Journal articles on the topic 'Isothermal conditions'

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1

Cano-Pleite, Eduardo, Mariano Rubio-Rubio, Néstor García-Hernando, and Antonio Soria-Verdugo. "Microalgae pyrolysis under isothermal and non-isothermal conditions." Algal Research 51 (October 2020): 102031. http://dx.doi.org/10.1016/j.algal.2020.102031.

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2

Medina, Sebastián F., Alberto Quispe, and Manuel Gómez. "Precipitation model in microalloyed steels both isothermal and continuous cooling conditions." Revista de Metalurgia 51, no. 4 (November 13, 2015): e056. http://dx.doi.org/10.3989/revmetalm.056.

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3

Chew, S., J. R. Griffiths, and Z. H. Stachurski. "The crystallization kinetics of polyethylene under isothermal and non-isothermal conditions." Polymer 30, no. 5 (May 1989): 874–81. http://dx.doi.org/10.1016/0032-3861(89)90185-7.

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4

Wang, Jinxing, and Haibo Zhao. "Pyrolysis kinetics of perfusion tubes under non-isothermal and isothermal conditions." Energy Conversion and Management 106 (December 2015): 1048–56. http://dx.doi.org/10.1016/j.enconman.2015.09.075.

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5

Bheemarasetti, J. V. Ram, J. D. Bapat, and T. Rajeswara Rao. "Drying Rates Under Non-isothermal Conditions." Indian Chemical Engineer 52, no. 2 (August 5, 2010): 99–105. http://dx.doi.org/10.1080/00194506.2010.485841.

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6

Lucchesi, Massimiliano, and Miroslav Šilhavý. "Il'yushin's conditions in non-isothermal plasticity." Archive for Rational Mechanics and Analysis 113, no. 2 (June 1991): 121–63. http://dx.doi.org/10.1007/bf00380414.

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7

Czerski, Grzegorz, Przemysław Grzywacz, and Katarzyna Śpiewak. "Comparison of CO2 gasification of coal in isothermal and non-isothermal conditions." E3S Web of Conferences 108 (2019): 02017. http://dx.doi.org/10.1051/e3sconf/201910802017.

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The thermogravimetric method allows to carry out measurements both in isothermal conditions for a given temperature and in non-isothermal conditions at a set heating rate. The aim of the work was to compare the process of gasification of the same coal in an atmosphere of CO2 under isothermal and non-isothermal conditions. The measurements were carried out with the use of DynTHERM Thermogravimetric analyzer by Rubotherm. Char derived from Polish bituminous coal “Janina” was used as material for gasification. In case of the isothermal method the measurements were performed at three temperatures – 850 °C, 900 °C and 950 °C, while in case of the non-isothermal method for three heating rates, i.e. 3 K/min, 5 K/min and 10 K/min. Based on the results obtained, kinetics curves of conversion degree of the gasification process were developed and kinetic parameters of the gasification reaction i.e. reaction order, activation energy and pre-exponential factor were determined. The values of the kinetic parameters obtained from measurements performed in isothermal and non-isothermal conditions were compared.
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8

Silva-Dias, Leonardo, and Alejandro Lopez-Castillo. "Turing patterns modulation by chemical gradient in isothermal and non-isothermal conditions." Physical Chemistry Chemical Physics 22, no. 14 (2020): 7507–15. http://dx.doi.org/10.1039/d0cp00650e.

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9

De Maio, Anna, Mansour El-Masry, Silvana Di Martino, Sergio Rossi, Umberto Bencivenga, Valentina Grano, Nadia Diano, Paolo Canciglia, and Damiano Gustavo Mita. "A novel packed-bed bioreactor operating under isothermal and non-isothermal conditions." Biotechnology and Bioengineering 86, no. 3 (2004): 308–16. http://dx.doi.org/10.1002/bit.20057.

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10

Ferreira, Bárbara D. L., Natália R. S. Araújo, Raphael F. Ligório, Fabrício J. P. Pujatti, Wagner N. Mussel, Maria Irene Yoshida, and Rita C. O. Sebastião. "Kinetic thermal decomposition studies of thalidomide under non-isothermal and isothermal conditions." Journal of Thermal Analysis and Calorimetry 134, no. 1 (July 25, 2018): 773–82. http://dx.doi.org/10.1007/s10973-018-7568-1.

