. The absence of an internal canal in the desmas suggests an unconventional silicification pattern leading to an unusually heavy isotopic signature. Additional internal variability derives from a systematic offset between the peripheral skeleton of the body having systematically a higher isotopic composition than the internal skeleton. A simplified silicon isotope fractionation model, in which desmas were excluded, suggests that the lack of a system for seawater pumping in carnivorous sponges favours a low replenishment of dissolved silicon within the internal tissues, causing kinetic fractionation during silicification that impacts the isotopic signature of the internal skeleton. Analysis of multiple spicules should be carried out to "average out" any artefacts in order to produce more robust downcore measurements.
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Wang, Wei, Jiang, Liu, Lei, Lin, and Zhao. "Silicon Isotope Geochemistry: Fractionation Linked to Silicon Complexations and Its Geological Applications." Molecules 24, no. 7 (April 10, 2019): 1415. http://dx.doi.org/10.3390/molecules24071415.
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The fundamental advances in silicon isotope geochemistry have been systematically demonstrated in this work. Firstly, the continuous modifications in analytical approaches and the silicon isotope variations in major reservoirs and geological processes have been briefly introduced. Secondly, the silicon isotope fractionation linked to silicon complexation/coordination and thermodynamic conditions have been extensively stressed, including silicate minerals with variable structures and chemical compositions, silica precipitation and diagenesis, chemical weathering of crustal surface silicate rocks, biological uptake, global oceanic Si cycle, etc. Finally, the relevant geological implications for meteorites and planetary core formation, ore deposits formation, hydrothermal fluids activities, and silicon cycling in hydrosphere have been summarized. Compared to the thermodynamic isotope fractionation of silicon associated with high-temperature processes, that in low-temperature geological processes is much more significant (e.g., chemical weathering, biogenic/non-biogenic precipitation, biological uptake, adsorption, etc.). The equilibrium silicon isotope fractionation during the mantle-core differentiation resulted in the observed heavy isotope composition of the bulk silicate Earth (BSE). The equilibrium fractionation of silicon isotopes among silicate minerals are sensitive to the Si–O bond length, Si coordination numbers (CN), the polymerization degrees of silicate unites, and the electronegativity of cations in minerals. The preferential enrichment of different speciation of dissoluble Si (DSi) (e.g., silicic acid H4SiO40 (H4) and H3SiO4− (H3)) in silica precipitation and diagenesis, and chemical weathering, lead to predominately positive Si isotope signatures in continental surface waters, in which the dynamic fractionation of silicon isotope could be well described by the Rayleigh fractionation model. The role of complexation in biological fractionations of silicon isotopes is more complicated, likely involving several enzymatic processes and active transport proteins. The integrated understanding greatly strengthens the potential of δ30Si proxy for reconstructing the paleo terrestrial and oceanic environments, and exploring the meteorites and planetary core formation, as well as constraining ore deposits and hydrothermal fluid activity.
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O’Connor, Liam, Dawid Szymanowski, Michael P. Eddy, Kyle M. Samperton, and Blair Schoene. "A red bole zircon record of cryptic silicic volcanism in the Deccan Traps, India." Geology 50, no. 4 (January 5, 2022): 460–64. http://dx.doi.org/10.1130/g49613.1.
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Abstract Silicic magmas within large igneous provinces (LIPs) are understudied relative to volumetrically dominant mafic magmas despite their prevalence and possible contribution to LIP-induced environmental degradation. In the 66 Ma Deccan LIP (India), evolved magmatism is documented, but its geographic distribution, duration, and significance remain poorly understood. Zircons deposited in weathered Deccan lava flow tops (“red boles”) offer a means of indirectly studying potentially widespread, silicic, explosive volcanism spanning the entire period of flood basalt eruptions. We explored this record through analysis of trace elements and Hf isotopes in zircon crystals previously dated by U–Pb geochronology. Our results show that zircon populations within individual red boles fingerprint distinct volcanic sources that likely developed in an intraplate setting on cratonic Indian lithosphere. However, our red bole zircon geochemical and isotopic characteristics do not match those from previously studied silicic magmatic centers, indicating that they must derive from yet undiscovered or understudied volcanic centers associated with the Deccan LIP.
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Kozlovskaia, Ol’ga N., Iuliia G. Shibetskaia, Nikolay A. Bezhin, and Ivan G. Tananaev. "Estimation of 226Ra and 228Ra Content Using Various Types of Sorbents and Their Distribution in the Surface Layer of the Black Sea." Materials 16, no. 5 (February 26, 2023): 1935. http://dx.doi.org/10.3390/ma16051935.
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Radium isotopes have traditionally been used as tracers of surface and underground fresh waters in land–ocean interactions. The concentration of these isotopes is most effective on sorbents containing mixed oxides of manganese. During the 116 RV Professor Vodyanitsky cruise (22 April–17 May 2021), a study about the possibility and efficiency of 226Ra and 228Ra recovery from seawater using various types of sorbents was conducted. The influence of seawater flow rate on the sorption of 226Ra and 228Ra isotopes was estimated. It was indicated that the Modix, DMM, PAN-MnO2, and CRM-Sr sorbents show the best sorption efficiency at a flow rate of 4–8 column volumes per minute. Additionally, the distribution of biogenic elements (dissolved inorganic phosphorus (DIP), silicic acid, and the sum of nitrates and nitrites), salinity, and 226Ra and 228Ra isotopes was studied in the surface layer of the Black Sea in April–May 2021. Correlation dependencies between the concentration of long-lived radium isotopes and salinity are defined for various areas of the Black Sea. Two processes control the dependence of radium isotope concentration on salinity: conservative mixing of riverine and marine end members and desorption of long-lived radium isotopes when river particulate matter meets saline seawater. Despite the high long-lived radium isotope concentration in freshwater in comparison with that in seawater, their content near the Caucasus shore is lower mainly because riverine waters meet with a great open seawater body with a low content of these radionuclides, and radium desorption processes take place in an offshore area. The 228Ra/226Ra ratio derived from our data displays freshwater inflow spreading over not only the coastal region, but also the deep-sea region. The lowered concentration of the main biogenic elements corresponds to high-temperature fields because of their intensive uptake by phytoplankton. Therefore, nutrients coupled with long-lived radium isotopes trace the hydrological and biogeochemical peculiarities of the studied region.
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Wiebe, R. A. "Mafic-silicic layered intrusions: the role of basaltic injections on magmatic processes and the evolution of silicic magma chambers." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 87, no. 1-2 (1996): 233–42. http://dx.doi.org/10.1017/s0263593300006647.
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ABSTRACT:Plutonic complexes with interlayered mafic and silicic rocks commonly contain layers (1–50 m thick) with a chilled gabbroic base that grades upwards to dioritic or silicic cumulates. Each chilled base records the infusion of new basaltic magma into the chamber. Some layers preserve a record of double-diffusive convection with hotter, denser mafic magma beneath silicic magma. Processes of hybridisation include mechanical mixing of crystals and selective exchange of H2O, alkalis and isotopes. These effects are convected away from the boundary into the interiors of both magmas. Fractional crystallisation aad replenishment of the mafic magma can also generate intermediate magma layers highly enriched in incompatible elements.Basaltic infusions into silicic magma chambers can significantly affect the thermal and chemical character of resident granitic magmas in shallow level chambers. In one Maine pluton, they converted resident I-type granitic magma into A-type granite and, in another, they produced a low-K (trondhjemitic) magma layer beneath normal granitic magma. If comparable interactions occur at deeper crustal levels, selective thermal, chemical and isotopic exchange should probably be even more effective. Because the mafic magmas crystallise first and relatively rapidly, silicic magmas that rise away from deep composite chambers may show little direct evidence (e.g. enclaves) of their prior involvement with mafic magma.
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Hendry, K. R., G. E. A. Swann, M. J. Leng, H. J. Sloane, C. Goodwin, J. Berman, and M. Maldonado. "Technical Note: Silica stable isotopes and silicification in a carnivorous sponge <i>Asbestopluma</i> sp." Biogeosciences 12, no. 11 (June 5, 2015): 3489–98. http://dx.doi.org/10.5194/bg-12-3489-2015.