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11

Cao, Jianwei, Jinshan Lu, Longxiang Jiang, and Zhi Wang. "Oxidation behavior of metallurgical silicon slag under non-isothermal and isothermal conditions." Journal of Thermal Analysis and Calorimetry 124, no. 2 (December 10, 2015): 593–99. http://dx.doi.org/10.1007/s10973-015-5157-0.

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12

Hanzlíková, Klára, Stanislav Vĕchet, Jan Kohout, and Josef Zapletal. "The Optimization of the Isothermal Transformation Dwell of the ADI Obtained at Transformation Temperature of 380 °C." Materials Science Forum 567-568 (December 2007): 337–40. http://dx.doi.org/10.4028/www.scientific.net/msf.567-568.337.

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The structure of austempered ductile iron (ADI) matrix and consequently its mechanical properties are influenced by the heat treatment conditions, above all by the temperature and dwell length of isothermal transformation. The paper is focused on deeper understanding the interrelation between matrix mixture composition and static mechanical properties of ADI in dependence on the isothermal transformation dwell. Practical aim of the paper is to find the optimal isothermal transformation dwell range for ADI isothermally transformed at the temperature of 380 °C with emphasis on the level of static mechanical properties in tension. Microstructure and mechanical properties changes that proceed during isothermal transformation are observed and evaluated for the transformation dwells of 2, 5, 10, 25, 60, 120, 270, and 540 minutes.
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13

Ebner, P. P., M. Schneebeli, and A. Steinfeld. "Tomography-based monitoring of isothermal snow metamorphism under advective conditions." Cryosphere Discussions 9, no. 1 (February 18, 2015): 1021–45. http://dx.doi.org/10.5194/tcd-9-1021-2015.

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Abstract. Time-lapse X-ray micro-tomography was used to investigate the structural dynamics of isothermal snow metamorphism exposed to an advective airflow. Diffusion and advection across the snow pores were analysed in controlled laboratory experiments. The 3-D digital geometry obtained by tomographic scans was used in direct pore-level numerical simulations to determine the effective transport properties. The results showed that isothermal advection with saturated air have no influence on the coarsening rate that is typical for isothermal snow metamorphism. Diffusion originating in the Kelvin effect between snow structures dominates and is the main transport process in isothermal snow packs.
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14

Zhu, Mingmei, Sikun Peng, Kunchi Jiang, Jie Luo, Yong Zhong, and Ping Tang. "Fluid Flow and Heat Transfer Behaviors under Non-Isothermal Conditions in a Four-Strand Tundish." Metals 12, no. 5 (May 13, 2022): 840. http://dx.doi.org/10.3390/met12050840.

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In the continuous casting process, the fluid flow of molten steel in the tundish is in a non-isothermal state. Because of the geometric shape and process parameters of a multi-strand tundish, the fluid flow behavior of each strand is quite inhomogeneous, and the difference in temperature, composition and inclusion content between each strand is great, which directly affects the quality of the steel products. In this paper, the fluid flow, heat transfer phenomena and inclusion trajectories in a four-strand tundish with and without flow-control devices (FCDs) are investigated using a water model and numerical simulation in isothermal and non-isothermal conditions. The results show that natural convection has a significant influence on the flow pattern and temperature distributions of molten steel in the tundish. Without FCDs, the average residence times of the molten steel in the tundish obtained by the isothermal water model, non-isothermal water model and non-isothermal mathematical model were 251.2 s, 263.3 s and 266.0 s, respectively, and the dead zone volumes were 21.51%, 29.26% and 28.21%, respectively. With FCDs, the average residence times of the molten steel obtained by the isothermal water model, non-isothermal water model and non-isothermal mathematical model were 293.0 s, 304.0 s and 305.2 s, respectively, and the dead zone volumes were 43.98%, 50.23% and 52.78%, respectively. The flow characteristics of the molten steel in the tundish were different between the isothermal and non-isothermal conditions. Compared with isothermal conditions, the numerical simulation results were closer to the water model results in non-isothermal conditions. The trial results showed that the fluid flow in a tundish has a non-isothermal characteristic, and the results in non-isothermal conditions can better reflect the actual fluid flow and heat transfer behaviors of molten steel in a tundish.
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15

Ebner, P. P., M. Schneebeli, and A. Steinfeld. "Tomography-based monitoring of isothermal snow metamorphism under advective conditions." Cryosphere 9, no. 4 (July 30, 2015): 1363–71. http://dx.doi.org/10.5194/tc-9-1363-2015.