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Abstract. The stable isotope composition of benthic sponge spicule silica is a potential source of palaeoceanographic information about past deep seawater chemistry. The silicon isotope composition of spicules has been shown to relate to the silicic acid concentration of ambient water, although existing calibrations do exhibit a degree of scatter in the relationship. Less is known about how the oxygen isotope composition of sponge spicule silica relates to environmental conditions during growth. Here, we investigate the vital effects on silica, silicon and oxygen isotope composition in a carnivorous sponge, Asbestopluma sp., from the Southern Ocean. We find significant variations in silicon and oxygen isotopic composition within the specimen that are related to unusual spicule silicification. The largest variation in both isotope systems was associated with the differential distribution of an unconventional, hypersilicified spicule type (desma) along the sponge body. The absence an internal canal in the desmas suggests an unconventional silicification pattern leading to an unusually heavy isotope signature. Additional internal variability derives from a systematic offset between the peripheral skeleton of the body having systematically a higher isotopic composition than the internal skeleton. A simplified silicon isotope fractionation model, in which desmas were excluded, suggests that the lack of a system for seawater pumping in carnivorous sponges favours a low replenishment of dissolved silicon within the internal tissues, causing kinetic fractionation during silicification that impacts the isotope signature of the internal skeleton. Analysis of multiple spicules should be carried out to "average out" any artefacts in order to produce more robust downcore measurements.
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Cassarino, Lucie, Christopher D. Coath, Joana R. Xavier, and Katharine R. Hendry. "Silicon isotopes of deep sea sponges: new insights into biomineralisation and skeletal structure." Biogeosciences 15, no. 22 (November 21, 2018): 6959–77. http://dx.doi.org/10.5194/bg-15-6959-2018.
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Abstract. The silicon isotopic composition (δ30Si) of deep sea sponges' skeletal element – spicules – reflects the silicic acid (DSi) concentration of their surrounding water and can be used as natural archives of bottom water nutrients. In order to reconstruct the past silica cycle robustly, it is essential to better constrain the mechanisms of biosilicification, which are not yet well understood. Here, we show that the apparent isotopic fractionation (δ30Si) during spicule formation in deep sea sponges from the equatorial Atlantic ranges from −6.74 ‰ to −1.50 ‰ in relatively low DSi concentrations (15 to 35 µM). The wide range in isotopic composition highlights the potential difference in silicification mechanism between the two major classes, Demospongiae and Hexactinellida. We find the anomalies in the isotopic fractionation correlate with skeletal morphology, whereby fused framework structures, characterised by secondary silicification, exhibit extremely light δ30Si signatures compared with previous studies. Our results provide insight into the processes involved during silica deposition and indicate that reliable reconstructions of past DSi can only be obtained using silicon isotope ratios derived from sponges with certain spicule types.
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Ondrejka, Martin, Xian-Hua Li, Rastislav Vojtko, Marian Putis, Pavel Uher, and Tomas Sobocký. "Permian A-type rhyolites of the Muráň Nappe, Inner Western Carpathians, Slovakia: in-situ zircon U–Pb SIMS ages and tectonic setting." Geologica Carpathica 69, no. 2 (April 1, 2018): 187–98. http://dx.doi.org/10.1515/geoca-2018-0011.
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AbstractThree representative A-type rhyolitic rock samples from the Muráň Nappe of the inferred Silicic Unit of the Inner Western Carpathians (Slovakia) were dated using the high-precision SIMS U–Pb isotope technique on zircons. The geochronological data presented in this paper is the first in-situ isotopic dating of these volcanic rocks. Oscillatory zoned zircon crystals mostly revealed concordant Permian (Guadalupian) ages: 266.6 ± 2.4 Ma in Tisovec-Rejkovo (TIS-1), 263.3 ± 1.9 Ma in Telgárt-Gregová Hill (TEL-1) and 269.5 ± 1.8 Ma in Veľká Stožka-Dudlavka (SD-2) rhyolites. The results indicate that the formation of A-type rhyolites and their plutonic equivalents are connected to magmatic activity during the Permian extensional tectonics and most likely related to the Pangea supercontinent break-up.
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Frick, Daniel A., Rainer Remus, Michael Sommer, Jürgen Augustin, Danuta Kaczorek, and Friedhelm von Blanckenburg. "Silicon uptake and isotope fractionation dynamics by crop species." Biogeosciences 17, no. 24 (December 22, 2020): 6475–90. http://dx.doi.org/10.5194/bg-17-6475-2020.
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Abstract. That silicon is an important element in global biogeochemical cycles is widely recognised. Recently, its relevance for global crop production has gained increasing attention in light of possible deficits in plant-available Si in soil. Silicon is beneficial for plant growth and is taken up in considerable amounts by crops like rice or wheat. However, plants differ in the way they take up silicic acid from soil solution, with some species rejecting silicic acid while others actively incorporate it. Yet because the processes governing Si uptake and regulation are not fully understood, these classifications are subject to intense debate. To gain a new perspective on the processes involved, we investigated the dependence of silicon stable isotope fractionation on silicon uptake strategy, transpiration, water use, and Si transfer efficiency. Crop plants with rejective (tomato, Solanum lycopersicum, and mustard, Sinapis alba) and active (spring wheat, Triticum aestivum) Si uptake were hydroponically grown for 6 weeks. Using inductively coupled plasma mass spectrometry, the silicon concentration and isotopic composition of the nutrient solution, the roots, and the shoots were determined. We found that measured Si uptake does not correlate with the amount of transpired water and is thus distinct from Si incorporation expected for unspecific passive uptake. We interpret this lack of correlation to indicate a highly selective Si uptake mechanism. All three species preferentially incorporated light 28Si, with a fractionation factor 1000×ln (α) of −0.33 ‰ (tomato), −0.55 ‰ (mustard), and −0.43 ‰ (wheat) between growth medium and bulk plant. Thus, even though the rates of active and passive Si root uptake differ, the physico-chemical processes governing Si uptake and stable isotope fractionation do not. We suggest that isotope fractionation during root uptake is governed by a diffusion process. In contrast, the transport of silicic acid from the roots to the shoots depends on the amount of silicon previously precipitated in the roots and the presence of active transporters in the root endodermis, facilitating Si transport into the shoots. Plants with significant biogenic silica precipitation in roots (mustard and wheat) preferentially transport silicon depleted in 28Si into their shoots. If biogenic silica is not precipitated in the roots, Si transport is dominated by a diffusion process, and hence light silicon 28Si is preferentially transported into the tomato shoots. This stable Si isotope fingerprinting of the processes that transfer biogenic silica between the roots and shoots has the potential to track Si availability and recycling in soils and to provide a monitor for efficient use of plant-available Si in agricultural production.
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Leat, P. T., R. N. Thompson, M. A. Morrison, G. L. Hendry, and A. P. Dickin. "Silicic Magmas Derived by Fractional Crystallization from Miocene Minette, Elkhead Mountains, Colorado." Mineralogical Magazine 52, no. 368 (December 1988): 577–85. http://dx.doi.org/10.1180/minmag.1988.052.368.03.
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AbstractThe rock association of minette with silicic lavas and intrusions (granites, syenites, dacites) is a common geologic feature in both collisional and extensional tectonic settings. Considerable doubt exists as to whether a genetic link exists between these mafic and silicic rocks. We describe a Miocene sill from NW Colorado which is a clear example of a mixed magma consisting of originally-liquid inclusions of minette in a silicic trachydacite host. Chemical and Sr, Nd and Pb isotopic data are consistent with derivation of the silicic host magma of the sill dominantly by fractional crystallization of the minette magma. Correlations between the elemental compositions of the rock types and their Sr and Nd isotopic ratios imply minor assimilation of continental crust with relatively low values of both 87Sr/86Sr and 143Nd/144Nd, concomitantly with fractional crystallization. The parental minette magma was probably derived by partial melting of subcontinental lithospheric mantle. While the sill was emplaced in a rift-like tectonic setting, the chemical and isotopic composition of the lithosphere-derived minette magmas (and hence the silicic fractionates) was largely independent of this setting, but dependent upon the composition and age of the lithospheric mantle and crust.
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Liu, Lei, Wenjiao Xiao, Xijun Liu, Zengxia Zhao, and Yabo Wang. "Early Triassic S-Type Granitoids in the Qinzhou Bay Area, South China: Petrogenesis and Tectonic Implications." Minerals 14, no. 1 (December 24, 2023): 22. http://dx.doi.org/10.3390/min14010022.