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Abstract. Time-lapse X-ray microtomography was used to investigate the structural dynamics of isothermal snow metamorphism exposed to an advective airflow. The effect of diffusion and advection across the snow pores on the snow microstructure were analysed in controlled laboratory experiments and possible effects on natural snowpacks discussed. The 3-D digital geometry obtained by tomographic scans was used in direct pore-level numerical simulations to determine the effective permeability. The results showed that isothermal advection with saturated air have no influence on the coarsening rate that is typical for isothermal snow metamorphism. Isothermal snow metamorphism is driven by sublimation deposition caused by the Kelvin effect and is the limiting factor independently of the transport regime in the pores.
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16

Damm, E. Buddy, Robert E. Hackenberg, and Chester J. van Tyne. "On the Formation of a Non-Traditional Pearlite Morphology." Materials Science Forum 539-543 (March 2007): 4544–49. http://dx.doi.org/10.4028/www.scientific.net/msf.539-543.4544.

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Continuous cooling and isothermal dilatometry was performed for a binary Fe-0.3C alloy and a ternary Fe-0.3C-1.0Mn alloy at slow (< 0.1 oC/s) cooling rates and isothermally at temperatures below the equilibrium eutectoid reaction temperature but above the bainite start temperature (625 to 715 oC). Some of the test conditions produced an unusual morphology in which fine scale ‘sub-grains’ are decorated with carbide, with additional discrete carbide particles inside the ‘sub-grains’. A detailed investigation into the network carbide formation indicates formation during austenite decomposition, as opposed to a post lamellar transformation coarsening or spheroidization reaction, but only for select temperatures, and apparently only during isothermal conditions.
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17

Roura, P., J. Costa, and J. Farjas. "Is sintering enhanced under non-isothermal conditions?" Materials Science and Engineering: A 337, no. 1-2 (November 2002): 248–53. http://dx.doi.org/10.1016/s0921-5093(02)00029-1.

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18

Lervik, Anders, Signe Kjelstrup, and Hong Qian. "Michaelis–Menten kinetics under non-isothermal conditions." Physical Chemistry Chemical Physics 17, no. 2 (2015): 1317–24. http://dx.doi.org/10.1039/c4cp04334k.

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19

Andritsos, N., M. Kontopoulou, A. J. Karabelas, and P. G. Koutsoukos. "Calcium carbonate deposit formation under isothermal conditions." Canadian Journal of Chemical Engineering 74, no. 6 (December 1996): 911–19. http://dx.doi.org/10.1002/cjce.5450740614.

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20

Joshi, S. C., J. C. Su, C. M. Liang, and Y. C. Lam. "Gelation of methylcellulose hydrogels under isothermal conditions." Journal of Applied Polymer Science 107, no. 4 (2007): 2101–8. http://dx.doi.org/10.1002/app.27350.

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21

Volodin, V. N., V. E. Khrapunov, G. S. Ruzakhunova, and I. A. Marki. "Determining a liquidus line under isothermal conditions." Russian Journal of Physical Chemistry A 85, no. 11 (October 7, 2011): 2047–49. http://dx.doi.org/10.1134/s0036024411110331.

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22

Le Marc, Y., J. Baranyi, and H. Fujikawa. "Predictions under Isothermal and Dynamically Changing Conditions." Applied and Environmental Microbiology 73, no. 7 (April 1, 2007): 2402–3. http://dx.doi.org/10.1128/aem.01436-06.

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23

Patrakov, Yury F., and Sergey V. Denisov. "Barzas coal liquefaction under non-isothermal conditions." Fuel 70, no. 2 (February 1991): 267–70. http://dx.doi.org/10.1016/0016-2361(91)90164-6.

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24

Rayhani, M. T., R. K. Rowe, R. W. I. Brachman, W. A. Take, and G. Siemens. "Factors affecting GCL hydration under isothermal conditions." Geotextiles and Geomembranes 29, no. 6 (December 2011): 525–33. http://dx.doi.org/10.1016/j.geotexmem.2011.06.001.