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The influence of the paleo-Tethys or paleo-Pacific oceanic plate subduction on Early Triassic South China has long been debated. We have studied the zircon U-Th-Hf isotopes, trace elements, and whole-rock geochemistry of Early Triassic peraluminous granitoids in the Qinzhou Bay area, South China Block. LA–ICP–MS zircon U–Pb dating has revealed the Jiuzhou granodiorites and Dasi-Taima granite porphyries formed between 248.32 ± 0.98 and 246.6 ± 1.1 Ma. These rocks are characterized by high K2O and Al2O3, and low MgO, CaO, and P2O5 contents with A/CNK = 1.06–1.17, showing high-K calc-alkaline S-type affinities. The Early Triassic intrusive rocks and adjacent silicic volcanic rocks in the Qinzhou Bay area were found to be comagmatic and derived from a common magma pool, detached in an undifferentiated melt instead of indicating remarkable crystal—melt separation. Although the analyzed granitoids have highly enriched zircon Hf isotopic compositions (εHf(t) = −23.9 to −7.8), they cannot originate solely from metasedimentary protoliths. Source discrimination indicators have revealed enriched lithospheric mantle-derived magma was also an endmember component of the S-type silicic magma, which provided a heat source for the crustal anatectic melting as well. We inferred the studied Early Triassic granitoids formed under the paleo-Tethys tectonic regime before the collision of South China and Indochina blocks, as the oceanic plate subduction would have created an extensional setting which further caused the mantle-derived upwelling and volcanic eruption.
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Bragin, I. V., G. A. Chelnokov, and N. A. Kharitonova. "NEW ISOTOPE-GEOCHEMICAL DATA ON THERMAL WATERS OF THE TALSKOE DEPOSIT (MAGADAN OBLAST)." Tikhookeanskaya Geologiya 40, no. 6 (2021): 111–19. http://dx.doi.org/10.30911/0207-4028-2021-40-6-111-119.
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In this paper, we summarize new data on the chemical and isotopic composition of thermal wa-ters of the Talskoye deposit in the Magadan Oblast. We were the first to obtain the data on the content of stable oxygen (δ18O) and hydrogen (δD) isotopes in thermal and background waters, as well as oxygen (δ18O) and carbon in bicarbonate ion (δ13C), even though this is the largest ex-ploited deposit of low-mineralized alkaline nitric thermal waters in the region. The thermal water is fresh (M = 980 mg/l), alkaline (pH = 8.9), hydrocarbonate-chloride-sulphate sodium with a high content of fluorine (up to 17 mg/l) and silicic acid (up to 152 mg/l). The deposit is fed by atmospheric precipitation; we did not find traces of melting underground ice supply. A sequential scheme for calculating the temperature of a deep reservoir was applied, which allowed the temperature of water formation to be constrained at 108 °C suggesting an input of fluids rich in potassium and sulfate ion.
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Debyser, Margot C. F., Laetitia Pichevin, Robyn E. Tuerena, Paul A. Dodd, Antonia Doncila, and Raja S. Ganeshram. "Tracing the role of Arctic shelf processes in Si and N cycling and export through the Fram Strait: insights from combined silicon and nitrate isotopes." Biogeosciences 19, no. 23 (December 6, 2022): 5499–520. http://dx.doi.org/10.5194/bg-19-5499-2022.
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Abstract. Nutrient cycles in the Arctic Ocean are being altered by changing hydrography, increasing riverine inputs, glacial melt and sea-ice loss due to climate change. In this study, combined isotopic measurements of dissolved nitrate (δ15N-NO3 and δ18O-NO3) and silicic acid (δ30Si(OH)4) are used to understand the pathways that major nutrients follow through the Arctic Ocean. Atlantic waters were found to be isotopically lighter (δ30Si(OH)4=+ 1.74 ‰) than their polar counterpart (δ30Si(OH)4=+ 1.85 ‰) owing to partial biological utilisation of dissolved Si (DSi) within the Arctic Ocean. Coupled partial benthic denitrification and nitrification on Eurasian Arctic shelves lead to the enrichment of δ15N-NO3 and lighter δ18O-NO3 in the polar surface waters (δ15N-NO3= 5.44 ‰, δ18O-NO3= 1.22 ‰) relative to Atlantic waters (δ15N-NO3= 5.18 ‰, δ18O-NO3= 2.33 ‰). Using a pan-Arctic DSi isotope dataset, we find that the input of isotopically light δ30Si(OH)4 by Arctic rivers and the subsequent partial biological uptake and biogenic Si burial on Eurasian shelves are the key processes that generate the enriched isotopic signatures of DSi exported through Fram Strait. A similar analysis of δ15N-NO3 highlights the role of N-limitation due to denitrification losses on Arctic shelves in generating the excess dissolved silicon exported through Fram Strait. We estimate that around 40 % of DSi exported in polar surface waters through Fram Strait is of riverine origin. As the Arctic Ocean is broadly N-limited and riverine sources of DSi are increasing faster than nitrogen inputs, a larger silicic acid export through the Fram Strait is expected in the future. Arctic riverine inputs therefore have the potential to modify the North Atlantic DSi budget and are expected to become more important than variable Pacific and glacial DSi sources over the coming decades.
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Guo, Xianzheng, Xinbiao Lü, Qunzi Jia, Jinchao Li, and Huilei Kong. "Fluid Inclusions and S–Pb Isotopes of the Reshui Porphyry Mo Deposit in East Kunlun, Qinghai Province, China." Minerals 9, no. 9 (September 11, 2019): 547. http://dx.doi.org/10.3390/min9090547.
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The Reshui porphyry Mo deposit is located in the East Kunlun orogenic belt (EKOB). Molybdenum mineralization is distributed in monzogranite and porphyritic monzogranite rocks, mainly presenting as various types of hydrothermal veinlets in altered wall rocks, and the orebodies are controlled by three groups of fractures. In this paper, we present the results of fluid-inclusion and isotopic (S and Pb) investigations of the Reshui Mo deposit. The ore-forming process of the deposit can be divided into three stages: an early disseminated molybdenite stage (stage 1), a middle quartz–molybdenite stage (stage 2) and a late quartz–polymetallic sulfide stage (stage 3). The alteration was mainly potassic and silicic in stage 1, silicic in stage 2, and sericitic and silicic in stage 3. Five types of fluid inclusions (FIs) can be distinguished in quartz phenocrysts and quartz veins, namely W, PL (pure liquid inclusions), PV (pure gas inclusions), C (CO2 three-phase inclusions), and S (daughter mineral-bearing inclusions). The homogenization temperatures of fluid inclusions belonging to stages 1 to 3 are 282.3–378 °C, 238.7–312.6 °C and 198.3–228 °C, respectively. The fluid salinities at stages 1 to 3 are 4.65–8.14% NaCl eq., 4.34–42.64% NaCl eq., and 3.55–4.65% NaCl eq., respectively. The fluids of this deposit were generally moderate–high temperature and moderate–low salinity and belong to the H2O–NaCl–CO2 ± CH4 system. The temperature and pressure changed considerably between stage 2 (high–medium-temperature) and stage 3 (low-temperature). The evidence for ore-forming fluids containing different types of coexisting inclusions in stage 2 and a decrease in the fluid temperature from stage 2 to stage 3 indicate that fluid boiling and fluid mixing were the main mechanisms of ore precipitation. The sulfide 34SV-CDT values range from 4.90‰ to 5.80‰, which is characteristic of magmatic sulfur. The 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb values of the ore minerals are 18.210–18.786, 15.589–15.723, and 38.298–39.126, respectively. These lead isotopic compositions suggest that the ores were mainly sourced from crustally derived magmas, with minor input from the mantle. The fluid inclusions and S–Pb isotopes provide important information on the genesis of the Reshui porphyry Mo deposit and indicate that the Triassic has high metallogenic porphyry potential in the EKOB.
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Grasse, Patricia, Mark A. Brzezinski, Damien Cardinal, Gregory F. de Souza, Per Andersson, Ivia Closset, Zhimian Cao, et al. "GEOTRACES inter-calibration of the stable silicon isotope composition of dissolved silicic acid in seawater." Journal of Analytical Atomic Spectrometry 32, no. 3 (2017): 562–78. http://dx.doi.org/10.1039/c6ja00302h.
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The first inter-calibration study of the stable silicon isotope composition of dissolved silicic acid in seawater, δ30Si(OH)4, is presented as a contribution to the international GEOTRACES program.
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Clemens, J. D., P. A. Helps, and G. Stevens. "Chemical structure in granitic magmas – a signal from the source?" Earth and Environmental Science Transactions of the Royal Society of Edinburgh 100, no. 1-2 (March 2009): 159–72. http://dx.doi.org/10.1017/s1755691009016053.
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ABSTRACTThough typically exhibiting considerable scatter, geochemical variations in granitic plutons and silicic volcanic deposits are commonly modelled as products of differentiation of originally homogeneous magmas. However, many silicic igneous bodies, particularly those classified as S-types, are internally heterogeneous in their mineralogy, geochemistry and isotope ratios, on scales from hundreds of metres down to one metre or less. The preservation of these heterogeneities supports recent models for the construction of granitic magma bodies through incremental additions of numerous batches (pulses) of magma derived from contrasting sources. Such pulses result from the sequential nature of the melting reactions and the commonly layered structure of crustal magma sources. Internal differentiation of these batches occurs, but not generally on the scales of whole magma chambers. Rather than being created through differentiation or hybridisation processes, at or near emplacement levels, much of the variation within such bodies (e.g. trace-element or Mg# variation with SiO2 or isotope ratios) is a primary or near-source feature. At emplacement levels, the relatively high magma viscosities and slow diffusion rates of many chemical components in silicic melts probably inhibit processes that would lead to homogenisation. This permits at least partial preservation of the primary heterogeneities.
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Fripiat, F., A. J. Cavagna, F. Dehairs, A. de Brauwere, L. André, and D. Cardinal. "Processes controlling the Si-isotopic composition in the Southern Ocean and application for paleoceanography." Biogeosciences Discussions 8, no. 5 (October 17, 2011): 10155–85. http://dx.doi.org/10.5194/bgd-8-10155-2011.
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Abstract. Southern Ocean biogeochemical processes have an impact on global marine primary production and global elemental cycling, e.g. by likely controlling glacial-interglacial pCO2 variation. The natural silicon isotopic composition (δ30Si) of sedimentary biogenic silica has been used to reconstruct past Si-consumption:supply ratio in the surface waters. We present a new dataset in the Southern Ocean which includes for the first time summer δ30Si signatures of suspended biogenic silica (i) for the whole water column at three stations and (ii) in the mixed layer at seven stations from the sub-tropical zone up to the Weddell Gyre. In general, the biogenic silica isotopic composition at depth reflected a mixed layer origin and seemed not affected by any diagenetic effect in the water column, even if in the northern part of the Weddell Gyre an effect of biogenic silica dissolution cannot be ruled out. We develop a mechanistic understanding of the processes involved in the modern Si-isotopic balance, by implementing a mixed layer model. We observe that the accumulated biogenic silica (sensu Rayleigh) should satisfactorily describe the δ30Si composition of biogenic silica exported out of the mixed layer, within the limit of the current analytical precision on the δ30Si. The failures of previous models (Rayleigh and steady state) become apparent especially at the end of the productive period in the mixed layer, when biogenic silica production is low. This results from: (1) a higher biogenic silica dissolution:production ratio imposing a lower net fractionation factor and (2) a higher Si-supply:Si-uptake ratio supplying light Si-isotopes into the mixed layer. The latter effect is especially expressed when the summer mixed layer becomes strongly Si-depleted together with a large vertical silicic acid gradient.
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Ellis, B. S., J. Neukampf, O. Bachmann, C. Harris, F. Forni, T. Magna, O. Laurent, and P. Ulmer. "Biotite as a recorder of an exsolved Li-rich volatile phase in upper-crustal silicic magma reservoirs." Geology 50, no. 4 (February 3, 2022): 481–85. http://dx.doi.org/10.1130/g49484.1.
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Abstract The magmatic-hydrothermal transition is key in controlling the fate of many economically important elements due to the change in partitioning when melt and magmatic fluid coexist. Despite its increasing economic importance, the behavior of lithium (Li) in such environments remains poorly known. We illustrate how compositionally unusual biotites from the rhyolitic Bishop Tuff (California, USA) and Kos Plateau Tuff (Greece) may contain a magmatic volatile phase trapped between layers of biotite crystals. Despite originating in pristine deposits and showing the expected X-ray diffraction spectra, these biotites return low (<95 wt%) analytical totals via electron microprobe (EMP) consistent with the presence of considerable amounts of light elements (non-measurable by EMP). Lithium contents and isotope ratios in these biotites are remarkable, with abundances reaching >2300 ppm, exceptionally light Li isotopic compositions (δ7Li as low as –27.6‰), and large isotopic fractionation between biotite and corresponding bulk samples (Δ7Libt–bulk as low as –36.5‰). Other mineral phases, groundmass glass, and melt inclusions from the same units do not support an extremely Li-rich melt prior to eruption. Biotites from phonolitic systems (Tenerife [Canary Islands] and Campi Flegrei [Italy]) do not show such extreme compositional differences, with biotite and melt showing roughly equivalent Li contents, underscored by significantly reduced Δ7Libt–bulk to a maximum of –10.9‰. We ascribe the difference in behavior to the near-liquidus appearance of biotite in alkaline magmatic suites, before widespread exsolution of a magmatic volatile phase in the magma reservoir, while in rhyolitic suites, biotite crystallizes at low temperature, trapping the coexisting exsolved fluid phase in the reservoir.
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LEAT, P. T., R. D. LARTER, and I. L. MILLAR. "Silicic magmas of Protector Shoal, South Sandwich arc: indicators of generation of primitive continental crust in an island arc." Geological Magazine 144, no. 1 (October 27, 2006): 179–90. http://dx.doi.org/10.1017/s0016756806002925.
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Protector Shoal, the northernmost and most silicic volcano of the South Sandwich arc, erupted dacite–rhyolite pumice in 1962. We report geochemical data for a new suite of samples dredged from the volcano. Geochemically, the dredge and 1962 samples form four distinct magma groups that cannot have been related to each other, and are unlikely to have been related to a single basaltic parent, by fractional crystallization. Instead, the silicic rocks are more likely to have been generated by partial melting of basaltic lower crust within the arc. Trace element and Sr–Nd isotope data indicate that the silicic volcanics have compositions that are more similar to the volcanic arc than the oceanic basement formed at a back-arc spreading centre, and volcanic arc basalts are considered to be the likely source for the silicic magmas. The South Sandwich Islands are one of several intra-oceanic arcs (Tonga–Kermadec, Izu–Bonin) that have: (1) significant amounts of compositionally bimodal mafic–silicic volcanic products and (2) 6.0–6.5 km s−1P-wave velocity layers in their mid-crusts that have been imaged by wide-angle seismic surveys and interpreted as intermediate-silicic plutons. Geochemical and volume considerations indicate that both the silicic volcanics and plutonic layers were generated by partial melting of basaltic arc crust, representing an early stage in the fractionation of oceanic basalt to form continental crust.
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Johnson, Clark M. "Isotopic zonations in silicic magma chambers." Geology 17, no. 12 (1989): 1136. http://dx.doi.org/10.1130/0091-7613(1989)017<1136:izismc>2.3.co;2.
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MARTIN, E., and O. SIGMARSSON. "Trondhjemitic and granitic melts formed by fractional crystallization of an olivine tholeiite from Reykjanes Peninsula, Iceland." Geological Magazine 142, no. 6 (October 10, 2005): 651–58. http://dx.doi.org/10.1017/s0016756805001160.
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A pair of samples, from host lava and an included segregation vein from the Reykjanes Peninsula, Iceland, allows the assessment of a complete fractional crystallization of an olivine tholeiite at low pressure. The final product consists of silicic glasses with bimodal composition: trondhjemitic and more rarely granitic. Compilation of data on major element compositions of Icelandic silicic rocks reveals a clear difference from those of the segregation glasses. Fractional crystallization of basalts at low pressure is therefore not the most likely mechanism for the origin of silicic magmas in Iceland. Similar conclusions have been reached in studies on O- and Th-isotope compositions. On the other hand, the trondhjemitic compositions of the glasses in the segregation vein from Reykjanes Peninsula suggest that fractional crystallization of olivine tholeiites could have played a significant role during the formation of the very early continental crust.
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Cucciniello, Ciro, Ashwini Kumar Choudhary, Kanchan Pande, and Hetu Sheth. "Mineralogy, geochemistry and 40Ar–39Ar geochronology of the Barda and Alech complexes, Saurashtra, northwestern Deccan Traps: early silicic magmas derived by flood basalt fractionation." Geological Magazine 156, no. 10 (January 22, 2019): 1668–90. http://dx.doi.org/10.1017/s0016756818000924.
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AbstractMost continental flood basalt (CFB) provinces of the world contain silicic (granitic and rhyolitic) rocks, which are of significant petrogenetic interest. These rocks can form by advanced fractional crystallization of basaltic magmas, crustal assimilation with fractional crystallization, partial melting of hydrothermally altered basaltic lava flows or intrusions, anatexis of old basement crust, or hybridization between basaltic and crustal melts. In the Deccan Traps CFB province of India, the Barda and Alech Hills, dominated by granophyre and rhyolite, respectively, form the largest silicic complexes. We present petrographic, mineral chemical, and whole-rock geochemical (major and trace element and Sr–Nd isotopic) data on rocks of both complexes, along with 40Ar–39Ar ages of 69.5–68.5 Ma on three Barda granophyres. Whereas silicic magmatism in the Deccan Traps typically postdates flood basalt eruptions, the Barda granophyre intrusions (and the Deccan basalt flows they intrude) significantly pre-date (by 3–4 My) the intense 66–65 Ma flood basalt phase forming the bulk of the province. A tholeiitic dyke cutting the Barda granophyres contains quartzite xenoliths, the first being reported from Saurashtra and probably representing Precambrian basement crust. However, geochemical–isotopic data show little involvement of ancient basement crust in the genesis of the Barda–Alech silicic rocks. We conclude that these rocks formed by advanced (70–75 %), nearly-closed system fractional crystallization of basaltic magmas in crustal magma chambers. The sheer size of each complex (tens of kilometres in diameter) indicates a very large mafic magma chamber, and a wide, pronounced, circular-shaped gravity high and magnetic anomaly mapped over these complexes is arguably the geophysical signature of this solidified magma chamber. The Barda and Alech complexes are important for understanding CFB-associated silicic magmatism, and anorogenic, intraplate silicic magmatism in general.