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25

Gasparini, Elisa, Serena C. Tarantino, Paolo Ghigna, M. Pia Riccardi, Erika I. Cedillo-González, Cristina Siligardi, and Michele Zema. "Thermal dehydroxylation of kaolinite under isothermal conditions." Applied Clay Science 80-81 (August 2013): 417–25. http://dx.doi.org/10.1016/j.clay.2013.07.017.

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26

Shvets, Ludmila, and Elena Trukhanska. "DEFORMATION OF ALUMINUM ALLOYS IN ISOTHERMAL CONDITIONS." ENGINEERING, ENERGY, TRANSPORT AIC, no. 3(114) (September 28, 2021): 68–74. http://dx.doi.org/10.37128/2520-6168-2021-3-8.

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It has been scientifically proven that aluminum, more than other materials, meets the requirements of production, storage and processing of various foods. Therefore, the prospects for its use in the agro-industrial complex are quite high. At the same time, the process of developing such materials should be improved and promoted. Aluminum alloys are widely used in the aviation industry, in mechanical engineering and in agricultural production, due to their properties and light metal consumption. Alloys are resistant to water, they are not afraid of corrosion, sunlight, easily disinfected. All these properties are best suited for the use of aluminum in the storage of both cereals and livestock products. Moisture, dangerous molds, rodents and various insects are released and absorbed in storage. Aluminum has a high thermal conductivity and reflectivity, which reduce the risk of moisture condensation, which normalizes storage. The smoothness of this material suggests that the walls of aluminum structures collect much less dust. The proposed isothermal method of hot deformation of aluminum alloys in the processing of metals by pressure, differs from traditional deformation, and the temperature of the heated workpiece and the deforming tool is kept constant, close to the upper limit of forging temperatures, throughout the process. The deformation of the metal under isometric conditions and approximate deformations is characterized by an increase in ductility compared with ductility when machined in a cold tool. This is due to the lower rate of deformation, the lower limit of which is limited only by the productivity of the process. As a result, the "filling time" of defects that occur during metal deformation increases, the temperature stress in the workpiece volume decreases, the deformation becomes more uniform.
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27

Gil, Maria M., Fátima A. Miller, Teresa R. S. Brandão, and Cristina L. M. Silva. "Predictions of Microbial Thermal Inactivation in Solid Foods: Isothermal and Non-isothermal Conditions." Procedia Food Science 7 (2016): 154–57. http://dx.doi.org/10.1016/j.profoo.2016.06.006.

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28

Zhang, Xin, Honghu Deng, Xueyi Hou, Rongliang Qiu, and Zhihua Chen. "Pyrolytic behavior and kinetic of wood sawdust at isothermal and non-isothermal conditions." Renewable Energy 142 (November 2019): 284–94. http://dx.doi.org/10.1016/j.renene.2019.04.115.

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29

Ahrné, L. M., J. Frías, F. A. R. Oliveira, and R. P. Singh. "MODELLING TEXTURAL CHANGES OF VEGETABLES DURING ACIDIFICATION UNDER ISOTHERMAL AND NON-ISOTHERMAL CONDITIONS." Acta Horticulturae, no. 566 (December 2001): 323–28. http://dx.doi.org/10.17660/actahortic.2001.566.41.

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30

Zarębski, J., and J. Dąbrowski. "Investigations of SiC merged pin Schottky diodes under isothermal and non-isothermal conditions." International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 24, no. 3 (April 20, 2011): 207–17. http://dx.doi.org/10.1002/jnm.771.

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31

Rojas, R. M., and M. L. de Paz. "Kinetics of dehydration of uranyl fumarate dihydrate under isothermal and non-isothermal conditions." Thermochimica Acta 85 (April 1985): 95–98. http://dx.doi.org/10.1016/0040-6031(85)85538-6.

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32

Seo, Myung Won, Sang Done Kim, See Hoon Lee, and Jae Goo Lee. "Pyrolysis characteristics of coal and RDF blends in non-isothermal and isothermal conditions." Journal of Analytical and Applied Pyrolysis 88, no. 2 (July 2010): 160–67. http://dx.doi.org/10.1016/j.jaap.2010.03.010.

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33

Urbanovici, E., and E. Segal. "Some critical considerations concerning the jmayk equation in isothermal and non-isothermal conditions." Thermochimica Acta 147, no. 2 (July 1989): 231–40. http://dx.doi.org/10.1016/0040-6031(89)85178-0.