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Fripiat, F., A. J. Cavagna, F. Dehairs, A. de Brauwere, L. André, and D. Cardinal. "Processes controlling the Si-isotopic composition in the Southern Ocean and application for paleoceanography." Biogeosciences 9, no. 7 (July 6, 2012): 2443–57. http://dx.doi.org/10.5194/bg-9-2443-2012.
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Abstract. Southern Ocean biogeochemical processes have an impact on global marine primary production and global elemental cycling, e.g. by likely controlling glacial-interglacial pCO2 variation. In this context, the natural silicon isotopic composition (δ30Si) of sedimentary biogenic silica has been used to reconstruct past Si-consumption:supply ratios in the surface waters. We present a new dataset in the Southern Ocean from a IPY-GEOTRACES transect (Bonus-GoodHope) which includes for the first time summer δ30Si signatures of suspended biogenic silica (i) for the whole water column at three stations and (ii) in the mixed layer at seven stations from the subtropical zone up to the Weddell Gyre. In general, the isotopic composition of biogenic opal exported to depth was comparable to the opal leaving the mixed layer and did not seem to be affected by any diagenetic processes during settling, even if an effect of biogenic silica dissolution cannot be ruled out in the northern part of the Weddell Gyre. We develop a mechanistic understanding of the processes involved in the modern Si-isotopic balance, by implementing a mixed layer model. We observe that the accumulated biogenic silica (sensu Rayleigh distillation) should satisfactorily describe the δ30Si composition of biogenic silica exported out of the mixed layer, within the limit of the current analytical precision on the δ30Si. The failures of previous models (Rayleigh and steady state) become apparent especially at the end of the productive period in the mixed layer, when biogenic silica production and export are low. This results from (1) a higher biogenic silica dissolution:production ratio imposing a lower net fractionation factor and (2) a higher Si-supply:Si-uptake ratio supplying light Si-isotopes into the mixed layer. The latter effect is especially expressed when the summer mixed layer becomes strongly Si-depleted, together with a large vertical silicic acid gradient, e.g. in the Polar Front Zone and at the Polar Front.
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Fripiat, F., A. J. Cavagna, F. Dehairs, S. Speich, L. André, and D. Cardinal. "Silicon pool dynamics and biogenic silica export in the Southern Ocean, inferred from Si-isotopes." Ocean Science Discussions 8, no. 2 (March 30, 2011): 639–74. http://dx.doi.org/10.5194/osd-8-639-2011.
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Abstract. Water column silicon isotopic signatures (δ30Si) of silicic acid (Si(OH)4) in the Southern Ocean were measured along a meridional transect from South Africa (Subtropical Zone) down to 57° S (northern Weddell Gyre). These data are the first reported for a summer transect across the whole Antarctic Circumpolar Current (ACC). δ30Si variations are large in the upper 1000 m, reflecting the effect of the silica pump superimposed upon meridional transfer across the ACC: the transport of Antarctic surface waters northward by a net Ekman drift and their convergence and mixing with warmer upper-ocean Si-depleted waters to the north. Using Si isotopic signatures, we determined different mixing interfaces between ACC water masses: the Antarctic Surface Water (AASW), the Antarctic Intermediate Water (AAIW), and the thermoclines in the low latitude areas. The residual silicic acid concentrations of end-members control the δ30Si alteration of the mixing products. With the exception of AASW, all mixing interfaces have a highly Si-depleted mixed layer end-member. These processes deplete the silicic acid AASW concentration across the different interfaces northward without significantly changing the AASW δ30Si. By comparing our new results with a previous study in the Australian sector we show that during the circumpolar transport of the ACC eastward, there is a slight but significant Si-isotopic lightening of the silicic acid pools from the Atlantic to the Australian sectors. This results either from the dissolution of biogenic silica in the deeper layers and/or from an isopycnal mixing with the deep water masses in the different oceanic basins: North Atlantic Deep Water in the Atlantic, and Indian Ocean deep water in the Indo-Australian sector. This eastward lightening is further transmitted to the subsurface waters, representing mixing interfaces between the surface and deeper layers. Using the Si-isotopic constraint, we estimate for the Greenwich Meridian a net biogenic silica production which should be representative of the annual export, at 4.5 ± 1.1 and 1.5 ± 0.4 mol Si m−2 for the Antarctic Zone and Polar Front Zone, respectively, in agreement with previous estimations. The summertime Si-supply into the mixed layer via vertical mixing was also assessed at 1.5 ± 0.4 and 0.1 ± 0.5 mol Si m−2, respectively.
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Mustafaev, Agababa A., Igor F. Gertner, Richard E. Ernst, Pavel A. Serov, and Yurii V. Kolmakov. "The Paleozoic-Aged University Foidolite-Gabbro Pluton of the Northeastern Part of the Kuznetsk Alatau Ridge, Siberia: Geochemical Characterization, Geochronology, Petrography and Geophysical Indication of Potential High-Grade Nepheline Ore." Minerals 10, no. 12 (December 15, 2020): 1128. http://dx.doi.org/10.3390/min10121128.
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Geological, geochemical and ground magnetic techniques are used to characterize the University alkaline-gabbroid pluton and crosscutting N-S trending alkaline dikes, located northeast of the Kuznetsk Alatau ridge, Siberia. Trace element concentrations and isotopic compositions of the igneous units were determined by XRF, ICP-MS and isotope analysis. The Sm-Nd age of subalkaline (melanogabbro, leucogabbro 494–491 Ma) intrusive phases and crosscutting alkaline dikes (plagioclase ijolite, analcime syenite 392–389 Ma) suggests two stages of activity, likely representing separate events. The subalkaline and alkaline rocks are characterized by low silicic acidity (SiO2 = 41–49 wt %), wide variations in alkalinity (Na2O + K2O = 3–19 wt %; Na2O/K2O = 1.2–7.2 wt %), high alumina content (Al2O3 = 15–28 wt %) and low titanium content (TiO2 = 0.07–1.59 wt %). The new trace element data for subalkaline rocks (∑REE 69–280 ppm; La/Yb 3.7–10.2) of the University pluton and also the crosscutting younger (390 Ma) alkaline dikes (∑REE 10–1567 ppm; La/Yb 0.7–17.8 ppm) both reflect an intermediate position between oceanic island basalts (OIBs) and island arc basalts (IABs). The presence of a negative Nb–Ta anomaly and the relative enrichment in Rb, Ba, Sr, and U indicate a probable interaction of mantle plume material with the lithospheric mantle beneath previously formed accretion complexes of subduction zones. The isotopic signatures of strontium (εSr(T) +3.13–+28.31) and neodymium (εNd(T) +3.2–+8.7) demonstrate the evolution of parental magmas from a plume source from moderately depleted PREMA mantle, whose derivatives underwent selective crustal contamination.
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Sigmarsson, Olgeir, Christophe Hémond, Michel Condomines, Serge Fourcade, and Niels Oskarsson. "Origin of silicic magma in Iceland revealed by Th isotopes." Geology 19, no. 6 (1991): 621. http://dx.doi.org/10.1130/0091-7613(1991)019<0621:oosmii>2.3.co;2.
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Boyarskaya, R. V., A. M. Garayev, V. V. Nasedkin, and L. P. Nosik. "DISTRIBUTION OF OXYGEN ISOTOPES AND MINERAL FORMATION IN SILICIC VOLCANICS." International Geology Review 32, no. 4 (April 1990): 364–74. http://dx.doi.org/10.1080/00206819009465783.
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Gubanov, Nikolai, Dmitry Zedgenizov, Igor Sharygin, and Alexey Ragozin. "Origin and Evolution of High-Mg Carbonatitic and Low-Mg Carbonatitic to Silicic High-Density Fluids in Coated Diamonds from Udachnaya Kimberlite Pipe." Minerals 9, no. 12 (November 28, 2019): 734. http://dx.doi.org/10.3390/min9120734.
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Microinclusions of high-density fluids (HDFs) were studied in coated diamonds from the Udachnaya kimberlite pipe (Siberian craton, Russia). The presence of C-centers in the coats testifies to their formation shortly before kimberlite eruption, whereas the cores have much longer mantle residence in chemically different mantle substrates, i.e., peridotite-type (P-type) and eclogite-type (E-type). The carbon isotope composition indicates an isotopically homogeneous carbon source for coats and a heterogeneous source for cores. Microinclusions in the coats belong to two groups: high-Mg carbonatitic and low-Mg carbonatitic to silicic. A relationship was found between high-Mg carbonatitic HDFs and peridotitic host rocks and between low-Mg carbonatitic to silicic and eclogites. The composition of high-Mg carbonatitic HDFs with a “planed” trace-element pattern can evolve to low-Mg carbonatitic to silicic during percolation through different mantle rocks. The compositional variations of microinclusions in the coats reflect this evolution.
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Fripiat, F., A. J. Cavagna, F. Dehairs, S. Speich, L. André, and D. Cardinal. "Silicon pool dynamics and biogenic silica export in the Southern Ocean inferred from Si-isotopes." Ocean Science 7, no. 5 (September 6, 2011): 533–47. http://dx.doi.org/10.5194/os-7-533-2011.
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Abstract. Silicon isotopic signatures (δ30Si) of water column silicic acid (Si(OH)4) were measured in the Southern Ocean, along a meridional transect from South Africa (Subtropical Zone) down to 57° S (northern Weddell Gyre). This provides the first reported data of a summer transect across the whole Antarctic Circumpolar Current (ACC). δ30Si variations are large in the upper 1000 m, reflecting the effect of the silica pump superimposed upon meridional water transfer across the ACC: the transport of Antarctic surface waters northward by a net Ekman drift and their convergence and mixing with warmer upper-ocean Si-depleted waters to the north. Using Si isotopic signatures, we determine different mixing interfaces: the Antarctic Surface Water (AASW), the Antarctic Intermediate Water (AAIW), and thermoclines in the low latitude areas. The residual silicic acid concentrations of end-members control the δ30Si alteration of the mixing products and with the exception of AASW, all mixing interfaces have a highly Si-depleted mixed layer end-member. These processes deplete the silicic acid AASW concentration northward, across the different interfaces, without significantly changing the AASW δ30Si composition. By comparing our new results with a previous study in the Australian sector we show that during the circumpolar transport of the ACC eastward, the δ30Si composition of the silicic acid pools is getting slightly, but significantly lighter from the Atlantic to the Australian sectors. This results either from the dissolution of biogenic silica in the deeper layers and/or from an isopycnal mixing with the deep water masses in the different oceanic basins: North Atlantic Deep Water in the Atlantic, and Indian Ocean deep water in the Indo-Australian sector. This isotopic trend is further transmitted to the subsurface waters, representing mixing interfaces between the surface and deeper layers. Through the use of δ30Si constraints, net biogenic silica production (representative of annual export), at the Greenwich Meridian is estimated to be 5.2 &pm; 1.3 and 1.1 &pm; 0.3 mol Si m−2 for the Antarctic Zone and Polar Front Zone, respectively. This is in good agreement with previous estimations. Furthermore, summertime Si-supply into the mixed layer of both zones, via vertical mixing, is estimated to be 1.6 &pm; 0.4 and 0.1 &pm; 0.5 mol Si m−2, respectively.
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Rasmussen, E., E. R. Neumann, T. Andersen, B. Sundvoll, V. Fjerdingstad, and A. Stabel. "Petrogenetic Processes Associated with Intermediate and Silicic Magmatism in the Oslo Rift, South-East Norway." Mineralogical Magazine 52, no. 366 (June 1988): 293–307. http://dx.doi.org/10.1180/minmag.1988.052.366.01.
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AbstractThe Permian magmatic province of the Oslo rift, south-east Norway, includes large volumes of felsic and silicic rocks. Based on their geochemical character, these rocks may be divided into two main groups. The Larvik larvikites (monzonites) are highly enriched in large ion lithophile elements (LILE) (e.g. 10–32 ppm Th. 8–15 ppm Ta), and have an initial 87Sr/86Sr of 0.70391 ± 5. The syenites and granites have moderate to high concentrations of LILE (e.g. 7–88 ppm Th, 4–25 ppm Ta), and initial 87Sr/86Sr ratios between 0.705 and 0.707. The Larvik larvikites and extrusive equivalents (rhomb porphyry lavas) have similar initial Sr isotope ratios to uncontaminated basalts and gabbros in the rift, and are believed to have a mantle origin. The higher initial 87Sr/86Sr ratios in the silicic than in the felsic rocks reflect a crustal component representing the intermediate or low crust. After intrusion into the upper crust, the major and traceelement concentrations of the silicic magmas were modified through fractional crystallization dominated by removal of alkali feldspar, and transport of elements with a fluid phase. The silicic magmas appear not to have interacted significantly with the side rock at this stage.
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Hendry, Katharine, Oscar Romero, and Vanessa Pashley. "Nutrient utilization and diatom productivity changes in the low-latitude south-eastern Atlantic over the past 70 ka: response to Southern Ocean leakage." Climate of the Past 17, no. 2 (March 9, 2021): 603–14. http://dx.doi.org/10.5194/cp-17-603-2021.
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Abstract. Eastern boundary upwellings (EBUs) are some of the key loci of biogenic silica (opal) burial in the modern ocean, representing important productive coastal systems that extraordinarily contribute to marine organic carbon fixation. The Benguela upwelling system (BUS), in the low-latitude south-eastern Atlantic, is one of the major EBUs and is under the direct influence of nutrient-rich Southern Ocean waters. Quantification of past changes in diatom productivity through time, in response to late Quaternary climatic change, feeds into our understanding of the sensitivity of EBUs to future climatic perturbations. Existing sediment archives of silica cycling include opal burial fluxes, diatom assemblages, and opaline silicon isotopic variations (denoted by δ30Si). Burial fluxes and siliceous assemblages are limited to recording the remains reaching the sediment (i.e. export), and δ30Si variations are complicated by species-specific influences and seasonality. Here, we present the first combined δ30Si record of two large centric diatoms from the BUS, encompassing full glacial conditions to the Holocene. In addition to export, our new data allow us to reconstruct the utilization of dissolved Si in surface waters in an area with strong input from Southern Ocean waters. Our new archives show that there was enhanced upwelling of Southern Ocean Si-rich water accompanied by strong silicic acid utilization by coastal dwelling diatoms during Marine Isotope Stage 3 (MIS3; 60–40 ka). This pulse of strong silicic acid utilization was followed by a weakening of upwelling and coastal diatom Si utilization into MIS2, before an increase in pelagic diatom Si utilization across the deglaciation. We combine our findings with mass balance model experiments to show that changes in surface water silica cycling through time are a function of both upwelling intensity and utilization changes, illustrating the sensitivity of EBUs to climatic change on glacial–interglacial scales.
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Árnason, Knútur. "New Conceptual Model for the Magma-Hydrothermal-Tectonic System of Krafla, NE Iceland." Geosciences 10, no. 1 (January 19, 2020): 34. http://dx.doi.org/10.3390/geosciences10010034.
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The complexity of the Krafla volcano and its geothermal system(s) has puzzled geoscientists for decades. New and old geoscientific studies are reviewed in order to shed some light on this complexity. The geological structure and history of the volcano is more complex than hitherto believed. The visible 110 ka caldera hosts, now buried, an 80 ka inner caldera. Both calderas are bisected by an ESE-WNW transverse low-density structure. Resistivity surveys show that geothermal activity has mainly been within the inner caldera but cut through by the ESE-WNW structure. The complexity of the geothermal system in the main drill field can be understood by considering the tectonic history. Isotope composition of the thermal fluids strongly suggests at least three different geothermal systems. Silicic magma encountered in wells K-39 and IDDP-1 indicates a hitherto overlooked heat transport mechanism in evolved volcanos. Basaltic intrusions into subsided hydrothermally altered basalt melt the hydrated parts, producing a buoyant silicic melt which migrates upwards forming sills at shallow crustal levels which are heat sources for the geothermal system above. This can explain the bimodal behavior of evolved volcanos like Krafla and Askja, with occasional silicic, often phreatic, eruptions but purely basaltic in-between. When substantial amounts of silicic intrusions/magma have accumulated, major basalt intrusion(s) may “ignite” them causing a silicic eruption.
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Cermeño, Pedro, Paul G. Falkowski, Oscar E. Romero, Morgan F. Schaller, and Sergio M. Vallina. "Continental erosion and the Cenozoic rise of marine diatoms." Proceedings of the National Academy of Sciences 112, no. 14 (March 23, 2015): 4239–44. http://dx.doi.org/10.1073/pnas.1412883112.