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34

Lu, Gui-bin, Ting Yang, Li-ping Chen, Yi-shan Zhou, and Wang-hua Chen. "Thermal decomposition kinetics of 2-ethylhexyl nitrate under non-isothermal and isothermal conditions." Journal of Thermal Analysis and Calorimetry 124, no. 1 (November 2, 2015): 471–78. http://dx.doi.org/10.1007/s10973-015-5099-6.

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35

Mohamed, Mona A., and Ali K. Attia. "Thermal behavior and decomposition kinetics of cinnarizine under isothermal and non-isothermal conditions." Journal of Thermal Analysis and Calorimetry 127, no. 2 (May 24, 2016): 1751–56. http://dx.doi.org/10.1007/s10973-016-5551-2.

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36

Fandaruff, C., A. M. Araya-Sibaja, R. N. Pereira, C. R. D. Hoffmeister, H. V. A. Rocha, and M. A. S. Silva. "Thermal behavior and decomposition kinetics of efavirenz under isothermal and non-isothermal conditions." Journal of Thermal Analysis and Calorimetry 115, no. 3 (July 23, 2013): 2351–56. http://dx.doi.org/10.1007/s10973-013-3306-x.

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37

Papageorgiou, George Z., Dimitris S. Achilias, and Dimitris N. Bikiaris. "Crystallization Kinetics of Biodegradable Poly(butylene succinate) under Isothermal and Non-Isothermal Conditions." Macromolecular Chemistry and Physics 208, no. 12 (June 19, 2007): 1250–64. http://dx.doi.org/10.1002/macp.200700084.

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38

KRAEV, Viacheslav. "Experimental research of turbulent flow frequency spectra." INCAS BULLETIN 12, no. 2 (June 5, 2020): 87–97. http://dx.doi.org/10.13111/2066-8201.2020.12.2.8.

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Hydraulic and heat transfer processes play a very important role in the design and prototyping of aerospace technology. In most cases this technique works under non-isothermal conditions. Non-isothermal conditions may significantly affect heat transfer and hydrodynamic process. Fundamental research of Non-isothermal turbulent flow is required for further engineering modeling. Models for unsteady processes calculation must be based on fundamental turbulent structure research. Moscow Aviation Institute National Research University (MAI) has been building non-isothermal turbulent flow structures since 1989. An experimental facility was designed to provide gas flow heating. Experimental data of a turbulent gas flow structure in isothermal and non-isothermal conditions are presented. The frequency spectra of axial and radial velocity pulsations are based on experimental data received. The results of experimental turbulent flow research demonstrate fundamental non-isothermal processes influence on the flow structure. The main results of non-isothermal experimental research show that there are three specific zones in turbulent flow structure: wall area, maximal turbulent structure transformation and flow core. The analysis of non-isothermal conditions influence on turbulent pulsations generation and development mechanisms is presented. The results show significant distinction in turbulent flow spectra between isothermal and non-isothermal conditions. The present paper describes a method of experimental research, methodology of data processing and non-isothermal turbulent flow spectra results.
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39

Chebaro, H. C., and K. P. Hallinan. "Boundary Conditions for an Evaporating Thin Film for Isothermal Interfacial Conditions." Journal of Heat Transfer 115, no. 3 (August 1, 1993): 816–19. http://dx.doi.org/10.1115/1.2910764.

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40

Sanaye, S., and J. Mahmoudimehr. "Technical Assessment of Isothermal and Non-Isothermal Modelings of Natural Gas Pipeline Operational Conditions." Oil & Gas Science and Technology – Revue d’IFP Energies nouvelles 67, no. 3 (May 2012): 435–49. http://dx.doi.org/10.2516/ogst/2011117.

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41

Alves, Ricardo, Thaís Vitória da Silva Reis, Luis Carlos Cides da Silva, Silvia Storpírtis, Lucildes Pita Mercuri, and Jivaldo do Rosário Matos. "Thermal behavior and decomposition kinetics of rifampicin polymorphs under isothermal and non-isothermal conditions." Brazilian Journal of Pharmaceutical Sciences 46, no. 2 (June 2010): 343–51. http://dx.doi.org/10.1590/s1984-82502010000200022.