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Marine diatoms are silica-precipitating microalgae that account for over half of organic carbon burial in marine sediments and thus they play a key role in the global carbon cycle. Their evolutionary expansion during the Cenozoic era (66 Ma to present) has been associated with a superior competitive ability for silicic acid relative to other siliceous plankton such as radiolarians, which evolved by reducing the weight of their silica test. Here we use a mathematical model in which diatoms and radiolarians compete for silicic acid to show that the observed reduction in the weight of radiolarian tests is insufficient to explain the rise of diatoms. Using the lithium isotope record of seawater as a proxy of silicate rock weathering and erosion, we calculate changes in the input flux of silicic acid to the oceans. Our results indicate that the long-term massive erosion of continental silicates was critical to the subsequent success of diatoms in marine ecosystems over the last 40 My and suggest an increase in the strength and efficiency of the oceanic biological pump over this period.
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Macdonald, R., R. S. J. Sparks, H. Sigurdsson, D. P. Mattey, D. W. McGarvie, and R. L. Smith. "The 1875 eruption of Askja volcano, Iceland: combined fractional crystallization and selective contamination in the generation of rhyolitic magma." Mineralogical Magazine 51, no. 360 (June 1987): 183–202. http://dx.doi.org/10.1180/minmag.1987.051.360.01.
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AbstractMajor and trace element and Sr, Nd and O isotopic data are presented for ferrobasalts, icelandites, rhyolites, mixed pumices and silicic xenoliths of the 1875 eruption of Askja. Trace element modelling and Sr and Nd data largely confirm previous major element calculations that fractional crystallization was dominant in the generation of the basalt-ferrobasalt-icelandite-rhyolite suite. Relative enrichment in Rb (and Th and U?), depletion in Cs, and low values of δ18O/16O, in the rhyolites are not explained by this mechanism alone. The silicic magmas were selectively contaminated by diffusion from partially molten granitic wall rocks, now found as xenoliths in the eruptive products, the process being particularly marked by lower δ18O and Cs/Rb ratios in the rhyolites than in the associated basalts. This is the first record of a combined fractional crystallization-selective contamination process in an Icelandic silicic complex.
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Andersson, U. B., L. A. Neymark, and K. Billström. "Petrogenesis of Mesoproterozoic (Subjotnian) rapakivi complexes of central Sweden: implications from U–Pb zircon ages, Nd, Sr and Pb isotopes." Transactions of the Royal Society of Edinburgh: Earth Sciences 92, no. 3 (September 2001): 201–28. http://dx.doi.org/10.1017/s0263593300000237.
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ABSTRACTU-Pb zircon geochronology of Mesoproterozoic (Subjotnian) rapakivi complexes in central Sweden yields: 1526 ± 3 Ma (Mullnäset), 1524 ± 3 Ma (Mårdsjö), 1520 ± 3 Ma (Nordsjö) and 1497 ± 6 Ma (Rödön). Together with complexes further S in Sweden, they constitute the westernmost, youngest (1·53−1·47 Ga) belt of rapakivi magmatism in the Fennoscandian shield.The low initial εNd values (−8·9 to −4·8) of all studied Subjotnian basic, intermediate and silicic rocks, require an input from an old (Archaean) low-radiogenic source component, as evidence for Palaeoproterozoic protoliths in the age range 2·5−2·1 Ga is lacking in this region. Crustal, early Svecofennian + Archaean (roughly 30−40%) sources are suggested for the Subjotnian A-type granites and syenites, where the granites derive from undepleted, granodioritic, and the syenites from monzodioritic (±depleted crustal) protoliths. The basic rocks originate from a depleted mantle acquiring the enriched Nd isotopic signatures during interaction with an Archaean lower crust (20−40%), largely depleted after rapakivi melt extraction. Pb isotope data from feldspars (207Pb/204Pb to 15·018−15·542) support the presence of Archaean components in the magmas.The results indicate that an Archaean basement is underlying relatively wide areas of Svecofennian formations in central Sweden. This old basement section was most likely rifted off the Archaean craton in the NE in Palaeoproterozoic times.
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Closset, Ivia, Damien Cardinal, Mathieu Rembauville, François Thil, and Stéphane Blain. "Unveiling the Si cycle using isotopes in an iron-fertilized zone of the Southern Ocean: from mixed-layer supply to export." Biogeosciences 13, no. 21 (November 3, 2016): 6049–66. http://dx.doi.org/10.5194/bg-13-6049-2016.
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Abstract. A massive diatom bloom forms annually in the surface waters of the naturally iron-fertilized Kerguelen Plateau (Southern Ocean). In this study, silicon isotopic signatures (δ30Si) of silicic acid (DSi) and suspended biogenic silica (BSi) were investigated through the whole water column with unprecedented spatial resolution, during the KEOPS-2 experiment (spring 2011). We used δ30Si measurements to track the sources of silicon that fuelled the bloom, and investigated the seasonal evolution of the Si biogeochemical cycle in the iron-fertilized area. We compared the results from stations with various degrees of iron enrichment and bloom conditions to an HNLC reference station. Dissolved and particulate δ30Si signatures were highly variable in the upper 500 m, reflecting the effect of intense silicon utilization in spring, while they were quite homogeneous in deeper waters. The Si isotopic and mass balance identified a unique Winter Water (WW) Si source for the iron-fertilized area that originated from southeast of the Kerguelen Plateau and spread northward. When the WW reached a retroflection of the Polar Front (PF), the δ30Si composition of the silicic acid pool became progressively heavier. This would result from sequential diapycnal and isopycnal mixings between the initial WW and ML water masses, highlighting the strong circulation of surface waters that defined this zone. When comparing the results from the two KEOPS expeditions, the relationship between DSi depletion, BSi production, and their isotopic composition appears decoupled in the iron-fertilized area. This seasonal decoupling could help to explain the low apparent fractionation factor observed in the ML at the end of summer. Taking into account these considerations, we refined the seasonal net BSi production in the ML of the iron-fertilized area to 3.0 ± 0.3 mol Si m−2 yr−1, which was exclusively sustained by surface water phytoplankton populations. These insights confirm that the isotopic composition of dissolved and particulate silicon is a promising tool to improve our understanding of the Si biogeochemical cycle since the isotopic and mass balance allows resolution of processes in the Si cycle (i.e. uptake, dissolution, mixing).
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Shellnutt, J. Gregory, and Jaroslav Dostal. "Derivation of the Early Carboniferous Wedgeport pluton by crystal fractionation of a mafic parental magma: a rare case of an A-type granite within the Meguma terrane (Nova Scotia, Canada)." Geological Magazine 157, no. 2 (August 13, 2019): 248–62. http://dx.doi.org/10.1017/s0016756819000694.
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AbstractThe Cambrian–Ordovician metasedimentary rocks of the Meguma terrane (Canadian Appalachians) were extensively intruded by silicic plutons during Middle Devonian to Early Carboniferous times. Syn-plutonic but volumetrically minor mafic-ultramafic intrusions were also emplaced. In most localities, the silicic plutons and mafic-ultramafic intrusions do not appear to be petrogenetically related and are likely derived from different sources. The Attwoods Brook gabbronorite of SW Nova Scotia yielded an in situ zircon weighted-mean 206Pb–238U age of 357.9 ± 3.3 Ma that is within the uncertainty of the age of the neighbouring Wedgeport pluton (357 ± 1 Ma). The Wedgeport pluton is a rare example of a mantle-derived, peraluminous A-type granite within the Meguma terrane. The similar ages and Nd isotopes of the Attwoods Brook gabbronorite (εNd(t) = +1.1 to +4.0) and Wedgeport pluton (εNd(t) = +2.1 to +3.3) suggest the two intrusions are petrogenetically related. Fractional crystallization modelling demonstrates that a parental magma similar to the Attwoods Brook gabbronorite can produce residual silicic liquids that resemble the granites of the Wedgeport pluton, indicating that they could be members of the same intrusive complex. The emplacement of the gabbronorite and Wedgeport pluton occurred during a period of tensional plate stress that was contemporaneous with rifting of the Maritimes Basin that produced the Fountain Lake continental flood basalts and A-type granites of the Cobequid Highlands within the Avalon terrane. It is possible that the Early Carboniferous rocks of SW Nova Scotia are related to the rifted-related magmatism within the Maritimes Basin.
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Weber, Thomas, Seth John, Alessandro Tagliabue, and Tim DeVries. "Biological uptake and reversible scavenging of zinc in the global ocean." Science 361, no. 6397 (July 5, 2018): 72–76. http://dx.doi.org/10.1126/science.aap8532.