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The thermal behavior of two polymorphic forms of rifampicin was studied by DSC and TG/DTG. The thermoanalytical results clearly showed the differences between the two crystalline forms. Polymorph I was the most thermally stable form, the DSC curve showed no fusion for this species and the thermal decomposition process occurred around 245 ºC. The DSC curve of polymorph II showed two consecutive events, an endothermic event (Tpeak = 193.9 ºC) and one exothermic event (Tpeak = 209.4 ºC), due to a melting process followed by recrystallization, which was attributed to the conversion of form II to form I. Isothermal and non-isothermal thermogravimetric methods were used to determine the kinetic parameters of the thermal decomposition process. For non-isothermal experiments, the activation energy (Ea) was derived from the plot of Log β vs 1/T, yielding values for polymorph form I and II of 154 and 123 kJ mol-1, respectively. In the isothermal experiments, the Ea was obtained from the plot of lnt vs 1/T at a constant conversion level. The mean values found for form I and form II were 137 and 144 kJ mol-1, respectively.
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42

Cervantes, A. "FLUID DYNAMICS AROUND FLAT-END CYLINDRICAL QUENCH PROBES UNDER ISOTHERMAL AND NON-ISOTHERMAL CONDITIONS." Revista Mexicana de Ingeniería Química 17, no. 2 (March 26, 2018): 707–21. http://dx.doi.org/10.24275/uam/izt/dcbi/revmexingquim/2018v17n2/cervantes.

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43

CHEN, Chao-yi, Hui-lin CHEN, Ya-qin MA, and Jing LIU. "Hydrogen desorption kinetics mechanism of Mg–Ni hydride under isothermal and non-isothermal conditions." Transactions of Nonferrous Metals Society of China 26, no. 1 (January 2016): 160–66. http://dx.doi.org/10.1016/s1003-6326(16)64101-8.

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44

Sangwai, Jitendra S., Deoki N. Saraf, and Santosh K. Gupta. "Viscosity of bulk free radical polymerizing systems under near-isothermal and non-isothermal conditions." Polymer 47, no. 9 (April 2006): 3028–35. http://dx.doi.org/10.1016/j.polymer.2006.03.007.

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45

Georgiadis, G., A. E. Tekkaya, P. Weigert, S. Horneber, and P. Aliaga Kuhnle. "Formability analysis of thin press hardening steel sheets under isothermal and non-isothermal conditions." International Journal of Material Forming 10, no. 3 (March 3, 2016): 405–19. http://dx.doi.org/10.1007/s12289-016-1289-4.

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46

Jeong, Ha Myung, Myung Won Seo, Sang Mun Jeong, Byung Ki Na, Sang Jun Yoon, Jae Goo Lee, and Woon Jae Lee. "Pyrolysis kinetics of coking coal mixed with biomass under non-isothermal and isothermal conditions." Bioresource Technology 155 (March 2014): 442–45. http://dx.doi.org/10.1016/j.biortech.2014.01.005.

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47

Salama, Nahla N., Mona A. Mohammad, and Taghreed A. Fattah. "Thermal behavior study and decomposition kinetics of amisulpride under non-isothermal and isothermal conditions." Journal of Thermal Analysis and Calorimetry 120, no. 1 (January 31, 2015): 953–58. http://dx.doi.org/10.1007/s10973-015-4419-1.

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48

Mohamed, Mona A., Shimaa A. Atty, and Craig E. Banks. "Thermal decomposition kinetics of the antiparkinson drug “entacapone” under isothermal and non-isothermal conditions." Journal of Thermal Analysis and Calorimetry 130, no. 3 (September 12, 2017): 2359–67. http://dx.doi.org/10.1007/s10973-017-6664-y.

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49

Felix, Fabiana S., L. C. Cides da Silva, L. Angnes, and J. R. Matos. "Thermal behavior study and decomposition kinetics of salbutamol under isothermal and non-isothermal conditions." Journal of Thermal Analysis and Calorimetry 95, no. 3 (August 13, 2008): 877–80. http://dx.doi.org/10.1007/s10973-007-8188-3.

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Bertol, C. D., A. P. Cruz, H. K. Stulzer, F. S. Murakami, and M. A. S. Silva. "Thermal decomposition kinetics and compatibility studies of primaquine under isothermal and non-isothermal conditions." Journal of Thermal Analysis and Calorimetry 102, no. 1 (November 3, 2009): 187–92. http://dx.doi.org/10.1007/s10973-009-0540-3.

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