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Zinc (Zn) is a key micronutrient for marine phytoplankton, with a global distribution that is similar to silicic acid. The processes that govern this relationship, despite the very different biological cycling of Zn and silica, remain poorly understood. Here, we use diagnostic and mechanistic models to show that only a combination of Southern Ocean biological uptake and reversible scavenging of Zn onto sinking particles can explain the observations. The distinction between organic and adsorbed Zn can also reconcile the vertical distribution and mass balance of Zn isotopes, which previously appeared at odds. This holistic understanding explains the Zn deficiencies observed throughout the low-latitude ocean and implies a greater sensitivity of the marine Zn cycle to climate-driven changes in organic matter cycling than previously recognized.
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Pichevin, Laetitia, Raja S. Ganeshram, Ben C. Reynolds, Fredrick Prahl, Thomas F. Pedersen, Robert Thunell, and Erin L. McClymont. "Silicic acid biogeochemistry in the Gulf of California: Insights from sedimentary Si isotopes." Paleoceanography 27, no. 2 (April 5, 2012): n/a. http://dx.doi.org/10.1029/2011pa002237.
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Preston, R. J., M. J. Hole, J. Still, and H. Patton. "The mineral chemistry and petrology of Tertiary pitchstones from Scotland." Transactions of the Royal Society of Edinburgh: Earth Sciences 89, no. 2 (1998): 95–111. http://dx.doi.org/10.1017/s0263593300007033.
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AbstractSub-silicic to silicic pitchstones are widespread throughout the British Tertiary Igneous Province (BTIP), with examples being found at all the major igneous centres. Both highly porphyritic and almost completely aphyric varieties occur, and take the form of sills, dykes and lava flows. Here we present previously unreported mineral chemistry data on phenocryst and microcrystallite populations from a number of pitchstones from throughout the BTIP. Phenocryst assemblages are completely anhydrous, comprising mixtures of plagioclase, sanidine, fayalite, orthopyroxene, pigeonite, ferroaugite, ferrohedenbergite and quartz. Microcrystallite assemblages are also diverse, consisting of sanidine, ferrohedenbergite, fayalite and, occasionally, almost pure end-member ferrosilite, as well as hydrous phases such as ferrohornblende and biotite. Textural and mineral chemistry observations support interpretations derived from whole-rock and residual glass major element analyses, together with whole-rock trace element and the available Sr-Nd-Pb isotope data, that the Tertiary pitchstones of Scotland are either the products of intimate mixing between a range of basaltic magmas with hydrous crustal melts, or were formed by the crustal contamination of basaltic magmas.
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DePaolo, Donald J., Frank V. Perry, and W. Scott Baldridge. "Crustal versus mantle sources of granitic magmas: a two-parameter model based on Nd isotopic studies." Earth and Environmental Science Transactions of the Royal Society of Edinburgh 83, no. 1-2 (1992): 439–46. http://dx.doi.org/10.1017/s0263593300008117.
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ABSTRACTTemporal and spatial variations in the Nd isotopic compositions of Tertiary caldera-forming rhyolite tuffs, and Cretaceous and Tertiary granites of the western U.S.A. are used as a basis for a model that accounts for the observed proportions of crustal versus mantle contributions to silicic magmas in terms of two parameters: the ambient crustal temperature and the rate of supply of basaltic magma from the mantle. The crustal contribution to silicic igneous rocks is measured in terms of the Neodymium Crustal Index (NCI). The relationships between crustal temperature, basalt supply and NCI are quantified using a model of a magma chamber undergoing continuous recharge, wall-rock assimilation and fractional crystallisation. From the model, a critical value of the ratio of basalt recharge-to-assimilation, (r/a)c, is deduced, which increases with decreasing crustal temperature. The r/a value must exceed (r/a)c to allow the volume of differentiated magma to increase, a prerequisite for developing large volumes of silicic magma. Strongly peraluminous (or S-type) magmas (NCI = 0·8–1), form under conditions of high crustal temperature and low basalt supply. Metaluminous or I-type granites form over a wide range of conditions (NCI = 0·1–1), generally where basalt supply is substantial. In individual long-lived volcanic centres, the large-volume high-silica ignimbrites are associated with the highest r/a and lowest NCI values, indicating that these magmas are typically differentiates of mantle-derived basaltic parents.
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DeGroat-Nelson, P. J., B. I. Cameron, J. H. Fink, and J. R. Holloway. "Hydrogen isotope analysis of rehydrated silicic lavas: implications for eruption mechanisms." Earth and Planetary Science Letters 185, no. 3-4 (February 2001): 331–41. http://dx.doi.org/10.1016/s0012-821x(00)00379-4.
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Poitrasson, Franck, and Thomas Zambardi. "An Earth–Moon silicon isotope model to track silicic magma origins." Geochimica et Cosmochimica Acta 167 (October 2015): 301–12. http://dx.doi.org/10.1016/j.gca.2015.07.005.
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Rocha, Brenda C., Joshua H. F. L. Davies, Valdecir A. Janasi, Urs Schaltegger, Antônio J. R. Nardy, Nicolas D. Greber, Ana Carolina F. Lucchetti, and Liza A. Polo. "Rapid eruption of silicic magmas from the Paraná magmatic province (Brazil) did not trigger the Valanginian event." Geology 48, no. 12 (July 31, 2020): 1174–78. http://dx.doi.org/10.1130/g47766.1.
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Abstract The Valanginian Stage is marked by a period of global positive δ13C carbon cycle perturbation and biotic crises, which are collectively referred to as the Valanginian event (VE). Many attempts have been made to link the Paraná-Etendeka large igneous province volcanism with the VE. However, currently there is no conclusive proof to support this hypothesis, since the timing and duration of the volcanic activity are not known with sufficient precision. In this study, we significantly revise the time scales of magmatism and environmental impact of the Paraná magmatic province (PMP) in Brazil with new high-precision zircon U-Pb ages from the low-Ti Palmas and high-Ti Chapecó sequences. Our data demonstrate that significant volumes of low-Ti silicic rocks from the PMP erupted rapidly at ca. 133.6 Ma within 0.12 ± 0.11 k.y. The age of the high-Ti Chapecó sequence from central PMP is constrained at ca. 132.9 Ma and thus extends the duration of magmatic activity by ∼700 k.y. Our new ages are systematically younger than previous ages and postdate the major positive carbon isotope excursion, indicating that PMP silicic magmatism did not trigger the VE but could have contributed to extending its duration. Within the framework of the stratigraphic column of the PMP, the earliest low-Ti basalts could have been responsible for the VE if they are at least 0.5 m.y. older than the low-Ti silicic rocks dated herein.
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NASH, B., M. PERKINS, J. CHRISTENSEN, D. LEE, and A. HALLIDAY. "The Yellowstone hotspot in space and time: Nd and Hf isotopes in silicic magmas." Earth and Planetary Science Letters 247, no. 1-2 (July 15, 2006): 143–56. http://dx.doi.org/10.1016/j.epsl.2006.04.030.
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Lu, Tian-Yu, Zhen-Yu He, and Reiner Klemd. "Identifying crystal accumulation and melt extraction during formation of high-silica granite." Geology 50, no. 2 (November 9, 2021): 216–21. http://dx.doi.org/10.1130/g49434.1.
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Abstract High-silica (>70 wt% SiO2) magmas are usually believed to form via shallow crustal–level fractional crystallization of intermediate magmas. However, the broad applicability of this model is controversial, because the required crystal-melt separation processes have rarely been documented globally up to now. The ca. 50 Ma Nyemo composite pluton of the Gangdese batholith belt in southern Tibet, which comprises intrusive rocks with intermediate- to high-silica compositions (65–78 wt%), offers a unique opportunity for substantiating the coexistence of extracted melts and complementary silicic cumulates in one of Earth's most complete transcrustal silicic magmatic systems. The Nyemo pluton intrusive rocks exhibit similar zircon Hf isotopic compositional ranges (mean εHf(t) = +5.7 to +8.3), suggesting a common, non-radiogenic magma source with crustal assimilation in the deep crust. Yet, these rocks have distinct geochemical characteristics. High-silica miarolitic and rapakivi granites are strongly depleted in Ba, Sr, and Eu, and their zircon trace elements show extremely low Eu/Eu* and Dy/Yb. In contrast, monzogranite is relatively enriched in Ba and Sr with minor Eu anomalies, and the zircon trace elements are characterized by relatively high Eu/Eu* and Dy/Yb. Therefore, we propose that the high-silica granites represent highly fractionated melt extracted from a mush reservoir at unusually low storage pressure (∼99–119 MPa), and that the monzogranite constitutes the complementary residual silicic cumulates.